---
_id: '41841'
abstract:
- lang: eng
  text: "<jats:title>Abstract</jats:title>\r\n               <jats:p>In this report,
    we summarize our experimental and theoretical investigations in the zinc(II) imidazolate,
    [Zn(im)<jats:sub>2</jats:sub>], and zinc(II) 4,5-dichloroimidazolate, [Zn(dcim)<jats:sub>2</jats:sub>],
    systems that have been published previously. This comprises a study on the thermodynamic
    stabilities of the two densest phases with coi and zni framework structures in
    the [Zn(im)<jats:sub>2</jats:sub>] system including the discovery and characterization
    of a new [Zn(im)<jats:sub>2</jats:sub>·0.5py]-neb phase (py = pyridine), a study
    on the mechanism of formation of the [Zn(im)<jats:sub>2</jats:sub>]-zni phase
    as well as a study on the discovery and characterization of a new [Zn(dcim)<jats:sub>2</jats:sub>]-SOD
    phase. In addition, we present as yet unpublished work. This concerns the discovery
    and characterization of a new [Zn(im)<jats:sub>2</jats:sub>·0.5mor]-neb phase
    (mor = morpholine) and investigations of the mechanisms of crystallization of
    [Zn(im)<jats:sub>2</jats:sub>·0.5py]-neb and [Zn(im)<jats:sub>2</jats:sub>·0.5mor]-neb
    as well as an evalutation of time-resolved SAXS/WAXS data recorded <jats:italic>in-situ</jats:italic>
    during the formation of [Zn(im)<jats:sub>2</jats:sub>]-zni.</jats:p>"
author:
- first_name: Christian A.
  full_name: Schröder, Christian A.
  last_name: Schröder
- first_name: Sanjib
  full_name: Saha, Sanjib
  last_name: Saha
- first_name: Klaus
  full_name: Huber, Klaus
  id: '237'
  last_name: Huber
- first_name: Stefano
  full_name: Leoni, Stefano
  last_name: Leoni
- first_name: Michael
  full_name: Wiebcke, Michael
  last_name: Wiebcke
citation:
  ama: 'Schröder CA, Saha S, Huber K, Leoni S, Wiebcke M. Metastable metal imidazolates:
    development of targeted syntheses by combining experimental and theoretical investigations
    of the formation mechanisms. <i>Zeitschrift für Kristallographie - Crystalline
    Materials</i>. 2014;229(12):807-822. doi:<a href="https://doi.org/10.1515/zkri-2014-1788">10.1515/zkri-2014-1788</a>'
  apa: 'Schröder, C. A., Saha, S., Huber, K., Leoni, S., &#38; Wiebcke, M. (2014).
    Metastable metal imidazolates: development of targeted syntheses by combining
    experimental and theoretical investigations of the formation mechanisms. <i>Zeitschrift
    Für Kristallographie - Crystalline Materials</i>, <i>229</i>(12), 807–822. <a
    href="https://doi.org/10.1515/zkri-2014-1788">https://doi.org/10.1515/zkri-2014-1788</a>'
  bibtex: '@article{Schröder_Saha_Huber_Leoni_Wiebcke_2014, title={Metastable metal
    imidazolates: development of targeted syntheses by combining experimental and
    theoretical investigations of the formation mechanisms}, volume={229}, DOI={<a
    href="https://doi.org/10.1515/zkri-2014-1788">10.1515/zkri-2014-1788</a>}, number={12},
    journal={Zeitschrift für Kristallographie - Crystalline Materials}, publisher={Walter
    de Gruyter GmbH}, author={Schröder, Christian A. and Saha, Sanjib and Huber, Klaus
    and Leoni, Stefano and Wiebcke, Michael}, year={2014}, pages={807–822} }'
  chicago: 'Schröder, Christian A., Sanjib Saha, Klaus Huber, Stefano Leoni, and Michael
    Wiebcke. “Metastable Metal Imidazolates: Development of Targeted Syntheses by
    Combining Experimental and Theoretical Investigations of the Formation Mechanisms.”
    <i>Zeitschrift Für Kristallographie - Crystalline Materials</i> 229, no. 12 (2014):
    807–22. <a href="https://doi.org/10.1515/zkri-2014-1788">https://doi.org/10.1515/zkri-2014-1788</a>.'
  ieee: 'C. A. Schröder, S. Saha, K. Huber, S. Leoni, and M. Wiebcke, “Metastable
    metal imidazolates: development of targeted syntheses by combining experimental
    and theoretical investigations of the formation mechanisms,” <i>Zeitschrift für
    Kristallographie - Crystalline Materials</i>, vol. 229, no. 12, pp. 807–822, 2014,
    doi: <a href="https://doi.org/10.1515/zkri-2014-1788">10.1515/zkri-2014-1788</a>.'
  mla: 'Schröder, Christian A., et al. “Metastable Metal Imidazolates: Development
    of Targeted Syntheses by Combining Experimental and Theoretical Investigations
    of the Formation Mechanisms.” <i>Zeitschrift Für Kristallographie - Crystalline
    Materials</i>, vol. 229, no. 12, Walter de Gruyter GmbH, 2014, pp. 807–22, doi:<a
    href="https://doi.org/10.1515/zkri-2014-1788">10.1515/zkri-2014-1788</a>.'
  short: C.A. Schröder, S. Saha, K. Huber, S. Leoni, M. Wiebcke, Zeitschrift Für Kristallographie
    - Crystalline Materials 229 (2014) 807–822.
date_created: 2023-02-06T12:52:06Z
date_updated: 2023-02-06T12:52:23Z
department:
- _id: '314'
doi: 10.1515/zkri-2014-1788
intvolume: '       229'
issue: '12'
keyword:
- Inorganic Chemistry
- Condensed Matter Physics
- General Materials Science
language:
- iso: eng
page: 807-822
publication: Zeitschrift für Kristallographie - Crystalline Materials
publication_identifier:
  issn:
  - 2196-7105
  - 2194-4946
publication_status: published
publisher: Walter de Gruyter GmbH
status: public
title: 'Metastable metal imidazolates: development of targeted syntheses by combining
  experimental and theoretical investigations of the formation mechanisms'
type: journal_article
user_id: '237'
volume: 229
year: '2014'
...
