[{"publication":"ChemistryOpen","type":"journal_article","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The synthesis of three novel imidazolyl‐substituted sulfur‐containing heteroacenes is reported. These heteroacenes consisting of annelated benzo‐ and naphthothiophenes serve as precursors for the generation of open‐shell quinoid heteroacenes by oxidation with alkaline ferric cyanide. Spectroscopic and computational experiments support the formation of reactive open‐shell quinoids, which, however, quickly produce paramagnetic polymeric material.</jats:p>"}],"status":"public","_id":"64893","department":[{"_id":"2"},{"_id":"389"}],"user_id":"53339","article_number":"e202300003","language":[{"iso":"eng"}],"publication_identifier":{"issn":["2191-1363","2191-1363"]},"publication_status":"published","issue":"11","year":"2023","intvolume":"        12","citation":{"ama":"Hou P, Peschtrich S, Feuerstein W, et al. Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids. <i>ChemistryOpen</i>. 2023;12(11). doi:<a href=\"https://doi.org/10.1002/open.202300003\">10.1002/open.202300003</a>","chicago":"Hou, Peng, Sebastian Peschtrich, Wolfram Feuerstein, Roland Schoch, Stephan Hohloch, Frank Breher, and Jan Paradies. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids.” <i>ChemistryOpen</i> 12, no. 11 (2023). <a href=\"https://doi.org/10.1002/open.202300003\">https://doi.org/10.1002/open.202300003</a>.","ieee":"P. Hou <i>et al.</i>, “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids,” <i>ChemistryOpen</i>, vol. 12, no. 11, Art. no. e202300003, 2023, doi: <a href=\"https://doi.org/10.1002/open.202300003\">10.1002/open.202300003</a>.","bibtex":"@article{Hou_Peschtrich_Feuerstein_Schoch_Hohloch_Breher_Paradies_2023, title={Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids}, volume={12}, DOI={<a href=\"https://doi.org/10.1002/open.202300003\">10.1002/open.202300003</a>}, number={11e202300003}, journal={ChemistryOpen}, publisher={Wiley}, author={Hou, Peng and Peschtrich, Sebastian and Feuerstein, Wolfram and Schoch, Roland and Hohloch, Stephan and Breher, Frank and Paradies, Jan}, year={2023} }","short":"P. Hou, S. Peschtrich, W. Feuerstein, R. Schoch, S. Hohloch, F. Breher, J. Paradies, ChemistryOpen 12 (2023).","mla":"Hou, Peng, et al. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids.” <i>ChemistryOpen</i>, vol. 12, no. 11, e202300003, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/open.202300003\">10.1002/open.202300003</a>.","apa":"Hou, P., Peschtrich, S., Feuerstein, W., Schoch, R., Hohloch, S., Breher, F., &#38; Paradies, J. (2023). Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids. <i>ChemistryOpen</i>, <i>12</i>(11), Article e202300003. <a href=\"https://doi.org/10.1002/open.202300003\">https://doi.org/10.1002/open.202300003</a>"},"publisher":"Wiley","date_updated":"2026-03-11T10:21:47Z","volume":12,"author":[{"first_name":"Peng","last_name":"Hou","full_name":"Hou, Peng"},{"first_name":"Sebastian","full_name":"Peschtrich, Sebastian","last_name":"Peschtrich"},{"first_name":"Wolfram","full_name":"Feuerstein, Wolfram","last_name":"Feuerstein"},{"first_name":"Roland","last_name":"Schoch","full_name":"Schoch, Roland"},{"last_name":"Hohloch","full_name":"Hohloch, Stephan","first_name":"Stephan"},{"first_name":"Frank","last_name":"Breher","full_name":"Breher, Frank"},{"first_name":"Jan","id":"53339","full_name":"Paradies, Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X"}],"date_created":"2026-03-11T10:21:31Z","title":"Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids","doi":"10.1002/open.202300003"},{"article_type":"original","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"41011","status":"public","type":"journal_article","doi":"10.1002/open.202000307","author":[{"full_name":"Chakraborty, Uttam","last_name":"Chakraborty","first_name":"Uttam"},{"last_name":"Bügel","full_name":"Bügel, Patrick","first_name":"Patrick"},{"full_name":"Fritsch, Lorena","id":"44418","last_name":"Fritsch","first_name":"Lorena"},{"first_name":"Florian","last_name":"Weigend","full_name":"Weigend, Florian"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Axel","last_name":"Jacobi von Wangelin","full_name":"Jacobi von Wangelin, Axel"}],"volume":10,"date_updated":"2023-01-31T08:07:01Z","citation":{"chicago":"Chakraborty, Uttam, Patrick Bügel, Lorena Fritsch, Florian Weigend, Matthias Bauer, and Axel Jacobi von Wangelin. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.” <i>ChemistryOpen</i> 10, no. 2 (2021): 265–71. <a href=\"https://doi.org/10.1002/open.202000307\">https://doi.org/10.1002/open.202000307</a>.","ieee":"U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, and A. Jacobi von Wangelin, “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles,” <i>ChemistryOpen</i>, vol. 10, no. 2, pp. 265–271, 2021, doi: <a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>.","ama":"Chakraborty U, Bügel P, Fritsch L, Weigend F, Bauer M, Jacobi von Wangelin A. Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles. <i>ChemistryOpen</i>. 2021;10(2):265-271. doi:<a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>","mla":"Chakraborty, Uttam, et al. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles.” <i>ChemistryOpen</i>, vol. 10, no. 2, Wiley, 2021, pp. 265–71, doi:<a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>.","bibtex":"@article{Chakraborty_Bügel_Fritsch_Weigend_Bauer_Jacobi von Wangelin_2021, title={Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles}, volume={10}, DOI={<a href=\"https://doi.org/10.1002/open.202000307\">10.1002/open.202000307</a>}, number={2}, journal={ChemistryOpen}, publisher={Wiley}, author={Chakraborty, Uttam and Bügel, Patrick and Fritsch, Lorena and Weigend, Florian and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021}, pages={265–271} }","short":"U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, A. Jacobi von Wangelin, ChemistryOpen 10 (2021) 265–271.","apa":"Chakraborty, U., Bügel, P., Fritsch, L., Weigend, F., Bauer, M., &#38; Jacobi von Wangelin, A. (2021). Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles. <i>ChemistryOpen</i>, <i>10</i>(2), 265–271. <a href=\"https://doi.org/10.1002/open.202000307\">https://doi.org/10.1002/open.202000307</a>"},"page":"265-271","intvolume":"        10","publication_status":"published","publication_identifier":{"issn":["2191-1363","2191-1363"]},"language":[{"iso":"eng"}],"keyword":["General Chemistry"],"abstract":[{"text":"The controlled assembly of well-defined planar nanoclusters from molecular precursors is synthetically challenging and often plagued by the predominant formation of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide). The structures and properties of isolated Fe4, Fe6, and Fe7 nanoplatelets and calculated intermediates enable an unprecedented insight into the underlying building principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.","lang":"eng"}],"publication":"ChemistryOpen","title":"Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights into Structures and Building Principles","date_created":"2023-01-30T17:00:36Z","publisher":"Wiley","year":"2021","issue":"2"}]