[{"year":"2020","title":"High cycle life all-solid-state fluoride ion battery with La<sub>2</sub>NiO<sub>4+d</sub> high voltage cathode","author":[{"first_name":"Mohammad Ali","last_name":"Nowroozi","full_name":"Nowroozi, Mohammad Ali"},{"full_name":"Wissel, Kerstin","last_name":"Wissel","first_name":"Kerstin"},{"full_name":"Donzelli, Manuel","first_name":"Manuel","last_name":"Donzelli"},{"last_name":"Hosseinpourkahvaz","first_name":"Niloofar","full_name":"Hosseinpourkahvaz, Niloofar"},{"first_name":"Sergi","last_name":"Plana-Ruiz","full_name":"Plana-Ruiz, Sergi"},{"last_name":"Kolb","first_name":"Ute","full_name":"Kolb, Ute"},{"first_name":"Roland","last_name":"Schoch","orcid":"0000-0003-2061-7289","full_name":"Schoch, Roland","id":"48467"},{"last_name":"Bauer","first_name":"Matthias","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241"},{"last_name":"Malik","first_name":"Ali Muhammad","full_name":"Malik, Ali Muhammad"},{"first_name":"Jochen","last_name":"Rohrer","full_name":"Rohrer, Jochen"},{"first_name":"Sergei","last_name":"Ivlev","full_name":"Ivlev, Sergei"},{"full_name":"Kraus, Florian","last_name":"Kraus","first_name":"Florian"},{"full_name":"Clemens, Oliver","last_name":"Clemens","first_name":"Oliver"}],"publication_identifier":{"issn":["2662-4443"]},"publication_status":"published","date_updated":"2026-09-23T13:45:49Z","intvolume":"         1","article_number":"27","language":[{"iso":"eng"}],"doi":"10.1038/s43246-020-0030-5","issue":"1","publication":"Communications Materials","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>Fluoride ion batteries (FIBs) are a recent alternative all-solid-state battery technology. However, the FIB systems proposed so far suffer from poor cycling performance. In this work, we report La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> with a Ruddlesden-Popper type structure as an intercalation-based active cathode material in all solid-state FIB with excellent cycling performance. The critical charging conditions to maintain the conductivity of the cell were determined, which seems to be a major obstacle towards improving the cycling stability of FIBs. For optimized operating conditions, a cycle life of about 60 cycles and over 220 cycles for critical cut-off capacities of 50 mAh/g and 30 mAh/g, respectively, could be achieved, with average Coulombic efficiencies between 95 – 99%. Cycling of the cell is a result of fluorination/de-fluorination into and from the La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> cathode, and it is revealed that La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> is a multivalent electrode material. Our findings suggest that La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> is a promising high energy cathode for FIBs.</jats:p>","lang":"eng"}],"date_created":"2023-01-30T17:49:27Z","type":"journal_article","keyword":["Mechanics of Materials","General Materials Science"],"department":[{"_id":"35"},{"_id":"306"}],"status":"public","_id":"41027","publisher":"Springer Science and Business Media LLC","user_id":"14972","volume":1,"citation":{"chicago":"Nowroozi, Mohammad Ali, Kerstin Wissel, Manuel Donzelli, Niloofar Hosseinpourkahvaz, Sergi Plana-Ruiz, Ute Kolb, Roland Schoch, et al. “High Cycle Life All-Solid-State Fluoride Ion Battery with La<sub>2</sub>NiO<sub>4+d</sub> High Voltage Cathode.” <i>Communications Materials</i> 1, no. 1 (2020). <a href=\"https://doi.org/10.1038/s43246-020-0030-5\">https://doi.org/10.1038/s43246-020-0030-5</a>.","short":"M.A. Nowroozi, K. Wissel, M. Donzelli, N. Hosseinpourkahvaz, S. Plana-Ruiz, U. Kolb, R. Schoch, M. Bauer, A.M. Malik, J. Rohrer, S. Ivlev, F. Kraus, O. Clemens, Communications Materials 1 (2020).","apa":"Nowroozi, M. A., Wissel, K., Donzelli, M., Hosseinpourkahvaz, N., Plana-Ruiz, S., Kolb, U., Schoch, R., Bauer, M., Malik, A. M., Rohrer, J., Ivlev, S., Kraus, F., &#38; Clemens, O. (2020). High cycle life all-solid-state fluoride ion battery with La<sub>2</sub>NiO<sub>4+d</sub> high voltage cathode. <i>Communications Materials</i>, <i>1</i>(1), Article 27. <a href=\"https://doi.org/10.1038/s43246-020-0030-5\">https://doi.org/10.1038/s43246-020-0030-5</a>","ieee":"M. A. Nowroozi <i>et al.</i>, “High cycle life all-solid-state fluoride ion battery with La<sub>2</sub>NiO<sub>4+d</sub> high voltage cathode,” <i>Communications Materials</i>, vol. 1, no. 1, Art. no. 27, 2020, doi: <a href=\"https://doi.org/10.1038/s43246-020-0030-5\">10.1038/s43246-020-0030-5</a>.","ama":"Nowroozi MA, Wissel K, Donzelli M, et al. High cycle life all-solid-state fluoride ion battery with La<sub>2</sub>NiO<sub>4+d</sub> high voltage cathode. <i>Communications Materials</i>. 2020;1(1). doi:<a href=\"https://doi.org/10.1038/s43246-020-0030-5\">10.1038/s43246-020-0030-5</a>","bibtex":"@article{Nowroozi_Wissel_Donzelli_Hosseinpourkahvaz_Plana-Ruiz_Kolb_Schoch_Bauer_Malik_Rohrer_et al._2020, title={High cycle life all-solid-state fluoride ion battery with La<sub>2</sub>NiO<sub>4+d</sub> high voltage cathode}, volume={1}, DOI={<a href=\"https://doi.org/10.1038/s43246-020-0030-5\">10.1038/s43246-020-0030-5</a>}, number={127}, journal={Communications Materials}, publisher={Springer Science and Business Media LLC}, author={Nowroozi, Mohammad Ali and Wissel, Kerstin and Donzelli, Manuel and Hosseinpourkahvaz, Niloofar and Plana-Ruiz, Sergi and Kolb, Ute and Schoch, Roland and Bauer, Matthias and Malik, Ali Muhammad and Rohrer, Jochen and et al.}, year={2020} }","mla":"Nowroozi, Mohammad Ali, et al. “High Cycle Life All-Solid-State Fluoride Ion Battery with La<sub>2</sub>NiO<sub>4+d</sub> High Voltage Cathode.” <i>Communications Materials</i>, vol. 1, no. 1, 27, Springer Science and Business Media LLC, 2020, doi:<a href=\"https://doi.org/10.1038/s43246-020-0030-5\">10.1038/s43246-020-0030-5</a>."}}]