[{"language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Electrochemistry","Surfaces","Coatings and Films","Condensed Matter Physics","Renewable Energy","Sustainability and the Environment","Electronic","Optical and Magnetic Materials"],"abstract":[{"text":"Due to the hydrolytic instability of LiPF6 in carbonate-based solvents, HF is a typical impurity in Li-ion battery electrolytes. HF significantly influences the performance of Li-ion batteries, for example by impacting the formation of the solid electrolyte interphase at the anode and by affecting transition metal dissolution at the cathode. Additionally, HF complicates studying fundamental interfacial electrochemistry of Li-ion battery electrolytes, such as direct anion reduction, because it is electrocatalytically relatively unstable, resulting in LiF passivation layers. Methods to selectively remove ppm levels of HF from LiPF6-containing carbonate-based electrolytes are limited. We introduce and benchmark a simple yet efficient electrochemical in situ method to selectively remove ppm amounts of HF from LiPF6-containing carbonate-based electrolytes. The basic idea is the application of a suitable potential to a high surface-area metallic electrode upon which only HF reacts (electrocatalytically) while all other electrolyte components are unaffected under the respective conditions.","lang":"eng"}],"publication":"Journal of The Electrochemical Society","title":"Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes","date_created":"2024-03-08T06:27:10Z","publisher":"The Electrochemical Society","year":"2024","quality_controlled":"1","article_type":"original","user_id":"23547","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"}],"_id":"52372","status":"public","type":"journal_article","main_file_link":[{"open_access":"1","url":"https://dx.doi.org/10.1149/1945-7111/ad30d3"}],"doi":"10.1149/1945-7111/ad30d3","author":[{"last_name":"Ge","full_name":"Ge, Xiaokun","first_name":"Xiaokun"},{"last_name":"Huck","full_name":"Huck, Marten","first_name":"Marten"},{"last_name":"Kuhlmann","full_name":"Kuhlmann, Andreas","first_name":"Andreas"},{"first_name":"Michael","id":"23547","full_name":"Tiemann, Michael","last_name":"Tiemann","orcid":"0000-0003-1711-2722"},{"full_name":"Weinberger, Christian","id":"11848","last_name":"Weinberger","first_name":"Christian"},{"last_name":"Xu","full_name":"Xu, Xiaodan","first_name":"Xiaodan"},{"first_name":"Zhenyu","full_name":"Zhao, Zhenyu","last_name":"Zhao"},{"last_name":"Steinrueck","full_name":"Steinrueck, Hans-Georg","first_name":"Hans-Georg"}],"volume":171,"oa":"1","date_updated":"2024-03-25T17:01:09Z","citation":{"ieee":"X. Ge <i>et al.</i>, “Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes,” <i>Journal of The Electrochemical Society</i>, vol. 171, p. 030552, 2024, doi: <a href=\"https://doi.org/10.1149/1945-7111/ad30d3\">10.1149/1945-7111/ad30d3</a>.","chicago":"Ge, Xiaokun, Marten Huck, Andreas Kuhlmann, Michael Tiemann, Christian Weinberger, Xiaodan Xu, Zhenyu Zhao, and Hans-Georg Steinrueck. “Electrochemical Removal of HF from Carbonate-Based LiPF6-Containing Li-Ion Battery Electrolytes.” <i>Journal of The Electrochemical Society</i> 171 (2024): 030552. <a href=\"https://doi.org/10.1149/1945-7111/ad30d3\">https://doi.org/10.1149/1945-7111/ad30d3</a>.","ama":"Ge X, Huck M, Kuhlmann A, et al. Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes. <i>Journal of The Electrochemical Society</i>. 2024;171:030552. doi:<a href=\"https://doi.org/10.1149/1945-7111/ad30d3\">10.1149/1945-7111/ad30d3</a>","bibtex":"@article{Ge_Huck_Kuhlmann_Tiemann_Weinberger_Xu_Zhao_Steinrueck_2024, title={Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes}, volume={171}, DOI={<a href=\"https://doi.org/10.1149/1945-7111/ad30d3\">10.1149/1945-7111/ad30d3</a>}, journal={Journal of The Electrochemical Society}, publisher={The Electrochemical Society}, author={Ge, Xiaokun and Huck, Marten and Kuhlmann, Andreas and Tiemann, Michael and Weinberger, Christian and Xu, Xiaodan and Zhao, Zhenyu and Steinrueck, Hans-Georg}, year={2024}, pages={030552} }","short":"X. Ge, M. Huck, A. Kuhlmann, M. Tiemann, C. Weinberger, X. Xu, Z. Zhao, H.-G. Steinrueck, Journal of The Electrochemical Society 171 (2024) 030552.","mla":"Ge, Xiaokun, et al. “Electrochemical Removal of HF from Carbonate-Based LiPF6-Containing Li-Ion Battery Electrolytes.” <i>Journal of The Electrochemical Society</i>, vol. 171, The Electrochemical Society, 2024, p. 030552, doi:<a href=\"https://doi.org/10.1149/1945-7111/ad30d3\">10.1149/1945-7111/ad30d3</a>.","apa":"Ge, X., Huck, M., Kuhlmann, A., Tiemann, M., Weinberger, C., Xu, X., Zhao, Z., &#38; Steinrueck, H.-G. (2024). Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes. <i>Journal of The Electrochemical Society</i>, <i>171</i>, 030552. <a href=\"https://doi.org/10.1149/1945-7111/ad30d3\">https://doi.org/10.1149/1945-7111/ad30d3</a>"},"page":"030552","intvolume":"       171","publication_status":"published","publication_identifier":{"issn":["0013-4651","1945-7111"]}},{"date_updated":"2023-05-03T08:27:13Z","publisher":"The Electrochemical Society","date_created":"2023-01-30T16:08:15Z","author":[{"last_name":"Kappler","full_name":"Kappler, Julian","first_name":"Julian"},{"first_name":"Güldeniz","last_name":"Tonbul","orcid":"0000-0002-0999-9995","id":"89054","full_name":"Tonbul, Güldeniz"},{"first_name":"Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","id":"48467","full_name":"Schoch, Roland"},{"full_name":"Murugan, Saravanakumar","last_name":"Murugan","first_name":"Saravanakumar"},{"first_name":"Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011","full_name":"Nowakowski, Michał","id":"78878"},{"full_name":"Lange, Pia Lena","last_name":"Lange","first_name":"Pia Lena"},{"first_name":"Sina Vanessa","last_name":"Klostermann","full_name":"Klostermann, Sina Vanessa"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"full_name":"Schleid, Thomas","last_name":"Schleid","first_name":"Thomas"},{"last_name":"Kästner","full_name":"Kästner, Johannes","first_name":"Johannes"},{"first_name":"Michael Rudolf","full_name":"Buchmeiser, Michael Rudolf","last_name":"Buchmeiser"}],"volume":170,"title":"Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries","doi":"10.1149/1945-7111/acb2fa","publication_status":"published","publication_identifier":{"issn":["0013-4651","1945-7111"]},"issue":"1","year":"2023","citation":{"mla":"Kappler, Julian, et al. “Understanding the Redox Mechanism of Sulfurized Poly(Acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries.” <i>Journal of The Electrochemical Society</i>, vol. 170, no. 1, 010526, The Electrochemical Society, 2023, doi:<a href=\"https://doi.org/10.1149/1945-7111/acb2fa\">10.1149/1945-7111/acb2fa</a>.","bibtex":"@article{Kappler_Tonbul_Schoch_Murugan_Nowakowski_Lange_Klostermann_Bauer_Schleid_Kästner_et al._2023, title={Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries}, volume={170}, DOI={<a href=\"https://doi.org/10.1149/1945-7111/acb2fa\">10.1149/1945-7111/acb2fa</a>}, number={1010526}, journal={Journal of The Electrochemical Society}, publisher={The Electrochemical Society}, author={Kappler, Julian and Tonbul, Güldeniz and Schoch, Roland and Murugan, Saravanakumar and Nowakowski, Michał and Lange, Pia Lena and Klostermann, Sina Vanessa and Bauer, Matthias and Schleid, Thomas and Kästner, Johannes and et al.}, year={2023} }","short":"J. Kappler, G. Tonbul, R. Schoch, S. Murugan, M. Nowakowski, P.L. Lange, S.V. Klostermann, M. Bauer, T. Schleid, J. Kästner, M.R. Buchmeiser, Journal of The Electrochemical Society 170 (2023).","apa":"Kappler, J., Tonbul, G., Schoch, R., Murugan, S., Nowakowski, M., Lange, P. L., Klostermann, S. V., Bauer, M., Schleid, T., Kästner, J., &#38; Buchmeiser, M. R. (2023). Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries. <i>Journal of The Electrochemical Society</i>, <i>170</i>(1), Article 010526. <a href=\"https://doi.org/10.1149/1945-7111/acb2fa\">https://doi.org/10.1149/1945-7111/acb2fa</a>","ama":"Kappler J, Tonbul G, Schoch R, et al. Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries. <i>Journal of The Electrochemical Society</i>. 2023;170(1). doi:<a href=\"https://doi.org/10.1149/1945-7111/acb2fa\">10.1149/1945-7111/acb2fa</a>","chicago":"Kappler, Julian, Güldeniz Tonbul, Roland Schoch, Saravanakumar Murugan, Michał Nowakowski, Pia Lena Lange, Sina Vanessa Klostermann, et al. “Understanding the Redox Mechanism of Sulfurized Poly(Acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries.” <i>Journal of The Electrochemical Society</i> 170, no. 1 (2023). <a href=\"https://doi.org/10.1149/1945-7111/acb2fa\">https://doi.org/10.1149/1945-7111/acb2fa</a>.","ieee":"J. Kappler <i>et al.</i>, “Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries,” <i>Journal of The Electrochemical Society</i>, vol. 170, no. 1, Art. no. 010526, 2023, doi: <a href=\"https://doi.org/10.1149/1945-7111/acb2fa\">10.1149/1945-7111/acb2fa</a>."},"intvolume":"       170","_id":"40981","user_id":"89054","department":[{"_id":"35"},{"_id":"306"}],"article_number":"010526","keyword":["Materials Chemistry","Electrochemistry","Surfaces","Coatings and Films","Condensed Matter Physics","Renewable Energy","Sustainability and the Environment","Electronic","Optical and Magnetic Materials"],"language":[{"iso":"eng"}],"type":"journal_article","publication":"Journal of The Electrochemical Society","abstract":[{"text":"Room temperature sodium-sulfur (RT Na-S) batteries are considered potential candidates for stationary power storage applications due to their low cost, broad active material availability and low toxicity. Challenges, such as high volume expansion of the S-cathode upon discharge, low electronic conductivity of S as active material and herewith limited rate capability as well as the shuttling of polysulfides (PSs) as intermediates often impede the cycle stability and practical application of Na-S batteries. Sulfurized poly(acrylonitrile) (SPAN) inherently inhibits the shuttling of PSs and shows compatibility with carbonate-based electrolytes, however, its exact redox mechanism remained unclear to date. Herein, we implement a commercially available and simple electrolyte into the Na-SPAN cell chemistry and demonstrate its high rate and cycle stability. Through the application of in situ techniques utilizing electronic impedance spectroscopy (EIS) and X-ray absorption spectroscopy (XAS) at different depths of charge and discharge, an insight into SPAN’s redox chemistry is obtained.","lang":"eng"}],"status":"public"},{"type":"journal_article","publication":"Journal of The Electrochemical Society","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title>\r\n               <jats:p>Batteries capable of extreme fast-charging (XFC) are a necessity for the deployment of electric vehicles. Material properties of electrodes and electrolytes along with cell parameters such as stack pressure and temperature have coupled, synergistic, and sometimes deleterious effects on fast-charging performance. We develop a new experimental testbed that allows precise and conformal application of electrode stack pressure. We focus on cell capacity degradation using single-layer pouch cells with graphite anodes, LiNi0.5Mn0.3Co0.2O2 (NMC532) cathodes, and carbonate-based electrolyte. In the tested range (10 – 125 psi), cells cycled at higher pressure show higher capacity and less capacity fading. Additionally, Li plating decreases with increasing pressure as observed with scanning electron microscopy (SEM) and optical imaging. While the loss of Li inventory from Li plating is the largest contributor to capacity fade, electrochemical and SEM examination of the NMC cathodes after XFC experiments show increased secondary particle damage at lower pressure. We infer that the better performance at higher pressure is due to more homogenous reactions of active materials across the electrode and less polarization through the electrode thickness. Our study emphasizes the importance of electrode stack pressure in XFC batteries and highlights its subtle role in cell conditions.</jats:p>"}],"status":"public","_id":"30920","user_id":"84268","department":[{"_id":"633"}],"keyword":["Materials Chemistry","Electrochemistry","Surfaces","Coatings and Films","Condensed Matter Physics","Renewable Energy","Sustainability and the Environment","Electronic","Optical and Magnetic Materials"],"language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"issn":["0013-4651","1945-7111"]},"year":"2022","citation":{"bibtex":"@article{Cao_Steinrück_Paul_Dunlop_Trask_Jansen_Kasse_Thampy_Yusuf_Nelson Weker_et al._2022, title={Conformal Pressure and Fast-Charging Li-Ion Batteries}, volume={169}, DOI={<a href=\"https://doi.org/10.1149/1945-7111/ac653f\">10.1149/1945-7111/ac653f</a>}, journal={Journal of The Electrochemical Society}, publisher={The Electrochemical Society}, author={Cao, Chuntian and Steinrück, Hans-Georg and Paul, Partha P and Dunlop, Alison R. and Trask, Stephen E. and Jansen, Andrew and Kasse, Robert M and Thampy, Vivek and Yusuf, Maha and Nelson Weker, Johanna and et al.}, year={2022}, pages={040540} }","mla":"Cao, Chuntian, et al. “Conformal Pressure and Fast-Charging Li-Ion Batteries.” <i>Journal of The Electrochemical Society</i>, vol. 169, The Electrochemical Society, 2022, p. 040540, doi:<a href=\"https://doi.org/10.1149/1945-7111/ac653f\">10.1149/1945-7111/ac653f</a>.","short":"C. Cao, H.-G. Steinrück, P.P. Paul, A.R. Dunlop, S.E. Trask, A. Jansen, R.M. Kasse, V. Thampy, M. Yusuf, J. Nelson Weker, B. Shyam, R. Subbaraman, K. Davis, C.M. Johnston, C.J. Takacs, M. Toney, Journal of The Electrochemical Society 169 (2022) 040540.","apa":"Cao, C., Steinrück, H.-G., Paul, P. P., Dunlop, A. R., Trask, S. E., Jansen, A., Kasse, R. M., Thampy, V., Yusuf, M., Nelson Weker, J., Shyam, B., Subbaraman, R., Davis, K., Johnston, C. M., Takacs, C. J., &#38; Toney, M. (2022). Conformal Pressure and Fast-Charging Li-Ion Batteries. <i>Journal of The Electrochemical Society</i>, <i>169</i>, 040540. <a href=\"https://doi.org/10.1149/1945-7111/ac653f\">https://doi.org/10.1149/1945-7111/ac653f</a>","chicago":"Cao, Chuntian, Hans-Georg Steinrück, Partha P Paul, Alison R. Dunlop, Stephen E. Trask, Andrew Jansen, Robert M Kasse, et al. “Conformal Pressure and Fast-Charging Li-Ion Batteries.” <i>Journal of The Electrochemical Society</i> 169 (2022): 040540. <a href=\"https://doi.org/10.1149/1945-7111/ac653f\">https://doi.org/10.1149/1945-7111/ac653f</a>.","ieee":"C. Cao <i>et al.</i>, “Conformal Pressure and Fast-Charging Li-Ion Batteries,” <i>Journal of The Electrochemical Society</i>, vol. 169, p. 040540, 2022, doi: <a href=\"https://doi.org/10.1149/1945-7111/ac653f\">10.1149/1945-7111/ac653f</a>.","ama":"Cao C, Steinrück H-G, Paul PP, et al. Conformal Pressure and Fast-Charging Li-Ion Batteries. <i>Journal of The Electrochemical Society</i>. 2022;169:040540. doi:<a href=\"https://doi.org/10.1149/1945-7111/ac653f\">10.1149/1945-7111/ac653f</a>"},"page":"040540","intvolume":"       169","date_updated":"2022-04-20T06:38:37Z","publisher":"The Electrochemical Society","date_created":"2022-04-20T06:37:40Z","author":[{"last_name":"Cao","full_name":"Cao, Chuntian","first_name":"Chuntian"},{"id":"84268","full_name":"Steinrück, Hans-Georg","last_name":"Steinrück","orcid":"0000-0001-6373-0877","first_name":"Hans-Georg"},{"full_name":"Paul, Partha P","last_name":"Paul","first_name":"Partha P"},{"last_name":"Dunlop","full_name":"Dunlop, Alison R.","first_name":"Alison R."},{"full_name":"Trask, Stephen E.","last_name":"Trask","first_name":"Stephen E."},{"first_name":"Andrew","full_name":"Jansen, Andrew","last_name":"Jansen"},{"first_name":"Robert M","full_name":"Kasse, Robert M","last_name":"Kasse"},{"last_name":"Thampy","full_name":"Thampy, Vivek","first_name":"Vivek"},{"last_name":"Yusuf","full_name":"Yusuf, Maha","first_name":"Maha"},{"first_name":"Johanna","full_name":"Nelson Weker, Johanna","last_name":"Nelson Weker"},{"first_name":"Badri","last_name":"Shyam","full_name":"Shyam, Badri"},{"last_name":"Subbaraman","full_name":"Subbaraman, Ram","first_name":"Ram"},{"last_name":"Davis","full_name":"Davis, Kelly","first_name":"Kelly"},{"first_name":"Christina M","last_name":"Johnston","full_name":"Johnston, Christina M"},{"first_name":"Christopher J","full_name":"Takacs, Christopher J","last_name":"Takacs"},{"full_name":"Toney, Michael","last_name":"Toney","first_name":"Michael"}],"volume":169,"title":"Conformal Pressure and Fast-Charging Li-Ion Batteries","doi":"10.1149/1945-7111/ac653f"}]