[{"abstract":[{"text":"Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+ pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with four mesoionic carbenes.","lang":"eng"}],"publication":"Chemical Communications","issue":"54","department":[{"_id":"35"},{"_id":"306"}],"keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composite","Metallkomplexe","Optical and Magnetic Materials","Catalysis"],"type":"journal_article","date_created":"2023-01-30T16:59:55Z","article_type":"original","intvolume":"        57","publication_status":"published","date_updated":"2024-10-11T08:42:44Z","publication_identifier":{"issn":["1359-7345","1364-548X"]},"author":[{"first_name":"Philipp","last_name":"Dierks","full_name":"Dierks, Philipp"},{"full_name":"Kruse, Ayla","last_name":"Kruse","first_name":"Ayla"},{"full_name":"Bokareva, Olga S.","first_name":"Olga S.","last_name":"Bokareva"},{"first_name":"Mohammed J.","last_name":"Al-Marri","full_name":"Al-Marri, Mohammed J."},{"full_name":"Kalmbach, Jens","first_name":"Jens","last_name":"Kalmbach"},{"last_name":"Baltrun","first_name":"Marc","full_name":"Baltrun, Marc"},{"first_name":"Adam","last_name":"Neuba","full_name":"Neuba, Adam"},{"id":"48467","full_name":"Schoch, Roland","last_name":"Schoch","orcid":"0000-0003-2061-7289","first_name":"Roland"},{"first_name":"Stephan","last_name":"Hohloch","full_name":"Hohloch, Stephan"},{"full_name":"Heinze, Katja","last_name":"Heinze","first_name":"Katja"},{"full_name":"Seitz, Michael","last_name":"Seitz","first_name":"Michael"},{"first_name":"Oliver","last_name":"Kühn","full_name":"Kühn, Oliver"},{"full_name":"Lochbrunner, Stefan","last_name":"Lochbrunner","first_name":"Stefan"},{"id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias","orcid":"0000-0002-9294-6076","last_name":"Bauer"}],"year":"2021","title":"Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes","doi":"10.1039/d1cc01716k","language":[{"iso":"eng"}],"citation":{"bibtex":"@article{Dierks_Kruse_Bokareva_Al-Marri_Kalmbach_Baltrun_Neuba_Schoch_Hohloch_Heinze_et al._2021, title={Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes}, volume={57}, DOI={<a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>}, number={54}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri, Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland and Hohloch, Stephan and Heinze, Katja and et al.}, year={2021}, pages={6640–6643} }","ama":"Dierks P, Kruse A, Bokareva OS, et al. Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. <i>Chemical Communications</i>. 2021;57(54):6640-6643. doi:<a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>","mla":"Dierks, Philipp, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” <i>Chemical Communications</i>, vol. 57, no. 54, Royal Society of Chemistry (RSC), 2021, pp. 6640–43, doi:<a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>.","short":"P. Dierks, A. Kruse, O.S. Bokareva, M.J. Al-Marri, J. Kalmbach, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner, M. Bauer, Chemical Communications 57 (2021) 6640–6643.","chicago":"Dierks, Philipp, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens Kalmbach, Marc Baltrun, Adam Neuba, et al. “Distinct Photodynamics of κ-N and κ-C Pseudoisomeric Iron(Ii) Complexes.” <i>Chemical Communications</i> 57, no. 54 (2021): 6640–43. <a href=\"https://doi.org/10.1039/d1cc01716k\">https://doi.org/10.1039/d1cc01716k</a>.","ieee":"P. Dierks <i>et al.</i>, “Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes,” <i>Chemical Communications</i>, vol. 57, no. 54, pp. 6640–6643, 2021, doi: <a href=\"https://doi.org/10.1039/d1cc01716k\">10.1039/d1cc01716k</a>.","apa":"Dierks, P., Kruse, A., Bokareva, O. S., Al-Marri, M. J., Kalmbach, J., Baltrun, M., Neuba, A., Schoch, R., Hohloch, S., Heinze, K., Seitz, M., Kühn, O., Lochbrunner, S., &#38; Bauer, M. (2021). Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes. <i>Chemical Communications</i>, <i>57</i>(54), 6640–6643. <a href=\"https://doi.org/10.1039/d1cc01716k\">https://doi.org/10.1039/d1cc01716k</a>"},"status":"public","volume":57,"user_id":"48467","_id":"41007","publisher":"Royal Society of Chemistry (RSC)","page":"6640-6643"}]