---
_id: '40999'
abstract:
- lang: eng
text: Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl,
NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene)
are presented. Selected catalysts were selectively immobilized inside the mesopores
of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous
progenitors, the immobilized catalysts were used in the hydrosilylation of terminal
alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed
excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic
alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the
neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and
stereoselective catalysts, allowing for the formation of the thermodynamically
less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15
immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement,
showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes,
too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer
was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with
its homogenous counterpart. These are the first examples of high β(Z)-selectivity
in the hydrosilylation of alkynes by confinement generated upon immobilization
inside mesoporous silica.
article_type: original
author:
- first_name: Pradeep K. R.
full_name: Panyam, Pradeep K. R.
last_name: Panyam
- first_name: Boshra
full_name: Atwi, Boshra
last_name: Atwi
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229.
doi:10.1002/chem.202103099'
apa: 'Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer,
M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68),
17220–17229. https://doi.org/10.1002/chem.202103099'
bibtex: '@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic
Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐
and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68},
journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep
K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał
and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229}
}'
chicago: 'Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michał
Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic
Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐
and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European
Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.'
ieee: 'P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol.
27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.'
mla: 'Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol.
27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.'
short: P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R.
Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.
date_created: 2023-01-30T16:48:41Z
date_updated: 2024-05-07T11:43:40Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/chem.202103099
intvolume: ' 27'
issue: '68'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 17220-17229
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement
Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes'
type: journal_article
user_id: '48467'
volume: 27
year: '2021'
...
---
_id: '30216'
author:
- first_name: Marina
full_name: Huber-Gedert, Marina
id: '38352'
last_name: Huber-Gedert
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Ahmet
full_name: Kertmen, Ahmet
last_name: Kertmen
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Natalia
full_name: Lindner, Natalia
last_name: Lindner
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Regine
full_name: Herbst‐Irmer, Regine
last_name: Herbst‐Irmer
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Lennart
full_name: Schmitz, Lennart
last_name: Schmitz
- first_name: Tae‐Kyu
full_name: Choi, Tae‐Kyu
last_name: Choi
- first_name: Jacek
full_name: Kubicki, Jacek
last_name: Kubicki
- first_name: Wojciech
full_name: Gawelda, Wojciech
last_name: Gawelda
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Huber-Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization,
Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry
– A European Journal. 2021;27(38):9905-9918. doi:10.1002/chem.202100766
apa: Huber-Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N.,
Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda,
W., & Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis
of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal,
27(38), 9905–9918. https://doi.org/10.1002/chem.202100766
bibtex: '@article{Huber-Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et
al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis
of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={10.1002/chem.202100766},
number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber-Gedert,
Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner,
Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz,
Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }'
chicago: 'Huber-Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt,
Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization,
Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry
– A European Journal 27, no. 38 (2021): 9905–18. https://doi.org/10.1002/chem.202100766.'
ieee: 'M. Huber-Gedert et al., “Fundamental Characterization, Photophysics
and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” Chemistry –
A European Journal, vol. 27, no. 38, pp. 9905–9918, 2021, doi: 10.1002/chem.202100766.'
mla: Huber-Gedert, Marina, et al. “Fundamental Characterization, Photophysics and
Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European
Journal, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:10.1002/chem.202100766.
short: M. Huber-Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R.
Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda,
M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.
date_created: 2022-03-09T08:20:58Z
date_updated: 2024-05-07T11:44:08Z
department:
- _id: '306'
doi: 10.1002/chem.202100766
intvolume: ' 27'
issue: '38'
keyword:
- Photocatalytic Hydrogen Production
- Catalysis
- Inorganic Chemistry
language:
- iso: eng
page: 9905-9918
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal
Iron(II)‐Cobalt(III) Dyad
type: journal_article
user_id: '48467'
volume: 27
year: '2021'
...
---
_id: '35686'
abstract:
- lang: eng
text: AbstractThe development of the frustrated
Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed.
Detailed insight into our strategies in order to overcome challenges during the
reaction development process is provided. Furthermore, the developed chemistry
is extended to the hydrogenation of polyamides and of trifluoroacetamides for
the convenient introduction of trifluoroethyl groups into organic molecules.
author:
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
- first_name: Laura
full_name: Köring, Laura
last_name: Köring
- first_name: Nikolai A.
full_name: Sitte, Nikolai A.
last_name: Sitte
citation:
ama: Paradies J, Köring L, Sitte NA. Towards the Development of Frustrated Lewis
Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.
Synthesis. 2021;54(05):1287-1300. doi:10.1055/a-1681-3972
apa: Paradies, J., Köring, L., & Sitte, N. A. (2021). Towards the Development
of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary
Carboxylic Amides. Synthesis, 54(05), 1287–1300. https://doi.org/10.1055/a-1681-3972
bibtex: '@article{Paradies_Köring_Sitte_2021, title={Towards the Development of
Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary
Carboxylic Amides}, volume={54}, DOI={10.1055/a-1681-3972},
number={05}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Paradies,
Jan and Köring, Laura and Sitte, Nikolai A.}, year={2021}, pages={1287–1300} }'
chicago: 'Paradies, Jan, Laura Köring, and Nikolai A. Sitte. “Towards the Development
of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary
Carboxylic Amides.” Synthesis 54, no. 05 (2021): 1287–1300. https://doi.org/10.1055/a-1681-3972.'
ieee: 'J. Paradies, L. Köring, and N. A. Sitte, “Towards the Development of Frustrated
Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic
Amides,” Synthesis, vol. 54, no. 05, pp. 1287–1300, 2021, doi: 10.1055/a-1681-3972.'
mla: Paradies, Jan, et al. “Towards the Development of Frustrated Lewis Pair (FLP)
Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” Synthesis,
vol. 54, no. 05, Georg Thieme Verlag KG, 2021, pp. 1287–300, doi:10.1055/a-1681-3972.
short: J. Paradies, L. Köring, N.A. Sitte, Synthesis 54 (2021) 1287–1300.
date_created: 2023-01-10T08:56:44Z
date_updated: 2023-01-23T12:51:23Z
doi: 10.1055/a-1681-3972
intvolume: ' 54'
issue: '05'
keyword:
- Organic Chemistry
- Catalysis
language:
- iso: eng
page: 1287-1300
publication: Synthesis
publication_identifier:
issn:
- 0039-7881
- 1437-210X
publication_status: published
publisher: Georg Thieme Verlag KG
status: public
title: Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations
of Tertiary and Secondary Carboxylic Amides
type: journal_article
user_id: '53339'
volume: 54
year: '2021'
...
---
_id: '40562'
article_number: '120965'
author:
- first_name: Marcos A.R.
full_name: da Silva, Marcos A.R.
last_name: da Silva
- first_name: Ingrid F.
full_name: Silva, Ingrid F.
last_name: Silva
- first_name: Qi
full_name: Xue, Qi
last_name: Xue
- first_name: Benedict T.W.
full_name: Lo, Benedict T.W.
last_name: Lo
- first_name: Nadezda V.
full_name: Tarakina, Nadezda V.
last_name: Tarakina
- first_name: Barbara N.
full_name: Nunes, Barbara N.
last_name: Nunes
- first_name: Peter
full_name: Adler, Peter
last_name: Adler
- first_name: Sudhir K.
full_name: Sahoo, Sudhir K.
last_name: Sahoo
- first_name: Detlef W.
full_name: Bahnemann, Detlef W.
last_name: Bahnemann
- first_name: Nieves
full_name: Lopez Salas, Nieves
last_name: Lopez Salas
- first_name: Aleksandr
full_name: Savateev, Aleksandr
last_name: Savateev
- first_name: Caue
full_name: Ribeiro, Caue
last_name: Ribeiro
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Markus
full_name: Antonietti, Markus
last_name: Antonietti
- first_name: Ivo F.
full_name: Teixeira, Ivo F.
last_name: Teixeira
citation:
ama: 'da Silva MAR, Silva IF, Xue Q, et al. Sustainable oxidation catalysis supported
by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst.
Applied Catalysis B: Environmental. 2021;304. doi:10.1016/j.apcatb.2021.120965'
apa: 'da Silva, M. A. R., Silva, I. F., Xue, Q., Lo, B. T. W., Tarakina, N. V.,
Nunes, B. N., Adler, P., Sahoo, S. K., Bahnemann, D. W., Lopez Salas, N., Savateev,
A., Ribeiro, C., Kühne, T. D., Antonietti, M., & Teixeira, I. F. (2021). Sustainable
oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous
single-atom photocatalyst. Applied Catalysis B: Environmental, 304,
Article 120965. https://doi.org/10.1016/j.apcatb.2021.120965'
bibtex: '@article{da Silva_Silva_Xue_Lo_Tarakina_Nunes_Adler_Sahoo_Bahnemann_Lopez
Salas_et al._2021, title={Sustainable oxidation catalysis supported by light:
Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}, volume={304},
DOI={10.1016/j.apcatb.2021.120965},
number={120965}, journal={Applied Catalysis B: Environmental}, publisher={Elsevier
BV}, author={da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict
T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo,
Sudhir K. and Bahnemann, Detlef W. and Lopez Salas, Nieves and et al.}, year={2021}
}'
chicago: 'Silva, Marcos A.R. da, Ingrid F. Silva, Qi Xue, Benedict T.W. Lo, Nadezda
V. Tarakina, Barbara N. Nunes, Peter Adler, et al. “Sustainable Oxidation Catalysis
Supported by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.”
Applied Catalysis B: Environmental 304 (2021). https://doi.org/10.1016/j.apcatb.2021.120965.'
ieee: 'M. A. R. da Silva et al., “Sustainable oxidation catalysis supported
by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst,”
Applied Catalysis B: Environmental, vol. 304, Art. no. 120965, 2021, doi:
10.1016/j.apcatb.2021.120965.'
mla: 'da Silva, Marcos A. R., et al. “Sustainable Oxidation Catalysis Supported
by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.”
Applied Catalysis B: Environmental, vol. 304, 120965, Elsevier BV, 2021,
doi:10.1016/j.apcatb.2021.120965.'
short: 'M.A.R. da Silva, I.F. Silva, Q. Xue, B.T.W. Lo, N.V. Tarakina, B.N. Nunes,
P. Adler, S.K. Sahoo, D.W. Bahnemann, N. Lopez Salas, A. Savateev, C. Ribeiro,
T.D. Kühne, M. Antonietti, I.F. Teixeira, Applied Catalysis B: Environmental 304
(2021).'
date_created: 2023-01-27T16:15:03Z
date_updated: 2023-01-27T16:35:15Z
doi: 10.1016/j.apcatb.2021.120965
intvolume: ' 304'
keyword:
- Process Chemistry and Technology
- General Environmental Science
- Catalysis
language:
- iso: eng
publication: 'Applied Catalysis B: Environmental'
publication_identifier:
issn:
- 0926-3373
publication_status: published
publisher: Elsevier BV
status: public
title: 'Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide)
as a heterogeneous single-atom photocatalyst'
type: journal_article
user_id: '98120'
volume: 304
year: '2021'
...
---
_id: '41323'
author:
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Hamzeh
full_name: Kraus, Hamzeh
last_name: Kraus
- first_name: Mathis J.
full_name: Benedikter, Mathis J.
last_name: Benedikter
- first_name: Dongren
full_name: Wang, Dongren
last_name: Wang
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Kilian
full_name: Weißer, Kilian
last_name: Weißer
- first_name: Helena
full_name: Solodenko, Helena
last_name: Solodenko
- first_name: Guido
full_name: Schmitz, Guido
last_name: Schmitz
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Niels
full_name: Hansen, Niels
last_name: Hansen
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient
Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene
N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578.
doi:10.1021/acscatal.1c03057
apa: Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski,
M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser,
M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with
Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.
ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057
bibtex: '@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et
al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions
with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene
Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057},
number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren
and Bruckner, Johanna R. and Nowakowski, Michal and Weißer, Kilian and Solodenko,
Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578}
}'
chicago: 'Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna
R. Bruckner, Michal Nowakowski, Kilian Weißer, et al. “Confinement Effects for
Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11,
no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.'
ieee: 'F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021,
doi: 10.1021/acscatal.1c03057.'
mla: Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society
(ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057.
short: F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski,
K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS
Catalysis 11 (2021) 11570–11578.
date_created: 2023-01-31T22:50:23Z
date_updated: 2023-02-01T08:50:59Z
doi: 10.1021/acscatal.1c03057
intvolume: ' 11'
issue: '18'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 11570-11578
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Confinement Effects for Efficient Macrocyclization Reactions with Supported
Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
type: journal_article
user_id: '78878'
volume: 11
year: '2021'
...
---
_id: '41325'
author:
- first_name: Marina
full_name: Huber‐Gedert, Marina
last_name: Huber‐Gedert
- first_name: Michał
full_name: Nowakowski, Michał
last_name: Nowakowski
- first_name: Ahmet
full_name: Kertmen, Ahmet
last_name: Kertmen
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Natalia
full_name: Lindner, Natalia
last_name: Lindner
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Regine
full_name: Herbst‐Irmer, Regine
last_name: Herbst‐Irmer
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Lennart
full_name: Schmitz, Lennart
last_name: Schmitz
- first_name: Tae‐Kyu
full_name: Choi, Tae‐Kyu
last_name: Choi
- first_name: Jacek
full_name: Kubicki, Jacek
last_name: Kubicki
- first_name: Wojciech
full_name: Gawelda, Wojciech
last_name: Gawelda
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
citation:
ama: Huber‐Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization,
Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry
– A European Journal. 2021;27(38):9905-9918. doi:10.1002/chem.202100766
apa: Huber‐Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N.,
Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda,
W., & Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis
of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal,
27(38), 9905–9918. https://doi.org/10.1002/chem.202100766
bibtex: '@article{Huber‐Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et
al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis
of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={10.1002/chem.202100766},
number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber‐Gedert,
Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner,
Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz,
Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }'
chicago: 'Huber‐Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt,
Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization,
Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry
– A European Journal 27, no. 38 (2021): 9905–18. https://doi.org/10.1002/chem.202100766.'
ieee: 'M. Huber‐Gedert et al., “Fundamental Characterization, Photophysics
and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” Chemistry –
A European Journal, vol. 27, no. 38, pp. 9905–9918, 2021, doi: 10.1002/chem.202100766.'
mla: Huber‐Gedert, Marina, et al. “Fundamental Characterization, Photophysics and
Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European
Journal, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:10.1002/chem.202100766.
short: M. Huber‐Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R.
Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda,
M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.
date_created: 2023-01-31T22:51:06Z
date_updated: 2023-02-01T08:50:53Z
doi: 10.1002/chem.202100766
intvolume: ' 27'
issue: '38'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 9905-9918
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal
Iron(II)‐Cobalt(III) Dyad
type: journal_article
user_id: '78878'
volume: 27
year: '2021'
...
---
_id: '41322'
author:
- first_name: Pradeep K. R.
full_name: Panyam, Pradeep K. R.
last_name: Panyam
- first_name: Boshra
full_name: Atwi, Boshra
last_name: Atwi
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229.
doi:10.1002/chem.202103099'
apa: 'Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer,
M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68),
17220–17229. https://doi.org/10.1002/chem.202103099'
bibtex: '@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic
Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐
and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68},
journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep
K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michal
and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229}
}'
chicago: 'Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michal
Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic
Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐
and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European
Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.'
ieee: 'P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol.
27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.'
mla: 'Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol.
27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.'
short: P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R.
Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.
date_created: 2023-01-31T22:50:03Z
date_updated: 2023-02-01T08:51:03Z
doi: 10.1002/chem.202103099
intvolume: ' 27'
issue: '68'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 17220-17229
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement
Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes'
type: journal_article
user_id: '78878'
volume: 27
year: '2021'
...
---
_id: '40998'
abstract:
- lang: eng
text: Covalent organic frameworks (COFs) offer vast structural and chemical diversity
enabling a wide and growing range of applications. While COFs are well-established
as heterogeneous catalysts, so far, their high and ordered porosity has scarcely
been utilized to its full potential when it comes to spatially confined reactions
in COF pores to alter the outcome of reactions. Here, we present a highly porous
and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing
metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall
modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation
reaction provides a molecularly precise heterogeneous olefin metathesis catalyst.
An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O)
for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the
homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency
in selectivity, pointing to diffusion limitations induced by the pore confinement.
article_type: original
author:
- first_name: Sebastian T.
full_name: Emmerling, Sebastian T.
last_name: Emmerling
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Felix R.
full_name: Fischer, Felix R.
last_name: Fischer
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
- first_name: Bettina V.
full_name: Lotsch, Bettina V.
last_name: Lotsch
citation:
ama: 'Emmerling ST, Ziegler F, Fischer FR, et al. Olefin Metathesis in Confinement:
Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.
Chemistry – A European Journal. 2021;28(8). doi:10.1002/chem.202104108'
apa: 'Emmerling, S. T., Ziegler, F., Fischer, F. R., Schoch, R., Bauer, M., Plietker,
B., Buchmeiser, M. R., & Lotsch, B. V. (2021). Olefin Metathesis in Confinement:
Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.
Chemistry – A European Journal, 28(8). https://doi.org/10.1002/chem.202104108'
bibtex: '@article{Emmerling_Ziegler_Fischer_Schoch_Bauer_Plietker_Buchmeiser_Lotsch_2021,
title={Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds
for Increased Macrocyclization Selectivity}, volume={28}, DOI={10.1002/chem.202104108},
number={8}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Emmerling,
Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer,
Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.},
year={2021} }'
chicago: 'Emmerling, Sebastian T., Felix Ziegler, Felix R. Fischer, Roland Schoch,
Matthias Bauer, Bernd Plietker, Michael R. Buchmeiser, and Bettina V. Lotsch.
“Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds
for Increased Macrocyclization Selectivity.” Chemistry – A European Journal
28, no. 8 (2021). https://doi.org/10.1002/chem.202104108.'
ieee: 'S. T. Emmerling et al., “Olefin Metathesis in Confinement: Towards
Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity,”
Chemistry – A European Journal, vol. 28, no. 8, 2021, doi: 10.1002/chem.202104108.'
mla: 'Emmerling, Sebastian T., et al. “Olefin Metathesis in Confinement: Towards
Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.”
Chemistry – A European Journal, vol. 28, no. 8, Wiley, 2021, doi:10.1002/chem.202104108.'
short: S.T. Emmerling, F. Ziegler, F.R. Fischer, R. Schoch, M. Bauer, B. Plietker,
M.R. Buchmeiser, B.V. Lotsch, Chemistry – A European Journal 28 (2021).
date_created: 2023-01-30T16:48:22Z
date_updated: 2023-01-31T08:05:07Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/chem.202104108
intvolume: ' 28'
issue: '8'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds
for Increased Macrocyclization Selectivity'
type: journal_article
user_id: '48467'
volume: 28
year: '2021'
...
---
_id: '41003'
abstract:
- lang: eng
text: Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting
pyridine ligands with a high octahedricity in rigid iron(II) complexes increases
the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2
ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane)
forms six-membered chelate rings with the iron(II) centre leading to close to
90° bite angles and enhanced iron-ligand orbital overlap
article_type: original
author:
- first_name: Thomas
full_name: Reuter, Thomas
last_name: Reuter
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
citation:
ama: Reuter T, Kruse A, Schoch R, Lochbrunner S, Bauer M, Heinze K. Higher MLCT
lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring
expansion. Chemical Communications. 2021;57(61):7541-7544. doi:10.1039/d1cc02173g
apa: Reuter, T., Kruse, A., Schoch, R., Lochbrunner, S., Bauer, M., & Heinze,
K. (2021). Higher MLCT lifetime of carbene iron(<scp>ii</scp>)
complexes by chelate ring expansion. Chemical Communications, 57(61),
7541–7544. https://doi.org/10.1039/d1cc02173g
bibtex: '@article{Reuter_Kruse_Schoch_Lochbrunner_Bauer_Heinze_2021, title={Higher
MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate
ring expansion}, volume={57}, DOI={10.1039/d1cc02173g},
number={61}, journal={Chemical Communications}, publisher={Royal Society of Chemistry
(RSC)}, author={Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner,
Stefan and Bauer, Matthias and Heinze, Katja}, year={2021}, pages={7541–7544}
}'
chicago: 'Reuter, Thomas, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias
Bauer, and Katja Heinze. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>)
Complexes by Chelate Ring Expansion.” Chemical Communications 57, no. 61
(2021): 7541–44. https://doi.org/10.1039/d1cc02173g.'
ieee: 'T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, and K. Heinze,
“Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes
by chelate ring expansion,” Chemical Communications, vol. 57, no. 61, pp.
7541–7544, 2021, doi: 10.1039/d1cc02173g.'
mla: Reuter, Thomas, et al. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>)
Complexes by Chelate Ring Expansion.” Chemical Communications, vol. 57,
no. 61, Royal Society of Chemistry (RSC), 2021, pp. 7541–44, doi:10.1039/d1cc02173g.
short: T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, K. Heinze, Chemical
Communications 57 (2021) 7541–7544.
date_created: 2023-01-30T16:49:33Z
date_updated: 2023-01-31T08:06:16Z
department:
- _id: '35'
- _id: '306'
doi: 10.1039/d1cc02173g
intvolume: ' 57'
issue: '61'
keyword:
- Materials Chemistry
- Metals and Alloys
- Surfaces
- Coatings and Films
- General Chemistry
- Ceramics and Composites
- Electronic
- Optical and Magnetic Materials
- Catalysis
language:
- iso: eng
page: 7541-7544
publication: Chemical Communications
publication_identifier:
issn:
- 1359-7345
- 1364-548X
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Higher MLCT lifetime of carbene iron(ii) complexes by chelate ring
expansion
type: journal_article
user_id: '48467'
volume: 57
year: '2021'
...
---
_id: '41000'
abstract:
- lang: eng
text: Metal-catalyzed C−H activations are environmentally and economically attractive
synthetic strategies for the construction of functional molecules as they obviate
the need for pre-functionalized substrates and minimize waste generation. Great
challenges reside in the control of selectivities, the utilization of unbiased
hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms.
An especially mild borylation of benzylic CH bonds was developed with the ligand-free
pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent
B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic,
and preparative mechanistic studies are indicative of a tandem catalysis mechanism
of CH-borylation and dehydrocoupling via molecular CoI catalysts.
article_type: original
author:
- first_name: Pradip
full_name: Ghosh, Pradip
last_name: Ghosh
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations
by Tandem Cobalt Catalysis. Angewandte Chemie International Edition. 2021;61(1).
doi:10.1002/anie.202110821
apa: Ghosh, P., Schoch, R., Bauer, M., & Jacobi von Wangelin, A. (2021). Selective
Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International
Edition, 61(1). https://doi.org/10.1002/anie.202110821
bibtex: '@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective
Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={10.1002/anie.202110821},
number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley},
author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin,
Axel}, year={2021} }'
chicago: Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin.
“Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte
Chemie International Edition 61, no. 1 (2021). https://doi.org/10.1002/anie.202110821.
ieee: 'P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic
CH‐Borylations by Tandem Cobalt Catalysis,” Angewandte Chemie International
Edition, vol. 61, no. 1, 2021, doi: 10.1002/anie.202110821.'
mla: Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.”
Angewandte Chemie International Edition, vol. 61, no. 1, Wiley, 2021, doi:10.1002/anie.202110821.
short: P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie
International Edition 61 (2021).
date_created: 2023-01-30T16:48:53Z
date_updated: 2023-01-31T08:05:26Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/anie.202110821
intvolume: ' 61'
issue: '1'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
status: public
title: Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis
type: journal_article
user_id: '48467'
volume: 61
year: '2021'
...
---
_id: '41010'
abstract:
- lang: eng
text: We present the η3-coordination of the 2-phosphaethynthiolate anion in the
complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)].
Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2
(3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the
[SCP]− coordination mode is mainly governed by electronic, rather than steric
factors. Quantum mechanical investigations reveal large contributions of the antibonding
π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal
precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore
reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand
to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)}
(5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization
is proposed based on DFT calculations.
article_type: original
author:
- first_name: Fabian A.
full_name: Watt, Fabian A.
last_name: Watt
- first_name: Lukas
full_name: Burkhardt, Lukas
last_name: Burkhardt
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Stefan
full_name: Mitzinger, Stefan
last_name: Mitzinger
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Florian
full_name: Weigend, Florian
last_name: Weigend
- first_name: Jose M.
full_name: Goicoechea, Jose M.
last_name: Goicoechea
- first_name: Frank
full_name: Tambornino, Frank
last_name: Tambornino
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
citation:
ama: Watt FA, Burkhardt L, Schoch R, et al. η 3
‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.
Angewandte Chemie International Edition. 2021;60(17):9534-9539. doi:10.1002/anie.202100559
apa: Watt, F. A., Burkhardt, L., Schoch, R., Mitzinger, S., Bauer, M., Weigend,
F., Goicoechea, J. M., Tambornino, F., & Hohloch, S. (2021). η
3 ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate
Anion at Lanthanum(III)**. Angewandte Chemie International Edition, 60(17),
9534–9539. https://doi.org/10.1002/anie.202100559
bibtex: '@article{Watt_Burkhardt_Schoch_Mitzinger_Bauer_Weigend_Goicoechea_Tambornino_Hohloch_2021,
title={η 3 ‐Coordination and Functionalization
of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}, volume={60}, DOI={10.1002/anie.202100559}, number={17},
journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Watt,
Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer,
Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and
Hohloch, Stephan}, year={2021}, pages={9534–9539} }'
chicago: 'Watt, Fabian A., Lukas Burkhardt, Roland Schoch, Stefan Mitzinger, Matthias
Bauer, Florian Weigend, Jose M. Goicoechea, Frank Tambornino, and Stephan Hohloch.
“η 3 ‐Coordination and Functionalization of the
2‐Phosphaethynthiolate Anion at Lanthanum(III)**.” Angewandte Chemie International
Edition 60, no. 17 (2021): 9534–39. https://doi.org/10.1002/anie.202100559.'
ieee: 'F. A. Watt et al., “η 3 ‐Coordination
and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**,”
Angewandte Chemie International Edition, vol. 60, no. 17, pp. 9534–9539,
2021, doi: 10.1002/anie.202100559.'
mla: Watt, Fabian A., et al. “η 3 ‐Coordination
and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**.”
Angewandte Chemie International Edition, vol. 60, no. 17, Wiley, 2021,
pp. 9534–39, doi:10.1002/anie.202100559.
short: F.A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend, J.M.
Goicoechea, F. Tambornino, S. Hohloch, Angewandte Chemie International Edition
60 (2021) 9534–9539.
date_created: 2023-01-30T17:00:21Z
date_updated: 2023-01-31T08:06:50Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/anie.202100559
intvolume: ' 60'
issue: '17'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
page: 9534-9539
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
status: public
title: η 3 ‐Coordination and Functionalization of
the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**
type: journal_article
user_id: '48467'
volume: 60
year: '2021'
...
---
_id: '46000'
author:
- first_name: Ran
full_name: Su, Ran
last_name: Su
- first_name: Zhipeng
full_name: Wang, Zhipeng
last_name: Wang
- first_name: Lina
full_name: Zhu, Lina
last_name: Zhu
- first_name: Ying
full_name: Pan, Ying
id: '100383'
last_name: Pan
- first_name: Dawei
full_name: Zhang, Dawei
last_name: Zhang
- first_name: Hui
full_name: Wen, Hui
last_name: Wen
- first_name: Zheng‐Dong
full_name: Luo, Zheng‐Dong
last_name: Luo
- first_name: Linglong
full_name: Li, Linglong
last_name: Li
- first_name: Fa‐tang
full_name: Li, Fa‐tang
last_name: Li
- first_name: Ming
full_name: Wu, Ming
last_name: Wu
- first_name: Liqiang
full_name: He, Liqiang
last_name: He
- first_name: Pankaj
full_name: Sharma, Pankaj
last_name: Sharma
- first_name: Jan
full_name: Seidel, Jan
last_name: Seidel
citation:
ama: Su R, Wang Z, Zhu L, et al. Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency
Piezocatalytic Overall Water Splitting. Angewandte Chemie International Edition.
2021;60(29):16019-16026. doi:10.1002/anie.202103112
apa: Su, R., Wang, Z., Zhu, L., Pan, Y., Zhang, D., Wen, H., Luo, Z., Li, L., Li,
F., Wu, M., He, L., Sharma, P., & Seidel, J. (2021). Strain‐Engineered Nano‐Ferroelectrics
for High‐Efficiency Piezocatalytic Overall Water Splitting. Angewandte Chemie
International Edition, 60(29), 16019–16026. https://doi.org/10.1002/anie.202103112
bibtex: '@article{Su_Wang_Zhu_Pan_Zhang_Wen_Luo_Li_Li_Wu_et al._2021, title={Strain‐Engineered
Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting},
volume={60}, DOI={10.1002/anie.202103112},
number={29}, journal={Angewandte Chemie International Edition}, publisher={Wiley},
author={Su, Ran and Wang, Zhipeng and Zhu, Lina and Pan, Ying and Zhang, Dawei
and Wen, Hui and Luo, Zheng‐Dong and Li, Linglong and Li, Fa‐tang and Wu, Ming
and et al.}, year={2021}, pages={16019–16026} }'
chicago: 'Su, Ran, Zhipeng Wang, Lina Zhu, Ying Pan, Dawei Zhang, Hui Wen, Zheng‐Dong
Luo, et al. “Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic
Overall Water Splitting.” Angewandte Chemie International Edition 60, no.
29 (2021): 16019–26. https://doi.org/10.1002/anie.202103112.'
ieee: 'R. Su et al., “Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency
Piezocatalytic Overall Water Splitting,” Angewandte Chemie International Edition,
vol. 60, no. 29, pp. 16019–16026, 2021, doi: 10.1002/anie.202103112.'
mla: Su, Ran, et al. “Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency
Piezocatalytic Overall Water Splitting.” Angewandte Chemie International Edition,
vol. 60, no. 29, Wiley, 2021, pp. 16019–26, doi:10.1002/anie.202103112.
short: R. Su, Z. Wang, L. Zhu, Y. Pan, D. Zhang, H. Wen, Z. Luo, L. Li, F. Li, M.
Wu, L. He, P. Sharma, J. Seidel, Angewandte Chemie International Edition 60 (2021)
16019–16026.
date_created: 2023-07-11T14:45:01Z
date_updated: 2023-07-11T16:41:48Z
doi: 10.1002/anie.202103112
extern: '1'
intvolume: ' 60'
issue: '29'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
page: 16019-16026
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
status: public
title: Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall
Water Splitting
type: journal_article
user_id: '100383'
volume: 60
year: '2021'
...
---
_id: '41007'
abstract:
- lang: eng
text: Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine
and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new
insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+
pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime
after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses
a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with
four mesoionic carbenes.
article_type: original
author:
- first_name: Philipp
full_name: Dierks, Philipp
last_name: Dierks
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Mohammed J.
full_name: Al-Marri, Mohammed J.
last_name: Al-Marri
- first_name: Jens
full_name: Kalmbach, Jens
last_name: Kalmbach
- first_name: Marc
full_name: Baltrun, Marc
last_name: Baltrun
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Michael
full_name: Seitz, Michael
last_name: Seitz
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Dierks P, Kruse A, Bokareva OS, et al. Distinct photodynamics of κ-N and κ-C
pseudoisomeric iron(ii) complexes. Chemical Communications. 2021;57(54):6640-6643.
doi:10.1039/d1cc01716k
apa: Dierks, P., Kruse, A., Bokareva, O. S., Al-Marri, M. J., Kalmbach, J., Baltrun,
M., Neuba, A., Schoch, R., Hohloch, S., Heinze, K., Seitz, M., Kühn, O., Lochbrunner,
S., & Bauer, M. (2021). Distinct photodynamics of κ-N and κ-C pseudoisomeric
iron(ii) complexes. Chemical Communications, 57(54), 6640–6643.
https://doi.org/10.1039/d1cc01716k
bibtex: '@article{Dierks_Kruse_Bokareva_Al-Marri_Kalmbach_Baltrun_Neuba_Schoch_Hohloch_Heinze_et
al._2021, title={Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii)
complexes}, volume={57}, DOI={10.1039/d1cc01716k},
number={54}, journal={Chemical Communications}, publisher={Royal Society of Chemistry
(RSC)}, author={Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri,
Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland
and Hohloch, Stephan and Heinze, Katja and et al.}, year={2021}, pages={6640–6643}
}'
chicago: 'Dierks, Philipp, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens
Kalmbach, Marc Baltrun, Adam Neuba, et al. “Distinct Photodynamics of κ-N and
κ-C Pseudoisomeric Iron(Ii) Complexes.” Chemical Communications 57, no.
54 (2021): 6640–43. https://doi.org/10.1039/d1cc01716k.'
ieee: 'P. Dierks et al., “Distinct photodynamics of κ-N and κ-C pseudoisomeric
iron(ii) complexes,” Chemical Communications, vol. 57, no. 54, pp. 6640–6643,
2021, doi: 10.1039/d1cc01716k.'
mla: Dierks, Philipp, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric
Iron(Ii) Complexes.” Chemical Communications, vol. 57, no. 54, Royal Society
of Chemistry (RSC), 2021, pp. 6640–43, doi:10.1039/d1cc01716k.
short: P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, J. Kalmbach, M. Baltrun,
A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner,
M. Bauer, Chemical Communications 57 (2021) 6640–6643.
date_created: 2023-01-30T16:59:55Z
date_updated: 2024-10-11T08:42:44Z
department:
- _id: '35'
- _id: '306'
doi: 10.1039/d1cc01716k
intvolume: ' 57'
issue: '54'
keyword:
- Materials Chemistry
- Metals and Alloys
- Surfaces
- Coatings and Films
- General Chemistry
- Ceramics and Composite
- Metallkomplexe
- Optical and Magnetic Materials
- Catalysis
language:
- iso: eng
page: 6640-6643
publication: Chemical Communications
publication_identifier:
issn:
- 1359-7345
- 1364-548X
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes
type: journal_article
user_id: '48467'
volume: 57
year: '2021'
...
---
_id: '41015'
author:
- first_name: Mathis
full_name: Benedikter, Mathis
last_name: Benedikter
- first_name: Janis
full_name: Musso, Janis
last_name: Musso
- first_name: Manoj K.
full_name: Kesharwani, Manoj K.
last_name: Kesharwani
- first_name: K. Leonard
full_name: Sterz, K. Leonard
last_name: Sterz
- first_name: Iris
full_name: Elser, Iris
last_name: Elser
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Felix
full_name: Fischer, Felix
last_name: Fischer
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Mario
full_name: Winkler, Mario
last_name: Winkler
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis.
2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978'
apa: 'Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler,
F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren,
J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution
in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes:
A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis,
10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978'
bibtex: '@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et
al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach},
volume={10}, DOI={10.1021/acscatal.0c03978},
number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz,
K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker,
Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823}
}'
chicago: 'Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz,
Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis
10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.'
ieee: 'M. Benedikter et al., “Charge Distribution in Cationic Molybdenum
Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS,
XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no.
24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.'
mla: 'Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES,
DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24,
American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.'
short: M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler,
F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M.
Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.
date_created: 2023-01-30T17:12:11Z
date_updated: 2024-05-07T11:42:56Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acscatal.0c03978
intvolume: ' 10'
issue: '24'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 14810-14823
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach'
type: journal_article
user_id: '48467'
volume: 10
year: '2020'
...
---
_id: '41020'
author:
- first_name: Bernhard J.
full_name: Gregori, Bernhard J.
last_name: Gregori
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Anke
full_name: Schoch, Anke
id: '27611'
last_name: Schoch
orcid: 0000-0002-9457-400X
- first_name: Simon
full_name: Pöllath, Simon
last_name: Pöllath
- first_name: Josef
full_name: Zweck, Josef
last_name: Zweck
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994
apa: Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer,
M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994
bibtex: '@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020,
title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12},
DOI={10.1002/cctc.202000994},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard
J. and Nowakowski, Michał and Schoch, Anke and Pöllath, Simon and Zweck, Josef
and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363}
}'
chicago: 'Gregori, Bernhard J., Michał Nowakowski, Anke Schoch, Simon Pöllath, Josef
Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63.
https://doi.org/10.1002/cctc.202000994.'
ieee: 'B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.'
mla: Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994.
short: B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A.
Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363.
date_created: 2023-01-30T17:35:14Z
date_updated: 2024-05-07T11:40:10Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/cctc.202000994
intvolume: ' 12'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
page: 5359-5363
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes
type: journal_article
user_id: '48467'
volume: 12
year: '2020'
...
---
_id: '41327'
author:
- first_name: Mathis
full_name: Benedikter, Mathis
last_name: Benedikter
- first_name: Janis
full_name: Musso, Janis
last_name: Musso
- first_name: Manoj K.
full_name: Kesharwani, Manoj K.
last_name: Kesharwani
- first_name: K. Leonard
full_name: Sterz, K. Leonard
last_name: Sterz
- first_name: Iris
full_name: Elser, Iris
last_name: Elser
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Felix
full_name: Fischer, Felix
last_name: Fischer
- first_name: Bernd
full_name: Plietker, Bernd
last_name: Plietker
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Johannes
full_name: Kästner, Johannes
last_name: Kästner
- first_name: Mario
full_name: Winkler, Mario
last_name: Winkler
- first_name: Joris
full_name: van Slageren, Joris
last_name: van Slageren
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Benedikter M, Musso J, Kesharwani MK, et al. Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis.
2020;10(24):14810-14823. doi:10.1021/acscatal.0c03978'
apa: 'Benedikter, M., Musso, J., Kesharwani, M. K., Sterz, K. L., Elser, I., Ziegler,
F., Fischer, F., Plietker, B., Frey, W., Kästner, J., Winkler, M., van Slageren,
J., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2020). Charge Distribution
in Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes:
A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach. ACS Catalysis,
10(24), 14810–14823. https://doi.org/10.1021/acscatal.0c03978'
bibtex: '@article{Benedikter_Musso_Kesharwani_Sterz_Elser_Ziegler_Fischer_Plietker_Frey_Kästner_et
al._2020, title={Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach},
volume={10}, DOI={10.1021/acscatal.0c03978},
number={24}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz,
K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker,
Bernd and Frey, Wolfgang and Kästner, Johannes and et al.}, year={2020}, pages={14810–14823}
}'
chicago: 'Benedikter, Mathis, Janis Musso, Manoj K. Kesharwani, K. Leonard Sterz,
Iris Elser, Felix Ziegler, Felix Fischer, et al. “Charge Distribution in Cationic
Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined
X-Ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis
10, no. 24 (2020): 14810–23. https://doi.org/10.1021/acscatal.0c03978.'
ieee: 'M. Benedikter et al., “Charge Distribution in Cationic Molybdenum
Imido Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-ray, XAS,
XES, DFT, Mössbauer, and Catalysis Approach,” ACS Catalysis, vol. 10, no.
24, pp. 14810–14823, 2020, doi: 10.1021/acscatal.0c03978.'
mla: 'Benedikter, Mathis, et al. “Charge Distribution in Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes: A Combined X-Ray, XAS, XES,
DFT, Mössbauer, and Catalysis Approach.” ACS Catalysis, vol. 10, no. 24,
American Chemical Society (ACS), 2020, pp. 14810–23, doi:10.1021/acscatal.0c03978.'
short: M. Benedikter, J. Musso, M.K. Kesharwani, K.L. Sterz, I. Elser, F. Ziegler,
F. Fischer, B. Plietker, W. Frey, J. Kästner, M. Winkler, J. van Slageren, M.
Nowakowski, M. Bauer, M.R. Buchmeiser, ACS Catalysis 10 (2020) 14810–14823.
date_created: 2023-01-31T22:52:07Z
date_updated: 2023-02-01T08:50:47Z
doi: 10.1021/acscatal.0c03978
intvolume: ' 10'
issue: '24'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 14810-14823
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: 'Charge Distribution in Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach'
type: journal_article
user_id: '78878'
volume: 10
year: '2020'
...
---
_id: '41329'
author:
- first_name: Bernhard J.
full_name: Gregori, Bernhard J.
last_name: Gregori
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Anke
full_name: Schoch, Anke
last_name: Schoch
- first_name: Simon
full_name: Pöllath, Simon
last_name: Pöllath
- first_name: Josef
full_name: Zweck, Josef
last_name: Zweck
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
- first_name: Axel
full_name: Jacobi von Wangelin, Axel
last_name: Jacobi von Wangelin
citation:
ama: Gregori BJ, Nowakowski M, Schoch A, et al. Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes. ChemCatChem. 2020;12(21):5359-5363. doi:10.1002/cctc.202000994
apa: Gregori, B. J., Nowakowski, M., Schoch, A., Pöllath, S., Zweck, J., Bauer,
M., & Jacobi von Wangelin, A. (2020). Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes. ChemCatChem, 12(21), 5359–5363. https://doi.org/10.1002/cctc.202000994
bibtex: '@article{Gregori_Nowakowski_Schoch_Pöllath_Zweck_Bauer_Jacobi von Wangelin_2020,
title={Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}, volume={12},
DOI={10.1002/cctc.202000994},
number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Gregori, Bernhard
J. and Nowakowski, Michal and Schoch, Anke and Pöllath, Simon and Zweck, Josef
and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2020}, pages={5359–5363}
}'
chicago: 'Gregori, Bernhard J., Michal Nowakowski, Anke Schoch, Simon Pöllath, Josef
Zweck, Matthias Bauer, and Axel Jacobi von Wangelin. “Stereoselective Chromium‐Catalyzed
Semi‐Hydrogenation of Alkynes.” ChemCatChem 12, no. 21 (2020): 5359–63.
https://doi.org/10.1002/cctc.202000994.'
ieee: 'B. J. Gregori et al., “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes,” ChemCatChem, vol. 12, no. 21, pp. 5359–5363, 2020, doi: 10.1002/cctc.202000994.'
mla: Gregori, Bernhard J., et al. “Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation
of Alkynes.” ChemCatChem, vol. 12, no. 21, Wiley, 2020, pp. 5359–63, doi:10.1002/cctc.202000994.
short: B.J. Gregori, M. Nowakowski, A. Schoch, S. Pöllath, J. Zweck, M. Bauer, A.
Jacobi von Wangelin, ChemCatChem 12 (2020) 5359–5363.
date_created: 2023-01-31T22:52:39Z
date_updated: 2023-02-01T08:50:41Z
doi: 10.1002/cctc.202000994
intvolume: ' 12'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
page: 5359-5363
publication: ChemCatChem
publication_identifier:
issn:
- 1867-3880
- 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes
type: journal_article
user_id: '78878'
volume: 12
year: '2020'
...
---
_id: '41820'
author:
- first_name: Benjamin
full_name: Hämisch, Benjamin
last_name: Hämisch
- first_name: Roland
full_name: Pollak, Roland
last_name: Pollak
- first_name: Simon
full_name: Ebbinghaus, Simon
last_name: Ebbinghaus
- first_name: Klaus
full_name: Huber, Klaus
id: '237'
last_name: Huber
citation:
ama: Hämisch B, Pollak R, Ebbinghaus S, Huber K. Self‐Assembly of Pseudo‐Isocyanine
Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo. Chemistry
– A European Journal. 2020;26(31):7041-7050. doi:10.1002/chem.202000113
apa: Hämisch, B., Pollak, R., Ebbinghaus, S., & Huber, K. (2020). Self‐Assembly
of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro
and In Vivo. Chemistry – A European Journal, 26(31), 7041–7050.
https://doi.org/10.1002/chem.202000113
bibtex: '@article{Hämisch_Pollak_Ebbinghaus_Huber_2020, title={Self‐Assembly of
Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and
In Vivo}, volume={26}, DOI={10.1002/chem.202000113},
number={31}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Hämisch,
Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}, year={2020},
pages={7041–7050} }'
chicago: 'Hämisch, Benjamin, Roland Pollak, Simon Ebbinghaus, and Klaus Huber. “Self‐Assembly
of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro
and In Vivo.” Chemistry – A European Journal 26, no. 31 (2020): 7041–50.
https://doi.org/10.1002/chem.202000113.'
ieee: 'B. Hämisch, R. Pollak, S. Ebbinghaus, and K. Huber, “Self‐Assembly of Pseudo‐Isocyanine
Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo,” Chemistry
– A European Journal, vol. 26, no. 31, pp. 7041–7050, 2020, doi: 10.1002/chem.202000113.'
mla: Hämisch, Benjamin, et al. “Self‐Assembly of Pseudo‐Isocyanine Chloride as a
Sensor for Macromolecular Crowding In Vitro and In Vivo.” Chemistry – A European
Journal, vol. 26, no. 31, Wiley, 2020, pp. 7041–50, doi:10.1002/chem.202000113.
short: B. Hämisch, R. Pollak, S. Ebbinghaus, K. Huber, Chemistry – A European Journal
26 (2020) 7041–7050.
date_created: 2023-02-06T12:12:40Z
date_updated: 2023-02-06T12:13:25Z
department:
- _id: '314'
doi: 10.1002/chem.202000113
intvolume: ' 26'
issue: '31'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 7041-7050
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular
Crowding In Vitro and In Vivo
type: journal_article
user_id: '237'
volume: 26
year: '2020'
...
---
_id: '41824'
author:
- first_name: Benjamin
full_name: Hämisch, Benjamin
last_name: Hämisch
- first_name: Roland
full_name: Pollak, Roland
last_name: Pollak
- first_name: Simon
full_name: Ebbinghaus, Simon
last_name: Ebbinghaus
- first_name: Klaus
full_name: Huber, Klaus
id: '237'
last_name: Huber
citation:
ama: Hämisch B, Pollak R, Ebbinghaus S, Huber K. Self‐Assembly of Pseudo‐Isocyanine
Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo. Chemistry
– A European Journal. 2020;26(31):7041-7050. doi:10.1002/chem.202000113
apa: Hämisch, B., Pollak, R., Ebbinghaus, S., & Huber, K. (2020). Self‐Assembly
of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro
and In Vivo. Chemistry – A European Journal, 26(31), 7041–7050.
https://doi.org/10.1002/chem.202000113
bibtex: '@article{Hämisch_Pollak_Ebbinghaus_Huber_2020, title={Self‐Assembly of
Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and
In Vivo}, volume={26}, DOI={10.1002/chem.202000113},
number={31}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Hämisch,
Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}, year={2020},
pages={7041–7050} }'
chicago: 'Hämisch, Benjamin, Roland Pollak, Simon Ebbinghaus, and Klaus Huber. “Self‐Assembly
of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro
and In Vivo.” Chemistry – A European Journal 26, no. 31 (2020): 7041–50.
https://doi.org/10.1002/chem.202000113.'
ieee: 'B. Hämisch, R. Pollak, S. Ebbinghaus, and K. Huber, “Self‐Assembly of Pseudo‐Isocyanine
Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo,” Chemistry
– A European Journal, vol. 26, no. 31, pp. 7041–7050, 2020, doi: 10.1002/chem.202000113.'
mla: Hämisch, Benjamin, et al. “Self‐Assembly of Pseudo‐Isocyanine Chloride as a
Sensor for Macromolecular Crowding In Vitro and In Vivo.” Chemistry – A European
Journal, vol. 26, no. 31, Wiley, 2020, pp. 7041–50, doi:10.1002/chem.202000113.
short: B. Hämisch, R. Pollak, S. Ebbinghaus, K. Huber, Chemistry – A European Journal
26 (2020) 7041–7050.
date_created: 2023-02-06T12:18:20Z
date_updated: 2023-02-06T12:26:26Z
department:
- _id: '314'
doi: 10.1002/chem.202000113
intvolume: ' 26'
issue: '31'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 7041-7050
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular
Crowding In Vitro and In Vivo
type: journal_article
user_id: '237'
volume: 26
year: '2020'
...
---
_id: '41025'
abstract:
- lang: eng
text: We investigate the structure-activity correlations of methanation catalysts
obtained by thermal decomposition of a Ni-based metal-organic framework, using
pair distribution function, X-ray absorption spectroscopy and X-ray diffraction.
author:
- first_name: Nils
full_name: Prinz, Nils
last_name: Prinz
- first_name: Leif
full_name: Schwensow, Leif
last_name: Schwensow
- first_name: Sven
full_name: Strübbe, Sven
id: '76968'
last_name: Strübbe
- first_name: Andreas
full_name: Jentys, Andreas
last_name: Jentys
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Wolfgang
full_name: Kleist, Wolfgang
last_name: Kleist
- first_name: Mirijam
full_name: Zobel, Mirijam
last_name: Zobel
citation:
ama: Prinz N, Schwensow L, Strübbe S, et al. Hard X-ray-based techniques for structural
investigations of CO2 methanation catalysts prepared by MOF decomposition. Nanoscale.
2020;12(29):15800-15813. doi:10.1039/d0nr01750g
apa: Prinz, N., Schwensow, L., Strübbe, S., Jentys, A., Bauer, M., Kleist, W., &
Zobel, M. (2020). Hard X-ray-based techniques for structural investigations of
CO2 methanation catalysts prepared by MOF decomposition. Nanoscale, 12(29),
15800–15813. https://doi.org/10.1039/d0nr01750g
bibtex: '@article{Prinz_Schwensow_Strübbe_Jentys_Bauer_Kleist_Zobel_2020, title={Hard
X-ray-based techniques for structural investigations of CO2 methanation catalysts
prepared by MOF decomposition}, volume={12}, DOI={10.1039/d0nr01750g},
number={29}, journal={Nanoscale}, publisher={Royal Society of Chemistry (RSC)},
author={Prinz, Nils and Schwensow, Leif and Strübbe, Sven and Jentys, Andreas
and Bauer, Matthias and Kleist, Wolfgang and Zobel, Mirijam}, year={2020}, pages={15800–15813}
}'
chicago: 'Prinz, Nils, Leif Schwensow, Sven Strübbe, Andreas Jentys, Matthias Bauer,
Wolfgang Kleist, and Mirijam Zobel. “Hard X-Ray-Based Techniques for Structural
Investigations of CO2 Methanation Catalysts Prepared by MOF Decomposition.” Nanoscale
12, no. 29 (2020): 15800–813. https://doi.org/10.1039/d0nr01750g.'
ieee: 'N. Prinz et al., “Hard X-ray-based techniques for structural investigations
of CO2 methanation catalysts prepared by MOF decomposition,” Nanoscale,
vol. 12, no. 29, pp. 15800–15813, 2020, doi: 10.1039/d0nr01750g.'
mla: Prinz, Nils, et al. “Hard X-Ray-Based Techniques for Structural Investigations
of CO2 Methanation Catalysts Prepared by MOF Decomposition.” Nanoscale,
vol. 12, no. 29, Royal Society of Chemistry (RSC), 2020, pp. 15800–13, doi:10.1039/d0nr01750g.
short: N. Prinz, L. Schwensow, S. Strübbe, A. Jentys, M. Bauer, W. Kleist, M. Zobel,
Nanoscale 12 (2020) 15800–15813.
date_created: 2023-01-30T17:47:17Z
date_updated: 2025-08-15T12:43:52Z
department:
- _id: '35'
- _id: '306'
doi: 10.1039/d0nr01750g
intvolume: ' 12'
issue: '29'
keyword:
- Xray
- Catalysis
language:
- iso: eng
page: 15800-15813
publication: Nanoscale
publication_identifier:
issn:
- 2040-3364
- 2040-3372
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Hard X-ray-based techniques for structural investigations of CO2 methanation
catalysts prepared by MOF decomposition
type: journal_article
user_id: '48467'
volume: 12
year: '2020'
...