[{"status":"public","type":"journal_article","user_id":"27611","department":[{"_id":"35"},{"_id":"306"}],"_id":"41050","citation":{"short":"P. Veit, C. Volkert, C. Förster, V. Ksenofontov, S. Schlicher, M. Bauer, K. Heinze, Chemical Communications 55 (2019) 4615–4618.","mla":"Veit, Philipp, et al. “Gold(&#60;scp&#62;ii&#60;/Scp&#62;) in Redox-Switchable Gold(&#60;scp&#62;i&#60;/Scp&#62;) Catalysis.” <i>Chemical Communications</i>, vol. 55, no. 32, Royal Society of Chemistry (RSC), 2019, pp. 4615–18, doi:<a href=\"https://doi.org/10.1039/c9cc00283a\">10.1039/c9cc00283a</a>.","bibtex":"@article{Veit_Volkert_Förster_Ksenofontov_Schlicher_Bauer_Heinze_2019, title={Gold(&#60;scp&#62;ii&#60;/scp&#62;) in redox-switchable gold(&#60;scp&#62;i&#60;/scp&#62;) catalysis}, volume={55}, DOI={<a href=\"https://doi.org/10.1039/c9cc00283a\">10.1039/c9cc00283a</a>}, number={32}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Veit, Philipp and Volkert, Carla and Förster, Christoph and Ksenofontov, Vadim and Schlicher, Steffen and Bauer, Matthias and Heinze, Katja}, year={2019}, pages={4615–4618} }","apa":"Veit, P., Volkert, C., Förster, C., Ksenofontov, V., Schlicher, S., Bauer, M., &#38; Heinze, K. (2019). Gold(&#60;scp&#62;ii&#60;/scp&#62;) in redox-switchable gold(&#60;scp&#62;i&#60;/scp&#62;) catalysis. <i>Chemical Communications</i>, <i>55</i>(32), 4615–4618. <a href=\"https://doi.org/10.1039/c9cc00283a\">https://doi.org/10.1039/c9cc00283a</a>","ieee":"P. Veit <i>et al.</i>, “Gold(&#60;scp&#62;ii&#60;/scp&#62;) in redox-switchable gold(&#60;scp&#62;i&#60;/scp&#62;) catalysis,” <i>Chemical Communications</i>, vol. 55, no. 32, pp. 4615–4618, 2019, doi: <a href=\"https://doi.org/10.1039/c9cc00283a\">10.1039/c9cc00283a</a>.","chicago":"Veit, Philipp, Carla Volkert, Christoph Förster, Vadim Ksenofontov, Steffen Schlicher, Matthias Bauer, and Katja Heinze. “Gold(&#60;scp&#62;ii&#60;/Scp&#62;) in Redox-Switchable Gold(&#60;scp&#62;i&#60;/Scp&#62;) Catalysis.” <i>Chemical Communications</i> 55, no. 32 (2019): 4615–18. <a href=\"https://doi.org/10.1039/c9cc00283a\">https://doi.org/10.1039/c9cc00283a</a>.","ama":"Veit P, Volkert C, Förster C, et al. Gold(&#60;scp&#62;ii&#60;/scp&#62;) in redox-switchable gold(&#60;scp&#62;i&#60;/scp&#62;) catalysis. <i>Chemical Communications</i>. 2019;55(32):4615-4618. doi:<a href=\"https://doi.org/10.1039/c9cc00283a\">10.1039/c9cc00283a</a>"},"page":"4615-4618","intvolume":"        55","publication_status":"published","publication_identifier":{"issn":["1359-7345","1364-548X"]},"doi":"10.1039/c9cc00283a","author":[{"first_name":"Philipp","last_name":"Veit","full_name":"Veit, Philipp"},{"full_name":"Volkert, Carla","last_name":"Volkert","first_name":"Carla"},{"first_name":"Christoph","full_name":"Förster, Christoph","last_name":"Förster"},{"last_name":"Ksenofontov","full_name":"Ksenofontov, Vadim","first_name":"Vadim"},{"first_name":"Steffen","full_name":"Schlicher, Steffen","last_name":"Schlicher"},{"first_name":"Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias","id":"47241"},{"last_name":"Heinze","full_name":"Heinze, Katja","first_name":"Katja"}],"volume":55,"date_updated":"2023-01-31T08:29:37Z","abstract":[{"text":"<p>Gold(<sc>ii</sc>) species catalyse the cyclisation of <italic>N</italic>(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the neutral gold(<sc>i</sc>) complex is inactive indicating a gold(<sc>ii</sc>/<sc>i</sc>) redox-switch.</p>","lang":"eng"}],"publication":"Chemical Communications","language":[{"iso":"eng"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"year":"2019","issue":"32","title":"Gold(<scp>ii</scp>) in redox-switchable gold(<scp>i</scp>) catalysis","date_created":"2023-01-30T20:01:46Z","publisher":"Royal Society of Chemistry (RSC)"},{"keyword":["Colloid and Surface Chemistry","Biochemistry","General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"_id":"40584","user_id":"98120","status":"public","type":"journal_article","publication":"Journal of the American Chemical Society","title":"Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides","doi":"10.1021/jacs.8b12860","publisher":"American Chemical Society (ACS)","date_updated":"2023-01-27T16:28:18Z","author":[{"last_name":"Castillo-Blas","full_name":"Castillo-Blas, Celia","first_name":"Celia"},{"orcid":"https://orcid.org/0000-0002-8438-9548","last_name":"Lopez Salas","id":"98120","full_name":"Lopez Salas, Nieves","first_name":"Nieves"},{"first_name":"María C.","last_name":"Gutiérrez","full_name":"Gutiérrez, María C."},{"last_name":"Puente-Orench","full_name":"Puente-Orench, Inés","first_name":"Inés"},{"first_name":"Enrique","last_name":"Gutiérrez-Puebla","full_name":"Gutiérrez-Puebla, Enrique"},{"full_name":"Ferrer, M. Luisa","last_name":"Ferrer","first_name":"M. Luisa"},{"first_name":"M. Ángeles","last_name":"Monge","full_name":"Monge, M. Ángeles"},{"full_name":"Gándara, Felipe","last_name":"Gándara","first_name":"Felipe"}],"date_created":"2023-01-27T16:21:47Z","volume":141,"year":"2019","citation":{"bibtex":"@article{Castillo-Blas_Lopez Salas_Gutiérrez_Puente-Orench_Gutiérrez-Puebla_Ferrer_Monge_Gándara_2019, title={Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides}, volume={141}, DOI={<a href=\"https://doi.org/10.1021/jacs.8b12860\">10.1021/jacs.8b12860</a>}, number={4}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Castillo-Blas, Celia and Lopez Salas, Nieves and Gutiérrez, María C. and Puente-Orench, Inés and Gutiérrez-Puebla, Enrique and Ferrer, M. Luisa and Monge, M. Ángeles and Gándara, Felipe}, year={2019}, pages={1766–1774} }","mla":"Castillo-Blas, Celia, et al. “Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides.” <i>Journal of the American Chemical Society</i>, vol. 141, no. 4, American Chemical Society (ACS), 2019, pp. 1766–74, doi:<a href=\"https://doi.org/10.1021/jacs.8b12860\">10.1021/jacs.8b12860</a>.","short":"C. Castillo-Blas, N. Lopez Salas, M.C. Gutiérrez, I. Puente-Orench, E. Gutiérrez-Puebla, M.L. Ferrer, M.Á. Monge, F. Gándara, Journal of the American Chemical Society 141 (2019) 1766–1774.","apa":"Castillo-Blas, C., Lopez Salas, N., Gutiérrez, M. C., Puente-Orench, I., Gutiérrez-Puebla, E., Ferrer, M. L., Monge, M. Á., &#38; Gándara, F. (2019). Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides. <i>Journal of the American Chemical Society</i>, <i>141</i>(4), 1766–1774. <a href=\"https://doi.org/10.1021/jacs.8b12860\">https://doi.org/10.1021/jacs.8b12860</a>","chicago":"Castillo-Blas, Celia, Nieves Lopez Salas, María C. Gutiérrez, Inés Puente-Orench, Enrique Gutiérrez-Puebla, M. Luisa Ferrer, M. Ángeles Monge, and Felipe Gándara. “Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides.” <i>Journal of the American Chemical Society</i> 141, no. 4 (2019): 1766–74. <a href=\"https://doi.org/10.1021/jacs.8b12860\">https://doi.org/10.1021/jacs.8b12860</a>.","ieee":"C. Castillo-Blas <i>et al.</i>, “Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides,” <i>Journal of the American Chemical Society</i>, vol. 141, no. 4, pp. 1766–1774, 2019, doi: <a href=\"https://doi.org/10.1021/jacs.8b12860\">10.1021/jacs.8b12860</a>.","ama":"Castillo-Blas C, Lopez Salas N, Gutiérrez MC, et al. Encoding Metal–Cation Arrangements in Metal–Organic Frameworks for Programming the Composition of Electrocatalytically Active Multimetal Oxides. <i>Journal of the American Chemical Society</i>. 2019;141(4):1766-1774. doi:<a href=\"https://doi.org/10.1021/jacs.8b12860\">10.1021/jacs.8b12860</a>"},"intvolume":"       141","page":"1766-1774","publication_status":"published","publication_identifier":{"issn":["0002-7863","1520-5126"]},"issue":"4"},{"keyword":["solid-state nmr","heterogeneous catalysis","dynamic nuclear polarization","Ferroelectrics","Nanocatalysis","Surface reactions"],"extern":"1","language":[{"iso":"eng"}],"_id":"63960","user_id":"100715","abstract":[{"lang":"eng","text":"Recent advances in solid-state nuclear magnetic resonance (NMR) spectroscopy and dynamic nuclear polarization (DNP) of nanostructured materials are reviewed. A first group of materials is based on crystalline nanocellulose (CNC) or microcrystalline cellulose (MCC), which are used as carrier materials for dye molecules, catalysts or in combination with heterocyclic molecules as ion conducting membranes. These materials have widespread applications in sensorics, optics, catalysis or fuel cell research. A second group are metal oxides such as V-Mo-W oxides, which are of enormous importance in the manufacturing process of basic chemicals. The third group are catalytically active nanocrystalline metal nanoparticles, coated with protectants or embedded in polymers. The last group includes of lead-free perovskite materials, which are employed as environmentally benign substitution materials for conventional lead-based electronics materials. These materials are discussed in terms of their application and physico-chemical characterization by solid-state NMR techniques, combined with gas-phase NMR and quantum-chemical modelling on the density functional theory (DFT) level. The application of multinuclear 1H, 2H, 13C, 15N and 23Na solid state NMR techniques under static or MAS conditions for the characterization of these materials, their surfaces and processes on their surfaces is discussed. Moreover, the analytic power of the combination of these techniques with DNP for the identification of low-concentrated carbon and nitrogen containing surface species in natural abundance is reviewed. Finally, approaches for sensitivity enhancement by DNP of quadrupolar nuclei such as 17O and 51V are presented that enable the identification of catalytic sites in metal oxide catalysts."}],"status":"public","type":"journal_article","publication":"Annual Reports on NMR Spectroscopy","title":"Solid-state NMR of nanocrystals","doi":"10.1016/bs.arnmr.2018.12.001","date_updated":"2026-02-17T16:17:56Z","author":[{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"full_name":"Groszewicz, Pedro B.","last_name":"Groszewicz","first_name":"Pedro B."},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"}],"date_created":"2026-02-07T15:37:03Z","volume":97,"year":"2019","citation":{"ieee":"T. Gutmann, P. B. Groszewicz, and G. Buntkowsky, “Solid-state NMR of nanocrystals,” <i>Annual Reports on NMR Spectroscopy</i>, vol. 97, pp. 1–82, 2019, doi: <a href=\"https://doi.org/10.1016/bs.arnmr.2018.12.001\">10.1016/bs.arnmr.2018.12.001</a>.","chicago":"Gutmann, Torsten, Pedro B. Groszewicz, and Gerd Buntkowsky. “Solid-State NMR of Nanocrystals.” <i>Annual Reports on NMR Spectroscopy</i> 97 (2019): 1–82. <a href=\"https://doi.org/10.1016/bs.arnmr.2018.12.001\">https://doi.org/10.1016/bs.arnmr.2018.12.001</a>.","ama":"Gutmann T, Groszewicz PB, Buntkowsky G. Solid-state NMR of nanocrystals. <i>Annual Reports on NMR Spectroscopy</i>. 2019;97:1–82. doi:<a href=\"https://doi.org/10.1016/bs.arnmr.2018.12.001\">10.1016/bs.arnmr.2018.12.001</a>","apa":"Gutmann, T., Groszewicz, P. B., &#38; Buntkowsky, G. (2019). Solid-state NMR of nanocrystals. <i>Annual Reports on NMR Spectroscopy</i>, <i>97</i>, 1–82. <a href=\"https://doi.org/10.1016/bs.arnmr.2018.12.001\">https://doi.org/10.1016/bs.arnmr.2018.12.001</a>","mla":"Gutmann, Torsten, et al. “Solid-State NMR of Nanocrystals.” <i>Annual Reports on NMR Spectroscopy</i>, vol. 97, 2019, pp. 1–82, doi:<a href=\"https://doi.org/10.1016/bs.arnmr.2018.12.001\">10.1016/bs.arnmr.2018.12.001</a>.","short":"T. Gutmann, P.B. Groszewicz, G. Buntkowsky, Annual Reports on NMR Spectroscopy 97 (2019) 1–82.","bibtex":"@article{Gutmann_Groszewicz_Buntkowsky_2019, title={Solid-state NMR of nanocrystals}, volume={97}, DOI={<a href=\"https://doi.org/10.1016/bs.arnmr.2018.12.001\">10.1016/bs.arnmr.2018.12.001</a>}, journal={Annual Reports on NMR Spectroscopy}, author={Gutmann, Torsten and Groszewicz, Pedro B. and Buntkowsky, Gerd}, year={2019}, pages={1–82} }"},"page":"1–82","intvolume":"        97"},{"citation":{"ieee":"A. Reitze, N. Jürgensmeyer, S. Lier, M. Kohnke, J. Riese, and M. Grünewald, “Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals,” <i>Angewandte Chemie International Edition</i>, vol. 57, no. 16, pp. 4242–4247, 2018, doi: <a href=\"https://doi.org/10.1002/anie.201711571\">10.1002/anie.201711571</a>.","chicago":"Reitze, Arnulf, Nikolas Jürgensmeyer, Stefan Lier, Marco Kohnke, Julia Riese, and Marcus Grünewald. “Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals.” <i>Angewandte Chemie International Edition</i> 57, no. 16 (2018): 4242–47. <a href=\"https://doi.org/10.1002/anie.201711571\">https://doi.org/10.1002/anie.201711571</a>.","ama":"Reitze A, Jürgensmeyer N, Lier S, Kohnke M, Riese J, Grünewald M. Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals. <i>Angewandte Chemie International Edition</i>. 2018;57(16):4242-4247. doi:<a href=\"https://doi.org/10.1002/anie.201711571\">10.1002/anie.201711571</a>","mla":"Reitze, Arnulf, et al. “Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals.” <i>Angewandte Chemie International Edition</i>, vol. 57, no. 16, Wiley, 2018, pp. 4242–47, doi:<a href=\"https://doi.org/10.1002/anie.201711571\">10.1002/anie.201711571</a>.","short":"A. Reitze, N. Jürgensmeyer, S. Lier, M. Kohnke, J. Riese, M. Grünewald, Angewandte Chemie International Edition 57 (2018) 4242–4247.","bibtex":"@article{Reitze_Jürgensmeyer_Lier_Kohnke_Riese_Grünewald_2018, title={Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals}, volume={57}, DOI={<a href=\"https://doi.org/10.1002/anie.201711571\">10.1002/anie.201711571</a>}, number={16}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Reitze, Arnulf and Jürgensmeyer, Nikolas and Lier, Stefan and Kohnke, Marco and Riese, Julia and Grünewald, Marcus}, year={2018}, pages={4242–4247} }","apa":"Reitze, A., Jürgensmeyer, N., Lier, S., Kohnke, M., Riese, J., &#38; Grünewald, M. (2018). Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals. <i>Angewandte Chemie International Edition</i>, <i>57</i>(16), 4242–4247. <a href=\"https://doi.org/10.1002/anie.201711571\">https://doi.org/10.1002/anie.201711571</a>"},"page":"4242-4247","intvolume":"        57","publication_status":"published","publication_identifier":{"issn":["1433-7851","1521-3773"]},"doi":"10.1002/anie.201711571","author":[{"last_name":"Reitze","full_name":"Reitze, Arnulf","first_name":"Arnulf"},{"first_name":"Nikolas","full_name":"Jürgensmeyer, Nikolas","last_name":"Jürgensmeyer"},{"first_name":"Stefan","full_name":"Lier, Stefan","last_name":"Lier"},{"first_name":"Marco","full_name":"Kohnke, Marco","last_name":"Kohnke"},{"id":"101499","full_name":"Riese, Julia","orcid":"0000-0002-3053-0534","last_name":"Riese","first_name":"Julia"},{"full_name":"Grünewald, Marcus","last_name":"Grünewald","first_name":"Marcus"}],"volume":57,"date_updated":"2024-03-08T11:32:25Z","status":"public","type":"journal_article","extern":"1","user_id":"101499","_id":"47585","year":"2018","issue":"16","quality_controlled":"1","title":"Roadmap for a Smart Factory: A Modular, Intelligent Concept for the Production of Specialty Chemicals","date_created":"2023-10-04T14:19:31Z","publisher":"Wiley","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>Digitalization and increasing the flexibility of production concepts offer the possibility to react to market challenges in the field of specialty chemicals. Shorter product lifetimes, increasing product individualization, and the resulting market volatility impose new requirements on plant operators. Novel concepts such as modular production plants and developments in digitalization (Industry 4.0) are able to assist the implementation of smart factories in specialty chemicals. These essential concepts will be presented in this Minireview.</jats:p>","lang":"eng"}],"publication":"Angewandte Chemie International Edition","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis"]},{"language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"department":[{"_id":"35"},{"_id":"306"}],"user_id":"27611","_id":"41042","status":"public","publication":"Chemistry - A European Journal","type":"journal_article","doi":"10.1002/chem.201801452","title":"Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence","volume":24,"author":[{"full_name":"Garai, Antara","last_name":"Garai","first_name":"Antara"},{"first_name":"Sebastian","last_name":"Sobottka","full_name":"Sobottka, Sebastian"},{"last_name":"Schepper","full_name":"Schepper, Rahel","first_name":"Rahel"},{"full_name":"Sinha, Woormileela","last_name":"Sinha","first_name":"Woormileela"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"full_name":"Sarkar, Biprajit","last_name":"Sarkar","first_name":"Biprajit"},{"first_name":"Sanjib","full_name":"Kar, Sanjib","last_name":"Kar"}],"date_created":"2023-01-30T18:44:13Z","publisher":"Wiley","date_updated":"2023-01-31T08:15:57Z","page":"12613-12622","intvolume":"        24","citation":{"chicago":"Garai, Antara, Sebastian Sobottka, Rahel Schepper, Woormileela Sinha, Matthias Bauer, Biprajit Sarkar, and Sanjib Kar. “Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence.” <i>Chemistry - A European Journal</i> 24, no. 48 (2018): 12613–22. <a href=\"https://doi.org/10.1002/chem.201801452\">https://doi.org/10.1002/chem.201801452</a>.","ieee":"A. Garai <i>et al.</i>, “Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence,” <i>Chemistry - A European Journal</i>, vol. 24, no. 48, pp. 12613–12622, 2018, doi: <a href=\"https://doi.org/10.1002/chem.201801452\">10.1002/chem.201801452</a>.","ama":"Garai A, Sobottka S, Schepper R, et al. Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence. <i>Chemistry - A European Journal</i>. 2018;24(48):12613-12622. doi:<a href=\"https://doi.org/10.1002/chem.201801452\">10.1002/chem.201801452</a>","apa":"Garai, A., Sobottka, S., Schepper, R., Sinha, W., Bauer, M., Sarkar, B., &#38; Kar, S. (2018). Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence. <i>Chemistry - A European Journal</i>, <i>24</i>(48), 12613–12622. <a href=\"https://doi.org/10.1002/chem.201801452\">https://doi.org/10.1002/chem.201801452</a>","bibtex":"@article{Garai_Sobottka_Schepper_Sinha_Bauer_Sarkar_Kar_2018, title={Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence}, volume={24}, DOI={<a href=\"https://doi.org/10.1002/chem.201801452\">10.1002/chem.201801452</a>}, number={48}, journal={Chemistry - A European Journal}, publisher={Wiley}, author={Garai, Antara and Sobottka, Sebastian and Schepper, Rahel and Sinha, Woormileela and Bauer, Matthias and Sarkar, Biprajit and Kar, Sanjib}, year={2018}, pages={12613–12622} }","mla":"Garai, Antara, et al. “Chromium Complexes with Oxido and Corrolato Ligands: Metal-Based Redox Processes versus Ligand Non-Innocence.” <i>Chemistry - A European Journal</i>, vol. 24, no. 48, Wiley, 2018, pp. 12613–22, doi:<a href=\"https://doi.org/10.1002/chem.201801452\">10.1002/chem.201801452</a>.","short":"A. Garai, S. Sobottka, R. Schepper, W. Sinha, M. Bauer, B. Sarkar, S. Kar, Chemistry - A European Journal 24 (2018) 12613–12622."},"year":"2018","issue":"48","publication_identifier":{"issn":["0947-6539"]},"publication_status":"published"},{"status":"public","type":"journal_article","_id":"41037","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"citation":{"ama":"Fischer S, Rösel A, Kammer A, et al. Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights. <i>Chemistry - A European Journal</i>. 2018;24(60):16052-16065. doi:<a href=\"https://doi.org/10.1002/chem.201802694\">10.1002/chem.201802694</a>","ieee":"S. Fischer <i>et al.</i>, “Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights,” <i>Chemistry - A European Journal</i>, vol. 24, no. 60, pp. 16052–16065, 2018, doi: <a href=\"https://doi.org/10.1002/chem.201802694\">10.1002/chem.201802694</a>.","chicago":"Fischer, Steffen, Arend Rösel, Anja Kammer, Enrico Barsch, Roland Schoch, Henrik Junge, Matthias Bauer, Matthias Beller, and Ralf Ludwig. “Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(Aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights.” <i>Chemistry - A European Journal</i> 24, no. 60 (2018): 16052–65. <a href=\"https://doi.org/10.1002/chem.201802694\">https://doi.org/10.1002/chem.201802694</a>.","apa":"Fischer, S., Rösel, A., Kammer, A., Barsch, E., Schoch, R., Junge, H., Bauer, M., Beller, M., &#38; Ludwig, R. (2018). Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights. <i>Chemistry - A European Journal</i>, <i>24</i>(60), 16052–16065. <a href=\"https://doi.org/10.1002/chem.201802694\">https://doi.org/10.1002/chem.201802694</a>","mla":"Fischer, Steffen, et al. “Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(Aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights.” <i>Chemistry - A European Journal</i>, vol. 24, no. 60, Wiley, 2018, pp. 16052–65, doi:<a href=\"https://doi.org/10.1002/chem.201802694\">10.1002/chem.201802694</a>.","short":"S. Fischer, A. Rösel, A. Kammer, E. Barsch, R. Schoch, H. Junge, M. Bauer, M. Beller, R. Ludwig, Chemistry - A European Journal 24 (2018) 16052–16065.","bibtex":"@article{Fischer_Rösel_Kammer_Barsch_Schoch_Junge_Bauer_Beller_Ludwig_2018, title={Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights}, volume={24}, DOI={<a href=\"https://doi.org/10.1002/chem.201802694\">10.1002/chem.201802694</a>}, number={60}, journal={Chemistry - A European Journal}, publisher={Wiley}, author={Fischer, Steffen and Rösel, Arend and Kammer, Anja and Barsch, Enrico and Schoch, Roland and Junge, Henrik and Bauer, Matthias and Beller, Matthias and Ludwig, Ralf}, year={2018}, pages={16052–16065} }"},"page":"16052-16065","intvolume":"        24","publication_status":"published","publication_identifier":{"issn":["0947-6539"]},"doi":"10.1002/chem.201802694","date_updated":"2023-01-31T07:57:14Z","author":[{"first_name":"Steffen","last_name":"Fischer","full_name":"Fischer, Steffen"},{"first_name":"Arend","last_name":"Rösel","full_name":"Rösel, Arend"},{"first_name":"Anja","last_name":"Kammer","full_name":"Kammer, Anja"},{"last_name":"Barsch","full_name":"Barsch, Enrico","first_name":"Enrico"},{"first_name":"Roland","orcid":"0000-0003-2061-7289","last_name":"Schoch","full_name":"Schoch, Roland","id":"48467"},{"first_name":"Henrik","last_name":"Junge","full_name":"Junge, Henrik"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"first_name":"Matthias","full_name":"Beller, Matthias","last_name":"Beller"},{"first_name":"Ralf","last_name":"Ludwig","full_name":"Ludwig, Ralf"}],"volume":24,"publication":"Chemistry - A European Journal","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"language":[{"iso":"eng"}],"year":"2018","issue":"60","title":"Diferrate [Fe<sub>2</sub>(CO)<sub>6</sub>(μ-CO){μ-P(aryl)<sub>2</sub>}]<sup>−</sup> as Self-Assembling Iron/Phosphor-Based Catalyst for the Hydrogen Evolution Reaction in Photocatalytic Proton Reduction-Spectroscopic Insights","publisher":"Wiley","date_created":"2023-01-30T18:39:34Z"},{"publisher":"Royal Society of Chemistry (RSC)","date_created":"2023-01-30T18:42:40Z","title":"Structure–function relationship during CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> catalysts under atmospheric pressure conditions","issue":"10","year":"2018","keyword":["Catalysis"],"language":[{"iso":"eng"}],"publication":"Catalysis Science &amp; Technology","abstract":[{"text":"<p>Intermediate species formed during CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> catalysts.</p>","lang":"eng"}],"date_updated":"2023-01-31T08:28:05Z","volume":8,"author":[{"first_name":"Natalia M.","last_name":"Martin","full_name":"Martin, Natalia M."},{"first_name":"Felix","full_name":"Hemmingsson, Felix","last_name":"Hemmingsson"},{"last_name":"Wang","full_name":"Wang, Xueting","first_name":"Xueting"},{"first_name":"Lindsay R.","full_name":"Merte, Lindsay R.","last_name":"Merte"},{"full_name":"Hejral, Uta","last_name":"Hejral","first_name":"Uta"},{"last_name":"Gustafson","full_name":"Gustafson, Johan","first_name":"Johan"},{"last_name":"Skoglundh","full_name":"Skoglundh, Magnus","first_name":"Magnus"},{"first_name":"Debora Motta","last_name":"Meira","full_name":"Meira, Debora Motta"},{"first_name":"Ann-Christin","full_name":"Dippel, Ann-Christin","last_name":"Dippel"},{"first_name":"Olof","full_name":"Gutowski, Olof","last_name":"Gutowski"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"},{"first_name":"Per-Anders","last_name":"Carlsson","full_name":"Carlsson, Per-Anders"}],"doi":"10.1039/c8cy00516h","publication_identifier":{"issn":["2044-4753","2044-4761"]},"publication_status":"published","page":"2686-2696","intvolume":"         8","citation":{"bibtex":"@article{Martin_Hemmingsson_Wang_Merte_Hejral_Gustafson_Skoglundh_Meira_Dippel_Gutowski_et al._2018, title={Structure–function relationship during CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> catalysts under atmospheric pressure conditions}, volume={8}, DOI={<a href=\"https://doi.org/10.1039/c8cy00516h\">10.1039/c8cy00516h</a>}, number={10}, journal={Catalysis Science &#38;amp; Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Martin, Natalia M. and Hemmingsson, Felix and Wang, Xueting and Merte, Lindsay R. and Hejral, Uta and Gustafson, Johan and Skoglundh, Magnus and Meira, Debora Motta and Dippel, Ann-Christin and Gutowski, Olof and et al.}, year={2018}, pages={2686–2696} }","mla":"Martin, Natalia M., et al. “Structure–Function Relationship during CO<sub>2</sub> Methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> Catalysts under Atmospheric Pressure Conditions.” <i>Catalysis Science &#38;amp; Technology</i>, vol. 8, no. 10, Royal Society of Chemistry (RSC), 2018, pp. 2686–96, doi:<a href=\"https://doi.org/10.1039/c8cy00516h\">10.1039/c8cy00516h</a>.","short":"N.M. Martin, F. Hemmingsson, X. Wang, L.R. Merte, U. Hejral, J. Gustafson, M. Skoglundh, D.M. Meira, A.-C. Dippel, O. Gutowski, M. Bauer, P.-A. Carlsson, Catalysis Science &#38;amp; Technology 8 (2018) 2686–2696.","apa":"Martin, N. M., Hemmingsson, F., Wang, X., Merte, L. R., Hejral, U., Gustafson, J., Skoglundh, M., Meira, D. M., Dippel, A.-C., Gutowski, O., Bauer, M., &#38; Carlsson, P.-A. (2018). Structure–function relationship during CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> catalysts under atmospheric pressure conditions. <i>Catalysis Science &#38;amp; Technology</i>, <i>8</i>(10), 2686–2696. <a href=\"https://doi.org/10.1039/c8cy00516h\">https://doi.org/10.1039/c8cy00516h</a>","ama":"Martin NM, Hemmingsson F, Wang X, et al. Structure–function relationship during CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> catalysts under atmospheric pressure conditions. <i>Catalysis Science &#38;amp; Technology</i>. 2018;8(10):2686-2696. doi:<a href=\"https://doi.org/10.1039/c8cy00516h\">10.1039/c8cy00516h</a>","chicago":"Martin, Natalia M., Felix Hemmingsson, Xueting Wang, Lindsay R. Merte, Uta Hejral, Johan Gustafson, Magnus Skoglundh, et al. “Structure–Function Relationship during CO<sub>2</sub> Methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> Catalysts under Atmospheric Pressure Conditions.” <i>Catalysis Science &#38;amp; Technology</i> 8, no. 10 (2018): 2686–96. <a href=\"https://doi.org/10.1039/c8cy00516h\">https://doi.org/10.1039/c8cy00516h</a>.","ieee":"N. M. Martin <i>et al.</i>, “Structure–function relationship during CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub> and Rh/SiO<sub>2</sub> catalysts under atmospheric pressure conditions,” <i>Catalysis Science &#38;amp; Technology</i>, vol. 8, no. 10, pp. 2686–2696, 2018, doi: <a href=\"https://doi.org/10.1039/c8cy00516h\">10.1039/c8cy00516h</a>."},"_id":"41040","department":[{"_id":"35"},{"_id":"306"}],"user_id":"27611","type":"journal_article","status":"public"},{"_id":"34306","user_id":"60250","type":"journal_article","status":"public","date_updated":"2022-12-09T12:21:23Z","volume":41,"author":[{"first_name":"Martin","last_name":"Pulst","full_name":"Pulst, Martin"},{"id":"60250","full_name":"Elgabarty, Hossam","orcid":"0000-0002-4945-1481","last_name":"Elgabarty","first_name":"Hossam"},{"full_name":"Sebastiani, Daniel","last_name":"Sebastiani","first_name":"Daniel"},{"first_name":"Jörg","full_name":"Kressler, Jörg","last_name":"Kressler"}],"doi":"10.1039/c6nj03732a","publication_identifier":{"issn":["1144-0546","1369-9261"]},"publication_status":"published","intvolume":"        41","page":"1430-1435","citation":{"apa":"Pulst, M., Elgabarty, H., Sebastiani, D., &#38; Kressler, J. (2017). The annular tautomerism of lithium 1,2,3-triazolate. <i>New Journal of Chemistry</i>, <i>41</i>(4), 1430–1435. <a href=\"https://doi.org/10.1039/c6nj03732a\">https://doi.org/10.1039/c6nj03732a</a>","short":"M. Pulst, H. Elgabarty, D. Sebastiani, J. Kressler, New Journal of Chemistry 41 (2017) 1430–1435.","mla":"Pulst, Martin, et al. “The Annular Tautomerism of Lithium 1,2,3-Triazolate.” <i>New Journal of Chemistry</i>, vol. 41, no. 4, Royal Society of Chemistry (RSC), 2017, pp. 1430–35, doi:<a href=\"https://doi.org/10.1039/c6nj03732a\">10.1039/c6nj03732a</a>.","bibtex":"@article{Pulst_Elgabarty_Sebastiani_Kressler_2017, title={The annular tautomerism of lithium 1,2,3-triazolate}, volume={41}, DOI={<a href=\"https://doi.org/10.1039/c6nj03732a\">10.1039/c6nj03732a</a>}, number={4}, journal={New Journal of Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Pulst, Martin and Elgabarty, Hossam and Sebastiani, Daniel and Kressler, Jörg}, year={2017}, pages={1430–1435} }","chicago":"Pulst, Martin, Hossam Elgabarty, Daniel Sebastiani, and Jörg Kressler. “The Annular Tautomerism of Lithium 1,2,3-Triazolate.” <i>New Journal of Chemistry</i> 41, no. 4 (2017): 1430–35. <a href=\"https://doi.org/10.1039/c6nj03732a\">https://doi.org/10.1039/c6nj03732a</a>.","ieee":"M. Pulst, H. Elgabarty, D. Sebastiani, and J. Kressler, “The annular tautomerism of lithium 1,2,3-triazolate,” <i>New Journal of Chemistry</i>, vol. 41, no. 4, pp. 1430–1435, 2017, doi: <a href=\"https://doi.org/10.1039/c6nj03732a\">10.1039/c6nj03732a</a>.","ama":"Pulst M, Elgabarty H, Sebastiani D, Kressler J. The annular tautomerism of lithium 1,2,3-triazolate. <i>New Journal of Chemistry</i>. 2017;41(4):1430-1435. doi:<a href=\"https://doi.org/10.1039/c6nj03732a\">10.1039/c6nj03732a</a>"},"keyword":["Materials Chemistry","General Chemistry","Catalysis"],"language":[{"iso":"eng"}],"publication":"New Journal of Chemistry","abstract":[{"lang":"eng","text":"<p>The tautomeric equilibrium of 1-lithium-1,2,3-triazolate (1Li-TR) and 2-lithium-1,2,3-triazolate (2Li-TR) is studied by X-ray diffraction, NMR spectroscopy and molecular dynamics simulations.</p>"}],"publisher":"Royal Society of Chemistry (RSC)","date_created":"2022-12-09T12:11:45Z","title":"The annular tautomerism of lithium 1,2,3-triazolate","issue":"4","year":"2017"},{"date_created":"2023-01-10T09:12:03Z","author":[{"first_name":"Sebastian","last_name":"Bestgen","full_name":"Bestgen, Sebastian"},{"first_name":"Carmen","last_name":"Seidl","full_name":"Seidl, Carmen"},{"last_name":"Wiesner","full_name":"Wiesner, Thomas","first_name":"Thomas"},{"last_name":"Zimmer","full_name":"Zimmer, Andreas","first_name":"Andreas"},{"last_name":"Falk","full_name":"Falk, Martina","first_name":"Martina"},{"first_name":"Beate","last_name":"Köberle","full_name":"Köberle, Beate"},{"first_name":"Martina","full_name":"Austeri, Martina","last_name":"Austeri"},{"orcid":"0000-0002-3698-668X","last_name":"Paradies","id":"53339","full_name":"Paradies, Jan","first_name":"Jan"},{"first_name":"Stefan","full_name":"Bräse, Stefan","last_name":"Bräse"},{"first_name":"Ute","full_name":"Schepers, Ute","last_name":"Schepers"},{"full_name":"Roesky, Peter W.","last_name":"Roesky","first_name":"Peter W."}],"volume":23,"publisher":"Wiley","date_updated":"2023-01-23T12:46:34Z","doi":"10.1002/chem.201700517","title":"Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017)","issue":"26","publication_status":"published","publication_identifier":{"issn":["0947-6539"]},"citation":{"ama":"Bestgen S, Seidl C, Wiesner T, et al. Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017). <i>Chemistry - A European Journal</i>. 2017;23(26):6459-6459. doi:<a href=\"https://doi.org/10.1002/chem.201700517\">10.1002/chem.201700517</a>","ieee":"S. Bestgen <i>et al.</i>, “Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017),” <i>Chemistry - A European Journal</i>, vol. 23, no. 26, pp. 6459–6459, 2017, doi: <a href=\"https://doi.org/10.1002/chem.201700517\">10.1002/chem.201700517</a>.","chicago":"Bestgen, Sebastian, Carmen Seidl, Thomas Wiesner, Andreas Zimmer, Martina Falk, Beate Köberle, Martina Austeri, et al. “Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017).” <i>Chemistry - A European Journal</i> 23, no. 26 (2017): 6459–6459. <a href=\"https://doi.org/10.1002/chem.201700517\">https://doi.org/10.1002/chem.201700517</a>.","apa":"Bestgen, S., Seidl, C., Wiesner, T., Zimmer, A., Falk, M., Köberle, B., Austeri, M., Paradies, J., Bräse, S., Schepers, U., &#38; Roesky, P. W. (2017). Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017). <i>Chemistry - A European Journal</i>, <i>23</i>(26), 6459–6459. <a href=\"https://doi.org/10.1002/chem.201700517\">https://doi.org/10.1002/chem.201700517</a>","short":"S. Bestgen, C. Seidl, T. Wiesner, A. Zimmer, M. Falk, B. Köberle, M. Austeri, J. Paradies, S. Bräse, U. Schepers, P.W. Roesky, Chemistry - A European Journal 23 (2017) 6459–6459.","mla":"Bestgen, Sebastian, et al. “Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017).” <i>Chemistry - A European Journal</i>, vol. 23, no. 26, Wiley, 2017, pp. 6459–6459, doi:<a href=\"https://doi.org/10.1002/chem.201700517\">10.1002/chem.201700517</a>.","bibtex":"@article{Bestgen_Seidl_Wiesner_Zimmer_Falk_Köberle_Austeri_Paradies_Bräse_Schepers_et al._2017, title={Inside Back Cover: Double-Strand DNA Breaks Induced by Paracyclophane Gold(I) Complexes (Chem. Eur. J. 26/2017)}, volume={23}, DOI={<a href=\"https://doi.org/10.1002/chem.201700517\">10.1002/chem.201700517</a>}, number={26}, journal={Chemistry - A European Journal}, publisher={Wiley}, author={Bestgen, Sebastian and Seidl, Carmen and Wiesner, Thomas and Zimmer, Andreas and Falk, Martina and Köberle, Beate and Austeri, Martina and Paradies, Jan and Bräse, Stefan and Schepers, Ute and et al.}, year={2017}, pages={6459–6459} }"},"intvolume":"        23","page":"6459-6459","year":"2017","user_id":"53339","department":[{"_id":"2"},{"_id":"389"}],"_id":"35705","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"type":"journal_article","publication":"Chemistry - A European Journal","status":"public"},{"title":"Catalytic hydrogenation of CO<sub>2</sub> to methane over supported Pd, Rh and Ni catalysts","publisher":"Royal Society of Chemistry (RSC)","date_created":"2023-01-30T18:50:10Z","year":"2017","issue":"5","keyword":["Catalysis"],"language":[{"iso":"eng"}],"abstract":[{"lang":"eng","text":"<p>CO<sub>2</sub> methanation over Rh/Al<sub>2</sub>O<sub>3</sub>, Rh/CeO<sub>2</sub> and Ni/CeO<sub>2</sub> at 350 °C highlighting the different surface speciation during reaction.</p>"}],"publication":"Catalysis Science &amp; Technology","doi":"10.1039/c6cy02536f","date_updated":"2023-01-31T08:28:17Z","volume":7,"author":[{"full_name":"Martin, Natalia M.","last_name":"Martin","first_name":"Natalia M."},{"first_name":"Peter","full_name":"Velin, Peter","last_name":"Velin"},{"last_name":"Skoglundh","full_name":"Skoglundh, Magnus","first_name":"Magnus"},{"last_name":"Bauer","orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias"},{"full_name":"Carlsson, Per-Anders","last_name":"Carlsson","first_name":"Per-Anders"}],"intvolume":"         7","page":"1086-1094","citation":{"mla":"Martin, Natalia M., et al. “Catalytic Hydrogenation of CO<sub>2</sub> to Methane over Supported Pd, Rh and Ni Catalysts.” <i>Catalysis Science &#38;amp; Technology</i>, vol. 7, no. 5, Royal Society of Chemistry (RSC), 2017, pp. 1086–94, doi:<a href=\"https://doi.org/10.1039/c6cy02536f\">10.1039/c6cy02536f</a>.","bibtex":"@article{Martin_Velin_Skoglundh_Bauer_Carlsson_2017, title={Catalytic hydrogenation of CO<sub>2</sub> to methane over supported Pd, Rh and Ni catalysts}, volume={7}, DOI={<a href=\"https://doi.org/10.1039/c6cy02536f\">10.1039/c6cy02536f</a>}, number={5}, journal={Catalysis Science &#38;amp; Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Martin, Natalia M. and Velin, Peter and Skoglundh, Magnus and Bauer, Matthias and Carlsson, Per-Anders}, year={2017}, pages={1086–1094} }","short":"N.M. Martin, P. Velin, M. Skoglundh, M. Bauer, P.-A. Carlsson, Catalysis Science &#38;amp; Technology 7 (2017) 1086–1094.","apa":"Martin, N. M., Velin, P., Skoglundh, M., Bauer, M., &#38; Carlsson, P.-A. (2017). Catalytic hydrogenation of CO<sub>2</sub> to methane over supported Pd, Rh and Ni catalysts. <i>Catalysis Science &#38;amp; Technology</i>, <i>7</i>(5), 1086–1094. <a href=\"https://doi.org/10.1039/c6cy02536f\">https://doi.org/10.1039/c6cy02536f</a>","ieee":"N. M. Martin, P. Velin, M. Skoglundh, M. Bauer, and P.-A. Carlsson, “Catalytic hydrogenation of CO<sub>2</sub> to methane over supported Pd, Rh and Ni catalysts,” <i>Catalysis Science &#38;amp; Technology</i>, vol. 7, no. 5, pp. 1086–1094, 2017, doi: <a href=\"https://doi.org/10.1039/c6cy02536f\">10.1039/c6cy02536f</a>.","chicago":"Martin, Natalia M., Peter Velin, Magnus Skoglundh, Matthias Bauer, and Per-Anders Carlsson. “Catalytic Hydrogenation of CO<sub>2</sub> to Methane over Supported Pd, Rh and Ni Catalysts.” <i>Catalysis Science &#38;amp; Technology</i> 7, no. 5 (2017): 1086–94. <a href=\"https://doi.org/10.1039/c6cy02536f\">https://doi.org/10.1039/c6cy02536f</a>.","ama":"Martin NM, Velin P, Skoglundh M, Bauer M, Carlsson P-A. Catalytic hydrogenation of CO<sub>2</sub> to methane over supported Pd, Rh and Ni catalysts. <i>Catalysis Science &#38;amp; Technology</i>. 2017;7(5):1086-1094. doi:<a href=\"https://doi.org/10.1039/c6cy02536f\">10.1039/c6cy02536f</a>"},"publication_identifier":{"issn":["2044-4753","2044-4761"]},"publication_status":"published","_id":"41045","department":[{"_id":"35"},{"_id":"306"}],"user_id":"27611","status":"public","type":"journal_article"},{"user_id":"100715","_id":"63956","language":[{"iso":"eng"}],"extern":"1","keyword":["Chemistry","dynamic nuclear-polarization","solid-state nmr","DFT","heterogeneous catalysis","hydrido complexes","hydrogenation","immobilized catalyst","inorganic hybrid","iridium","materials","mesoporous","molecular-orbital methods","PHIP","phosphine complexes","reusable catalysts","silica","solid-state-NMR","wilkinsons catalyst"],"publication":"Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry & Chemical Physics","type":"journal_article","status":"public","abstract":[{"text":"The synthesis of novel robust and stable iridium-based immobilized catalysts on silica-polymer hybrid materials (Si-PB-Ir) is described. These catalysts are characterized by a combination of 1D P-31 CP-MAS and 2D P-31-H-1 HETCOR and J-resolved multinuclear solid state NMR experiments. Different binding situations such as singly and multiply coordinated phosphines are identified. Density functional theory (DFT) calculations are performed to corroborate the interpretation of the experimental NMR data, in order to propose a structural model of the heterogenized catalysts. Finally, the catalytic activity of the Si-PB-Ir catalysts is investigated for the hydrogenation of styrene employing para-enriched hydrogen gas.","lang":"eng"}],"volume":231,"author":[{"first_name":"Torsten","id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann"},{"full_name":"Alkhagani, S.","last_name":"Alkhagani","first_name":"S."},{"full_name":"Rothermel, N.","last_name":"Rothermel","first_name":"N."},{"first_name":"H. H.","full_name":"Limbach, H. H.","last_name":"Limbach"},{"first_name":"H.","last_name":"Breitzke","full_name":"Breitzke, H."},{"first_name":"G.","full_name":"Buntkowsky, G.","last_name":"Buntkowsky"}],"date_created":"2026-02-07T15:35:41Z","date_updated":"2026-02-17T16:18:04Z","doi":"10.1515/zpch-2016-0837","title":"P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts","issue":"3","publication_identifier":{"issn":["0942-9352"]},"intvolume":"       231","page":"653–669","citation":{"bibtex":"@article{Gutmann_Alkhagani_Rothermel_Limbach_Breitzke_Buntkowsky_2017, title={P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts}, volume={231}, DOI={<a href=\"https://doi.org/10.1515/zpch-2016-0837\">10.1515/zpch-2016-0837</a>}, number={3}, journal={Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics}, author={Gutmann, Torsten and Alkhagani, S. and Rothermel, N. and Limbach, H. H. and Breitzke, H. and Buntkowsky, G.}, year={2017}, pages={653–669} }","mla":"Gutmann, Torsten, et al. “P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel Heterogenized Iridium-Catalysts.” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, vol. 231, no. 3, 2017, pp. 653–669, doi:<a href=\"https://doi.org/10.1515/zpch-2016-0837\">10.1515/zpch-2016-0837</a>.","short":"T. Gutmann, S. Alkhagani, N. Rothermel, H.H. Limbach, H. Breitzke, G. Buntkowsky, Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics 231 (2017) 653–669.","apa":"Gutmann, T., Alkhagani, S., Rothermel, N., Limbach, H. H., Breitzke, H., &#38; Buntkowsky, G. (2017). P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts. <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, <i>231</i>(3), 653–669. <a href=\"https://doi.org/10.1515/zpch-2016-0837\">https://doi.org/10.1515/zpch-2016-0837</a>","ama":"Gutmann T, Alkhagani S, Rothermel N, Limbach HH, Breitzke H, Buntkowsky G. P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts. <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>. 2017;231(3):653–669. doi:<a href=\"https://doi.org/10.1515/zpch-2016-0837\">10.1515/zpch-2016-0837</a>","ieee":"T. Gutmann, S. Alkhagani, N. Rothermel, H. H. Limbach, H. Breitzke, and G. Buntkowsky, “P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel heterogenized Iridium-Catalysts,” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i>, vol. 231, no. 3, pp. 653–669, 2017, doi: <a href=\"https://doi.org/10.1515/zpch-2016-0837\">10.1515/zpch-2016-0837</a>.","chicago":"Gutmann, Torsten, S. Alkhagani, N. Rothermel, H. H. Limbach, H. Breitzke, and G. Buntkowsky. “P-31-Solid-State NMR Characterization and Catalytic Hydrogenation Tests of Novel Heterogenized Iridium-Catalysts.” <i>Zeitschrift Fur Physikalische Chemie-International Journal of Research in Physical Chemistry &#38; Chemical Physics</i> 231, no. 3 (2017): 653–669. <a href=\"https://doi.org/10.1515/zpch-2016-0837\">https://doi.org/10.1515/zpch-2016-0837</a>."},"year":"2017"},{"publication":"Chemistry – A European Journal","type":"journal_article","status":"public","_id":"35710","department":[{"_id":"2"},{"_id":"389"}],"user_id":"53339","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"language":[{"iso":"eng"}],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","issue":"22","year":"2016","page":"7302-7302","intvolume":"        22","citation":{"apa":"Tussing, S., Kaupmees, K., &#38; Paradies, J. (2016). Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016). <i>Chemistry – A European Journal</i>, <i>22</i>(22), 7302–7302. <a href=\"https://doi.org/10.1002/chem.201601558\">https://doi.org/10.1002/chem.201601558</a>","bibtex":"@article{Tussing_Kaupmees_Paradies_2016, title={Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016)}, volume={22}, DOI={<a href=\"https://doi.org/10.1002/chem.201601558\">10.1002/chem.201601558</a>}, number={22}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Tussing, Sebastian and Kaupmees, Karl and Paradies, Jan}, year={2016}, pages={7302–7302} }","mla":"Tussing, Sebastian, et al. “Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016).” <i>Chemistry – A European Journal</i>, vol. 22, no. 22, Wiley, 2016, pp. 7302–7302, doi:<a href=\"https://doi.org/10.1002/chem.201601558\">10.1002/chem.201601558</a>.","short":"S. Tussing, K. Kaupmees, J. Paradies, Chemistry – A European Journal 22 (2016) 7302–7302.","ama":"Tussing S, Kaupmees K, Paradies J. Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016). <i>Chemistry – A European Journal</i>. 2016;22(22):7302-7302. doi:<a href=\"https://doi.org/10.1002/chem.201601558\">10.1002/chem.201601558</a>","chicago":"Tussing, Sebastian, Karl Kaupmees, and Jan Paradies. “Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016).” <i>Chemistry – A European Journal</i> 22, no. 22 (2016): 7302–7302. <a href=\"https://doi.org/10.1002/chem.201601558\">https://doi.org/10.1002/chem.201601558</a>.","ieee":"S. Tussing, K. Kaupmees, and J. Paradies, “Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016),” <i>Chemistry – A European Journal</i>, vol. 22, no. 22, pp. 7302–7302, 2016, doi: <a href=\"https://doi.org/10.1002/chem.201601558\">10.1002/chem.201601558</a>."},"date_updated":"2023-01-23T12:54:23Z","publisher":"Wiley","volume":22,"author":[{"last_name":"Tussing","full_name":"Tussing, Sebastian","first_name":"Sebastian"},{"last_name":"Kaupmees","full_name":"Kaupmees, Karl","first_name":"Karl"},{"first_name":"Jan","full_name":"Paradies, Jan","id":"53339","orcid":"0000-0002-3698-668X","last_name":"Paradies"}],"date_created":"2023-01-10T09:13:44Z","title":"Inside Cover: Structure–Reactivity Relationship in the Frustrated Lewis Pair (FLP)‐Catalyzed Hydrogenation of Imines (Chem. Eur. J. 22/2016)","doi":"10.1002/chem.201601558"},{"citation":{"apa":"Srour, M., Hadjiali, S., Sauer, G., Brunnengräber, K., Breitzke, H., Xu, Y., Weidler, H., Limbach, H.-H., Gutmann, T., &#38; Buntkowsky, G. (2016). Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance. <i>ChemCatChem</i>, <i>8</i>(21), 3409–3416. <a href=\"https://doi.org/10.1002/cctc.201600882\">https://doi.org/10.1002/cctc.201600882</a>","short":"M. Srour, S. Hadjiali, G. Sauer, K. Brunnengräber, H. Breitzke, Y. Xu, H. Weidler, H.-H. Limbach, T. Gutmann, G. Buntkowsky, ChemCatChem 8 (2016) 3409–3416.","mla":"Srour, Mohamad, et al. “Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance.” <i>ChemCatChem</i>, vol. 8, no. 21, 2016, pp. 3409–3416, doi:<a href=\"https://doi.org/10.1002/cctc.201600882\">10.1002/cctc.201600882</a>.","bibtex":"@article{Srour_Hadjiali_Sauer_Brunnengräber_Breitzke_Xu_Weidler_Limbach_Gutmann_Buntkowsky_2016, title={Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance}, volume={8}, DOI={<a href=\"https://doi.org/10.1002/cctc.201600882\">10.1002/cctc.201600882</a>}, number={21}, journal={ChemCatChem}, author={Srour, Mohamad and Hadjiali, Sara and Sauer, Grit and Brunnengräber, Kai and Breitzke, Hergen and Xu, Yeping and Weidler, Heiko and Limbach, Hans-Heinrich and Gutmann, Torsten and Buntkowsky, Gerd}, year={2016}, pages={3409–3416} }","ama":"Srour M, Hadjiali S, Sauer G, et al. Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance. <i>ChemCatChem</i>. 2016;8(21):3409–3416. doi:<a href=\"https://doi.org/10.1002/cctc.201600882\">10.1002/cctc.201600882</a>","ieee":"M. Srour <i>et al.</i>, “Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance,” <i>ChemCatChem</i>, vol. 8, no. 21, pp. 3409–3416, 2016, doi: <a href=\"https://doi.org/10.1002/cctc.201600882\">10.1002/cctc.201600882</a>.","chicago":"Srour, Mohamad, Sara Hadjiali, Grit Sauer, Kai Brunnengräber, Hergen Breitzke, Yeping Xu, Heiko Weidler, Hans-Heinrich Limbach, Torsten Gutmann, and Gerd Buntkowsky. “Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance.” <i>ChemCatChem</i> 8, no. 21 (2016): 3409–3416. <a href=\"https://doi.org/10.1002/cctc.201600882\">https://doi.org/10.1002/cctc.201600882</a>."},"page":"3409–3416","intvolume":"         8","year":"2016","issue":"21","doi":"10.1002/cctc.201600882","title":"Synthesis and Solid-State NMR Characterization of a Robust, Pyridyl-Based Immobilized Wilkinson’s Type Catalyst with High Catalytic Performance","date_created":"2026-02-07T16:12:46Z","author":[{"full_name":"Srour, Mohamad","last_name":"Srour","first_name":"Mohamad"},{"last_name":"Hadjiali","full_name":"Hadjiali, Sara","first_name":"Sara"},{"first_name":"Grit","full_name":"Sauer, Grit","last_name":"Sauer"},{"full_name":"Brunnengräber, Kai","last_name":"Brunnengräber","first_name":"Kai"},{"full_name":"Breitzke, Hergen","last_name":"Breitzke","first_name":"Hergen"},{"first_name":"Yeping","full_name":"Xu, Yeping","last_name":"Xu"},{"last_name":"Weidler","full_name":"Weidler, Heiko","first_name":"Heiko"},{"first_name":"Hans-Heinrich","last_name":"Limbach","full_name":"Limbach, Hans-Heinrich"},{"last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165","first_name":"Torsten"},{"first_name":"Gerd","last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd"}],"volume":8,"date_updated":"2026-02-17T16:13:06Z","status":"public","abstract":[{"lang":"eng","text":"A novel strategy for the immobilization of Wilkinson’s catalyst on silica nanoparticles is presented, employing pyridyl linkers as anchoring groups. The coordination binding of the catalyst to the pyridyl linker via ligand exchange of the trans-phosphine group is verified by 1 D and 2 D solid-state NMR spectroscopy. Catalytic activities are monitored by GC employing the hydrogenation of styrene as model reaction, and the leaching properties as well as the robustness of the catalyst are investigated. The resulting immobilized catalyst shows high catalytic activity, which is within a factor of three comparable to the homogeneous catalyst, and excellent stability in leaching tests. Finally, it is efficient to produce hyperpolarization in solution by employing parahydrogen-enriched hydrogen gas for hydrogenation."}],"type":"journal_article","publication":"ChemCatChem","extern":"1","language":[{"iso":"eng"}],"keyword":["heterogeneous catalysis","hydrogenation","immobilization","phosphane ligands","rhodium"],"user_id":"100715","_id":"64047"},{"title":"Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting","date_created":"2023-01-30T20:38:01Z","publisher":"American Chemical Society (ACS)","year":"2015","issue":"9","language":[{"iso":"eng"}],"keyword":["Catalysis","General Chemistry"],"publication":"ACS Catalysis","doi":"10.1021/acscatal.5b01428","author":[{"last_name":"Busser","full_name":"Busser, G. Wilma","first_name":"G. Wilma"},{"first_name":"Bastian","full_name":"Mei, Bastian","last_name":"Mei"},{"full_name":"Weide, Philipp","last_name":"Weide","first_name":"Philipp"},{"first_name":"Peter C. K.","full_name":"Vesborg, Peter C. K.","last_name":"Vesborg"},{"first_name":"Kai","last_name":"Stührenberg","full_name":"Stührenberg, Kai"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"},{"first_name":"Xing","last_name":"Huang","full_name":"Huang, Xing"},{"first_name":"Marc-Georg","last_name":"Willinger","full_name":"Willinger, Marc-Georg"},{"last_name":"Chorkendorff","full_name":"Chorkendorff, Ib","first_name":"Ib"},{"full_name":"Schlögl, Robert","last_name":"Schlögl","first_name":"Robert"},{"first_name":"Martin","last_name":"Muhler","full_name":"Muhler, Martin"}],"volume":5,"date_updated":"2023-01-31T08:36:11Z","citation":{"apa":"Busser, G. W., Mei, B., Weide, P., Vesborg, P. C. K., Stührenberg, K., Bauer, M., Huang, X., Willinger, M.-G., Chorkendorff, I., Schlögl, R., &#38; Muhler, M. (2015). Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting. <i>ACS Catalysis</i>, <i>5</i>(9), 5530–5539. <a href=\"https://doi.org/10.1021/acscatal.5b01428\">https://doi.org/10.1021/acscatal.5b01428</a>","short":"G.W. Busser, B. Mei, P. Weide, P.C.K. Vesborg, K. Stührenberg, M. Bauer, X. Huang, M.-G. Willinger, I. Chorkendorff, R. Schlögl, M. Muhler, ACS Catalysis 5 (2015) 5530–5539.","mla":"Busser, G. Wilma, et al. “Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting.” <i>ACS Catalysis</i>, vol. 5, no. 9, American Chemical Society (ACS), 2015, pp. 5530–39, doi:<a href=\"https://doi.org/10.1021/acscatal.5b01428\">10.1021/acscatal.5b01428</a>.","bibtex":"@article{Busser_Mei_Weide_Vesborg_Stührenberg_Bauer_Huang_Willinger_Chorkendorff_Schlögl_et al._2015, title={Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting}, volume={5}, DOI={<a href=\"https://doi.org/10.1021/acscatal.5b01428\">10.1021/acscatal.5b01428</a>}, number={9}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Busser, G. Wilma and Mei, Bastian and Weide, Philipp and Vesborg, Peter C. K. and Stührenberg, Kai and Bauer, Matthias and Huang, Xing and Willinger, Marc-Georg and Chorkendorff, Ib and Schlögl, Robert and et al.}, year={2015}, pages={5530–5539} }","ama":"Busser GW, Mei B, Weide P, et al. Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting. <i>ACS Catalysis</i>. 2015;5(9):5530-5539. doi:<a href=\"https://doi.org/10.1021/acscatal.5b01428\">10.1021/acscatal.5b01428</a>","chicago":"Busser, G. Wilma, Bastian Mei, Philipp Weide, Peter C. K. Vesborg, Kai Stührenberg, Matthias Bauer, Xing Huang, et al. “Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting.” <i>ACS Catalysis</i> 5, no. 9 (2015): 5530–39. <a href=\"https://doi.org/10.1021/acscatal.5b01428\">https://doi.org/10.1021/acscatal.5b01428</a>.","ieee":"G. W. Busser <i>et al.</i>, “Cocatalyst Designing: A Regenerable Molybdenum-Containing Ternary Cocatalyst System for Efficient Photocatalytic Water Splitting,” <i>ACS Catalysis</i>, vol. 5, no. 9, pp. 5530–5539, 2015, doi: <a href=\"https://doi.org/10.1021/acscatal.5b01428\">10.1021/acscatal.5b01428</a>."},"intvolume":"         5","page":"5530-5539","publication_status":"published","publication_identifier":{"issn":["2155-5435","2155-5435"]},"user_id":"27611","department":[{"_id":"35"},{"_id":"306"}],"_id":"41059","status":"public","type":"journal_article"},{"page":"13769-13774","intvolume":"        54","citation":{"ieee":"W. Sinha <i>et al.</i>, “Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes,” <i>Angewandte Chemie International Edition</i>, vol. 54, no. 46, pp. 13769–13774, 2015, doi: <a href=\"https://doi.org/10.1002/anie.201507330\">10.1002/anie.201507330</a>.","chicago":"Sinha, Woormileela, Michael G. Sommer, Naina Deibel, Fabian Ehret, Matthias Bauer, Biprajit Sarkar, and Sanjib Kar. “Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes.” <i>Angewandte Chemie International Edition</i> 54, no. 46 (2015): 13769–74. <a href=\"https://doi.org/10.1002/anie.201507330\">https://doi.org/10.1002/anie.201507330</a>.","ama":"Sinha W, Sommer MG, Deibel N, et al. Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes. <i>Angewandte Chemie International Edition</i>. 2015;54(46):13769-13774. doi:<a href=\"https://doi.org/10.1002/anie.201507330\">10.1002/anie.201507330</a>","short":"W. Sinha, M.G. Sommer, N. Deibel, F. Ehret, M. Bauer, B. Sarkar, S. Kar, Angewandte Chemie International Edition 54 (2015) 13769–13774.","mla":"Sinha, Woormileela, et al. “Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes.” <i>Angewandte Chemie International Edition</i>, vol. 54, no. 46, Wiley, 2015, pp. 13769–74, doi:<a href=\"https://doi.org/10.1002/anie.201507330\">10.1002/anie.201507330</a>.","bibtex":"@article{Sinha_Sommer_Deibel_Ehret_Bauer_Sarkar_Kar_2015, title={Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes}, volume={54}, DOI={<a href=\"https://doi.org/10.1002/anie.201507330\">10.1002/anie.201507330</a>}, number={46}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Sinha, Woormileela and Sommer, Michael G. and Deibel, Naina and Ehret, Fabian and Bauer, Matthias and Sarkar, Biprajit and Kar, Sanjib}, year={2015}, pages={13769–13774} }","apa":"Sinha, W., Sommer, M. G., Deibel, N., Ehret, F., Bauer, M., Sarkar, B., &#38; Kar, S. (2015). Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes. <i>Angewandte Chemie International Edition</i>, <i>54</i>(46), 13769–13774. <a href=\"https://doi.org/10.1002/anie.201507330\">https://doi.org/10.1002/anie.201507330</a>"},"year":"2015","issue":"46","publication_identifier":{"issn":["1433-7851"]},"publication_status":"published","doi":"10.1002/anie.201507330","title":"Experimental and Theoretical Investigations of the Existence of Cu<sup>II</sup>, Cu<sup>III</sup>, and Cu<sup>IV</sup>in Copper Corrolato Complexes","volume":54,"date_created":"2023-01-30T20:30:16Z","author":[{"last_name":"Sinha","full_name":"Sinha, Woormileela","first_name":"Woormileela"},{"first_name":"Michael G.","last_name":"Sommer","full_name":"Sommer, Michael G."},{"full_name":"Deibel, Naina","last_name":"Deibel","first_name":"Naina"},{"full_name":"Ehret, Fabian","last_name":"Ehret","first_name":"Fabian"},{"first_name":"Matthias","id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"first_name":"Biprajit","last_name":"Sarkar","full_name":"Sarkar, Biprajit"},{"last_name":"Kar","full_name":"Kar, Sanjib","first_name":"Sanjib"}],"publisher":"Wiley","date_updated":"2023-01-31T08:35:26Z","status":"public","publication":"Angewandte Chemie International Edition","type":"journal_article","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis"],"department":[{"_id":"35"},{"_id":"306"}],"user_id":"27611","_id":"41053"},{"status":"public","abstract":[{"text":"A novel heterogeneous dirhodium catalyst has been synthesized. This stable catalyst is constructed from dirhodium acetate dimer (Rh2(OAc)4) units, which are covalently linked to amine- and carboxyl-bifunctionalized mesoporous silica (SBA-15NH2COOH). It shows good efficiency in catalyzing the cyclopropanation reaction of styrene and ethyl diazoacetate (EDA) forming cis- and trans-1-ethoxycarbonyl-2-phenylcyclopropane. To characterize the structure of this catalyst and to confirm the successful immobilization, heteronuclear solid-state NMR experiments have been performed. The high application potential of dynamic nuclear polarization (DNP) NMR for the analysis of binding sites in this novel catalyst is demonstrated. Signal-enhanced 13C CP MAS and 15N CP MAS techniques have been employed to detect different carboxyl and amine binding sites in natural abundance on a fast time scale. The interpretation of the experimental chemical shift values for different binding sites has been corroborated by quantum chemical calculations on dirhodium model complexes.","lang":"eng"}],"publication":"Chemistry A European Journal","type":"journal_article","extern":"1","language":[{"iso":"eng"}],"keyword":["heterogeneous catalysis","immobilized catalyst","dynamic nuclear polarization","hyperpolarization","NMR spectroscopy"],"user_id":"100715","_id":"63963","intvolume":"        21","page":"3798–3805","citation":{"short":"T. Gutmann, J. Liu, N. Rothermel, Y. Xu, E. Jaumann, M. Werner, H. Breitzke, S.T. Sigurdsson, G. Buntkowsky, Chemistry A European Journal 21 (2015) 3798–3805.","mla":"Gutmann, Torsten, et al. “Natural Abundance 15N NMR by Dynamic Nuclear Polarization: Fast Analysis of Binding Sites of a Novel Amine-Carboxyl-Linked Immobilized Dirhodium Catalyst.” <i>Chemistry A European Journal</i>, vol. 21, no. 9, WILEY-VCH Verlag, 2015, pp. 3798–3805, doi:<a href=\"https://doi.org/10.1002/chem.201405043\">10.1002/chem.201405043</a>.","bibtex":"@article{Gutmann_Liu_Rothermel_Xu_Jaumann_Werner_Breitzke_Sigurdsson_Buntkowsky_2015, title={Natural Abundance 15N NMR by Dynamic Nuclear Polarization: Fast Analysis of Binding Sites of a Novel Amine-Carboxyl-Linked Immobilized Dirhodium Catalyst}, volume={21}, DOI={<a href=\"https://doi.org/10.1002/chem.201405043\">10.1002/chem.201405043</a>}, number={9}, journal={Chemistry A European Journal}, publisher={WILEY-VCH Verlag}, author={Gutmann, Torsten and Liu, Jiquan and Rothermel, Niels and Xu, Yeping and Jaumann, Eva and Werner, Mayke and Breitzke, Hergen and Sigurdsson, Snorri T. and Buntkowsky, Gerd}, year={2015}, pages={3798–3805} }","apa":"Gutmann, T., Liu, J., Rothermel, N., Xu, Y., Jaumann, E., Werner, M., Breitzke, H., Sigurdsson, S. 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