---
_id: '64893'
abstract:
- lang: eng
text: AbstractThe synthesis of three novel imidazolyl‐substituted
sulfur‐containing heteroacenes is reported. These heteroacenes consisting of annelated
benzo‐ and naphthothiophenes serve as precursors for the generation of open‐shell
quinoid heteroacenes by oxidation with alkaline ferric cyanide. Spectroscopic
and computational experiments support the formation of reactive open‐shell quinoids,
which, however, quickly produce paramagnetic polymeric material.
article_number: e202300003
author:
- first_name: Peng
full_name: Hou, Peng
last_name: Hou
- first_name: Sebastian
full_name: Peschtrich, Sebastian
last_name: Peschtrich
- first_name: Wolfram
full_name: Feuerstein, Wolfram
last_name: Feuerstein
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Frank
full_name: Breher, Frank
last_name: Breher
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
citation:
ama: Hou P, Peschtrich S, Feuerstein W, et al. Imidazolyl‐Substituted Benzo‐ and
Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids.
ChemistryOpen. 2023;12(11). doi:10.1002/open.202300003
apa: Hou, P., Peschtrich, S., Feuerstein, W., Schoch, R., Hohloch, S., Breher, F.,
& Paradies, J. (2023). Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes
as Precursors for the Synthesis of Transient Open‐Shell Quinoids. ChemistryOpen,
12(11), Article e202300003. https://doi.org/10.1002/open.202300003
bibtex: '@article{Hou_Peschtrich_Feuerstein_Schoch_Hohloch_Breher_Paradies_2023,
title={Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for
the Synthesis of Transient Open‐Shell Quinoids}, volume={12}, DOI={10.1002/open.202300003},
number={11e202300003}, journal={ChemistryOpen}, publisher={Wiley}, author={Hou,
Peng and Peschtrich, Sebastian and Feuerstein, Wolfram and Schoch, Roland and
Hohloch, Stephan and Breher, Frank and Paradies, Jan}, year={2023} }'
chicago: Hou, Peng, Sebastian Peschtrich, Wolfram Feuerstein, Roland Schoch, Stephan
Hohloch, Frank Breher, and Jan Paradies. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes
as Precursors for the Synthesis of Transient Open‐Shell Quinoids.” ChemistryOpen
12, no. 11 (2023). https://doi.org/10.1002/open.202300003.
ieee: 'P. Hou et al., “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes
as Precursors for the Synthesis of Transient Open‐Shell Quinoids,” ChemistryOpen,
vol. 12, no. 11, Art. no. e202300003, 2023, doi: 10.1002/open.202300003.'
mla: Hou, Peng, et al. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as
Precursors for the Synthesis of Transient Open‐Shell Quinoids.” ChemistryOpen,
vol. 12, no. 11, e202300003, Wiley, 2023, doi:10.1002/open.202300003.
short: P. Hou, S. Peschtrich, W. Feuerstein, R. Schoch, S. Hohloch, F. Breher, J.
Paradies, ChemistryOpen 12 (2023).
date_created: 2026-03-11T10:21:31Z
date_updated: 2026-03-11T10:21:47Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/open.202300003
intvolume: ' 12'
issue: '11'
language:
- iso: eng
publication: ChemistryOpen
publication_identifier:
issn:
- 2191-1363
- 2191-1363
publication_status: published
publisher: Wiley
status: public
title: Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the
Synthesis of Transient Open‐Shell Quinoids
type: journal_article
user_id: '53339'
volume: 12
year: '2023'
...
---
_id: '41011'
abstract:
- lang: eng
text: The controlled assembly of well-defined planar nanoclusters from molecular
precursors is synthetically challenging and often plagued by the predominant formation
of 3D-structures and nanoparticles. Herein, we report planar iron hydride nanoclusters
from reactions of main group element hydrides with iron(II) bis(hexamethyldisilazide).
The structures and properties of isolated Fe4, Fe6, and Fe7 nanoplatelets and
calculated intermediates enable an unprecedented insight into the underlying building
principle and growth mechanism of iron clusters, metal monolayers, and nanoparticles.
article_type: original
author:
- first_name: Uttam
full_name: Chakraborty, Uttam
last_name: Chakraborty
- first_name: Patrick
full_name: Bügel, Patrick
last_name: Bügel
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Florian
full_name: Weigend, Florian
last_name: Weigend
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: 'Chakraborty U, Bügel P, Fritsch L, Weigend F, Bauer M, Jacobi von Wangelin
A. Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights
into Structures and Building Principles. ChemistryOpen. 2021;10(2):265-271.
doi:10.1002/open.202000307'
apa: 'Chakraborty, U., Bügel, P., Fritsch, L., Weigend, F., Bauer, M., & Jacobi
von Wangelin, A. (2021). Planar Iron Hydride Nanoclusters: Combined Spectroscopic
and Theoretical Insights into Structures and Building Principles. ChemistryOpen,
10(2), 265–271. https://doi.org/10.1002/open.202000307'
bibtex: '@article{Chakraborty_Bügel_Fritsch_Weigend_Bauer_Jacobi von Wangelin_2021,
title={Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical
Insights into Structures and Building Principles}, volume={10}, DOI={10.1002/open.202000307},
number={2}, journal={ChemistryOpen}, publisher={Wiley}, author={Chakraborty, Uttam
and Bügel, Patrick and Fritsch, Lorena and Weigend, Florian and Bauer, Matthias
and Jacobi von Wangelin, Axel}, year={2021}, pages={265–271} }'
chicago: 'Chakraborty, Uttam, Patrick Bügel, Lorena Fritsch, Florian Weigend, Matthias
Bauer, and Axel Jacobi von Wangelin. “Planar Iron Hydride Nanoclusters: Combined
Spectroscopic and Theoretical Insights into Structures and Building Principles.”
ChemistryOpen 10, no. 2 (2021): 265–71. https://doi.org/10.1002/open.202000307.'
ieee: 'U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, and A. Jacobi
von Wangelin, “Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical
Insights into Structures and Building Principles,” ChemistryOpen, vol.
10, no. 2, pp. 265–271, 2021, doi: 10.1002/open.202000307.'
mla: 'Chakraborty, Uttam, et al. “Planar Iron Hydride Nanoclusters: Combined Spectroscopic
and Theoretical Insights into Structures and Building Principles.” ChemistryOpen,
vol. 10, no. 2, Wiley, 2021, pp. 265–71, doi:10.1002/open.202000307.'
short: U. Chakraborty, P. Bügel, L. Fritsch, F. Weigend, M. Bauer, A. Jacobi von
Wangelin, ChemistryOpen 10 (2021) 265–271.
date_created: 2023-01-30T17:00:36Z
date_updated: 2023-01-31T08:07:01Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/open.202000307
intvolume: ' 10'
issue: '2'
keyword:
- General Chemistry
language:
- iso: eng
page: 265-271
publication: ChemistryOpen
publication_identifier:
issn:
- 2191-1363
- 2191-1363
publication_status: published
publisher: Wiley
status: public
title: 'Planar Iron Hydride Nanoclusters: Combined Spectroscopic and Theoretical Insights
into Structures and Building Principles'
type: journal_article
user_id: '48467'
volume: 10
year: '2021'
...