---
_id: '41027'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>Fluoride ion batteries (FIBs) are
    a recent alternative all-solid-state battery technology. However, the FIB systems
    proposed so far suffer from poor cycling performance. In this work, we report
    La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> with a Ruddlesden-Popper
    type structure as an intercalation-based active cathode material in all solid-state
    FIB with excellent cycling performance. The critical charging conditions to maintain
    the conductivity of the cell were determined, which seems to be a major obstacle
    towards improving the cycling stability of FIBs. For optimized operating conditions,
    a cycle life of about 60 cycles and over 220 cycles for critical cut-off capacities
    of 50 mAh/g and 30 mAh/g, respectively, could be achieved, with average Coulombic
    efficiencies between 95 – 99%. Cycling of the cell is a result of fluorination/de-fluorination
    into and from the La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> cathode,
    and it is revealed that La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> is
    a multivalent electrode material. Our findings suggest that La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub>
    is a promising high energy cathode for FIBs.</jats:p>
article_number: '27'
author:
- first_name: Mohammad Ali
  full_name: Nowroozi, Mohammad Ali
  last_name: Nowroozi
- first_name: Kerstin
  full_name: Wissel, Kerstin
  last_name: Wissel
- first_name: Manuel
  full_name: Donzelli, Manuel
  last_name: Donzelli
- first_name: Niloofar
  full_name: Hosseinpourkahvaz, Niloofar
  last_name: Hosseinpourkahvaz
- first_name: Sergi
  full_name: Plana-Ruiz, Sergi
  last_name: Plana-Ruiz
- first_name: Ute
  full_name: Kolb, Ute
  last_name: Kolb
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
- first_name: Ali Muhammad
  full_name: Malik, Ali Muhammad
  last_name: Malik
- first_name: Jochen
  full_name: Rohrer, Jochen
  last_name: Rohrer
- first_name: Sergei
  full_name: Ivlev, Sergei
  last_name: Ivlev
- first_name: Florian
  full_name: Kraus, Florian
  last_name: Kraus
- first_name: Oliver
  full_name: Clemens, Oliver
  last_name: Clemens
citation:
  ama: Nowroozi MA, Wissel K, Donzelli M, et al. High cycle life all-solid-state fluoride
    ion battery with La&#60;jats:sub&#62;2&#60;/jats:sub&#62;NiO&#60;jats:sub&#62;4+d&#60;/jats:sub&#62;
    high voltage cathode. <i>Communications Materials</i>. 2020;1(1). doi:<a href="https://doi.org/10.1038/s43246-020-0030-5">10.1038/s43246-020-0030-5</a>
  apa: Nowroozi, M. A., Wissel, K., Donzelli, M., Hosseinpourkahvaz, N., Plana-Ruiz,
    S., Kolb, U., Schoch, R., Bauer, M., Malik, A. M., Rohrer, J., Ivlev, S., Kraus,
    F., &#38; Clemens, O. (2020). High cycle life all-solid-state fluoride ion battery
    with La&#60;jats:sub&#62;2&#60;/jats:sub&#62;NiO&#60;jats:sub&#62;4+d&#60;/jats:sub&#62;
    high voltage cathode. <i>Communications Materials</i>, <i>1</i>(1), Article 27.
    <a href="https://doi.org/10.1038/s43246-020-0030-5">https://doi.org/10.1038/s43246-020-0030-5</a>
  bibtex: '@article{Nowroozi_Wissel_Donzelli_Hosseinpourkahvaz_Plana-Ruiz_Kolb_Schoch_Bauer_Malik_Rohrer_et
    al._2020, title={High cycle life all-solid-state fluoride ion battery with La&#60;jats:sub&#62;2&#60;/jats:sub&#62;NiO&#60;jats:sub&#62;4+d&#60;/jats:sub&#62;
    high voltage cathode}, volume={1}, DOI={<a href="https://doi.org/10.1038/s43246-020-0030-5">10.1038/s43246-020-0030-5</a>},
    number={127}, journal={Communications Materials}, publisher={Springer Science
    and Business Media LLC}, author={Nowroozi, Mohammad Ali and Wissel, Kerstin and
    Donzelli, Manuel and Hosseinpourkahvaz, Niloofar and Plana-Ruiz, Sergi and Kolb,
    Ute and Schoch, Roland and Bauer, Matthias and Malik, Ali Muhammad and Rohrer,
    Jochen and et al.}, year={2020} }'
  chicago: Nowroozi, Mohammad Ali, Kerstin Wissel, Manuel Donzelli, Niloofar Hosseinpourkahvaz,
    Sergi Plana-Ruiz, Ute Kolb, Roland Schoch, et al. “High Cycle Life All-Solid-State
    Fluoride Ion Battery with La&#60;jats:Sub&#62;2&#60;/Jats:Sub&#62;NiO&#60;jats:Sub&#62;4+d&#60;/Jats:Sub&#62;
    High Voltage Cathode.” <i>Communications Materials</i> 1, no. 1 (2020). <a href="https://doi.org/10.1038/s43246-020-0030-5">https://doi.org/10.1038/s43246-020-0030-5</a>.
  ieee: 'M. A. Nowroozi <i>et al.</i>, “High cycle life all-solid-state fluoride ion
    battery with La&#60;jats:sub&#62;2&#60;/jats:sub&#62;NiO&#60;jats:sub&#62;4+d&#60;/jats:sub&#62;
    high voltage cathode,” <i>Communications Materials</i>, vol. 1, no. 1, Art. no.
    27, 2020, doi: <a href="https://doi.org/10.1038/s43246-020-0030-5">10.1038/s43246-020-0030-5</a>.'
  mla: Nowroozi, Mohammad Ali, et al. “High Cycle Life All-Solid-State Fluoride Ion
    Battery with La&#60;jats:Sub&#62;2&#60;/Jats:Sub&#62;NiO&#60;jats:Sub&#62;4+d&#60;/Jats:Sub&#62;
    High Voltage Cathode.” <i>Communications Materials</i>, vol. 1, no. 1, 27, Springer
    Science and Business Media LLC, 2020, doi:<a href="https://doi.org/10.1038/s43246-020-0030-5">10.1038/s43246-020-0030-5</a>.
  short: M.A. Nowroozi, K. Wissel, M. Donzelli, N. Hosseinpourkahvaz, S. Plana-Ruiz,
    U. Kolb, R. Schoch, M. Bauer, A.M. Malik, J. Rohrer, S. Ivlev, F. Kraus, O. Clemens,
    Communications Materials 1 (2020).
date_created: 2023-01-30T17:49:27Z
date_updated: 2023-01-31T07:45:41Z
department:
- _id: '35'
- _id: '306'
doi: 10.1038/s43246-020-0030-5
intvolume: '         1'
issue: '1'
keyword:
- Mechanics of Materials
- General Materials Science
language:
- iso: eng
publication: Communications Materials
publication_identifier:
  issn:
  - 2662-4443
publication_status: published
publisher: Springer Science and Business Media LLC
status: public
title: High cycle life all-solid-state fluoride ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub>
  high voltage cathode
type: journal_article
user_id: '48467'
volume: 1
year: '2020'
...