[{"status":"public","abstract":[{"text":"<jats:title>Abstract</jats:title>\r\n                  <jats:p>\r\n                    The development of efficient and broadly applicable n‐doping strategies for organic semiconductors (OSCs) is crucial for advancing the performance of various organic electronic devices. Here, a novel nucleophilic‐attack n‐doping mechanism is unveiled that achieves exceptionally high conductivity in doped OSC films and demonstrates broad applicability across OSCs. The remarkable efficacy of n‐Butyl lithium (n‐BuLi) is highlighted in n‐doping C\r\n                    <jats:sub>60</jats:sub>\r\n                    and PC\r\n                    <jats:sub>61</jats:sub>\r\n                    BM, achieving a conductivity of 1.27 S cm\r\n                    <jats:sup>−1</jats:sup>\r\n                    and 2.57 S cm\r\n                    <jats:sup>−1</jats:sup>\r\n                    , respectively, which are among the highest reported values for these materials. The investigation reveals that the n‐BuLi anion interacts with electron‐deficient units in OSCs, generating a carbanion that facilitates efficient electron transfer for n‐doping. This mechanism is further validated across diverse fullerenes, polymeric, and small molecule OSCs, and is extendable to other high‐performance dopants such as tert‐Butyllithium (tert‐BuLi) and sodium ethoxide (NaOEt). Device studies show that n‐BuLi‐doped C\r\n                    <jats:sub>60</jats:sub>\r\n                    enables substantially improved diode rectification, attributed to greater junction built‐in potential. These findings establish a unified chemical‐bonding‐based n‐doping paradigm, complementing existing electrophilic‐attack p‐doping concepts, and pave the way for achieving efficient doping of OSCs for advanced organic electronic applications.\r\n                  </jats:p>","lang":"eng"}],"type":"journal_article","publication":"Advanced Science","language":[{"iso":"eng"}],"article_number":"e20487","user_id":"16199","department":[{"_id":"15"},{"_id":"170"},{"_id":"297"},{"_id":"705"},{"_id":"35"},{"_id":"230"}],"_id":"62866","citation":{"bibtex":"@article{Wei_Wu_Dong_Chen_Gong_Xia_Peng_Ding_Zhang_Shi_et al._2025, title={Efficient n‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism}, DOI={<a href=\"https://doi.org/10.1002/advs.202520487\">10.1002/advs.202520487</a>}, number={e20487}, journal={Advanced Science}, publisher={Wiley}, author={Wei, Huan and Wu, Tong and Dong, Chuanding and Chen, Chen and Gong, Zhenqi and Xia, Jiangnan and Peng, Chengyuan and Ding, Jiaqi and Zhang, Yu and Shi, Wenpei and et al.}, year={2025} }","mla":"Wei, Huan, et al. “Efficient N‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism.” <i>Advanced Science</i>, e20487, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/advs.202520487\">10.1002/advs.202520487</a>.","short":"H. Wei, T. Wu, C. Dong, C. Chen, Z. Gong, J. Xia, C. Peng, J. Ding, Y. Zhang, W. Shi, S. Schumacher, X. Zhang, Y. Bai, L. Jiang, L. Liao, T. Nguyen, Y. Hu, Advanced Science (2025).","apa":"Wei, H., Wu, T., Dong, C., Chen, C., Gong, Z., Xia, J., Peng, C., Ding, J., Zhang, Y., Shi, W., Schumacher, S., Zhang, X., Bai, Y., Jiang, L., Liao, L., Nguyen, T., &#38; Hu, Y. (2025). Efficient n‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism. <i>Advanced Science</i>, Article e20487. <a href=\"https://doi.org/10.1002/advs.202520487\">https://doi.org/10.1002/advs.202520487</a>","chicago":"Wei, Huan, Tong Wu, Chuanding Dong, Chen Chen, Zhenqi Gong, Jiangnan Xia, Chengyuan Peng, et al. “Efficient N‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism.” <i>Advanced Science</i>, 2025. <a href=\"https://doi.org/10.1002/advs.202520487\">https://doi.org/10.1002/advs.202520487</a>.","ieee":"H. Wei <i>et al.</i>, “Efficient n‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism,” <i>Advanced Science</i>, Art. no. e20487, 2025, doi: <a href=\"https://doi.org/10.1002/advs.202520487\">10.1002/advs.202520487</a>.","ama":"Wei H, Wu T, Dong C, et al. Efficient n‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism. <i>Advanced Science</i>. Published online 2025. doi:<a href=\"https://doi.org/10.1002/advs.202520487\">10.1002/advs.202520487</a>"},"year":"2025","publication_status":"published","publication_identifier":{"issn":["2198-3844","2198-3844"]},"doi":"10.1002/advs.202520487","title":"Efficient n‐Doping of Organic Semiconductors via a Broadly Applicable Nucleophilic‐Attack Mechanism","date_created":"2025-12-04T12:30:39Z","author":[{"last_name":"Wei","full_name":"Wei, Huan","first_name":"Huan"},{"last_name":"Wu","full_name":"Wu, Tong","first_name":"Tong"},{"full_name":"Dong, Chuanding","last_name":"Dong","first_name":"Chuanding"},{"last_name":"Chen","full_name":"Chen, Chen","first_name":"Chen"},{"first_name":"Zhenqi","last_name":"Gong","full_name":"Gong, Zhenqi"},{"last_name":"Xia","full_name":"Xia, Jiangnan","first_name":"Jiangnan"},{"first_name":"Chengyuan","full_name":"Peng, Chengyuan","last_name":"Peng"},{"first_name":"Jiaqi","last_name":"Ding","full_name":"Ding, Jiaqi"},{"last_name":"Zhang","full_name":"Zhang, Yu","first_name":"Yu"},{"first_name":"Wenpei","last_name":"Shi","full_name":"Shi, Wenpei"},{"full_name":"Schumacher, Stefan","id":"27271","last_name":"Schumacher","orcid":"0000-0003-4042-4951","first_name":"Stefan"},{"first_name":"Xue","last_name":"Zhang","full_name":"Zhang, Xue"},{"first_name":"Yugang","full_name":"Bai, Yugang","last_name":"Bai"},{"first_name":"Lang","last_name":"Jiang","full_name":"Jiang, Lang"},{"full_name":"Liao, Lei","last_name":"Liao","first_name":"Lei"},{"first_name":"Thuc‐Quyen","last_name":"Nguyen","full_name":"Nguyen, Thuc‐Quyen"},{"full_name":"Hu, Yuanyuan","last_name":"Hu","first_name":"Yuanyuan"}],"date_updated":"2025-12-05T13:40:48Z","publisher":"Wiley"},{"keyword":["Photo","Xray"],"language":[{"iso":"eng"}],"_id":"56074","department":[{"_id":"306"}],"user_id":"48467","abstract":[{"lang":"eng","text":"Effective photoinduced charge transfer makes molecular bimetallic assemblies attractive for applications as active light‐induced proton reduction systems. Developing competitive base metal dyads is mandatory for a more sustainable future. However, the electron transfer mechanisms from the photosensitizer to the proton reduction catalyst in base metal dyads remain so far unexplored. A Fe─Co dyad that exhibits photocatalytic H2 production activity is studied using femtosecond X‐ray emission spectroscopy, complemented by ultrafast optical spectroscopy and theoretical time‐dependent DFT calculations, to understand the electronic and structural dynamics after photoexcitation and during the subsequent charge transfer process from the Fe(II) photosensitizer to the cobaloxime catalyst. This novel approach enables the simultaneous measurement of the transient X‐ray emission at the iron and cobalt K‐edges in a two‐color experiment. With this methodology, the excited state dynamics are correlated to the electron transfer processes, and evidence of the Fe→Co electron transfer as an initial step of proton reduction activity is unraveled."}],"status":"public","publication":"Advanced Science","type":"journal_article","title":"Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad","doi":"10.1002/advs.202404348","date_updated":"2025-08-15T12:49:56Z","publisher":"Wiley","date_created":"2024-09-05T11:31:30Z","author":[{"first_name":"Michał","full_name":"Nowakowski, Michał","id":"78878","orcid":"0000-0002-3734-7011","last_name":"Nowakowski"},{"last_name":"Huber‐Gedert","full_name":"Huber‐Gedert, Marina","first_name":"Marina"},{"id":"60250","full_name":"Elgabarty, Hossam","orcid":"0000-0002-4945-1481","last_name":"Elgabarty","first_name":"Hossam"},{"last_name":"Kalinko","full_name":"Kalinko, Aleksandr","first_name":"Aleksandr"},{"first_name":"Jacek","last_name":"Kubicki","full_name":"Kubicki, Jacek"},{"first_name":"Ahmet","last_name":"Kertmen","full_name":"Kertmen, Ahmet"},{"first_name":"Natalia","full_name":"Lindner, Natalia","last_name":"Lindner"},{"full_name":"Khakhulin, Dmitry","last_name":"Khakhulin","first_name":"Dmitry"},{"last_name":"Lima","full_name":"Lima, Frederico A.","first_name":"Frederico A."},{"full_name":"Choi, Tae‐Kyu","last_name":"Choi","first_name":"Tae‐Kyu"},{"last_name":"Biednov","full_name":"Biednov, Mykola","first_name":"Mykola"},{"first_name":"Lennart","last_name":"Schmitz","id":"53140","full_name":"Schmitz, Lennart"},{"first_name":"Natalia","last_name":"Piergies","full_name":"Piergies, Natalia"},{"first_name":"Peter","last_name":"Zalden","full_name":"Zalden, Peter"},{"full_name":"Kubicek, Katerina","last_name":"Kubicek","first_name":"Katerina"},{"first_name":"Angel","full_name":"Rodriguez‐Fernandez, Angel","last_name":"Rodriguez‐Fernandez"},{"full_name":"Salem, Mohammad Alaraby","last_name":"Salem","first_name":"Mohammad Alaraby"},{"last_name":"Canton","full_name":"Canton, Sophie E.","first_name":"Sophie E."},{"first_name":"Christian","full_name":"Bressler, Christian","last_name":"Bressler"},{"last_name":"Kühne","full_name":"Kühne, Thomas D.","first_name":"Thomas D."},{"first_name":"Wojciech","full_name":"Gawelda, Wojciech","last_name":"Gawelda"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"}],"year":"2024","citation":{"ama":"Nowakowski M, Huber‐Gedert M, Elgabarty H, et al. Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad. <i>Advanced Science</i>. Published online 2024. doi:<a href=\"https://doi.org/10.1002/advs.202404348\">10.1002/advs.202404348</a>","ieee":"M. Nowakowski <i>et al.</i>, “Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad,” <i>Advanced Science</i>, 2024, doi: <a href=\"https://doi.org/10.1002/advs.202404348\">10.1002/advs.202404348</a>.","chicago":"Nowakowski, Michał, Marina Huber‐Gedert, Hossam Elgabarty, Aleksandr Kalinko, Jacek Kubicki, Ahmet Kertmen, Natalia Lindner, et al. “Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad.” <i>Advanced Science</i>, 2024. <a href=\"https://doi.org/10.1002/advs.202404348\">https://doi.org/10.1002/advs.202404348</a>.","apa":"Nowakowski, M., Huber‐Gedert, M., Elgabarty, H., Kalinko, A., Kubicki, J., Kertmen, A., Lindner, N., Khakhulin, D., Lima, F. A., Choi, T., Biednov, M., Schmitz, L., Piergies, N., Zalden, P., Kubicek, K., Rodriguez‐Fernandez, A., Salem, M. A., Canton, S. E., Bressler, C., … Bauer, M. (2024). Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad. <i>Advanced Science</i>. <a href=\"https://doi.org/10.1002/advs.202404348\">https://doi.org/10.1002/advs.202404348</a>","short":"M. Nowakowski, M. Huber‐Gedert, H. Elgabarty, A. Kalinko, J. Kubicki, A. Kertmen, N. Lindner, D. Khakhulin, F.A. Lima, T. Choi, M. Biednov, L. Schmitz, N. Piergies, P. Zalden, K. Kubicek, A. Rodriguez‐Fernandez, M.A. Salem, S.E. Canton, C. Bressler, T.D. Kühne, W. Gawelda, M. Bauer, Advanced Science (2024).","bibtex":"@article{Nowakowski_Huber‐Gedert_Elgabarty_Kalinko_Kubicki_Kertmen_Lindner_Khakhulin_Lima_Choi_et al._2024, title={Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad}, DOI={<a href=\"https://doi.org/10.1002/advs.202404348\">10.1002/advs.202404348</a>}, journal={Advanced Science}, publisher={Wiley}, author={Nowakowski, Michał and Huber‐Gedert, Marina and Elgabarty, Hossam and Kalinko, Aleksandr and Kubicki, Jacek and Kertmen, Ahmet and Lindner, Natalia and Khakhulin, Dmitry and Lima, Frederico A. and Choi, Tae‐Kyu and et al.}, year={2024} }","mla":"Nowakowski, Michał, et al. “Ultrafast Two‐Color X‐Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad.” <i>Advanced Science</i>, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/advs.202404348\">10.1002/advs.202404348</a>."},"publication_identifier":{"issn":["2198-3844","2198-3844"]},"publication_status":"published"},{"user_id":"98120","_id":"62675","language":[{"iso":"eng"}],"article_number":"2300099","publication":"Advanced Science","type":"journal_article","status":"public","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title>\r\n                  <jats:p>\r\n                    Materials dictate carbon neutral industrial chemical processes. Visible‐light photoelectrocatalysts from abundant resources will play a key role in exploiting solar irradiation. Anionic doping via pre‐organization of precursors and further co‐polymerization creates tuneable semiconductors. Triazole derivative‐purpald, an unexplored precursor with sulfur (S) container, combined in different initial ratios with melamine during one solid‐state polycondensation with two thermal steps yields hybrid S‐doped carbon nitrides (C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    ). The series of S‐doped/C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    ‐based materials show enhanced optical, electronic, structural, textural, and morphological properties and exhibit higher performance in organic benzylamine photooxidation, oxygen evolution, and similar energy storage (capacitor brief investigation). 50M‐50P exhibits the highest photooxidation conversion (84 ± 3%) of benzylamine to imine at 535 nm – green light for 48 h, due to a discrete shoulder (≈700) nm, high sulfur content, preservation of crystal size, new intraband energy states, structural defects by layer distortion, and 10–16 nm pores with arbitrary depth. This work innovates by studying the concomitant relationships between: 1) the precursor decomposition while C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    is formed, 2) the insertion of S impurities, 3) the S‐doped C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    property‐activity relationships, and 4) combinatorial surface, bulk, structural, optical, and electronic characterization analysis. This work contributes to the development of disordered long‐visible‐light photocatalysts for solar energy conversion and storage.\r\n                  </jats:p>"}],"volume":10,"date_created":"2025-11-27T13:16:31Z","author":[{"full_name":"Jerigova, Maria","last_name":"Jerigova","first_name":"Maria"},{"first_name":"Yevheniia","last_name":"Markushyna","full_name":"Markushyna, Yevheniia"},{"first_name":"Ivo F.","last_name":"Teixeira","full_name":"Teixeira, Ivo F."},{"last_name":"Badamdorj","full_name":"Badamdorj, Bolortuya","first_name":"Bolortuya"},{"last_name":"Isaacs","full_name":"Isaacs, Mark","first_name":"Mark"},{"first_name":"Daniel","last_name":"Cruz","full_name":"Cruz, Daniel"},{"full_name":"Lauermann, Iver","last_name":"Lauermann","first_name":"Iver"},{"first_name":"Miguel Ángel","full_name":"Muñoz‐Márquez, Miguel Ángel","last_name":"Muñoz‐Márquez"},{"first_name":"Nadezda V.","full_name":"Tarakina, Nadezda V.","last_name":"Tarakina"},{"orcid":"https://orcid.org/0000-0002-8438-9548","last_name":"Lopez Salas","full_name":"Lopez Salas, Nieves","id":"98120","first_name":"Nieves"},{"full_name":"Savateev, Oleksandr","last_name":"Savateev","first_name":"Oleksandr"},{"first_name":"Pablo","last_name":"Jimenéz‐Calvo","full_name":"Jimenéz‐Calvo, Pablo"}],"publisher":"Wiley","date_updated":"2026-01-08T13:11:24Z","doi":"10.1002/advs.202300099","title":"Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions","issue":"13","publication_identifier":{"issn":["2198-3844","2198-3844"]},"publication_status":"published","intvolume":"        10","citation":{"chicago":"Jerigova, Maria, Yevheniia Markushyna, Ivo F. Teixeira, Bolortuya Badamdorj, Mark Isaacs, Daniel Cruz, Iver Lauermann, et al. “Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions.” <i>Advanced Science</i> 10, no. 13 (2023). <a href=\"https://doi.org/10.1002/advs.202300099\">https://doi.org/10.1002/advs.202300099</a>.","ieee":"M. Jerigova <i>et al.</i>, “Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions,” <i>Advanced Science</i>, vol. 10, no. 13, Art. no. 2300099, 2023, doi: <a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>.","ama":"Jerigova M, Markushyna Y, Teixeira IF, et al. Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions. <i>Advanced Science</i>. 2023;10(13). doi:<a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>","mla":"Jerigova, Maria, et al. “Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions.” <i>Advanced Science</i>, vol. 10, no. 13, 2300099, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>.","bibtex":"@article{Jerigova_Markushyna_Teixeira_Badamdorj_Isaacs_Cruz_Lauermann_Muñoz‐Márquez_Tarakina_Lopez Salas_et al._2023, title={Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions}, volume={10}, DOI={<a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>}, number={132300099}, journal={Advanced Science}, publisher={Wiley}, author={Jerigova, Maria and Markushyna, Yevheniia and Teixeira, Ivo F. and Badamdorj, Bolortuya and Isaacs, Mark and Cruz, Daniel and Lauermann, Iver and Muñoz‐Márquez, Miguel Ángel and Tarakina, Nadezda V. and Lopez Salas, Nieves and et al.}, year={2023} }","short":"M. Jerigova, Y. Markushyna, I.F. Teixeira, B. Badamdorj, M. Isaacs, D. Cruz, I. Lauermann, M.Á. Muñoz‐Márquez, N.V. Tarakina, N. Lopez Salas, O. Savateev, P. Jimenéz‐Calvo, Advanced Science 10 (2023).","apa":"Jerigova, M., Markushyna, Y., Teixeira, I. F., Badamdorj, B., Isaacs, M., Cruz, D., Lauermann, I., Muñoz‐Márquez, M. Á., Tarakina, N. V., Lopez Salas, N., Savateev, O., &#38; Jimenéz‐Calvo, P. (2023). Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions. <i>Advanced Science</i>, <i>10</i>(13), Article 2300099. <a href=\"https://doi.org/10.1002/advs.202300099\">https://doi.org/10.1002/advs.202300099</a>"},"year":"2023"},{"doi":"10.1002/advs.202300526","title":"Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution","author":[{"first_name":"Chun","full_name":"Li, Chun","last_name":"Li"},{"full_name":"Lepre, Enrico","last_name":"Lepre","first_name":"Enrico"},{"first_name":"Min","full_name":"Bi, Min","last_name":"Bi"},{"last_name":"Antonietti","full_name":"Antonietti, Markus","first_name":"Markus"},{"first_name":"Junwu","full_name":"Zhu, Junwu","last_name":"Zhu"},{"full_name":"Fu, Yongsheng","last_name":"Fu","first_name":"Yongsheng"},{"first_name":"Nieves","last_name":"Lopez Salas","orcid":"https://orcid.org/0000-0002-8438-9548","full_name":"Lopez Salas, Nieves","id":"98120"}],"date_created":"2025-11-27T13:16:12Z","volume":10,"publisher":"Wiley","date_updated":"2026-01-08T13:16:44Z","citation":{"short":"C. Li, E. Lepre, M. Bi, M. Antonietti, J. Zhu, Y. Fu, N. Lopez Salas, Advanced Science 10 (2023).","bibtex":"@article{Li_Lepre_Bi_Antonietti_Zhu_Fu_Lopez Salas_2023, title={Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution}, volume={10}, DOI={<a href=\"https://doi.org/10.1002/advs.202300526\">10.1002/advs.202300526</a>}, number={222300526}, journal={Advanced Science}, publisher={Wiley}, author={Li, Chun and Lepre, Enrico and Bi, Min and Antonietti, Markus and Zhu, Junwu and Fu, Yongsheng and Lopez Salas, Nieves}, year={2023} }","mla":"Li, Chun, et al. “Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution.” <i>Advanced Science</i>, vol. 10, no. 22, 2300526, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/advs.202300526\">10.1002/advs.202300526</a>.","apa":"Li, C., Lepre, E., Bi, M., Antonietti, M., Zhu, J., Fu, Y., &#38; Lopez Salas, N. (2023). Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution. <i>Advanced Science</i>, <i>10</i>(22), Article 2300526. <a href=\"https://doi.org/10.1002/advs.202300526\">https://doi.org/10.1002/advs.202300526</a>","ieee":"C. Li <i>et al.</i>, “Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution,” <i>Advanced Science</i>, vol. 10, no. 22, Art. no. 2300526, 2023, doi: <a href=\"https://doi.org/10.1002/advs.202300526\">10.1002/advs.202300526</a>.","chicago":"Li, Chun, Enrico Lepre, Min Bi, Markus Antonietti, Junwu Zhu, Yongsheng Fu, and Nieves Lopez Salas. “Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution.” <i>Advanced Science</i> 10, no. 22 (2023). <a href=\"https://doi.org/10.1002/advs.202300526\">https://doi.org/10.1002/advs.202300526</a>.","ama":"Li C, Lepre E, Bi M, et al. Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution. <i>Advanced Science</i>. 2023;10(22). doi:<a href=\"https://doi.org/10.1002/advs.202300526\">10.1002/advs.202300526</a>"},"intvolume":"        10","year":"2023","issue":"22","publication_status":"published","publication_identifier":{"issn":["2198-3844","2198-3844"]},"language":[{"iso":"eng"}],"article_number":"2300526","user_id":"98120","_id":"62672","status":"public","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>Functionalized porous carbons are central to various important applications such as energy storage and conversion. Here, a simple synthetic route to prepare oxygen‐rich carbon nitrides (CNOs) decorated with stable Ni and Fe‐nanosites is demonstrated. The CNOs are prepared via a salt templating method using ribose and adenine as precursors and CaCl<jats:sub>2</jats:sub>·2H<jats:sub>2</jats:sub>O as a template. The formation of supramolecular eutectic complexes between CaCl<jats:sub>2</jats:sub>·2H<jats:sub>2</jats:sub>O and ribose at relatively low temperatures facilitates the formation of a homogeneous starting mixture, promotes the condensation of ribose through the dehydrating effect of CaCl<jats:sub>2</jats:sub>·2H<jats:sub>2</jats:sub>O to covalent frameworks, and finally generates homogeneous CNOs. As a specific of the recipe, the condensation of the precursors at higher temperatures and the removal of water promotes the recrystallization of CaCl<jats:sub>2</jats:sub> (<jats:italic>T</jats:italic> &lt; <jats:italic>T<jats:sub>m</jats:sub></jats:italic> = 772 °C), which then acts as a hard porogen. Due to salt catalysis, CNOs with oxygen and nitrogen contents as high as 12 and 20 wt%, respectively, can be obtained, while heteroatom content stayed about unchanged even at higher temperatures of synthesis, pointing to the extraordinarily high stability of the materials. After decorating Ni and Fe‐nanosites onto the CNOs, the materials exhibit high activity and stability for electrochemical oxygen evolution reaction with an overpotential of 351 mV.</jats:p>"}],"type":"journal_article","publication":"Advanced Science"},{"status":"public","type":"journal_article","file_date_updated":"2022-03-03T07:23:15Z","article_type":"original","article_number":"2104508","user_id":"30525","department":[{"_id":"15"},{"_id":"230"},{"_id":"289"},{"_id":"623"}],"project":[{"name":"TRR 142: TRR 142","_id":"53"},{"_id":"56","name":"TRR 142 - C: TRR 142 - Project Area C"},{"name":"TRR 142 - C5: TRR 142 - Subproject C5","_id":"75"}],"_id":"29902","citation":{"apa":"Reineke Matsudo, B., Sain, B., Carletti, L., Zhang, X., Gao, W., Angelis, C., Huang, L., &#38; Zentgraf, T. (2022). Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces. <i>Advanced Science</i>, <i>9</i>(12), Article 2104508. <a href=\"https://doi.org/10.1002/advs.202104508\">https://doi.org/10.1002/advs.202104508</a>","bibtex":"@article{Reineke Matsudo_Sain_Carletti_Zhang_Gao_Angelis_Huang_Zentgraf_2022, title={Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces}, volume={9}, DOI={<a href=\"https://doi.org/10.1002/advs.202104508\">10.1002/advs.202104508</a>}, number={122104508}, journal={Advanced Science}, publisher={Wiley}, author={Reineke Matsudo, Bernhard and Sain, Basudeb and Carletti, Luca and Zhang, Xue and Gao, Wenlong and Angelis, Costantino and Huang, Lingling and Zentgraf, Thomas}, year={2022} }","short":"B. Reineke Matsudo, B. Sain, L. Carletti, X. Zhang, W. Gao, C. Angelis, L. Huang, T. Zentgraf, Advanced Science 9 (2022).","mla":"Reineke Matsudo, Bernhard, et al. “Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces.” <i>Advanced Science</i>, vol. 9, no. 12, 2104508, Wiley, 2022, doi:<a href=\"https://doi.org/10.1002/advs.202104508\">10.1002/advs.202104508</a>.","ama":"Reineke Matsudo B, Sain B, Carletti L, et al. Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces. <i>Advanced Science</i>. 2022;9(12). doi:<a href=\"https://doi.org/10.1002/advs.202104508\">10.1002/advs.202104508</a>","chicago":"Reineke Matsudo, Bernhard, Basudeb Sain, Luca Carletti, Xue Zhang, Wenlong Gao, Costantino Angelis, Lingling Huang, and Thomas Zentgraf. “Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces.” <i>Advanced Science</i> 9, no. 12 (2022). <a href=\"https://doi.org/10.1002/advs.202104508\">https://doi.org/10.1002/advs.202104508</a>.","ieee":"B. Reineke Matsudo <i>et al.</i>, “Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces,” <i>Advanced Science</i>, vol. 9, no. 12, Art. no. 2104508, 2022, doi: <a href=\"https://doi.org/10.1002/advs.202104508\">10.1002/advs.202104508</a>."},"intvolume":"         9","publication_status":"published","has_accepted_license":"1","publication_identifier":{"issn":["2198-3844","2198-3844"]},"main_file_link":[{"url":"https://doi.org/10.1002/advs.202104508","open_access":"1"}],"doi":"10.1002/advs.202104508","author":[{"last_name":"Reineke Matsudo","full_name":"Reineke Matsudo, Bernhard","first_name":"Bernhard"},{"full_name":"Sain, Basudeb","last_name":"Sain","first_name":"Basudeb"},{"full_name":"Carletti, Luca","last_name":"Carletti","first_name":"Luca"},{"first_name":"Xue","full_name":"Zhang, Xue","last_name":"Zhang"},{"last_name":"Gao","full_name":"Gao, Wenlong","first_name":"Wenlong"},{"full_name":"Angelis, Costantino","last_name":"Angelis","first_name":"Costantino"},{"first_name":"Lingling","last_name":"Huang","full_name":"Huang, Lingling"},{"first_name":"Thomas","last_name":"Zentgraf","orcid":"0000-0002-8662-1101","id":"30525","full_name":"Zentgraf, Thomas"}],"volume":9,"date_updated":"2022-04-25T13:04:44Z","oa":"1","file":[{"file_name":"2022_ACSPhotonics_NonlinearChiral_Arxiv.pdf","file_id":"30196","access_level":"closed","file_size":1001422,"date_created":"2022-03-03T07:23:15Z","creator":"zentgraf","date_updated":"2022-03-03T07:23:15Z","relation":"main_file","success":1,"content_type":"application/pdf"}],"publication":"Advanced Science","language":[{"iso":"eng"}],"ddc":["530"],"keyword":["General Physics and Astronomy","General Engineering","Biochemistry","Genetics and Molecular Biology (miscellaneous)","General Materials Science","General Chemical Engineering","Medicine (miscellaneous)"],"year":"2022","issue":"12","quality_controlled":"1","title":"Efficient Frequency Conversion with Geometric Phase Control in Optical Metasurfaces","date_created":"2022-02-21T08:09:02Z","publisher":"Wiley"},{"language":[{"iso":"eng"}],"keyword":["General Physics and Astronomy","General Engineering","Biochemistry","Genetics and Molecular Biology (miscellaneous)","General Materials Science","General Chemical Engineering","Medicine (miscellaneous)"],"publication":"Advanced Science","date_created":"2022-10-20T12:23:54Z","publisher":"Wiley","title":"Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice","issue":"24","year":"2022","user_id":"84268","department":[{"_id":"633"}],"_id":"33833","type":"journal_article","status":"public","author":[{"first_name":"Sanghoon","last_name":"Kim","full_name":"Kim, Sanghoon"},{"last_name":"Pathak","full_name":"Pathak, Sachin","first_name":"Sachin"},{"full_name":"Rhim, Sonny H.","last_name":"Rhim","first_name":"Sonny H."},{"full_name":"Cha, Jongin","last_name":"Cha","first_name":"Jongin"},{"first_name":"Soyoung","last_name":"Jekal","full_name":"Jekal, Soyoung"},{"last_name":"Hong","full_name":"Hong, Soon Cheol","first_name":"Soon Cheol"},{"last_name":"Lee","full_name":"Lee, Hyun Hwi","first_name":"Hyun Hwi"},{"first_name":"Sung‐Hun","last_name":"Park","full_name":"Park, Sung‐Hun"},{"first_name":"Han‐Koo","last_name":"Lee","full_name":"Lee, Han‐Koo"},{"first_name":"Jae‐Hoon","last_name":"Park","full_name":"Park, Jae‐Hoon"},{"full_name":"Lee, Soogil","last_name":"Lee","first_name":"Soogil"},{"orcid":"0000-0001-6373-0877","last_name":"Steinrück","id":"84268","full_name":"Steinrück, Hans-Georg","first_name":"Hans-Georg"},{"first_name":"Apurva","last_name":"Mehta","full_name":"Mehta, Apurva"},{"first_name":"Shan X.","full_name":"Wang, Shan X.","last_name":"Wang"},{"first_name":"Jongill","last_name":"Hong","full_name":"Hong, Jongill"}],"volume":9,"date_updated":"2022-10-20T12:25:35Z","doi":"10.1002/advs.202201749","publication_status":"published","publication_identifier":{"issn":["2198-3844","2198-3844"]},"citation":{"ieee":"S. Kim <i>et al.</i>, “Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice,” <i>Advanced Science</i>, vol. 9, no. 24, p. 2201749, 2022, doi: <a href=\"https://doi.org/10.1002/advs.202201749\">10.1002/advs.202201749</a>.","chicago":"Kim, Sanghoon, Sachin Pathak, Sonny H. Rhim, Jongin Cha, Soyoung Jekal, Soon Cheol Hong, Hyun Hwi Lee, et al. “Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice.” <i>Advanced Science</i> 9, no. 24 (2022): 2201749. <a href=\"https://doi.org/10.1002/advs.202201749\">https://doi.org/10.1002/advs.202201749</a>.","ama":"Kim S, Pathak S, Rhim SH, et al. Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice. <i>Advanced Science</i>. 2022;9(24):2201749. doi:<a href=\"https://doi.org/10.1002/advs.202201749\">10.1002/advs.202201749</a>","apa":"Kim, S., Pathak, S., Rhim, S. H., Cha, J., Jekal, S., Hong, S. C., Lee, H. H., Park, S., Lee, H., Park, J., Lee, S., Steinrück, H.-G., Mehta, A., Wang, S. X., &#38; Hong, J. (2022). Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice. <i>Advanced Science</i>, <i>9</i>(24), 2201749. <a href=\"https://doi.org/10.1002/advs.202201749\">https://doi.org/10.1002/advs.202201749</a>","short":"S. Kim, S. Pathak, S.H. Rhim, J. Cha, S. Jekal, S.C. Hong, H.H. Lee, S. Park, H. Lee, J. Park, S. Lee, H.-G. Steinrück, A. Mehta, S.X. Wang, J. Hong, Advanced Science 9 (2022) 2201749.","mla":"Kim, Sanghoon, et al. “Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice.” <i>Advanced Science</i>, vol. 9, no. 24, Wiley, 2022, p. 2201749, doi:<a href=\"https://doi.org/10.1002/advs.202201749\">10.1002/advs.202201749</a>.","bibtex":"@article{Kim_Pathak_Rhim_Cha_Jekal_Hong_Lee_Park_Lee_Park_et al._2022, title={Giant Orbital Anisotropy with Strong Spin–Orbit Coupling Established at the Pseudomorphic Interface of the Co/Pd Superlattice}, volume={9}, DOI={<a href=\"https://doi.org/10.1002/advs.202201749\">10.1002/advs.202201749</a>}, number={24}, journal={Advanced Science}, publisher={Wiley}, author={Kim, Sanghoon and Pathak, Sachin and Rhim, Sonny H. and Cha, Jongin and Jekal, Soyoung and Hong, Soon Cheol and Lee, Hyun Hwi and Park, Sung‐Hun and Lee, Han‐Koo and Park, Jae‐Hoon and et al.}, year={2022}, pages={2201749} }"},"page":"2201749","intvolume":"         9"},{"language":[{"iso":"eng"}],"keyword":["General Physics and Astronomy","General Engineering","Biochemistry","Genetics and Molecular Biology (miscellaneous)","General Materials Science","General Chemical Engineering","Medicine (miscellaneous)"],"article_number":"2203588","department":[{"_id":"15"},{"_id":"170"},{"_id":"297"},{"_id":"705"},{"_id":"230"},{"_id":"429"},{"_id":"35"}],"user_id":"16199","_id":"33080","project":[{"name":"TRR 142: TRR 142","_id":"53"},{"name":"TRR 142 - A: TRR 142 - Project Area A","_id":"54"},{"name":"TRR 142 - A4: TRR 142 - Subproject A4","_id":"61"},{"name":"TRR 142: Maßgeschneiderte nichtlineare Photonik: Von grundlegenden Konzepten zu funktionellen Strukturen","_id":"53"}],"status":"public","publication":"Advanced Science","type":"journal_article","doi":"10.1002/advs.202203588","title":"Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity","volume":9,"date_created":"2022-08-22T19:05:04Z","author":[{"full_name":"Long, Teng","last_name":"Long","first_name":"Teng"},{"first_name":"Xuekai","id":"59416","full_name":"Ma, Xuekai","last_name":"Ma"},{"first_name":"Jiahuan","last_name":"Ren","full_name":"Ren, Jiahuan"},{"first_name":"Feng","last_name":"Li","full_name":"Li, Feng"},{"full_name":"Liao, Qing","last_name":"Liao","first_name":"Qing"},{"full_name":"Schumacher, Stefan","id":"27271","last_name":"Schumacher","orcid":"0000-0003-4042-4951","first_name":"Stefan"},{"full_name":"Malpuech, Guillaume","last_name":"Malpuech","first_name":"Guillaume"},{"first_name":"Dmitry","full_name":"Solnyshkov, Dmitry","last_name":"Solnyshkov"},{"full_name":"Fu, Hongbing","last_name":"Fu","first_name":"Hongbing"}],"date_updated":"2025-12-05T13:56:26Z","publisher":"Wiley","intvolume":"         9","citation":{"apa":"Long, T., Ma, X., Ren, J., Li, F., Liao, Q., Schumacher, S., Malpuech, G., Solnyshkov, D., &#38; Fu, H. (2022). Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity. <i>Advanced Science</i>, <i>9</i>(29), Article 2203588. <a href=\"https://doi.org/10.1002/advs.202203588\">https://doi.org/10.1002/advs.202203588</a>","mla":"Long, Teng, et al. “Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity.” <i>Advanced Science</i>, vol. 9, no. 29, 2203588, Wiley, 2022, doi:<a href=\"https://doi.org/10.1002/advs.202203588\">10.1002/advs.202203588</a>.","short":"T. Long, X. Ma, J. Ren, F. Li, Q. Liao, S. Schumacher, G. Malpuech, D. Solnyshkov, H. Fu, Advanced Science 9 (2022).","bibtex":"@article{Long_Ma_Ren_Li_Liao_Schumacher_Malpuech_Solnyshkov_Fu_2022, title={Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity}, volume={9}, DOI={<a href=\"https://doi.org/10.1002/advs.202203588\">10.1002/advs.202203588</a>}, number={292203588}, journal={Advanced Science}, publisher={Wiley}, author={Long, Teng and Ma, Xuekai and Ren, Jiahuan and Li, Feng and Liao, Qing and Schumacher, Stefan and Malpuech, Guillaume and Solnyshkov, Dmitry and Fu, Hongbing}, year={2022} }","ieee":"T. Long <i>et al.</i>, “Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity,” <i>Advanced Science</i>, vol. 9, no. 29, Art. no. 2203588, 2022, doi: <a href=\"https://doi.org/10.1002/advs.202203588\">10.1002/advs.202203588</a>.","chicago":"Long, Teng, Xuekai Ma, Jiahuan Ren, Feng Li, Qing Liao, Stefan Schumacher, Guillaume Malpuech, Dmitry Solnyshkov, and Hongbing Fu. “Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity.” <i>Advanced Science</i> 9, no. 29 (2022). <a href=\"https://doi.org/10.1002/advs.202203588\">https://doi.org/10.1002/advs.202203588</a>.","ama":"Long T, Ma X, Ren J, et al. Helical Polariton Lasing from Topological Valleys in an Organic Crystalline Microcavity. <i>Advanced Science</i>. 2022;9(29). doi:<a href=\"https://doi.org/10.1002/advs.202203588\">10.1002/advs.202203588</a>"},"year":"2022","issue":"29","publication_identifier":{"issn":["2198-3844","2198-3844"]},"publication_status":"published"},{"type":"journal_article","publication":"Advanced Science","status":"public","user_id":"98120","_id":"40577","language":[{"iso":"eng"}],"article_number":"2001767","keyword":["General Physics and Astronomy","General Engineering","Biochemistry","Genetics and Molecular Biology (miscellaneous)","General Materials Science","General Chemical Engineering","Medicine (miscellaneous)"],"issue":"24","publication_status":"published","publication_identifier":{"issn":["2198-3844","2198-3844"]},"citation":{"ama":"Tian Z, Lopez Salas N, Liu C, Liu T, Antonietti M. C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties. <i>Advanced Science</i>. 2020;7(24). doi:<a href=\"https://doi.org/10.1002/advs.202001767\">10.1002/advs.202001767</a>","ieee":"Z. Tian, N. Lopez Salas, C. Liu, T. Liu, and M. Antonietti, “C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties,” <i>Advanced Science</i>, vol. 7, no. 24, Art. no. 2001767, 2020, doi: <a href=\"https://doi.org/10.1002/advs.202001767\">10.1002/advs.202001767</a>.","chicago":"Tian, Zhihong, Nieves Lopez Salas, Chuntai Liu, Tianxi Liu, and Markus Antonietti. “C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties.” <i>Advanced Science</i> 7, no. 24 (2020). <a href=\"https://doi.org/10.1002/advs.202001767\">https://doi.org/10.1002/advs.202001767</a>.","short":"Z. Tian, N. Lopez Salas, C. Liu, T. Liu, M. Antonietti, Advanced Science 7 (2020).","mla":"Tian, Zhihong, et al. “C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties.” <i>Advanced Science</i>, vol. 7, no. 24, 2001767, Wiley, 2020, doi:<a href=\"https://doi.org/10.1002/advs.202001767\">10.1002/advs.202001767</a>.","bibtex":"@article{Tian_Lopez Salas_Liu_Liu_Antonietti_2020, title={C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties}, volume={7}, DOI={<a href=\"https://doi.org/10.1002/advs.202001767\">10.1002/advs.202001767</a>}, number={242001767}, journal={Advanced Science}, publisher={Wiley}, author={Tian, Zhihong and Lopez Salas, Nieves and Liu, Chuntai and Liu, Tianxi and Antonietti, Markus}, year={2020} }","apa":"Tian, Z., Lopez Salas, N., Liu, C., Liu, T., &#38; Antonietti, M. (2020). C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties. <i>Advanced Science</i>, <i>7</i>(24), Article 2001767. <a href=\"https://doi.org/10.1002/advs.202001767\">https://doi.org/10.1002/advs.202001767</a>"},"intvolume":"         7","year":"2020","author":[{"full_name":"Tian, Zhihong","last_name":"Tian","first_name":"Zhihong"},{"orcid":"https://orcid.org/0000-0002-8438-9548","last_name":"Lopez Salas","id":"98120","full_name":"Lopez Salas, Nieves","first_name":"Nieves"},{"first_name":"Chuntai","full_name":"Liu, Chuntai","last_name":"Liu"},{"first_name":"Tianxi","full_name":"Liu, Tianxi","last_name":"Liu"},{"first_name":"Markus","full_name":"Antonietti, Markus","last_name":"Antonietti"}],"date_created":"2023-01-27T16:21:09Z","volume":7,"date_updated":"2023-01-27T16:29:57Z","publisher":"Wiley","doi":"10.1002/advs.202001767","title":"C            <sub>2</sub>            N: A Class of Covalent Frameworks with Unique Properties"}]
