---
_id: '63883'
abstract:
- lang: eng
  text: Proton exchange membranes (PEMs) are essential for fuel cells, yet conventional
    materials like Nafion suffer from humidity dependence and limited thermal stability.
    This study introduces sulfonated phenylene-bridged periodic mesoporous organosilicas
    (PMOs) as promising inorganic–organic hybrid PEMs, synthesized via surfactant-templating
    with varying alkyl chain lengths for different mesopore sizes. Post-synthetic
    functionalization involves nitration of phenylene moieties, reduction to amines,
    and ring-opening of propane or butane sultones to graft sulfonic acid groups via
    flexible spacers, achieving homogeneous distribution along pore walls. Post-functionalization
    is confirmed by powder X-ray diffraction (PXRD), revealing preserved 2D hexagonal
    p6mm ordering and phenylene stacking. N2 physisorption shows type IV isotherms
    with reduced pore volumes and pore sizes. 1H NMR is used to quantify functionalization
    degrees. Impedance spectroscopy on pressed pellets demonstrates proton conductivities
    up to 2 × 10−3 S cm−1 at 30 °C and 90% RH, depending on the functionalization
    degree, confirming sulfonic acid-mediated conduction.
article_number: '203'
author:
- first_name: Tobias
  full_name: Wagner, Tobias
  last_name: Wagner
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Wagner T, Tiemann M. Proton-Conducting Sulfonated Periodic Mesoporous Organosilica.
    <i>Nanomaterials</i>. 2026;16(3). doi:<a href="https://doi.org/10.3390/nano16030203">10.3390/nano16030203</a>
  apa: Wagner, T., &#38; Tiemann, M. (2026). Proton-Conducting Sulfonated Periodic
    Mesoporous Organosilica. <i>Nanomaterials</i>, <i>16</i>(3), Article 203. <a href="https://doi.org/10.3390/nano16030203">https://doi.org/10.3390/nano16030203</a>
  bibtex: '@article{Wagner_Tiemann_2026, title={Proton-Conducting Sulfonated Periodic
    Mesoporous Organosilica}, volume={16}, DOI={<a href="https://doi.org/10.3390/nano16030203">10.3390/nano16030203</a>},
    number={3203}, journal={Nanomaterials}, publisher={MDPI AG}, author={Wagner, Tobias
    and Tiemann, Michael}, year={2026} }'
  chicago: Wagner, Tobias, and Michael Tiemann. “Proton-Conducting Sulfonated Periodic
    Mesoporous Organosilica.” <i>Nanomaterials</i> 16, no. 3 (2026). <a href="https://doi.org/10.3390/nano16030203">https://doi.org/10.3390/nano16030203</a>.
  ieee: 'T. Wagner and M. Tiemann, “Proton-Conducting Sulfonated Periodic Mesoporous
    Organosilica,” <i>Nanomaterials</i>, vol. 16, no. 3, Art. no. 203, 2026, doi:
    <a href="https://doi.org/10.3390/nano16030203">10.3390/nano16030203</a>.'
  mla: Wagner, Tobias, and Michael Tiemann. “Proton-Conducting Sulfonated Periodic
    Mesoporous Organosilica.” <i>Nanomaterials</i>, vol. 16, no. 3, 203, MDPI AG,
    2026, doi:<a href="https://doi.org/10.3390/nano16030203">10.3390/nano16030203</a>.
  short: T. Wagner, M. Tiemann, Nanomaterials 16 (2026).
date_created: 2026-02-05T09:46:20Z
date_updated: 2026-02-05T09:48:27Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.3390/nano16030203
intvolume: '        16'
issue: '3'
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
quality_controlled: '1'
status: public
title: Proton-Conducting Sulfonated Periodic Mesoporous Organosilica
type: journal_article
user_id: '23547'
volume: 16
year: '2026'
...
---
_id: '57618'
abstract:
- lang: eng
  text: <jats:p>The presence of a polymer network and/or the addition of ferroelectric
    nanoparticles to a nematic liquid crystal are found to lower transition temperatures
    and birefringence, which indicates reduced orientational order. In addition, the
    electro-optic switching voltage is considerably increased when a polymer network
    is formed by in situ polymerization in the nematic state. However, the resulting
    polymer network liquid crystal switches at similar voltages as the neat liquid
    crystal when polymerization is performed at an elevated temperature in the isotropic
    state. When nanoparticle dispersions are polymerized at an applied DC voltage,
    the transition temperatures and switching voltages are reduced, yet they are larger
    than those observed for polymer network liquid crystals without nanoparticles
    polymerized in the isotropic phase.</jats:p>
article_number: '961'
author:
- first_name: Gaby
  full_name: Nordendorf, Gaby
  last_name: Nordendorf
- first_name: Gisela
  full_name: Jünnemann-Held, Gisela
  last_name: Jünnemann-Held
- first_name: Alexander
  full_name: Lorenz, Alexander
  last_name: Lorenz
- first_name: Heinz-Siegfried
  full_name: Kitzerow, Heinz-Siegfried
  id: '254'
  last_name: Kitzerow
citation:
  ama: Nordendorf G, Jünnemann-Held G, Lorenz A, Kitzerow H-S. Effects of Composition
    and Polymerization Conditions on the Electro-Optic Performance of Liquid Crystal–Polymer
    Composites Doped with Ferroelectric Nanoparticles. <i>Nanomaterials</i>. 2024;14(11).
    doi:<a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>
  apa: Nordendorf, G., Jünnemann-Held, G., Lorenz, A., &#38; Kitzerow, H.-S. (2024).
    Effects of Composition and Polymerization Conditions on the Electro-Optic Performance
    of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles. <i>Nanomaterials</i>,
    <i>14</i>(11), Article 961. <a href="https://doi.org/10.3390/nano14110961">https://doi.org/10.3390/nano14110961</a>
  bibtex: '@article{Nordendorf_Jünnemann-Held_Lorenz_Kitzerow_2024, title={Effects
    of Composition and Polymerization Conditions on the Electro-Optic Performance
    of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles},
    volume={14}, DOI={<a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>},
    number={11961}, journal={Nanomaterials}, publisher={MDPI AG}, author={Nordendorf,
    Gaby and Jünnemann-Held, Gisela and Lorenz, Alexander and Kitzerow, Heinz-Siegfried},
    year={2024} }'
  chicago: Nordendorf, Gaby, Gisela Jünnemann-Held, Alexander Lorenz, and Heinz-Siegfried
    Kitzerow. “Effects of Composition and Polymerization Conditions on the Electro-Optic
    Performance of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles.”
    <i>Nanomaterials</i> 14, no. 11 (2024). <a href="https://doi.org/10.3390/nano14110961">https://doi.org/10.3390/nano14110961</a>.
  ieee: 'G. Nordendorf, G. Jünnemann-Held, A. Lorenz, and H.-S. Kitzerow, “Effects
    of Composition and Polymerization Conditions on the Electro-Optic Performance
    of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles,”
    <i>Nanomaterials</i>, vol. 14, no. 11, Art. no. 961, 2024, doi: <a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>.'
  mla: Nordendorf, Gaby, et al. “Effects of Composition and Polymerization Conditions
    on the Electro-Optic Performance of Liquid Crystal–Polymer Composites Doped with
    Ferroelectric Nanoparticles.” <i>Nanomaterials</i>, vol. 14, no. 11, 961, MDPI
    AG, 2024, doi:<a href="https://doi.org/10.3390/nano14110961">10.3390/nano14110961</a>.
  short: G. Nordendorf, G. Jünnemann-Held, A. Lorenz, H.-S. Kitzerow, Nanomaterials
    14 (2024).
date_created: 2024-12-08T14:36:04Z
date_updated: 2024-12-08T14:46:05Z
department:
- _id: '313'
- _id: '230'
- _id: '2'
doi: 10.3390/nano14110961
intvolume: '        14'
issue: '11'
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: Effects of Composition and Polymerization Conditions on the Electro-Optic Performance
  of Liquid Crystal–Polymer Composites Doped with Ferroelectric Nanoparticles
type: journal_article
user_id: '254'
volume: 14
year: '2024'
...
---
_id: '56947'
abstract:
- lang: eng
  text: <jats:p>Pore engineering is commonly used to alter the properties of metal–organic
    frameworks. This is achieved by incorporating different linker molecules (L) into
    the structure, generating isoreticular frameworks. CPO-27, also named MOF-74,
    is a prototypical material for this approach, offering the potential to modify
    the size of its one-dimensional pore channels and the hydrophobicity of pore walls
    using various linker ligands during synthesis. Thermal activation of these materials
    yields accessible open metal sites (i.e., under-coordinated metal centers) at
    the pore walls, thus acting as strong primary binding sites for guest molecules,
    including water. We study the effect of the pore size and linker hydrophobicity
    within a series of Ni2+-based isoreticular frameworks (i.e., Ni2L, L = dhtp, dhip,
    dondc, bpp, bpm, tpp), analyzing their water sorption behavior and the water interactions
    in the confined pore space. For this purpose, we apply water vapor sorption analysis
    and Fourier transform infrared spectroscopy. In addition, defect degrees of all
    compounds are determined by thermogravimetric analysis and solution 1H nuclear
    magnetic resonance spectroscopy. We find that larger defect degrees affect the
    preferential sorption sites in Ni2dhtp, while no such indication is found for
    the other materials in our study. Instead, strong evidence is found for the formation
    of water bridges/chains between coordinating water molecules, as previously observed
    for hydrophobic porous carbons and mesoporous silica. This suggests similar sorption
    energies for additional water molecules in materials with larger pore sizes after
    saturation of the primary binding sites, resulting in more bulk-like water arrangements.
    Consequently, the sorption mechanism is driven by classical pore condensation
    through H-bonding anchor sites instead of sorption at discrete sites.</jats:p>
article_type: original
author:
- first_name: Marvin
  full_name: Kloß, Marvin
  last_name: Kloß
- first_name: Lara
  full_name: Schäfers, Lara
  last_name: Schäfers
- first_name: Zhenyu
  full_name: Zhao, Zhenyu
  last_name: Zhao
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Hans
  full_name: Egold, Hans
  id: '101'
  last_name: Egold
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Kloß M, Schäfers L, Zhao Z, Weinberger C, Egold H, Tiemann M. Water Sorption
    on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated
    Pore Condensation. <i>Nanomaterials</i>. 2024;14(22):1791. doi:<a href="https://doi.org/10.3390/nano14221791">10.3390/nano14221791</a>'
  apa: 'Kloß, M., Schäfers, L., Zhao, Z., Weinberger, C., Egold, H., &#38; Tiemann,
    M. (2024). Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption
    Sites to Water-Bridge-Mediated Pore Condensation. <i>Nanomaterials</i>, <i>14</i>(22),
    1791. <a href="https://doi.org/10.3390/nano14221791">https://doi.org/10.3390/nano14221791</a>'
  bibtex: '@article{Kloß_Schäfers_Zhao_Weinberger_Egold_Tiemann_2024, title={Water
    Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated
    Pore Condensation}, volume={14}, DOI={<a href="https://doi.org/10.3390/nano14221791">10.3390/nano14221791</a>},
    number={22}, journal={Nanomaterials}, publisher={MDPI AG}, author={Kloß, Marvin
    and Schäfers, Lara and Zhao, Zhenyu and Weinberger, Christian and Egold, Hans
    and Tiemann, Michael}, year={2024}, pages={1791} }'
  chicago: 'Kloß, Marvin, Lara Schäfers, Zhenyu Zhao, Christian Weinberger, Hans Egold,
    and Michael Tiemann. “Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete
    Sorption Sites to Water-Bridge-Mediated Pore Condensation.” <i>Nanomaterials</i>
    14, no. 22 (2024): 1791. <a href="https://doi.org/10.3390/nano14221791">https://doi.org/10.3390/nano14221791</a>.'
  ieee: 'M. Kloß, L. Schäfers, Z. Zhao, C. Weinberger, H. Egold, and M. Tiemann, “Water
    Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites to Water-Bridge-Mediated
    Pore Condensation,” <i>Nanomaterials</i>, vol. 14, no. 22, p. 1791, 2024, doi:
    <a href="https://doi.org/10.3390/nano14221791">10.3390/nano14221791</a>.'
  mla: 'Kloß, Marvin, et al. “Water Sorption on Isoreticular CPO-27-Type MOFs: From
    Discrete Sorption Sites to Water-Bridge-Mediated Pore Condensation.” <i>Nanomaterials</i>,
    vol. 14, no. 22, MDPI AG, 2024, p. 1791, doi:<a href="https://doi.org/10.3390/nano14221791">10.3390/nano14221791</a>.'
  short: M. Kloß, L. Schäfers, Z. Zhao, C. Weinberger, H. Egold, M. Tiemann, Nanomaterials
    14 (2024) 1791.
date_created: 2024-11-08T06:18:11Z
date_updated: 2025-01-10T14:27:39Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.3390/nano14221791
intvolume: '        14'
issue: '22'
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
page: '1791'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
quality_controlled: '1'
status: public
title: 'Water Sorption on Isoreticular CPO-27-Type MOFs: From Discrete Sorption Sites
  to Water-Bridge-Mediated Pore Condensation'
type: journal_article
user_id: '23547'
volume: 14
year: '2024'
...
---
_id: '46278'
abstract:
- lang: eng
  text: '<jats:p>Site-controlled Ga droplets on AlGaAs substrates are fabricated using
    area-selective deposition of Ga through apertures in a mask during molecular beam
    epitaxy (MBE). The Ga droplets can be crystallized into GaAs quantum dots using
    a crystallization step under As flux. In order to model the complex process, including
    the masked deposition of the droplets and a reduction of their number during a
    thermal annealing step, a multiscale kinetic Monte Carlo (mkMC) simulation of
    self-assembled Ga droplet formation on AlGaAs is expanded for area-selective deposition.
    The simulation has only two free model parameters: the activation energy for surface
    diffusion and the activation energy for thermal escape of adatoms from a droplet.
    Simulated droplet numbers within the opening of the aperture agree quantitatively
    with the experimental results down to the perfect site-control, with one droplet
    per aperture. However, the model parameters are different compared to those of
    the self-assembled droplet growth. We attribute this to the presence of the mask
    in close proximity to the surface, which modifies the local process temperature
    and the As background. This approach also explains the dependence of the model
    parameters on the size of the aperture.</jats:p>'
article_number: '466'
author:
- first_name: Stefan
  full_name: Feddersen, Stefan
  last_name: Feddersen
- first_name: Viktoryia
  full_name: Zolatanosha, Viktoryia
  last_name: Zolatanosha
- first_name: Ahmed
  full_name: Alshaikh, Ahmed
  last_name: Alshaikh
- first_name: Dirk
  full_name: Reuter, Dirk
  id: '37763'
  last_name: Reuter
- first_name: Christian
  full_name: Heyn, Christian
  last_name: Heyn
citation:
  ama: Feddersen S, Zolatanosha V, Alshaikh A, Reuter D, Heyn C. Modeling of Masked
    Droplet Deposition for Site-Controlled Ga Droplets. <i>Nanomaterials</i>. 2023;13(3).
    doi:<a href="https://doi.org/10.3390/nano13030466">10.3390/nano13030466</a>
  apa: Feddersen, S., Zolatanosha, V., Alshaikh, A., Reuter, D., &#38; Heyn, C. (2023).
    Modeling of Masked Droplet Deposition for Site-Controlled Ga Droplets. <i>Nanomaterials</i>,
    <i>13</i>(3), Article 466. <a href="https://doi.org/10.3390/nano13030466">https://doi.org/10.3390/nano13030466</a>
  bibtex: '@article{Feddersen_Zolatanosha_Alshaikh_Reuter_Heyn_2023, title={Modeling
    of Masked Droplet Deposition for Site-Controlled Ga Droplets}, volume={13}, DOI={<a
    href="https://doi.org/10.3390/nano13030466">10.3390/nano13030466</a>}, number={3466},
    journal={Nanomaterials}, publisher={MDPI AG}, author={Feddersen, Stefan and Zolatanosha,
    Viktoryia and Alshaikh, Ahmed and Reuter, Dirk and Heyn, Christian}, year={2023}
    }'
  chicago: Feddersen, Stefan, Viktoryia Zolatanosha, Ahmed Alshaikh, Dirk Reuter,
    and Christian Heyn. “Modeling of Masked Droplet Deposition for Site-Controlled
    Ga Droplets.” <i>Nanomaterials</i> 13, no. 3 (2023). <a href="https://doi.org/10.3390/nano13030466">https://doi.org/10.3390/nano13030466</a>.
  ieee: 'S. Feddersen, V. Zolatanosha, A. Alshaikh, D. Reuter, and C. Heyn, “Modeling
    of Masked Droplet Deposition for Site-Controlled Ga Droplets,” <i>Nanomaterials</i>,
    vol. 13, no. 3, Art. no. 466, 2023, doi: <a href="https://doi.org/10.3390/nano13030466">10.3390/nano13030466</a>.'
  mla: Feddersen, Stefan, et al. “Modeling of Masked Droplet Deposition for Site-Controlled
    Ga Droplets.” <i>Nanomaterials</i>, vol. 13, no. 3, 466, MDPI AG, 2023, doi:<a
    href="https://doi.org/10.3390/nano13030466">10.3390/nano13030466</a>.
  short: S. Feddersen, V. Zolatanosha, A. Alshaikh, D. Reuter, C. Heyn, Nanomaterials
    13 (2023).
date_created: 2023-08-03T11:13:28Z
date_updated: 2023-08-03T11:14:10Z
department:
- _id: '15'
- _id: '230'
doi: 10.3390/nano13030466
intvolume: '        13'
issue: '3'
keyword:
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: Modeling of Masked Droplet Deposition for Site-Controlled Ga Droplets
type: journal_article
user_id: '42514'
volume: 13
year: '2023'
...
---
_id: '22639'
author:
- first_name: Y
  full_name: Yang, Y
  last_name: Yang
- first_name: S
  full_name: Knust, S
  last_name: Knust
- first_name: S
  full_name: Schwiderek, S
  last_name: Schwiderek
- first_name: Q
  full_name: Qin, Q
  last_name: Qin
- first_name: Q
  full_name: Yun, Q
  last_name: Yun
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: 'Yang Y, Knust S, Schwiderek S, et al. Protein Adsorption at Nanorough Titanium
    Oxide Surfaces: The Importance of Surface Statistical Parameters beyond Surface
    Roughness. <i>Nanomaterials</i>. 2021;11(2):357. doi:<a href="https://doi.org/10.3390/nano11020357">10.3390/nano11020357</a>'
  apa: 'Yang, Y., Knust, S., Schwiderek, S., Qin, Q., Yun, Q., Grundmeier, G., &#38;
    Keller, A. (2021). Protein Adsorption at Nanorough Titanium Oxide Surfaces: The
    Importance of Surface Statistical Parameters beyond Surface Roughness. <i>Nanomaterials</i>,
    <i>11</i>(2), 357. <a href="https://doi.org/10.3390/nano11020357">https://doi.org/10.3390/nano11020357</a>'
  bibtex: '@article{Yang_Knust_Schwiderek_Qin_Yun_Grundmeier_Keller_2021, title={Protein
    Adsorption at Nanorough Titanium Oxide Surfaces: The Importance of Surface Statistical
    Parameters beyond Surface Roughness.}, volume={11}, DOI={<a href="https://doi.org/10.3390/nano11020357">10.3390/nano11020357</a>},
    number={2}, journal={Nanomaterials}, author={Yang, Y and Knust, S and Schwiderek,
    S and Qin, Q and Yun, Q and Grundmeier, Guido and Keller, Adrian}, year={2021},
    pages={357} }'
  chicago: 'Yang, Y, S Knust, S Schwiderek, Q Qin, Q Yun, Guido Grundmeier, and Adrian
    Keller. “Protein Adsorption at Nanorough Titanium Oxide Surfaces: The Importance
    of Surface Statistical Parameters beyond Surface Roughness.” <i>Nanomaterials</i>
    11, no. 2 (2021): 357. <a href="https://doi.org/10.3390/nano11020357">https://doi.org/10.3390/nano11020357</a>.'
  ieee: 'Y. Yang <i>et al.</i>, “Protein Adsorption at Nanorough Titanium Oxide Surfaces:
    The Importance of Surface Statistical Parameters beyond Surface Roughness.,” <i>Nanomaterials</i>,
    vol. 11, no. 2, p. 357, 2021.'
  mla: 'Yang, Y., et al. “Protein Adsorption at Nanorough Titanium Oxide Surfaces:
    The Importance of Surface Statistical Parameters beyond Surface Roughness.” <i>Nanomaterials</i>,
    vol. 11, no. 2, 2021, p. 357, doi:<a href="https://doi.org/10.3390/nano11020357">10.3390/nano11020357</a>.'
  short: Y. Yang, S. Knust, S. Schwiderek, Q. Qin, Q. Yun, G. Grundmeier, A. Keller,
    Nanomaterials 11 (2021) 357.
date_created: 2021-07-08T11:50:44Z
date_updated: 2022-01-06T06:55:37Z
department:
- _id: '302'
doi: 10.3390/nano11020357
external_id:
  pmid:
  - '33535535'
intvolume: '        11'
issue: '2'
language:
- iso: eng
page: ' 357 '
pmid: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
status: public
title: 'Protein Adsorption at Nanorough Titanium Oxide Surfaces: The Importance of
  Surface Statistical Parameters beyond Surface Roughness.'
type: journal_article
user_id: '48864'
volume: 11
year: '2021'
...
---
_id: '22825'
abstract:
- lang: eng
  text: <jats:p>In this work, the electrografting of Al-7075 aluminium alloy substrates
    with 4-nitrobenzenediazonium salt (4-NBD) films was studied on a complex aluminium
    alloy surface. Prior to the electrografting reaction, the substrates were submitted
    to different surface treatments to modify the native aluminium oxide layer and
    unveil intermetallic particles (IMPs). The formation of the 4-NBD films could
    be correlated with the passive film state and the distribution of IMPs. The corresponding
    electrografting reaction was performed by cyclic voltammetry which allowed the
    simultaneous analysis of the redox reaction by a number of complementary surface-analytical
    techniques. Spatially resolved thin film analysis was performed by means of SEM-EDX,
    AFM, PM-IRRAS, Raman spectroscopy, XPS, and SKPFM. The collected data show that
    the 4-NBD film is preferentially formed either on the Al oxide layer or the IMP
    surface depending on the applied potential range. Potentials between −0.1 and
    −1.0 VAg/AgCl mostly generated nitrophenylene films on the oxide covered aluminium,
    while grafting between −0.1 and −0.4 VAg/AgCl favours the growth of these films
    on IMPs.</jats:p>
article_number: '894'
author:
- first_name: Jiangling
  full_name: Su, Jiangling
  last_name: Su
- first_name: Juan Carlos
  full_name: Calderón Gómez, Juan Carlos
  last_name: Calderón Gómez
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Alejandro
  full_name: González Orive, Alejandro
  last_name: González Orive
citation:
  ama: Su J, Calderón Gómez JC, Grundmeier G, González Orive A. Electrografting of
    4-Nitrobenzenediazonium Salts on Al-7075 Alloy Surfaces—The Role of Intermetallic
    Particles. <i>Nanomaterials</i>. 2021. doi:<a href="https://doi.org/10.3390/nano11040894">10.3390/nano11040894</a>
  apa: Su, J., Calderón Gómez, J. C., Grundmeier, G., &#38; González Orive, A. (2021).
    Electrografting of 4-Nitrobenzenediazonium Salts on Al-7075 Alloy Surfaces—The
    Role of Intermetallic Particles. <i>Nanomaterials</i>. <a href="https://doi.org/10.3390/nano11040894">https://doi.org/10.3390/nano11040894</a>
  bibtex: '@article{Su_Calderón Gómez_Grundmeier_González Orive_2021, title={Electrografting
    of 4-Nitrobenzenediazonium Salts on Al-7075 Alloy Surfaces—The Role of Intermetallic
    Particles}, DOI={<a href="https://doi.org/10.3390/nano11040894">10.3390/nano11040894</a>},
    number={894}, journal={Nanomaterials}, author={Su, Jiangling and Calderón Gómez,
    Juan Carlos and Grundmeier, Guido and González Orive, Alejandro}, year={2021}
    }'
  chicago: Su, Jiangling, Juan Carlos Calderón Gómez, Guido Grundmeier, and Alejandro
    González Orive. “Electrografting of 4-Nitrobenzenediazonium Salts on Al-7075 Alloy
    Surfaces—The Role of Intermetallic Particles.” <i>Nanomaterials</i>, 2021. <a
    href="https://doi.org/10.3390/nano11040894">https://doi.org/10.3390/nano11040894</a>.
  ieee: J. Su, J. C. Calderón Gómez, G. Grundmeier, and A. González Orive, “Electrografting
    of 4-Nitrobenzenediazonium Salts on Al-7075 Alloy Surfaces—The Role of Intermetallic
    Particles,” <i>Nanomaterials</i>, 2021.
  mla: Su, Jiangling, et al. “Electrografting of 4-Nitrobenzenediazonium Salts on
    Al-7075 Alloy Surfaces—The Role of Intermetallic Particles.” <i>Nanomaterials</i>,
    894, 2021, doi:<a href="https://doi.org/10.3390/nano11040894">10.3390/nano11040894</a>.
  short: J. Su, J.C. Calderón Gómez, G. Grundmeier, A. González Orive, Nanomaterials
    (2021).
date_created: 2021-07-27T14:04:30Z
date_updated: 2022-01-06T06:55:42Z
doi: 10.3390/nano11040894
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
status: public
title: Electrografting of 4-Nitrobenzenediazonium Salts on Al-7075 Alloy Surfaces—The
  Role of Intermetallic Particles
type: journal_article
user_id: '194'
year: '2021'
...
---
_id: '39383'
abstract:
- lang: eng
  text: '<jats:p>Zinc oxide nanoparticles (ZnO NP) used for the channel region in
    inverted coplanar setup in Thin Film Transistors (TFT) were the focus of this
    study. The regions between the source electrode and the ZnO NP and the drain electrode
    were under investigation as they produce a Schottky barrier in metal-semiconductor
    interfaces. A more general Thermionic emission theory must be evaluated: one that
    considers both metal/semiconductor interfaces (MSM structures). Aluminum, gold,
    and nickel were used as metallization layers for source and drain electrodes.
    An organic-inorganic nanocomposite was used as a gate dielectric. The TFTs transfer
    and output characteristics curves were extracted, and a numerical computational
    program was used for fitting the data; hence information about Schottky Barrier
    Height (SBH) and ideality factors for each TFT could be estimated. The nickel
    metallization appears with the lowest SBH among the metals investigated. For this
    metal and for higher drain-to-source voltages, the SBH tended to converge to some
    value around 0.3 eV. The developed fitting method showed good fitting accuracy
    even when the metallization produced different SBH in each metal-semiconductor
    interface, as was the case for gold metallization. The Schottky effect is also
    present and was studied when the drain-to-source voltages and/or the gate voltage
    were increased.</jats:p>'
article_number: '1188'
author:
- first_name: Ivan Rodrigo
  full_name: Kaufmann, Ivan Rodrigo
  last_name: Kaufmann
- first_name: Onur
  full_name: Zerey, Onur
  last_name: Zerey
- first_name: Thorsten
  full_name: Meyers, Thorsten
  last_name: Meyers
- first_name: Julia
  full_name: Reker, Julia
  last_name: Reker
- first_name: Fábio
  full_name: Vidor, Fábio
  last_name: Vidor
- first_name: Ulrich
  full_name: Hilleringmann, Ulrich
  id: '20179'
  last_name: Hilleringmann
citation:
  ama: Kaufmann IR, Zerey O, Meyers T, Reker J, Vidor F, Hilleringmann U. A Study
    about Schottky Barrier Height and Ideality Factor in Thin Film Transistors with
    Metal/Zinc Oxide Nanoparticles Structures Aiming Flexible Electronics Application.
    <i>Nanomaterials</i>. 2021;11(5). doi:<a href="https://doi.org/10.3390/nano11051188">10.3390/nano11051188</a>
  apa: Kaufmann, I. R., Zerey, O., Meyers, T., Reker, J., Vidor, F., &#38; Hilleringmann,
    U. (2021). A Study about Schottky Barrier Height and Ideality Factor in Thin Film
    Transistors with Metal/Zinc Oxide Nanoparticles Structures Aiming Flexible Electronics
    Application. <i>Nanomaterials</i>, <i>11</i>(5), Article 1188. <a href="https://doi.org/10.3390/nano11051188">https://doi.org/10.3390/nano11051188</a>
  bibtex: '@article{Kaufmann_Zerey_Meyers_Reker_Vidor_Hilleringmann_2021, title={A
    Study about Schottky Barrier Height and Ideality Factor in Thin Film Transistors
    with Metal/Zinc Oxide Nanoparticles Structures Aiming Flexible Electronics Application},
    volume={11}, DOI={<a href="https://doi.org/10.3390/nano11051188">10.3390/nano11051188</a>},
    number={51188}, journal={Nanomaterials}, publisher={MDPI AG}, author={Kaufmann,
    Ivan Rodrigo and Zerey, Onur and Meyers, Thorsten and Reker, Julia and Vidor,
    Fábio and Hilleringmann, Ulrich}, year={2021} }'
  chicago: Kaufmann, Ivan Rodrigo, Onur Zerey, Thorsten Meyers, Julia Reker, Fábio
    Vidor, and Ulrich Hilleringmann. “A Study about Schottky Barrier Height and Ideality
    Factor in Thin Film Transistors with Metal/Zinc Oxide Nanoparticles Structures
    Aiming Flexible Electronics Application.” <i>Nanomaterials</i> 11, no. 5 (2021).
    <a href="https://doi.org/10.3390/nano11051188">https://doi.org/10.3390/nano11051188</a>.
  ieee: 'I. R. Kaufmann, O. Zerey, T. Meyers, J. Reker, F. Vidor, and U. Hilleringmann,
    “A Study about Schottky Barrier Height and Ideality Factor in Thin Film Transistors
    with Metal/Zinc Oxide Nanoparticles Structures Aiming Flexible Electronics Application,”
    <i>Nanomaterials</i>, vol. 11, no. 5, Art. no. 1188, 2021, doi: <a href="https://doi.org/10.3390/nano11051188">10.3390/nano11051188</a>.'
  mla: Kaufmann, Ivan Rodrigo, et al. “A Study about Schottky Barrier Height and Ideality
    Factor in Thin Film Transistors with Metal/Zinc Oxide Nanoparticles Structures
    Aiming Flexible Electronics Application.” <i>Nanomaterials</i>, vol. 11, no. 5,
    1188, MDPI AG, 2021, doi:<a href="https://doi.org/10.3390/nano11051188">10.3390/nano11051188</a>.
  short: I.R. Kaufmann, O. Zerey, T. Meyers, J. Reker, F. Vidor, U. Hilleringmann,
    Nanomaterials 11 (2021).
date_created: 2023-01-24T10:08:10Z
date_updated: 2023-03-22T10:27:25Z
department:
- _id: '59'
doi: 10.3390/nano11051188
intvolume: '        11'
issue: '5'
keyword:
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: A Study about Schottky Barrier Height and Ideality Factor in Thin Film Transistors
  with Metal/Zinc Oxide Nanoparticles Structures Aiming Flexible Electronics Application
type: journal_article
user_id: '20179'
volume: 11
year: '2021'
...
---
_id: '20893'
abstract:
- lang: eng
  text: <jats:p>Block copolymer (BCP) self-assembly is a promising tool for next generation
    lithography as microphase separated polymer domains in thin films can act as templates
    for surface nanopatterning with sub-20 nm features. The replicated patterns can,
    however, only be as precise as their templates. Thus, the investigation of the
    morphology of polymer domains is of great importance. Commonly used analytical
    techniques (neutron scattering, scanning force microscopy) either lack spatial
    information or nanoscale resolution. Using advanced analytical (scanning) transmission
    electron microscopy ((S)TEM), we provide real space information on polymer domain
    morphology and interfaces between polystyrene (PS) and polymethylmethacrylate
    (PMMA) in cylinder- and lamellae-forming BCPs at highest resolution. This allows
    us to correlate the internal structure of polymer domains with line edge roughnesses,
    interface widths and domain sizes. STEM is employed for high-resolution imaging,
    electron energy loss spectroscopy and energy filtered TEM (EFTEM) spectroscopic
    imaging for material identification and EFTEM thickness mapping for visualisation
    of material densities at defects. The volume fraction of non-phase separated polymer
    species can be analysed by EFTEM. These methods give new insights into the morphology
    of polymer domains the exact knowledge of which will allow to improve pattern
    quality for nanolithography.</jats:p>
article_number: '141'
author:
- first_name: Julius
  full_name: Bürger, Julius
  last_name: Bürger
- first_name: Vinay S.
  full_name: Kunnathully, Vinay S.
  last_name: Kunnathully
- first_name: Daniel
  full_name: Kool, Daniel
  last_name: Kool
- first_name: Jörg K. N.
  full_name: Lindner, Jörg K. N.
  last_name: Lindner
- first_name: Katharina
  full_name: Brassat, Katharina
  last_name: Brassat
citation:
  ama: Bürger J, Kunnathully VS, Kool D, Lindner JKN, Brassat K. Characterisation
    of the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by
    Analytical (S)TEM. <i>Nanomaterials</i>. 2020. doi:<a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>
  apa: Bürger, J., Kunnathully, V. S., Kool, D., Lindner, J. K. N., &#38; Brassat,
    K. (2020). Characterisation of the PS-PMMA Interfaces in Microphase Separated
    Block Copolymer Thin Films by Analytical (S)TEM. <i>Nanomaterials</i>. <a href="https://doi.org/10.3390/nano10010141">https://doi.org/10.3390/nano10010141</a>
  bibtex: '@article{Bürger_Kunnathully_Kool_Lindner_Brassat_2020, title={Characterisation
    of the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by
    Analytical (S)TEM}, DOI={<a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>},
    number={141}, journal={Nanomaterials}, author={Bürger, Julius and Kunnathully,
    Vinay S. and Kool, Daniel and Lindner, Jörg K. N. and Brassat, Katharina}, year={2020}
    }'
  chicago: Bürger, Julius, Vinay S. Kunnathully, Daniel Kool, Jörg K. N. Lindner,
    and Katharina Brassat. “Characterisation of the PS-PMMA Interfaces in Microphase
    Separated Block Copolymer Thin Films by Analytical (S)TEM.” <i>Nanomaterials</i>,
    2020. <a href="https://doi.org/10.3390/nano10010141">https://doi.org/10.3390/nano10010141</a>.
  ieee: J. Bürger, V. S. Kunnathully, D. Kool, J. K. N. Lindner, and K. Brassat, “Characterisation
    of the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by
    Analytical (S)TEM,” <i>Nanomaterials</i>, 2020.
  mla: Bürger, Julius, et al. “Characterisation of the PS-PMMA Interfaces in Microphase
    Separated Block Copolymer Thin Films by Analytical (S)TEM.” <i>Nanomaterials</i>,
    141, 2020, doi:<a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>.
  short: J. Bürger, V.S. Kunnathully, D. Kool, J.K.N. Lindner, K. Brassat, Nanomaterials
    (2020).
date_created: 2021-01-12T08:28:16Z
date_updated: 2022-01-06T06:54:41Z
doi: 10.3390/nano10010141
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
status: public
title: Characterisation of the PS-PMMA Interfaces in Microphase Separated Block Copolymer
  Thin Films by Analytical (S)TEM
type: journal_article
user_id: '46952'
year: '2020'
...
---
_id: '22644'
abstract:
- lang: eng
  text: <jats:p>The aggregation of human islet amyloid polypeptide (hIAPP) plays a
    major role in the pathogenesis of type 2 diabetes mellitus (T2DM), and numerous
    strategies for controlling hIAPP aggregation have been investigated so far. In
    particular, several organic and inorganic nanoparticles (NPs) have shown the potential
    to influence the aggregation of hIAPP and other amyloidogenic proteins and peptides.
    In addition to conventional NPs, DNA nanostructures are receiving more and more
    attention from the biomedical field. Therefore, in this work, we investigated
    the effects of two different DNA origami nanostructures on hIAPP aggregation.
    To this end, we employed in situ turbidity measurements and ex situ atomic force
    microscopy (AFM). The turbidity measurements revealed a retarding effect of the
    DNA nanostructures on hIAPP aggregation, while the AFM results showed the co-aggregation
    of hIAPP with the DNA origami nanostructures into hybrid peptide–DNA aggregates.
    We assume that this was caused by strong electrostatic interactions between the
    negatively charged DNA origami nanostructures and the positively charged peptide.
    Most intriguingly, the influence of the DNA origami nanostructures on hIAPP aggregation
    differed from that of genomic double-stranded DNA (dsDNA) and appeared to depend
    on DNA origami superstructure. DNA origami nanostructures may thus represent a
    novel route for modulating amyloid aggregation in vivo.</jats:p>
author:
- first_name: Marcel
  full_name: Hanke, Marcel
  last_name: Hanke
- first_name: Alejandro
  full_name: Gonzalez Orive, Alejandro
  last_name: Gonzalez Orive
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Hanke M, Gonzalez Orive A, Grundmeier G, Keller A. Effect of DNA Origami Nanostructures
    on hIAPP Aggregation. <i>Nanomaterials</i>. 2020;10:2200. doi:<a href="https://doi.org/10.3390/nano10112200">10.3390/nano10112200</a>
  apa: Hanke, M., Gonzalez Orive, A., Grundmeier, G., &#38; Keller, A. (2020). Effect
    of DNA Origami Nanostructures on hIAPP Aggregation. <i>Nanomaterials</i>, <i>10</i>,
    2200. <a href="https://doi.org/10.3390/nano10112200">https://doi.org/10.3390/nano10112200</a>
  bibtex: '@article{Hanke_Gonzalez Orive_Grundmeier_Keller_2020, title={Effect of
    DNA Origami Nanostructures on hIAPP Aggregation}, volume={10}, DOI={<a href="https://doi.org/10.3390/nano10112200">10.3390/nano10112200</a>},
    journal={Nanomaterials}, author={Hanke, Marcel and Gonzalez Orive, Alejandro and
    Grundmeier, Guido and Keller, Adrian}, year={2020}, pages={2200} }'
  chicago: 'Hanke, Marcel, Alejandro Gonzalez Orive, Guido Grundmeier, and Adrian
    Keller. “Effect of DNA Origami Nanostructures on HIAPP Aggregation.” <i>Nanomaterials</i>
    10 (2020): 2200. <a href="https://doi.org/10.3390/nano10112200">https://doi.org/10.3390/nano10112200</a>.'
  ieee: M. Hanke, A. Gonzalez Orive, G. Grundmeier, and A. Keller, “Effect of DNA
    Origami Nanostructures on hIAPP Aggregation,” <i>Nanomaterials</i>, vol. 10, p.
    2200, 2020.
  mla: Hanke, Marcel, et al. “Effect of DNA Origami Nanostructures on HIAPP Aggregation.”
    <i>Nanomaterials</i>, vol. 10, 2020, p. 2200, doi:<a href="https://doi.org/10.3390/nano10112200">10.3390/nano10112200</a>.
  short: M. Hanke, A. Gonzalez Orive, G. Grundmeier, A. Keller, Nanomaterials 10 (2020)
    2200.
date_created: 2021-07-08T11:59:01Z
date_updated: 2022-01-06T06:55:37Z
department:
- _id: '302'
doi: 10.3390/nano10112200
intvolume: '        10'
language:
- iso: eng
page: '2200'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
status: public
title: Effect of DNA Origami Nanostructures on hIAPP Aggregation
type: journal_article
user_id: '48864'
volume: 10
year: '2020'
...
---
_id: '34092'
abstract:
- lang: eng
  text: <jats:p>Block copolymer (BCP) self-assembly is a promising tool for next generation
    lithography as microphase separated polymer domains in thin films can act as templates
    for surface nanopatterning with sub-20 nm features. The replicated patterns can,
    however, only be as precise as their templates. Thus, the investigation of the
    morphology of polymer domains is of great importance. Commonly used analytical
    techniques (neutron scattering, scanning force microscopy) either lack spatial
    information or nanoscale resolution. Using advanced analytical (scanning) transmission
    electron microscopy ((S)TEM), we provide real space information on polymer domain
    morphology and interfaces between polystyrene (PS) and polymethylmethacrylate
    (PMMA) in cylinder- and lamellae-forming BCPs at highest resolution. This allows
    us to correlate the internal structure of polymer domains with line edge roughnesses,
    interface widths and domain sizes. STEM is employed for high-resolution imaging,
    electron energy loss spectroscopy and energy filtered TEM (EFTEM) spectroscopic
    imaging for material identification and EFTEM thickness mapping for visualisation
    of material densities at defects. The volume fraction of non-phase separated polymer
    species can be analysed by EFTEM. These methods give new insights into the morphology
    of polymer domains the exact knowledge of which will allow to improve pattern
    quality for nanolithography.</jats:p>
article_number: '141'
author:
- first_name: Julius
  full_name: Bürger, Julius
  id: '46952'
  last_name: Bürger
- first_name: Vinay
  full_name: Kunnathully, Vinay
  last_name: Kunnathully
- first_name: Daniel
  full_name: Kool, Daniel
  id: '44586'
  last_name: Kool
- first_name: Jörg
  full_name: Lindner, Jörg
  id: '20797'
  last_name: Lindner
- first_name: Katharina
  full_name: Brassat, Katharina
  id: '11305'
  last_name: Brassat
citation:
  ama: Bürger J, Kunnathully V, Kool D, Lindner J, Brassat K. Characterisation of
    the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by Analytical
    (S)TEM. <i>Nanomaterials</i>. 2020;10(1). doi:<a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>
  apa: Bürger, J., Kunnathully, V., Kool, D., Lindner, J., &#38; Brassat, K. (2020).
    Characterisation of the PS-PMMA Interfaces in Microphase Separated Block Copolymer
    Thin Films by Analytical (S)TEM. <i>Nanomaterials</i>, <i>10</i>(1), Article 141.
    <a href="https://doi.org/10.3390/nano10010141">https://doi.org/10.3390/nano10010141</a>
  bibtex: '@article{Bürger_Kunnathully_Kool_Lindner_Brassat_2020, title={Characterisation
    of the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by
    Analytical (S)TEM}, volume={10}, DOI={<a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>},
    number={1141}, journal={Nanomaterials}, publisher={MDPI AG}, author={Bürger, Julius
    and Kunnathully, Vinay and Kool, Daniel and Lindner, Jörg and Brassat, Katharina},
    year={2020} }'
  chicago: Bürger, Julius, Vinay Kunnathully, Daniel Kool, Jörg Lindner, and Katharina
    Brassat. “Characterisation of the PS-PMMA Interfaces in Microphase Separated Block
    Copolymer Thin Films by Analytical (S)TEM.” <i>Nanomaterials</i> 10, no. 1 (2020).
    <a href="https://doi.org/10.3390/nano10010141">https://doi.org/10.3390/nano10010141</a>.
  ieee: 'J. Bürger, V. Kunnathully, D. Kool, J. Lindner, and K. Brassat, “Characterisation
    of the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by
    Analytical (S)TEM,” <i>Nanomaterials</i>, vol. 10, no. 1, Art. no. 141, 2020,
    doi: <a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>.'
  mla: Bürger, Julius, et al. “Characterisation of the PS-PMMA Interfaces in Microphase
    Separated Block Copolymer Thin Films by Analytical (S)TEM.” <i>Nanomaterials</i>,
    vol. 10, no. 1, 141, MDPI AG, 2020, doi:<a href="https://doi.org/10.3390/nano10010141">10.3390/nano10010141</a>.
  short: J. Bürger, V. Kunnathully, D. Kool, J. Lindner, K. Brassat, Nanomaterials
    10 (2020).
date_created: 2022-11-15T14:20:33Z
date_updated: 2023-01-10T12:11:57Z
department:
- _id: '15'
- _id: '230'
doi: 10.3390/nano10010141
intvolume: '        10'
issue: '1'
keyword:
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: Characterisation of the PS-PMMA Interfaces in Microphase Separated Block Copolymer
  Thin Films by Analytical (S)TEM
type: journal_article
user_id: '77496'
volume: 10
year: '2020'
...
---
_id: '35868'
abstract:
- lang: eng
  text: <jats:p>Rod-like and sheet-like nano-particles made of desoxyribonucleic acid
    (DNA) fabricated by the DNA origami method (base sequence-controlled self-organized
    folding of DNA) are dispersed in a lyotropic chromonic liquid crystal made of
    an aqueous solution of disodium cromoglycate. The respective liquid crystalline
    nanodispersions are doped with a dichroic fluorescent dye and their orientational
    order parameter is studied by means of polarized fluorescence spectroscopy. The
    presence of the nano-particles is found to slightly reduce the orientational order
    parameter of the nematic mesophase. Nano-rods with a large length/width ratio
    tend to preserve the orientational order, while more compact stiff nano-rods and
    especially nano-sheets reduce the order parameter to a larger extent. In spite
    of the difference between the sizes of the DNA nano-particles and the rod-like
    columnar aggregates forming the liquid crystal, a similarity between the shapes
    of the former and the latter seems to be better compatible with the orientational
    order of the liquid crystal.</jats:p>
article_number: '1695'
author:
- first_name: Bingru
  full_name: Zhang, Bingru
  last_name: Zhang
- first_name: Kevin
  full_name: Martens, Kevin
  last_name: Martens
- first_name: Luisa
  full_name: Kneer, Luisa
  last_name: Kneer
- first_name: Timon
  full_name: Funck, Timon
  last_name: Funck
- first_name: Linh
  full_name: Nguyen, Linh
  last_name: Nguyen
- first_name: Ricarda
  full_name: Berger, Ricarda
  last_name: Berger
- first_name: Mihir
  full_name: Dass, Mihir
  last_name: Dass
- first_name: Susanne
  full_name: Kempter, Susanne
  last_name: Kempter
- first_name: Jürgen
  full_name: Schmidtke, Jürgen
  last_name: Schmidtke
- first_name: Tim
  full_name: Liedl, Tim
  last_name: Liedl
- first_name: Heinz-Siegfried
  full_name: Kitzerow, Heinz-Siegfried
  id: '254'
  last_name: Kitzerow
citation:
  ama: Zhang B, Martens K, Kneer L, et al. DNA Origami Nano-Sheets and Nano-Rods Alter
    the Orientational Order in a Lyotropic Chromonic Liquid Crystal. <i>Nanomaterials</i>.
    2020;10(9). doi:<a href="https://doi.org/10.3390/nano10091695">10.3390/nano10091695</a>
  apa: Zhang, B., Martens, K., Kneer, L., Funck, T., Nguyen, L., Berger, R., Dass,
    M., Kempter, S., Schmidtke, J., Liedl, T., &#38; Kitzerow, H.-S. (2020). DNA Origami
    Nano-Sheets and Nano-Rods Alter the Orientational Order in a Lyotropic Chromonic
    Liquid Crystal. <i>Nanomaterials</i>, <i>10</i>(9), Article 1695. <a href="https://doi.org/10.3390/nano10091695">https://doi.org/10.3390/nano10091695</a>
  bibtex: '@article{Zhang_Martens_Kneer_Funck_Nguyen_Berger_Dass_Kempter_Schmidtke_Liedl_et
    al._2020, title={DNA Origami Nano-Sheets and Nano-Rods Alter the Orientational
    Order in a Lyotropic Chromonic Liquid Crystal}, volume={10}, DOI={<a href="https://doi.org/10.3390/nano10091695">10.3390/nano10091695</a>},
    number={91695}, journal={Nanomaterials}, publisher={MDPI AG}, author={Zhang, Bingru
    and Martens, Kevin and Kneer, Luisa and Funck, Timon and Nguyen, Linh and Berger,
    Ricarda and Dass, Mihir and Kempter, Susanne and Schmidtke, Jürgen and Liedl,
    Tim and et al.}, year={2020} }'
  chicago: Zhang, Bingru, Kevin Martens, Luisa Kneer, Timon Funck, Linh Nguyen, Ricarda
    Berger, Mihir Dass, et al. “DNA Origami Nano-Sheets and Nano-Rods Alter the Orientational
    Order in a Lyotropic Chromonic Liquid Crystal.” <i>Nanomaterials</i> 10, no. 9
    (2020). <a href="https://doi.org/10.3390/nano10091695">https://doi.org/10.3390/nano10091695</a>.
  ieee: 'B. Zhang <i>et al.</i>, “DNA Origami Nano-Sheets and Nano-Rods Alter the
    Orientational Order in a Lyotropic Chromonic Liquid Crystal,” <i>Nanomaterials</i>,
    vol. 10, no. 9, Art. no. 1695, 2020, doi: <a href="https://doi.org/10.3390/nano10091695">10.3390/nano10091695</a>.'
  mla: Zhang, Bingru, et al. “DNA Origami Nano-Sheets and Nano-Rods Alter the Orientational
    Order in a Lyotropic Chromonic Liquid Crystal.” <i>Nanomaterials</i>, vol. 10,
    no. 9, 1695, MDPI AG, 2020, doi:<a href="https://doi.org/10.3390/nano10091695">10.3390/nano10091695</a>.
  short: B. Zhang, K. Martens, L. Kneer, T. Funck, L. Nguyen, R. Berger, M. Dass,
    S. Kempter, J. Schmidtke, T. Liedl, H.-S. Kitzerow, Nanomaterials 10 (2020).
date_created: 2023-01-10T14:01:14Z
date_updated: 2023-01-24T17:17:14Z
department:
- _id: '313'
doi: 10.3390/nano10091695
intvolume: '        10'
issue: '9'
keyword:
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: DNA Origami Nano-Sheets and Nano-Rods Alter the Orientational Order in a Lyotropic
  Chromonic Liquid Crystal
type: journal_article
user_id: '254'
volume: 10
year: '2020'
...
---
_id: '25901'
abstract:
- lang: eng
  text: Thermally stabilized and subsequently carbonized nanofibers are a promising
    material for many technical applications in fields such as tissue engineering
    or energy storage. They can be obtained from a variety of different polymer precursors
    via electrospinning. While some methods have been tested for post-carbonization
    doping of nanofibers with the desired ingredients, very little is known about
    carbonization of blend nanofibers from two or more polymeric precursors. In this
    paper, we report on the preparation, thermal treatment and resulting properties
    of poly(acrylonitrile) (PAN)/poly(vinylidene fluoride) (PVDF) blend nanofibers
    produced by wire-based electrospinning of binary polymer solutions. Using a wide
    variety of spectroscopic, microscopic and thermal characterization methods, the
    chemical and morphological transition during oxidative stabilization (280 °C)
    and incipient carbonization (500 °C) was thoroughly investigated. Both PAN and
    PVDF precursor polymers were detected and analyzed qualitatively and quantitatively
    during all stages of thermal treatment. Compared to pure PAN nanofibers, the blend
    nanofibers showed increased fiber diameters, strong reduction of undesired morphological
    changes during oxidative stabilization and increased conductivity after carbonization.
article_number: '1210'
article_type: original
author:
- first_name: Martin
  full_name: Wortmann, Martin
  last_name: Wortmann
- first_name: Natalie
  full_name: Frese, Natalie
  last_name: Frese
- first_name: Al
  full_name: Mamun, Al
  last_name: Mamun
- first_name: Marah
  full_name: Trabelsi, Marah
  last_name: Trabelsi
- first_name: Waldemar
  full_name: Keil, Waldemar
  last_name: Keil
- first_name: Björn
  full_name: Büker, Björn
  last_name: Büker
- first_name: Ali
  full_name: Javed, Ali
  last_name: Javed
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Elmar
  full_name: Moritzer, Elmar
  id: '20531'
  last_name: Moritzer
- first_name: Andrea
  full_name: Ehrmann, Andrea
  last_name: Ehrmann
- first_name: Andreas
  full_name: Hütten, Andreas
  last_name: Hütten
- first_name: Claudia
  full_name: Schmidt, Claudia
  id: '466'
  last_name: Schmidt
  orcid: 0000-0003-3179-9997
- first_name: Armin
  full_name: Gölzhäuser, Armin
  last_name: Gölzhäuser
- first_name: Bruno
  full_name: Hüsgen, Bruno
  last_name: Hüsgen
- first_name: Lilia
  full_name: Sabantina, Lilia
  last_name: Sabantina
citation:
  ama: Wortmann M, Frese N, Mamun A, et al. Chemical and Morphological Transition
    of Poly(acrylonitrile)/Poly(vinylidene Fluoride) Blend Nanofibers during Oxidative
    Stabilization and Incipient Carbonization. <i>Nanomaterials</i>. Published online
    2020. doi:<a href="https://doi.org/10.3390/nano10061210">10.3390/nano10061210</a>
  apa: Wortmann, M., Frese, N., Mamun, A., Trabelsi, M., Keil, W., Büker, B., Javed,
    A., Tiemann, M., Moritzer, E., Ehrmann, A., Hütten, A., Schmidt, C., Gölzhäuser,
    A., Hüsgen, B., &#38; Sabantina, L. (2020). Chemical and Morphological Transition
    of Poly(acrylonitrile)/Poly(vinylidene Fluoride) Blend Nanofibers during Oxidative
    Stabilization and Incipient Carbonization. <i>Nanomaterials</i>, Article 1210.
    <a href="https://doi.org/10.3390/nano10061210">https://doi.org/10.3390/nano10061210</a>
  bibtex: '@article{Wortmann_Frese_Mamun_Trabelsi_Keil_Büker_Javed_Tiemann_Moritzer_Ehrmann_et
    al._2020, title={Chemical and Morphological Transition of Poly(acrylonitrile)/Poly(vinylidene
    Fluoride) Blend Nanofibers during Oxidative Stabilization and Incipient Carbonization},
    DOI={<a href="https://doi.org/10.3390/nano10061210">10.3390/nano10061210</a>},
    number={1210}, journal={Nanomaterials}, author={Wortmann, Martin and Frese, Natalie
    and Mamun, Al and Trabelsi, Marah and Keil, Waldemar and Büker, Björn and Javed,
    Ali and Tiemann, Michael and Moritzer, Elmar and Ehrmann, Andrea and et al.},
    year={2020} }'
  chicago: Wortmann, Martin, Natalie Frese, Al Mamun, Marah Trabelsi, Waldemar Keil,
    Björn Büker, Ali Javed, et al. “Chemical and Morphological Transition of Poly(Acrylonitrile)/Poly(Vinylidene
    Fluoride) Blend Nanofibers during Oxidative Stabilization and Incipient Carbonization.”
    <i>Nanomaterials</i>, 2020. <a href="https://doi.org/10.3390/nano10061210">https://doi.org/10.3390/nano10061210</a>.
  ieee: 'M. Wortmann <i>et al.</i>, “Chemical and Morphological Transition of Poly(acrylonitrile)/Poly(vinylidene
    Fluoride) Blend Nanofibers during Oxidative Stabilization and Incipient Carbonization,”
    <i>Nanomaterials</i>, Art. no. 1210, 2020, doi: <a href="https://doi.org/10.3390/nano10061210">10.3390/nano10061210</a>.'
  mla: Wortmann, Martin, et al. “Chemical and Morphological Transition of Poly(Acrylonitrile)/Poly(Vinylidene
    Fluoride) Blend Nanofibers during Oxidative Stabilization and Incipient Carbonization.”
    <i>Nanomaterials</i>, 1210, 2020, doi:<a href="https://doi.org/10.3390/nano10061210">10.3390/nano10061210</a>.
  short: M. Wortmann, N. Frese, A. Mamun, M. Trabelsi, W. Keil, B. Büker, A. Javed,
    M. Tiemann, E. Moritzer, A. Ehrmann, A. Hütten, C. Schmidt, A. Gölzhäuser, B.
    Hüsgen, L. Sabantina, Nanomaterials (2020).
date_created: 2021-10-08T10:36:26Z
date_updated: 2023-03-08T08:18:03Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
- _id: '315'
- _id: '232'
doi: 10.3390/nano10061210
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://www.mdpi.com/2079-4991/10/6/1210/pdf?version=1592726383
oa: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
quality_controlled: '1'
status: public
title: Chemical and Morphological Transition of Poly(acrylonitrile)/Poly(vinylidene
  Fluoride) Blend Nanofibers during Oxidative Stabilization and Incipient Carbonization
type: journal_article
user_id: '23547'
year: '2020'
...
---
_id: '25899'
abstract:
- lang: eng
  text: Large Co-MOF-74 crystals of a few hundred micrometers were prepared by solvothermal
    synthesis, and their structure and morphology were characterized by scanning electron
    microscopy (SEM), IR, and Raman spectroscopy. The hydrothermal stability of the
    material up to 60 °C at 93% relative humidity was verified by temperature-dependent
    XRD. Proton conductivity was studied by impedance spectroscopy, using a single
    crystal. By varying the relative humidity (70–95%), temperature (21–60 °C), and
    orientation of the crystal relative to the electrical potential, it was found
    that proton conduction occurs predominantly through the linear, unidirectional
    (1D) micropore channels of Co-MOF-74, and that water molecules inside the channels
    are responsible for the proton mobility by a Grotthuss-type mechanism.
article_number: '1263'
article_type: original
author:
- first_name: Ali
  full_name: Javed, Ali
  last_name: Javed
- first_name: Ina
  full_name: Strauss, Ina
  last_name: Strauss
- first_name: Hana
  full_name: Bunzen, Hana
  last_name: Bunzen
- first_name: Jürgen
  full_name: Caro, Jürgen
  last_name: Caro
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Javed A, Strauss I, Bunzen H, Caro J, Tiemann M. Humidity-Mediated Anisotropic
    Proton Conductivity through the 1D Channels of Co-MOF-74. <i>Nanomaterials</i>.
    Published online 2020. doi:<a href="https://doi.org/10.3390/nano10071263">10.3390/nano10071263</a>
  apa: Javed, A., Strauss, I., Bunzen, H., Caro, J., &#38; Tiemann, M. (2020). Humidity-Mediated
    Anisotropic Proton Conductivity through the 1D Channels of Co-MOF-74. <i>Nanomaterials</i>,
    Article 1263. <a href="https://doi.org/10.3390/nano10071263">https://doi.org/10.3390/nano10071263</a>
  bibtex: '@article{Javed_Strauss_Bunzen_Caro_Tiemann_2020, title={Humidity-Mediated
    Anisotropic Proton Conductivity through the 1D Channels of Co-MOF-74}, DOI={<a
    href="https://doi.org/10.3390/nano10071263">10.3390/nano10071263</a>}, number={1263},
    journal={Nanomaterials}, author={Javed, Ali and Strauss, Ina and Bunzen, Hana
    and Caro, Jürgen and Tiemann, Michael}, year={2020} }'
  chicago: Javed, Ali, Ina Strauss, Hana Bunzen, Jürgen Caro, and Michael Tiemann.
    “Humidity-Mediated Anisotropic Proton Conductivity through the 1D Channels of
    Co-MOF-74.” <i>Nanomaterials</i>, 2020. <a href="https://doi.org/10.3390/nano10071263">https://doi.org/10.3390/nano10071263</a>.
  ieee: 'A. Javed, I. Strauss, H. Bunzen, J. Caro, and M. Tiemann, “Humidity-Mediated
    Anisotropic Proton Conductivity through the 1D Channels of Co-MOF-74,” <i>Nanomaterials</i>,
    Art. no. 1263, 2020, doi: <a href="https://doi.org/10.3390/nano10071263">10.3390/nano10071263</a>.'
  mla: Javed, Ali, et al. “Humidity-Mediated Anisotropic Proton Conductivity through
    the 1D Channels of Co-MOF-74.” <i>Nanomaterials</i>, 1263, 2020, doi:<a href="https://doi.org/10.3390/nano10071263">10.3390/nano10071263</a>.
  short: A. Javed, I. Strauss, H. Bunzen, J. Caro, M. Tiemann, Nanomaterials (2020).
date_created: 2021-10-08T10:33:26Z
date_updated: 2023-03-08T08:22:31Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.3390/nano10071263
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://www.mdpi.com/2079-4991/10/7/1263/pdf?version=1594009427
oa: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
quality_controlled: '1'
status: public
title: Humidity-Mediated Anisotropic Proton Conductivity through the 1D Channels of
  Co-MOF-74
type: journal_article
user_id: '23547'
year: '2020'
...
---
_id: '25902'
abstract:
- lang: eng
  text: This Special Issue on “Functional Nanoporous Materials” in the MDPI journal
    nanomaterials features seven original papers ...
article_number: '699'
article_type: original
author:
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Weinberger C, Tiemann M. Functional Nanoporous Materials. <i>Nanomaterials</i>.
    Published online 2020. doi:<a href="https://doi.org/10.3390/nano10040699">10.3390/nano10040699</a>
  apa: Weinberger, C., &#38; Tiemann, M. (2020). Functional Nanoporous Materials.
    <i>Nanomaterials</i>, Article 699. <a href="https://doi.org/10.3390/nano10040699">https://doi.org/10.3390/nano10040699</a>
  bibtex: '@article{Weinberger_Tiemann_2020, title={Functional Nanoporous Materials},
    DOI={<a href="https://doi.org/10.3390/nano10040699">10.3390/nano10040699</a>},
    number={699}, journal={Nanomaterials}, author={Weinberger, Christian and Tiemann,
    Michael}, year={2020} }'
  chicago: Weinberger, Christian, and Michael Tiemann. “Functional Nanoporous Materials.”
    <i>Nanomaterials</i>, 2020. <a href="https://doi.org/10.3390/nano10040699">https://doi.org/10.3390/nano10040699</a>.
  ieee: 'C. Weinberger and M. Tiemann, “Functional Nanoporous Materials,” <i>Nanomaterials</i>,
    Art. no. 699, 2020, doi: <a href="https://doi.org/10.3390/nano10040699">10.3390/nano10040699</a>.'
  mla: Weinberger, Christian, and Michael Tiemann. “Functional Nanoporous Materials.”
    <i>Nanomaterials</i>, 699, 2020, doi:<a href="https://doi.org/10.3390/nano10040699">10.3390/nano10040699</a>.
  short: C. Weinberger, M. Tiemann, Nanomaterials (2020).
date_created: 2021-10-08T10:37:54Z
date_updated: 2023-03-08T08:27:09Z
department:
- _id: '2'
- _id: '307'
- _id: '35'
doi: 10.3390/nano10040699
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://www.mdpi.com/2079-4991/10/4/699/pdf?version=1586249724
oa: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
status: public
title: Functional Nanoporous Materials
type: journal_article
user_id: '23547'
year: '2020'
...
---
_id: '25907'
abstract:
- lang: eng
  text: <jats:p>The combined benefits of moisture-stable phosphonic acids and mesoporous
    silica materials (SBA-15 and MCM-41) as large-surface-area solid supports offer
    new opportunities for several applications, such as catalysis or drug delivery.
    We present a comprehensive study of a straightforward synthesis method via direct
    immobilization of several phosphonic acids and phosphoric acid esters on various
    mesoporous silicas in a Dean–Stark apparatus with toluene as the solvent. Due
    to the utilization of azeotropic distillation, there was no need to dry phosphonic
    acids, phosphoric acid esters, solvents, or silicas prior to synthesis. In addition
    to modeling phosphonic acids, immobilization of the important biomolecule adenosine
    monophosphate (AMP) on the porous supports was also investigated. Due to the high
    surface area of the mesoporous silicas, a possible catalytic application based
    on immobilization of an organocatalyst for an asymmetric aldol reaction is discussed.</jats:p>
article_number: '249'
article_type: original
author:
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Tatjana
  full_name: Heckel, Tatjana
  last_name: Heckel
- first_name: Patrick
  full_name: Schnippering, Patrick
  last_name: Schnippering
- first_name: Markus
  full_name: Schmitz, Markus
  last_name: Schmitz
- first_name: Anpeng
  full_name: Guo, Anpeng
  last_name: Guo
- first_name: Waldemar
  full_name: Keil, Waldemar
  last_name: Keil
- first_name: Heinrich C.
  full_name: Marsmann, Heinrich C.
  last_name: Marsmann
- first_name: Claudia
  full_name: Schmidt, Claudia
  id: '466'
  last_name: Schmidt
  orcid: 0000-0003-3179-9997
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: René
  full_name: Wilhelm, René
  last_name: Wilhelm
citation:
  ama: Weinberger C, Heckel T, Schnippering P, et al. Straightforward Immobilization
    of Phosphonic Acids and Phosphoric Acid Esters on Mesoporous Silica and Their
    Application in an Asymmetric Aldol Reaction. <i>Nanomaterials</i>. Published online
    2019. doi:<a href="https://doi.org/10.3390/nano9020249">10.3390/nano9020249</a>
  apa: Weinberger, C., Heckel, T., Schnippering, P., Schmitz, M., Guo, A., Keil, W.,
    Marsmann, H. C., Schmidt, C., Tiemann, M., &#38; Wilhelm, R. (2019). Straightforward
    Immobilization of Phosphonic Acids and Phosphoric Acid Esters on Mesoporous Silica
    and Their Application in an Asymmetric Aldol Reaction. <i>Nanomaterials</i>, Article
    249. <a href="https://doi.org/10.3390/nano9020249">https://doi.org/10.3390/nano9020249</a>
  bibtex: '@article{Weinberger_Heckel_Schnippering_Schmitz_Guo_Keil_Marsmann_Schmidt_Tiemann_Wilhelm_2019,
    title={Straightforward Immobilization of Phosphonic Acids and Phosphoric Acid
    Esters on Mesoporous Silica and Their Application in an Asymmetric Aldol Reaction},
    DOI={<a href="https://doi.org/10.3390/nano9020249">10.3390/nano9020249</a>}, number={249},
    journal={Nanomaterials}, author={Weinberger, Christian and Heckel, Tatjana and
    Schnippering, Patrick and Schmitz, Markus and Guo, Anpeng and Keil, Waldemar and
    Marsmann, Heinrich C. and Schmidt, Claudia and Tiemann, Michael and Wilhelm, René},
    year={2019} }'
  chicago: Weinberger, Christian, Tatjana Heckel, Patrick Schnippering, Markus Schmitz,
    Anpeng Guo, Waldemar Keil, Heinrich C. Marsmann, Claudia Schmidt, Michael Tiemann,
    and René Wilhelm. “Straightforward Immobilization of Phosphonic Acids and Phosphoric
    Acid Esters on Mesoporous Silica and Their Application in an Asymmetric Aldol
    Reaction.” <i>Nanomaterials</i>, 2019. <a href="https://doi.org/10.3390/nano9020249">https://doi.org/10.3390/nano9020249</a>.
  ieee: 'C. Weinberger <i>et al.</i>, “Straightforward Immobilization of Phosphonic
    Acids and Phosphoric Acid Esters on Mesoporous Silica and Their Application in
    an Asymmetric Aldol Reaction,” <i>Nanomaterials</i>, Art. no. 249, 2019, doi:
    <a href="https://doi.org/10.3390/nano9020249">10.3390/nano9020249</a>.'
  mla: Weinberger, Christian, et al. “Straightforward Immobilization of Phosphonic
    Acids and Phosphoric Acid Esters on Mesoporous Silica and Their Application in
    an Asymmetric Aldol Reaction.” <i>Nanomaterials</i>, 249, 2019, doi:<a href="https://doi.org/10.3390/nano9020249">10.3390/nano9020249</a>.
  short: C. Weinberger, T. Heckel, P. Schnippering, M. Schmitz, A. Guo, W. Keil, H.C.
    Marsmann, C. Schmidt, M. Tiemann, R. Wilhelm, Nanomaterials (2019).
date_created: 2021-10-08T10:44:56Z
date_updated: 2023-03-08T08:32:12Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
- _id: '315'
doi: 10.3390/nano9020249
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://www.mdpi.com/2079-4991/9/2/249/pdf?version=1550901386
oa: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
quality_controlled: '1'
status: public
title: Straightforward Immobilization of Phosphonic Acids and Phosphoric Acid Esters
  on Mesoporous Silica and Their Application in an Asymmetric Aldol Reaction
type: journal_article
user_id: '23547'
year: '2019'
...
---
_id: '25910'
abstract:
- lang: eng
  text: We describe the synthesis of mesoporous Al2O3 and MgO layers on silicon wafer
    substrates by using poly(dimethylacrylamide) hydrogels as porogenic matrices.
    Hydrogel films are prepared by spreading the polymer through spin-coating, followed
    by photo-cross-linking and anchoring to the substrate surface. The metal oxides
    are obtained by swelling the hydrogels in the respective metal nitrate solutions
    and subsequent thermal conversion. Combustion of the hydrogel results in mesoporous
    metal oxide layers with thicknesses in the μm range and high specific surface
    areas up to 558 m2∙g−1. Materials are characterized by SEM, FIB ablation, EDX,
    and Kr physisorption porosimetry.
article_number: '186'
article_type: original
author:
- first_name: Zimei
  full_name: Chen, Zimei
  last_name: Chen
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: Chen Z, Kuckling D, Tiemann M. Porous Aluminum Oxide and Magnesium Oxide Films
    Using Organic Hydrogels as Structure Matrices. <i>Nanomaterials</i>. Published
    online 2018. doi:<a href="https://doi.org/10.3390/nano8040186">10.3390/nano8040186</a>
  apa: Chen, Z., Kuckling, D., &#38; Tiemann, M. (2018). Porous Aluminum Oxide and
    Magnesium Oxide Films Using Organic Hydrogels as Structure Matrices. <i>Nanomaterials</i>,
    Article 186. <a href="https://doi.org/10.3390/nano8040186">https://doi.org/10.3390/nano8040186</a>
  bibtex: '@article{Chen_Kuckling_Tiemann_2018, title={Porous Aluminum Oxide and Magnesium
    Oxide Films Using Organic Hydrogels as Structure Matrices}, DOI={<a href="https://doi.org/10.3390/nano8040186">10.3390/nano8040186</a>},
    number={186}, journal={Nanomaterials}, author={Chen, Zimei and Kuckling, Dirk
    and Tiemann, Michael}, year={2018} }'
  chicago: Chen, Zimei, Dirk Kuckling, and Michael Tiemann. “Porous Aluminum Oxide
    and Magnesium Oxide Films Using Organic Hydrogels as Structure Matrices.” <i>Nanomaterials</i>,
    2018. <a href="https://doi.org/10.3390/nano8040186">https://doi.org/10.3390/nano8040186</a>.
  ieee: 'Z. Chen, D. Kuckling, and M. Tiemann, “Porous Aluminum Oxide and Magnesium
    Oxide Films Using Organic Hydrogels as Structure Matrices,” <i>Nanomaterials</i>,
    Art. no. 186, 2018, doi: <a href="https://doi.org/10.3390/nano8040186">10.3390/nano8040186</a>.'
  mla: Chen, Zimei, et al. “Porous Aluminum Oxide and Magnesium Oxide Films Using
    Organic Hydrogels as Structure Matrices.” <i>Nanomaterials</i>, 186, 2018, doi:<a
    href="https://doi.org/10.3390/nano8040186">10.3390/nano8040186</a>.
  short: Z. Chen, D. Kuckling, M. Tiemann, Nanomaterials (2018).
date_created: 2021-10-08T10:48:59Z
date_updated: 2023-03-08T10:22:33Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
- _id: '311'
doi: 10.3390/nano8040186
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://www.mdpi.com/2079-4991/8/4/186/pdf?version=1525344745
oa: '1'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
quality_controlled: '1'
status: public
title: Porous Aluminum Oxide and Magnesium Oxide Films Using Organic Hydrogels as
  Structure Matrices
type: journal_article
user_id: '23547'
year: '2018'
...
---
_id: '64053'
abstract:
- lang: eng
  text: The utilization and preparation of functional hybrid films for optical sensing
    applications and membranes is of utmost importance. In this work, we report the
    convenient and scalable preparation of self-crosslinking particle-based films
    derived by directed self-assembly of alkoxysilane-based cross-linkers as part
    of a core-shell particle architecture. The synthesis of well-designed monodisperse
    core-shell particles by emulsion polymerization is the basic prerequisite for
    subsequent particle processing via the melt-shear organization technique. In more
    detail, the core particles consist of polystyrene (PS) or poly(methyl methacrylate)
    (PMMA), while the comparably soft particle shell consists of poly(ethyl acrylate)
    (PEA) and different alkoxysilane-based poly(methacrylate)s. For hybrid film formation
    and convenient self-cross-linking, different alkyl groups at the siloxane moieties
    were investigated in detail by solid-state Magic-Angle Spinning Nuclear Magnetic
    Resonance (MAS, NMR) spectroscopy revealing different crosslinking capabilities,
    which strongly influence the properties of the core or shell particle films with
    respect to transparency and iridescent reflection colors. Furthermore, solid-state
    NMR spectroscopy and investigation of the thermal properties by differential scanning
    calorimetry (DSC) measurements allow for insights into the cross-linking capabilities
    prior to and after synthesis, as well as after the thermally and pressure-induced
    processing steps. Subsequently, free-standing and self-crosslinked particle-based
    films featuring excellent particle order are obtained by application of the melt-shear
    organization technique, as shown by microscopy (TEM, SEM).
author:
- first_name: S.
  full_name: Vowinkel, S.
  last_name: Vowinkel
- first_name: S.
  full_name: Paul, S.
  last_name: Paul
- first_name: Torsten
  full_name: Gutmann, Torsten
  id: '118165'
  last_name: Gutmann
- first_name: M.
  full_name: Gallei, M.
  last_name: Gallei
citation:
  ama: Vowinkel S, Paul S, Gutmann T, Gallei M. Free-Standing and Self-Crosslinkable
    Hybrid Films by Core-Shell Particle Design and Processing. <i>Nanomaterials</i>.
    2017;7(11):390. doi:<a href="https://doi.org/10.3390/nano7110390">10.3390/nano7110390</a>
  apa: Vowinkel, S., Paul, S., Gutmann, T., &#38; Gallei, M. (2017). Free-Standing
    and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing.
    <i>Nanomaterials</i>, <i>7</i>(11), 390. <a href="https://doi.org/10.3390/nano7110390">https://doi.org/10.3390/nano7110390</a>
  bibtex: '@article{Vowinkel_Paul_Gutmann_Gallei_2017, title={Free-Standing and Self-Crosslinkable
    Hybrid Films by Core-Shell Particle Design and Processing}, volume={7}, DOI={<a
    href="https://doi.org/10.3390/nano7110390">10.3390/nano7110390</a>}, number={11},
    journal={Nanomaterials}, author={Vowinkel, S. and Paul, S. and Gutmann, Torsten
    and Gallei, M.}, year={2017}, pages={390} }'
  chicago: 'Vowinkel, S., S. Paul, Torsten Gutmann, and M. Gallei. “Free-Standing
    and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design and Processing.”
    <i>Nanomaterials</i> 7, no. 11 (2017): 390. <a href="https://doi.org/10.3390/nano7110390">https://doi.org/10.3390/nano7110390</a>.'
  ieee: 'S. Vowinkel, S. Paul, T. Gutmann, and M. Gallei, “Free-Standing and Self-Crosslinkable
    Hybrid Films by Core-Shell Particle Design and Processing,” <i>Nanomaterials</i>,
    vol. 7, no. 11, p. 390, 2017, doi: <a href="https://doi.org/10.3390/nano7110390">10.3390/nano7110390</a>.'
  mla: Vowinkel, S., et al. “Free-Standing and Self-Crosslinkable Hybrid Films by
    Core-Shell Particle Design and Processing.” <i>Nanomaterials</i>, vol. 7, no.
    11, 2017, p. 390, doi:<a href="https://doi.org/10.3390/nano7110390">10.3390/nano7110390</a>.
  short: S. Vowinkel, S. Paul, T. Gutmann, M. Gallei, Nanomaterials 7 (2017) 390.
date_created: 2026-02-07T16:15:23Z
date_updated: 2026-02-17T16:12:54Z
doi: 10.3390/nano7110390
extern: '1'
intvolume: '         7'
issue: '11'
keyword:
- Materials Science
- Science & Technology - Other Topics
- solid-state nmr
- spectroscopy
- catalysts
- colloidal crystals
- colloids
- cross-linking
- elastomeric opal films
- emulsion polymerization
- gamma-methacryloxypropyltrimethoxysilane
- hybrid films
- melt-shear organization
- nanoparticles
- particle
- photons
- polymers
- processing
- self-assembly
- transition
language:
- iso: eng
page: '390'
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
status: public
title: Free-Standing and Self-Crosslinkable Hybrid Films by Core-Shell Particle Design
  and Processing
type: journal_article
user_id: '100715'
volume: 7
year: '2017'
...
---
_id: '39467'
article_number: '154'
author:
- first_name: Fábio
  full_name: Vidor, Fábio
  last_name: Vidor
- first_name: Thorsten
  full_name: Meyers, Thorsten
  last_name: Meyers
- first_name: Ulrich
  full_name: Hilleringmann, Ulrich
  id: '20179'
  last_name: Hilleringmann
citation:
  ama: Vidor F, Meyers T, Hilleringmann U. Inverter Circuits Using ZnO Nanoparticle
    Based Thin-Film Transistors for Flexible Electronic Applications. <i>Nanomaterials</i>.
    2016;6(9). doi:<a href="https://doi.org/10.3390/nano6090154">10.3390/nano6090154</a>
  apa: Vidor, F., Meyers, T., &#38; Hilleringmann, U. (2016). Inverter Circuits Using
    ZnO Nanoparticle Based Thin-Film Transistors for Flexible Electronic Applications.
    <i>Nanomaterials</i>, <i>6</i>(9), Article 154. <a href="https://doi.org/10.3390/nano6090154">https://doi.org/10.3390/nano6090154</a>
  bibtex: '@article{Vidor_Meyers_Hilleringmann_2016, title={Inverter Circuits Using
    ZnO Nanoparticle Based Thin-Film Transistors for Flexible Electronic Applications},
    volume={6}, DOI={<a href="https://doi.org/10.3390/nano6090154">10.3390/nano6090154</a>},
    number={9154}, journal={Nanomaterials}, publisher={MDPI AG}, author={Vidor, Fábio
    and Meyers, Thorsten and Hilleringmann, Ulrich}, year={2016} }'
  chicago: Vidor, Fábio, Thorsten Meyers, and Ulrich Hilleringmann. “Inverter Circuits
    Using ZnO Nanoparticle Based Thin-Film Transistors for Flexible Electronic Applications.”
    <i>Nanomaterials</i> 6, no. 9 (2016). <a href="https://doi.org/10.3390/nano6090154">https://doi.org/10.3390/nano6090154</a>.
  ieee: 'F. Vidor, T. Meyers, and U. Hilleringmann, “Inverter Circuits Using ZnO Nanoparticle
    Based Thin-Film Transistors for Flexible Electronic Applications,” <i>Nanomaterials</i>,
    vol. 6, no. 9, Art. no. 154, 2016, doi: <a href="https://doi.org/10.3390/nano6090154">10.3390/nano6090154</a>.'
  mla: Vidor, Fábio, et al. “Inverter Circuits Using ZnO Nanoparticle Based Thin-Film
    Transistors for Flexible Electronic Applications.” <i>Nanomaterials</i>, vol.
    6, no. 9, 154, MDPI AG, 2016, doi:<a href="https://doi.org/10.3390/nano6090154">10.3390/nano6090154</a>.
  short: F. Vidor, T. Meyers, U. Hilleringmann, Nanomaterials 6 (2016).
date_created: 2023-01-24T11:15:22Z
date_updated: 2023-03-22T10:22:33Z
department:
- _id: '59'
doi: 10.3390/nano6090154
intvolume: '         6'
issue: '9'
keyword:
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
publisher: MDPI AG
status: public
title: Inverter Circuits Using ZnO Nanoparticle Based Thin-Film Transistors for Flexible
  Electronic Applications
type: journal_article
user_id: '20179'
volume: 6
year: '2016'
...
---
_id: '25939'
abstract:
- lang: eng
  text: A variety of metal nitrates were filled into the pores of an ordered mesoporous
    CMK-3 carbon matrix by solution-based impregnation. Thermal conversion of the
    metal nitrates into the respective metal oxides, and subsequent removal of the
    carbon matrix by thermal combustion, provides a versatile means to prepare mesoporous
    metal oxides (so-called nanocasting). This study aims to monitor the thermally
    induced processes by thermogravimetric analysis (TGA), coupled with mass ion detection
    (MS). The highly dispersed metal nitrates in the pores of the carbon matrix tend
    to react to the respective metal oxides at lower temperature than reported in
    the literature for pure, i.e., carbon-free, metal nitrates. The subsequent thermal
    combustion of the CMK-3 carbon matrix also occurs at lower temperature, which
    is explained by a catalytic effect of the metal oxides present in the pores. This
    catalytic effect is particularly strong for oxides of redox active metals, such
    as transition group VII and VIII metals (Mn, Fe, Co, Ni), Cu, and Ce.
article_type: original
author:
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Jan
  full_name: Roggenbuck, Jan
  last_name: Roggenbuck
- first_name: Jan
  full_name: Hanss, Jan
  last_name: Hanss
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
citation:
  ama: 'Weinberger C, Roggenbuck J, Hanss J, Tiemann M. Synthesis of Mesoporous Metal
    Oxides by Structure Replication: Thermal Analysis of Metal Nitrates in Porous
    Carbon Matrices. <i>Nanomaterials</i>. Published online 2015:1431-1441. doi:<a
    href="https://doi.org/10.3390/nano5031431">10.3390/nano5031431</a>'
  apa: 'Weinberger, C., Roggenbuck, J., Hanss, J., &#38; Tiemann, M. (2015). Synthesis
    of Mesoporous Metal Oxides by Structure Replication: Thermal Analysis of Metal
    Nitrates in Porous Carbon Matrices. <i>Nanomaterials</i>, 1431–1441. <a href="https://doi.org/10.3390/nano5031431">https://doi.org/10.3390/nano5031431</a>'
  bibtex: '@article{Weinberger_Roggenbuck_Hanss_Tiemann_2015, title={Synthesis of
    Mesoporous Metal Oxides by Structure Replication: Thermal Analysis of Metal Nitrates
    in Porous Carbon Matrices}, DOI={<a href="https://doi.org/10.3390/nano5031431">10.3390/nano5031431</a>},
    journal={Nanomaterials}, author={Weinberger, Christian and Roggenbuck, Jan and
    Hanss, Jan and Tiemann, Michael}, year={2015}, pages={1431–1441} }'
  chicago: 'Weinberger, Christian, Jan Roggenbuck, Jan Hanss, and Michael Tiemann.
    “Synthesis of Mesoporous Metal Oxides by Structure Replication: Thermal Analysis
    of Metal Nitrates in Porous Carbon Matrices.” <i>Nanomaterials</i>, 2015, 1431–41.
    <a href="https://doi.org/10.3390/nano5031431">https://doi.org/10.3390/nano5031431</a>.'
  ieee: 'C. Weinberger, J. Roggenbuck, J. Hanss, and M. Tiemann, “Synthesis of Mesoporous
    Metal Oxides by Structure Replication: Thermal Analysis of Metal Nitrates in Porous
    Carbon Matrices,” <i>Nanomaterials</i>, pp. 1431–1441, 2015, doi: <a href="https://doi.org/10.3390/nano5031431">10.3390/nano5031431</a>.'
  mla: 'Weinberger, Christian, et al. “Synthesis of Mesoporous Metal Oxides by Structure
    Replication: Thermal Analysis of Metal Nitrates in Porous Carbon Matrices.” <i>Nanomaterials</i>,
    2015, pp. 1431–41, doi:<a href="https://doi.org/10.3390/nano5031431">10.3390/nano5031431</a>.'
  short: C. Weinberger, J. Roggenbuck, J. Hanss, M. Tiemann, Nanomaterials (2015)
    1431–1441.
date_created: 2021-10-08T13:49:57Z
date_updated: 2023-03-08T10:29:19Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.3390/nano5031431
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://www.mdpi.com/2079-4991/5/3/1431/pdf?version=1440760886
oa: '1'
page: 1431-1441
publication: Nanomaterials
publication_identifier:
  issn:
  - 2079-4991
publication_status: published
quality_controlled: '1'
status: public
title: 'Synthesis of Mesoporous Metal Oxides by Structure Replication: Thermal Analysis
  of Metal Nitrates in Porous Carbon Matrices'
type: journal_article
user_id: '23547'
year: '2015'
...
