[{"title":"Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes","date_created":"2023-01-30T16:48:41Z","publisher":"Wiley","year":"2021","issue":"68","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"abstract":[{"text":"Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica.","lang":"eng"}],"publication":"Chemistry – A European Journal","doi":"10.1002/chem.202103099","volume":27,"author":[{"first_name":"Pradeep K. R.","last_name":"Panyam","full_name":"Panyam, Pradeep K. R."},{"full_name":"Atwi, Boshra","last_name":"Atwi","first_name":"Boshra"},{"last_name":"Ziegler","full_name":"Ziegler, Felix","first_name":"Felix"},{"last_name":"Frey","full_name":"Frey, Wolfgang","first_name":"Wolfgang"},{"orcid":"0000-0002-3734-7011","last_name":"Nowakowski","id":"78878","full_name":"Nowakowski, Michał","first_name":"Michał"},{"full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076","first_name":"Matthias"},{"last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R.","first_name":"Michael R."}],"date_updated":"2024-05-07T11:43:40Z","intvolume":"        27","page":"17220-17229","citation":{"apa":"Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., &#38; Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. <i>Chemistry – A European Journal</i>, <i>27</i>(68), 17220–17229. <a href=\"https://doi.org/10.1002/chem.202103099\">https://doi.org/10.1002/chem.202103099</a>","short":"P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.","mla":"Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” <i>Chemistry – A European Journal</i>, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:<a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>.","bibtex":"@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={<a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }","chicago":"Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michał Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” <i>Chemistry – A European Journal</i> 27, no. 68 (2021): 17220–29. <a href=\"https://doi.org/10.1002/chem.202103099\">https://doi.org/10.1002/chem.202103099</a>.","ieee":"P. K. R. Panyam <i>et al.</i>, “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” <i>Chemistry – A European Journal</i>, vol. 27, no. 68, pp. 17220–17229, 2021, doi: <a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>.","ama":"Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. <i>Chemistry – A European Journal</i>. 2021;27(68):17220-17229. doi:<a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>"},"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","article_type":"original","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"40999","status":"public","type":"journal_article"},{"language":[{"iso":"eng"}],"keyword":["Photocatalytic Hydrogen Production","Catalysis","Inorganic Chemistry"],"publication":"Chemistry – A European Journal","title":"Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad","date_created":"2022-03-09T08:20:58Z","publisher":"Wiley","year":"2021","issue":"38","user_id":"48467","department":[{"_id":"306"}],"_id":"30216","status":"public","type":"journal_article","doi":"10.1002/chem.202100766","author":[{"last_name":"Huber-Gedert","id":"38352","full_name":"Huber-Gedert, Marina","first_name":"Marina"},{"first_name":"Michał","full_name":"Nowakowski, Michał","id":"78878","last_name":"Nowakowski","orcid":"0000-0002-3734-7011"},{"first_name":"Ahmet","full_name":"Kertmen, Ahmet","last_name":"Kertmen"},{"id":"54038","full_name":"Burkhardt, Lukas","last_name":"Burkhardt","orcid":"0000-0003-0747-9811","first_name":"Lukas"},{"first_name":"Natalia","full_name":"Lindner, Natalia","last_name":"Lindner"},{"last_name":"Schoch","full_name":"Schoch, Roland","first_name":"Roland"},{"first_name":"Regine","last_name":"Herbst‐Irmer","full_name":"Herbst‐Irmer, Regine"},{"first_name":"Adam","full_name":"Neuba, Adam","last_name":"Neuba"},{"first_name":"Lennart","last_name":"Schmitz","full_name":"Schmitz, Lennart"},{"first_name":"Tae‐Kyu","full_name":"Choi, Tae‐Kyu","last_name":"Choi"},{"first_name":"Jacek","full_name":"Kubicki, Jacek","last_name":"Kubicki"},{"first_name":"Wojciech","full_name":"Gawelda, Wojciech","last_name":"Gawelda"},{"first_name":"Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","full_name":"Bauer, Matthias"}],"volume":27,"date_updated":"2024-05-07T11:44:08Z","citation":{"ama":"Huber-Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. <i>Chemistry – A European Journal</i>. 2021;27(38):9905-9918. doi:<a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>","chicago":"Huber-Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt, Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” <i>Chemistry – A European Journal</i> 27, no. 38 (2021): 9905–18. <a href=\"https://doi.org/10.1002/chem.202100766\">https://doi.org/10.1002/chem.202100766</a>.","ieee":"M. Huber-Gedert <i>et al.</i>, “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” <i>Chemistry – A European Journal</i>, vol. 27, no. 38, pp. 9905–9918, 2021, doi: <a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>.","mla":"Huber-Gedert, Marina, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” <i>Chemistry – A European Journal</i>, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:<a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>.","short":"M. Huber-Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R. Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda, M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.","bibtex":"@article{Huber-Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={<a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>}, number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber-Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }","apa":"Huber-Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N., Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda, W., &#38; Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. <i>Chemistry – A European Journal</i>, <i>27</i>(38), 9905–9918. <a href=\"https://doi.org/10.1002/chem.202100766\">https://doi.org/10.1002/chem.202100766</a>"},"page":"9905-9918","intvolume":"        27","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]}},{"user_id":"53339","_id":"35686","language":[{"iso":"eng"}],"keyword":["Organic Chemistry","Catalysis"],"type":"journal_article","publication":"Synthesis","status":"public","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>The development of the frustrated Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed. Detailed insight into our strategies in order to overcome challenges during the reaction development process is provided. Furthermore, the developed chemistry is extended to the hydrogenation of polyamides and of trifluoroacetamides for the convenient introduction of trifluoroethyl groups into organic molecules.</jats:p>","lang":"eng"}],"author":[{"id":"53339","full_name":"Paradies, Jan","orcid":"0000-0002-3698-668X","last_name":"Paradies","first_name":"Jan"},{"last_name":"Köring","full_name":"Köring, Laura","first_name":"Laura"},{"first_name":"Nikolai A.","last_name":"Sitte","full_name":"Sitte, Nikolai A."}],"date_created":"2023-01-10T08:56:44Z","volume":54,"publisher":"Georg Thieme Verlag KG","date_updated":"2023-01-23T12:51:23Z","doi":"10.1055/a-1681-3972","title":"Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides","issue":"05","publication_status":"published","publication_identifier":{"issn":["0039-7881","1437-210X"]},"citation":{"ama":"Paradies J, Köring L, Sitte NA. Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides. <i>Synthesis</i>. 2021;54(05):1287-1300. doi:<a href=\"https://doi.org/10.1055/a-1681-3972\">10.1055/a-1681-3972</a>","ieee":"J. Paradies, L. Köring, and N. A. Sitte, “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides,” <i>Synthesis</i>, vol. 54, no. 05, pp. 1287–1300, 2021, doi: <a href=\"https://doi.org/10.1055/a-1681-3972\">10.1055/a-1681-3972</a>.","chicago":"Paradies, Jan, Laura Köring, and Nikolai A. Sitte. “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” <i>Synthesis</i> 54, no. 05 (2021): 1287–1300. <a href=\"https://doi.org/10.1055/a-1681-3972\">https://doi.org/10.1055/a-1681-3972</a>.","bibtex":"@article{Paradies_Köring_Sitte_2021, title={Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides}, volume={54}, DOI={<a href=\"https://doi.org/10.1055/a-1681-3972\">10.1055/a-1681-3972</a>}, number={05}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Paradies, Jan and Köring, Laura and Sitte, Nikolai A.}, year={2021}, pages={1287–1300} }","short":"J. Paradies, L. Köring, N.A. Sitte, Synthesis 54 (2021) 1287–1300.","mla":"Paradies, Jan, et al. “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” <i>Synthesis</i>, vol. 54, no. 05, Georg Thieme Verlag KG, 2021, pp. 1287–300, doi:<a href=\"https://doi.org/10.1055/a-1681-3972\">10.1055/a-1681-3972</a>.","apa":"Paradies, J., Köring, L., &#38; Sitte, N. A. (2021). Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides. <i>Synthesis</i>, <i>54</i>(05), 1287–1300. <a href=\"https://doi.org/10.1055/a-1681-3972\">https://doi.org/10.1055/a-1681-3972</a>"},"intvolume":"        54","page":"1287-1300","year":"2021"},{"status":"public","publication":"Applied Catalysis B: Environmental","type":"journal_article","keyword":["Process Chemistry and Technology","General Environmental Science","Catalysis"],"article_number":"120965","language":[{"iso":"eng"}],"_id":"40562","user_id":"98120","year":"2021","intvolume":"       304","citation":{"mla":"da Silva, Marcos A. R., et al. “Sustainable Oxidation Catalysis Supported by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.” <i>Applied Catalysis B: Environmental</i>, vol. 304, 120965, Elsevier BV, 2021, doi:<a href=\"https://doi.org/10.1016/j.apcatb.2021.120965\">10.1016/j.apcatb.2021.120965</a>.","bibtex":"@article{da Silva_Silva_Xue_Lo_Tarakina_Nunes_Adler_Sahoo_Bahnemann_Lopez Salas_et al._2021, title={Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}, volume={304}, DOI={<a href=\"https://doi.org/10.1016/j.apcatb.2021.120965\">10.1016/j.apcatb.2021.120965</a>}, number={120965}, journal={Applied Catalysis B: Environmental}, publisher={Elsevier BV}, author={da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo, Sudhir K. and Bahnemann, Detlef W. and Lopez Salas, Nieves and et al.}, year={2021} }","short":"M.A.R. da Silva, I.F. Silva, Q. Xue, B.T.W. Lo, N.V. Tarakina, B.N. Nunes, P. Adler, S.K. Sahoo, D.W. Bahnemann, N. Lopez Salas, A. Savateev, C. Ribeiro, T.D. Kühne, M. Antonietti, I.F. Teixeira, Applied Catalysis B: Environmental 304 (2021).","apa":"da Silva, M. A. R., Silva, I. F., Xue, Q., Lo, B. T. W., Tarakina, N. V., Nunes, B. N., Adler, P., Sahoo, S. K., Bahnemann, D. W., Lopez Salas, N., Savateev, A., Ribeiro, C., Kühne, T. D., Antonietti, M., &#38; Teixeira, I. F. (2021). Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst. <i>Applied Catalysis B: Environmental</i>, <i>304</i>, Article 120965. <a href=\"https://doi.org/10.1016/j.apcatb.2021.120965\">https://doi.org/10.1016/j.apcatb.2021.120965</a>","ama":"da Silva MAR, Silva IF, Xue Q, et al. Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst. <i>Applied Catalysis B: Environmental</i>. 2021;304. doi:<a href=\"https://doi.org/10.1016/j.apcatb.2021.120965\">10.1016/j.apcatb.2021.120965</a>","chicago":"Silva, Marcos A.R. da, Ingrid F. Silva, Qi Xue, Benedict T.W. Lo, Nadezda V. Tarakina, Barbara N. Nunes, Peter Adler, et al. “Sustainable Oxidation Catalysis Supported by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.” <i>Applied Catalysis B: Environmental</i> 304 (2021). <a href=\"https://doi.org/10.1016/j.apcatb.2021.120965\">https://doi.org/10.1016/j.apcatb.2021.120965</a>.","ieee":"M. A. R. da Silva <i>et al.</i>, “Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst,” <i>Applied Catalysis B: Environmental</i>, vol. 304, Art. no. 120965, 2021, doi: <a href=\"https://doi.org/10.1016/j.apcatb.2021.120965\">10.1016/j.apcatb.2021.120965</a>."},"publication_identifier":{"issn":["0926-3373"]},"publication_status":"published","title":"Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst","doi":"10.1016/j.apcatb.2021.120965","publisher":"Elsevier BV","date_updated":"2023-01-27T16:35:15Z","volume":304,"date_created":"2023-01-27T16:15:03Z","author":[{"last_name":"da Silva","full_name":"da Silva, Marcos A.R.","first_name":"Marcos A.R."},{"last_name":"Silva","full_name":"Silva, Ingrid F.","first_name":"Ingrid F."},{"first_name":"Qi","last_name":"Xue","full_name":"Xue, Qi"},{"first_name":"Benedict T.W.","last_name":"Lo","full_name":"Lo, Benedict T.W."},{"first_name":"Nadezda V.","last_name":"Tarakina","full_name":"Tarakina, Nadezda V."},{"full_name":"Nunes, Barbara N.","last_name":"Nunes","first_name":"Barbara N."},{"first_name":"Peter","full_name":"Adler, Peter","last_name":"Adler"},{"first_name":"Sudhir K.","full_name":"Sahoo, Sudhir K.","last_name":"Sahoo"},{"last_name":"Bahnemann","full_name":"Bahnemann, Detlef W.","first_name":"Detlef W."},{"last_name":"Lopez Salas","full_name":"Lopez Salas, Nieves","first_name":"Nieves"},{"last_name":"Savateev","full_name":"Savateev, Aleksandr","first_name":"Aleksandr"},{"full_name":"Ribeiro, Caue","last_name":"Ribeiro","first_name":"Caue"},{"first_name":"Thomas D.","full_name":"Kühne, Thomas D.","last_name":"Kühne"},{"last_name":"Antonietti","full_name":"Antonietti, Markus","first_name":"Markus"},{"first_name":"Ivo F.","last_name":"Teixeira","full_name":"Teixeira, Ivo F."}]},{"year":"2021","intvolume":"        11","page":"11570-11578","citation":{"chicago":"Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna R. Bruckner, Michal Nowakowski, Kilian Weißer, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes.” <i>ACS Catalysis</i> 11, no. 18 (2021): 11570–78. <a href=\"https://doi.org/10.1021/acscatal.1c03057\">https://doi.org/10.1021/acscatal.1c03057</a>.","ieee":"F. Ziegler <i>et al.</i>, “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes,” <i>ACS Catalysis</i>, vol. 11, no. 18, pp. 11570–11578, 2021, doi: <a href=\"https://doi.org/10.1021/acscatal.1c03057\">10.1021/acscatal.1c03057</a>.","ama":"Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes. <i>ACS Catalysis</i>. 2021;11(18):11570-11578. doi:<a href=\"https://doi.org/10.1021/acscatal.1c03057\">10.1021/acscatal.1c03057</a>","apa":"Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski, M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., &#38; Buchmeiser, M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes. <i>ACS Catalysis</i>, <i>11</i>(18), 11570–11578. <a href=\"https://doi.org/10.1021/acscatal.1c03057\">https://doi.org/10.1021/acscatal.1c03057</a>","mla":"Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes.” <i>ACS Catalysis</i>, vol. 11, no. 18, American Chemical Society (ACS), 2021, pp. 11570–78, doi:<a href=\"https://doi.org/10.1021/acscatal.1c03057\">10.1021/acscatal.1c03057</a>.","short":"F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski, K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS Catalysis 11 (2021) 11570–11578.","bibtex":"@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes}, volume={11}, DOI={<a href=\"https://doi.org/10.1021/acscatal.1c03057\">10.1021/acscatal.1c03057</a>}, number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren and Bruckner, Johanna R. and Nowakowski, Michal and Weißer, Kilian and Solodenko, Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578} }"},"publication_identifier":{"issn":["2155-5435","2155-5435"]},"publication_status":"published","issue":"18","title":"Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes","doi":"10.1021/acscatal.1c03057","publisher":"American Chemical Society (ACS)","date_updated":"2023-02-01T08:50:59Z","volume":11,"date_created":"2023-01-31T22:50:23Z","author":[{"first_name":"Felix","last_name":"Ziegler","full_name":"Ziegler, Felix"},{"last_name":"Kraus","full_name":"Kraus, Hamzeh","first_name":"Hamzeh"},{"last_name":"Benedikter","full_name":"Benedikter, Mathis J.","first_name":"Mathis J."},{"first_name":"Dongren","last_name":"Wang","full_name":"Wang, Dongren"},{"last_name":"Bruckner","full_name":"Bruckner, Johanna R.","first_name":"Johanna R."},{"last_name":"Nowakowski","full_name":"Nowakowski, Michal","first_name":"Michal"},{"first_name":"Kilian","last_name":"Weißer","full_name":"Weißer, Kilian"},{"full_name":"Solodenko, Helena","last_name":"Solodenko","first_name":"Helena"},{"first_name":"Guido","last_name":"Schmitz","full_name":"Schmitz, Guido"},{"first_name":"Matthias","last_name":"Bauer","full_name":"Bauer, Matthias"},{"first_name":"Niels","last_name":"Hansen","full_name":"Hansen, Niels"},{"first_name":"Michael R.","last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R."}],"status":"public","publication":"ACS Catalysis","type":"journal_article","keyword":["Catalysis","General Chemistry"],"language":[{"iso":"eng"}],"_id":"41323","user_id":"78878"},{"publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"issue":"38","year":"2021","citation":{"apa":"Huber‐Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N., Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda, W., &#38; Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. <i>Chemistry – A European Journal</i>, <i>27</i>(38), 9905–9918. <a href=\"https://doi.org/10.1002/chem.202100766\">https://doi.org/10.1002/chem.202100766</a>","short":"M. Huber‐Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R. Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda, M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.","mla":"Huber‐Gedert, Marina, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” <i>Chemistry – A European Journal</i>, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:<a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>.","bibtex":"@article{Huber‐Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={<a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>}, number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber‐Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }","ieee":"M. Huber‐Gedert <i>et al.</i>, “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” <i>Chemistry – A European Journal</i>, vol. 27, no. 38, pp. 9905–9918, 2021, doi: <a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>.","chicago":"Huber‐Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt, Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” <i>Chemistry – A European Journal</i> 27, no. 38 (2021): 9905–18. <a href=\"https://doi.org/10.1002/chem.202100766\">https://doi.org/10.1002/chem.202100766</a>.","ama":"Huber‐Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. <i>Chemistry – A European Journal</i>. 2021;27(38):9905-9918. doi:<a href=\"https://doi.org/10.1002/chem.202100766\">10.1002/chem.202100766</a>"},"page":"9905-9918","intvolume":"        27","publisher":"Wiley","date_updated":"2023-02-01T08:50:53Z","date_created":"2023-01-31T22:51:06Z","author":[{"full_name":"Huber‐Gedert, Marina","last_name":"Huber‐Gedert","first_name":"Marina"},{"last_name":"Nowakowski","full_name":"Nowakowski, Michał","first_name":"Michał"},{"last_name":"Kertmen","full_name":"Kertmen, Ahmet","first_name":"Ahmet"},{"first_name":"Lukas","full_name":"Burkhardt, Lukas","last_name":"Burkhardt"},{"full_name":"Lindner, Natalia","last_name":"Lindner","first_name":"Natalia"},{"first_name":"Roland","last_name":"Schoch","full_name":"Schoch, Roland"},{"full_name":"Herbst‐Irmer, Regine","last_name":"Herbst‐Irmer","first_name":"Regine"},{"first_name":"Adam","full_name":"Neuba, Adam","last_name":"Neuba"},{"last_name":"Schmitz","full_name":"Schmitz, Lennart","first_name":"Lennart"},{"last_name":"Choi","full_name":"Choi, Tae‐Kyu","first_name":"Tae‐Kyu"},{"first_name":"Jacek","last_name":"Kubicki","full_name":"Kubicki, Jacek"},{"first_name":"Wojciech","last_name":"Gawelda","full_name":"Gawelda, Wojciech"},{"last_name":"Bauer","full_name":"Bauer, Matthias","first_name":"Matthias"}],"volume":27,"title":"Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad","doi":"10.1002/chem.202100766","type":"journal_article","publication":"Chemistry – A European Journal","status":"public","_id":"41325","user_id":"78878","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"language":[{"iso":"eng"}]},{"citation":{"ama":"Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. <i>Chemistry – A European Journal</i>. 2021;27(68):17220-17229. doi:<a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>","chicago":"Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michal Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” <i>Chemistry – A European Journal</i> 27, no. 68 (2021): 17220–29. <a href=\"https://doi.org/10.1002/chem.202103099\">https://doi.org/10.1002/chem.202103099</a>.","ieee":"P. K. R. Panyam <i>et al.</i>, “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” <i>Chemistry – A European Journal</i>, vol. 27, no. 68, pp. 17220–17229, 2021, doi: <a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>.","bibtex":"@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={<a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michal and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }","mla":"Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” <i>Chemistry – A European Journal</i>, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:<a href=\"https://doi.org/10.1002/chem.202103099\">10.1002/chem.202103099</a>.","short":"P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.","apa":"Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., &#38; Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. <i>Chemistry – A European Journal</i>, <i>27</i>(68), 17220–17229. <a href=\"https://doi.org/10.1002/chem.202103099\">https://doi.org/10.1002/chem.202103099</a>"},"intvolume":"        27","page":"17220-17229","year":"2021","issue":"68","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"doi":"10.1002/chem.202103099","title":"Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes","date_created":"2023-01-31T22:50:03Z","author":[{"first_name":"Pradeep K. R.","full_name":"Panyam, Pradeep K. R.","last_name":"Panyam"},{"first_name":"Boshra","full_name":"Atwi, Boshra","last_name":"Atwi"},{"first_name":"Felix","last_name":"Ziegler","full_name":"Ziegler, Felix"},{"first_name":"Wolfgang","full_name":"Frey, Wolfgang","last_name":"Frey"},{"first_name":"Michal","full_name":"Nowakowski, Michal","last_name":"Nowakowski"},{"first_name":"Matthias","full_name":"Bauer, Matthias","last_name":"Bauer"},{"last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R.","first_name":"Michael R."}],"volume":27,"date_updated":"2023-02-01T08:51:03Z","publisher":"Wiley","status":"public","type":"journal_article","publication":"Chemistry – A European Journal","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"user_id":"78878","_id":"41322"},{"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"article_type":"original","language":[{"iso":"eng"}],"_id":"40998","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","abstract":[{"lang":"eng","text":"Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and growing range of applications. While COFs are well-established as heterogeneous catalysts, so far, their high and ordered porosity has scarcely been utilized to its full potential when it comes to spatially confined reactions in COF pores to alter the outcome of reactions. Here, we present a highly porous and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation reaction provides a molecularly precise heterogeneous olefin metathesis catalyst. An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O) for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency in selectivity, pointing to diffusion limitations induced by the pore confinement."}],"status":"public","publication":"Chemistry – A European Journal","type":"journal_article","title":"Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity","doi":"10.1002/chem.202104108","publisher":"Wiley","date_updated":"2023-01-31T08:05:07Z","volume":28,"date_created":"2023-01-30T16:48:22Z","author":[{"last_name":"Emmerling","full_name":"Emmerling, Sebastian T.","first_name":"Sebastian T."},{"full_name":"Ziegler, Felix","last_name":"Ziegler","first_name":"Felix"},{"last_name":"Fischer","full_name":"Fischer, Felix R.","first_name":"Felix R."},{"id":"48467","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Bernd","last_name":"Plietker","full_name":"Plietker, Bernd"},{"first_name":"Michael R.","full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser"},{"last_name":"Lotsch","full_name":"Lotsch, Bettina V.","first_name":"Bettina V."}],"year":"2021","intvolume":"        28","citation":{"bibtex":"@article{Emmerling_Ziegler_Fischer_Schoch_Bauer_Plietker_Buchmeiser_Lotsch_2021, title={Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity}, volume={28}, DOI={<a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>}, number={8}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Emmerling, Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer, Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.}, year={2021} }","mla":"Emmerling, Sebastian T., et al. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” <i>Chemistry – A European Journal</i>, vol. 28, no. 8, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>.","short":"S.T. Emmerling, F. Ziegler, F.R. Fischer, R. Schoch, M. Bauer, B. Plietker, M.R. Buchmeiser, B.V. Lotsch, Chemistry – A European Journal 28 (2021).","apa":"Emmerling, S. T., Ziegler, F., Fischer, F. R., Schoch, R., Bauer, M., Plietker, B., Buchmeiser, M. R., &#38; Lotsch, B. V. (2021). Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. <i>Chemistry – A European Journal</i>, <i>28</i>(8). <a href=\"https://doi.org/10.1002/chem.202104108\">https://doi.org/10.1002/chem.202104108</a>","ama":"Emmerling ST, Ziegler F, Fischer FR, et al. Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. <i>Chemistry – A European Journal</i>. 2021;28(8). doi:<a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>","chicago":"Emmerling, Sebastian T., Felix Ziegler, Felix R. Fischer, Roland Schoch, Matthias Bauer, Bernd Plietker, Michael R. Buchmeiser, and Bettina V. Lotsch. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” <i>Chemistry – A European Journal</i> 28, no. 8 (2021). <a href=\"https://doi.org/10.1002/chem.202104108\">https://doi.org/10.1002/chem.202104108</a>.","ieee":"S. T. Emmerling <i>et al.</i>, “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity,” <i>Chemistry – A European Journal</i>, vol. 28, no. 8, 2021, doi: <a href=\"https://doi.org/10.1002/chem.202104108\">10.1002/chem.202104108</a>."},"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","issue":"8"},{"issue":"61","year":"2021","date_created":"2023-01-30T16:49:33Z","publisher":"Royal Society of Chemistry (RSC)","title":"Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion","publication":"Chemical Communications","abstract":[{"text":"Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap","lang":"eng"}],"language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"publication_status":"published","publication_identifier":{"issn":["1359-7345","1364-548X"]},"citation":{"bibtex":"@article{Reuter_Kruse_Schoch_Lochbrunner_Bauer_Heinze_2021, title={Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion}, volume={57}, DOI={<a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>}, number={61}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}, year={2021}, pages={7541–7544} }","mla":"Reuter, Thomas, et al. “Higher MLCT Lifetime of Carbene Iron(&#60;scp&#62;ii&#60;/Scp&#62;) Complexes by Chelate Ring Expansion.” <i>Chemical Communications</i>, vol. 57, no. 61, Royal Society of Chemistry (RSC), 2021, pp. 7541–44, doi:<a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>.","short":"T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, K. Heinze, Chemical Communications 57 (2021) 7541–7544.","apa":"Reuter, T., Kruse, A., Schoch, R., Lochbrunner, S., Bauer, M., &#38; Heinze, K. (2021). Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion. <i>Chemical Communications</i>, <i>57</i>(61), 7541–7544. <a href=\"https://doi.org/10.1039/d1cc02173g\">https://doi.org/10.1039/d1cc02173g</a>","ieee":"T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, and K. Heinze, “Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion,” <i>Chemical Communications</i>, vol. 57, no. 61, pp. 7541–7544, 2021, doi: <a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>.","chicago":"Reuter, Thomas, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias Bauer, and Katja Heinze. “Higher MLCT Lifetime of Carbene Iron(&#60;scp&#62;ii&#60;/Scp&#62;) Complexes by Chelate Ring Expansion.” <i>Chemical Communications</i> 57, no. 61 (2021): 7541–44. <a href=\"https://doi.org/10.1039/d1cc02173g\">https://doi.org/10.1039/d1cc02173g</a>.","ama":"Reuter T, Kruse A, Schoch R, Lochbrunner S, Bauer M, Heinze K. Higher MLCT lifetime of carbene iron(&#60;scp&#62;ii&#60;/scp&#62;) complexes by chelate ring expansion. <i>Chemical Communications</i>. 2021;57(61):7541-7544. doi:<a href=\"https://doi.org/10.1039/d1cc02173g\">10.1039/d1cc02173g</a>"},"page":"7541-7544","intvolume":"        57","author":[{"first_name":"Thomas","last_name":"Reuter","full_name":"Reuter, Thomas"},{"full_name":"Kruse, Ayla","last_name":"Kruse","first_name":"Ayla"},{"id":"48467","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","first_name":"Roland"},{"full_name":"Lochbrunner, Stefan","last_name":"Lochbrunner","first_name":"Stefan"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Katja","full_name":"Heinze, Katja","last_name":"Heinze"}],"volume":57,"date_updated":"2023-01-31T08:06:16Z","doi":"10.1039/d1cc02173g","type":"journal_article","status":"public","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"_id":"41003","article_type":"original"},{"publication":"Angewandte Chemie International Edition","type":"journal_article","status":"public","abstract":[{"text":"Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts.","lang":"eng"}],"department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41000","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis"],"article_type":"original","issue":"1","publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","intvolume":"        61","citation":{"ieee":"P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis,” <i>Angewandte Chemie International Edition</i>, vol. 61, no. 1, 2021, doi: <a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>.","chicago":"Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” <i>Angewandte Chemie International Edition</i> 61, no. 1 (2021). <a href=\"https://doi.org/10.1002/anie.202110821\">https://doi.org/10.1002/anie.202110821</a>.","ama":"Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. <i>Angewandte Chemie International Edition</i>. 2021;61(1). doi:<a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>","apa":"Ghosh, P., Schoch, R., Bauer, M., &#38; Jacobi von Wangelin, A. (2021). Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. <i>Angewandte Chemie International Edition</i>, <i>61</i>(1). <a href=\"https://doi.org/10.1002/anie.202110821\">https://doi.org/10.1002/anie.202110821</a>","short":"P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie International Edition 61 (2021).","mla":"Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” <i>Angewandte Chemie International Edition</i>, vol. 61, no. 1, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>.","bibtex":"@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={<a href=\"https://doi.org/10.1002/anie.202110821\">10.1002/anie.202110821</a>}, number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021} }"},"year":"2021","volume":61,"author":[{"first_name":"Pradip","full_name":"Ghosh, Pradip","last_name":"Ghosh"},{"last_name":"Schoch","orcid":"0000-0003-2061-7289","full_name":"Schoch, Roland","id":"48467","first_name":"Roland"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"last_name":"Jacobi von Wangelin","full_name":"Jacobi von Wangelin, Axel","first_name":"Axel"}],"date_created":"2023-01-30T16:48:53Z","date_updated":"2023-01-31T08:05:26Z","publisher":"Wiley","doi":"10.1002/anie.202110821","title":"Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis"},{"title":"η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**","publisher":"Wiley","date_created":"2023-01-30T17:00:21Z","year":"2021","issue":"17","keyword":["General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"abstract":[{"text":"We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)]. Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2 (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the [SCP]− coordination mode is mainly governed by electronic, rather than steric factors. Quantum mechanical investigations reveal large contributions of the antibonding π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)} (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization is proposed based on DFT calculations.","lang":"eng"}],"publication":"Angewandte Chemie International Edition","doi":"10.1002/anie.202100559","date_updated":"2023-01-31T08:06:50Z","volume":60,"author":[{"last_name":"Watt","full_name":"Watt, Fabian A.","first_name":"Fabian A."},{"first_name":"Lukas","last_name":"Burkhardt","full_name":"Burkhardt, Lukas"},{"first_name":"Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","full_name":"Schoch, Roland","id":"48467"},{"last_name":"Mitzinger","full_name":"Mitzinger, Stefan","first_name":"Stefan"},{"first_name":"Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","full_name":"Bauer, Matthias"},{"first_name":"Florian","last_name":"Weigend","full_name":"Weigend, Florian"},{"first_name":"Jose M.","last_name":"Goicoechea","full_name":"Goicoechea, Jose M."},{"last_name":"Tambornino","full_name":"Tambornino, Frank","first_name":"Frank"},{"full_name":"Hohloch, Stephan","last_name":"Hohloch","first_name":"Stephan"}],"intvolume":"        60","page":"9534-9539","citation":{"chicago":"Watt, Fabian A., Lukas Burkhardt, Roland Schoch, Stefan Mitzinger, Matthias Bauer, Florian Weigend, Jose M. Goicoechea, Frank Tambornino, and Stephan Hohloch. “η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” <i>Angewandte Chemie International Edition</i> 60, no. 17 (2021): 9534–39. <a href=\"https://doi.org/10.1002/anie.202100559\">https://doi.org/10.1002/anie.202100559</a>.","ieee":"F. A. Watt <i>et al.</i>, “η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**,” <i>Angewandte Chemie International Edition</i>, vol. 60, no. 17, pp. 9534–9539, 2021, doi: <a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>.","ama":"Watt FA, Burkhardt L, Schoch R, et al. η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. <i>Angewandte Chemie International Edition</i>. 2021;60(17):9534-9539. doi:<a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>","mla":"Watt, Fabian A., et al. “η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” <i>Angewandte Chemie International Edition</i>, vol. 60, no. 17, Wiley, 2021, pp. 9534–39, doi:<a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>.","short":"F.A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend, J.M. Goicoechea, F. Tambornino, S. Hohloch, Angewandte Chemie International Edition 60 (2021) 9534–9539.","bibtex":"@article{Watt_Burkhardt_Schoch_Mitzinger_Bauer_Weigend_Goicoechea_Tambornino_Hohloch_2021, title={η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}, volume={60}, DOI={<a href=\"https://doi.org/10.1002/anie.202100559\">10.1002/anie.202100559</a>}, number={17}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Watt, Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer, Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and Hohloch, Stephan}, year={2021}, pages={9534–9539} }","apa":"Watt, F. A., Burkhardt, L., Schoch, R., Mitzinger, S., Bauer, M., Weigend, F., Goicoechea, J. M., Tambornino, F., &#38; Hohloch, S. (2021). η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**. <i>Angewandte Chemie International Edition</i>, <i>60</i>(17), 9534–9539. <a href=\"https://doi.org/10.1002/anie.202100559\">https://doi.org/10.1002/anie.202100559</a>"},"publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","article_type":"original","_id":"41010","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","status":"public","type":"journal_article"},{"publication":"Angewandte Chemie International Edition","type":"journal_article","status":"public","user_id":"100383","_id":"46000","language":[{"iso":"eng"}],"extern":"1","keyword":["General Chemistry","Catalysis"],"issue":"29","publication_identifier":{"issn":["1433-7851","1521-3773"]},"publication_status":"published","intvolume":"        60","page":"16019-16026","citation":{"apa":"Su, R., Wang, Z., Zhu, L., Pan, Y., Zhang, D., Wen, H., Luo, Z., Li, L., Li, F., Wu, M., He, L., Sharma, P., &#38; Seidel, J. (2021). Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting. <i>Angewandte Chemie International Edition</i>, <i>60</i>(29), 16019–16026. <a href=\"https://doi.org/10.1002/anie.202103112\">https://doi.org/10.1002/anie.202103112</a>","short":"R. Su, Z. Wang, L. Zhu, Y. Pan, D. Zhang, H. Wen, Z. Luo, L. Li, F. Li, M. Wu, L. He, P. Sharma, J. Seidel, Angewandte Chemie International Edition 60 (2021) 16019–16026.","bibtex":"@article{Su_Wang_Zhu_Pan_Zhang_Wen_Luo_Li_Li_Wu_et al._2021, title={Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting}, volume={60}, DOI={<a href=\"https://doi.org/10.1002/anie.202103112\">10.1002/anie.202103112</a>}, number={29}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Su, Ran and Wang, Zhipeng and Zhu, Lina and Pan, Ying and Zhang, Dawei and Wen, Hui and Luo, Zheng‐Dong and Li, Linglong and Li, Fa‐tang and Wu, Ming and et al.}, year={2021}, pages={16019–16026} }","mla":"Su, Ran, et al. “Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting.” <i>Angewandte Chemie International Edition</i>, vol. 60, no. 29, Wiley, 2021, pp. 16019–26, doi:<a href=\"https://doi.org/10.1002/anie.202103112\">10.1002/anie.202103112</a>.","ieee":"R. Su <i>et al.</i>, “Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting,” <i>Angewandte Chemie International Edition</i>, vol. 60, no. 29, pp. 16019–16026, 2021, doi: <a href=\"https://doi.org/10.1002/anie.202103112\">10.1002/anie.202103112</a>.","chicago":"Su, Ran, Zhipeng Wang, Lina Zhu, Ying Pan, Dawei Zhang, Hui Wen, Zheng‐Dong Luo, et al. “Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting.” <i>Angewandte Chemie International Edition</i> 60, no. 29 (2021): 16019–26. <a href=\"https://doi.org/10.1002/anie.202103112\">https://doi.org/10.1002/anie.202103112</a>.","ama":"Su R, Wang Z, Zhu L, et al. Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting. <i>Angewandte Chemie International Edition</i>. 2021;60(29):16019-16026. doi:<a href=\"https://doi.org/10.1002/anie.202103112\">10.1002/anie.202103112</a>"},"year":"2021","volume":60,"author":[{"last_name":"Su","full_name":"Su, Ran","first_name":"Ran"},{"first_name":"Zhipeng","full_name":"Wang, Zhipeng","last_name":"Wang"},{"first_name":"Lina","full_name":"Zhu, Lina","last_name":"Zhu"},{"full_name":"Pan, Ying","id":"100383","last_name":"Pan","first_name":"Ying"},{"first_name":"Dawei","full_name":"Zhang, Dawei","last_name":"Zhang"},{"last_name":"Wen","full_name":"Wen, Hui","first_name":"Hui"},{"last_name":"Luo","full_name":"Luo, Zheng‐Dong","first_name":"Zheng‐Dong"},{"full_name":"Li, Linglong","last_name":"Li","first_name":"Linglong"},{"last_name":"Li","full_name":"Li, Fa‐tang","first_name":"Fa‐tang"},{"first_name":"Ming","last_name":"Wu","full_name":"Wu, Ming"},{"first_name":"Liqiang","full_name":"He, Liqiang","last_name":"He"},{"first_name":"Pankaj","last_name":"Sharma","full_name":"Sharma, Pankaj"},{"first_name":"Jan","full_name":"Seidel, Jan","last_name":"Seidel"}],"date_created":"2023-07-11T14:45:01Z","publisher":"Wiley","date_updated":"2023-07-11T16:41:48Z","doi":"10.1002/anie.202103112","title":"Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting"},{"publication":"Chemical Communications","type":"journal_article","abstract":[{"lang":"eng","text":"Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+ pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with four mesoionic carbenes."}],"status":"public","_id":"41007","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composite","Metallkomplexe","Optical and Magnetic Materials","Catalysis"],"article_type":"original","language":[{"iso":"eng"}],"publication_identifier":{"issn":["1359-7345","1364-548X"]},"publication_status":"published","issue":"54","year":"2021","page":"6640-6643","intvolume":"        57","citation":{"ama":"Dierks P, Kruse A, Bokareva OS, et al. Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. <i>Chemical Communications</i>. 2021;57(54):6640-6643. doi:<a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>","ieee":"P. Dierks <i>et al.</i>, “Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes,” <i>Chemical Communications</i>, vol. 57, no. 54, pp. 6640–6643, 2021, doi: <a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>.","chicago":"Dierks, Philipp, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens Kalmbach, Marc Baltrun, Adam Neuba, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” <i>Chemical Communications</i> 57, no. 54 (2021): 6640–43. <a href=\"https://doi.org/10.1039/d1cc01716k\">https://doi.org/10.1039/d1cc01716k</a>.","apa":"Dierks, P., Kruse, A., Bokareva, O. S., Al-Marri, M. J., Kalmbach, J., Baltrun, M., Neuba, A., Schoch, R., Hohloch, S., Heinze, K., Seitz, M., Kühn, O., Lochbrunner, S., &#38; Bauer, M. (2021). Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. <i>Chemical Communications</i>, <i>57</i>(54), 6640–6643. <a href=\"https://doi.org/10.1039/d1cc01716k\">https://doi.org/10.1039/d1cc01716k</a>","mla":"Dierks, Philipp, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” <i>Chemical Communications</i>, vol. 57, no. 54, Royal Society of Chemistry (RSC), 2021, pp. 6640–43, doi:<a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>.","short":"P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, J. Kalmbach, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner, M. Bauer, Chemical Communications 57 (2021) 6640–6643.","bibtex":"@article{Dierks_Kruse_Bokareva_Al-Marri_Kalmbach_Baltrun_Neuba_Schoch_Hohloch_Heinze_et al._2021, title={Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes}, volume={57}, DOI={<a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>}, number={54}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri, Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland and Hohloch, Stephan and Heinze, Katja and et al.}, year={2021}, pages={6640–6643} }"},"date_updated":"2024-10-11T08:42:44Z","publisher":"Royal Society of Chemistry (RSC)","volume":57,"date_created":"2023-01-30T16:59:55Z","author":[{"first_name":"Philipp","last_name":"Dierks","full_name":"Dierks, Philipp"},{"last_name":"Kruse","full_name":"Kruse, Ayla","first_name":"Ayla"},{"last_name":"Bokareva","full_name":"Bokareva, Olga S.","first_name":"Olga S."},{"full_name":"Al-Marri, Mohammed J.","last_name":"Al-Marri","first_name":"Mohammed J."},{"first_name":"Jens","last_name":"Kalmbach","full_name":"Kalmbach, Jens"},{"last_name":"Baltrun","full_name":"Baltrun, Marc","first_name":"Marc"},{"full_name":"Neuba, Adam","last_name":"Neuba","first_name":"Adam"},{"orcid":"0000-0003-2061-7289","last_name":"Schoch","full_name":"Schoch, Roland","id":"48467","first_name":"Roland"},{"full_name":"Hohloch, Stephan","last_name":"Hohloch","first_name":"Stephan"},{"first_name":"Katja","full_name":"Heinze, Katja","last_name":"Heinze"},{"first_name":"Michael","full_name":"Seitz, Michael","last_name":"Seitz"},{"first_name":"Oliver","last_name":"Kühn","full_name":"Kühn, Oliver"},{"first_name":"Stefan","last_name":"Lochbrunner","full_name":"Lochbrunner, Stefan"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"}],"title":"Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes","doi":"10.1039/d1cc01716k"},{"date_updated":"2024-05-07T11:42:56Z","publisher":"American Chemical Society (ACS)","date_created":"2023-01-30T17:12:11Z","author":[{"last_name":"Benedikter","full_name":"Benedikter, Mathis","first_name":"Mathis"},{"last_name":"Musso","full_name":"Musso, Janis","first_name":"Janis"},{"first_name":"Manoj K.","full_name":"Kesharwani, Manoj K.","last_name":"Kesharwani"},{"first_name":"K. Leonard","full_name":"Sterz, K. Leonard","last_name":"Sterz"},{"first_name":"Iris","last_name":"Elser","full_name":"Elser, Iris"},{"first_name":"Felix","last_name":"Ziegler","full_name":"Ziegler, Felix"},{"full_name":"Fischer, Felix","last_name":"Fischer","first_name":"Felix"},{"full_name":"Plietker, Bernd","last_name":"Plietker","first_name":"Bernd"},{"last_name":"Frey","full_name":"Frey, Wolfgang","first_name":"Wolfgang"},{"first_name":"Johannes","full_name":"Kästner, Johannes","last_name":"Kästner"},{"first_name":"Mario","last_name":"Winkler","full_name":"Winkler, Mario"},{"last_name":"van Slageren","full_name":"van Slageren, Joris","first_name":"Joris"},{"first_name":"Michał","id":"78878","full_name":"Nowakowski, Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser","first_name":"Michael R."}],"volume":10,"title":"Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach","doi":"10.1021/acscatal.0c03978","publication_status":"published","publication_identifier":{"issn":["2155-5435","2155-5435"]},"issue":"24","year":"2020","citation":{"mla":"Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” <i>ACS Catalysis</i>, vol. 10, no. 24, American Chemical Society (ACS), 2020, pp. 14810–23, doi:<a href=\"https://doi.org/10.1021/acscatal.0c03978\">10.1021/acscatal.0c03978</a>.","bibtex":"@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach}, volume={10}, DOI={<a href=\"https://doi.org/10.1021/acscatal.0c03978\">10.1021/acscatal.0c03978</a>}, number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz, K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker, Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823} }","short":"M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler, F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M. Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.","apa":"Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler, F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren, J., Nowakowski, M., Bauer, M., &#38; Buchmeiser, M. R. (2020). 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Hämisch, R. Pollak, S. Ebbinghaus, K. Huber, Chemistry – A European Journal 26 (2020) 7041–7050.","bibtex":"@article{Hämisch_Pollak_Ebbinghaus_Huber_2020, title={Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo}, volume={26}, DOI={<a href=\"https://doi.org/10.1002/chem.202000113\">10.1002/chem.202000113</a>}, number={31}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Hämisch, Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}, year={2020}, pages={7041–7050} }","mla":"Hämisch, Benjamin, et al. “Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo.” <i>Chemistry – A European Journal</i>, vol. 26, no. 31, Wiley, 2020, pp. 7041–50, doi:<a href=\"https://doi.org/10.1002/chem.202000113\">10.1002/chem.202000113</a>.","apa":"Hämisch, B., Pollak, R., Ebbinghaus, S., &#38; Huber, K. (2020). Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo. <i>Chemistry – A European Journal</i>, <i>26</i>(31), 7041–7050. <a href=\"https://doi.org/10.1002/chem.202000113\">https://doi.org/10.1002/chem.202000113</a>","ieee":"B. Hämisch, R. Pollak, S. Ebbinghaus, and K. Huber, “Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo,” <i>Chemistry – A European Journal</i>, vol. 26, no. 31, pp. 7041–7050, 2020, doi: <a href=\"https://doi.org/10.1002/chem.202000113\">10.1002/chem.202000113</a>.","chicago":"Hämisch, Benjamin, Roland Pollak, Simon Ebbinghaus, and Klaus Huber. “Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo.” <i>Chemistry – A European Journal</i> 26, no. 31 (2020): 7041–50. <a href=\"https://doi.org/10.1002/chem.202000113\">https://doi.org/10.1002/chem.202000113</a>.","ama":"Hämisch B, Pollak R, Ebbinghaus S, Huber K. Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo. <i>Chemistry – A European Journal</i>. 2020;26(31):7041-7050. doi:<a href=\"https://doi.org/10.1002/chem.202000113\">10.1002/chem.202000113</a>"},"intvolume":"        26","page":"7041-7050","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"doi":"10.1002/chem.202000113","date_updated":"2023-02-06T12:26:26Z","author":[{"full_name":"Hämisch, Benjamin","last_name":"Hämisch","first_name":"Benjamin"},{"last_name":"Pollak","full_name":"Pollak, Roland","first_name":"Roland"},{"first_name":"Simon","last_name":"Ebbinghaus","full_name":"Ebbinghaus, Simon"},{"id":"237","full_name":"Huber, Klaus","last_name":"Huber","first_name":"Klaus"}],"volume":26,"status":"public","type":"journal_article","_id":"41824","user_id":"237","department":[{"_id":"314"}]},{"_id":"41025","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","keyword":["Xray","Catalysis"],"language":[{"iso":"eng"}],"publication":"Nanoscale","type":"journal_article","abstract":[{"lang":"eng","text":"We investigate the structure-activity correlations of methanation catalysts obtained by thermal decomposition of a Ni-based metal-organic framework, using pair distribution function, X-ray absorption spectroscopy and X-ray diffraction."}],"status":"public","date_updated":"2025-08-15T12:43:52Z","publisher":"Royal Society of Chemistry (RSC)","volume":12,"author":[{"first_name":"Nils","full_name":"Prinz, Nils","last_name":"Prinz"},{"first_name":"Leif","full_name":"Schwensow, Leif","last_name":"Schwensow"},{"last_name":"Strübbe","full_name":"Strübbe, Sven","id":"76968","first_name":"Sven"},{"full_name":"Jentys, Andreas","last_name":"Jentys","first_name":"Andreas"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"last_name":"Kleist","full_name":"Kleist, Wolfgang","first_name":"Wolfgang"},{"last_name":"Zobel","full_name":"Zobel, Mirijam","first_name":"Mirijam"}],"date_created":"2023-01-30T17:47:17Z","title":"Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition","doi":"10.1039/d0nr01750g","publication_identifier":{"issn":["2040-3364","2040-3372"]},"publication_status":"published","issue":"29","year":"2020","page":"15800-15813","intvolume":"        12","citation":{"apa":"Prinz, N., Schwensow, L., Strübbe, S., Jentys, A., Bauer, M., Kleist, W., &#38; Zobel, M. (2020). Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition. <i>Nanoscale</i>, <i>12</i>(29), 15800–15813. <a href=\"https://doi.org/10.1039/d0nr01750g\">https://doi.org/10.1039/d0nr01750g</a>","short":"N. Prinz, L. Schwensow, S. Strübbe, A. Jentys, M. Bauer, W. Kleist, M. Zobel, Nanoscale 12 (2020) 15800–15813.","bibtex":"@article{Prinz_Schwensow_Strübbe_Jentys_Bauer_Kleist_Zobel_2020, title={Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition}, volume={12}, DOI={<a href=\"https://doi.org/10.1039/d0nr01750g\">10.1039/d0nr01750g</a>}, number={29}, journal={Nanoscale}, publisher={Royal Society of Chemistry (RSC)}, author={Prinz, Nils and Schwensow, Leif and Strübbe, Sven and Jentys, Andreas and Bauer, Matthias and Kleist, Wolfgang and Zobel, Mirijam}, year={2020}, pages={15800–15813} }","mla":"Prinz, Nils, et al. “Hard X-Ray-Based Techniques for Structural Investigations of CO2 Methanation Catalysts Prepared by MOF Decomposition.” <i>Nanoscale</i>, vol. 12, no. 29, Royal Society of Chemistry (RSC), 2020, pp. 15800–13, doi:<a href=\"https://doi.org/10.1039/d0nr01750g\">10.1039/d0nr01750g</a>.","ieee":"N. Prinz <i>et al.</i>, “Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition,” <i>Nanoscale</i>, vol. 12, no. 29, pp. 15800–15813, 2020, doi: <a href=\"https://doi.org/10.1039/d0nr01750g\">10.1039/d0nr01750g</a>.","chicago":"Prinz, Nils, Leif Schwensow, Sven Strübbe, Andreas Jentys, Matthias Bauer, Wolfgang Kleist, and Mirijam Zobel. “Hard X-Ray-Based Techniques for Structural Investigations of CO2 Methanation Catalysts Prepared by MOF Decomposition.” <i>Nanoscale</i> 12, no. 29 (2020): 15800–813. <a href=\"https://doi.org/10.1039/d0nr01750g\">https://doi.org/10.1039/d0nr01750g</a>.","ama":"Prinz N, Schwensow L, Strübbe S, et al. Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition. <i>Nanoscale</i>. 2020;12(29):15800-15813. doi:<a href=\"https://doi.org/10.1039/d0nr01750g\">10.1039/d0nr01750g</a>"}}]