[{"language":[{"iso":"eng"}],"keyword":["flow chemistry","heterogeneous catalysis","sustainable synthesis","organo-catalysis","polymeric gel dots"],"publication":"Gels","abstract":[{"text":"<jats:p>The use of organo-catalysis in continuous-flow reactor systems is gaining attention in medicinal chemistry due to its cost-effectiveness and reduced chemical waste. In this study, bioactive curcumin (CUM) derivatives were synthesized in a continuously operated microfluidic reactor (MFR), using piperidine-based polymeric networks as catalysts. Piperidine methacrylate and piperidine acrylate were synthesized and subsequently copolymerized with complementary monomers (MMA or DMAA) and crosslinkers (EGDMA or MBAM) via photopolymerization, yielding different polymeric networks. Initially, batch reactions were optimized for the organo-catalytic Knoevenagel condensation between CUM and 4-nitrobenzaldehyde, under various conditions, in the presence of polymer networks. Conversion was assessed using offline 1H NMR spectroscopy, revealing an increase in conversion with enhanced swelling properties of the polymer networks, which facilitated greater accessibility of catalytic sites. In continuous-flow MFR experiments, optimized polymer gel dots exhibited superior catalytic performance, achieving a conversion of up to 72%, compared to other compositions. This improvement was attributed to the enhanced swelling in the reaction mixture (DMSO/methanol, 7:3 v/v) at 40 °C over 72 h. Furthermore, the MFR system enabled the efficient synthesis of a series of CUM derivatives, demonstrating significantly higher conversion rates than traditional batch reactions. Notably, while batch reactions required 90% catalyst loading in the gel, the MFR system achieved a comparable or superior performance with only 50% catalyst, resulting in a higher turnover number. These findings underscore the advantages of continuous-flow organo-catalysis in enhancing catalytic efficiency and sustainability in organic synthesis.</jats:p>","lang":"eng"}],"date_created":"2025-04-11T07:12:02Z","publisher":"MDPI AG","title":"Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst","issue":"4","year":"2025","department":[{"_id":"163"}],"user_id":"94","_id":"59510","article_number":"278","type":"journal_article","status":"public","volume":11,"author":[{"first_name":"Naresh","last_name":"Killi","full_name":"Killi, Naresh"},{"last_name":"Rumpke","full_name":"Rumpke, Katja","first_name":"Katja"},{"id":"287","full_name":"Kuckling, Dirk","last_name":"Kuckling","first_name":"Dirk"}],"date_updated":"2025-04-11T07:13:26Z","doi":"10.3390/gels11040278","main_file_link":[{"url":"https://www.mdpi.com/2310-2861/11/4/278"}],"publication_identifier":{"issn":["2310-2861"]},"publication_status":"published","intvolume":"        11","citation":{"chicago":"Killi, Naresh, Katja Rumpke, and Dirk Kuckling. “Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst.” <i>Gels</i> 11, no. 4 (2025). <a href=\"https://doi.org/10.3390/gels11040278\">https://doi.org/10.3390/gels11040278</a>.","ieee":"N. Killi, K. Rumpke, and D. Kuckling, “Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst,” <i>Gels</i>, vol. 11, no. 4, Art. no. 278, 2025, doi: <a href=\"https://doi.org/10.3390/gels11040278\">10.3390/gels11040278</a>.","ama":"Killi N, Rumpke K, Kuckling D. Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst. <i>Gels</i>. 2025;11(4). doi:<a href=\"https://doi.org/10.3390/gels11040278\">10.3390/gels11040278</a>","short":"N. Killi, K. Rumpke, D. Kuckling, Gels 11 (2025).","mla":"Killi, Naresh, et al. “Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst.” <i>Gels</i>, vol. 11, no. 4, 278, MDPI AG, 2025, doi:<a href=\"https://doi.org/10.3390/gels11040278\">10.3390/gels11040278</a>.","bibtex":"@article{Killi_Rumpke_Kuckling_2025, title={Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst}, volume={11}, DOI={<a href=\"https://doi.org/10.3390/gels11040278\">10.3390/gels11040278</a>}, number={4278}, journal={Gels}, publisher={MDPI AG}, author={Killi, Naresh and Rumpke, Katja and Kuckling, Dirk}, year={2025} }","apa":"Killi, N., Rumpke, K., &#38; Kuckling, D. (2025). Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a Catalyst. <i>Gels</i>, <i>11</i>(4), Article 278. <a href=\"https://doi.org/10.3390/gels11040278\">https://doi.org/10.3390/gels11040278</a>"}},{"doi":"10.1039/d3cc05985e","title":"Cold denaturation of DNA origami nanostructures","date_created":"2024-04-23T08:20:05Z","author":[{"first_name":"Daniel","last_name":"Dornbusch","full_name":"Dornbusch, Daniel"},{"full_name":"Hanke, Marcel","last_name":"Hanke","first_name":"Marcel"},{"last_name":"Tomm","id":"68157","full_name":"Tomm, Emilia","first_name":"Emilia"},{"full_name":"Kielar, Charlotte","last_name":"Kielar","first_name":"Charlotte"},{"first_name":"Guido","full_name":"Grundmeier, Guido","id":"194","last_name":"Grundmeier"},{"first_name":"Adrian","full_name":"Keller, Adrian","id":"48864","last_name":"Keller","orcid":"0000-0001-7139-3110"},{"full_name":"Fahmy, Karim","last_name":"Fahmy","first_name":"Karim"}],"publisher":"Royal Society of Chemistry (RSC)","date_updated":"2024-04-23T08:21:05Z","citation":{"apa":"Dornbusch, D., Hanke, M., Tomm, E., Kielar, C., Grundmeier, G., Keller, A., &#38; Fahmy, K. (2024). Cold denaturation of DNA origami nanostructures. <i>Chemical Communications</i>. <a href=\"https://doi.org/10.1039/d3cc05985e\">https://doi.org/10.1039/d3cc05985e</a>","mla":"Dornbusch, Daniel, et al. “Cold Denaturation of DNA Origami Nanostructures.” <i>Chemical Communications</i>, Royal Society of Chemistry (RSC), 2024, doi:<a href=\"https://doi.org/10.1039/d3cc05985e\">10.1039/d3cc05985e</a>.","short":"D. Dornbusch, M. Hanke, E. Tomm, C. Kielar, G. Grundmeier, A. Keller, K. Fahmy, Chemical Communications (2024).","bibtex":"@article{Dornbusch_Hanke_Tomm_Kielar_Grundmeier_Keller_Fahmy_2024, title={Cold denaturation of DNA origami nanostructures}, DOI={<a href=\"https://doi.org/10.1039/d3cc05985e\">10.1039/d3cc05985e</a>}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Dornbusch, Daniel and Hanke, Marcel and Tomm, Emilia and Kielar, Charlotte and Grundmeier, Guido and Keller, Adrian and Fahmy, Karim}, year={2024} }","ama":"Dornbusch D, Hanke M, Tomm E, et al. Cold denaturation of DNA origami nanostructures. <i>Chemical Communications</i>. Published online 2024. doi:<a href=\"https://doi.org/10.1039/d3cc05985e\">10.1039/d3cc05985e</a>","ieee":"D. Dornbusch <i>et al.</i>, “Cold denaturation of DNA origami nanostructures,” <i>Chemical Communications</i>, 2024, doi: <a href=\"https://doi.org/10.1039/d3cc05985e\">10.1039/d3cc05985e</a>.","chicago":"Dornbusch, Daniel, Marcel Hanke, Emilia Tomm, Charlotte Kielar, Guido Grundmeier, Adrian Keller, and Karim Fahmy. “Cold Denaturation of DNA Origami Nanostructures.” <i>Chemical Communications</i>, 2024. <a href=\"https://doi.org/10.1039/d3cc05985e\">https://doi.org/10.1039/d3cc05985e</a>."},"year":"2024","publication_status":"published","publication_identifier":{"issn":["1359-7345","1364-548X"]},"language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"user_id":"48864","department":[{"_id":"302"}],"_id":"53621","status":"public","abstract":[{"text":"<jats:p>The coupling of structural transitions to heat capacity changes leads to destabilization of macromolecules at both, elevated and lowered temperatures. DNA origami not only exhibit this property but also provide...</jats:p>","lang":"eng"}],"type":"journal_article","publication":"Chemical Communications"},{"status":"public","abstract":[{"lang":"eng","text":"Abstract Recent advances in solid-state nuclear magnetic resonance (NMR) spectroscopy, combined with dynamic nuclear polarization (DNP), quantum chemical DFT calculations, and gas-phase NMR spectroscopy investigating the structure and reactivity of heterogeneous catalysts are reviewed. The investigated catalysts range from classical mononuclear catalysts, like immobilized derivates of Wilkinson’s catalysts over binuclear catalysts such as the dirhodium paddlewheel catalyst to catalytic nanoparticles, employing various support materials, such as mesoporous silica gels, coordination polymers, and biomaterials such as cellulose."}],"type":"journal_article","publication":"ChemCatChem","language":[{"iso":"eng"}],"extern":"1","keyword":["solid-state nmr","heterogeneous catalysis","dynamic nuclear polarization","Nanocatalysis","Surface-reactions"],"user_id":"100715","_id":"63970","citation":{"short":"N. Haro Mares, M. Logrado, J. Kergassner, B. Zhang, T. Gutmann, G. Buntkowsky, ChemCatChem (2024) e202401159.","mla":"Haro Mares, Nadia, et al. “Solid-State NMR of Heterogeneous Catalysts.” <i>ChemCatChem</i>, John Wiley &#38; Sons, Ltd, 2024, p. e202401159, doi:<a href=\"https://doi.org/10.1002/cctc.202401159\">10.1002/cctc.202401159</a>.","bibtex":"@article{Haro Mares_Logrado_Kergassner_Zhang_Gutmann_Buntkowsky_2024, title={Solid-State NMR of Heterogeneous Catalysts}, DOI={<a href=\"https://doi.org/10.1002/cctc.202401159\">10.1002/cctc.202401159</a>}, journal={ChemCatChem}, publisher={John Wiley &#38; Sons, Ltd}, author={Haro Mares, Nadia and Logrado, Millena and Kergassner, Jan and Zhang, Bingyu and Gutmann, Torsten and Buntkowsky, Gerd}, year={2024}, pages={e202401159} }","apa":"Haro Mares, N., Logrado, M., Kergassner, J., Zhang, B., Gutmann, T., &#38; Buntkowsky, G. (2024). Solid-State NMR of Heterogeneous Catalysts. <i>ChemCatChem</i>, e202401159. <a href=\"https://doi.org/10.1002/cctc.202401159\">https://doi.org/10.1002/cctc.202401159</a>","chicago":"Haro Mares, Nadia, Millena Logrado, Jan Kergassner, Bingyu Zhang, Torsten Gutmann, and Gerd Buntkowsky. “Solid-State NMR of Heterogeneous Catalysts.” <i>ChemCatChem</i>, 2024, e202401159. <a href=\"https://doi.org/10.1002/cctc.202401159\">https://doi.org/10.1002/cctc.202401159</a>.","ieee":"N. Haro Mares, M. Logrado, J. Kergassner, B. Zhang, T. Gutmann, and G. Buntkowsky, “Solid-State NMR of Heterogeneous Catalysts,” <i>ChemCatChem</i>, p. e202401159, 2024, doi: <a href=\"https://doi.org/10.1002/cctc.202401159\">10.1002/cctc.202401159</a>.","ama":"Haro Mares N, Logrado M, Kergassner J, Zhang B, Gutmann T, Buntkowsky G. Solid-State NMR of Heterogeneous Catalysts. <i>ChemCatChem</i>. Published online 2024:e202401159. doi:<a href=\"https://doi.org/10.1002/cctc.202401159\">10.1002/cctc.202401159</a>"},"page":"e202401159","year":"2024","publication_identifier":{"issn":["1867-3880"]},"doi":"10.1002/cctc.202401159","title":"Solid-State NMR of Heterogeneous Catalysts","date_created":"2026-02-07T15:40:38Z","author":[{"last_name":"Haro Mares","full_name":"Haro Mares, Nadia","first_name":"Nadia"},{"first_name":"Millena","full_name":"Logrado, Millena","last_name":"Logrado"},{"last_name":"Kergassner","full_name":"Kergassner, Jan","first_name":"Jan"},{"first_name":"Bingyu","full_name":"Zhang, Bingyu","last_name":"Zhang"},{"last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten","first_name":"Torsten"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"}],"publisher":"John Wiley & Sons, Ltd","date_updated":"2026-02-17T16:17:30Z"},{"intvolume":"        14","citation":{"ieee":"S. Schlicher, R. Schoch, N. Prinz, M. Zobel, and M. Bauer, “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation,” <i>Catalysts</i>, vol. 14, no. 7, Art. no. 416, 2024, doi: <a href=\"https://doi.org/10.3390/catal14070416\">10.3390/catal14070416</a>.","chicago":"Schlicher, Steffen, Roland Schoch, Nils Prinz, Mirijam Zobel, and Matthias Bauer. “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation.” <i>Catalysts</i> 14, no. 7 (2024). <a href=\"https://doi.org/10.3390/catal14070416\">https://doi.org/10.3390/catal14070416</a>.","mla":"Schlicher, Steffen, et al. “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation.” <i>Catalysts</i>, vol. 14, no. 7, 416, MDPI AG, 2024, doi:<a href=\"https://doi.org/10.3390/catal14070416\">10.3390/catal14070416</a>.","short":"S. Schlicher, R. Schoch, N. Prinz, M. Zobel, M. Bauer, Catalysts 14 (2024).","bibtex":"@article{Schlicher_Schoch_Prinz_Zobel_Bauer_2024, title={New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation}, volume={14}, DOI={<a href=\"https://doi.org/10.3390/catal14070416\">10.3390/catal14070416</a>}, number={7416}, journal={Catalysts}, publisher={MDPI AG}, author={Schlicher, Steffen and Schoch, Roland and Prinz, Nils and Zobel, Mirijam and Bauer, Matthias}, year={2024} }","apa":"Schlicher, S., Schoch, R., Prinz, N., Zobel, M., &#38; Bauer, M. (2024). New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation. <i>Catalysts</i>, <i>14</i>(7), Article 416. <a href=\"https://doi.org/10.3390/catal14070416\">https://doi.org/10.3390/catal14070416</a>","ama":"Schlicher S, Schoch R, Prinz N, Zobel M, Bauer M. New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation. <i>Catalysts</i>. 2024;14(7). doi:<a href=\"https://doi.org/10.3390/catal14070416\">10.3390/catal14070416</a>"},"publication_identifier":{"issn":["2073-4344"]},"publication_status":"published","doi":"10.3390/catal14070416","volume":14,"author":[{"first_name":"Steffen","full_name":"Schlicher, Steffen","last_name":"Schlicher"},{"first_name":"Roland","last_name":"Schoch","orcid":"0000-0003-2061-7289","id":"48467","full_name":"Schoch, Roland"},{"full_name":"Prinz, Nils","last_name":"Prinz","first_name":"Nils"},{"full_name":"Zobel, Mirijam","last_name":"Zobel","first_name":"Mirijam"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076"}],"date_updated":"2025-08-15T12:50:52Z","status":"public","type":"journal_article","article_type":"original","article_number":"416","department":[{"_id":"306"}],"user_id":"48467","_id":"54969","year":"2024","issue":"7","title":"New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation","date_created":"2024-07-02T07:10:14Z","publisher":"MDPI AG","abstract":[{"text":"This work presents a new and facile route for the preparation of iron oxide-based catalysts supported on alumina, which enables the targeted synthesis of catalysts with an increased amount of isolated tetrahedrally coordinated iron centers compared to a conventional impregnation procedure, and therefore leads to an increase in activity for CO oxidation reaction. By a multi-step impregnation–calcination protocol, the catalysts were synthesized with iron loadings of between 1 and 10 wt%, and their catalytic activity was then compared with a 10 wt% loaded catalyst prepared by conventional single impregnation. With a loading of 8 wt%, the presented catalysts showed an improved catalytic activity regarding light-off and full conversion temperatures compared to this reference. Through the application of several analytical methods (PXRD, PDF, DRUVS, SEM, XAFS), the improved catalytic activity can be correlated with an increased amount of isolated iron centers and a significantly reduced fraction of agglomerates or particles.","lang":"eng"}],"publication":"Catalysts","language":[{"iso":"eng"}],"keyword":["Catalysis"]},{"user_id":"48864","department":[{"_id":"302"},{"_id":"633"}],"_id":"48588","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"type":"journal_article","publication":"Chemistry – A European Journal","status":"public","abstract":[{"lang":"eng","text":"<jats:p>Bacterial colonization and biofilm formation on abiotic surfaces are initiated by the adhesion of peptides and proteins. Understanding the adhesion of such peptides and proteins at a molecular level thus represents an important step toward controlling and suppressing biofilm formation on technological and medical materials. This study investigates the molecular adhesion of a pilus‐derived peptide that facilitates biofilm formation of Pseudomonas aeruginosa, a multidrug‐resistant opportunistic pathogen frequently encountered in healthcare settings. Single‐molecule force spectroscopy (SMFS) was performed on chemically etched ZnO surfaces to gather insights about peptide adsorption force and its kinetics. Metal‐free click chemistry for the fabrication of peptide‐terminated SMFS cantilevers was performed on amine‐terminated gold cantilevers and verified by X‐ray photoelectron spectroscopy (XPS) and polarization‐modulated infrared reflection absorption spectroscopy (PM‐IRRAS). Atomic force microscopy (AFM) and XPS analyses reveal stable topographies and surface chemistries of the substrates that are not affected by SMFS. Rupture events described by the worm‐like chain model (WLC) up to 600 pN were detected for the non‐polar ZnO(11‐20) surfaces. The dissociation barrier energy at zero force ΔG(0), the transition state distance xb and bound‐unbound dissociation rate at zero force koff(0) for the single crystalline substrate indicate that coordination and hydrogen bonds dominate the peptide/surface interaction.</jats:p>"}],"author":[{"full_name":"Prüßner, Tim","last_name":"Prüßner","first_name":"Tim"},{"first_name":"Dennis","full_name":"Meinderink, Dennis","id":"32378","orcid":"0000-0002-2755-6514","last_name":"Meinderink"},{"last_name":"Zhu","full_name":"Zhu, Siqi","first_name":"Siqi"},{"first_name":"Alejandro G.","last_name":"Orive","full_name":"Orive, Alejandro G."},{"last_name":"Kielar","full_name":"Kielar, Charlotte","first_name":"Charlotte"},{"full_name":"Huck, Marten","last_name":"Huck","first_name":"Marten"},{"first_name":"Hans-Georg","id":"84268","full_name":"Steinrück, Hans-Georg","orcid":"0000-0001-6373-0877","last_name":"Steinrück"},{"first_name":"Adrian","id":"48864","full_name":"Keller, Adrian","orcid":"0000-0001-7139-3110","last_name":"Keller"},{"first_name":"Guido","last_name":"Grundmeier","id":"194","full_name":"Grundmeier, Guido"}],"date_created":"2023-11-02T09:23:41Z","publisher":"Wiley","date_updated":"2023-11-02T09:26:00Z","doi":"10.1002/chem.202302464","title":"Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"citation":{"apa":"Prüßner, T., Meinderink, D., Zhu, S., Orive, A. G., Kielar, C., Huck, M., Steinrück, H.-G., Keller, A., &#38; Grundmeier, G. (2023). Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces. <i>Chemistry – A European Journal</i>. <a href=\"https://doi.org/10.1002/chem.202302464\">https://doi.org/10.1002/chem.202302464</a>","bibtex":"@article{Prüßner_Meinderink_Zhu_Orive_Kielar_Huck_Steinrück_Keller_Grundmeier_2023, title={Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces}, DOI={<a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Prüßner, Tim and Meinderink, Dennis and Zhu, Siqi and Orive, Alejandro G. and Kielar, Charlotte and Huck, Marten and Steinrück, Hans-Georg and Keller, Adrian and Grundmeier, Guido}, year={2023} }","short":"T. Prüßner, D. Meinderink, S. Zhu, A.G. Orive, C. Kielar, M. Huck, H.-G. Steinrück, A. Keller, G. Grundmeier, Chemistry – A European Journal (2023).","mla":"Prüßner, Tim, et al. “Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas Aeruginosa Biofilm Formation on Non‐polar ZnO Surfaces.” <i>Chemistry – A European Journal</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>.","ama":"Prüßner T, Meinderink D, Zhu S, et al. Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces. <i>Chemistry – A European Journal</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>","ieee":"T. Prüßner <i>et al.</i>, “Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces,” <i>Chemistry – A European Journal</i>, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202302464\">10.1002/chem.202302464</a>.","chicago":"Prüßner, Tim, Dennis Meinderink, Siqi Zhu, Alejandro G. Orive, Charlotte Kielar, Marten Huck, Hans-Georg Steinrück, Adrian Keller, and Guido Grundmeier. “Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas Aeruginosa Biofilm Formation on Non‐polar ZnO Surfaces.” <i>Chemistry – A European Journal</i>, 2023. <a href=\"https://doi.org/10.1002/chem.202302464\">https://doi.org/10.1002/chem.202302464</a>."},"year":"2023"},{"publication_status":"published","publication_identifier":{"issn":["1422-0067"]},"issue":"8","year":"2023","citation":{"mla":"Müller, Patrick, et al. “Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study.” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 8, 7226, MDPI AG, 2023, doi:<a href=\"https://doi.org/10.3390/ijms24087226\">10.3390/ijms24087226</a>.","bibtex":"@article{Müller_Meta_Meidner_Schwickert_Meyr_Schwickert_Kersten_Zimmer_Hammerschmidt_Frey_et al._2023, title={Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study}, volume={24}, DOI={<a href=\"https://doi.org/10.3390/ijms24087226\">10.3390/ijms24087226</a>}, number={87226}, journal={International Journal of Molecular Sciences}, publisher={MDPI AG}, author={Müller, Patrick and Meta, Mergim and Meidner, Jan Laurenz and Schwickert, Marvin and Meyr, Jessica and Schwickert, Kevin and Kersten, Christian and Zimmer, Collin and Hammerschmidt, Stefan Josef and Frey, Ariane and et al.}, year={2023} }","short":"P. Müller, M. Meta, J.L. Meidner, M. Schwickert, J. Meyr, K. Schwickert, C. Kersten, C. Zimmer, S.J. Hammerschmidt, A. Frey, A. Lahu, S. de la Hoz-Rodríguez, L. Agost-Beltrán, S. Rodríguez, K. Diemer, W. Neumann, F.V. Gonzàlez, B. Engels, T. Schirmeister, International Journal of Molecular Sciences 24 (2023).","apa":"Müller, P., Meta, M., Meidner, J. L., Schwickert, M., Meyr, J., Schwickert, K., Kersten, C., Zimmer, C., Hammerschmidt, S. J., Frey, A., Lahu, A., de la Hoz-Rodríguez, S., Agost-Beltrán, L., Rodríguez, S., Diemer, K., Neumann, W., Gonzàlez, F. V., Engels, B., &#38; Schirmeister, T. (2023). Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study. <i>International Journal of Molecular Sciences</i>, <i>24</i>(8), Article 7226. <a href=\"https://doi.org/10.3390/ijms24087226\">https://doi.org/10.3390/ijms24087226</a>","ama":"Müller P, Meta M, Meidner JL, et al. Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study. <i>International Journal of Molecular Sciences</i>. 2023;24(8). doi:<a href=\"https://doi.org/10.3390/ijms24087226\">10.3390/ijms24087226</a>","ieee":"P. Müller <i>et al.</i>, “Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study,” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 8, Art. no. 7226, 2023, doi: <a href=\"https://doi.org/10.3390/ijms24087226\">10.3390/ijms24087226</a>.","chicago":"Müller, Patrick, Mergim Meta, Jan Laurenz Meidner, Marvin Schwickert, Jessica Meyr, Kevin Schwickert, Christian Kersten, et al. “Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study.” <i>International Journal of Molecular Sciences</i> 24, no. 8 (2023). <a href=\"https://doi.org/10.3390/ijms24087226\">https://doi.org/10.3390/ijms24087226</a>."},"intvolume":"        24","publisher":"MDPI AG","date_updated":"2024-01-05T12:59:32Z","author":[{"first_name":"Patrick","full_name":"Müller, Patrick","last_name":"Müller"},{"full_name":"Meta, Mergim","last_name":"Meta","first_name":"Mergim"},{"full_name":"Meidner, Jan Laurenz","last_name":"Meidner","first_name":"Jan Laurenz"},{"full_name":"Schwickert, Marvin","last_name":"Schwickert","first_name":"Marvin"},{"first_name":"Jessica","full_name":"Meyr, Jessica","last_name":"Meyr"},{"first_name":"Kevin","full_name":"Schwickert, Kevin","last_name":"Schwickert"},{"full_name":"Kersten, Christian","last_name":"Kersten","first_name":"Christian"},{"first_name":"Collin","full_name":"Zimmer, Collin","last_name":"Zimmer"},{"last_name":"Hammerschmidt","full_name":"Hammerschmidt, Stefan Josef","first_name":"Stefan Josef"},{"first_name":"Ariane","full_name":"Frey, Ariane","last_name":"Frey"},{"full_name":"Lahu, Albin","last_name":"Lahu","first_name":"Albin"},{"full_name":"de la Hoz-Rodríguez, Sergio","last_name":"de la Hoz-Rodríguez","first_name":"Sergio"},{"first_name":"Laura","full_name":"Agost-Beltrán, Laura","last_name":"Agost-Beltrán"},{"full_name":"Rodríguez, Santiago","last_name":"Rodríguez","first_name":"Santiago"},{"first_name":"Kira","last_name":"Diemer","full_name":"Diemer, Kira"},{"first_name":"Wilhelm","full_name":"Neumann, Wilhelm","last_name":"Neumann"},{"full_name":"Gonzàlez, Florenci V.","last_name":"Gonzàlez","first_name":"Florenci V."},{"first_name":"Bernd","last_name":"Engels","full_name":"Engels, Bernd"},{"last_name":"Schirmeister","full_name":"Schirmeister, Tanja","first_name":"Tanja"}],"date_created":"2024-01-04T08:24:31Z","volume":24,"title":"Investigation of the Compatibility between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study","doi":"10.3390/ijms24087226","type":"journal_article","publication":"International Journal of Molecular Sciences","abstract":[{"lang":"eng","text":"<jats:p>Covalent peptidomimetic protease inhibitors have gained a lot of attention in drug development in recent years. They are designed to covalently bind the catalytically active amino acids through electrophilic groups called warheads. Covalent inhibition has an advantage in terms of pharmacodynamic properties but can also bear toxicity risks due to non-selective off-target protein binding. Therefore, the right combination of a reactive warhead with a well-suited peptidomimetic sequence is of great importance. Herein, the selectivities of well-known warheads combined with peptidomimetic sequences suited for five different proteases were investigated, highlighting the impact of both structure parts (warhead and peptidomimetic sequence) for affinity and selectivity. Molecular docking gave insights into the predicted binding modes of the inhibitors inside the binding pockets of the different enzymes. Moreover, the warheads were investigated by NMR and LC-MS reactivity assays against serine/threonine and cysteine nucleophile models, as well as by quantum mechanics simulations.</jats:p>"}],"status":"public","project":[{"_id":"52","name":"PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing"}],"_id":"50150","user_id":"67287","article_number":"7226","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Computer Science Applications","Spectroscopy","Molecular Biology","General Medicine","Catalysis"],"language":[{"iso":"eng"}]},{"publication_status":"published","publication_identifier":{"issn":["2155-5435","2155-5435"]},"issue":"13","year":"2023","citation":{"apa":"Rogolino, A., Filho, J. B. G., Fritsch, L., Ardisson, J. D., da Silva, M. A. R., Atta Diab, G. A., Silva, I. F., Moraes, C. A. F., Forim, M. R., Bauer, M., Kühne, T. D., Antonietti, M., &#38; Teixeira, I. F. (2023). Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions. <i>ACS Catalysis</i>, <i>13</i>(13), 8662–8669. <a href=\"https://doi.org/10.1021/acscatal.3c02092\">https://doi.org/10.1021/acscatal.3c02092</a>","bibtex":"@article{Rogolino_Filho_Fritsch_Ardisson_da Silva_Atta Diab_Silva_Moraes_Forim_Bauer_et al._2023, title={Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions}, volume={13}, DOI={<a href=\"https://doi.org/10.1021/acscatal.3c02092\">10.1021/acscatal.3c02092</a>}, number={13}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Rogolino, Andrea and Filho, José B. G. and Fritsch, Lorena and Ardisson, José D. and da Silva, Marcos A. R. and Atta Diab, Gabriel Ali and Silva, Ingrid Fernandes and Moraes, Carlos André Ferreira and Forim, Moacir Rossi and Bauer, Matthias and et al.}, year={2023}, pages={8662–8669} }","mla":"Rogolino, Andrea, et al. “Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions.” <i>ACS Catalysis</i>, vol. 13, no. 13, American Chemical Society (ACS), 2023, pp. 8662–69, doi:<a href=\"https://doi.org/10.1021/acscatal.3c02092\">10.1021/acscatal.3c02092</a>.","short":"A. Rogolino, J.B.G. Filho, L. Fritsch, J.D. Ardisson, M.A.R. da Silva, G.A. Atta Diab, I.F. Silva, C.A.F. Moraes, M.R. Forim, M. Bauer, T.D. Kühne, M. Antonietti, I.F. Teixeira, ACS Catalysis 13 (2023) 8662–8669.","ieee":"A. Rogolino <i>et al.</i>, “Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions,” <i>ACS Catalysis</i>, vol. 13, no. 13, pp. 8662–8669, 2023, doi: <a href=\"https://doi.org/10.1021/acscatal.3c02092\">10.1021/acscatal.3c02092</a>.","chicago":"Rogolino, Andrea, José B. G. Filho, Lorena Fritsch, José D. Ardisson, Marcos A. R. da Silva, Gabriel Ali Atta Diab, Ingrid Fernandes Silva, et al. “Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions.” <i>ACS Catalysis</i> 13, no. 13 (2023): 8662–69. <a href=\"https://doi.org/10.1021/acscatal.3c02092\">https://doi.org/10.1021/acscatal.3c02092</a>.","ama":"Rogolino A, Filho JBG, Fritsch L, et al. Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions. <i>ACS Catalysis</i>. 2023;13(13):8662-8669. doi:<a href=\"https://doi.org/10.1021/acscatal.3c02092\">10.1021/acscatal.3c02092</a>"},"page":"8662-8669","intvolume":"        13","publisher":"American Chemical Society (ACS)","date_updated":"2024-03-07T09:34:41Z","date_created":"2023-08-16T14:44:11Z","author":[{"first_name":"Andrea","full_name":"Rogolino, Andrea","last_name":"Rogolino"},{"last_name":"Filho","full_name":"Filho, José B. G.","first_name":"José B. G."},{"first_name":"Lorena","full_name":"Fritsch, Lorena","id":"44418","last_name":"Fritsch"},{"first_name":"José D.","last_name":"Ardisson","full_name":"Ardisson, José D."},{"full_name":"da Silva, Marcos A. R.","last_name":"da Silva","first_name":"Marcos A. R."},{"last_name":"Atta Diab","full_name":"Atta Diab, Gabriel Ali","first_name":"Gabriel Ali"},{"last_name":"Silva","full_name":"Silva, Ingrid Fernandes","first_name":"Ingrid Fernandes"},{"first_name":"Carlos André Ferreira","last_name":"Moraes","full_name":"Moraes, Carlos André Ferreira"},{"last_name":"Forim","full_name":"Forim, Moacir Rossi","first_name":"Moacir Rossi"},{"first_name":"Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer","id":"47241","full_name":"Bauer, Matthias"},{"first_name":"Thomas D.","full_name":"Kühne, Thomas D.","last_name":"Kühne"},{"full_name":"Antonietti, Markus","last_name":"Antonietti","first_name":"Markus"},{"last_name":"Teixeira","full_name":"Teixeira, Ivo F.","first_name":"Ivo F."}],"volume":13,"title":"Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions","doi":"10.1021/acscatal.3c02092","type":"journal_article","publication":"ACS Catalysis","status":"public","_id":"46547","user_id":"44418","keyword":["Catalysis","General Chemistry","pc2-ressources","Computing Resources Provided by the Paderborn Center for Parallel Computing"],"language":[{"iso":"eng"}]},{"citation":{"apa":"Krämer, F., Paradies, J., Fernández, I., &#38; Breher, F. (2023). Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>, <i>30</i>(5). <a href=\"https://doi.org/10.1002/chem.202303380\">https://doi.org/10.1002/chem.202303380</a>","mla":"Krämer, Felix, et al. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European Journal</i>, vol. 30, no. 5, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>.","bibtex":"@article{Krämer_Paradies_Fernández_Breher_2023, title={Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles}, volume={30}, DOI={<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>}, number={5}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}, year={2023} }","short":"F. Krämer, J. Paradies, I. Fernández, F. Breher, Chemistry – A European Journal 30 (2023).","ama":"Krämer F, Paradies J, Fernández I, Breher F. Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>. 2023;30(5). doi:<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>","ieee":"F. Krämer, J. Paradies, I. Fernández, and F. Breher, “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles,” <i>Chemistry – A European Journal</i>, vol. 30, no. 5, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>.","chicago":"Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European Journal</i> 30, no. 5 (2023). <a href=\"https://doi.org/10.1002/chem.202303380\">https://doi.org/10.1002/chem.202303380</a>."},"intvolume":"        30","year":"2023","issue":"5","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"doi":"10.1002/chem.202303380","title":"Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles","author":[{"last_name":"Krämer","full_name":"Krämer, Felix","first_name":"Felix"},{"full_name":"Paradies, Jan","id":"53339","orcid":"0000-0002-3698-668X","last_name":"Paradies","first_name":"Jan"},{"full_name":"Fernández, Israel","last_name":"Fernández","first_name":"Israel"},{"full_name":"Breher, Frank","last_name":"Breher","first_name":"Frank"}],"date_created":"2024-03-13T17:17:52Z","volume":30,"date_updated":"2024-03-13T17:18:17Z","publisher":"Wiley","status":"public","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>We report on so‐called “hidden FLPs” (FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group 13 fragment in the <jats:italic>ortho</jats:italic> position of a phenyl ring scaffold to form five‐membered ring structures. Although the formation of the Lewis acid/base adducts was observed in the solid state, most of the title compounds readily react with carbon dioxide to provide stable insertion products. Strikingly, 0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze the reduction of CO<jats:sub>2</jats:sub> to methanol with satisfactory high selectivity and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive computational studies provided valuable mechanistic insights and shed more light on activity differences.</jats:p>","lang":"eng"}],"type":"journal_article","publication":"Chemistry – A European Journal","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"user_id":"53339","department":[{"_id":"2"},{"_id":"389"}],"_id":"52542"},{"_id":"52344","user_id":"48467","department":[{"_id":"306"}],"article_type":"original","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"language":[{"iso":"eng"}],"type":"journal_article","publication":"ChemCatChem","abstract":[{"lang":"eng","text":"Macrocyclization reactions are still challenging due to competing oligomerization, which requires the use of small substrate concentrations. Here, the cationic tungsten imido and tungsten oxo alkylidene N-heterocyclic carbene complexes [[W(N-2,6-Cl2-C6H3)(CHCMe2Ph(OC6F5)(pivalonitrile)(IMes)+ B(ArF)4−] (W1) and [W(O)(CHCMe2Ph(OCMe(CF3)2)(IMes)(CH3CN)+ B(ArF)4−] (W2) (IMes=1,3-dimesitylimidazol-2-ylidene; B(ArF)4−=tetrakis(3,5-bis(trifluoromethyl)phenyl borate) have been immobilized inside the pores of ordered mesoporous silica (OMS) with pore diameters of 3.3 and 6.8 nm, respectively, using a pore-selective immobilization protocol. X-ray absorption spectroscopy of W1@OMS showed that even though the catalyst structure is contracted due to confinement by the mesopores, both the oxidation state and structure of the catalyst stayed intact upon immobilization. Catalytic testing with four differently sized α,ω-dienes revealed a dramatically increased macrocyclization (MC) and Z-selectivity of the supported catalysts compared to the homogenous progenitors, allowing high substrate concentrations of 25 mM. With the supported complexes, a maximum increase in MC-selectivity from 27 to 81 % and in Z-selectivity from 17 to 34 % was achieved. In general, smaller mesopores exhibited a stronger confinement effect. A comparison of the two supported tungsten-based catalysts showed that W1@OMS possesses a higher MC-selectivity, while W2@OMS exhibits a higher Z-selectivity which can be rationalized by the structures of the catalysts."}],"status":"public","date_updated":"2024-05-07T11:41:51Z","publisher":"Wiley","author":[{"first_name":"Felix","full_name":"Ziegler, Felix","last_name":"Ziegler"},{"full_name":"Bruckner, Johanna R.","last_name":"Bruckner","first_name":"Johanna R."},{"first_name":"Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011","id":"78878","full_name":"Nowakowski, Michał"},{"first_name":"Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer","id":"47241","full_name":"Bauer, Matthias"},{"first_name":"Patrick","last_name":"Probst","full_name":"Probst, Patrick"},{"first_name":"Boshra","last_name":"Atwi","full_name":"Atwi, Boshra"},{"first_name":"Michael R.","full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser"}],"date_created":"2024-03-07T09:44:33Z","volume":15,"title":"Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes","doi":"10.1002/cctc.202300871","publication_status":"published","publication_identifier":{"issn":["1867-3880","1867-3899"]},"issue":"21","year":"2023","citation":{"short":"F. Ziegler, J.R. Bruckner, M. Nowakowski, M. Bauer, P. Probst, B. Atwi, M.R. Buchmeiser, ChemCatChem 15 (2023).","mla":"Ziegler, Felix, et al. “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes.” <i>ChemCatChem</i>, vol. 15, no. 21, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>.","bibtex":"@article{Ziegler_Bruckner_Nowakowski_Bauer_Probst_Atwi_Buchmeiser_2023, title={Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes}, volume={15}, DOI={<a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>}, number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Ziegler, Felix and Bruckner, Johanna R. and Nowakowski, Michał and Bauer, Matthias and Probst, Patrick and Atwi, Boshra and Buchmeiser, Michael R.}, year={2023} }","apa":"Ziegler, F., Bruckner, J. R., Nowakowski, M., Bauer, M., Probst, P., Atwi, B., &#38; Buchmeiser, M. R. (2023). Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes. <i>ChemCatChem</i>, <i>15</i>(21). <a href=\"https://doi.org/10.1002/cctc.202300871\">https://doi.org/10.1002/cctc.202300871</a>","ama":"Ziegler F, Bruckner JR, Nowakowski M, et al. Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes. <i>ChemCatChem</i>. 2023;15(21). doi:<a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>","chicago":"Ziegler, Felix, Johanna R. Bruckner, Michał Nowakowski, Matthias Bauer, Patrick Probst, Boshra Atwi, and Michael R. Buchmeiser. “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes.” <i>ChemCatChem</i> 15, no. 21 (2023). <a href=\"https://doi.org/10.1002/cctc.202300871\">https://doi.org/10.1002/cctc.202300871</a>.","ieee":"F. Ziegler <i>et al.</i>, “Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes,” <i>ChemCatChem</i>, vol. 15, no. 21, 2023, doi: <a href=\"https://doi.org/10.1002/cctc.202300871\">10.1002/cctc.202300871</a>."},"intvolume":"        15"},{"language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis"],"user_id":"53339","_id":"35694","status":"public","publication":"Angewandte Chemie International Edition","type":"journal_article","doi":"10.1002/anie.202216959","title":"Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation","date_created":"2023-01-10T08:59:12Z","author":[{"first_name":"Laura","full_name":"Köring, Laura","last_name":"Köring"},{"first_name":"Arne","last_name":"Stepen","full_name":"Stepen, Arne"},{"last_name":"Birenheide","full_name":"Birenheide, Bernhard","first_name":"Bernhard"},{"full_name":"Barth, Simon","last_name":"Barth","first_name":"Simon"},{"full_name":"Leskov, Maxim","last_name":"Leskov","first_name":"Maxim"},{"last_name":"Schoch","full_name":"Schoch, Roland","first_name":"Roland"},{"first_name":"Felix","full_name":"Krämer, Felix","last_name":"Krämer"},{"first_name":"Frank","last_name":"Breher","full_name":"Breher, Frank"},{"first_name":"Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","full_name":"Paradies, Jan","id":"53339"}],"date_updated":"2023-01-23T12:56:01Z","publisher":"Wiley","citation":{"mla":"Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation.” <i>Angewandte Chemie International Edition</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202216959\">10.1002/anie.202216959</a>.","short":"L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer, F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).","bibtex":"@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023, title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation}, DOI={<a href=\"https://doi.org/10.1002/anie.202216959\">10.1002/anie.202216959</a>}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Köring, Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023} }","apa":"Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R., Krämer, F., Breher, F., &#38; Paradies, J. (2023). Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation. <i>Angewandte Chemie International Edition</i>. <a href=\"https://doi.org/10.1002/anie.202216959\">https://doi.org/10.1002/anie.202216959</a>","ieee":"L. Köring <i>et al.</i>, “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation,” <i>Angewandte Chemie International Edition</i>, 2023, doi: <a href=\"https://doi.org/10.1002/anie.202216959\">10.1002/anie.202216959</a>.","chicago":"Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov, Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation.” <i>Angewandte Chemie International Edition</i>, 2023. <a href=\"https://doi.org/10.1002/anie.202216959\">https://doi.org/10.1002/anie.202216959</a>.","ama":"Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation. <i>Angewandte Chemie International Edition</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/anie.202216959\">10.1002/anie.202216959</a>"},"year":"2023","publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published"},{"year":"2023","citation":{"mla":"Zhou, Rundong, et al. “Frustrated Lewis Pair Catalysed Reactions.” <i>SynOpen</i>, Georg Thieme Verlag KG, 2023, doi:<a href=\"https://doi.org/10.1055/a-2005-5443\">10.1055/a-2005-5443</a>.","bibtex":"@article{Zhou_Tavandashti_Paradies_2023, title={Frustrated Lewis Pair Catalysed Reactions}, DOI={<a href=\"https://doi.org/10.1055/a-2005-5443\">10.1055/a-2005-5443</a>}, journal={SynOpen}, publisher={Georg Thieme Verlag KG}, author={Zhou, Rundong and Tavandashti, Zoleykha and Paradies, Jan}, year={2023} }","short":"R. Zhou, Z. Tavandashti, J. Paradies, SynOpen (2023).","apa":"Zhou, R., Tavandashti, Z., &#38; Paradies, J. (2023). Frustrated Lewis Pair Catalysed Reactions. <i>SynOpen</i>. <a href=\"https://doi.org/10.1055/a-2005-5443\">https://doi.org/10.1055/a-2005-5443</a>","chicago":"Zhou, Rundong, Zoleykha Tavandashti, and Jan Paradies. “Frustrated Lewis Pair Catalysed Reactions.” <i>SynOpen</i>, 2023. <a href=\"https://doi.org/10.1055/a-2005-5443\">https://doi.org/10.1055/a-2005-5443</a>.","ieee":"R. Zhou, Z. Tavandashti, and J. Paradies, “Frustrated Lewis Pair Catalysed Reactions,” <i>SynOpen</i>, 2023, doi: <a href=\"https://doi.org/10.1055/a-2005-5443\">10.1055/a-2005-5443</a>.","ama":"Zhou R, Tavandashti Z, Paradies J. Frustrated Lewis Pair Catalysed Reactions. <i>SynOpen</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1055/a-2005-5443\">10.1055/a-2005-5443</a>"},"publication_identifier":{"issn":["2509-9396"]},"publication_status":"published","title":"Frustrated Lewis Pair Catalysed Reactions","doi":"10.1055/a-2005-5443","publisher":"Georg Thieme Verlag KG","date_updated":"2023-01-23T12:54:12Z","date_created":"2023-01-10T08:58:57Z","author":[{"last_name":"Zhou","full_name":"Zhou, Rundong","first_name":"Rundong"},{"last_name":"Tavandashti","full_name":"Tavandashti, Zoleykha","first_name":"Zoleykha"},{"first_name":"Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","id":"53339","full_name":"Paradies, Jan"}],"abstract":[{"text":"<jats:p>In recent years, frustrated Lewis pairs have been widely used in small molecules activation and catalytic transformations. This graphic review is aimed to provide the fundamental understanding of frustrated Lewis pair reactivity and the exploitation thereof in catalytic reactions.</jats:p>","lang":"eng"}],"status":"public","publication":"SynOpen","type":"journal_article","keyword":["Organic Chemistry","Materials Science (miscellaneous)","Biomaterials","Catalysis"],"language":[{"iso":"eng"}],"_id":"35693","user_id":"53339"},{"date_updated":"2023-03-08T19:31:59Z","publisher":"Wiley","author":[{"full_name":"Köring, Laura","last_name":"Köring","first_name":"Laura"},{"first_name":"Arne","last_name":"Stepen","full_name":"Stepen, Arne"},{"full_name":"Birenheide, Bernhard","last_name":"Birenheide","first_name":"Bernhard"},{"first_name":"Simon","full_name":"Barth, Simon","last_name":"Barth"},{"full_name":"Leskov, Maxim","last_name":"Leskov","first_name":"Maxim"},{"first_name":"Roland","last_name":"Schoch","full_name":"Schoch, Roland"},{"first_name":"Felix","last_name":"Krämer","full_name":"Krämer, Felix"},{"first_name":"Frank","full_name":"Breher, Frank","last_name":"Breher"},{"full_name":"Paradies, Jan","id":"53339","orcid":"0000-0002-3698-668X","last_name":"Paradies","first_name":"Jan"}],"date_created":"2023-03-08T19:27:25Z","title":"Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation","doi":"10.1002/anie.202301632","publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","year":"2023","citation":{"mla":"Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.” <i>Angewandte Chemie International Edition</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202301632\">10.1002/anie.202301632</a>.","bibtex":"@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023, title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation}, DOI={<a href=\"https://doi.org/10.1002/anie.202301632\">10.1002/anie.202301632</a>}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Köring, Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023} }","short":"L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer, F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).","apa":"Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R., Krämer, F., Breher, F., &#38; Paradies, J. (2023). Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte Chemie International Edition</i>. <a href=\"https://doi.org/10.1002/anie.202301632\">https://doi.org/10.1002/anie.202301632</a>","ama":"Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. <i>Angewandte Chemie International Edition</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/anie.202301632\">10.1002/anie.202301632</a>","ieee":"L. Köring <i>et al.</i>, “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation,” <i>Angewandte Chemie International Edition</i>, 2023, doi: <a href=\"https://doi.org/10.1002/anie.202301632\">10.1002/anie.202301632</a>.","chicago":"Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov, Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.” <i>Angewandte Chemie International Edition</i>, 2023. <a href=\"https://doi.org/10.1002/anie.202301632\">https://doi.org/10.1002/anie.202301632</a>."},"_id":"42878","department":[{"_id":"2"},{"_id":"389"}],"user_id":"53339","keyword":["General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"publication":"Angewandte Chemie International Edition","type":"journal_article","status":"public"},{"type":"journal_article","status":"public","_id":"44116","department":[{"_id":"35"},{"_id":"2"},{"_id":"307"}],"user_id":"23547","publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","page":"e202303111","intvolume":"        62","citation":{"ieee":"J. M. Wrogemann <i>et al.</i>, “Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage,” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 26, p. e202303111, 2023, doi: <a href=\"https://doi.org/10.1002/anie.202303111\">10.1002/anie.202303111</a>.","chicago":"Wrogemann, Jens Matthies, Marco Joes Lüther, Peer Bärmann, Mailis Lounasvuori, Ali Javed, Michael Tiemann, Ronny Golnak, et al. “Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage.” <i>Angewandte Chemie International Edition</i> 62, no. 26 (2023): e202303111. <a href=\"https://doi.org/10.1002/anie.202303111\">https://doi.org/10.1002/anie.202303111</a>.","ama":"Wrogemann JM, Lüther MJ, Bärmann P, et al. Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage. <i>Angewandte Chemie International Edition</i>. 2023;62(26):e202303111. doi:<a href=\"https://doi.org/10.1002/anie.202303111\">10.1002/anie.202303111</a>","bibtex":"@article{Wrogemann_Lüther_Bärmann_Lounasvuori_Javed_Tiemann_Golnak_Xiao_Petit_Placke_et al._2023, title={Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage}, volume={62}, DOI={<a href=\"https://doi.org/10.1002/anie.202303111\">10.1002/anie.202303111</a>}, number={26}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Wrogemann, Jens Matthies and Lüther, Marco Joes and Bärmann, Peer and Lounasvuori, Mailis and Javed, Ali and Tiemann, Michael and Golnak, Ronny and Xiao, Jie and Petit, Tristan and Placke, Tobias and et al.}, year={2023}, pages={e202303111} }","short":"J.M. Wrogemann, M.J. Lüther, P. Bärmann, M. Lounasvuori, A. Javed, M. Tiemann, R. Golnak, J. Xiao, T. Petit, T. Placke, M. Winter, Angewandte Chemie International Edition 62 (2023) e202303111.","mla":"Wrogemann, Jens Matthies, et al. “Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage.” <i>Angewandte Chemie International Edition</i>, vol. 62, no. 26, Wiley, 2023, p. e202303111, doi:<a href=\"https://doi.org/10.1002/anie.202303111\">10.1002/anie.202303111</a>.","apa":"Wrogemann, J. M., Lüther, M. J., Bärmann, P., Lounasvuori, M., Javed, A., Tiemann, M., Golnak, R., Xiao, J., Petit, T., Placke, T., &#38; Winter, M. (2023). Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage. <i>Angewandte Chemie International Edition</i>, <i>62</i>(26), e202303111. <a href=\"https://doi.org/10.1002/anie.202303111\">https://doi.org/10.1002/anie.202303111</a>"},"oa":"1","date_updated":"2023-06-21T09:50:14Z","volume":62,"author":[{"last_name":"Wrogemann","full_name":"Wrogemann, Jens Matthies","first_name":"Jens Matthies"},{"first_name":"Marco Joes","full_name":"Lüther, Marco Joes","last_name":"Lüther"},{"last_name":"Bärmann","full_name":"Bärmann, Peer","first_name":"Peer"},{"last_name":"Lounasvuori","full_name":"Lounasvuori, Mailis","first_name":"Mailis"},{"last_name":"Javed","full_name":"Javed, Ali","first_name":"Ali"},{"first_name":"Michael","last_name":"Tiemann","orcid":"0000-0003-1711-2722","full_name":"Tiemann, Michael","id":"23547"},{"full_name":"Golnak, Ronny","last_name":"Golnak","first_name":"Ronny"},{"first_name":"Jie","last_name":"Xiao","full_name":"Xiao, Jie"},{"last_name":"Petit","full_name":"Petit, Tristan","first_name":"Tristan"},{"first_name":"Tobias","last_name":"Placke","full_name":"Placke, Tobias"},{"first_name":"Martin","full_name":"Winter, Martin","last_name":"Winter"}],"doi":"10.1002/anie.202303111","main_file_link":[{"open_access":"1"}],"publication":"Angewandte Chemie International Edition","abstract":[{"text":"Faradaic reactions including charge transfer are often accompanied with diffusion limitation inside the bulk. Conductive two-dimensional frameworks (2D MOFs) with a fast ion transport can combine both - charge transfer and fast diffusion inside their porous structure. To study remaining diffusion limitations caused by particle morphology, different synthesis routes of Cu-2,3,6,7,10,11-hexahydroxytriphenylene (Cu3(HHTP)2), a copper-based 2D MOF, are used to obtain flake- and rod-like MOF particles. Both morphologies are systematically characterized and evaluated for redox-active Li+ ion storage. The redox mechanism is investigated by means of X-ray absorption spectroscopy, FTIR spectroscopy and in situ XRD. Both types are compared regarding kinetic properties for Li+ ion storage via cyclic voltammetry and impedance spectroscopy. A significant influence of particle morphology for 2D MOFs on kinetic aspects of electrochemical Li+ ion storage can be observed. This study opens the path for optimization of redox active porous structures to overcome diffusion limitations of Faradaic processes.","lang":"eng"}],"keyword":["General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"quality_controlled":"1","issue":"26","year":"2023","publisher":"Wiley","date_created":"2023-04-22T06:17:33Z","title":"Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage"},{"publisher":"Wiley","date_created":"2023-04-16T18:14:24Z","title":"Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation","issue":"22","year":"2023","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"language":[{"iso":"eng"}],"publication":"Chemistry – A European Journal","abstract":[{"lang":"eng","text":"A series of new organic donor–π–acceptor dyes incorporating a diquat moiety as a novel electron-acceptor unit have been synthesized and characterized. The analytical data were supported by DFT calculations. These dyes were explored in the aerobic thiocyanation of indoles and pyrroles. Here they showed a high photocatalytic activity under visible light, giving isolated yields of up to 97 %. In addition, the photocatalytic activity of standalone diquat and methyl viologen through formation of an electron donor acceptor complex is presented."}],"oa":"1","date_updated":"2023-06-26T02:29:15Z","volume":" 29","author":[{"last_name":"Meier","full_name":"Meier, Armin","first_name":"Armin"},{"orcid":"0000-0002-8481-4161","last_name":"Badalov","full_name":"Badalov, Sabuhi","id":"78800","first_name":"Sabuhi"},{"first_name":"Timur","last_name":"Biktagirov","full_name":"Biktagirov, Timur","id":"65612"},{"last_name":"Schmidt","orcid":"0000-0002-2717-5076","full_name":"Schmidt, Wolf Gero","id":"468","first_name":"Wolf Gero"},{"full_name":"Wilhelm, René","last_name":"Wilhelm","first_name":"René"}],"doi":"10.1002/chem.202203541","main_file_link":[{"open_access":"1","url":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202203541"}],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","related_material":{"link":[{"url":"https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202203541&file=chem202203541-sup-0001-misc_information.pdf","relation":"supplementary_material"}]},"page":" e202203541","citation":{"apa":"Meier, A., Badalov, S., Biktagirov, T., Schmidt, W. G., &#38; Wilhelm, R. (2023). Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation. <i>Chemistry – A European Journal</i>, <i>29</i>(22), e202203541. <a href=\"https://doi.org/10.1002/chem.202203541\">https://doi.org/10.1002/chem.202203541</a>","mla":"Meier, Armin, et al. “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation.” <i>Chemistry – A European Journal</i>, vol. 29, no. 22, Wiley, 2023, p. e202203541, doi:<a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>.","bibtex":"@article{Meier_Badalov_Biktagirov_Schmidt_Wilhelm_2023, title={Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation}, volume={29}, DOI={<a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>}, number={22}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Meier, Armin and Badalov, Sabuhi and Biktagirov, Timur and Schmidt, Wolf Gero and Wilhelm, René}, year={2023}, pages={e202203541} }","short":"A. Meier, S. Badalov, T. Biktagirov, W.G. Schmidt, R. Wilhelm, Chemistry – A European Journal 29 (2023) e202203541.","ama":"Meier A, Badalov S, Biktagirov T, Schmidt WG, Wilhelm R. Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation. <i>Chemistry – A European Journal</i>. 2023;29(22):e202203541. doi:<a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>","chicago":"Meier, Armin, Sabuhi Badalov, Timur Biktagirov, Wolf Gero Schmidt, and René Wilhelm. “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation.” <i>Chemistry – A European Journal</i> 29, no. 22 (2023): e202203541. <a href=\"https://doi.org/10.1002/chem.202203541\">https://doi.org/10.1002/chem.202203541</a>.","ieee":"A. Meier, S. Badalov, T. Biktagirov, W. G. Schmidt, and R. Wilhelm, “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation,” <i>Chemistry – A European Journal</i>, vol. 29, no. 22, p. e202203541, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>."},"_id":"43827","project":[{"_id":"52","name":"PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing"}],"department":[{"_id":"35"},{"_id":"15"},{"_id":"170"},{"_id":"295"},{"_id":"230"}],"user_id":"78800","article_type":"original","extern":"1","type":"journal_article","status":"public"},{"keyword":["General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"_id":"46277","department":[{"_id":"2"},{"_id":"389"}],"user_id":"53339","status":"public","publication":"Angewandte Chemie International Edition","type":"journal_article","title":"Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs","doi":"10.1002/anie.202308752","publisher":"Wiley","date_updated":"2023-08-03T09:01:41Z","author":[{"first_name":"Benedikt","full_name":"Sieland, Benedikt","last_name":"Sieland"},{"last_name":"Stahn","full_name":"Stahn, Marcel","first_name":"Marcel"},{"full_name":"Schoch, Roland","last_name":"Schoch","first_name":"Roland"},{"last_name":"Daniliuc","full_name":"Daniliuc, Constantin","first_name":"Constantin"},{"first_name":"Sebastian","last_name":"Spicher","full_name":"Spicher, Sebastian"},{"first_name":"Stefan","full_name":"Grimme, Stefan","last_name":"Grimme"},{"last_name":"Hansen","full_name":"Hansen, Andreas","first_name":"Andreas"},{"first_name":"Jan","last_name":"Paradies","orcid":"0000-0002-3698-668X","full_name":"Paradies, Jan","id":"53339"}],"date_created":"2023-08-03T09:00:33Z","year":"2023","citation":{"apa":"Sieland, B., Stahn, M., Schoch, R., Daniliuc, C., Spicher, S., Grimme, S., Hansen, A., &#38; Paradies, J. (2023). Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs. <i>Angewandte Chemie International Edition</i>. <a href=\"https://doi.org/10.1002/anie.202308752\">https://doi.org/10.1002/anie.202308752</a>","bibtex":"@article{Sieland_Stahn_Schoch_Daniliuc_Spicher_Grimme_Hansen_Paradies_2023, title={Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs}, DOI={<a href=\"https://doi.org/10.1002/anie.202308752\">10.1002/anie.202308752</a>}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Sieland, Benedikt and Stahn, Marcel and Schoch, Roland and Daniliuc, Constantin and Spicher, Sebastian and Grimme, Stefan and Hansen, Andreas and Paradies, Jan}, year={2023} }","short":"B. Sieland, M. Stahn, R. Schoch, C. Daniliuc, S. Spicher, S. Grimme, A. Hansen, J. Paradies, Angewandte Chemie International Edition (2023).","mla":"Sieland, Benedikt, et al. “Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs.” <i>Angewandte Chemie International Edition</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/anie.202308752\">10.1002/anie.202308752</a>.","ama":"Sieland B, Stahn M, Schoch R, et al. Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs. <i>Angewandte Chemie International Edition</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/anie.202308752\">10.1002/anie.202308752</a>","ieee":"B. Sieland <i>et al.</i>, “Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs,” <i>Angewandte Chemie International Edition</i>, 2023, doi: <a href=\"https://doi.org/10.1002/anie.202308752\">10.1002/anie.202308752</a>.","chicago":"Sieland, Benedikt, Marcel Stahn, Roland Schoch, Constantin Daniliuc, Sebastian Spicher, Stefan Grimme, Andreas Hansen, and Jan Paradies. “Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs.” <i>Angewandte Chemie International Edition</i>, 2023. <a href=\"https://doi.org/10.1002/anie.202308752\">https://doi.org/10.1002/anie.202308752</a>."},"publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published"},{"type":"journal_article","publication":"International Journal of Molecular Sciences","abstract":[{"lang":"eng","text":"<jats:p>The influence of nanoscale surface topography on protein adsorption is highly important for numerous applications in medicine and technology. Herein, ferritin adsorption at flat and nanofaceted, single-crystalline Al2O3 surfaces is investigated using atomic force microscopy and X-ray photoelectron spectroscopy. The nanofaceted surfaces are generated by the thermal annealing of Al2O3 wafers at temperatures above 1000 °C, which leads to the formation of faceted saw-tooth-like surface topographies with periodicities of about 160 nm and amplitudes of about 15 nm. Ferritin adsorption at these nanofaceted surfaces is notably suppressed compared to the flat surface at a concentration of 10 mg/mL, which is attributed to lower adsorption affinities of the newly formed facets. Consequently, adsorption is restricted mostly to the pattern grooves, where the proteins can maximize their contact area with the surface. However, this effect depends on the protein concentration, with an inverse trend being observed at 30 mg/mL. Furthermore, different ferritin adsorption behavior is observed at topographically similar nanofacet patterns fabricated at different annealing temperatures and attributed to different step and kink densities. These results demonstrate that while protein adsorption at solid surfaces can be notably affected by nanofacet patterns, fine-tuning protein adsorption in this way requires the precise control of facet properties.</jats:p>"}],"status":"public","_id":"46543","user_id":"48864","department":[{"_id":"302"}],"article_number":"12808","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Computer Science Applications","Spectroscopy","Molecular Biology","General Medicine","Catalysis"],"language":[{"iso":"eng"}],"publication_status":"published","publication_identifier":{"issn":["1422-0067"]},"issue":"16","year":"2023","citation":{"chicago":"Pothineni, Bhanu K., Sabrina Kollmann, Xinyang Li, Guido Grundmeier, Denise J. Erb, and Adrian Keller. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.” <i>International Journal of Molecular Sciences</i> 24, no. 16 (2023). <a href=\"https://doi.org/10.3390/ijms241612808\">https://doi.org/10.3390/ijms241612808</a>.","ieee":"B. K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D. J. Erb, and A. Keller, “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces,” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 16, Art. no. 12808, 2023, doi: <a href=\"https://doi.org/10.3390/ijms241612808\">10.3390/ijms241612808</a>.","ama":"Pothineni BK, Kollmann S, Li X, Grundmeier G, Erb DJ, Keller A. Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces. <i>International Journal of Molecular Sciences</i>. 2023;24(16). doi:<a href=\"https://doi.org/10.3390/ijms241612808\">10.3390/ijms241612808</a>","apa":"Pothineni, B. K., Kollmann, S., Li, X., Grundmeier, G., Erb, D. J., &#38; Keller, A. (2023). Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces. <i>International Journal of Molecular Sciences</i>, <i>24</i>(16), Article 12808. <a href=\"https://doi.org/10.3390/ijms241612808\">https://doi.org/10.3390/ijms241612808</a>","short":"B.K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D.J. Erb, A. Keller, International Journal of Molecular Sciences 24 (2023).","mla":"Pothineni, Bhanu K., et al. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.” <i>International Journal of Molecular Sciences</i>, vol. 24, no. 16, 12808, MDPI AG, 2023, doi:<a href=\"https://doi.org/10.3390/ijms241612808\">10.3390/ijms241612808</a>.","bibtex":"@article{Pothineni_Kollmann_Li_Grundmeier_Erb_Keller_2023, title={Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces}, volume={24}, DOI={<a href=\"https://doi.org/10.3390/ijms241612808\">10.3390/ijms241612808</a>}, number={1612808}, journal={International Journal of Molecular Sciences}, publisher={MDPI AG}, author={Pothineni, Bhanu K. and Kollmann, Sabrina and Li, Xinyang and Grundmeier, Guido and Erb, Denise J. and Keller, Adrian}, year={2023} }"},"intvolume":"        24","date_updated":"2023-08-16T10:53:00Z","publisher":"MDPI AG","author":[{"first_name":"Bhanu K.","full_name":"Pothineni, Bhanu K.","last_name":"Pothineni"},{"last_name":"Kollmann","full_name":"Kollmann, Sabrina","first_name":"Sabrina"},{"last_name":"Li","full_name":"Li, Xinyang","first_name":"Xinyang"},{"last_name":"Grundmeier","id":"194","full_name":"Grundmeier, Guido","first_name":"Guido"},{"first_name":"Denise J.","last_name":"Erb","full_name":"Erb, Denise J."},{"first_name":"Adrian","last_name":"Keller","orcid":"0000-0001-7139-3110","full_name":"Keller, Adrian","id":"48864"}],"date_created":"2023-08-16T10:52:25Z","volume":24,"title":"Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces","doi":"10.3390/ijms241612808"},{"volume":13,"author":[{"full_name":"Kirchhof, Manuel","last_name":"Kirchhof","first_name":"Manuel"},{"full_name":"Gugeler, Katrin","last_name":"Gugeler","first_name":"Katrin"},{"full_name":"Beurer, Ann-Katrin","last_name":"Beurer","first_name":"Ann-Katrin"},{"first_name":"Felix Richard","last_name":"Fischer","full_name":"Fischer, Felix Richard"},{"first_name":"Derman","last_name":"Batman","full_name":"Batman, Derman"},{"last_name":"Bauch","full_name":"Bauch, Soeren M.","first_name":"Soeren M."},{"first_name":"Sofia","full_name":"Kolin, Sofia","last_name":"Kolin"},{"first_name":"Elliot","full_name":"Nicholas, Elliot","last_name":"Nicholas"},{"first_name":"Roland","id":"48467","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch"},{"first_name":"Charlotte","last_name":"Vogler","full_name":"Vogler, Charlotte"},{"last_name":"Kousik","full_name":"Kousik, Shravan R.","first_name":"Shravan R."},{"first_name":"Anna","full_name":"Zens, Anna","last_name":"Zens"},{"first_name":"Bernd","full_name":"Plietker, Bernd","last_name":"Plietker"},{"first_name":"Petia","last_name":"Atanasova","full_name":"Atanasova, Petia"},{"full_name":"Naumann, Stefan","last_name":"Naumann","first_name":"Stefan"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"full_name":"Bruckner, Johanna R.","last_name":"Bruckner","first_name":"Johanna R."},{"first_name":"Yvonne","last_name":"Traa","full_name":"Traa, Yvonne"},{"first_name":"Johannes","full_name":"Kästner, Johannes","last_name":"Kästner"},{"first_name":"Sabine","full_name":"Laschat, Sabine","last_name":"Laschat"}],"date_updated":"2025-06-16T09:00:17Z","doi":"10.1039/d3cy00381g","publication_identifier":{"issn":["2044-4753","2044-4761"]},"publication_status":"published","page":"3709-3724","intvolume":"        13","citation":{"apa":"Kirchhof, M., Gugeler, K., Beurer, A.-K., Fischer, F. R., Batman, D., Bauch, S. M., Kolin, S., Nicholas, E., Schoch, R., Vogler, C., Kousik, S. R., Zens, A., Plietker, B., Atanasova, P., Naumann, S., Bauer, M., Bruckner, J. R., Traa, Y., Kästner, J., &#38; Laschat, S. (2023). Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. <i>Catalysis Science Technology</i>, <i>13</i>(12), 3709–3724. <a href=\"https://doi.org/10.1039/d3cy00381g\">https://doi.org/10.1039/d3cy00381g</a>","mla":"Kirchhof, Manuel, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” <i>Catalysis Science Technology</i>, vol. 13, no. 12, Royal Society of Chemistry (RSC), 2023, pp. 3709–24, doi:<a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>.","bibtex":"@article{Kirchhof_Gugeler_Beurer_Fischer_Batman_Bauch_Kolin_Nicholas_Schoch_Vogler_et al._2023, title={Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis}, volume={13}, DOI={<a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>}, number={12}, journal={Catalysis Science Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Kirchhof, Manuel and Gugeler, Katrin and Beurer, Ann-Katrin and Fischer, Felix Richard and Batman, Derman and Bauch, Soeren M. and Kolin, Sofia and Nicholas, Elliot and Schoch, Roland and Vogler, Charlotte and et al.}, year={2023}, pages={3709–3724} }","short":"M. Kirchhof, K. Gugeler, A.-K. Beurer, F.R. Fischer, D. Batman, S.M. Bauch, S. Kolin, E. Nicholas, R. Schoch, C. Vogler, S.R. Kousik, A. Zens, B. Plietker, P. Atanasova, S. Naumann, M. Bauer, J.R. Bruckner, Y. Traa, J. Kästner, S. Laschat, Catalysis Science Technology 13 (2023) 3709–3724.","ama":"Kirchhof M, Gugeler K, Beurer A-K, et al. Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. <i>Catalysis Science Technology</i>. 2023;13(12):3709-3724. doi:<a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>","ieee":"M. Kirchhof <i>et al.</i>, “Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis,” <i>Catalysis Science Technology</i>, vol. 13, no. 12, pp. 3709–3724, 2023, doi: <a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>.","chicago":"Kirchhof, Manuel, Katrin Gugeler, Ann-Katrin Beurer, Felix Richard Fischer, Derman Batman, Soeren M. Bauch, Sofia Kolin, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” <i>Catalysis Science Technology</i> 13, no. 12 (2023): 3709–24. <a href=\"https://doi.org/10.1039/d3cy00381g\">https://doi.org/10.1039/d3cy00381g</a>."},"department":[{"_id":"306"}],"user_id":"48467","_id":"52343","article_type":"original","type":"journal_article","status":"public","date_created":"2024-03-07T09:12:06Z","publisher":"Royal Society of Chemistry (RSC)","title":"Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis","issue":"12","year":"2023","language":[{"iso":"eng"}],"keyword":["Catalysis"],"publication":"Catalysis Science Technology","abstract":[{"lang":"eng","text":"Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies."}]},{"status":"public","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>A new approach for the characterization of CO<jats:sub>2</jats:sub> methanation catalysts prepared by thermal decomposition of a nickel MOF by hard X‐ray photon‐in/photon‐out spectroscopy in form of high energy resolution fluorescence detected X‐ray absorption near edge structure spectroscopy (HERFD‐XANES) and valence‐to‐core X‐ray emission (VtC‐XES) is presented. In contrast to conventional X‐ray absorption spectroscopy, the increased resolution of both methods allows a more precise phase determination of the final catalyst, which is influenced by the conditions during MOF decomposition.</jats:p>"}],"type":"journal_article","publication":"ChemPhysChem","language":[{"iso":"eng"}],"keyword":["Catalysis"],"user_id":"48467","_id":"48167","citation":{"apa":"Strübbe, S., Nowakowski, M., Schoch, R., &#38; Bauer, M. (2023). High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts. <i>ChemPhysChem</i>. <a href=\"https://doi.org/10.1002/cphc.202300113\">https://doi.org/10.1002/cphc.202300113</a>","mla":"Strübbe, Sven, et al. “High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts.” <i>ChemPhysChem</i>, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/cphc.202300113\">10.1002/cphc.202300113</a>.","bibtex":"@article{Strübbe_Nowakowski_Schoch_Bauer_2023, title={High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts}, DOI={<a href=\"https://doi.org/10.1002/cphc.202300113\">10.1002/cphc.202300113</a>}, journal={ChemPhysChem}, publisher={Wiley}, author={Strübbe, Sven and Nowakowski, Michał and Schoch, Roland and Bauer, Matthias}, year={2023} }","short":"S. Strübbe, M. Nowakowski, R. Schoch, M. Bauer, ChemPhysChem (2023).","ama":"Strübbe S, Nowakowski M, Schoch R, Bauer M. High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts. <i>ChemPhysChem</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1002/cphc.202300113\">10.1002/cphc.202300113</a>","ieee":"S. Strübbe, M. Nowakowski, R. Schoch, and M. Bauer, “High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts,” <i>ChemPhysChem</i>, 2023, doi: <a href=\"https://doi.org/10.1002/cphc.202300113\">10.1002/cphc.202300113</a>.","chicago":"Strübbe, Sven, Michał Nowakowski, Roland Schoch, and Matthias Bauer. “High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts.” <i>ChemPhysChem</i>, 2023. <a href=\"https://doi.org/10.1002/cphc.202300113\">https://doi.org/10.1002/cphc.202300113</a>."},"year":"2023","publication_status":"published","publication_identifier":{"issn":["1439-4235","1439-7641"]},"doi":"10.1002/cphc.202300113","title":"High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts","author":[{"id":"76968","full_name":"Strübbe, Sven","last_name":"Strübbe","first_name":"Sven"},{"id":"78878","full_name":"Nowakowski, Michał","orcid":"0000-0002-3734-7011","last_name":"Nowakowski","first_name":"Michał"},{"id":"48467","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"}],"date_created":"2023-10-17T08:14:08Z","date_updated":"2025-08-15T12:53:23Z","publisher":"Wiley"},{"year":"2023","citation":{"short":"N. Prinz, S. Strübbe, M. Bauer, M. Zobel, New Journal of Chemistry (2023).","bibtex":"@article{Prinz_Strübbe_Bauer_Zobel_2023, title={Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering}, DOI={<a href=\"https://doi.org/10.1039/d3nj00493g\">10.1039/d3nj00493g</a>}, journal={New Journal of Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Prinz, Nils and Strübbe, Sven and Bauer, Matthias and Zobel, Mirijam}, year={2023} }","mla":"Prinz, Nils, et al. “Structural Transitions during Ni Nanoparticle Formation by Decomposition of a Ni-Containing Metal-Organic Framework Using in-Situ Total Scattering.” <i>New Journal of Chemistry</i>, Royal Society of Chemistry (RSC), 2023, doi:<a href=\"https://doi.org/10.1039/d3nj00493g\">10.1039/d3nj00493g</a>.","apa":"Prinz, N., Strübbe, S., Bauer, M., &#38; Zobel, M. (2023). Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering. <i>New Journal of Chemistry</i>. <a href=\"https://doi.org/10.1039/d3nj00493g\">https://doi.org/10.1039/d3nj00493g</a>","ama":"Prinz N, Strübbe S, Bauer M, Zobel M. Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering. <i>New Journal of Chemistry</i>. Published online 2023. doi:<a href=\"https://doi.org/10.1039/d3nj00493g\">10.1039/d3nj00493g</a>","ieee":"N. Prinz, S. Strübbe, M. Bauer, and M. Zobel, “Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering,” <i>New Journal of Chemistry</i>, 2023, doi: <a href=\"https://doi.org/10.1039/d3nj00493g\">10.1039/d3nj00493g</a>.","chicago":"Prinz, Nils, Sven Strübbe, Matthias Bauer, and Mirijam Zobel. “Structural Transitions during Ni Nanoparticle Formation by Decomposition of a Ni-Containing Metal-Organic Framework Using in-Situ Total Scattering.” <i>New Journal of Chemistry</i>, 2023. <a href=\"https://doi.org/10.1039/d3nj00493g\">https://doi.org/10.1039/d3nj00493g</a>."},"publication_status":"published","publication_identifier":{"issn":["1144-0546","1369-9261"]},"title":"Structural transitions during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework using in-situ total scattering","doi":"10.1039/d3nj00493g","date_updated":"2025-08-15T12:56:35Z","publisher":"Royal Society of Chemistry (RSC)","date_created":"2023-06-06T07:33:35Z","author":[{"last_name":"Prinz","full_name":"Prinz, Nils","first_name":"Nils"},{"first_name":"Sven","last_name":"Strübbe","id":"76968","full_name":"Strübbe, Sven"},{"first_name":"Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241"},{"first_name":"Mirijam","full_name":"Zobel, Mirijam","last_name":"Zobel"}],"abstract":[{"lang":"eng","text":"<jats:p>For improved and rational design of catalysts, in-depth knowledge of their formation and structural evolution during synthesis is a key parameter. Thus, preparation of a Ni methanation catalyst derived from...</jats:p>"}],"status":"public","type":"journal_article","publication":"New Journal of Chemistry","keyword":["Catalysis"],"language":[{"iso":"eng"}],"_id":"45480","user_id":"48467"},{"year":"2023","issue":"3","title":"Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates","publisher":"American Chemical Society (ACS)","date_created":"2023-01-12T12:07:52Z","publication":"Journal of the American Chemical Society (JACS)","keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"intvolume":"       145","page":"1557-1563","citation":{"apa":"De, J., Ma, X., Yin, F., Ren, J., Yao, J., Schumacher, S., Liao, Q., Fu, H., Malpuech, G., &#38; Solnyshkov, D. (2023). Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates. <i>Journal of the American Chemical Society (JACS)</i>, <i>145</i>(3), 1557–1563. <a href=\"https://doi.org/10.1021/jacs.2c07557\">https://doi.org/10.1021/jacs.2c07557</a>","bibtex":"@article{De_Ma_Yin_Ren_Yao_Schumacher_Liao_Fu_Malpuech_Solnyshkov_2023, title={Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates}, volume={145}, DOI={<a href=\"https://doi.org/10.1021/jacs.2c07557\">10.1021/jacs.2c07557</a>}, number={3}, journal={Journal of the American Chemical Society (JACS)}, publisher={American Chemical Society (ACS)}, author={De, Jianbo and Ma, Xuekai and Yin, Fan and Ren, Jiahuan and Yao, Jiannian and Schumacher, Stefan and Liao, Qing and Fu, Hongbing and Malpuech, Guillaume and Solnyshkov, Dmitry}, year={2023}, pages={1557–1563} }","mla":"De, Jianbo, et al. “Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates.” <i>Journal of the American Chemical Society (JACS)</i>, vol. 145, no. 3, American Chemical Society (ACS), 2023, pp. 1557–63, doi:<a href=\"https://doi.org/10.1021/jacs.2c07557\">10.1021/jacs.2c07557</a>.","short":"J. De, X. Ma, F. Yin, J. Ren, J. Yao, S. Schumacher, Q. Liao, H. Fu, G. Malpuech, D. Solnyshkov, Journal of the American Chemical Society (JACS) 145 (2023) 1557–1563.","chicago":"De, Jianbo, Xuekai Ma, Fan Yin, Jiahuan Ren, Jiannian Yao, Stefan Schumacher, Qing Liao, Hongbing Fu, Guillaume Malpuech, and Dmitry Solnyshkov. “Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates.” <i>Journal of the American Chemical Society (JACS)</i> 145, no. 3 (2023): 1557–63. <a href=\"https://doi.org/10.1021/jacs.2c07557\">https://doi.org/10.1021/jacs.2c07557</a>.","ieee":"J. De <i>et al.</i>, “Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates,” <i>Journal of the American Chemical Society (JACS)</i>, vol. 145, no. 3, pp. 1557–1563, 2023, doi: <a href=\"https://doi.org/10.1021/jacs.2c07557\">10.1021/jacs.2c07557</a>.","ama":"De J, Ma X, Yin F, et al. Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates. <i>Journal of the American Chemical Society (JACS)</i>. 2023;145(3):1557-1563. doi:<a href=\"https://doi.org/10.1021/jacs.2c07557\">10.1021/jacs.2c07557</a>"},"publication_identifier":{"issn":["0002-7863","1520-5126"]},"publication_status":"published","doi":"10.1021/jacs.2c07557","date_updated":"2025-12-05T13:50:32Z","volume":145,"author":[{"first_name":"Jianbo","full_name":"De, Jianbo","last_name":"De"},{"first_name":"Xuekai","last_name":"Ma","full_name":"Ma, Xuekai","id":"59416"},{"first_name":"Fan","full_name":"Yin, Fan","last_name":"Yin"},{"last_name":"Ren","full_name":"Ren, Jiahuan","first_name":"Jiahuan"},{"first_name":"Jiannian","last_name":"Yao","full_name":"Yao, Jiannian"},{"first_name":"Stefan","full_name":"Schumacher, Stefan","id":"27271","last_name":"Schumacher","orcid":"0000-0003-4042-4951"},{"full_name":"Liao, Qing","last_name":"Liao","first_name":"Qing"},{"first_name":"Hongbing","full_name":"Fu, Hongbing","last_name":"Fu"},{"full_name":"Malpuech, Guillaume","last_name":"Malpuech","first_name":"Guillaume"},{"full_name":"Solnyshkov, Dmitry","last_name":"Solnyshkov","first_name":"Dmitry"}],"status":"public","type":"journal_article","_id":"36416","project":[{"_id":"53","name":"TRR 142: TRR 142"},{"name":"TRR 142 - A: TRR 142 - Project Area A","_id":"54"},{"name":"TRR 142 - A4: TRR 142 - Subproject A4","_id":"61"},{"_id":"53","name":"TRR 142: Maßgeschneiderte nichtlineare Photonik: Von grundlegenden Konzepten zu funktionellen Strukturen"}],"department":[{"_id":"15"},{"_id":"170"},{"_id":"705"},{"_id":"297"},{"_id":"230"},{"_id":"429"},{"_id":"35"}],"user_id":"16199"}]