---
_id: '59510'
abstract:
- lang: eng
text: The use of organo-catalysis in continuous-flow reactor systems is
gaining attention in medicinal chemistry due to its cost-effectiveness and reduced
chemical waste. In this study, bioactive curcumin (CUM) derivatives were synthesized
in a continuously operated microfluidic reactor (MFR), using piperidine-based
polymeric networks as catalysts. Piperidine methacrylate and piperidine acrylate
were synthesized and subsequently copolymerized with complementary monomers (MMA
or DMAA) and crosslinkers (EGDMA or MBAM) via photopolymerization, yielding different
polymeric networks. Initially, batch reactions were optimized for the organo-catalytic
Knoevenagel condensation between CUM and 4-nitrobenzaldehyde, under various conditions,
in the presence of polymer networks. Conversion was assessed using offline 1H
NMR spectroscopy, revealing an increase in conversion with enhanced swelling properties
of the polymer networks, which facilitated greater accessibility of catalytic
sites. In continuous-flow MFR experiments, optimized polymer gel dots exhibited
superior catalytic performance, achieving a conversion of up to 72%, compared
to other compositions. This improvement was attributed to the enhanced swelling
in the reaction mixture (DMSO/methanol, 7:3 v/v) at 40 °C over 72 h. Furthermore,
the MFR system enabled the efficient synthesis of a series of CUM derivatives,
demonstrating significantly higher conversion rates than traditional batch reactions.
Notably, while batch reactions required 90% catalyst loading in the gel, the MFR
system achieved a comparable or superior performance with only 50% catalyst, resulting
in a higher turnover number. These findings underscore the advantages of continuous-flow
organo-catalysis in enhancing catalytic efficiency and sustainability in organic
synthesis.
article_number: '278'
author:
- first_name: Naresh
full_name: Killi, Naresh
last_name: Killi
- first_name: Katja
full_name: Rumpke, Katja
last_name: Rumpke
- first_name: Dirk
full_name: Kuckling, Dirk
id: '287'
last_name: Kuckling
citation:
ama: Killi N, Rumpke K, Kuckling D. Synthesis of Curcumin Derivatives via Knoevenagel
Reaction Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks
Containing Piperidine as a Catalyst. Gels. 2025;11(4). doi:10.3390/gels11040278
apa: Killi, N., Rumpke, K., & Kuckling, D. (2025). Synthesis of Curcumin Derivatives
via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using
Polymeric Networks Containing Piperidine as a Catalyst. Gels, 11(4),
Article 278. https://doi.org/10.3390/gels11040278
bibtex: '@article{Killi_Rumpke_Kuckling_2025, title={Synthesis of Curcumin Derivatives
via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using
Polymeric Networks Containing Piperidine as a Catalyst}, volume={11}, DOI={10.3390/gels11040278}, number={4278},
journal={Gels}, publisher={MDPI AG}, author={Killi, Naresh and Rumpke, Katja and
Kuckling, Dirk}, year={2025} }'
chicago: Killi, Naresh, Katja Rumpke, and Dirk Kuckling. “Synthesis of Curcumin
Derivatives via Knoevenagel Reaction Within a Continuously Driven Microfluidic
Reactor Using Polymeric Networks Containing Piperidine as a Catalyst.” Gels
11, no. 4 (2025). https://doi.org/10.3390/gels11040278.
ieee: 'N. Killi, K. Rumpke, and D. Kuckling, “Synthesis of Curcumin Derivatives
via Knoevenagel Reaction Within a Continuously Driven Microfluidic Reactor Using
Polymeric Networks Containing Piperidine as a Catalyst,” Gels, vol. 11,
no. 4, Art. no. 278, 2025, doi: 10.3390/gels11040278.'
mla: Killi, Naresh, et al. “Synthesis of Curcumin Derivatives via Knoevenagel Reaction
Within a Continuously Driven Microfluidic Reactor Using Polymeric Networks Containing
Piperidine as a Catalyst.” Gels, vol. 11, no. 4, 278, MDPI AG, 2025, doi:10.3390/gels11040278.
short: N. Killi, K. Rumpke, D. Kuckling, Gels 11 (2025).
date_created: 2025-04-11T07:12:02Z
date_updated: 2025-04-11T07:13:26Z
department:
- _id: '163'
doi: 10.3390/gels11040278
intvolume: ' 11'
issue: '4'
keyword:
- flow chemistry
- heterogeneous catalysis
- sustainable synthesis
- organo-catalysis
- polymeric gel dots
language:
- iso: eng
main_file_link:
- url: https://www.mdpi.com/2310-2861/11/4/278
publication: Gels
publication_identifier:
issn:
- 2310-2861
publication_status: published
publisher: MDPI AG
status: public
title: Synthesis of Curcumin Derivatives via Knoevenagel Reaction Within a Continuously
Driven Microfluidic Reactor Using Polymeric Networks Containing Piperidine as a
Catalyst
type: journal_article
user_id: '94'
volume: 11
year: '2025'
...
---
_id: '53621'
abstract:
- lang: eng
text: The coupling of structural transitions to heat capacity changes leads
to destabilization of macromolecules at both, elevated and lowered temperatures.
DNA origami not only exhibit this property but also provide...
author:
- first_name: Daniel
full_name: Dornbusch, Daniel
last_name: Dornbusch
- first_name: Marcel
full_name: Hanke, Marcel
last_name: Hanke
- first_name: Emilia
full_name: Tomm, Emilia
id: '68157'
last_name: Tomm
- first_name: Charlotte
full_name: Kielar, Charlotte
last_name: Kielar
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
- first_name: Karim
full_name: Fahmy, Karim
last_name: Fahmy
citation:
ama: Dornbusch D, Hanke M, Tomm E, et al. Cold denaturation of DNA origami nanostructures.
Chemical Communications. Published online 2024. doi:10.1039/d3cc05985e
apa: Dornbusch, D., Hanke, M., Tomm, E., Kielar, C., Grundmeier, G., Keller, A.,
& Fahmy, K. (2024). Cold denaturation of DNA origami nanostructures. Chemical
Communications. https://doi.org/10.1039/d3cc05985e
bibtex: '@article{Dornbusch_Hanke_Tomm_Kielar_Grundmeier_Keller_Fahmy_2024, title={Cold
denaturation of DNA origami nanostructures}, DOI={10.1039/d3cc05985e},
journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)},
author={Dornbusch, Daniel and Hanke, Marcel and Tomm, Emilia and Kielar, Charlotte
and Grundmeier, Guido and Keller, Adrian and Fahmy, Karim}, year={2024} }'
chicago: Dornbusch, Daniel, Marcel Hanke, Emilia Tomm, Charlotte Kielar, Guido Grundmeier,
Adrian Keller, and Karim Fahmy. “Cold Denaturation of DNA Origami Nanostructures.”
Chemical Communications, 2024. https://doi.org/10.1039/d3cc05985e.
ieee: 'D. Dornbusch et al., “Cold denaturation of DNA origami nanostructures,”
Chemical Communications, 2024, doi: 10.1039/d3cc05985e.'
mla: Dornbusch, Daniel, et al. “Cold Denaturation of DNA Origami Nanostructures.”
Chemical Communications, Royal Society of Chemistry (RSC), 2024, doi:10.1039/d3cc05985e.
short: D. Dornbusch, M. Hanke, E. Tomm, C. Kielar, G. Grundmeier, A. Keller, K.
Fahmy, Chemical Communications (2024).
date_created: 2024-04-23T08:20:05Z
date_updated: 2024-04-23T08:21:05Z
department:
- _id: '302'
doi: 10.1039/d3cc05985e
keyword:
- Materials Chemistry
- Metals and Alloys
- Surfaces
- Coatings and Films
- General Chemistry
- Ceramics and Composites
- Electronic
- Optical and Magnetic Materials
- Catalysis
language:
- iso: eng
publication: Chemical Communications
publication_identifier:
issn:
- 1359-7345
- 1364-548X
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Cold denaturation of DNA origami nanostructures
type: journal_article
user_id: '48864'
year: '2024'
...
---
_id: '63970'
abstract:
- lang: eng
text: Abstract Recent advances in solid-state nuclear magnetic resonance (NMR) spectroscopy,
combined with dynamic nuclear polarization (DNP), quantum chemical DFT calculations,
and gas-phase NMR spectroscopy investigating the structure and reactivity of heterogeneous
catalysts are reviewed. The investigated catalysts range from classical mononuclear
catalysts, like immobilized derivates of Wilkinson’s catalysts over binuclear
catalysts such as the dirhodium paddlewheel catalyst to catalytic nanoparticles,
employing various support materials, such as mesoporous silica gels, coordination
polymers, and biomaterials such as cellulose.
author:
- first_name: Nadia
full_name: Haro Mares, Nadia
last_name: Haro Mares
- first_name: Millena
full_name: Logrado, Millena
last_name: Logrado
- first_name: Jan
full_name: Kergassner, Jan
last_name: Kergassner
- first_name: Bingyu
full_name: Zhang, Bingyu
last_name: Zhang
- first_name: Torsten
full_name: Gutmann, Torsten
id: '118165'
last_name: Gutmann
- first_name: Gerd
full_name: Buntkowsky, Gerd
last_name: Buntkowsky
citation:
ama: Haro Mares N, Logrado M, Kergassner J, Zhang B, Gutmann T, Buntkowsky G. Solid-State
NMR of Heterogeneous Catalysts. ChemCatChem. Published online 2024:e202401159.
doi:10.1002/cctc.202401159
apa: Haro Mares, N., Logrado, M., Kergassner, J., Zhang, B., Gutmann, T., &
Buntkowsky, G. (2024). Solid-State NMR of Heterogeneous Catalysts. ChemCatChem,
e202401159. https://doi.org/10.1002/cctc.202401159
bibtex: '@article{Haro Mares_Logrado_Kergassner_Zhang_Gutmann_Buntkowsky_2024, title={Solid-State
NMR of Heterogeneous Catalysts}, DOI={10.1002/cctc.202401159},
journal={ChemCatChem}, publisher={John Wiley & Sons, Ltd}, author={Haro Mares,
Nadia and Logrado, Millena and Kergassner, Jan and Zhang, Bingyu and Gutmann,
Torsten and Buntkowsky, Gerd}, year={2024}, pages={e202401159} }'
chicago: Haro Mares, Nadia, Millena Logrado, Jan Kergassner, Bingyu Zhang, Torsten
Gutmann, and Gerd Buntkowsky. “Solid-State NMR of Heterogeneous Catalysts.” ChemCatChem,
2024, e202401159. https://doi.org/10.1002/cctc.202401159.
ieee: 'N. Haro Mares, M. Logrado, J. Kergassner, B. Zhang, T. Gutmann, and G. Buntkowsky,
“Solid-State NMR of Heterogeneous Catalysts,” ChemCatChem, p. e202401159,
2024, doi: 10.1002/cctc.202401159.'
mla: Haro Mares, Nadia, et al. “Solid-State NMR of Heterogeneous Catalysts.” ChemCatChem,
John Wiley & Sons, Ltd, 2024, p. e202401159, doi:10.1002/cctc.202401159.
short: N. Haro Mares, M. Logrado, J. Kergassner, B. Zhang, T. Gutmann, G. Buntkowsky,
ChemCatChem (2024) e202401159.
date_created: 2026-02-07T15:40:38Z
date_updated: 2026-02-17T16:17:30Z
doi: 10.1002/cctc.202401159
extern: '1'
keyword:
- solid-state nmr
- heterogeneous catalysis
- dynamic nuclear polarization
- Nanocatalysis
- Surface-reactions
language:
- iso: eng
page: e202401159
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
publisher: John Wiley & Sons, Ltd
status: public
title: Solid-State NMR of Heterogeneous Catalysts
type: journal_article
user_id: '100715'
year: '2024'
...
---
_id: '54969'
abstract:
- lang: eng
text: This work presents a new and facile route for the preparation of iron oxide-based
catalysts supported on alumina, which enables the targeted synthesis of catalysts
with an increased amount of isolated tetrahedrally coordinated iron centers compared
to a conventional impregnation procedure, and therefore leads to an increase in
activity for CO oxidation reaction. By a multi-step impregnation–calcination protocol,
the catalysts were synthesized with iron loadings of between 1 and 10 wt%, and
their catalytic activity was then compared with a 10 wt% loaded catalyst prepared
by conventional single impregnation. With a loading of 8 wt%, the presented catalysts
showed an improved catalytic activity regarding light-off and full conversion
temperatures compared to this reference. Through the application of several analytical
methods (PXRD, PDF, DRUVS, SEM, XAFS), the improved catalytic activity can be
correlated with an increased amount of isolated iron centers and a significantly
reduced fraction of agglomerates or particles.
article_number: '416'
article_type: original
author:
- first_name: Steffen
full_name: Schlicher, Steffen
last_name: Schlicher
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Schlicher S, Schoch R, Prinz N, Zobel M, Bauer M. New and Facile Preparation
Method for Highly Active Iron Oxide Catalysts for CO Oxidation. Catalysts.
2024;14(7). doi:10.3390/catal14070416
apa: Schlicher, S., Schoch, R., Prinz, N., Zobel, M., & Bauer, M. (2024). New
and Facile Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation.
Catalysts, 14(7), Article 416. https://doi.org/10.3390/catal14070416
bibtex: '@article{Schlicher_Schoch_Prinz_Zobel_Bauer_2024, title={New and Facile
Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation}, volume={14},
DOI={10.3390/catal14070416},
number={7416}, journal={Catalysts}, publisher={MDPI AG}, author={Schlicher, Steffen
and Schoch, Roland and Prinz, Nils and Zobel, Mirijam and Bauer, Matthias}, year={2024}
}'
chicago: Schlicher, Steffen, Roland Schoch, Nils Prinz, Mirijam Zobel, and Matthias
Bauer. “New and Facile Preparation Method for Highly Active Iron Oxide Catalysts
for CO Oxidation.” Catalysts 14, no. 7 (2024). https://doi.org/10.3390/catal14070416.
ieee: 'S. Schlicher, R. Schoch, N. Prinz, M. Zobel, and M. Bauer, “New and Facile
Preparation Method for Highly Active Iron Oxide Catalysts for CO Oxidation,” Catalysts,
vol. 14, no. 7, Art. no. 416, 2024, doi: 10.3390/catal14070416.'
mla: Schlicher, Steffen, et al. “New and Facile Preparation Method for Highly Active
Iron Oxide Catalysts for CO Oxidation.” Catalysts, vol. 14, no. 7, 416,
MDPI AG, 2024, doi:10.3390/catal14070416.
short: S. Schlicher, R. Schoch, N. Prinz, M. Zobel, M. Bauer, Catalysts 14 (2024).
date_created: 2024-07-02T07:10:14Z
date_updated: 2025-08-15T12:50:52Z
department:
- _id: '306'
doi: 10.3390/catal14070416
intvolume: ' 14'
issue: '7'
keyword:
- Catalysis
language:
- iso: eng
publication: Catalysts
publication_identifier:
issn:
- 2073-4344
publication_status: published
publisher: MDPI AG
status: public
title: New and Facile Preparation Method for Highly Active Iron Oxide Catalysts for
CO Oxidation
type: journal_article
user_id: '48467'
volume: 14
year: '2024'
...
---
_id: '48588'
abstract:
- lang: eng
text: Bacterial colonization and biofilm formation on abiotic surfaces are
initiated by the adhesion of peptides and proteins. Understanding the adhesion
of such peptides and proteins at a molecular level thus represents an important
step toward controlling and suppressing biofilm formation on technological and
medical materials. This study investigates the molecular adhesion of a pilus‐derived
peptide that facilitates biofilm formation of Pseudomonas aeruginosa, a multidrug‐resistant
opportunistic pathogen frequently encountered in healthcare settings. Single‐molecule
force spectroscopy (SMFS) was performed on chemically etched ZnO surfaces to gather
insights about peptide adsorption force and its kinetics. Metal‐free click chemistry
for the fabrication of peptide‐terminated SMFS cantilevers was performed on amine‐terminated
gold cantilevers and verified by X‐ray photoelectron spectroscopy (XPS) and polarization‐modulated
infrared reflection absorption spectroscopy (PM‐IRRAS). Atomic force microscopy
(AFM) and XPS analyses reveal stable topographies and surface chemistries of the
substrates that are not affected by SMFS. Rupture events described by the worm‐like
chain model (WLC) up to 600 pN were detected for the non‐polar ZnO(11‐20) surfaces.
The dissociation barrier energy at zero force ΔG(0), the transition state distance
xb and bound‐unbound dissociation rate at zero force koff(0) for the single crystalline
substrate indicate that coordination and hydrogen bonds dominate the peptide/surface
interaction.
author:
- first_name: Tim
full_name: Prüßner, Tim
last_name: Prüßner
- first_name: Dennis
full_name: Meinderink, Dennis
id: '32378'
last_name: Meinderink
orcid: 0000-0002-2755-6514
- first_name: Siqi
full_name: Zhu, Siqi
last_name: Zhu
- first_name: Alejandro G.
full_name: Orive, Alejandro G.
last_name: Orive
- first_name: Charlotte
full_name: Kielar, Charlotte
last_name: Kielar
- first_name: Marten
full_name: Huck, Marten
last_name: Huck
- first_name: Hans-Georg
full_name: Steinrück, Hans-Georg
id: '84268'
last_name: Steinrück
orcid: 0000-0001-6373-0877
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
citation:
ama: Prüßner T, Meinderink D, Zhu S, et al. Molecular Adhesion of a Pilus‐derived
Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO
Surfaces. Chemistry – A European Journal. Published online 2023. doi:10.1002/chem.202302464
apa: Prüßner, T., Meinderink, D., Zhu, S., Orive, A. G., Kielar, C., Huck, M., Steinrück,
H.-G., Keller, A., & Grundmeier, G. (2023). Molecular Adhesion of a Pilus‐derived
Peptide Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO
Surfaces. Chemistry – A European Journal. https://doi.org/10.1002/chem.202302464
bibtex: '@article{Prüßner_Meinderink_Zhu_Orive_Kielar_Huck_Steinrück_Keller_Grundmeier_2023,
title={Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa
Biofilm Formation on non‐polar ZnO Surfaces}, DOI={10.1002/chem.202302464},
journal={Chemistry – A European Journal}, publisher={Wiley}, author={Prüßner,
Tim and Meinderink, Dennis and Zhu, Siqi and Orive, Alejandro G. and Kielar, Charlotte
and Huck, Marten and Steinrück, Hans-Georg and Keller, Adrian and Grundmeier,
Guido}, year={2023} }'
chicago: Prüßner, Tim, Dennis Meinderink, Siqi Zhu, Alejandro G. Orive, Charlotte
Kielar, Marten Huck, Hans-Georg Steinrück, Adrian Keller, and Guido Grundmeier.
“Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas Aeruginosa
Biofilm Formation on Non‐polar ZnO Surfaces.” Chemistry – A European Journal,
2023. https://doi.org/10.1002/chem.202302464.
ieee: 'T. Prüßner et al., “Molecular Adhesion of a Pilus‐derived Peptide
Involved in Pseudomonas aeruginosa Biofilm Formation on non‐polar ZnO Surfaces,”
Chemistry – A European Journal, 2023, doi: 10.1002/chem.202302464.'
mla: Prüßner, Tim, et al. “Molecular Adhesion of a Pilus‐derived Peptide Involved
in Pseudomonas Aeruginosa Biofilm Formation on Non‐polar ZnO Surfaces.” Chemistry
– A European Journal, Wiley, 2023, doi:10.1002/chem.202302464.
short: T. Prüßner, D. Meinderink, S. Zhu, A.G. Orive, C. Kielar, M. Huck, H.-G.
Steinrück, A. Keller, G. Grundmeier, Chemistry – A European Journal (2023).
date_created: 2023-11-02T09:23:41Z
date_updated: 2023-11-02T09:26:00Z
department:
- _id: '302'
- _id: '633'
doi: 10.1002/chem.202302464
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Molecular Adhesion of a Pilus‐derived Peptide Involved in Pseudomonas aeruginosa
Biofilm Formation on non‐polar ZnO Surfaces
type: journal_article
user_id: '48864'
year: '2023'
...
---
_id: '50150'
abstract:
- lang: eng
text: Covalent peptidomimetic protease inhibitors have gained a lot of attention
in drug development in recent years. They are designed to covalently bind the
catalytically active amino acids through electrophilic groups called warheads.
Covalent inhibition has an advantage in terms of pharmacodynamic properties but
can also bear toxicity risks due to non-selective off-target protein binding.
Therefore, the right combination of a reactive warhead with a well-suited peptidomimetic
sequence is of great importance. Herein, the selectivities of well-known warheads
combined with peptidomimetic sequences suited for five different proteases were
investigated, highlighting the impact of both structure parts (warhead and peptidomimetic
sequence) for affinity and selectivity. Molecular docking gave insights into the
predicted binding modes of the inhibitors inside the binding pockets of the different
enzymes. Moreover, the warheads were investigated by NMR and LC-MS reactivity
assays against serine/threonine and cysteine nucleophile models, as well as by
quantum mechanics simulations.
article_number: '7226'
author:
- first_name: Patrick
full_name: Müller, Patrick
last_name: Müller
- first_name: Mergim
full_name: Meta, Mergim
last_name: Meta
- first_name: Jan Laurenz
full_name: Meidner, Jan Laurenz
last_name: Meidner
- first_name: Marvin
full_name: Schwickert, Marvin
last_name: Schwickert
- first_name: Jessica
full_name: Meyr, Jessica
last_name: Meyr
- first_name: Kevin
full_name: Schwickert, Kevin
last_name: Schwickert
- first_name: Christian
full_name: Kersten, Christian
last_name: Kersten
- first_name: Collin
full_name: Zimmer, Collin
last_name: Zimmer
- first_name: Stefan Josef
full_name: Hammerschmidt, Stefan Josef
last_name: Hammerschmidt
- first_name: Ariane
full_name: Frey, Ariane
last_name: Frey
- first_name: Albin
full_name: Lahu, Albin
last_name: Lahu
- first_name: Sergio
full_name: de la Hoz-Rodríguez, Sergio
last_name: de la Hoz-Rodríguez
- first_name: Laura
full_name: Agost-Beltrán, Laura
last_name: Agost-Beltrán
- first_name: Santiago
full_name: Rodríguez, Santiago
last_name: Rodríguez
- first_name: Kira
full_name: Diemer, Kira
last_name: Diemer
- first_name: Wilhelm
full_name: Neumann, Wilhelm
last_name: Neumann
- first_name: Florenci V.
full_name: Gonzàlez, Florenci V.
last_name: Gonzàlez
- first_name: Bernd
full_name: Engels, Bernd
last_name: Engels
- first_name: Tanja
full_name: Schirmeister, Tanja
last_name: Schirmeister
citation:
ama: Müller P, Meta M, Meidner JL, et al. Investigation of the Compatibility between
Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
and Selectivity Study. International Journal of Molecular Sciences. 2023;24(8).
doi:10.3390/ijms24087226
apa: Müller, P., Meta, M., Meidner, J. L., Schwickert, M., Meyr, J., Schwickert,
K., Kersten, C., Zimmer, C., Hammerschmidt, S. J., Frey, A., Lahu, A., de la Hoz-Rodríguez,
S., Agost-Beltrán, L., Rodríguez, S., Diemer, K., Neumann, W., Gonzàlez, F. V.,
Engels, B., & Schirmeister, T. (2023). Investigation of the Compatibility
between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive
Reactivity and Selectivity Study. International Journal of Molecular Sciences,
24(8), Article 7226. https://doi.org/10.3390/ijms24087226
bibtex: '@article{Müller_Meta_Meidner_Schwickert_Meyr_Schwickert_Kersten_Zimmer_Hammerschmidt_Frey_et
al._2023, title={Investigation of the Compatibility between Warheads and Peptidomimetic
Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study},
volume={24}, DOI={10.3390/ijms24087226},
number={87226}, journal={International Journal of Molecular Sciences}, publisher={MDPI
AG}, author={Müller, Patrick and Meta, Mergim and Meidner, Jan Laurenz and Schwickert,
Marvin and Meyr, Jessica and Schwickert, Kevin and Kersten, Christian and Zimmer,
Collin and Hammerschmidt, Stefan Josef and Frey, Ariane and et al.}, year={2023}
}'
chicago: Müller, Patrick, Mergim Meta, Jan Laurenz Meidner, Marvin Schwickert, Jessica
Meyr, Kevin Schwickert, Christian Kersten, et al. “Investigation of the Compatibility
between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive
Reactivity and Selectivity Study.” International Journal of Molecular Sciences
24, no. 8 (2023). https://doi.org/10.3390/ijms24087226.
ieee: 'P. Müller et al., “Investigation of the Compatibility between Warheads
and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
and Selectivity Study,” International Journal of Molecular Sciences, vol.
24, no. 8, Art. no. 7226, 2023, doi: 10.3390/ijms24087226.'
mla: Müller, Patrick, et al. “Investigation of the Compatibility between Warheads
and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
and Selectivity Study.” International Journal of Molecular Sciences, vol.
24, no. 8, 7226, MDPI AG, 2023, doi:10.3390/ijms24087226.
short: P. Müller, M. Meta, J.L. Meidner, M. Schwickert, J. Meyr, K. Schwickert,
C. Kersten, C. Zimmer, S.J. Hammerschmidt, A. Frey, A. Lahu, S. de la Hoz-Rodríguez,
L. Agost-Beltrán, S. Rodríguez, K. Diemer, W. Neumann, F.V. Gonzàlez, B. Engels,
T. Schirmeister, International Journal of Molecular Sciences 24 (2023).
date_created: 2024-01-04T08:24:31Z
date_updated: 2024-01-05T12:59:32Z
doi: 10.3390/ijms24087226
intvolume: ' 24'
issue: '8'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
project:
- _id: '52'
name: 'PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing'
publication: International Journal of Molecular Sciences
publication_identifier:
issn:
- 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Investigation of the Compatibility between Warheads and Peptidomimetic Sequences
of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study
type: journal_article
user_id: '67287'
volume: 24
year: '2023'
...
---
_id: '46547'
author:
- first_name: Andrea
full_name: Rogolino, Andrea
last_name: Rogolino
- first_name: José B. G.
full_name: Filho, José B. G.
last_name: Filho
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: José D.
full_name: Ardisson, José D.
last_name: Ardisson
- first_name: Marcos A. R.
full_name: da Silva, Marcos A. R.
last_name: da Silva
- first_name: Gabriel Ali
full_name: Atta Diab, Gabriel Ali
last_name: Atta Diab
- first_name: Ingrid Fernandes
full_name: Silva, Ingrid Fernandes
last_name: Silva
- first_name: Carlos André Ferreira
full_name: Moraes, Carlos André Ferreira
last_name: Moraes
- first_name: Moacir Rossi
full_name: Forim, Moacir Rossi
last_name: Forim
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Markus
full_name: Antonietti, Markus
last_name: Antonietti
- first_name: Ivo F.
full_name: Teixeira, Ivo F.
last_name: Teixeira
citation:
ama: Rogolino A, Filho JBG, Fritsch L, et al. Direct Synthesis of Acetone by Aerobic
Propane Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions.
ACS Catalysis. 2023;13(13):8662-8669. doi:10.1021/acscatal.3c02092
apa: Rogolino, A., Filho, J. B. G., Fritsch, L., Ardisson, J. D., da Silva, M. A.
R., Atta Diab, G. A., Silva, I. F., Moraes, C. A. F., Forim, M. R., Bauer, M.,
Kühne, T. D., Antonietti, M., & Teixeira, I. F. (2023). Direct Synthesis of
Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III) Chloride
under Mild Conditions. ACS Catalysis, 13(13), 8662–8669. https://doi.org/10.1021/acscatal.3c02092
bibtex: '@article{Rogolino_Filho_Fritsch_Ardisson_da Silva_Atta Diab_Silva_Moraes_Forim_Bauer_et
al._2023, title={Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted
by Photoactive Iron(III) Chloride under Mild Conditions}, volume={13}, DOI={10.1021/acscatal.3c02092},
number={13}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Rogolino, Andrea and Filho, José B. G. and Fritsch, Lorena and Ardisson,
José D. and da Silva, Marcos A. R. and Atta Diab, Gabriel Ali and Silva, Ingrid
Fernandes and Moraes, Carlos André Ferreira and Forim, Moacir Rossi and Bauer,
Matthias and et al.}, year={2023}, pages={8662–8669} }'
chicago: 'Rogolino, Andrea, José B. G. Filho, Lorena Fritsch, José D. Ardisson,
Marcos A. R. da Silva, Gabriel Ali Atta Diab, Ingrid Fernandes Silva, et al. “Direct
Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive Iron(III)
Chloride under Mild Conditions.” ACS Catalysis 13, no. 13 (2023): 8662–69.
https://doi.org/10.1021/acscatal.3c02092.'
ieee: 'A. Rogolino et al., “Direct Synthesis of Acetone by Aerobic Propane
Oxidation Promoted by Photoactive Iron(III) Chloride under Mild Conditions,” ACS
Catalysis, vol. 13, no. 13, pp. 8662–8669, 2023, doi: 10.1021/acscatal.3c02092.'
mla: Rogolino, Andrea, et al. “Direct Synthesis of Acetone by Aerobic Propane Oxidation
Promoted by Photoactive Iron(III) Chloride under Mild Conditions.” ACS Catalysis,
vol. 13, no. 13, American Chemical Society (ACS), 2023, pp. 8662–69, doi:10.1021/acscatal.3c02092.
short: A. Rogolino, J.B.G. Filho, L. Fritsch, J.D. Ardisson, M.A.R. da Silva, G.A.
Atta Diab, I.F. Silva, C.A.F. Moraes, M.R. Forim, M. Bauer, T.D. Kühne, M. Antonietti,
I.F. Teixeira, ACS Catalysis 13 (2023) 8662–8669.
date_created: 2023-08-16T14:44:11Z
date_updated: 2024-03-07T09:34:41Z
doi: 10.1021/acscatal.3c02092
intvolume: ' 13'
issue: '13'
keyword:
- Catalysis
- General Chemistry
- pc2-ressources
- Computing Resources Provided by the Paderborn Center for Parallel Computing
language:
- iso: eng
page: 8662-8669
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Direct Synthesis of Acetone by Aerobic Propane Oxidation Promoted by Photoactive
Iron(III) Chloride under Mild Conditions
type: journal_article
user_id: '44418'
volume: 13
year: '2023'
...
---
_id: '52542'
abstract:
- lang: eng
text: 'AbstractWe report on so‐called “hidden FLPs”
(FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group
13 fragment in the ortho position of a phenyl ring
scaffold to form five‐membered ring structures. Although the formation of the
Lewis acid/base adducts was observed in the solid state, most of the title compounds
readily react with carbon dioxide to provide stable insertion products. Strikingly,
0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze
the reduction of CO2 to methanol with satisfactory high selectivity
and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive
computational studies provided valuable mechanistic insights and shed more light
on activity differences.'
author:
- first_name: Felix
full_name: Krämer, Felix
last_name: Krämer
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
- first_name: Israel
full_name: Fernández, Israel
last_name: Fernández
- first_name: Frank
full_name: Breher, Frank
last_name: Breher
citation:
ama: 'Krämer F, Paradies J, Fernández I, Breher F. Quo Vadis CO2 Activation:
Catalytic Reduction of CO2 to Methanol Using Aluminum and Gallium/Carbon‐based
Ambiphiles. Chemistry – A European Journal. 2023;30(5). doi:10.1002/chem.202303380'
apa: 'Krämer, F., Paradies, J., Fernández, I., & Breher, F. (2023). Quo Vadis
CO2 Activation: Catalytic Reduction of CO2 to Methanol Using
Aluminum and Gallium/Carbon‐based Ambiphiles. Chemistry – A European Journal,
30(5). https://doi.org/10.1002/chem.202303380'
bibtex: '@article{Krämer_Paradies_Fernández_Breher_2023, title={Quo Vadis CO2
Activation: Catalytic Reduction of CO2 to Methanol Using Aluminum and
Gallium/Carbon‐based Ambiphiles}, volume={30}, DOI={10.1002/chem.202303380},
number={5}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Krämer,
Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}, year={2023}
}'
chicago: 'Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “Quo
Vadis CO2 Activation: Catalytic Reduction of CO2 to Methanol
Using Aluminum and Gallium/Carbon‐based Ambiphiles.” Chemistry – A European
Journal 30, no. 5 (2023). https://doi.org/10.1002/chem.202303380.'
ieee: 'F. Krämer, J. Paradies, I. Fernández, and F. Breher, “Quo Vadis CO2
Activation: Catalytic Reduction of CO2 to Methanol Using Aluminum and
Gallium/Carbon‐based Ambiphiles,” Chemistry – A European Journal, vol.
30, no. 5, 2023, doi: 10.1002/chem.202303380.'
mla: 'Krämer, Felix, et al. “Quo Vadis CO2 Activation: Catalytic Reduction
of CO2 to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.”
Chemistry – A European Journal, vol. 30, no. 5, Wiley, 2023, doi:10.1002/chem.202303380.'
short: F. Krämer, J. Paradies, I. Fernández, F. Breher, Chemistry – A European Journal
30 (2023).
date_created: 2024-03-13T17:17:52Z
date_updated: 2024-03-13T17:18:17Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/chem.202303380
intvolume: ' 30'
issue: '5'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Quo Vadis CO2 Activation: Catalytic Reduction of CO2
to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles'
type: journal_article
user_id: '53339'
volume: 30
year: '2023'
...
---
_id: '52344'
abstract:
- lang: eng
text: Macrocyclization reactions are still challenging due to competing oligomerization,
which requires the use of small substrate concentrations. Here, the cationic tungsten
imido and tungsten oxo alkylidene N-heterocyclic carbene complexes [[W(N-2,6-Cl2-C6H3)(CHCMe2Ph(OC6F5)(pivalonitrile)(IMes)+
B(ArF)4−] (W1) and [W(O)(CHCMe2Ph(OCMe(CF3)2)(IMes)(CH3CN)+ B(ArF)4−] (W2) (IMes=1,3-dimesitylimidazol-2-ylidene;
B(ArF)4−=tetrakis(3,5-bis(trifluoromethyl)phenyl borate) have been immobilized
inside the pores of ordered mesoporous silica (OMS) with pore diameters of 3.3
and 6.8 nm, respectively, using a pore-selective immobilization protocol. X-ray
absorption spectroscopy of W1@OMS showed that even though the catalyst structure
is contracted due to confinement by the mesopores, both the oxidation state and
structure of the catalyst stayed intact upon immobilization. Catalytic testing
with four differently sized α,ω-dienes revealed a dramatically increased macrocyclization
(MC) and Z-selectivity of the supported catalysts compared to the homogenous progenitors,
allowing high substrate concentrations of 25 mM. With the supported complexes,
a maximum increase in MC-selectivity from 27 to 81 % and in Z-selectivity from
17 to 34 % was achieved. In general, smaller mesopores exhibited a stronger confinement
effect. A comparison of the two supported tungsten-based catalysts showed that
W1@OMS possesses a higher MC-selectivity, while W2@OMS exhibits a higher Z-selectivity
which can be rationalized by the structures of the catalysts.
article_type: original
author:
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Patrick
full_name: Probst, Patrick
last_name: Probst
- first_name: Boshra
full_name: Atwi, Boshra
last_name: Atwi
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: Ziegler F, Bruckner JR, Nowakowski M, et al. Macrocyclization of Dienes under
Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic
Carbene Complexes. ChemCatChem. 2023;15(21). doi:10.1002/cctc.202300871
apa: Ziegler, F., Bruckner, J. R., Nowakowski, M., Bauer, M., Probst, P., Atwi,
B., & Buchmeiser, M. R. (2023). Macrocyclization of Dienes under Confinement
with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes.
ChemCatChem, 15(21). https://doi.org/10.1002/cctc.202300871
bibtex: '@article{Ziegler_Bruckner_Nowakowski_Bauer_Probst_Atwi_Buchmeiser_2023,
title={Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo
Alkylidene N‐Heterocyclic Carbene Complexes}, volume={15}, DOI={10.1002/cctc.202300871},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Ziegler, Felix
and Bruckner, Johanna R. and Nowakowski, Michał and Bauer, Matthias and Probst,
Patrick and Atwi, Boshra and Buchmeiser, Michael R.}, year={2023} }'
chicago: Ziegler, Felix, Johanna R. Bruckner, Michał Nowakowski, Matthias Bauer,
Patrick Probst, Boshra Atwi, and Michael R. Buchmeiser. “Macrocyclization of Dienes
under Confinement with Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic
Carbene Complexes.” ChemCatChem 15, no. 21 (2023). https://doi.org/10.1002/cctc.202300871.
ieee: 'F. Ziegler et al., “Macrocyclization of Dienes under Confinement with
Cationic Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes,”
ChemCatChem, vol. 15, no. 21, 2023, doi: 10.1002/cctc.202300871.'
mla: Ziegler, Felix, et al. “Macrocyclization of Dienes under Confinement with Cationic
Tungsten Imido/Oxo Alkylidene N‐Heterocyclic Carbene Complexes.” ChemCatChem,
vol. 15, no. 21, Wiley, 2023, doi:10.1002/cctc.202300871.
short: F. Ziegler, J.R. Bruckner, M. Nowakowski, M. Bauer, P. Probst, B. Atwi, M.R.
Buchmeiser, ChemCatChem 15 (2023).
date_created: 2024-03-07T09:44:33Z
date_updated: 2024-05-07T11:41:51Z
department:
- _id: '306'
doi: 10.1002/cctc.202300871
intvolume: ' 15'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo
Alkylidene N‐Heterocyclic Carbene Complexes
type: journal_article
user_id: '48467'
volume: 15
year: '2023'
...
---
_id: '35694'
author:
- first_name: Laura
full_name: Köring, Laura
last_name: Köring
- first_name: Arne
full_name: Stepen, Arne
last_name: Stepen
- first_name: Bernhard
full_name: Birenheide, Bernhard
last_name: Birenheide
- first_name: Simon
full_name: Barth, Simon
last_name: Barth
- first_name: Maxim
full_name: Leskov, Maxim
last_name: Leskov
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Felix
full_name: Krämer, Felix
last_name: Krämer
- first_name: Frank
full_name: Breher, Frank
last_name: Breher
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
citation:
ama: 'Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through
Redox‐Active Ligands: Application in C–F and S–F Bond Activation. Angewandte
Chemie International Edition. Published online 2023. doi:10.1002/anie.202216959'
apa: 'Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R.,
Krämer, F., Breher, F., & Paradies, J. (2023). Boron‐Centered Lewis Superacid
through Redox‐Active Ligands: Application in C–F and S–F Bond Activation. Angewandte
Chemie International Edition. https://doi.org/10.1002/anie.202216959'
bibtex: '@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023,
title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application
in C–F and S–F Bond Activation}, DOI={10.1002/anie.202216959},
journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Köring,
Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim
and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023}
}'
chicago: 'Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov,
Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis
Superacid through Redox‐Active Ligands: Application in C–F and S–F Bond Activation.”
Angewandte Chemie International Edition, 2023. https://doi.org/10.1002/anie.202216959.'
ieee: 'L. Köring et al., “Boron‐Centered Lewis Superacid through Redox‐Active
Ligands: Application in C–F and S–F Bond Activation,” Angewandte Chemie International
Edition, 2023, doi: 10.1002/anie.202216959.'
mla: 'Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active
Ligands: Application in C–F and S–F Bond Activation.” Angewandte Chemie International
Edition, Wiley, 2023, doi:10.1002/anie.202216959.'
short: L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer,
F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).
date_created: 2023-01-10T08:59:12Z
date_updated: 2023-01-23T12:56:01Z
doi: 10.1002/anie.202216959
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
status: public
title: 'Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in
C–F and S–F Bond Activation'
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '35693'
abstract:
- lang: eng
text: In recent years, frustrated Lewis pairs have been widely used in small
molecules activation and catalytic transformations. This graphic review is aimed
to provide the fundamental understanding of frustrated Lewis pair reactivity and
the exploitation thereof in catalytic reactions.
author:
- first_name: Rundong
full_name: Zhou, Rundong
last_name: Zhou
- first_name: Zoleykha
full_name: Tavandashti, Zoleykha
last_name: Tavandashti
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
citation:
ama: Zhou R, Tavandashti Z, Paradies J. Frustrated Lewis Pair Catalysed Reactions.
SynOpen. Published online 2023. doi:10.1055/a-2005-5443
apa: Zhou, R., Tavandashti, Z., & Paradies, J. (2023). Frustrated Lewis Pair
Catalysed Reactions. SynOpen. https://doi.org/10.1055/a-2005-5443
bibtex: '@article{Zhou_Tavandashti_Paradies_2023, title={Frustrated Lewis Pair Catalysed
Reactions}, DOI={10.1055/a-2005-5443},
journal={SynOpen}, publisher={Georg Thieme Verlag KG}, author={Zhou, Rundong and
Tavandashti, Zoleykha and Paradies, Jan}, year={2023} }'
chicago: Zhou, Rundong, Zoleykha Tavandashti, and Jan Paradies. “Frustrated Lewis
Pair Catalysed Reactions.” SynOpen, 2023. https://doi.org/10.1055/a-2005-5443.
ieee: 'R. Zhou, Z. Tavandashti, and J. Paradies, “Frustrated Lewis Pair Catalysed
Reactions,” SynOpen, 2023, doi: 10.1055/a-2005-5443.'
mla: Zhou, Rundong, et al. “Frustrated Lewis Pair Catalysed Reactions.” SynOpen,
Georg Thieme Verlag KG, 2023, doi:10.1055/a-2005-5443.
short: R. Zhou, Z. Tavandashti, J. Paradies, SynOpen (2023).
date_created: 2023-01-10T08:58:57Z
date_updated: 2023-01-23T12:54:12Z
doi: 10.1055/a-2005-5443
keyword:
- Organic Chemistry
- Materials Science (miscellaneous)
- Biomaterials
- Catalysis
language:
- iso: eng
publication: SynOpen
publication_identifier:
issn:
- 2509-9396
publication_status: published
publisher: Georg Thieme Verlag KG
status: public
title: Frustrated Lewis Pair Catalysed Reactions
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '42878'
author:
- first_name: Laura
full_name: Köring, Laura
last_name: Köring
- first_name: Arne
full_name: Stepen, Arne
last_name: Stepen
- first_name: Bernhard
full_name: Birenheide, Bernhard
last_name: Birenheide
- first_name: Simon
full_name: Barth, Simon
last_name: Barth
- first_name: Maxim
full_name: Leskov, Maxim
last_name: Leskov
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Felix
full_name: Krämer, Felix
last_name: Krämer
- first_name: Frank
full_name: Breher, Frank
last_name: Breher
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
citation:
ama: 'Köring L, Stepen A, Birenheide B, et al. Boron‐Centered Lewis Superacid through
Redox‐Active Ligands: Application in C−F and S−F Bond Activation. Angewandte
Chemie International Edition. Published online 2023. doi:10.1002/anie.202301632'
apa: 'Köring, L., Stepen, A., Birenheide, B., Barth, S., Leskov, M., Schoch, R.,
Krämer, F., Breher, F., & Paradies, J. (2023). Boron‐Centered Lewis Superacid
through Redox‐Active Ligands: Application in C−F and S−F Bond Activation. Angewandte
Chemie International Edition. https://doi.org/10.1002/anie.202301632'
bibtex: '@article{Köring_Stepen_Birenheide_Barth_Leskov_Schoch_Krämer_Breher_Paradies_2023,
title={Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application
in C−F and S−F Bond Activation}, DOI={10.1002/anie.202301632},
journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Köring,
Laura and Stepen, Arne and Birenheide, Bernhard and Barth, Simon and Leskov, Maxim
and Schoch, Roland and Krämer, Felix and Breher, Frank and Paradies, Jan}, year={2023}
}'
chicago: 'Köring, Laura, Arne Stepen, Bernhard Birenheide, Simon Barth, Maxim Leskov,
Roland Schoch, Felix Krämer, Frank Breher, and Jan Paradies. “Boron‐Centered Lewis
Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation.”
Angewandte Chemie International Edition, 2023. https://doi.org/10.1002/anie.202301632.'
ieee: 'L. Köring et al., “Boron‐Centered Lewis Superacid through Redox‐Active
Ligands: Application in C−F and S−F Bond Activation,” Angewandte Chemie International
Edition, 2023, doi: 10.1002/anie.202301632.'
mla: 'Köring, Laura, et al. “Boron‐Centered Lewis Superacid through Redox‐Active
Ligands: Application in C−F and S−F Bond Activation.” Angewandte Chemie International
Edition, Wiley, 2023, doi:10.1002/anie.202301632.'
short: L. Köring, A. Stepen, B. Birenheide, S. Barth, M. Leskov, R. Schoch, F. Krämer,
F. Breher, J. Paradies, Angewandte Chemie International Edition (2023).
date_created: 2023-03-08T19:27:25Z
date_updated: 2023-03-08T19:31:59Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/anie.202301632
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
status: public
title: 'Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in
C−F and S−F Bond Activation'
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '44116'
abstract:
- lang: eng
text: Faradaic reactions including charge transfer are often accompanied with diffusion
limitation inside the bulk. Conductive two-dimensional frameworks (2D MOFs) with
a fast ion transport can combine both - charge transfer and fast diffusion inside
their porous structure. To study remaining diffusion limitations caused by particle
morphology, different synthesis routes of Cu-2,3,6,7,10,11-hexahydroxytriphenylene
(Cu3(HHTP)2), a copper-based 2D MOF, are used to obtain flake- and rod-like MOF
particles. Both morphologies are systematically characterized and evaluated for
redox-active Li+ ion storage. The redox mechanism is investigated by means of
X-ray absorption spectroscopy, FTIR spectroscopy and in situ XRD. Both types are
compared regarding kinetic properties for Li+ ion storage via cyclic voltammetry
and impedance spectroscopy. A significant influence of particle morphology for
2D MOFs on kinetic aspects of electrochemical Li+ ion storage can be observed.
This study opens the path for optimization of redox active porous structures to
overcome diffusion limitations of Faradaic processes.
author:
- first_name: Jens Matthies
full_name: Wrogemann, Jens Matthies
last_name: Wrogemann
- first_name: Marco Joes
full_name: Lüther, Marco Joes
last_name: Lüther
- first_name: Peer
full_name: Bärmann, Peer
last_name: Bärmann
- first_name: Mailis
full_name: Lounasvuori, Mailis
last_name: Lounasvuori
- first_name: Ali
full_name: Javed, Ali
last_name: Javed
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
- first_name: Ronny
full_name: Golnak, Ronny
last_name: Golnak
- first_name: Jie
full_name: Xiao, Jie
last_name: Xiao
- first_name: Tristan
full_name: Petit, Tristan
last_name: Petit
- first_name: Tobias
full_name: Placke, Tobias
last_name: Placke
- first_name: Martin
full_name: Winter, Martin
last_name: Winter
citation:
ama: 'Wrogemann JM, Lüther MJ, Bärmann P, et al. Overcoming Diffusion Limitation
of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic
Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage. Angewandte Chemie
International Edition. 2023;62(26):e202303111. doi:10.1002/anie.202303111'
apa: 'Wrogemann, J. M., Lüther, M. J., Bärmann, P., Lounasvuori, M., Javed, A.,
Tiemann, M., Golnak, R., Xiao, J., Petit, T., Placke, T., & Winter, M. (2023).
Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance Relationships
of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible Lithium‐Ion
Storage. Angewandte Chemie International Edition, 62(26), e202303111.
https://doi.org/10.1002/anie.202303111'
bibtex: '@article{Wrogemann_Lüther_Bärmann_Lounasvuori_Javed_Tiemann_Golnak_Xiao_Petit_Placke_et
al._2023, title={Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance
Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible
Lithium‐Ion Storage}, volume={62}, DOI={10.1002/anie.202303111},
number={26}, journal={Angewandte Chemie International Edition}, publisher={Wiley},
author={Wrogemann, Jens Matthies and Lüther, Marco Joes and Bärmann, Peer and
Lounasvuori, Mailis and Javed, Ali and Tiemann, Michael and Golnak, Ronny and
Xiao, Jie and Petit, Tristan and Placke, Tobias and et al.}, year={2023}, pages={e202303111}
}'
chicago: 'Wrogemann, Jens Matthies, Marco Joes Lüther, Peer Bärmann, Mailis Lounasvuori,
Ali Javed, Michael Tiemann, Ronny Golnak, et al. “Overcoming Diffusion Limitation
of Faradaic Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic
Framework Cu3(HHTP)2 for Reversible Lithium‐Ion Storage.” Angewandte Chemie
International Edition 62, no. 26 (2023): e202303111. https://doi.org/10.1002/anie.202303111.'
ieee: 'J. M. Wrogemann et al., “Overcoming Diffusion Limitation of Faradaic
Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework
Cu3(HHTP)2 for Reversible Lithium‐Ion Storage,” Angewandte Chemie International
Edition, vol. 62, no. 26, p. e202303111, 2023, doi: 10.1002/anie.202303111.'
mla: 'Wrogemann, Jens Matthies, et al. “Overcoming Diffusion Limitation of Faradaic
Processes: Property‐Performance Relationships of 2D Conductive Metal‐Organic Framework
Cu3(HHTP)2 for Reversible Lithium‐Ion Storage.” Angewandte Chemie International
Edition, vol. 62, no. 26, Wiley, 2023, p. e202303111, doi:10.1002/anie.202303111.'
short: J.M. Wrogemann, M.J. Lüther, P. Bärmann, M. Lounasvuori, A. Javed, M. Tiemann,
R. Golnak, J. Xiao, T. Petit, T. Placke, M. Winter, Angewandte Chemie International
Edition 62 (2023) e202303111.
date_created: 2023-04-22T06:17:33Z
date_updated: 2023-06-21T09:50:14Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1002/anie.202303111
intvolume: ' 62'
issue: '26'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
page: e202303111
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: 'Overcoming Diffusion Limitation of Faradaic Processes: Property‐Performance
Relationships of 2D Conductive Metal‐Organic Framework Cu3(HHTP)2 for Reversible
Lithium‐Ion Storage'
type: journal_article
user_id: '23547'
volume: 62
year: '2023'
...
---
_id: '43827'
abstract:
- lang: eng
text: A series of new organic donor–π–acceptor dyes incorporating a diquat moiety
as a novel electron-acceptor unit have been synthesized and characterized. The
analytical data were supported by DFT calculations. These dyes were explored in
the aerobic thiocyanation of indoles and pyrroles. Here they showed a high photocatalytic
activity under visible light, giving isolated yields of up to 97 %. In addition,
the photocatalytic activity of standalone diquat and methyl viologen through formation
of an electron donor acceptor complex is presented.
article_type: original
author:
- first_name: Armin
full_name: Meier, Armin
last_name: Meier
- first_name: Sabuhi
full_name: Badalov, Sabuhi
id: '78800'
last_name: Badalov
orcid: 0000-0002-8481-4161
- first_name: Timur
full_name: Biktagirov, Timur
id: '65612'
last_name: Biktagirov
- first_name: Wolf Gero
full_name: Schmidt, Wolf Gero
id: '468'
last_name: Schmidt
orcid: 0000-0002-2717-5076
- first_name: René
full_name: Wilhelm, René
last_name: Wilhelm
citation:
ama: 'Meier A, Badalov S, Biktagirov T, Schmidt WG, Wilhelm R. Diquat Based Dyes:
A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation. Chemistry
– A European Journal. 2023;29(22):e202203541. doi:10.1002/chem.202203541'
apa: 'Meier, A., Badalov, S., Biktagirov, T., Schmidt, W. G., & Wilhelm, R.
(2023). Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in
Aerobic Thiocyanation. Chemistry – A European Journal, 29(22), e202203541.
https://doi.org/10.1002/chem.202203541'
bibtex: '@article{Meier_Badalov_Biktagirov_Schmidt_Wilhelm_2023, title={Diquat Based
Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation},
volume={29}, DOI={10.1002/chem.202203541},
number={22}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Meier,
Armin and Badalov, Sabuhi and Biktagirov, Timur and Schmidt, Wolf Gero and Wilhelm,
René}, year={2023}, pages={e202203541} }'
chicago: 'Meier, Armin, Sabuhi Badalov, Timur Biktagirov, Wolf Gero Schmidt, and
René Wilhelm. “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their
Use in Aerobic Thiocyanation.” Chemistry – A European Journal 29, no. 22
(2023): e202203541. https://doi.org/10.1002/chem.202203541.'
ieee: 'A. Meier, S. Badalov, T. Biktagirov, W. G. Schmidt, and R. Wilhelm, “Diquat
Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation,”
Chemistry – A European Journal, vol. 29, no. 22, p. e202203541, 2023, doi:
10.1002/chem.202203541.'
mla: 'Meier, Armin, et al. “Diquat Based Dyes: A New Class of Photoredox Catalysts
and Their Use in Aerobic Thiocyanation.” Chemistry – A European Journal,
vol. 29, no. 22, Wiley, 2023, p. e202203541, doi:10.1002/chem.202203541.'
short: A. Meier, S. Badalov, T. Biktagirov, W.G. Schmidt, R. Wilhelm, Chemistry
– A European Journal 29 (2023) e202203541.
date_created: 2023-04-16T18:14:24Z
date_updated: 2023-06-26T02:29:15Z
department:
- _id: '35'
- _id: '15'
- _id: '170'
- _id: '295'
- _id: '230'
doi: 10.1002/chem.202203541
extern: '1'
issue: '22'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202203541
oa: '1'
page: ' e202203541'
project:
- _id: '52'
name: 'PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing'
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
related_material:
link:
- relation: supplementary_material
url: https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202203541&file=chem202203541-sup-0001-misc_information.pdf
status: public
title: 'Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic
Thiocyanation'
type: journal_article
user_id: '78800'
volume: ' 29'
year: '2023'
...
---
_id: '46277'
author:
- first_name: Benedikt
full_name: Sieland, Benedikt
last_name: Sieland
- first_name: Marcel
full_name: Stahn, Marcel
last_name: Stahn
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Constantin
full_name: Daniliuc, Constantin
last_name: Daniliuc
- first_name: Sebastian
full_name: Spicher, Sebastian
last_name: Spicher
- first_name: Stefan
full_name: Grimme, Stefan
last_name: Grimme
- first_name: Andreas
full_name: Hansen, Andreas
last_name: Hansen
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
citation:
ama: Sieland B, Stahn M, Schoch R, et al. Dispersion Energy‐Stabilized Boron and
Phosphorus Lewis Pairs. Angewandte Chemie International Edition. Published
online 2023. doi:10.1002/anie.202308752
apa: Sieland, B., Stahn, M., Schoch, R., Daniliuc, C., Spicher, S., Grimme, S.,
Hansen, A., & Paradies, J. (2023). Dispersion Energy‐Stabilized Boron and
Phosphorus Lewis Pairs. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202308752
bibtex: '@article{Sieland_Stahn_Schoch_Daniliuc_Spicher_Grimme_Hansen_Paradies_2023,
title={Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs}, DOI={10.1002/anie.202308752}, journal={Angewandte
Chemie International Edition}, publisher={Wiley}, author={Sieland, Benedikt and
Stahn, Marcel and Schoch, Roland and Daniliuc, Constantin and Spicher, Sebastian
and Grimme, Stefan and Hansen, Andreas and Paradies, Jan}, year={2023} }'
chicago: Sieland, Benedikt, Marcel Stahn, Roland Schoch, Constantin Daniliuc, Sebastian
Spicher, Stefan Grimme, Andreas Hansen, and Jan Paradies. “Dispersion Energy‐Stabilized
Boron and Phosphorus Lewis Pairs.” Angewandte Chemie International Edition,
2023. https://doi.org/10.1002/anie.202308752.
ieee: 'B. Sieland et al., “Dispersion Energy‐Stabilized Boron and Phosphorus
Lewis Pairs,” Angewandte Chemie International Edition, 2023, doi: 10.1002/anie.202308752.'
mla: Sieland, Benedikt, et al. “Dispersion Energy‐Stabilized Boron and Phosphorus
Lewis Pairs.” Angewandte Chemie International Edition, Wiley, 2023, doi:10.1002/anie.202308752.
short: B. Sieland, M. Stahn, R. Schoch, C. Daniliuc, S. Spicher, S. Grimme, A. Hansen,
J. Paradies, Angewandte Chemie International Edition (2023).
date_created: 2023-08-03T09:00:33Z
date_updated: 2023-08-03T09:01:41Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/anie.202308752
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
status: public
title: Dispersion Energy‐Stabilized Boron and Phosphorus Lewis Pairs
type: journal_article
user_id: '53339'
year: '2023'
...
---
_id: '46543'
abstract:
- lang: eng
text: The influence of nanoscale surface topography on protein adsorption
is highly important for numerous applications in medicine and technology. Herein,
ferritin adsorption at flat and nanofaceted, single-crystalline Al2O3 surfaces
is investigated using atomic force microscopy and X-ray photoelectron spectroscopy.
The nanofaceted surfaces are generated by the thermal annealing of Al2O3 wafers
at temperatures above 1000 °C, which leads to the formation of faceted saw-tooth-like
surface topographies with periodicities of about 160 nm and amplitudes of about
15 nm. Ferritin adsorption at these nanofaceted surfaces is notably suppressed
compared to the flat surface at a concentration of 10 mg/mL, which is attributed
to lower adsorption affinities of the newly formed facets. Consequently, adsorption
is restricted mostly to the pattern grooves, where the proteins can maximize their
contact area with the surface. However, this effect depends on the protein concentration,
with an inverse trend being observed at 30 mg/mL. Furthermore, different ferritin
adsorption behavior is observed at topographically similar nanofacet patterns
fabricated at different annealing temperatures and attributed to different step
and kink densities. These results demonstrate that while protein adsorption at
solid surfaces can be notably affected by nanofacet patterns, fine-tuning protein
adsorption in this way requires the precise control of facet properties.
article_number: '12808'
author:
- first_name: Bhanu K.
full_name: Pothineni, Bhanu K.
last_name: Pothineni
- first_name: Sabrina
full_name: Kollmann, Sabrina
last_name: Kollmann
- first_name: Xinyang
full_name: Li, Xinyang
last_name: Li
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Denise J.
full_name: Erb, Denise J.
last_name: Erb
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
citation:
ama: Pothineni BK, Kollmann S, Li X, Grundmeier G, Erb DJ, Keller A. Adsorption
of Ferritin at Nanofaceted Al2O3 Surfaces. International Journal of Molecular
Sciences. 2023;24(16). doi:10.3390/ijms241612808
apa: Pothineni, B. K., Kollmann, S., Li, X., Grundmeier, G., Erb, D. J., & Keller,
A. (2023). Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces. International
Journal of Molecular Sciences, 24(16), Article 12808. https://doi.org/10.3390/ijms241612808
bibtex: '@article{Pothineni_Kollmann_Li_Grundmeier_Erb_Keller_2023, title={Adsorption
of Ferritin at Nanofaceted Al2O3 Surfaces}, volume={24}, DOI={10.3390/ijms241612808},
number={1612808}, journal={International Journal of Molecular Sciences}, publisher={MDPI
AG}, author={Pothineni, Bhanu K. and Kollmann, Sabrina and Li, Xinyang and Grundmeier,
Guido and Erb, Denise J. and Keller, Adrian}, year={2023} }'
chicago: Pothineni, Bhanu K., Sabrina Kollmann, Xinyang Li, Guido Grundmeier, Denise
J. Erb, and Adrian Keller. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.”
International Journal of Molecular Sciences 24, no. 16 (2023). https://doi.org/10.3390/ijms241612808.
ieee: 'B. K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D. J. Erb, and A. Keller,
“Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces,” International Journal
of Molecular Sciences, vol. 24, no. 16, Art. no. 12808, 2023, doi: 10.3390/ijms241612808.'
mla: Pothineni, Bhanu K., et al. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.”
International Journal of Molecular Sciences, vol. 24, no. 16, 12808, MDPI
AG, 2023, doi:10.3390/ijms241612808.
short: B.K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D.J. Erb, A. Keller, International
Journal of Molecular Sciences 24 (2023).
date_created: 2023-08-16T10:52:25Z
date_updated: 2023-08-16T10:53:00Z
department:
- _id: '302'
doi: 10.3390/ijms241612808
intvolume: ' 24'
issue: '16'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
publication: International Journal of Molecular Sciences
publication_identifier:
issn:
- 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces
type: journal_article
user_id: '48864'
volume: 24
year: '2023'
...
---
_id: '52343'
abstract:
- lang: eng
text: Improved enantioselectivity in the 1,2-addition was observed for chiral Rh
norbornadiene catalysts immobilized on ordered mesoporous silica with small pores.
Confinement effects were rationalized by experimental and computational studies.
article_type: original
author:
- first_name: Manuel
full_name: Kirchhof, Manuel
last_name: Kirchhof
- first_name: Katrin
full_name: Gugeler, Katrin
last_name: Gugeler
- first_name: Ann-Katrin
full_name: Beurer, Ann-Katrin
last_name: Beurer
- first_name: Felix Richard
full_name: Fischer, Felix Richard
last_name: Fischer
- first_name: Derman
full_name: Batman, Derman
last_name: Batman
- first_name: Soeren M.
full_name: Bauch, Soeren M.
last_name: Bauch
- first_name: Sofia
full_name: Kolin, Sofia
last_name: Kolin
- first_name: Elliot
full_name: Nicholas, Elliot
last_name: Nicholas
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Charlotte
full_name: Vogler, Charlotte
last_name: Vogler
- first_name: Shravan R.
full_name: Kousik, Shravan R.
last_name: Kousik
- first_name: Anna
full_name: Zens, Anna
last_name: Zens
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Petia
full_name: Atanasova, Petia
last_name: Atanasova
- first_name: Stefan
full_name: Naumann, Stefan
last_name: Naumann
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Yvonne
full_name: Traa, Yvonne
last_name: Traa
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Sabine
full_name: Laschat, Sabine
last_name: Laschat
citation:
ama: 'Kirchhof M, Gugeler K, Beurer A-K, et al. Tethering chiral Rh diene complexes
inside mesoporous solids: experimental and theoretical study of substituent, pore
and linker effects on asymmetric catalysis. Catalysis Science Technology.
2023;13(12):3709-3724. doi:10.1039/d3cy00381g'
apa: 'Kirchhof, M., Gugeler, K., Beurer, A.-K., Fischer, F. R., Batman, D., Bauch,
S. M., Kolin, S., Nicholas, E., Schoch, R., Vogler, C., Kousik, S. R., Zens, A.,
Plietker, B., Atanasova, P., Naumann, S., Bauer, M., Bruckner, J. R., Traa, Y.,
Kästner, J., & Laschat, S. (2023). Tethering chiral Rh diene complexes inside
mesoporous solids: experimental and theoretical study of substituent, pore and
linker effects on asymmetric catalysis. Catalysis Science Technology, 13(12),
3709–3724. https://doi.org/10.1039/d3cy00381g'
bibtex: '@article{Kirchhof_Gugeler_Beurer_Fischer_Batman_Bauch_Kolin_Nicholas_Schoch_Vogler_et
al._2023, title={Tethering chiral Rh diene complexes inside mesoporous solids:
experimental and theoretical study of substituent, pore and linker effects on
asymmetric catalysis}, volume={13}, DOI={10.1039/d3cy00381g},
number={12}, journal={Catalysis Science Technology}, publisher={Royal Society
of Chemistry (RSC)}, author={Kirchhof, Manuel and Gugeler, Katrin and Beurer,
Ann-Katrin and Fischer, Felix Richard and Batman, Derman and Bauch, Soeren M.
and Kolin, Sofia and Nicholas, Elliot and Schoch, Roland and Vogler, Charlotte
and et al.}, year={2023}, pages={3709–3724} }'
chicago: 'Kirchhof, Manuel, Katrin Gugeler, Ann-Katrin Beurer, Felix Richard Fischer,
Derman Batman, Soeren M. Bauch, Sofia Kolin, et al. “Tethering Chiral Rh Diene
Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent,
Pore and Linker Effects on Asymmetric Catalysis.” Catalysis Science Technology
13, no. 12 (2023): 3709–24. https://doi.org/10.1039/d3cy00381g.'
ieee: 'M. Kirchhof et al., “Tethering chiral Rh diene complexes inside mesoporous
solids: experimental and theoretical study of substituent, pore and linker effects
on asymmetric catalysis,” Catalysis Science Technology, vol. 13, no. 12,
pp. 3709–3724, 2023, doi: 10.1039/d3cy00381g.'
mla: 'Kirchhof, Manuel, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous
Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects
on Asymmetric Catalysis.” Catalysis Science Technology, vol. 13, no. 12,
Royal Society of Chemistry (RSC), 2023, pp. 3709–24, doi:10.1039/d3cy00381g.'
short: M. Kirchhof, K. Gugeler, A.-K. Beurer, F.R. Fischer, D. Batman, S.M. Bauch,
S. Kolin, E. Nicholas, R. Schoch, C. Vogler, S.R. Kousik, A. Zens, B. Plietker,
P. Atanasova, S. Naumann, M. Bauer, J.R. Bruckner, Y. Traa, J. Kästner, S. Laschat,
Catalysis Science Technology 13 (2023) 3709–3724.
date_created: 2024-03-07T09:12:06Z
date_updated: 2025-06-16T09:00:17Z
department:
- _id: '306'
doi: 10.1039/d3cy00381g
intvolume: ' 13'
issue: '12'
keyword:
- Catalysis
language:
- iso: eng
page: 3709-3724
publication: Catalysis Science Technology
publication_identifier:
issn:
- 2044-4753
- 2044-4761
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: 'Tethering chiral Rh diene complexes inside mesoporous solids: experimental
and theoretical study of substituent, pore and linker effects on asymmetric catalysis'
type: journal_article
user_id: '48467'
volume: 13
year: '2023'
...
---
_id: '48167'
abstract:
- lang: eng
text: AbstractA new approach for the characterization
of CO2 methanation catalysts prepared by thermal decomposition
of a nickel MOF by hard X‐ray photon‐in/photon‐out spectroscopy in form of high
energy resolution fluorescence detected X‐ray absorption near edge structure spectroscopy
(HERFD‐XANES) and valence‐to‐core X‐ray emission (VtC‐XES) is presented. In contrast
to conventional X‐ray absorption spectroscopy, the increased resolution of both
methods allows a more precise phase determination of the final catalyst, which
is influenced by the conditions during MOF decomposition.
author:
- first_name: Sven
full_name: Strübbe, Sven
id: '76968'
last_name: Strübbe
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Strübbe S, Nowakowski M, Schoch R, Bauer M. High‐Resolution X‐ray Absorption
and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation Catalysts.
ChemPhysChem. Published online 2023. doi:10.1002/cphc.202300113
apa: Strübbe, S., Nowakowski, M., Schoch, R., & Bauer, M. (2023). High‐Resolution
X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation
Catalysts. ChemPhysChem. https://doi.org/10.1002/cphc.202300113
bibtex: '@article{Strübbe_Nowakowski_Schoch_Bauer_2023, title={High‐Resolution X‐ray
Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation
Catalysts}, DOI={10.1002/cphc.202300113},
journal={ChemPhysChem}, publisher={Wiley}, author={Strübbe, Sven and Nowakowski,
Michał and Schoch, Roland and Bauer, Matthias}, year={2023} }'
chicago: Strübbe, Sven, Michał Nowakowski, Roland Schoch, and Matthias Bauer. “High‐Resolution
X‐ray Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation
Catalysts.” ChemPhysChem, 2023. https://doi.org/10.1002/cphc.202300113.
ieee: 'S. Strübbe, M. Nowakowski, R. Schoch, and M. Bauer, “High‐Resolution X‐ray
Absorption and Emission Spectroscopy for Detailed Analysis of New CO2 Methanation
Catalysts,” ChemPhysChem, 2023, doi: 10.1002/cphc.202300113.'
mla: Strübbe, Sven, et al. “High‐Resolution X‐ray Absorption and Emission Spectroscopy
for Detailed Analysis of New CO2 Methanation Catalysts.” ChemPhysChem,
Wiley, 2023, doi:10.1002/cphc.202300113.
short: S. Strübbe, M. Nowakowski, R. Schoch, M. Bauer, ChemPhysChem (2023).
date_created: 2023-10-17T08:14:08Z
date_updated: 2025-08-15T12:53:23Z
doi: 10.1002/cphc.202300113
keyword:
- Catalysis
language:
- iso: eng
publication: ChemPhysChem
publication_identifier:
issn:
- 1439-4235
- 1439-7641
publication_status: published
publisher: Wiley
status: public
title: High‐Resolution X‐ray Absorption and Emission Spectroscopy for Detailed Analysis
of New CO2 Methanation Catalysts
type: journal_article
user_id: '48467'
year: '2023'
...
---
_id: '45480'
abstract:
- lang: eng
text: For improved and rational design of catalysts, in-depth knowledge
of their formation and structural evolution during synthesis is a key parameter.
Thus, preparation of a Ni methanation catalyst derived from...
author:
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Sven
full_name: Strübbe, Sven
id: '76968'
last_name: Strübbe
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
citation:
ama: Prinz N, Strübbe S, Bauer M, Zobel M. Structural transitions during Ni nanoparticle
formation by decomposition of a Ni-containing metal-organic framework using in-situ
total scattering. New Journal of Chemistry. Published online 2023. doi:10.1039/d3nj00493g
apa: Prinz, N., Strübbe, S., Bauer, M., & Zobel, M. (2023). Structural transitions
during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic
framework using in-situ total scattering. New Journal of Chemistry. https://doi.org/10.1039/d3nj00493g
bibtex: '@article{Prinz_Strübbe_Bauer_Zobel_2023, title={Structural transitions
during Ni nanoparticle formation by decomposition of a Ni-containing metal-organic
framework using in-situ total scattering}, DOI={10.1039/d3nj00493g},
journal={New Journal of Chemistry}, publisher={Royal Society of Chemistry (RSC)},
author={Prinz, Nils and Strübbe, Sven and Bauer, Matthias and Zobel, Mirijam},
year={2023} }'
chicago: Prinz, Nils, Sven Strübbe, Matthias Bauer, and Mirijam Zobel. “Structural
Transitions during Ni Nanoparticle Formation by Decomposition of a Ni-Containing
Metal-Organic Framework Using in-Situ Total Scattering.” New Journal of Chemistry,
2023. https://doi.org/10.1039/d3nj00493g.
ieee: 'N. Prinz, S. Strübbe, M. Bauer, and M. Zobel, “Structural transitions during
Ni nanoparticle formation by decomposition of a Ni-containing metal-organic framework
using in-situ total scattering,” New Journal of Chemistry, 2023, doi: 10.1039/d3nj00493g.'
mla: Prinz, Nils, et al. “Structural Transitions during Ni Nanoparticle Formation
by Decomposition of a Ni-Containing Metal-Organic Framework Using in-Situ Total
Scattering.” New Journal of Chemistry, Royal Society of Chemistry (RSC),
2023, doi:10.1039/d3nj00493g.
short: N. Prinz, S. Strübbe, M. Bauer, M. Zobel, New Journal of Chemistry (2023).
date_created: 2023-06-06T07:33:35Z
date_updated: 2025-08-15T12:56:35Z
doi: 10.1039/d3nj00493g
keyword:
- Catalysis
language:
- iso: eng
publication: New Journal of Chemistry
publication_identifier:
issn:
- 1144-0546
- 1369-9261
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Structural transitions during Ni nanoparticle formation by decomposition of
a Ni-containing metal-organic framework using in-situ total scattering
type: journal_article
user_id: '48467'
year: '2023'
...
---
_id: '36416'
author:
- first_name: Jianbo
full_name: De, Jianbo
last_name: De
- first_name: Xuekai
full_name: Ma, Xuekai
id: '59416'
last_name: Ma
- first_name: Fan
full_name: Yin, Fan
last_name: Yin
- first_name: Jiahuan
full_name: Ren, Jiahuan
last_name: Ren
- first_name: Jiannian
full_name: Yao, Jiannian
last_name: Yao
- first_name: Stefan
full_name: Schumacher, Stefan
id: '27271'
last_name: Schumacher
orcid: 0000-0003-4042-4951
- first_name: Qing
full_name: Liao, Qing
last_name: Liao
- first_name: Hongbing
full_name: Fu, Hongbing
last_name: Fu
- first_name: Guillaume
full_name: Malpuech, Guillaume
last_name: Malpuech
- first_name: Dmitry
full_name: Solnyshkov, Dmitry
last_name: Solnyshkov
citation:
ama: De J, Ma X, Yin F, et al. Room-Temperature Electrical Field-Enhanced Ultrafast
Switch in Organic Microcavity Polariton Condensates. Journal of the American
Chemical Society (JACS). 2023;145(3):1557-1563. doi:10.1021/jacs.2c07557
apa: De, J., Ma, X., Yin, F., Ren, J., Yao, J., Schumacher, S., Liao, Q., Fu, H.,
Malpuech, G., & Solnyshkov, D. (2023). Room-Temperature Electrical Field-Enhanced
Ultrafast Switch in Organic Microcavity Polariton Condensates. Journal of the
American Chemical Society (JACS), 145(3), 1557–1563. https://doi.org/10.1021/jacs.2c07557
bibtex: '@article{De_Ma_Yin_Ren_Yao_Schumacher_Liao_Fu_Malpuech_Solnyshkov_2023,
title={Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic
Microcavity Polariton Condensates}, volume={145}, DOI={10.1021/jacs.2c07557},
number={3}, journal={Journal of the American Chemical Society (JACS)}, publisher={American
Chemical Society (ACS)}, author={De, Jianbo and Ma, Xuekai and Yin, Fan and Ren,
Jiahuan and Yao, Jiannian and Schumacher, Stefan and Liao, Qing and Fu, Hongbing
and Malpuech, Guillaume and Solnyshkov, Dmitry}, year={2023}, pages={1557–1563}
}'
chicago: 'De, Jianbo, Xuekai Ma, Fan Yin, Jiahuan Ren, Jiannian Yao, Stefan Schumacher,
Qing Liao, Hongbing Fu, Guillaume Malpuech, and Dmitry Solnyshkov. “Room-Temperature
Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity Polariton Condensates.”
Journal of the American Chemical Society (JACS) 145, no. 3 (2023): 1557–63.
https://doi.org/10.1021/jacs.2c07557.'
ieee: 'J. De et al., “Room-Temperature Electrical Field-Enhanced Ultrafast
Switch in Organic Microcavity Polariton Condensates,” Journal of the American
Chemical Society (JACS), vol. 145, no. 3, pp. 1557–1563, 2023, doi: 10.1021/jacs.2c07557.'
mla: De, Jianbo, et al. “Room-Temperature Electrical Field-Enhanced Ultrafast Switch
in Organic Microcavity Polariton Condensates.” Journal of the American Chemical
Society (JACS), vol. 145, no. 3, American Chemical Society (ACS), 2023, pp.
1557–63, doi:10.1021/jacs.2c07557.
short: J. De, X. Ma, F. Yin, J. Ren, J. Yao, S. Schumacher, Q. Liao, H. Fu, G. Malpuech,
D. Solnyshkov, Journal of the American Chemical Society (JACS) 145 (2023) 1557–1563.
date_created: 2023-01-12T12:07:52Z
date_updated: 2025-12-05T13:50:32Z
department:
- _id: '15'
- _id: '170'
- _id: '705'
- _id: '297'
- _id: '230'
- _id: '429'
- _id: '35'
doi: 10.1021/jacs.2c07557
intvolume: ' 145'
issue: '3'
keyword:
- Colloid and Surface Chemistry
- Biochemistry
- General Chemistry
- Catalysis
language:
- iso: eng
page: 1557-1563
project:
- _id: '53'
name: 'TRR 142: TRR 142'
- _id: '54'
name: 'TRR 142 - A: TRR 142 - Project Area A'
- _id: '61'
name: 'TRR 142 - A4: TRR 142 - Subproject A4'
- _id: '53'
name: 'TRR 142: Maßgeschneiderte nichtlineare Photonik: Von grundlegenden Konzepten
zu funktionellen Strukturen'
publication: Journal of the American Chemical Society (JACS)
publication_identifier:
issn:
- 0002-7863
- 1520-5126
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Room-Temperature Electrical Field-Enhanced Ultrafast Switch in Organic Microcavity
Polariton Condensates
type: journal_article
user_id: '16199'
volume: 145
year: '2023'
...