[{"date_created":"2025-09-17T15:16:49Z","keyword":["T2","T","CSSD"],"type":"journal_article","department":[{"_id":"2"},{"_id":"389"}],"publication":"Advanced Synthesis and Catalysis","citation":{"ieee":"V. Medvaric, J. Paradies, and T. Werner, “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides,” <i>Advanced Synthesis and Catalysis</i>, Art. no. 202500394, 2025, doi: <a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>.","apa":"Medvaric, V., Paradies, J., &#38; Werner, T. (2025). Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis and Catalysis</i>, Article 202500394. <a href=\"https://doi.org/10.1002/adsc.70059\">https://doi.org/10.1002/adsc.70059</a>","short":"V. Medvaric, J. Paradies, T. Werner, Advanced Synthesis and Catalysis (2025).","chicago":"Medvaric, Viktorija, Jan Paradies, and Thomas Werner. “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis and Catalysis</i>, 2025. <a href=\"https://doi.org/10.1002/adsc.70059\">https://doi.org/10.1002/adsc.70059</a>.","mla":"Medvaric, Viktorija, et al. “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis and Catalysis</i>, 202500394, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>.","bibtex":"@article{Medvaric_Paradies_Werner_2025, title={Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides}, DOI={<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>}, number={202500394}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Medvaric, Viktorija and Paradies, Jan and Werner, Thomas}, year={2025} }","ama":"Medvaric V, Paradies J, Werner T. Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis and Catalysis</i>. Published online 2025. doi:<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>"},"abstract":[{"text":"<jats:p>Amidines are a ubiquitous class of bioactive compounds found in a wide variety of natural products; thus, efficient strategies for their preparation are in great demand. Herein, a novel protocol is reported for the synthesis of amidines based on P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O redox catalysis. This two‐step, one‐pot approach involves the activation of amides via P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O catalyzed in situ formation of imidoyl chloride intermediates which are directly converted upon reaction with amines into the corresponding amidines. Instead of traditionally used toxic and corrosive chloride sources, hexachloroacetone (HCA) is successfully employed as a halide source. The reaction proceeds with low catalyst loading (2 mol%) in BuOAc as the solvent. Under the optimized conditions, 20 amidines are prepared in yields up to 99%. A feasible mechanism is proposed based on experimental results. The synthetic potential of this method is evaluated in the preparation of the tyrosine kinase inhibitor (TKI) Erlotinib.</jats:p>","lang":"eng"}],"article_number":"202500394","publisher":"Wiley","_id":"61335","language":[{"iso":"eng"}],"user_id":"89271","doi":"10.1002/adsc.70059","title":"Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides","year":"2025","status":"public","author":[{"id":"92677","full_name":"Medvaric, Viktorija","first_name":"Viktorija","last_name":"Medvaric"},{"full_name":"Paradies, Jan","first_name":"Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","id":"53339"},{"full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","id":"89271"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"publication_status":"published","date_updated":"2025-11-10T08:44:04Z"},{"volume":90,"user_id":"89271","_id":"62086","publisher":"American Chemical Society (ACS)","page":"12877-12887","status":"public","citation":{"apa":"Stefanow, V., Kell, L., Leduskrasta, A., Eh, M., Panten, J., &#38; Werner, T. (2025). Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients. <i>The Journal of Organic Chemistry</i>, <i>90</i>(37), 12877–12887. <a href=\"https://doi.org/10.1021/acs.joc.5c00889\">https://doi.org/10.1021/acs.joc.5c00889</a>","ieee":"V. Stefanow, L. Kell, A. Leduskrasta, M. Eh, J. Panten, and T. Werner, “Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients,” <i>The Journal of Organic Chemistry</i>, vol. 90, no. 37, pp. 12877–12887, 2025, doi: <a href=\"https://doi.org/10.1021/acs.joc.5c00889\">10.1021/acs.joc.5c00889</a>.","chicago":"Stefanow, Vivian, Lukas Kell, Aiga Leduskrasta, Marcus Eh, Johannes Panten, and Thomas Werner. “Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients.” <i>The Journal of Organic Chemistry</i> 90, no. 37 (2025): 12877–87. <a href=\"https://doi.org/10.1021/acs.joc.5c00889\">https://doi.org/10.1021/acs.joc.5c00889</a>.","short":"V. Stefanow, L. Kell, A. Leduskrasta, M. Eh, J. Panten, T. Werner, The Journal of Organic Chemistry 90 (2025) 12877–12887.","mla":"Stefanow, Vivian, et al. “Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients.” <i>The Journal of Organic Chemistry</i>, vol. 90, no. 37, American Chemical Society (ACS), 2025, pp. 12877–87, doi:<a href=\"https://doi.org/10.1021/acs.joc.5c00889\">10.1021/acs.joc.5c00889</a>.","ama":"Stefanow V, Kell L, Leduskrasta A, Eh M, Panten J, Werner T. Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients. <i>The Journal of Organic Chemistry</i>. 2025;90(37):12877-12887. doi:<a href=\"https://doi.org/10.1021/acs.joc.5c00889\">10.1021/acs.joc.5c00889</a>","bibtex":"@article{Stefanow_Kell_Leduskrasta_Eh_Panten_Werner_2025, title={Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients}, volume={90}, DOI={<a href=\"https://doi.org/10.1021/acs.joc.5c00889\">10.1021/acs.joc.5c00889</a>}, number={37}, journal={The Journal of Organic Chemistry}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Kell, Lukas and Leduskrasta, Aiga and Eh, Marcus and Panten, Johannes and Werner, Thomas}, year={2025}, pages={12877–12887} }"},"doi":"10.1021/acs.joc.5c00889","language":[{"iso":"eng"}],"intvolume":"        90","publication_status":"published","date_updated":"2025-11-10T08:43:33Z","publication_identifier":{"issn":["0022-3263","1520-6904"]},"author":[{"first_name":"Vivian","last_name":"Stefanow","full_name":"Stefanow, Vivian"},{"full_name":"Kell, Lukas","last_name":"Kell","first_name":"Lukas"},{"full_name":"Leduskrasta, Aiga","last_name":"Leduskrasta","first_name":"Aiga"},{"first_name":"Marcus","last_name":"Eh","full_name":"Eh, Marcus"},{"full_name":"Panten, Johannes","last_name":"Panten","first_name":"Johannes"},{"id":"89271","last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas","full_name":"Werner, Thomas"}],"year":"2025","title":"Straightforward Access to Terpene-Based 1,2-Diols and Their Acetals as Fragrance Ingredients","department":[{"_id":"35"},{"_id":"2"}],"keyword":["T4","CSSD"],"type":"journal_article","date_created":"2025-11-05T15:10:13Z","issue":"37","publication":"The Journal of Organic Chemistry"},{"publication_identifier":{"issn":["0002-7863","1520-5126"]},"author":[{"full_name":"Zhou, Rundong","first_name":"Rundong","last_name":"Zhou"},{"id":"92677","full_name":"Medvaric, Viktorija","last_name":"Medvaric","first_name":"Viktorija"},{"id":"89271","full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner","orcid":"https://orcid.org/0000-0001-9025-3244"},{"orcid":"0000-0002-3698-668X","first_name":"Jan","last_name":"Paradies","full_name":"Paradies, Jan","id":"53339"}],"year":"2025","status":"public","title":"Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance","publication_status":"published","date_updated":"2025-11-10T08:43:50Z","language":[{"iso":"eng"}],"_id":"61336","publisher":"American Chemical Society (ACS)","article_number":"jacs.5c06190","user_id":"89271","doi":"10.1021/jacs.5c06190","citation":{"chicago":"Zhou, Rundong, Viktorija Medvaric, Thomas Werner, and Jan Paradies. “Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance.” <i>Journal of the American Chemical Society</i>, 2025. <a href=\"https://doi.org/10.1021/jacs.5c06190\">https://doi.org/10.1021/jacs.5c06190</a>.","short":"R. Zhou, V. Medvaric, T. Werner, J. Paradies, Journal of the American Chemical Society (2025).","ieee":"R. Zhou, V. Medvaric, T. Werner, and J. Paradies, “Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance,” <i>Journal of the American Chemical Society</i>, Art. no. jacs. 5c06190, 2025, doi: <a href=\"https://doi.org/10.1021/jacs.5c06190\">10.1021/jacs.5c06190</a>.","apa":"Zhou, R., Medvaric, V., Werner, T., &#38; Paradies, J. (2025). Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance. <i>Journal of the American Chemical Society</i>, Article jacs. 5c06190. <a href=\"https://doi.org/10.1021/jacs.5c06190\">https://doi.org/10.1021/jacs.5c06190</a>","bibtex":"@article{Zhou_Medvaric_Werner_Paradies_2025, title={Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance}, DOI={<a href=\"https://doi.org/10.1021/jacs.5c06190\">10.1021/jacs.5c06190</a>}, number={jacs. 5c06190}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Zhou, Rundong and Medvaric, Viktorija and Werner, Thomas and Paradies, Jan}, year={2025} }","ama":"Zhou R, Medvaric V, Werner T, Paradies J. Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance. <i>Journal of the American Chemical Society</i>. Published online 2025. doi:<a href=\"https://doi.org/10.1021/jacs.5c06190\">10.1021/jacs.5c06190</a>","mla":"Zhou, Rundong, et al. “Metal-Free Reduction of Nitrous Oxide via P<sup>III</sup>/P<sup>V</sup>═O Cycling: Mechanistic Insights and Catalytic Performance.” <i>Journal of the American Chemical Society</i>, jacs. 5c06190, American Chemical Society (ACS), 2025, doi:<a href=\"https://doi.org/10.1021/jacs.5c06190\">10.1021/jacs.5c06190</a>."},"publication":"Journal of the American Chemical Society","date_created":"2025-09-17T15:18:11Z","department":[{"_id":"2"},{"_id":"389"}],"type":"journal_article","keyword":["T2","CSSD"]},{"date_created":"2025-11-05T15:16:32Z","department":[{"_id":"35"},{"_id":"2"}],"keyword":["T1","T2","CSSD"],"type":"journal_article","publication":"Green Chemistry","issue":"1","abstract":[{"lang":"eng","text":"<jats:p>The selective <jats:italic>N</jats:italic>-formylation and <jats:italic>N</jats:italic>-methylation of amines with carbon dioxide (CO<jats:sub>2</jats:sub>) catalyzed by methyltriphenylphosphonium methylcarbonate and tuned by polymethylhydrosiloxane or trimethoxysilane as reducing agents is reported.</jats:p>"}],"language":[{"iso":"eng"}],"doi":"10.1039/d3gc03993e","author":[{"first_name":"Changyue","last_name":"Ren","full_name":"Ren, Changyue"},{"last_name":"Terazzi","first_name":"Constanza","full_name":"Terazzi, Constanza"},{"id":"89271","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["1463-9262","1463-9270"]},"year":"2024","title":"Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines","intvolume":"        26","publication_status":"published","date_updated":"2025-11-10T08:44:44Z","citation":{"bibtex":"@article{Ren_Terazzi_Werner_2024, title={Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines}, volume={26}, DOI={<a href=\"https://doi.org/10.1039/d3gc03993e\">10.1039/d3gc03993e</a>}, number={1}, journal={Green Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Ren, Changyue and Terazzi, Constanza and Werner, Thomas}, year={2024}, pages={439–447} }","ama":"Ren C, Terazzi C, Werner T. Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines. <i>Green Chemistry</i>. 2024;26(1):439-447. doi:<a href=\"https://doi.org/10.1039/d3gc03993e\">10.1039/d3gc03993e</a>","mla":"Ren, Changyue, et al. “Tuneable Reduction of CO<sub>2</sub> – Organocatalyzed Selective Formylation and Methylation of Amines.” <i>Green Chemistry</i>, vol. 26, no. 1, Royal Society of Chemistry (RSC), 2024, pp. 439–47, doi:<a href=\"https://doi.org/10.1039/d3gc03993e\">10.1039/d3gc03993e</a>.","short":"C. Ren, C. Terazzi, T. Werner, Green Chemistry 26 (2024) 439–447.","chicago":"Ren, Changyue, Constanza Terazzi, and Thomas Werner. “Tuneable Reduction of CO<sub>2</sub> – Organocatalyzed Selective Formylation and Methylation of Amines.” <i>Green Chemistry</i> 26, no. 1 (2024): 439–47. <a href=\"https://doi.org/10.1039/d3gc03993e\">https://doi.org/10.1039/d3gc03993e</a>.","ieee":"C. Ren, C. Terazzi, and T. Werner, “Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines,” <i>Green Chemistry</i>, vol. 26, no. 1, pp. 439–447, 2024, doi: <a href=\"https://doi.org/10.1039/d3gc03993e\">10.1039/d3gc03993e</a>.","apa":"Ren, C., Terazzi, C., &#38; Werner, T. (2024). Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines. <i>Green Chemistry</i>, <i>26</i>(1), 439–447. <a href=\"https://doi.org/10.1039/d3gc03993e\">https://doi.org/10.1039/d3gc03993e</a>"},"publisher":"Royal Society of Chemistry (RSC)","_id":"62090","page":"439-447","volume":26,"user_id":"89271","status":"public"},{"publication":"ACS Sustainable Chemistry &amp; Engineering","issue":"29","department":[{"_id":"35"},{"_id":"2"}],"keyword":["T1","T2","CSSD"],"type":"journal_article","date_created":"2025-11-05T15:17:55Z","intvolume":"        12","date_updated":"2025-11-10T08:45:58Z","publication_status":"published","author":[{"full_name":"Ren, Changyue","first_name":"Changyue","last_name":"Ren"},{"last_name":"Spannenberg","first_name":"Anke","full_name":"Spannenberg, Anke"},{"full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","id":"89271"}],"publication_identifier":{"issn":["2168-0485","2168-0485"]},"year":"2024","title":"Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>","doi":"10.1021/acssuschemeng.4c03464","language":[{"iso":"eng"}],"citation":{"mla":"Ren, Changyue, et al. “Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>.” <i>ACS Sustainable Chemistry &#38;amp; Engineering</i>, vol. 12, no. 29, American Chemical Society (ACS), 2024, pp. 10969–77, doi:<a href=\"https://doi.org/10.1021/acssuschemeng.4c03464\">10.1021/acssuschemeng.4c03464</a>.","ama":"Ren C, Spannenberg A, Werner T. Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>. <i>ACS Sustainable Chemistry &#38;amp; Engineering</i>. 2024;12(29):10969-10977. doi:<a href=\"https://doi.org/10.1021/acssuschemeng.4c03464\">10.1021/acssuschemeng.4c03464</a>","bibtex":"@article{Ren_Spannenberg_Werner_2024, title={Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>}, volume={12}, DOI={<a href=\"https://doi.org/10.1021/acssuschemeng.4c03464\">10.1021/acssuschemeng.4c03464</a>}, number={29}, journal={ACS Sustainable Chemistry &#38;amp; Engineering}, publisher={American Chemical Society (ACS)}, author={Ren, Changyue and Spannenberg, Anke and Werner, Thomas}, year={2024}, pages={10969–10977} }","apa":"Ren, C., Spannenberg, A., &#38; Werner, T. (2024). Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>. <i>ACS Sustainable Chemistry &#38;amp; Engineering</i>, <i>12</i>(29), 10969–10977. <a href=\"https://doi.org/10.1021/acssuschemeng.4c03464\">https://doi.org/10.1021/acssuschemeng.4c03464</a>","ieee":"C. Ren, A. Spannenberg, and T. Werner, “Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>,” <i>ACS Sustainable Chemistry &#38;amp; Engineering</i>, vol. 12, no. 29, pp. 10969–10977, 2024, doi: <a href=\"https://doi.org/10.1021/acssuschemeng.4c03464\">10.1021/acssuschemeng.4c03464</a>.","chicago":"Ren, Changyue, Anke Spannenberg, and Thomas Werner. “Phosphonium-Salt-Catalyzed <i>N</i>-Methylation and <i>N</i>-Formylation of Amines with CO<sub>2</sub>.” <i>ACS Sustainable Chemistry &#38;amp; Engineering</i> 12, no. 29 (2024): 10969–77. <a href=\"https://doi.org/10.1021/acssuschemeng.4c03464\">https://doi.org/10.1021/acssuschemeng.4c03464</a>.","short":"C. Ren, A. Spannenberg, T. Werner, ACS Sustainable Chemistry &#38;amp; Engineering 12 (2024) 10969–10977."},"status":"public","volume":12,"user_id":"89271","_id":"62091","publisher":"American Chemical Society (ACS)","page":"10969-10977"},{"status":"public","volume":89,"user_id":"89271","publisher":"American Chemical Society (ACS)","_id":"62088","page":"10729-10735","citation":{"bibtex":"@article{Tönjes_Medvarić_Werner_2024, title={Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis}, volume={89}, DOI={<a href=\"https://doi.org/10.1021/acs.joc.4c00985\">10.1021/acs.joc.4c00985</a>}, number={15}, journal={The Journal of Organic Chemistry}, publisher={American Chemical Society (ACS)}, author={Tönjes, Jan and Medvarić, Viktorija and Werner, Thomas}, year={2024}, pages={10729–10735} }","ama":"Tönjes J, Medvarić V, Werner T. Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis. <i>The Journal of Organic Chemistry</i>. 2024;89(15):10729-10735. doi:<a href=\"https://doi.org/10.1021/acs.joc.4c00985\">10.1021/acs.joc.4c00985</a>","mla":"Tönjes, Jan, et al. “Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis.” <i>The Journal of Organic Chemistry</i>, vol. 89, no. 15, American Chemical Society (ACS), 2024, pp. 10729–35, doi:<a href=\"https://doi.org/10.1021/acs.joc.4c00985\">10.1021/acs.joc.4c00985</a>.","chicago":"Tönjes, Jan, Viktorija Medvarić, and Thomas Werner. “Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis.” <i>The Journal of Organic Chemistry</i> 89, no. 15 (2024): 10729–35. <a href=\"https://doi.org/10.1021/acs.joc.4c00985\">https://doi.org/10.1021/acs.joc.4c00985</a>.","short":"J. Tönjes, V. Medvarić, T. Werner, The Journal of Organic Chemistry 89 (2024) 10729–10735.","ieee":"J. Tönjes, V. Medvarić, and T. Werner, “Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis,” <i>The Journal of Organic Chemistry</i>, vol. 89, no. 15, pp. 10729–10735, 2024, doi: <a href=\"https://doi.org/10.1021/acs.joc.4c00985\">10.1021/acs.joc.4c00985</a>.","apa":"Tönjes, J., Medvarić, V., &#38; Werner, T. (2024). Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis. <i>The Journal of Organic Chemistry</i>, <i>89</i>(15), 10729–10735. <a href=\"https://doi.org/10.1021/acs.joc.4c00985\">https://doi.org/10.1021/acs.joc.4c00985</a>"},"intvolume":"        89","publication_status":"published","date_updated":"2025-11-10T08:45:17Z","author":[{"full_name":"Tönjes, Jan","first_name":"Jan","last_name":"Tönjes"},{"first_name":"Viktorija","last_name":"Medvarić","full_name":"Medvarić, Viktorija"},{"first_name":"Thomas","last_name":"Werner","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["0022-3263","1520-6904"]},"year":"2024","title":"Synthesis of Trisubstituted Furans from Activated Alkenes by P(III)/P(V) Redox Cycling Catalysis","doi":"10.1021/acs.joc.4c00985","language":[{"iso":"eng"}],"publication":"The Journal of Organic Chemistry","issue":"15","department":[{"_id":"35"},{"_id":"2"}],"keyword":["T2","CSSD"],"type":"journal_article","date_created":"2025-11-05T15:12:46Z"},{"doi":"10.1002/cctc.202300917","article_number":"e202300917","language":[{"iso":"eng"}],"date_updated":"2025-11-10T08:46:22Z","publication_status":"published","intvolume":"        15","title":"Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates","year":"2023","author":[{"full_name":"Terazzi, Constanza","first_name":"Constanza","last_name":"Terazzi"},{"full_name":"Spannenberg, Anke","first_name":"Anke","last_name":"Spannenberg"},{"full_name":"von Langermann, Jan","first_name":"Jan","last_name":"von Langermann"},{"id":"89271","full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244"}],"publication_identifier":{"issn":["1867-3880","1867-3899"]},"type":"journal_article","keyword":["T1","T4","CSSD"],"department":[{"_id":"35"},{"_id":"2"}],"date_created":"2025-11-05T15:23:21Z","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>The biocatalytic kinetic resolution of cyclic carbonates derived from glycerol is reported. A selection of 26 esterases and lipases was tested for the asymmetric hydrolysis of the model substrate (epichlorohydrin carbonate) in aqueous medium. Among them, Pig Liver Esterase and Novozym® 435 showed the best selectivity with <jats:italic>E</jats:italic>=38 and 49, respectively. Both enzymes were employed for the conversion of 12 glycerol derivatives under optimized conditions. The resolution of halogenated carbonates afforded the unconverted enantiomer in up to &gt;99 : 1 <jats:italic>er</jats:italic>. Furthermore, Novozym® 435 was successfully recycled 10 times without significant loss of activity. Upscaling and isolation of the chiral carbonate was also demonstrated. Subsequent conversion of this chiral building block allowed the direct one‐pot synthesis of (<jats:italic>S</jats:italic>)‐Guaifenesin, (<jats:italic>S</jats:italic>)‐Mephenesin and (<jats:italic>S</jats:italic>)‐Chlorphenesin in up to 89 % yield and 94 : 6 <jats:italic>er</jats:italic>.</jats:p>","lang":"eng"}],"issue":"19","publication":"ChemCatChem","user_id":"89271","volume":15,"_id":"62096","publisher":"Wiley","status":"public","citation":{"ama":"Terazzi C, Spannenberg A, von Langermann J, Werner T. Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates. <i>ChemCatChem</i>. 2023;15(19). doi:<a href=\"https://doi.org/10.1002/cctc.202300917\">10.1002/cctc.202300917</a>","bibtex":"@article{Terazzi_Spannenberg_von Langermann_Werner_2023, title={Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates}, volume={15}, DOI={<a href=\"https://doi.org/10.1002/cctc.202300917\">10.1002/cctc.202300917</a>}, number={19e202300917}, journal={ChemCatChem}, publisher={Wiley}, author={Terazzi, Constanza and Spannenberg, Anke and von Langermann, Jan and Werner, Thomas}, year={2023} }","mla":"Terazzi, Constanza, et al. “Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates.” <i>ChemCatChem</i>, vol. 15, no. 19, e202300917, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202300917\">10.1002/cctc.202300917</a>.","chicago":"Terazzi, Constanza, Anke Spannenberg, Jan von Langermann, and Thomas Werner. “Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates.” <i>ChemCatChem</i> 15, no. 19 (2023). <a href=\"https://doi.org/10.1002/cctc.202300917\">https://doi.org/10.1002/cctc.202300917</a>.","short":"C. Terazzi, A. Spannenberg, J. von Langermann, T. Werner, ChemCatChem 15 (2023).","apa":"Terazzi, C., Spannenberg, A., von Langermann, J., &#38; Werner, T. (2023). Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates. <i>ChemCatChem</i>, <i>15</i>(19), Article e202300917. <a href=\"https://doi.org/10.1002/cctc.202300917\">https://doi.org/10.1002/cctc.202300917</a>","ieee":"C. Terazzi, A. Spannenberg, J. von Langermann, and T. Werner, “Chemoenzymatic Synthesis of Chiral Building Blocks Based on the Kinetic Resolution of Glycerol‐Derived Cyclic Carbonates,” <i>ChemCatChem</i>, vol. 15, no. 19, Art. no. e202300917, 2023, doi: <a href=\"https://doi.org/10.1002/cctc.202300917\">10.1002/cctc.202300917</a>."}},{"citation":{"mla":"Tönjes, Jan, et al. “Organocatalytic Stereospecific Appel Reaction.” <i>Organic Letters</i>, vol. 25, no. 51, American Chemical Society (ACS), 2023, pp. 9114–18, doi:<a href=\"https://doi.org/10.1021/acs.orglett.3c03463\">10.1021/acs.orglett.3c03463</a>.","ama":"Tönjes J, Kell L, Werner T. Organocatalytic Stereospecific Appel Reaction. <i>Organic Letters</i>. 2023;25(51):9114-9118. doi:<a href=\"https://doi.org/10.1021/acs.orglett.3c03463\">10.1021/acs.orglett.3c03463</a>","bibtex":"@article{Tönjes_Kell_Werner_2023, title={Organocatalytic Stereospecific Appel Reaction}, volume={25}, DOI={<a href=\"https://doi.org/10.1021/acs.orglett.3c03463\">10.1021/acs.orglett.3c03463</a>}, number={51}, journal={Organic Letters}, publisher={American Chemical Society (ACS)}, author={Tönjes, Jan and Kell, Lukas and Werner, Thomas}, year={2023}, pages={9114–9118} }","apa":"Tönjes, J., Kell, L., &#38; Werner, T. (2023). Organocatalytic Stereospecific Appel Reaction. <i>Organic Letters</i>, <i>25</i>(51), 9114–9118. <a href=\"https://doi.org/10.1021/acs.orglett.3c03463\">https://doi.org/10.1021/acs.orglett.3c03463</a>","ieee":"J. Tönjes, L. Kell, and T. Werner, “Organocatalytic Stereospecific Appel Reaction,” <i>Organic Letters</i>, vol. 25, no. 51, pp. 9114–9118, 2023, doi: <a href=\"https://doi.org/10.1021/acs.orglett.3c03463\">10.1021/acs.orglett.3c03463</a>.","short":"J. Tönjes, L. Kell, T. Werner, Organic Letters 25 (2023) 9114–9118.","chicago":"Tönjes, Jan, Lukas Kell, and Thomas Werner. “Organocatalytic Stereospecific Appel Reaction.” <i>Organic Letters</i> 25, no. 51 (2023): 9114–18. <a href=\"https://doi.org/10.1021/acs.orglett.3c03463\">https://doi.org/10.1021/acs.orglett.3c03463</a>."},"volume":25,"user_id":"89271","publisher":"American Chemical Society (ACS)","_id":"62095","page":"9114-9118","status":"public","department":[{"_id":"35"},{"_id":"2"}],"type":"journal_article","keyword":["T2","CSSD"],"date_created":"2025-11-05T15:22:44Z","issue":"51","publication":"Organic Letters","doi":"10.1021/acs.orglett.3c03463","language":[{"iso":"eng"}],"intvolume":"        25","date_updated":"2025-11-10T08:46:39Z","publication_status":"published","author":[{"last_name":"Tönjes","first_name":"Jan","full_name":"Tönjes, Jan"},{"last_name":"Kell","first_name":"Lukas","full_name":"Kell, Lukas"},{"id":"89271","last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["1523-7060","1523-7052"]},"year":"2023","title":"Organocatalytic Stereospecific Appel Reaction"},{"doi":"10.1021/acssuschemeng.2c03210","language":[{"iso":"eng"}],"intvolume":"        10","date_updated":"2025-11-10T08:47:07Z","publication_status":"published","publication_identifier":{"issn":["2168-0485","2168-0485"]},"author":[{"full_name":"Terazzi, Constanza","last_name":"Terazzi","first_name":"Constanza"},{"last_name":"Laatz","first_name":"Karoline","full_name":"Laatz, Karoline"},{"full_name":"von Langermann, Jan","first_name":"Jan","last_name":"von Langermann"},{"full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","id":"89271"}],"year":"2022","title":"Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution","department":[{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["T1","T3","CSSD"],"date_created":"2023-01-22T20:10:44Z","issue":"40","publication":"ACS Sustainable Chemistry and Engineering","volume":10,"user_id":"89271","_id":"37938","publisher":"American Chemical Society (ACS)","page":"13335-13342","status":"public","citation":{"mla":"Terazzi, Constanza, et al. “Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution.” <i>ACS Sustainable Chemistry and Engineering</i>, vol. 10, no. 40, American Chemical Society (ACS), 2022, pp. 13335–42, doi:<a href=\"https://doi.org/10.1021/acssuschemeng.2c03210\">10.1021/acssuschemeng.2c03210</a>.","apa":"Terazzi, C., Laatz, K., von Langermann, J., &#38; Werner, T. (2022). Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution. <i>ACS Sustainable Chemistry and Engineering</i>, <i>10</i>(40), 13335–13342. <a href=\"https://doi.org/10.1021/acssuschemeng.2c03210\">https://doi.org/10.1021/acssuschemeng.2c03210</a>","ieee":"C. Terazzi, K. Laatz, J. von Langermann, and T. Werner, “Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution,” <i>ACS Sustainable Chemistry and Engineering</i>, vol. 10, no. 40, pp. 13335–13342, 2022, doi: <a href=\"https://doi.org/10.1021/acssuschemeng.2c03210\">10.1021/acssuschemeng.2c03210</a>.","ama":"Terazzi C, Laatz K, von Langermann J, Werner T. Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution. <i>ACS Sustainable Chemistry and Engineering</i>. 2022;10(40):13335-13342. doi:<a href=\"https://doi.org/10.1021/acssuschemeng.2c03210\">10.1021/acssuschemeng.2c03210</a>","short":"C. Terazzi, K. Laatz, J. von Langermann, T. Werner, ACS Sustainable Chemistry and Engineering 10 (2022) 13335–13342.","chicago":"Terazzi, Constanza, Karoline Laatz, Jan von Langermann, and Thomas Werner. “Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution.” <i>ACS Sustainable Chemistry and Engineering</i> 10, no. 40 (2022): 13335–42. <a href=\"https://doi.org/10.1021/acssuschemeng.2c03210\">https://doi.org/10.1021/acssuschemeng.2c03210</a>.","bibtex":"@article{Terazzi_Laatz_von Langermann_Werner_2022, title={Synthesis of Cyclic Carbonates Catalyzed by CaI<sub>2</sub>–Et<sub>3</sub>N and Studies on Their Biocatalytic Kinetic Resolution}, volume={10}, DOI={<a href=\"https://doi.org/10.1021/acssuschemeng.2c03210\">10.1021/acssuschemeng.2c03210</a>}, number={40}, journal={ACS Sustainable Chemistry and Engineering}, publisher={American Chemical Society (ACS)}, author={Terazzi, Constanza and Laatz, Karoline and von Langermann, Jan and Werner, Thomas}, year={2022}, pages={13335–13342} }"}},{"status":"public","_id":"37940","publisher":"Wiley","user_id":"89271","volume":11,"citation":{"mla":"Ren, Changyue, et al. “Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>.” <i>Asian Journal of Organic Chemistry</i>, vol. 11, no. 9, Wiley, 2022, doi:<a href=\"https://doi.org/10.1002/ajoc.202200156\">10.1002/ajoc.202200156</a>.","bibtex":"@article{Ren_Spannenberg_Werner_2022, title={Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>}, volume={11}, DOI={<a href=\"https://doi.org/10.1002/ajoc.202200156\">10.1002/ajoc.202200156</a>}, number={9}, journal={Asian Journal of Organic Chemistry}, publisher={Wiley}, author={Ren, Changyue and Spannenberg, Anke and Werner, Thomas}, year={2022} }","ama":"Ren C, Spannenberg A, Werner T. Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>. <i>Asian Journal of Organic Chemistry</i>. 2022;11(9). doi:<a href=\"https://doi.org/10.1002/ajoc.202200156\">10.1002/ajoc.202200156</a>","ieee":"C. Ren, A. Spannenberg, and T. Werner, “Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>,” <i>Asian Journal of Organic Chemistry</i>, vol. 11, no. 9, 2022, doi: <a href=\"https://doi.org/10.1002/ajoc.202200156\">10.1002/ajoc.202200156</a>.","apa":"Ren, C., Spannenberg, A., &#38; Werner, T. (2022). Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>. <i>Asian Journal of Organic Chemistry</i>, <i>11</i>(9). <a href=\"https://doi.org/10.1002/ajoc.202200156\">https://doi.org/10.1002/ajoc.202200156</a>","chicago":"Ren, Changyue, Anke Spannenberg, and Thomas Werner. “Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>.” <i>Asian Journal of Organic Chemistry</i> 11, no. 9 (2022). <a href=\"https://doi.org/10.1002/ajoc.202200156\">https://doi.org/10.1002/ajoc.202200156</a>.","short":"C. Ren, A. Spannenberg, T. Werner, Asian Journal of Organic Chemistry 11 (2022)."},"year":"2022","title":"Synthesis of Bifunctional Phosphonium Salts Bearing Perfluorinated Side Chains and Their Application in the Synthesis of Cyclic Carbonates from Epoxides and CO            <sub>2</sub>","publication_identifier":{"issn":["2193-5807","2193-5815"]},"author":[{"full_name":"Ren, Changyue","last_name":"Ren","first_name":"Changyue"},{"last_name":"Spannenberg","first_name":"Anke","full_name":"Spannenberg, Anke"},{"last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271"}],"date_updated":"2025-11-10T08:47:20Z","publication_status":"published","intvolume":"        11","language":[{"iso":"eng"}],"doi":"10.1002/ajoc.202200156","issue":"9","publication":"Asian Journal of Organic Chemistry","date_created":"2023-01-22T20:19:21Z","keyword":["T1","T2","CSSD"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}]},{"page":"3545-3554","publisher":"Georg Thieme Verlag KG","_id":"37946","user_id":"89271","volume":53,"status":"public","citation":{"mla":"Werner, Thomas, et al. “Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones.” <i>Synthesis</i>, vol. 53, no. 19, Georg Thieme Verlag KG, 2021, pp. 3545–54, doi:<a href=\"https://doi.org/10.1055/a-1509-6078\">10.1055/a-1509-6078</a>.","bibtex":"@article{Werner_Grandane_Pudnika_Domraceva_Zalubovskis_2021, title={Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones}, volume={53}, DOI={<a href=\"https://doi.org/10.1055/a-1509-6078\">10.1055/a-1509-6078</a>}, number={19}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Werner, Thomas and Grandane, Aiga and Pudnika, Linda and Domraceva, Ilona and Zalubovskis, Raivis}, year={2021}, pages={3545–3554} }","ama":"Werner T, Grandane A, Pudnika L, Domraceva I, Zalubovskis R. Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones. <i>Synthesis</i>. 2021;53(19):3545-3554. doi:<a href=\"https://doi.org/10.1055/a-1509-6078\">10.1055/a-1509-6078</a>","ieee":"T. Werner, A. Grandane, L. Pudnika, I. Domraceva, and R. Zalubovskis, “Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones,” <i>Synthesis</i>, vol. 53, no. 19, pp. 3545–3554, 2021, doi: <a href=\"https://doi.org/10.1055/a-1509-6078\">10.1055/a-1509-6078</a>.","apa":"Werner, T., Grandane, A., Pudnika, L., Domraceva, I., &#38; Zalubovskis, R. (2021). Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones. <i>Synthesis</i>, <i>53</i>(19), 3545–3554. <a href=\"https://doi.org/10.1055/a-1509-6078\">https://doi.org/10.1055/a-1509-6078</a>","chicago":"Werner, Thomas, Aiga Grandane, Linda Pudnika, Ilona Domraceva, and Raivis Zalubovskis. “Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones.” <i>Synthesis</i> 53, no. 19 (2021): 3545–54. <a href=\"https://doi.org/10.1055/a-1509-6078\">https://doi.org/10.1055/a-1509-6078</a>.","short":"T. Werner, A. Grandane, L. Pudnika, I. Domraceva, R. Zalubovskis, Synthesis 53 (2021) 3545–3554."},"language":[{"iso":"eng"}],"doi":"10.1055/a-1509-6078","title":"Base-Free Catalytic Wittig-/Cross-Coupling Reaction Sequence as Short Synthetic Strategy for the Preparation of Highly Functionalized Arylbenzoxepinones","year":"2021","publication_identifier":{"issn":["0039-7881","1437-210X"]},"author":[{"full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","id":"89271"},{"last_name":"Grandane","first_name":"Aiga","full_name":"Grandane, Aiga"},{"first_name":"Linda","last_name":"Pudnika","full_name":"Pudnika, Linda"},{"full_name":"Domraceva, Ilona","last_name":"Domraceva","first_name":"Ilona"},{"last_name":"Zalubovskis","first_name":"Raivis","full_name":"Zalubovskis, Raivis"}],"publication_status":"published","date_updated":"2025-11-10T08:47:47Z","intvolume":"        53","date_created":"2023-01-22T20:27:34Z","type":"journal_article","keyword":["T2","T4","CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"publication":"Synthesis","issue":"19","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>The facile synthesis of highly functionalized building blocks with potential biological activity is of great interest to medicinal chemistry. The benzoxepinone core structures commonly exhibit biological activity. Thus, a short and efficient synthetic route towards benzoxepine containing scaffold, which enables late stage modification was developed. Namely, base-free catalytic Wittig reactions enabled the synthesis of bromobenzoxepinones from readily available starting materials. Subsequent, Suzuki–Miyaura and Stille reactions proved to be suitable methods to access a variety of benzoxepinone diaryl derivatives by late stage modification in only three steps. This three-step reaction sequence is suitable for high throughput applications and gives facile access to highly complex molecular structures, which are suitable for further functionalization. The antiproliferative properties of selected arylbenzoxepinones­ were tested in vitro on monolayer tumor cell line A549. Notably, in this initial screening, these compounds were found to be active in the micromolar range.</jats:p>","lang":"eng"}]},{"date_created":"2023-01-22T20:24:03Z","type":"journal_article","keyword":["T1","T3","CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"publication":"Chemical Science","issue":"31","abstract":[{"text":"<p>A Mn–PNP complex proved to be a suitable catalyst for the transfer hydrogenation of amides, carbamates, urea derivatives and even polyurethanes.</p>","lang":"eng"}],"language":[{"iso":"eng"}],"doi":"10.1039/d1sc02663a","year":"2021","title":"Indirect reduction of CO<sub>2</sub> and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes","author":[{"full_name":"Liu, Xin","last_name":"Liu","first_name":"Xin"},{"last_name":"Werner","orcid":"https://orcid.org/0000-0001-9025-3244","first_name":"Thomas","full_name":"Werner, Thomas","id":"89271"}],"publication_identifier":{"issn":["2041-6520","2041-6539"]},"publication_status":"published","date_updated":"2025-11-10T08:49:01Z","intvolume":"        12","citation":{"ieee":"X. Liu and T. Werner, “Indirect reduction of CO<sub>2</sub> and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes,” <i>Chemical Science</i>, vol. 12, no. 31, pp. 10590–10597, 2021, doi: <a href=\"https://doi.org/10.1039/d1sc02663a\">10.1039/d1sc02663a</a>.","apa":"Liu, X., &#38; Werner, T. (2021). Indirect reduction of CO<sub>2</sub> and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes. <i>Chemical Science</i>, <i>12</i>(31), 10590–10597. <a href=\"https://doi.org/10.1039/d1sc02663a\">https://doi.org/10.1039/d1sc02663a</a>","short":"X. Liu, T. Werner, Chemical Science 12 (2021) 10590–10597.","chicago":"Liu, Xin, and Thomas Werner. “Indirect Reduction of CO<sub>2</sub> and Recycling of Polymers by Manganese-Catalyzed Transfer Hydrogenation of Amides, Carbamates, Urea Derivatives, and Polyurethanes.” <i>Chemical Science</i> 12, no. 31 (2021): 10590–97. <a href=\"https://doi.org/10.1039/d1sc02663a\">https://doi.org/10.1039/d1sc02663a</a>.","mla":"Liu, Xin, and Thomas Werner. “Indirect Reduction of CO<sub>2</sub> and Recycling of Polymers by Manganese-Catalyzed Transfer Hydrogenation of Amides, Carbamates, Urea Derivatives, and Polyurethanes.” <i>Chemical Science</i>, vol. 12, no. 31, Royal Society of Chemistry (RSC), 2021, pp. 10590–97, doi:<a href=\"https://doi.org/10.1039/d1sc02663a\">10.1039/d1sc02663a</a>.","bibtex":"@article{Liu_Werner_2021, title={Indirect reduction of CO<sub>2</sub> and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes}, volume={12}, DOI={<a href=\"https://doi.org/10.1039/d1sc02663a\">10.1039/d1sc02663a</a>}, number={31}, journal={Chemical Science}, publisher={Royal Society of Chemistry (RSC)}, author={Liu, Xin and Werner, Thomas}, year={2021}, pages={10590–10597} }","ama":"Liu X, Werner T. Indirect reduction of CO<sub>2</sub> and recycling of polymers by manganese-catalyzed transfer hydrogenation of amides, carbamates, urea derivatives, and polyurethanes. <i>Chemical Science</i>. 2021;12(31):10590-10597. doi:<a href=\"https://doi.org/10.1039/d1sc02663a\">10.1039/d1sc02663a</a>"},"page":"10590-10597","publisher":"Royal Society of Chemistry (RSC)","_id":"37944","user_id":"89271","volume":12,"status":"public"},{"doi":"10.1039/d1gc00953b","language":[{"iso":"eng"}],"intvolume":"        23","publication_status":"published","date_updated":"2025-11-10T08:48:01Z","publication_identifier":{"issn":["1463-9262","1463-9270"]},"author":[{"last_name":"Tönjes","first_name":"Jan","full_name":"Tönjes, Jan"},{"full_name":"Longwitz, Lars","first_name":"Lars","last_name":"Longwitz"},{"id":"89271","full_name":"Werner, Thomas","orcid":"0000-0001-9025-3244","first_name":"Thomas","last_name":"Werner"}],"title":"Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction","year":"2021","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T2","CSSD"],"type":"journal_article","date_created":"2023-01-22T20:25:13Z","abstract":[{"text":"<p>PMHS proved to be a suitable terminal reductant for P(<sc>iii</sc>)/P(<sc>v</sc>) redox cycling with a methyl-substituted phosphetane as catalyst and BuOAc as solvent. The formation of water by silanol condensation was identified as main pathway of siloxane formation.</p>","lang":"eng"}],"issue":"13","publication":"Green Chemistry","volume":23,"user_id":"89271","publisher":"Royal Society of Chemistry (RSC)","_id":"37945","page":"4852-4857","status":"public","citation":{"ama":"Tönjes J, Longwitz L, Werner T. Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. <i>Green Chemistry</i>. 2021;23(13):4852-4857. doi:<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>","short":"J. Tönjes, L. Longwitz, T. Werner, Green Chemistry 23 (2021) 4852–4857.","chicago":"Tönjes, Jan, Lars Longwitz, and Thomas Werner. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” <i>Green Chemistry</i> 23, no. 13 (2021): 4852–57. <a href=\"https://doi.org/10.1039/d1gc00953b\">https://doi.org/10.1039/d1gc00953b</a>.","bibtex":"@article{Tönjes_Longwitz_Werner_2021, title={Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction}, volume={23}, DOI={<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>}, number={13}, journal={Green Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Tönjes, Jan and Longwitz, Lars and Werner, Thomas}, year={2021}, pages={4852–4857} }","mla":"Tönjes, Jan, et al. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” <i>Green Chemistry</i>, vol. 23, no. 13, Royal Society of Chemistry (RSC), 2021, pp. 4852–57, doi:<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>.","apa":"Tönjes, J., Longwitz, L., &#38; Werner, T. (2021). Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. <i>Green Chemistry</i>, <i>23</i>(13), 4852–4857. <a href=\"https://doi.org/10.1039/d1gc00953b\">https://doi.org/10.1039/d1gc00953b</a>","ieee":"J. Tönjes, L. Longwitz, and T. Werner, “Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction,” <i>Green Chemistry</i>, vol. 23, no. 13, pp. 4852–4857, 2021, doi: <a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>."}},{"language":[{"iso":"eng"}],"doi":"10.1021/acs.oprd.0c00423","author":[{"full_name":"Stefanow, Vivian","last_name":"Stefanow","first_name":"Vivian"},{"full_name":"Grandane, Aiga","first_name":"Aiga","last_name":"Grandane"},{"full_name":"Eh, Marcus","first_name":"Marcus","last_name":"Eh"},{"full_name":"Panten, Johannes","last_name":"Panten","first_name":"Johannes"},{"full_name":"Spannenberg, Anke","last_name":"Spannenberg","first_name":"Anke"},{"id":"89271","full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244"}],"publication_identifier":{"issn":["1083-6160","1520-586X"]},"title":"Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant","year":"2021","intvolume":"        25","publication_status":"published","date_updated":"2025-11-10T08:48:33Z","date_created":"2025-11-05T15:26:05Z","department":[{"_id":"35"},{"_id":"2"}],"type":"journal_article","keyword":["T4","CSSD"],"publication":"Organic Process Research &amp; Development","issue":"1","publisher":"American Chemical Society (ACS)","_id":"62098","page":"89-97","volume":25,"user_id":"89271","status":"public","citation":{"chicago":"Stefanow, Vivian, Aiga Grandane, Marcus Eh, Johannes Panten, Anke Spannenberg, and Thomas Werner. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i> 25, no. 1 (2021): 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>.","short":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, T. Werner, Organic Process Research &#38;amp; Development 25 (2021) 89–97.","ieee":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, and T. Werner, “Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant,” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, pp. 89–97, 2021, doi: <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>.","apa":"Stefanow, V., Grandane, A., Eh, M., Panten, J., Spannenberg, A., &#38; Werner, T. (2021). Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>, <i>25</i>(1), 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>","bibtex":"@article{Stefanow_Grandane_Eh_Panten_Spannenberg_Werner_2021, title={Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant}, volume={25}, DOI={<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>}, number={1}, journal={Organic Process Research &#38;amp; Development}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Grandane, Aiga and Eh, Marcus and Panten, Johannes and Spannenberg, Anke and Werner, Thomas}, year={2021}, pages={89–97} }","ama":"Stefanow V, Grandane A, Eh M, Panten J, Spannenberg A, Werner T. Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>. 2021;25(1):89-97. doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>","mla":"Stefanow, Vivian, et al. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, American Chemical Society (ACS), 2021, pp. 89–97, doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>."}},{"user_id":"89271","volume":25,"page":"89-97","_id":"62099","publisher":"American Chemical Society (ACS)","status":"public","citation":{"mla":"Stefanow, Vivian, et al. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, American Chemical Society (ACS), 2021, pp. 89–97, doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>.","bibtex":"@article{Stefanow_Grandane_Eh_Panten_Spannenberg_Werner_2021, title={Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant}, volume={25}, DOI={<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>}, number={1}, journal={Organic Process Research &#38;amp; Development}, publisher={American Chemical Society (ACS)}, author={Stefanow, Vivian and Grandane, Aiga and Eh, Marcus and Panten, Johannes and Spannenberg, Anke and Werner, Thomas}, year={2021}, pages={89–97} }","ama":"Stefanow V, Grandane A, Eh M, Panten J, Spannenberg A, Werner T. Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>. 2021;25(1):89-97. doi:<a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>","ieee":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, and T. Werner, “Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant,” <i>Organic Process Research &#38;amp; Development</i>, vol. 25, no. 1, pp. 89–97, 2021, doi: <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">10.1021/acs.oprd.0c00423</a>.","apa":"Stefanow, V., Grandane, A., Eh, M., Panten, J., Spannenberg, A., &#38; Werner, T. (2021). Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant. <i>Organic Process Research &#38;amp; Development</i>, <i>25</i>(1), 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>","short":"V. Stefanow, A. Grandane, M. Eh, J. Panten, A. Spannenberg, T. Werner, Organic Process Research &#38;amp; Development 25 (2021) 89–97.","chicago":"Stefanow, Vivian, Aiga Grandane, Marcus Eh, Johannes Panten, Anke Spannenberg, and Thomas Werner. “Stereoselective Synthesis of a<i>Cis</i>-Cedrane-8,9-Diol as a Key Intermediate for an Amber Odorant.” <i>Organic Process Research &#38;amp; Development</i> 25, no. 1 (2021): 89–97. <a href=\"https://doi.org/10.1021/acs.oprd.0c00423\">https://doi.org/10.1021/acs.oprd.0c00423</a>."},"doi":"10.1021/acs.oprd.0c00423","language":[{"iso":"eng"}],"publication_status":"published","date_updated":"2025-11-10T08:49:27Z","intvolume":"        25","year":"2021","title":"Stereoselective Synthesis of a<i>cis</i>-Cedrane-8,9-diol as a Key Intermediate for an Amber Odorant","publication_identifier":{"issn":["1083-6160","1520-586X"]},"author":[{"full_name":"Stefanow, Vivian","last_name":"Stefanow","first_name":"Vivian"},{"last_name":"Grandane","first_name":"Aiga","full_name":"Grandane, Aiga"},{"last_name":"Eh","first_name":"Marcus","full_name":"Eh, Marcus"},{"last_name":"Panten","first_name":"Johannes","full_name":"Panten, Johannes"},{"full_name":"Spannenberg, Anke","last_name":"Spannenberg","first_name":"Anke"},{"last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas","full_name":"Werner, Thomas","id":"89271"}],"keyword":["T4","CSSD"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"}],"date_created":"2025-11-05T15:28:23Z","publication":"Organic Process Research &amp; Development","issue":"1"},{"citation":{"bibtex":"@article{Wirth_Longwitz_Kanwischer_Gros_Leinweber_Werner_2021, title={AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate}, volume={225}, DOI={<a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>}, number={112768}, journal={Ecotoxicology and Environmental Safety}, publisher={Elsevier BV}, author={Wirth, Marisa A. and Longwitz, Lars and Kanwischer, Marion and Gros, Peter and Leinweber, Peter and Werner, Thomas}, year={2021} }","ama":"Wirth MA, Longwitz L, Kanwischer M, Gros P, Leinweber P, Werner T. AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate. <i>Ecotoxicology and Environmental Safety</i>. 2021;225. doi:<a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>","mla":"Wirth, Marisa A., et al. “AMPA-15N – Synthesis and Application as Standard Compound in Traceable Degradation Studies of Glyphosate.” <i>Ecotoxicology and Environmental Safety</i>, vol. 225, 112768, Elsevier BV, 2021, doi:<a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>.","short":"M.A. Wirth, L. Longwitz, M. Kanwischer, P. Gros, P. Leinweber, T. Werner, Ecotoxicology and Environmental Safety 225 (2021).","chicago":"Wirth, Marisa A., Lars Longwitz, Marion Kanwischer, Peter Gros, Peter Leinweber, and Thomas Werner. “AMPA-15N – Synthesis and Application as Standard Compound in Traceable Degradation Studies of Glyphosate.” <i>Ecotoxicology and Environmental Safety</i> 225 (2021). <a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">https://doi.org/10.1016/j.ecoenv.2021.112768</a>.","ieee":"M. A. Wirth, L. Longwitz, M. Kanwischer, P. Gros, P. Leinweber, and T. Werner, “AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate,” <i>Ecotoxicology and Environmental Safety</i>, vol. 225, Art. no. 112768, 2021, doi: <a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">10.1016/j.ecoenv.2021.112768</a>.","apa":"Wirth, M. A., Longwitz, L., Kanwischer, M., Gros, P., Leinweber, P., &#38; Werner, T. (2021). AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate. <i>Ecotoxicology and Environmental Safety</i>, <i>225</i>, Article 112768. <a href=\"https://doi.org/10.1016/j.ecoenv.2021.112768\">https://doi.org/10.1016/j.ecoenv.2021.112768</a>"},"user_id":"89271","volume":225,"publisher":"Elsevier BV","_id":"37943","status":"public","type":"journal_article","keyword":["T4","CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"date_created":"2023-01-22T20:23:06Z","publication":"Ecotoxicology and Environmental Safety","doi":"10.1016/j.ecoenv.2021.112768","article_number":"112768","language":[{"iso":"eng"}],"publication_status":"published","date_updated":"2025-11-10T08:48:20Z","intvolume":"       225","title":"AMPA-15N – Synthesis and application as standard compound in traceable degradation studies of glyphosate","year":"2021","publication_identifier":{"issn":["0147-6513"]},"author":[{"full_name":"Wirth, Marisa A.","first_name":"Marisa A.","last_name":"Wirth"},{"first_name":"Lars","last_name":"Longwitz","full_name":"Longwitz, Lars"},{"full_name":"Kanwischer, Marion","first_name":"Marion","last_name":"Kanwischer"},{"full_name":"Gros, Peter","last_name":"Gros","first_name":"Peter"},{"full_name":"Leinweber, Peter","first_name":"Peter","last_name":"Leinweber"},{"full_name":"Werner, Thomas","first_name":"Thomas","last_name":"Werner","orcid":"https://orcid.org/0000-0001-9025-3244","id":"89271"}]},{"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["T1","T3","CSSD"],"date_created":"2023-01-22T20:30:29Z","extern":"1","publication":"Advanced Synthesis and Catalysis","issue":"4","doi":"10.1002/adsc.202001209","language":[{"iso":"eng"}],"intvolume":"       363","date_updated":"2025-11-10T08:48:47Z","publication_status":"published","author":[{"first_name":"Xin","last_name":"Liu","full_name":"Liu, Xin"},{"full_name":"Werner, Thomas","last_name":"Werner","orcid":"https://orcid.org/0000-0001-9025-3244","first_name":"Thomas","id":"89271"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"title":"Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides","year":"2021","citation":{"ama":"Liu X, Werner T. Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. <i>Advanced Synthesis and Catalysis</i>. 2021;363(4):1096-1104. doi:<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>","bibtex":"@article{Liu_Werner_2021, title={Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides}, volume={363}, DOI={<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>}, number={4}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Liu, Xin and Werner, Thomas}, year={2021}, pages={1096–1104} }","mla":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” <i>Advanced Synthesis and Catalysis</i>, vol. 363, no. 4, Wiley, 2021, pp. 1096–104, doi:<a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>.","short":"X. Liu, T. Werner, Advanced Synthesis and Catalysis 363 (2021) 1096–1104.","chicago":"Liu, Xin, and Thomas Werner. “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides.” <i>Advanced Synthesis and Catalysis</i> 363, no. 4 (2021): 1096–1104. <a href=\"https://doi.org/10.1002/adsc.202001209\">https://doi.org/10.1002/adsc.202001209</a>.","apa":"Liu, X., &#38; Werner, T. (2021). Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides. <i>Advanced Synthesis and Catalysis</i>, <i>363</i>(4), 1096–1104. <a href=\"https://doi.org/10.1002/adsc.202001209\">https://doi.org/10.1002/adsc.202001209</a>","ieee":"X. Liu and T. Werner, “Selective Construction of C−C and C=C Bonds by Manganese Catalyzed Coupling of Alcohols with Phosphorus Ylides,” <i>Advanced Synthesis and Catalysis</i>, vol. 363, no. 4, pp. 1096–1104, 2021, doi: <a href=\"https://doi.org/10.1002/adsc.202001209\">10.1002/adsc.202001209</a>."},"volume":363,"user_id":"89271","_id":"37948","publisher":"Wiley","page":"1096-1104","status":"public"},{"language":[{"iso":"eng"}],"doi":"10.1002/anie.201912991","author":[{"first_name":"Lars","last_name":"Longwitz","full_name":"Longwitz, Lars"},{"full_name":"Werner, Thomas","last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","id":"89271"}],"publication_identifier":{"issn":["1433-7851","1521-3773"]},"title":"Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis","year":"2020","intvolume":"        59","date_updated":"2025-11-10T08:49:52Z","publication_status":"published","date_created":"2025-11-05T15:39:56Z","department":[{"_id":"35"},{"_id":"2"}],"type":"journal_article","keyword":["T2","T4","CSSD"],"publication":"Angewandte Chemie International Edition","issue":"7","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>","lang":"eng"}],"_id":"62102","publisher":"Wiley","page":"2760-2763","volume":59,"user_id":"89271","status":"public","citation":{"chicago":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie International Edition</i> 59, no. 7 (2020): 2760–63. <a href=\"https://doi.org/10.1002/anie.201912991\">https://doi.org/10.1002/anie.201912991</a>.","short":"L. Longwitz, T. Werner, Angewandte Chemie International Edition 59 (2020) 2760–2763.","ieee":"L. Longwitz and T. Werner, “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis,” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 7, pp. 2760–2763, 2020, doi: <a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>.","apa":"Longwitz, L., &#38; Werner, T. (2020). Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie International Edition</i>, <i>59</i>(7), 2760–2763. <a href=\"https://doi.org/10.1002/anie.201912991\">https://doi.org/10.1002/anie.201912991</a>","bibtex":"@article{Longwitz_Werner_2020, title={Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}, volume={59}, DOI={<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>}, number={7}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Longwitz, Lars and Werner, Thomas}, year={2020}, pages={2760–2763} }","ama":"Longwitz L, Werner T. Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie International Edition</i>. 2020;59(7):2760-2763. doi:<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>","mla":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 7, Wiley, 2020, pp. 2760–63, doi:<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>."}},{"language":[{"iso":"eng"}],"doi":"10.1021/acscatal.0c03294","publication_identifier":{"issn":["2155-5435","2155-5435"]},"author":[{"full_name":"Liu, Xin","first_name":"Xin","last_name":"Liu"},{"full_name":"Longwitz, Lars","first_name":"Lars","last_name":"Longwitz"},{"full_name":"Spiegelberg, Brian","last_name":"Spiegelberg","first_name":"Brian"},{"full_name":"Tönjes, Jan","last_name":"Tönjes","first_name":"Jan"},{"full_name":"Beweries, Torsten","first_name":"Torsten","last_name":"Beweries"},{"orcid":"0000-0001-9025-3244","first_name":"Thomas","last_name":"Werner","full_name":"Werner, Thomas","id":"89271"}],"title":"Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions","year":"2020","intvolume":"        10","date_updated":"2025-11-10T08:50:10Z","publication_status":"published","date_created":"2023-01-22T20:35:25Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"keyword":["T3","CSSD"],"type":"journal_article","issue":"22","publication":"ACS Catalysis","extern":"1","_id":"37951","publisher":"American Chemical Society (ACS)","page":"13659-13667","volume":10,"user_id":"89271","status":"public","citation":{"short":"X. Liu, L. Longwitz, B. Spiegelberg, J. Tönjes, T. Beweries, T. Werner, ACS Catalysis 10 (2020) 13659–13667.","chicago":"Liu, Xin, Lars Longwitz, Brian Spiegelberg, Jan Tönjes, Torsten Beweries, and Thomas Werner. “Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions.” <i>ACS Catalysis</i> 10, no. 22 (2020): 13659–67. <a href=\"https://doi.org/10.1021/acscatal.0c03294\">https://doi.org/10.1021/acscatal.0c03294</a>.","ieee":"X. Liu, L. Longwitz, B. Spiegelberg, J. Tönjes, T. Beweries, and T. 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Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions. <i>ACS Catalysis</i>. 2020;10(22):13659-13667. doi:<a href=\"https://doi.org/10.1021/acscatal.0c03294\">10.1021/acscatal.0c03294</a>","mla":"Liu, Xin, et al. “Erbium-Catalyzed Regioselective Isomerization–Cobalt-Catalyzed Transfer Hydrogenation Sequence for the Synthesis of Anti-Markovnikov Alcohols from Epoxides under Mild Conditions.” <i>ACS Catalysis</i>, vol. 10, no. 22, American Chemical Society (ACS), 2020, pp. 13659–67, doi:<a href=\"https://doi.org/10.1021/acscatal.0c03294\">10.1021/acscatal.0c03294</a>."}},{"doi":"10.1021/acssuschemeng.9b06662","language":[{"iso":"eng"}],"intvolume":"         8","date_updated":"2025-11-10T08:51:03Z","publication_status":"published","author":[{"full_name":"Wulf, Christoph","first_name":"Christoph","last_name":"Wulf"},{"last_name":"Reckers","first_name":"Matthias","full_name":"Reckers, Matthias"},{"full_name":"Perechodjuk, Anna","first_name":"Anna","last_name":"Perechodjuk"},{"id":"89271","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["2168-0485","2168-0485"]},"year":"2020","title":"Catalytic Systems for the Synthesis of Biscarbonates and Their Impact on the Sequential Preparation of Non-Isocyanate Polyurethanes","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["T1","T3","CSSD"],"date_created":"2023-01-22T20:39:32Z","extern":"1","publication":"ACS Sustainable Chemistry and Engineering","issue":"3","volume":8,"user_id":"89271","publisher":"American Chemical Society (ACS)","_id":"37955","page":"1651-1658","status":"public","citation":{"ama":"Wulf C, Reckers M, Perechodjuk A, Werner T. Catalytic Systems for the Synthesis of Biscarbonates and Their Impact on the Sequential Preparation of Non-Isocyanate Polyurethanes. <i>ACS Sustainable Chemistry and Engineering</i>. 2020;8(3):1651-1658. doi:<a href=\"https://doi.org/10.1021/acssuschemeng.9b06662\">10.1021/acssuschemeng.9b06662</a>","bibtex":"@article{Wulf_Reckers_Perechodjuk_Werner_2020, title={Catalytic Systems for the Synthesis of Biscarbonates and Their Impact on the Sequential Preparation of Non-Isocyanate Polyurethanes}, volume={8}, DOI={<a href=\"https://doi.org/10.1021/acssuschemeng.9b06662\">10.1021/acssuschemeng.9b06662</a>}, number={3}, journal={ACS Sustainable Chemistry and Engineering}, publisher={American Chemical Society (ACS)}, author={Wulf, Christoph and Reckers, Matthias and Perechodjuk, Anna and Werner, Thomas}, year={2020}, pages={1651–1658} }","mla":"Wulf, Christoph, et al. “Catalytic Systems for the Synthesis of Biscarbonates and Their Impact on the Sequential Preparation of Non-Isocyanate Polyurethanes.” <i>ACS Sustainable Chemistry and Engineering</i>, vol. 8, no. 3, American Chemical Society (ACS), 2020, pp. 1651–58, doi:<a href=\"https://doi.org/10.1021/acssuschemeng.9b06662\">10.1021/acssuschemeng.9b06662</a>.","short":"C. 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