---
_id: '64182'
abstract:
- lang: eng
text: Overcoming the slow kinetics of the oxygen evolution reaction at the anode
is a key challenge for the production of hydrogen via electrolysis. This reaction
operates at very positive potentials, where the electrocatalyst is exposed to
highly oxidative conditions and prone to potential-dependent transformation of
the near-surface region. While substantial evidence for such surface restructuring
exists, its extent and relevance for the catalyst’s activity are unclear. We address
this topic for the case of Co3O4, one of the best-known electrocatalysts exhibiting
surface restructuring, by studies of epitaxial (111)-ordered electrodeposited
films with combined operando X-ray surface diffraction and absorption spectroscopy,
electrochemical impedance spectroscopy, and electrochemical measurements on rotating
disk electrodes. Comparison of the as-prepared and annealed state of the same
samples, which both are stable even under long-term oxygen evolution conditions,
provides clear insight into the role of surface defects. Our results show that
defect-free annealed Co3O4(111) surfaces are structurally stable over a wide potential
range and hydroxylate via adsorption at surface oxygen and Co sites. Potential-induced
surface restructuring of the Co3O4 lattice occurs only in the presence of surface
defects, leading to the formation of the well-known nanometer-thick oxyhydroxide
skin layer. The presence of this skin layer promotes oxygen evolution at low overpotentials
but results in higher Tafel slopes. As a result, highly ordered Co3O4(111) surfaces
are more active at high current densities than defective Co3O4 surfaces that undergo
surface restructuring. These results highlight that strategies for catalyst surface
defect engineering need to be application-oriented.
article_number: acscatal.5c08785
article_type: original
author:
- first_name: Carl Hendric
full_name: Scharf, Carl Hendric
last_name: Scharf
- first_name: Alex
full_name: Chandraraj, Alex
last_name: Chandraraj
- first_name: Konrad
full_name: Dyk, Konrad
last_name: Dyk
- first_name: Felix
full_name: Stebner, Felix
last_name: Stebner
- first_name: Sören
full_name: Lepin, Sören
last_name: Lepin
- first_name: Jing
full_name: Tian, Jing
last_name: Tian
- first_name: Laila
full_name: El Bergmi Byaz, Laila
last_name: El Bergmi Byaz
- first_name: Jochim
full_name: Stettner, Jochim
last_name: Stettner
- first_name: Christian
full_name: Leppin, Christian
id: '117722'
last_name: Leppin
- first_name: Anastasiia
full_name: Kotova, Anastasiia
last_name: Kotova
- first_name: Sebastian
full_name: Reinke, Sebastian
id: '117727'
last_name: Reinke
- first_name: Julia
full_name: Linnemann, Julia
id: '116779'
last_name: Linnemann
orcid: 0000-0001-6883-5424
- first_name: Fouad
full_name: Maroun, Fouad
last_name: Maroun
- first_name: Olaf M.
full_name: Magnussen, Olaf M.
last_name: Magnussen
citation:
ama: Scharf CH, Chandraraj A, Dyk K, et al. Role of Defects in Reversible Surface
Restructuring and Activity of Co3O4 Oxygen Evolution Electrocatalysts.
ACS Catalysis. Published online 2026. doi:10.1021/acscatal.5c08785
apa: Scharf, C. H., Chandraraj, A., Dyk, K., Stebner, F., Lepin, S., Tian, J., El
Bergmi Byaz, L., Stettner, J., Leppin, C., Kotova, A., Reinke, S., Linnemann,
J., Maroun, F., & Magnussen, O. M. (2026). Role of Defects in Reversible Surface
Restructuring and Activity of Co3O4 Oxygen Evolution Electrocatalysts.
ACS Catalysis, Article acscatal.5c08785. https://doi.org/10.1021/acscatal.5c08785
bibtex: '@article{Scharf_Chandraraj_Dyk_Stebner_Lepin_Tian_El Bergmi Byaz_Stettner_Leppin_Kotova_et
al._2026, title={Role of Defects in Reversible Surface Restructuring and Activity
of Co3O4 Oxygen Evolution Electrocatalysts}, DOI={10.1021/acscatal.5c08785},
number={acscatal.5c08785}, journal={ACS Catalysis}, publisher={American Chemical
Society (ACS)}, author={Scharf, Carl Hendric and Chandraraj, Alex and Dyk, Konrad
and Stebner, Felix and Lepin, Sören and Tian, Jing and El Bergmi Byaz, Laila and
Stettner, Jochim and Leppin, Christian and Kotova, Anastasiia and et al.}, year={2026}
}'
chicago: Scharf, Carl Hendric, Alex Chandraraj, Konrad Dyk, Felix Stebner, Sören
Lepin, Jing Tian, Laila El Bergmi Byaz, et al. “Role of Defects in Reversible
Surface Restructuring and Activity of Co3O4 Oxygen Evolution
Electrocatalysts.” ACS Catalysis, 2026. https://doi.org/10.1021/acscatal.5c08785.
ieee: 'C. H. Scharf et al., “Role of Defects in Reversible Surface Restructuring
and Activity of Co3O4 Oxygen Evolution Electrocatalysts,”
ACS Catalysis, Art. no. acscatal.5c08785, 2026, doi: 10.1021/acscatal.5c08785.'
mla: Scharf, Carl Hendric, et al. “Role of Defects in Reversible Surface Restructuring
and Activity of Co3O4 Oxygen Evolution Electrocatalysts.”
ACS Catalysis, acscatal.5c08785, American Chemical Society (ACS), 2026,
doi:10.1021/acscatal.5c08785.
short: C.H. Scharf, A. Chandraraj, K. Dyk, F. Stebner, S. Lepin, J. Tian, L. El
Bergmi Byaz, J. Stettner, C. Leppin, A. Kotova, S. Reinke, J. Linnemann, F. Maroun,
O.M. Magnussen, ACS Catalysis (2026).
date_created: 2026-02-16T14:22:15Z
date_updated: 2026-02-16T14:25:00Z
department:
- _id: '985'
doi: 10.1021/acscatal.5c08785
keyword:
- electrocatalysis
- oxygen evolution reaction
- cobalt spinel
- operando characterization
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://pubs.acs.org/doi/10.1021/acscatal.5c08785
oa: '1'
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Role of Defects in Reversible Surface Restructuring and Activity of Co3O4
Oxygen Evolution Electrocatalysts
type: journal_article
user_id: '116779'
year: '2026'
...
---
_id: '61982'
abstract:
- lang: eng
text: Doped Co3O4 nanoparticles are investigated via spectro-electrochemistry in
the (pre-) oxygen evolution reaction (OER) regime by tracing the absorption signal
of the Co3+ d–d transition under applied bias for getting insight into the catalysts
activation and the formation of catalytically active phases. In the low potential
regime up to 1.37 VRHE, a rise in the optical absorption signal of the [Co3+]oct
d–d transition is observed and attributed to a structural change from [Co2+]tet
to [Co3+]oct due to an electrochemically induced surface restructuring with water.
For applied potentials higher than 1.37 VRHE an overall offset of the absorption
spectra in the UV–vis range, equivalent to a darkening of the materials is detected.
This is attributed to the formation of a CoOx(OH)y skin layer as supported by
high-energy X-ray diffraction (HE-XRD) measurements. We found that the kinetics
of the Co3+ states are heavily influenced by the type of dopant with V-doped Co3O4
exhibiting stable Co3+ states (>20 min) while the Mn-doped Co3O4 Co3+ states reduce
within 36 s under reductive bias. We conclude that doping Co3O4 with transition
metals affects the formation and potential-dependent thickness of the CoOx(OH)y
skin layer as the catalytically active phase and the formation of long-time stable
surface Co3+ states after activation in the first OER cycle.
article_type: original
author:
- first_name: L.
full_name: Kampermann, L.
last_name: Kampermann
- first_name: J.
full_name: Klein, J.
last_name: Klein
- first_name: T.
full_name: Wagner, T.
last_name: Wagner
- first_name: A.
full_name: Kotova, A.
last_name: Kotova
- first_name: C.
full_name: Placke-Yan, C.
last_name: Placke-Yan
- first_name: A.
full_name: Yasar, A.
last_name: Yasar
- first_name: L.
full_name: Jacobse, L.
last_name: Jacobse
- first_name: S.
full_name: Lasagna, S.
last_name: Lasagna
- first_name: Christian
full_name: Leppin, Christian
id: '117722'
last_name: Leppin
- first_name: S.
full_name: Schulz, S.
last_name: Schulz
- first_name: Julia
full_name: Linnemann, Julia
id: '116779'
last_name: Linnemann
orcid: 0000-0001-6883-5424
- first_name: A.
full_name: Bergmann, A.
last_name: Bergmann
- first_name: B.
full_name: Roldan Cuenya, B.
last_name: Roldan Cuenya
- first_name: G.
full_name: Bacher, G.
last_name: Bacher
citation:
ama: Kampermann L, Klein J, Wagner T, et al. Operando Analysis of the Pre-OER Activation
of Metal-Doped Co3O4 Nanoparticle Catalysts. ACS Catalysis.
2025;15(21):18391-18403. doi:10.1021/acscatal.5c03900
apa: Kampermann, L., Klein, J., Wagner, T., Kotova, A., Placke-Yan, C., Yasar, A.,
Jacobse, L., Lasagna, S., Leppin, C., Schulz, S., Linnemann, J., Bergmann, A.,
Roldan Cuenya, B., & Bacher, G. (2025). Operando Analysis of the Pre-OER Activation
of Metal-Doped Co3O4 Nanoparticle Catalysts. ACS Catalysis,
15(21), 18391–18403. https://doi.org/10.1021/acscatal.5c03900
bibtex: '@article{Kampermann_Klein_Wagner_Kotova_Placke-Yan_Yasar_Jacobse_Lasagna_Leppin_Schulz_et
al._2025, title={Operando Analysis of the Pre-OER Activation of Metal-Doped Co3O4
Nanoparticle Catalysts}, volume={15}, DOI={10.1021/acscatal.5c03900},
number={21}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Kampermann, L. and Klein, J. and Wagner, T. and Kotova, A. and Placke-Yan,
C. and Yasar, A. and Jacobse, L. and Lasagna, S. and Leppin, Christian and Schulz,
S. and et al.}, year={2025}, pages={18391–18403} }'
chicago: 'Kampermann, L., J. Klein, T. Wagner, A. Kotova, C. Placke-Yan, A. Yasar,
L. Jacobse, et al. “Operando Analysis of the Pre-OER Activation of Metal-Doped
Co3O4 Nanoparticle Catalysts.” ACS Catalysis 15,
no. 21 (2025): 18391–403. https://doi.org/10.1021/acscatal.5c03900.'
ieee: 'L. Kampermann et al., “Operando Analysis of the Pre-OER Activation
of Metal-Doped Co3O4 Nanoparticle Catalysts,” ACS Catalysis,
vol. 15, no. 21, pp. 18391–18403, 2025, doi: 10.1021/acscatal.5c03900.'
mla: Kampermann, L., et al. “Operando Analysis of the Pre-OER Activation of Metal-Doped
Co3O4 Nanoparticle Catalysts.” ACS Catalysis, vol.
15, no. 21, American Chemical Society (ACS), 2025, pp. 18391–403, doi:10.1021/acscatal.5c03900.
short: L. Kampermann, J. Klein, T. Wagner, A. Kotova, C. Placke-Yan, A. Yasar, L.
Jacobse, S. Lasagna, C. Leppin, S. Schulz, J. Linnemann, A. Bergmann, B. Roldan
Cuenya, G. Bacher, ACS Catalysis 15 (2025) 18391–18403.
date_created: 2025-10-24T07:49:21Z
date_updated: 2025-12-07T17:15:53Z
department:
- _id: '985'
doi: 10.1021/acscatal.5c03900
intvolume: ' 15'
issue: '21'
keyword:
- electrocatalysis
- oxygen evolution reaction
- cobalt spinel
- operando characterization
- spectroelectrochemistry
language:
- iso: eng
page: 18391-18403
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Operando Analysis of the Pre-OER Activation of Metal-Doped Co3O4
Nanoparticle Catalysts
type: journal_article
user_id: '116779'
volume: 15
year: '2025'
...
---
_id: '46547'
author:
- first_name: Andrea
full_name: Rogolino, Andrea
last_name: Rogolino
- first_name: José B. G.
full_name: Filho, José B. G.
last_name: Filho
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: José D.
full_name: Ardisson, José D.
last_name: Ardisson
- first_name: Marcos A. R.
full_name: da Silva, Marcos A. R.
last_name: da Silva
- first_name: Gabriel Ali
full_name: Atta Diab, Gabriel Ali
last_name: Atta Diab
- first_name: Ingrid Fernandes
full_name: Silva, Ingrid Fernandes
last_name: Silva
- first_name: Carlos André Ferreira
full_name: Moraes, Carlos André Ferreira
last_name: Moraes
- first_name: Moacir Rossi
full_name: Forim, Moacir Rossi
last_name: Forim
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Markus
full_name: Antonietti, Markus
last_name: Antonietti
- first_name: Ivo F.
full_name: Teixeira, Ivo F.
last_name: Teixeira
citation:
ama: Rogolino A, Filho JBG, Fritsch L, et al. Direct Synthesis of Acetone by Aerobic
Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions.
ACS Catalysis. 2023;13(13):8662-8669. doi:10.1021/acscatal.3c02092
apa: Rogolino, A., Filho, J. B. G., Fritsch, L., Ardisson, J. D., da Silva, M. A.
R., Atta Diab, G. A., Silva, I. F., Moraes, C. A. F., Forim, M. R., Bauer, M.,
Kühne, T. D., Antonietti, M., & Teixeira, I. F. (2023). Direct Synthesis of
Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride
under Mild Conditions. ACS Catalysis, 13(13), 8662–8669. https://doi.org/10.1021/acscatal.3c02092
bibtex: '@article{Rogolino_Filho_Fritsch_Ardisson_da Silva_Atta Diab_Silva_Moraes_Forim_Bauer_et
al._2023, title={Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted
by Photoactive Iron(III) Chloride under Mild Conditions}, volume={13}, DOI={10.1021/acscatal.3c02092},
number={13}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Rogolino, Andrea and Filho, José B. G. and Fritsch, Lorena and Ardisson,
José D. and da Silva, Marcos A. R. and Atta Diab, Gabriel Ali and Silva, Ingrid
Fernandes and Moraes, Carlos André Ferreira and Forim, Moacir Rossi and Bauer,
Matthias and et al.}, year={2023}, pages={8662–8669} }'
chicago: 'Rogolino, Andrea, José B. G. Filho, Lorena Fritsch, José D. Ardisson,
Marcos A. R. da Silva, Gabriel Ali Atta Diab, Ingrid Fernandes Silva, et al. “Direct
Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III)
Chloride under Mild Conditions.” ACS Catalysis 13, no. 13 (2023): 8662–69.
https://doi.org/10.1021/acscatal.3c02092.'
ieee: 'A. Rogolino et al., “Direct Synthesis of Acetone by Aerobic Propane
Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions,” ACS
Catalysis, vol. 13, no. 13, pp. 8662–8669, 2023, doi: 10.1021/acscatal.3c02092.'
mla: Rogolino, Andrea, et al. “Direct Synthesis of Acetone by Aerobic Propane Oxidation
Promoted by Photoactive Iron(III) Chloride under Mild Conditions.” ACS Catalysis,
vol. 13, no. 13, American Chemical Society (ACS), 2023, pp. 8662–69, doi:10.1021/acscatal.3c02092.
short: A. Rogolino, J.B.G. Filho, L. Fritsch, J.D. Ardisson, M.A.R. da Silva, G.A.
Atta Diab, I.F. Silva, C.A.F. Moraes, M.R. Forim, M. Bauer, T.D. Kühne, M. Antonietti,
I.F. Teixeira, ACS Catalysis 13 (2023) 8662–8669.
date_created: 2023-08-16T14:44:11Z
date_updated: 2024-03-07T09:34:41Z
doi: 10.1021/acscatal.3c02092
intvolume: ' 13'
issue: '13'
keyword:
- Catalysis
- General Chemistry
- pc2-ressources
- Computing Resources Provided by the Paderborn Center for Parallel Computing
language:
- iso: eng
page: 8662-8669
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive
Iron(III) Chloride under Mild Conditions
type: journal_article
user_id: '44418'
volume: 13
year: '2023'
...
---
_id: '41001'
abstract:
- lang: eng
text: For entropic reasons, the synthesis of macrocycles via olefin ring-closing
metathesis (RCM) is impeded by competing acyclic diene metathesis (ADMET) oligomerization.
With cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes
confined in tailored ordered mesoporous silica, RCM can be run with macrocyclization
selectivities up to 98% and high substrate concentrations up to 0.1 M. Molecular
dynamics simulations show that the high conversions are a direct result of the
proximity between the surface-bound catalyst, proven by extended X-ray absorption
spectroscopy, and the surface-located substrates. Back-diffusion of the macrocycles
decreases with decreasing pore diameter of the silica and is responsible for the
high macrocyclization efficiency. Also, Z-selectivity increases with decreasing
pore diameter and increasing Tolman electronic parameter of the NHC. Running reactions
at different concentrations allows for identifying the optimum substrate concentration
for each material and substrate combination.
article_type: original
author:
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Hamzeh
full_name: Kraus, Hamzeh
last_name: Kraus
- first_name: Mathis J.
full_name: Benedikter, Mathis J.
last_name: Benedikter
- first_name: Dongren
full_name: Wang, Dongren
last_name: Wang
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Kilian
full_name: Weißer, Kilian
last_name: Weißer
- first_name: Helena
full_name: Solodenko, Helena
last_name: Solodenko
- first_name: Guido
full_name: Schmitz, Guido
last_name: Schmitz
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Niels
full_name: Hansen, Niels
last_name: Hansen
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient
Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene
N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578.
doi:10.1021/acscatal.1c03057
apa: Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski,
M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser,
M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with
Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.
ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057
bibtex: '@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et
al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions
with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene
Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057},
number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren
and Bruckner, Johanna R. and Nowakowski, Michał and Weißer, Kilian and Solodenko,
Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578}
}'
chicago: 'Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna
R. Bruckner, Michał Nowakowski, Kilian Weißer, et al. “Confinement Effects for
Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11,
no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.'
ieee: 'F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021,
doi: 10.1021/acscatal.1c03057.'
mla: Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society
(ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057.
short: F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski,
K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS
Catalysis 11 (2021) 11570–11578.
date_created: 2023-01-30T16:49:07Z
date_updated: 2024-05-07T11:44:19Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acscatal.1c03057
intvolume: ' 11'
issue: '18'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 11570-11578
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Confinement Effects for Efficient Macrocyclization Reactions with Supported
Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
type: journal_article
user_id: '48467'
volume: 11
year: '2021'
...
---
_id: '41323'
author:
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Hamzeh
full_name: Kraus, Hamzeh
last_name: Kraus
- first_name: Mathis J.
full_name: Benedikter, Mathis J.
last_name: Benedikter
- first_name: Dongren
full_name: Wang, Dongren
last_name: Wang
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Kilian
full_name: Weißer, Kilian
last_name: Weißer
- first_name: Helena
full_name: Solodenko, Helena
last_name: Solodenko
- first_name: Guido
full_name: Schmitz, Guido
last_name: Schmitz
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Niels
full_name: Hansen, Niels
last_name: Hansen
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient
Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene
N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578.
doi:10.1021/acscatal.1c03057
apa: Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski,
M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser,
M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with
Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.
ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057
bibtex: '@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et
al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions
with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene
Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057},
number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren
and Bruckner, Johanna R. and Nowakowski, Michal and Weißer, Kilian and Solodenko,
Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578}
}'
chicago: 'Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna
R. Bruckner, Michal Nowakowski, Kilian Weißer, et al. “Confinement Effects for
Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11,
no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.'
ieee: 'F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021,
doi: 10.1021/acscatal.1c03057.'
mla: Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society
(ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057.
short: F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski,
K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS
Catalysis 11 (2021) 11570–11578.
date_created: 2023-01-31T22:50:23Z
date_updated: 2023-02-01T08:50:59Z
doi: 10.1021/acscatal.1c03057
intvolume: ' 11'
issue: '18'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 11570-11578
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Confinement Effects for Efficient Macrocyclization Reactions with Supported
Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
type: journal_article
user_id: '78878'
volume: 11
year: '2021'
...
---
_id: '62803'
abstract:
- lang: eng
text: The aim to produce highly active, selective, and long-lived electrocatalysts
by design drives major research efforts toward gaining fundamental understanding
of the relationship between material properties and their catalytic performance.
Surface characterization tools enable to assess atomic scale information on the
complexity of electrocatalyst materials. Advancing electrochemical methodologies
to adequately characterize such systems was less of a research focus point. In
this Review, we shed light on the ability to gain fundamental insights into electrocatalysis
from a complementary perspective and establish corresponding design strategies.
These may rely on adopting the perceptions and models of other subareas of electrochemistry,
such as corrosion, battery research, or electrodeposition. Concepts on how to
account for and improve mass transport, manage gas bubble release, or exploit
magnetic fields are highlighted in this respect. Particular attention is paid
to deriving design strategies for nanoelectrocatalysts, which is often impeded,
as structural and physical material properties are buried in electrochemical data
of whole electrodes or even devices. Thus, a second major approach focuses on
overcoming this difference in the considered level of complexity by methods of
single-entity electrochemistry. The gained understanding of intrinsic catalyst
performance may allow to rationally advance design concepts with increased complexity,
such as three-dimensional electrode architectures. Many materials undergo structural
changes upon formation of the working catalyst. Accordingly, developing “precatalysts”
with low hindrance of the electrochemical transformation to the active catalyst
is suggested as a final design strategy.
article_type: review
author:
- first_name: Julia
full_name: Linnemann, Julia
id: '116779'
last_name: Linnemann
orcid: 0000-0001-6883-5424
- first_name: Kannasoot
full_name: Kanokkanchana, Kannasoot
last_name: Kanokkanchana
- first_name: Kristina
full_name: Tschulik, Kristina
last_name: Tschulik
citation:
ama: Linnemann J, Kanokkanchana K, Tschulik K. Design Strategies for Electrocatalysts
from an Electrochemist’s Perspective. ACS Catalysis. 2021;11(9):5318-5346.
doi:10.1021/acscatal.0c04118
apa: Linnemann, J., Kanokkanchana, K., & Tschulik, K. (2021). Design Strategies
for Electrocatalysts from an Electrochemist’s Perspective. ACS Catalysis,
11(9), 5318–5346. https://doi.org/10.1021/acscatal.0c04118
bibtex: '@article{Linnemann_Kanokkanchana_Tschulik_2021, title={Design Strategies
for Electrocatalysts from an Electrochemist’s Perspective}, volume={11}, DOI={10.1021/acscatal.0c04118},
number={9}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Linnemann, Julia and Kanokkanchana, Kannasoot and Tschulik, Kristina},
year={2021}, pages={5318–5346} }'
chicago: 'Linnemann, Julia, Kannasoot Kanokkanchana, and Kristina Tschulik. “Design
Strategies for Electrocatalysts from an Electrochemist’s Perspective.” ACS
Catalysis 11, no. 9 (2021): 5318–46. https://doi.org/10.1021/acscatal.0c04118.'
ieee: 'J. Linnemann, K. Kanokkanchana, and K. Tschulik, “Design Strategies for Electrocatalysts
from an Electrochemist’s Perspective,” ACS Catalysis, vol. 11, no. 9, pp.
5318–5346, 2021, doi: 10.1021/acscatal.0c04118.'
mla: Linnemann, Julia, et al. “Design Strategies for Electrocatalysts from an Electrochemist’s
Perspective.” ACS Catalysis, vol. 11, no. 9, American Chemical Society
(ACS), 2021, pp. 5318–46, doi:10.1021/acscatal.0c04118.
short: J. Linnemann, K. Kanokkanchana, K. Tschulik, ACS Catalysis 11 (2021) 5318–5346.
date_created: 2025-12-03T15:31:28Z
date_updated: 2025-12-03T16:32:18Z
department:
- _id: '985'
doi: 10.1021/acscatal.0c04118
extern: '1'
intvolume: ' 11'
issue: '9'
keyword:
- electrocatalysis
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://pubs.acs.org/doi/full/10.1021/acscatal.0c04118
oa: '1'
page: 5318-5346
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Design Strategies for Electrocatalysts from an Electrochemist’s Perspective
type: journal_article
user_id: '116779'
volume: 11
year: '2021'
...
---
_id: '41015'
author:
- first_name: Mathis
full_name: Benedikter, Mathis
last_name: Benedikter
- first_name: Janis
full_name: Musso, Janis
last_name: Musso
- first_name: Manoj K.
full_name: Kesharwani, Manoj K.
last_name: Kesharwani
- first_name: K. Leonard
full_name: Sterz, K. Leonard
last_name: Sterz
- first_name: Iris
full_name: Elser, Iris
last_name: Elser
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Felix
full_name: Fischer, Felix
last_name: Fischer
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Mario
full_name: Winkler, Mario
last_name: Winkler
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis.
2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978'
apa: 'Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler,
F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren,
J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution
in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes:
A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis,
10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978'
bibtex: '@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et
al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach},
volume={10}, DOI={10.1021/acscatal.0c03978},
number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz,
K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker,
Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823}
}'
chicago: 'Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz,
Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis
10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.'
ieee: 'M. Benedikter et al., “Charge Distribution in Cationic Molybdenum
Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS,
XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no.
24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.'
mla: 'Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES,
DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24,
American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.'
short: M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler,
F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M.
Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.
date_created: 2023-01-30T17:12:11Z
date_updated: 2024-05-07T11:42:56Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acscatal.0c03978
intvolume: ' 10'
issue: '24'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 14810-14823
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach'
type: journal_article
user_id: '48467'
volume: 10
year: '2020'
...
---
_id: '41327'
author:
- first_name: Mathis
full_name: Benedikter, Mathis
last_name: Benedikter
- first_name: Janis
full_name: Musso, Janis
last_name: Musso
- first_name: Manoj K.
full_name: Kesharwani, Manoj K.
last_name: Kesharwani
- first_name: K. Leonard
full_name: Sterz, K. Leonard
last_name: Sterz
- first_name: Iris
full_name: Elser, Iris
last_name: Elser
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Felix
full_name: Fischer, Felix
last_name: Fischer
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Mario
full_name: Winkler, Mario
last_name: Winkler
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis.
2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978'
apa: 'Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler,
F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren,
J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution
in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes:
A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis,
10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978'
bibtex: '@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et
al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach},
volume={10}, DOI={10.1021/acscatal.0c03978},
number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz,
K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker,
Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823}
}'
chicago: 'Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz,
Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis
10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.'
ieee: 'M. Benedikter et al., “Charge Distribution in Cationic Molybdenum
Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS,
XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no.
24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.'
mla: 'Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES,
DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24,
American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.'
short: M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler,
F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M.
Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.
date_created: 2023-01-31T22:52:07Z
date_updated: 2023-02-01T08:50:47Z
doi: 10.1021/acscatal.0c03978
intvolume: ' 10'
issue: '24'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 14810-14823
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach'
type: journal_article
user_id: '78878'
volume: 10
year: '2020'
...
---
_id: '37951'
author:
- first_name: Xin
full_name: Liu, Xin
last_name: Liu
- first_name: Lars
full_name: Longwitz, Lars
last_name: Longwitz
- first_name: Brian
full_name: Spiegelberg, Brian
last_name: Spiegelberg
- first_name: Jan
full_name: Tönjes, Jan
last_name: Tönjes
- first_name: Torsten
full_name: Beweries, Torsten
last_name: Beweries
- first_name: Thomas
full_name: Werner, Thomas
id: '89271'
last_name: Werner
orcid: 0000-0001-9025-3244
citation:
ama: Liu X, Longwitz L, Spiegelberg B, Tönjes J, Beweries T, Werner T. Erbium-Catalyzed
Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence
for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions.
ACS Catalysis. 2020;10(22):13659-13667. doi:10.1021/acscatal.0c03294
apa: Liu, X., Longwitz, L., Spiegelberg, B., Tönjes, J., Beweries, T., & Werner,
T. (2020). Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer
Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides
under Mild Conditions. ACS Catalysis, 10(22), 13659–13667. https://doi.org/10.1021/acscatal.0c03294
bibtex: '@article{Liu_Longwitz_Spiegelberg_Tönjes_Beweries_Werner_2020, title={Erbium-Catalyzed
Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence
for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions},
volume={10}, DOI={10.1021/acscatal.0c03294},
number={22}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Liu, Xin and Longwitz, Lars and Spiegelberg, Brian and Tönjes, Jan and
Beweries, Torsten and Werner, Thomas}, year={2020}, pages={13659–13667} }'
chicago: 'Liu, Xin, Lars Longwitz, Brian Spiegelberg, Jan Tönjes, Torsten Beweries,
and Thomas Werner. “Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed
Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols
from Epoxides under Mild Conditions.” ACS Catalysis 10, no. 22 (2020):
13659–67. https://doi.org/10.1021/acscatal.0c03294.'
ieee: 'X. Liu, L. Longwitz, B. Spiegelberg, J. Tönjes, T. Beweries, and T. Werner,
“Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation
Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild
Conditions,” ACS Catalysis, vol. 10, no. 22, pp. 13659–13667, 2020, doi:
10.1021/acscatal.0c03294.'
mla: Liu, Xin, et al. “Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed
Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols
from Epoxides under Mild Conditions.” ACS Catalysis, vol. 10, no. 22, American
Chemical Society (ACS), 2020, pp. 13659–67, doi:10.1021/acscatal.0c03294.
short: X. Liu, L. Longwitz, B. Spiegelberg, J. Tönjes, T. Beweries, T. Werner, ACS
Catalysis 10 (2020) 13659–13667.
date_created: 2023-01-22T20:35:25Z
date_updated: 2025-11-10T08:50:10Z
department:
- _id: '35'
- _id: '2'
- _id: '657'
doi: 10.1021/acscatal.0c03294
extern: '1'
intvolume: ' 10'
issue: '22'
keyword:
- T3
- CSSD
language:
- iso: eng
page: 13659-13667
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation
Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild
Conditions
type: journal_article
user_id: '89271'
volume: 10
year: '2020'
...
---
_id: '37958'
author:
- first_name: Lars
full_name: Longwitz, Lars
last_name: Longwitz
- first_name: Anke
full_name: Spannenberg, Anke
last_name: Spannenberg
- first_name: Thomas
full_name: Werner, Thomas
id: '89271'
last_name: Werner
orcid: 0000-0001-9025-3244
citation:
ama: Longwitz L, Spannenberg A, Werner T. Phosphetane Oxides as Redox Cycling Catalysts
in the Catalytic Wittig Reaction at Room Temperature. ACS Catalysis. 2019;9(10):9237-9244.
doi:10.1021/acscatal.9b02456
apa: Longwitz, L., Spannenberg, A., & Werner, T. (2019). Phosphetane Oxides
as Redox Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature.
ACS Catalysis, 9(10), 9237–9244. https://doi.org/10.1021/acscatal.9b02456
bibtex: '@article{Longwitz_Spannenberg_Werner_2019, title={Phosphetane Oxides as
Redox Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature},
volume={9}, DOI={10.1021/acscatal.9b02456},
number={10}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Longwitz, Lars and Spannenberg, Anke and Werner, Thomas}, year={2019},
pages={9237–9244} }'
chicago: 'Longwitz, Lars, Anke Spannenberg, and Thomas Werner. “Phosphetane Oxides
as Redox Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature.”
ACS Catalysis 9, no. 10 (2019): 9237–44. https://doi.org/10.1021/acscatal.9b02456.'
ieee: 'L. Longwitz, A. Spannenberg, and T. Werner, “Phosphetane Oxides as Redox
Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature,” ACS
Catalysis, vol. 9, no. 10, pp. 9237–9244, 2019, doi: 10.1021/acscatal.9b02456.'
mla: Longwitz, Lars, et al. “Phosphetane Oxides as Redox Cycling Catalysts in the
Catalytic Wittig Reaction at Room Temperature.” ACS Catalysis, vol. 9,
no. 10, American Chemical Society (ACS), 2019, pp. 9237–44, doi:10.1021/acscatal.9b02456.
short: L. Longwitz, A. Spannenberg, T. Werner, ACS Catalysis 9 (2019) 9237–9244.
date_created: 2023-01-22T20:41:56Z
date_updated: 2025-11-10T08:54:03Z
department:
- _id: '35'
- _id: '2'
- _id: '657'
doi: 10.1021/acscatal.9b02456
extern: '1'
intvolume: ' 9'
issue: '10'
keyword:
- T2
- CSSD
language:
- iso: eng
page: 9237-9244
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Phosphetane Oxides as Redox Cycling Catalysts in the Catalytic Wittig Reaction
at Room Temperature
type: journal_article
user_id: '89271'
volume: 9
year: '2019'
...
---
_id: '37960'
author:
- first_name: Bernhard M.
full_name: Stadler, Bernhard M.
last_name: Stadler
- first_name: Christoph
full_name: Wulf, Christoph
last_name: Wulf
- first_name: Thomas
full_name: Werner, Thomas
id: '89271'
last_name: Werner
orcid: 0000-0001-9025-3244
- first_name: Sergey
full_name: Tin, Sergey
last_name: Tin
- first_name: Johannes G.
full_name: de Vries, Johannes G.
last_name: de Vries
citation:
ama: Stadler BM, Wulf C, Werner T, Tin S, de Vries JG. Catalytic Approaches to Monomers
for Polymers Based on Renewables. ACS Catalysis. 2019;9(9):8012-8067. doi:10.1021/acscatal.9b01665
apa: Stadler, B. M., Wulf, C., Werner, T., Tin, S., & de Vries, J. G. (2019).
Catalytic Approaches to Monomers for Polymers Based on Renewables. ACS Catalysis,
9(9), 8012–8067. https://doi.org/10.1021/acscatal.9b01665
bibtex: '@article{Stadler_Wulf_Werner_Tin_de Vries_2019, title={Catalytic Approaches
to Monomers for Polymers Based on Renewables}, volume={9}, DOI={10.1021/acscatal.9b01665},
number={9}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Stadler, Bernhard M. and Wulf, Christoph and Werner, Thomas and Tin, Sergey
and de Vries, Johannes G.}, year={2019}, pages={8012–8067} }'
chicago: 'Stadler, Bernhard M., Christoph Wulf, Thomas Werner, Sergey Tin, and Johannes
G. de Vries. “Catalytic Approaches to Monomers for Polymers Based on Renewables.”
ACS Catalysis 9, no. 9 (2019): 8012–67. https://doi.org/10.1021/acscatal.9b01665.'
ieee: 'B. M. Stadler, C. Wulf, T. Werner, S. Tin, and J. G. de Vries, “Catalytic
Approaches to Monomers for Polymers Based on Renewables,” ACS Catalysis,
vol. 9, no. 9, pp. 8012–8067, 2019, doi: 10.1021/acscatal.9b01665.'
mla: Stadler, Bernhard M., et al. “Catalytic Approaches to Monomers for Polymers
Based on Renewables.” ACS Catalysis, vol. 9, no. 9, American Chemical Society
(ACS), 2019, pp. 8012–67, doi:10.1021/acscatal.9b01665.
short: B.M. Stadler, C. Wulf, T. Werner, S. Tin, J.G. de Vries, ACS Catalysis 9
(2019) 8012–8067.
date_created: 2023-01-22T20:42:48Z
date_updated: 2025-11-10T09:01:51Z
department:
- _id: '35'
- _id: '2'
- _id: '657'
doi: 10.1021/acscatal.9b01665
intvolume: ' 9'
issue: '9'
keyword:
- T4
- CSSD
language:
- iso: eng
page: 8012-8067
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Catalytic Approaches to Monomers for Polymers Based on Renewables
type: journal_article
user_id: '89271'
volume: 9
year: '2019'
...
---
_id: '62105'
author:
- first_name: Lars
full_name: Longwitz, Lars
last_name: Longwitz
- first_name: Johannes
full_name: Steinbauer, Johannes
last_name: Steinbauer
- first_name: Anke
full_name: Spannenberg, Anke
last_name: Spannenberg
- first_name: Thomas
full_name: Werner, Thomas
id: '89271'
last_name: Werner
orcid: 0000-0001-9025-3244
citation:
ama: Longwitz L, Steinbauer J, Spannenberg A, Werner T. Calcium-Based Catalytic
System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions.
ACS Catalysis. 2018;8(1):665-672. doi:10.1021/acscatal.7b03367
apa: Longwitz, L., Steinbauer, J., Spannenberg, A., & Werner, T. (2018). Calcium-Based
Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild
Conditions. ACS Catalysis, 8(1), 665–672. https://doi.org/10.1021/acscatal.7b03367
bibtex: '@article{Longwitz_Steinbauer_Spannenberg_Werner_2018, title={Calcium-Based
Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild
Conditions}, volume={8}, DOI={10.1021/acscatal.7b03367},
number={1}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Longwitz, Lars and Steinbauer, Johannes and Spannenberg, Anke and Werner,
Thomas}, year={2018}, pages={665–672} }'
chicago: 'Longwitz, Lars, Johannes Steinbauer, Anke Spannenberg, and Thomas Werner.
“Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates
under Mild Conditions.” ACS Catalysis 8, no. 1 (2018): 665–72. https://doi.org/10.1021/acscatal.7b03367.'
ieee: 'L. Longwitz, J. Steinbauer, A. Spannenberg, and T. Werner, “Calcium-Based
Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild
Conditions,” ACS Catalysis, vol. 8, no. 1, pp. 665–672, 2018, doi: 10.1021/acscatal.7b03367.'
mla: Longwitz, Lars, et al. “Calcium-Based Catalytic System for the Synthesis of
Bio-Derived Cyclic Carbonates under Mild Conditions.” ACS Catalysis, vol.
8, no. 1, American Chemical Society (ACS), 2018, pp. 665–72, doi:10.1021/acscatal.7b03367.
short: L. Longwitz, J. Steinbauer, A. Spannenberg, T. Werner, ACS Catalysis 8 (2018)
665–672.
date_created: 2025-11-05T15:47:56Z
date_updated: 2025-11-10T09:05:26Z
department:
- _id: '35'
- _id: '2'
doi: 10.1021/acscatal.7b03367
intvolume: ' 8'
issue: '1'
keyword:
- T1
- T3
- T4
- CSSD
language:
- iso: eng
page: 665-672
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates
under Mild Conditions
type: journal_article
user_id: '89271'
volume: 8
year: '2018'
...
---
_id: '37970'
author:
- first_name: Lars
full_name: Longwitz, Lars
last_name: Longwitz
- first_name: Johannes
full_name: Steinbauer, Johannes
last_name: Steinbauer
- first_name: Anke
full_name: Spannenberg, Anke
last_name: Spannenberg
- first_name: Thomas
full_name: Werner, Thomas
id: '89271'
last_name: Werner
orcid: https://orcid.org/0000-0001-9025-3244
citation:
ama: Longwitz L, Steinbauer J, Spannenberg A, Werner T. Calcium-Based Catalytic
System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild Conditions.
ACS Catalysis. 2017;8(1):665-672. doi:10.1021/acscatal.7b03367
apa: Longwitz, L., Steinbauer, J., Spannenberg, A., & Werner, T. (2017). Calcium-Based
Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild
Conditions. ACS Catalysis, 8(1), 665–672. https://doi.org/10.1021/acscatal.7b03367
bibtex: '@article{Longwitz_Steinbauer_Spannenberg_Werner_2017, title={Calcium-Based
Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild
Conditions}, volume={8}, DOI={10.1021/acscatal.7b03367},
number={1}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Longwitz, Lars and Steinbauer, Johannes and Spannenberg, Anke and Werner,
Thomas}, year={2017}, pages={665–672} }'
chicago: 'Longwitz, Lars, Johannes Steinbauer, Anke Spannenberg, and Thomas Werner.
“Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates
under Mild Conditions.” ACS Catalysis 8, no. 1 (2017): 665–72. https://doi.org/10.1021/acscatal.7b03367.'
ieee: 'L. Longwitz, J. Steinbauer, A. Spannenberg, and T. Werner, “Calcium-Based
Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates under Mild
Conditions,” ACS Catalysis, vol. 8, no. 1, pp. 665–672, 2017, doi: 10.1021/acscatal.7b03367.'
mla: Longwitz, Lars, et al. “Calcium-Based Catalytic System for the Synthesis of
Bio-Derived Cyclic Carbonates under Mild Conditions.” ACS Catalysis, vol.
8, no. 1, American Chemical Society (ACS), 2017, pp. 665–72, doi:10.1021/acscatal.7b03367.
short: L. Longwitz, J. Steinbauer, A. Spannenberg, T. Werner, ACS Catalysis 8 (2017)
665–672.
date_created: 2023-01-22T20:47:19Z
date_updated: 2025-11-06T08:38:07Z
department:
- _id: '35'
- _id: '2'
- _id: '657'
doi: 10.1021/acscatal.7b03367
extern: '1'
intvolume: ' 8'
issue: '1'
keyword:
- T1
- T3
- T4
language:
- iso: eng
page: 665-672
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Calcium-Based Catalytic System for the Synthesis of Bio-Derived Cyclic Carbonates
under Mild Conditions
type: journal_article
user_id: '89271'
volume: 8
year: '2017'
...
---
_id: '41059'
author:
- first_name: G. Wilma
full_name: Busser, G. Wilma
last_name: Busser
- first_name: Bastian
full_name: Mei, Bastian
last_name: Mei
- first_name: Philipp
full_name: Weide, Philipp
last_name: Weide
- first_name: Peter C. K.
full_name: Vesborg, Peter C. K.
last_name: Vesborg
- first_name: Kai
full_name: Stührenberg, Kai
last_name: Stührenberg
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Xing
full_name: Huang, Xing
last_name: Huang
- first_name: Marc-Georg
full_name: Willinger, Marc-Georg
last_name: Willinger
- first_name: Ib
full_name: Chorkendorff, Ib
last_name: Chorkendorff
- first_name: Robert
full_name: Schlögl, Robert
last_name: Schlögl
- first_name: Martin
full_name: Muhler, Martin
last_name: Muhler
citation:
ama: 'Busser GW, Mei B, Weide P, et al. Cocatalyst Designing: A Regenerable Molybdenum-Containing
Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting. ACS
Catalysis. 2015;5(9):5530-5539. doi:10.1021/acscatal.5b01428'
apa: 'Busser, G. W., Mei, B., Weide, P., Vesborg, P. C. K., Stührenberg, K., Bauer,
M., Huang, X., Willinger, M.-G., Chorkendorff, I., Schlögl, R., & Muhler,
M. (2015). Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst
System for Efficient Photocatalytic Water Splitting. ACS Catalysis, 5(9),
5530–5539. https://doi.org/10.1021/acscatal.5b01428'
bibtex: '@article{Busser_Mei_Weide_Vesborg_Stührenberg_Bauer_Huang_Willinger_Chorkendorff_Schlögl_et
al._2015, title={Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary
Cocatalyst System for Efficient Photocatalytic Water Splitting}, volume={5}, DOI={10.1021/acscatal.5b01428},
number={9}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Busser, G. Wilma and Mei, Bastian and Weide, Philipp and Vesborg, Peter
C. K. and Stührenberg, Kai and Bauer, Matthias and Huang, Xing and Willinger,
Marc-Georg and Chorkendorff, Ib and Schlögl, Robert and et al.}, year={2015},
pages={5530–5539} }'
chicago: 'Busser, G. Wilma, Bastian Mei, Philipp Weide, Peter C. K. Vesborg, Kai
Stührenberg, Matthias Bauer, Xing Huang, et al. “Cocatalyst Designing: A Regenerable
Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water
Splitting.” ACS Catalysis 5, no. 9 (2015): 5530–39. https://doi.org/10.1021/acscatal.5b01428.'
ieee: 'G. W. Busser et al., “Cocatalyst Designing: A Regenerable Molybdenum-Containing
Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting,” ACS
Catalysis, vol. 5, no. 9, pp. 5530–5539, 2015, doi: 10.1021/acscatal.5b01428.'
mla: 'Busser, G. Wilma, et al. “Cocatalyst Designing: A Regenerable Molybdenum-Containing
Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting.” ACS
Catalysis, vol. 5, no. 9, American Chemical Society (ACS), 2015, pp. 5530–39,
doi:10.1021/acscatal.5b01428.'
short: G.W. Busser, B. Mei, P. Weide, P.C.K. Vesborg, K. Stührenberg, M. Bauer,
X. Huang, M.-G. Willinger, I. Chorkendorff, R. Schlögl, M. Muhler, ACS Catalysis
5 (2015) 5530–5539.
date_created: 2023-01-30T20:38:01Z
date_updated: 2023-01-31T08:36:11Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acscatal.5b01428
intvolume: ' 5'
issue: '9'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 5530-5539
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst
System for Efficient Photocatalytic Water Splitting'
type: journal_article
user_id: '27611'
volume: 5
year: '2015'
...
---
_id: '41247'
author:
- first_name: Jabor
full_name: Rabeah, Jabor
last_name: Rabeah
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Wolfgang
full_name: Baumann, Wolfgang
last_name: Baumann
- first_name: Ann E. C.
full_name: McConnell, Ann E. C.
last_name: McConnell
- first_name: William F.
full_name: Gabrielli, William F.
last_name: Gabrielli
- first_name: Paul B.
full_name: Webb, Paul B.
last_name: Webb
- first_name: Detlef
full_name: Selent, Detlef
last_name: Selent
- first_name: Angelika
full_name: Brückner, Angelika
last_name: Brückner
citation:
ama: Rabeah J, Bauer M, Baumann W, et al. Formation, Operation and Deactivation
of Cr Catalysts in Ethylene Tetramerization Directly Assessed by Operando EPR
and XAS. ACS Catalysis. 2012;3(1):95-102. doi:10.1021/cs300686m
apa: Rabeah, J., Bauer, M., Baumann, W., McConnell, A. E. C., Gabrielli, W. F.,
Webb, P. B., Selent, D., & Brückner, A. (2012). Formation, Operation and Deactivation
of Cr Catalysts in Ethylene Tetramerization Directly Assessed by Operando EPR
and XAS. ACS Catalysis, 3(1), 95–102. https://doi.org/10.1021/cs300686m
bibtex: '@article{Rabeah_Bauer_Baumann_McConnell_Gabrielli_Webb_Selent_Brückner_2012,
title={Formation, Operation and Deactivation of Cr Catalysts in Ethylene Tetramerization
Directly Assessed by Operando EPR and XAS}, volume={3}, DOI={10.1021/cs300686m},
number={1}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Rabeah, Jabor and Bauer, Matthias and Baumann, Wolfgang and McConnell,
Ann E. C. and Gabrielli, William F. and Webb, Paul B. and Selent, Detlef and Brückner,
Angelika}, year={2012}, pages={95–102} }'
chicago: 'Rabeah, Jabor, Matthias Bauer, Wolfgang Baumann, Ann E. C. McConnell,
William F. Gabrielli, Paul B. Webb, Detlef Selent, and Angelika Brückner. “Formation,
Operation and Deactivation of Cr Catalysts in Ethylene Tetramerization Directly
Assessed by Operando EPR and XAS.” ACS Catalysis 3, no. 1 (2012): 95–102.
https://doi.org/10.1021/cs300686m.'
ieee: 'J. Rabeah et al., “Formation, Operation and Deactivation of Cr Catalysts
in Ethylene Tetramerization Directly Assessed by Operando EPR and XAS,” ACS
Catalysis, vol. 3, no. 1, pp. 95–102, 2012, doi: 10.1021/cs300686m.'
mla: Rabeah, Jabor, et al. “Formation, Operation and Deactivation of Cr Catalysts
in Ethylene Tetramerization Directly Assessed by Operando EPR and XAS.” ACS
Catalysis, vol. 3, no. 1, American Chemical Society (ACS), 2012, pp. 95–102,
doi:10.1021/cs300686m.
short: J. Rabeah, M. Bauer, W. Baumann, A.E.C. McConnell, W.F. Gabrielli, P.B. Webb,
D. Selent, A. Brückner, ACS Catalysis 3 (2012) 95–102.
date_created: 2023-01-31T14:57:15Z
date_updated: 2023-01-31T14:57:33Z
department:
- _id: '306'
doi: 10.1021/cs300686m
intvolume: ' 3'
issue: '1'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 95-102
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Formation, Operation and Deactivation of Cr Catalysts in Ethylene Tetramerization
Directly Assessed by Operando EPR and XAS
type: journal_article
user_id: '48467'
volume: 3
year: '2012'
...