[{"publication_identifier":{"issn":["0926-3373"]},"publication_status":"published","year":"2021","intvolume":" 304","citation":{"bibtex":"@article{da Silva_Silva_Xue_Lo_Tarakina_Nunes_Adler_Sahoo_Bahnemann_López-Salas_et al._2021, title={Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}, volume={304}, DOI={10.1016/j.apcatb.2021.120965}, number={120965}, journal={Applied Catalysis B: Environmental}, publisher={Elsevier BV}, author={da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo, Sudhir K. and Bahnemann, Detlef W. and López-Salas, Nieves and et al.}, year={2021} }","mla":"da Silva, Marcos A. R., et al. “Sustainable Oxidation Catalysis Supported by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.” Applied Catalysis B: Environmental, vol. 304, 120965, Elsevier BV, 2021, doi:10.1016/j.apcatb.2021.120965.","short":"M.A.R. da Silva, I.F. Silva, Q. Xue, B.T.W. Lo, N.V. Tarakina, B.N. Nunes, P. Adler, S.K. Sahoo, D.W. Bahnemann, N. López-Salas, A. Savateev, C. Ribeiro, T. Kühne, M. Antonietti, I.F. Teixeira, Applied Catalysis B: Environmental 304 (2021).","apa":"da Silva, M. A. R., Silva, I. F., Xue, Q., Lo, B. T. W., Tarakina, N. V., Nunes, B. N., Adler, P., Sahoo, S. K., Bahnemann, D. W., López-Salas, N., Savateev, A., Ribeiro, C., Kühne, T., Antonietti, M., & Teixeira, I. F. (2021). Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst. Applied Catalysis B: Environmental, 304, Article 120965. https://doi.org/10.1016/j.apcatb.2021.120965","ieee":"M. A. R. da Silva et al., “Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst,” Applied Catalysis B: Environmental, vol. 304, Art. no. 120965, 2021, doi: 10.1016/j.apcatb.2021.120965.","chicago":"Silva, Marcos A.R. da, Ingrid F. Silva, Qi Xue, Benedict T.W. Lo, Nadezda V. Tarakina, Barbara N. Nunes, Peter Adler, et al. “Sustainable Oxidation Catalysis Supported by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.” Applied Catalysis B: Environmental 304 (2021). https://doi.org/10.1016/j.apcatb.2021.120965.","ama":"da Silva MAR, Silva IF, Xue Q, et al. Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst. Applied Catalysis B: Environmental. 2021;304. doi:10.1016/j.apcatb.2021.120965"},"date_updated":"2022-10-11T08:14:47Z","publisher":"Elsevier BV","volume":304,"date_created":"2022-10-11T08:14:22Z","author":[{"last_name":"da Silva","full_name":"da Silva, Marcos A.R.","first_name":"Marcos A.R."},{"first_name":"Ingrid F.","last_name":"Silva","full_name":"Silva, Ingrid F."},{"full_name":"Xue, Qi","last_name":"Xue","first_name":"Qi"},{"last_name":"Lo","full_name":"Lo, Benedict T.W.","first_name":"Benedict T.W."},{"first_name":"Nadezda V.","last_name":"Tarakina","full_name":"Tarakina, Nadezda V."},{"full_name":"Nunes, Barbara N.","last_name":"Nunes","first_name":"Barbara N."},{"full_name":"Adler, Peter","last_name":"Adler","first_name":"Peter"},{"first_name":"Sudhir K.","last_name":"Sahoo","full_name":"Sahoo, Sudhir K."},{"full_name":"Bahnemann, Detlef W.","last_name":"Bahnemann","first_name":"Detlef W."},{"full_name":"López-Salas, Nieves","last_name":"López-Salas","first_name":"Nieves"},{"last_name":"Savateev","full_name":"Savateev, Aleksandr","first_name":"Aleksandr"},{"full_name":"Ribeiro, Caue","last_name":"Ribeiro","first_name":"Caue"},{"first_name":"Thomas","last_name":"Kühne","full_name":"Kühne, Thomas","id":"49079"},{"last_name":"Antonietti","full_name":"Antonietti, Markus","first_name":"Markus"},{"first_name":"Ivo F.","last_name":"Teixeira","full_name":"Teixeira, Ivo F."}],"title":"Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst","doi":"10.1016/j.apcatb.2021.120965","publication":"Applied Catalysis B: Environmental","type":"journal_article","status":"public","_id":"33681","department":[{"_id":"613"}],"user_id":"71051","keyword":["Process Chemistry and Technology","General Environmental Science","Catalysis"],"article_number":"120965","language":[{"iso":"eng"}]},{"author":[{"first_name":"Lukas","last_name":"Mai","full_name":"Mai, Lukas"},{"last_name":"Maniar","full_name":"Maniar, Dina","first_name":"Dina"},{"first_name":"Frederik","full_name":"Zysk, Frederik","id":"14757","last_name":"Zysk"},{"first_name":"Judith","full_name":"Schöbel, Judith","last_name":"Schöbel"},{"id":"49079","full_name":"Kühne, Thomas","last_name":"Kühne","first_name":"Thomas"},{"first_name":"Katja","last_name":"Loos","full_name":"Loos, Katja"},{"full_name":"Devi, Anjana","last_name":"Devi","first_name":"Anjana"}],"date_created":"2022-10-11T08:08:11Z","volume":51,"publisher":"Royal Society of Chemistry (RSC)","date_updated":"2022-10-11T08:08:35Z","doi":"10.1039/d1dt03753f","title":"Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum","issue":"4","publication_status":"published","publication_identifier":{"issn":["1477-9226","1477-9234"]},"citation":{"ama":"Mai L, Maniar D, Zysk F, et al. Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum. Dalton Transactions. 2021;51(4):1384-1394. doi:10.1039/d1dt03753f","ieee":"L. Mai et al., “Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum,” Dalton Transactions, vol. 51, no. 4, pp. 1384–1394, 2021, doi: 10.1039/d1dt03753f.","chicago":"Mai, Lukas, Dina Maniar, Frederik Zysk, Judith Schöbel, Thomas Kühne, Katja Loos, and Anjana Devi. “Influence of Different Ester Side Groups in Polymers on the Vapor Phase Infiltration with Trimethyl Aluminum.” Dalton Transactions 51, no. 4 (2021): 1384–94. https://doi.org/10.1039/d1dt03753f.","short":"L. Mai, D. Maniar, F. Zysk, J. Schöbel, T. Kühne, K. Loos, A. Devi, Dalton Transactions 51 (2021) 1384–1394.","bibtex":"@article{Mai_Maniar_Zysk_Schöbel_Kühne_Loos_Devi_2021, title={Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum}, volume={51}, DOI={10.1039/d1dt03753f}, number={4}, journal={Dalton Transactions}, publisher={Royal Society of Chemistry (RSC)}, author={Mai, Lukas and Maniar, Dina and Zysk, Frederik and Schöbel, Judith and Kühne, Thomas and Loos, Katja and Devi, Anjana}, year={2021}, pages={1384–1394} }","mla":"Mai, Lukas, et al. “Influence of Different Ester Side Groups in Polymers on the Vapor Phase Infiltration with Trimethyl Aluminum.” Dalton Transactions, vol. 51, no. 4, Royal Society of Chemistry (RSC), 2021, pp. 1384–94, doi:10.1039/d1dt03753f.","apa":"Mai, L., Maniar, D., Zysk, F., Schöbel, J., Kühne, T., Loos, K., & Devi, A. (2021). Influence of different ester side groups in polymers on the vapor phase infiltration with trimethyl aluminum. Dalton Transactions, 51(4), 1384–1394. https://doi.org/10.1039/d1dt03753f"},"intvolume":" 51","page":"1384-1394","year":"2021","user_id":"71051","department":[{"_id":"613"}],"_id":"33675","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry"],"type":"journal_article","publication":"Dalton Transactions","status":"public","abstract":[{"text":"The influence of different polymer side chains on the vapor phase infiltration with TMA is investigated and supported by DFT-calculations.","lang":"eng"}]},{"title":"“Seeing Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films","date_created":"2023-10-11T08:19:51Z","publisher":"MDPI AG","year":"2021","issue":"3","quality_controlled":"1","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Condensed Matter Physics","General Materials Science","General Chemical Engineering"],"abstract":[{"lang":"eng","text":"Nonlinear and quantum optical devices based on periodically-poled thin film lithium niobate (PP-TFLN) have gained considerable interest lately, due to their significantly improved performance as compared to their bulk counterparts. Nevertheless, performance parameters such as conversion efficiency, minimum pump power, and spectral bandwidth strongly depend on the quality of the domain structure in these PP-TFLN samples, e.g., their homogeneity and duty cycle, as well as on the overlap and penetration depth of domains with the waveguide mode. Hence, in order to propose improved fabrication protocols, a profound quality control of domain structures is needed that allows quantifying and thoroughly analyzing these parameters. In this paper, we propose to combine a set of nanometer-to-micrometer-scale imaging techniques, i.e., piezoresponse force microscopy (PFM), second-harmonic generation (SHG), and Raman spectroscopy (RS), to access the relevant and crucial sample properties through cross-correlating these methods. Based on our findings, we designate SHG to be the best-suited standard imaging technique for this purpose, in particular when investigating the domain poling process in x-cut TFLNs. While PFM is excellently recommended for near-surface high-resolution imaging, RS provides thorough insights into stress and/or defect distributions, as associated with these domain structures. In this context, our work here indicates unexpectedly large signs for internal fields occurring in x-cut PP-TFLNs that are substantially larger as compared to previous observations in bulk LN."}],"publication":"Crystals","doi":"10.3390/cryst11030288","volume":11,"author":[{"first_name":"Sven","full_name":"Reitzig, Sven","last_name":"Reitzig"},{"id":"22501","full_name":"Rüsing, Michael","orcid":"0000-0003-4682-4577","last_name":"Rüsing","first_name":"Michael"},{"last_name":"Zhao","full_name":"Zhao, Jie","first_name":"Jie"},{"full_name":"Kirbus, Benjamin","last_name":"Kirbus","first_name":"Benjamin"},{"first_name":"Shayan","last_name":"Mookherjea","full_name":"Mookherjea, Shayan"},{"first_name":"Lukas M.","full_name":"Eng, Lukas M.","last_name":"Eng"}],"date_updated":"2023-10-11T08:20:25Z","intvolume":" 11","citation":{"ama":"Reitzig S, Rüsing M, Zhao J, Kirbus B, Mookherjea S, Eng LM. “Seeing Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films. Crystals. 2021;11(3). doi:10.3390/cryst11030288","chicago":"Reitzig, Sven, Michael Rüsing, Jie Zhao, Benjamin Kirbus, Shayan Mookherjea, and Lukas M. Eng. “‘Seeing Is Believing’—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films.” Crystals 11, no. 3 (2021). https://doi.org/10.3390/cryst11030288.","ieee":"S. Reitzig, M. Rüsing, J. Zhao, B. Kirbus, S. Mookherjea, and L. M. Eng, “‘Seeing Is Believing’—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films,” Crystals, vol. 11, no. 3, Art. no. 288, 2021, doi: 10.3390/cryst11030288.","bibtex":"@article{Reitzig_Rüsing_Zhao_Kirbus_Mookherjea_Eng_2021, title={“Seeing Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films}, volume={11}, DOI={10.3390/cryst11030288}, number={3288}, journal={Crystals}, publisher={MDPI AG}, author={Reitzig, Sven and Rüsing, Michael and Zhao, Jie and Kirbus, Benjamin and Mookherjea, Shayan and Eng, Lukas M.}, year={2021} }","mla":"Reitzig, Sven, et al. “‘Seeing Is Believing’—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films.” Crystals, vol. 11, no. 3, 288, MDPI AG, 2021, doi:10.3390/cryst11030288.","short":"S. Reitzig, M. Rüsing, J. Zhao, B. Kirbus, S. Mookherjea, L.M. Eng, Crystals 11 (2021).","apa":"Reitzig, S., Rüsing, M., Zhao, J., Kirbus, B., Mookherjea, S., & Eng, L. M. (2021). “Seeing Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films. Crystals, 11(3), Article 288. https://doi.org/10.3390/cryst11030288"},"publication_identifier":{"issn":["2073-4352"]},"publication_status":"published","extern":"1","article_type":"original","article_number":"288","user_id":"22501","_id":"47963","status":"public","type":"journal_article"},{"title":"Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals","date_created":"2023-10-11T08:20:40Z","publisher":"MDPI AG","year":"2021","issue":"7","quality_controlled":"1","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Condensed Matter Physics","General Materials Science","General Chemical Engineering"],"abstract":[{"lang":"eng","text":"In the last two decades, variably doped strontium barium niobate (SBN) has attracted a lot of scientific interest mainly due to its specific non-linear optical response. Comparably, the parental compound, i.e., undoped SBN, appears to be less studied so far. Here, two different cuts of single-crystalline nominally pure strontium barium niobate in the composition Sr0.61Ba0.39Nb2O6 (SBN61) are comprehensively studied and analyzed with regard to their photoconductive responses. We present conductance measurements under systematically varied illumination conditions along either the polar z-axis or perpendicular to it (x-cut). Apart from a pronounced photoconductance (PC) already under daylight and a large effect upon super-bandgap illumination in general, we observe (i) distinct spectral features when sweeping the excitation wavelength over the sub-bandgap region as then discussed in the context of deep and shallow trap states, (ii) extremely slow long-term relaxation for both light-on and light-off transients in the range of hours and days, (iii) a critical dependence of the photoresponse on the pre-illumination history of the sample, and (iv) a current–voltage hysteresis depending on both the illumination and the electrical-measurement conditions in a complex manner."}],"publication":"Crystals","main_file_link":[{"open_access":"1","url":"https://doi.org/10.3390/cryst11070780"}],"doi":"10.3390/cryst11070780","author":[{"full_name":"Beyreuther, Elke","last_name":"Beyreuther","first_name":"Elke"},{"full_name":"Ratzenberger, Julius","last_name":"Ratzenberger","first_name":"Julius"},{"last_name":"Roeper","full_name":"Roeper, Matthias","first_name":"Matthias"},{"last_name":"Kirbus","full_name":"Kirbus, Benjamin","first_name":"Benjamin"},{"first_name":"Michael","full_name":"Rüsing, Michael","id":"22501","last_name":"Rüsing","orcid":"0000-0003-4682-4577"},{"first_name":"Liudmila I.","full_name":"Ivleva, Liudmila I.","last_name":"Ivleva"},{"last_name":"Eng","full_name":"Eng, Lukas M.","first_name":"Lukas M."}],"volume":11,"oa":"1","date_updated":"2023-10-11T08:21:17Z","citation":{"mla":"Beyreuther, Elke, et al. “Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals.” Crystals, vol. 11, no. 7, 780, MDPI AG, 2021, doi:10.3390/cryst11070780.","short":"E. Beyreuther, J. Ratzenberger, M. Roeper, B. Kirbus, M. Rüsing, L.I. Ivleva, L.M. Eng, Crystals 11 (2021).","bibtex":"@article{Beyreuther_Ratzenberger_Roeper_Kirbus_Rüsing_Ivleva_Eng_2021, title={Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals}, volume={11}, DOI={10.3390/cryst11070780}, number={7780}, journal={Crystals}, publisher={MDPI AG}, author={Beyreuther, Elke and Ratzenberger, Julius and Roeper, Matthias and Kirbus, Benjamin and Rüsing, Michael and Ivleva, Liudmila I. and Eng, Lukas M.}, year={2021} }","apa":"Beyreuther, E., Ratzenberger, J., Roeper, M., Kirbus, B., Rüsing, M., Ivleva, L. I., & Eng, L. M. (2021). Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals. Crystals, 11(7), Article 780. https://doi.org/10.3390/cryst11070780","chicago":"Beyreuther, Elke, Julius Ratzenberger, Matthias Roeper, Benjamin Kirbus, Michael Rüsing, Liudmila I. Ivleva, and Lukas M. Eng. “Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals.” Crystals 11, no. 7 (2021). https://doi.org/10.3390/cryst11070780.","ieee":"E. Beyreuther et al., “Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals,” Crystals, vol. 11, no. 7, Art. no. 780, 2021, doi: 10.3390/cryst11070780.","ama":"Beyreuther E, Ratzenberger J, Roeper M, et al. Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals. Crystals. 2021;11(7). doi:10.3390/cryst11070780"},"intvolume":" 11","publication_status":"published","publication_identifier":{"issn":["2073-4352"]},"extern":"1","funded_apc":"1","article_type":"original","article_number":"780","user_id":"22501","_id":"47964","status":"public","type":"journal_article"},{"year":"2021","issue":"29","quality_controlled":"1","title":"Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands","date_created":"2023-10-11T08:21:55Z","publisher":"Wiley","abstract":[{"lang":"eng","text":"Exceptionally electron-rich, nearly trigonal-planar tricyanidometalate anions [Fe(CN)3]7− and [Ru(CN)3]7− were stabilized in LiSr3[Fe(CN)3] and AE3.5[M(CN)3] (AE=Sr, Ba; M=Fe, Ru). They are the first examples of group 8 elements with the oxidation state of −IV. Microcrystalline powders were obtained by a solid-state route, single crystals from alkali metal flux. While LiSr3[Fe(CN)3] crystallizes in P63/m, the polar space group P63 with three-fold cell volume for AE3.5[M(CN)3] is confirmed by second harmonic generation. X-ray diffraction, IR and Raman spectroscopy reveal longer C−N distances (124–128 pm) and much lower stretching frequencies (1484–1634 cm−1) than in classical cyanidometalates. Weak C−N bonds in combination with strong M−C π-bonding is a scheme also known for carbonylmetalates. Instead of the formal notation [Fe−IV(CN−)3]7−, quantum chemical calculations reveal non-innocent intermediate-valent CN1.67− ligands and a closed-shell d10 configuration for Fe, that is, Fe2−."}],"publication":"Angewandte Chemie International Edition","language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis"],"citation":{"ieee":"F. Jach et al., “Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands,” Angewandte Chemie International Edition, vol. 60, no. 29, pp. 15879–15885, 2021, doi: 10.1002/anie.202103268.","chicago":"Jach, Franziska, Frank R. Wagner, Zeeshan H. Amber, Michael Rüsing, Jens Hunger, Yurii Prots, Martin Kaiser, et al. “Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands.” Angewandte Chemie International Edition 60, no. 29 (2021): 15879–85. https://doi.org/10.1002/anie.202103268.","ama":"Jach F, Wagner FR, Amber ZH, et al. Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands. Angewandte Chemie International Edition. 2021;60(29):15879-15885. doi:10.1002/anie.202103268","mla":"Jach, Franziska, et al. “Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands.” Angewandte Chemie International Edition, vol. 60, no. 29, Wiley, 2021, pp. 15879–85, doi:10.1002/anie.202103268.","short":"F. Jach, F.R. Wagner, Z.H. Amber, M. Rüsing, J. Hunger, Y. Prots, M. Kaiser, M. Bobnar, A. Jesche, L.M. Eng, M. Ruck, P. Höhn, Angewandte Chemie International Edition 60 (2021) 15879–15885.","bibtex":"@article{Jach_Wagner_Amber_Rüsing_Hunger_Prots_Kaiser_Bobnar_Jesche_Eng_et al._2021, title={Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands}, volume={60}, DOI={10.1002/anie.202103268}, number={29}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Jach, Franziska and Wagner, Frank R. and Amber, Zeeshan H. and Rüsing, Michael and Hunger, Jens and Prots, Yurii and Kaiser, Martin and Bobnar, Matej and Jesche, Anton and Eng, Lukas M. and et al.}, year={2021}, pages={15879–15885} }","apa":"Jach, F., Wagner, F. R., Amber, Z. H., Rüsing, M., Hunger, J., Prots, Y., Kaiser, M., Bobnar, M., Jesche, A., Eng, L. M., Ruck, M., & Höhn, P. (2021). Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands. Angewandte Chemie International Edition, 60(29), 15879–15885. https://doi.org/10.1002/anie.202103268"},"intvolume":" 60","page":"15879-15885","publication_status":"published","publication_identifier":{"issn":["1433-7851","1521-3773"]},"doi":"10.1002/anie.202103268","author":[{"first_name":"Franziska","full_name":"Jach, Franziska","last_name":"Jach"},{"full_name":"Wagner, Frank R.","last_name":"Wagner","first_name":"Frank R."},{"first_name":"Zeeshan H.","full_name":"Amber, Zeeshan H.","last_name":"Amber"},{"orcid":"0000-0003-4682-4577","last_name":"Rüsing","full_name":"Rüsing, Michael","id":"22501","first_name":"Michael"},{"first_name":"Jens","full_name":"Hunger, Jens","last_name":"Hunger"},{"first_name":"Yurii","last_name":"Prots","full_name":"Prots, Yurii"},{"last_name":"Kaiser","full_name":"Kaiser, Martin","first_name":"Martin"},{"last_name":"Bobnar","full_name":"Bobnar, Matej","first_name":"Matej"},{"first_name":"Anton","last_name":"Jesche","full_name":"Jesche, Anton"},{"first_name":"Lukas M.","full_name":"Eng, Lukas M.","last_name":"Eng"},{"last_name":"Ruck","full_name":"Ruck, Michael","first_name":"Michael"},{"first_name":"Peter","last_name":"Höhn","full_name":"Höhn, Peter"}],"volume":60,"date_updated":"2023-10-11T08:24:32Z","status":"public","type":"journal_article","extern":"1","article_type":"original","user_id":"22501","_id":"47965"},{"language":[{"iso":"eng"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication":"Chemistry – A European Journal","abstract":[{"lang":"eng","text":"Orange-colored crystals of the oxoferrate tellurate K12+6xFe6Te4−xO27 [x=0.222(4)] were synthesized in a potassium hydroxide hydroflux with a molar water–base ratio n(H2O)/n(KOH) of 1.5 starting from Fe(NO3)3 ⋅ 9H2O, TeO2 and H2O2 at about 200 °C. By using (NH4)2TeO4 instead of TeO2, a fine powder consisting of microcrystalline spheres of K12+6xFe6Te4−xO27 was obtained. K12+6xFe6Te4−xO27 crystallizes in the acentric cubic space group Iurn:x-wiley:09476539:media:chem202102464:chem202102464-math-0001 3d. [FeIIIO5] pyramids share their apical atoms in [Fe2O9] groups and two of their edges with [TeVIO6] octahedra to form an open framework that consists of two loosely connected, but not interpenetrating, chiral networks. The flexibility of the hinged oxometalate network manifests in a piezoelectric response similar to that of LiNbO3.The potassium cations are mobile in channels that run along the <111> directions and cross in cavities acting as nodes. The ion conductivity of cold-pressed pellets of ball-milled K12+6xFe6Te4−xO27 is 2.3×10^(−4) S ⋅ cm^(−1) at room temperature. Magnetization measurements and neutron diffraction indicate antiferromagnetic coupling in the [Fe2O9] groups."}],"date_created":"2023-10-11T08:39:51Z","publisher":"Wiley","title":"Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI)","issue":"57","quality_controlled":"1","year":"2021","user_id":"22501","_id":"47977","extern":"1","type":"journal_article","status":"public","author":[{"first_name":"Ralf","last_name":"Albrecht","full_name":"Albrecht, Ralf"},{"full_name":"Hoelzel, Markus","last_name":"Hoelzel","first_name":"Markus"},{"full_name":"Beccard, Henrik","last_name":"Beccard","first_name":"Henrik"},{"first_name":"Michael","full_name":"Rüsing, Michael","id":"22501","last_name":"Rüsing","orcid":"0000-0003-4682-4577"},{"first_name":"Lukas","last_name":"Eng","full_name":"Eng, Lukas"},{"last_name":"Doert","full_name":"Doert, Thomas","first_name":"Thomas"},{"full_name":"Ruck, Michael","last_name":"Ruck","first_name":"Michael"}],"volume":27,"date_updated":"2023-10-11T08:41:35Z","doi":"10.1002/chem.202102464","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"citation":{"chicago":"Albrecht, Ralf, Markus Hoelzel, Henrik Beccard, Michael Rüsing, Lukas Eng, Thomas Doert, and Michael Ruck. “Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).” Chemistry – A European Journal 27, no. 57 (2021): 14299–306. https://doi.org/10.1002/chem.202102464.","ieee":"R. Albrecht et al., “Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI),” Chemistry – A European Journal, vol. 27, no. 57, pp. 14299–14306, 2021, doi: 10.1002/chem.202102464.","apa":"Albrecht, R., Hoelzel, M., Beccard, H., Rüsing, M., Eng, L., Doert, T., & Ruck, M. (2021). Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI). Chemistry – A European Journal, 27(57), 14299–14306. https://doi.org/10.1002/chem.202102464","ama":"Albrecht R, Hoelzel M, Beccard H, et al. Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI). Chemistry – A European Journal. 2021;27(57):14299-14306. doi:10.1002/chem.202102464","mla":"Albrecht, Ralf, et al. “Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).” Chemistry – A European Journal, vol. 27, no. 57, Wiley, 2021, pp. 14299–306, doi:10.1002/chem.202102464.","short":"R. Albrecht, M. Hoelzel, H. Beccard, M. Rüsing, L. Eng, T. Doert, M. Ruck, Chemistry – A European Journal 27 (2021) 14299–14306.","bibtex":"@article{Albrecht_Hoelzel_Beccard_Rüsing_Eng_Doert_Ruck_2021, title={Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI)}, volume={27}, DOI={10.1002/chem.202102464}, number={57}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Albrecht, Ralf and Hoelzel, Markus and Beccard, Henrik and Rüsing, Michael and Eng, Lukas and Doert, Thomas and Ruck, Michael}, year={2021}, pages={14299–14306} }"},"intvolume":" 27","page":"14299-14306"},{"keyword":["Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"language":[{"iso":"eng"}],"extern":"1","_id":"47569","user_id":"101499","abstract":[{"text":"AbstractThe trend of increasing product diversity and decreasing production amounts led to the requirement of higher flexibility of production processes of specialty chemicals. Conventional distillation columns, mostly equipped with structured packings, lack the flexibility to handle product changeovers and throughput. Thus, a newly designed distillation column for specialty chemicals is presented. A numerical model was implemented to analyze the potential of the wetted‐wall column. The simulation of the distillation of a binary methanol/water mixture demonstrated that the wetted‐wall column can generate the desired concentration and temperature profiles. Furthermore, analyses of the pressure drop and separation efficiency with the test system chlorobenzene/ethylbenzene were conducted.","lang":"eng"}],"status":"public","type":"journal_article","publication":"Chemical Engineering & Technology","title":"Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals","doi":"10.1002/ceat.202000468","date_updated":"2024-03-08T11:37:39Z","publisher":"Wiley","date_created":"2023-10-04T14:17:00Z","author":[{"first_name":"Arnulf","last_name":"Reitze","full_name":"Reitze, Arnulf"},{"first_name":"Marcus","full_name":"Grünewald, Marcus","last_name":"Grünewald"},{"first_name":"Julia","orcid":"0000-0002-3053-0534","last_name":"Riese","full_name":"Riese, Julia","id":"101499"}],"volume":44,"year":"2021","citation":{"chicago":"Reitze, Arnulf, Marcus Grünewald, and Julia Riese. “Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals.” Chemical Engineering &amp; Technology 44, no. 7 (2021): 1327–35. https://doi.org/10.1002/ceat.202000468.","ieee":"A. Reitze, M. Grünewald, and J. Riese, “Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals,” Chemical Engineering &amp; Technology, vol. 44, no. 7, pp. 1327–1335, 2021, doi: 10.1002/ceat.202000468.","ama":"Reitze A, Grünewald M, Riese J. Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals. Chemical Engineering &amp; Technology. 2021;44(7):1327-1335. doi:10.1002/ceat.202000468","short":"A. Reitze, M. Grünewald, J. Riese, Chemical Engineering &amp; Technology 44 (2021) 1327–1335.","bibtex":"@article{Reitze_Grünewald_Riese_2021, title={Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals}, volume={44}, DOI={10.1002/ceat.202000468}, number={7}, journal={Chemical Engineering &amp; Technology}, publisher={Wiley}, author={Reitze, Arnulf and Grünewald, Marcus and Riese, Julia}, year={2021}, pages={1327–1335} }","mla":"Reitze, Arnulf, et al. “Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals.” Chemical Engineering &amp; Technology, vol. 44, no. 7, Wiley, 2021, pp. 1327–35, doi:10.1002/ceat.202000468.","apa":"Reitze, A., Grünewald, M., & Riese, J. (2021). Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty Chemicals. Chemical Engineering &amp; Technology, 44(7), 1327–1335. https://doi.org/10.1002/ceat.202000468"},"intvolume":" 44","page":"1327-1335","publication_status":"published","quality_controlled":"1","publication_identifier":{"issn":["0930-7516","1521-4125"]},"issue":"7"},{"language":[{"iso":"eng"}],"keyword":["Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"publication":"Industrial & Engineering Chemistry Research","date_created":"2023-10-04T14:16:01Z","publisher":"American Chemical Society (ACS)","title":"Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall","issue":"1","quality_controlled":"1","year":"2021","user_id":"101499","_id":"47564","extern":"1","type":"journal_article","status":"public","volume":61,"author":[{"first_name":"Arnulf","last_name":"Reitze","full_name":"Reitze, Arnulf"},{"last_name":"Grünewald","full_name":"Grünewald, Marcus","first_name":"Marcus"},{"first_name":"Julia","orcid":"0000-0002-3053-0534","last_name":"Riese","id":"101499","full_name":"Riese, Julia"}],"date_updated":"2024-03-08T11:38:39Z","doi":"10.1021/acs.iecr.1c03931","publication_identifier":{"issn":["0888-5885","1520-5045"]},"publication_status":"published","intvolume":" 61","page":"740-746","citation":{"ieee":"A. Reitze, M. Grünewald, and J. Riese, “Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall,” Industrial &amp; Engineering Chemistry Research, vol. 61, no. 1, pp. 740–746, 2021, doi: 10.1021/acs.iecr.1c03931.","chicago":"Reitze, Arnulf, Marcus Grünewald, and Julia Riese. “Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall.” Industrial &amp; Engineering Chemistry Research 61, no. 1 (2021): 740–46. https://doi.org/10.1021/acs.iecr.1c03931.","ama":"Reitze A, Grünewald M, Riese J. Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall. Industrial &amp; Engineering Chemistry Research. 2021;61(1):740-746. doi:10.1021/acs.iecr.1c03931","short":"A. Reitze, M. Grünewald, J. Riese, Industrial &amp; Engineering Chemistry Research 61 (2021) 740–746.","bibtex":"@article{Reitze_Grünewald_Riese_2021, title={Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall}, volume={61}, DOI={10.1021/acs.iecr.1c03931}, number={1}, journal={Industrial &amp; Engineering Chemistry Research}, publisher={American Chemical Society (ACS)}, author={Reitze, Arnulf and Grünewald, Marcus and Riese, Julia}, year={2021}, pages={740–746} }","mla":"Reitze, Arnulf, et al. “Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall.” Industrial &amp; Engineering Chemistry Research, vol. 61, no. 1, American Chemical Society (ACS), 2021, pp. 740–46, doi:10.1021/acs.iecr.1c03931.","apa":"Reitze, A., Grünewald, M., & Riese, J. (2021). Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column Wall. Industrial &amp; Engineering Chemistry Research, 61(1), 740–746. https://doi.org/10.1021/acs.iecr.1c03931"}},{"doi":"10.1016/j.ces.2021.116779","volume":243,"author":[{"first_name":"Bastian","last_name":"Bruns","full_name":"Bruns, Bastian"},{"full_name":"Di Pretoro, Alessandro","last_name":"Di Pretoro","first_name":"Alessandro"},{"last_name":"Grünewald","full_name":"Grünewald, Marcus","first_name":"Marcus"},{"last_name":"Riese","orcid":"0000-0002-3053-0534","full_name":"Riese, Julia","id":"101499","first_name":"Julia"}],"date_updated":"2024-03-08T11:38:05Z","intvolume":" 243","citation":{"ama":"Bruns B, Di Pretoro A, Grünewald M, Riese J. Flexibility analysis for demand-side management in large-scale chemical processes: An ethylene oxide production case study. Chemical Engineering Science. 2021;243. doi:10.1016/j.ces.2021.116779","ieee":"B. Bruns, A. Di Pretoro, M. Grünewald, and J. Riese, “Flexibility analysis for demand-side management in large-scale chemical processes: An ethylene oxide production case study,” Chemical Engineering Science, vol. 243, Art. no. 116779, 2021, doi: 10.1016/j.ces.2021.116779.","chicago":"Bruns, Bastian, Alessandro Di Pretoro, Marcus Grünewald, and Julia Riese. “Flexibility Analysis for Demand-Side Management in Large-Scale Chemical Processes: An Ethylene Oxide Production Case Study.” Chemical Engineering Science 243 (2021). https://doi.org/10.1016/j.ces.2021.116779.","apa":"Bruns, B., Di Pretoro, A., Grünewald, M., & Riese, J. (2021). Flexibility analysis for demand-side management in large-scale chemical processes: An ethylene oxide production case study. Chemical Engineering Science, 243, Article 116779. https://doi.org/10.1016/j.ces.2021.116779","mla":"Bruns, Bastian, et al. “Flexibility Analysis for Demand-Side Management in Large-Scale Chemical Processes: An Ethylene Oxide Production Case Study.” Chemical Engineering Science, vol. 243, 116779, Elsevier BV, 2021, doi:10.1016/j.ces.2021.116779.","short":"B. Bruns, A. Di Pretoro, M. Grünewald, J. Riese, Chemical Engineering Science 243 (2021).","bibtex":"@article{Bruns_Di Pretoro_Grünewald_Riese_2021, title={Flexibility analysis for demand-side management in large-scale chemical processes: An ethylene oxide production case study}, volume={243}, DOI={10.1016/j.ces.2021.116779}, number={116779}, journal={Chemical Engineering Science}, publisher={Elsevier BV}, author={Bruns, Bastian and Di Pretoro, Alessandro and Grünewald, Marcus and Riese, Julia}, year={2021} }"},"publication_identifier":{"issn":["0009-2509"]},"publication_status":"published","extern":"1","article_number":"116779","user_id":"101499","_id":"47567","status":"public","type":"journal_article","title":"Flexibility analysis for demand-side management in large-scale chemical processes: An ethylene oxide production case study","date_created":"2023-10-04T14:16:25Z","publisher":"Elsevier BV","year":"2021","quality_controlled":"1","language":[{"iso":"eng"}],"keyword":["Applied Mathematics","Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"publication":"Chemical Engineering Science"},{"keyword":["Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"language":[{"iso":"eng"}],"publication":"Industrial & Engineering Chemistry Research","publisher":"American Chemical Society (ACS)","date_created":"2023-10-04T14:16:10Z","title":"Indirect Demand Response Potential of Large-Scale Chemical Processes","quality_controlled":"1","issue":"1","year":"2021","_id":"47565","user_id":"101499","extern":"1","type":"journal_article","status":"public","date_updated":"2024-03-08T11:38:28Z","volume":61,"author":[{"full_name":"Bruns, Bastian","last_name":"Bruns","first_name":"Bastian"},{"first_name":"Alessandro","full_name":"Di Pretoro, Alessandro","last_name":"Di Pretoro"},{"full_name":"Grünewald, Marcus","last_name":"Grünewald","first_name":"Marcus"},{"full_name":"Riese, Julia","id":"101499","last_name":"Riese","orcid":"0000-0002-3053-0534","first_name":"Julia"}],"doi":"10.1021/acs.iecr.1c03925","publication_identifier":{"issn":["0888-5885","1520-5045"]},"publication_status":"published","page":"605-620","intvolume":" 61","citation":{"apa":"Bruns, B., Di Pretoro, A., Grünewald, M., & Riese, J. (2021). Indirect Demand Response Potential of Large-Scale Chemical Processes. Industrial &amp; Engineering Chemistry Research, 61(1), 605–620. https://doi.org/10.1021/acs.iecr.1c03925","mla":"Bruns, Bastian, et al. “Indirect Demand Response Potential of Large-Scale Chemical Processes.” Industrial &amp; Engineering Chemistry Research, vol. 61, no. 1, American Chemical Society (ACS), 2021, pp. 605–20, doi:10.1021/acs.iecr.1c03925.","short":"B. Bruns, A. Di Pretoro, M. Grünewald, J. Riese, Industrial &amp; Engineering Chemistry Research 61 (2021) 605–620.","bibtex":"@article{Bruns_Di Pretoro_Grünewald_Riese_2021, title={Indirect Demand Response Potential of Large-Scale Chemical Processes}, volume={61}, DOI={10.1021/acs.iecr.1c03925}, number={1}, journal={Industrial &amp; Engineering Chemistry Research}, publisher={American Chemical Society (ACS)}, author={Bruns, Bastian and Di Pretoro, Alessandro and Grünewald, Marcus and Riese, Julia}, year={2021}, pages={605–620} }","chicago":"Bruns, Bastian, Alessandro Di Pretoro, Marcus Grünewald, and Julia Riese. “Indirect Demand Response Potential of Large-Scale Chemical Processes.” Industrial &amp; Engineering Chemistry Research 61, no. 1 (2021): 605–20. https://doi.org/10.1021/acs.iecr.1c03925.","ieee":"B. Bruns, A. Di Pretoro, M. Grünewald, and J. Riese, “Indirect Demand Response Potential of Large-Scale Chemical Processes,” Industrial &amp; Engineering Chemistry Research, vol. 61, no. 1, pp. 605–620, 2021, doi: 10.1021/acs.iecr.1c03925.","ama":"Bruns B, Di Pretoro A, Grünewald M, Riese J. Indirect Demand Response Potential of Large-Scale Chemical Processes. Industrial &amp; Engineering Chemistry Research. 2021;61(1):605-620. doi:10.1021/acs.iecr.1c03925"}},{"status":"public","type":"journal_article","publication":"Industrial & Engineering Chemistry Research","extern":"1","language":[{"iso":"eng"}],"keyword":["Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"user_id":"101499","_id":"47568","citation":{"mla":"Bruns, Bastian, et al. “Dynamic Design Optimization for Flexible Process Equipment.” Industrial &amp; Engineering Chemistry Research, vol. 60, no. 20, American Chemical Society (ACS), 2021, pp. 7678–88, doi:10.1021/acs.iecr.1c00306.","bibtex":"@article{Bruns_Herrmann_Grünewald_Riese_2021, title={Dynamic Design Optimization for Flexible Process Equipment}, volume={60}, DOI={10.1021/acs.iecr.1c00306}, number={20}, journal={Industrial &amp; Engineering Chemistry Research}, publisher={American Chemical Society (ACS)}, author={Bruns, Bastian and Herrmann, Felix and Grünewald, Marcus and Riese, Julia}, year={2021}, pages={7678–7688} }","short":"B. Bruns, F. Herrmann, M. Grünewald, J. Riese, Industrial &amp; Engineering Chemistry Research 60 (2021) 7678–7688.","apa":"Bruns, B., Herrmann, F., Grünewald, M., & Riese, J. (2021). Dynamic Design Optimization for Flexible Process Equipment. Industrial &amp; Engineering Chemistry Research, 60(20), 7678–7688. https://doi.org/10.1021/acs.iecr.1c00306","ieee":"B. Bruns, F. Herrmann, M. Grünewald, and J. Riese, “Dynamic Design Optimization for Flexible Process Equipment,” Industrial &amp; Engineering Chemistry Research, vol. 60, no. 20, pp. 7678–7688, 2021, doi: 10.1021/acs.iecr.1c00306.","chicago":"Bruns, Bastian, Felix Herrmann, Marcus Grünewald, and Julia Riese. “Dynamic Design Optimization for Flexible Process Equipment.” Industrial &amp; Engineering Chemistry Research 60, no. 20 (2021): 7678–88. https://doi.org/10.1021/acs.iecr.1c00306.","ama":"Bruns B, Herrmann F, Grünewald M, Riese J. Dynamic Design Optimization for Flexible Process Equipment. Industrial &amp; Engineering Chemistry Research. 2021;60(20):7678-7688. doi:10.1021/acs.iecr.1c00306"},"page":"7678-7688","intvolume":" 60","year":"2021","issue":"20","publication_status":"published","publication_identifier":{"issn":["0888-5885","1520-5045"]},"quality_controlled":"1","doi":"10.1021/acs.iecr.1c00306","title":"Dynamic Design Optimization for Flexible Process Equipment","author":[{"first_name":"Bastian","last_name":"Bruns","full_name":"Bruns, Bastian"},{"last_name":"Herrmann","full_name":"Herrmann, Felix","first_name":"Felix"},{"first_name":"Marcus","full_name":"Grünewald, Marcus","last_name":"Grünewald"},{"first_name":"Julia","id":"101499","full_name":"Riese, Julia","orcid":"0000-0002-3053-0534","last_name":"Riese"}],"date_created":"2023-10-04T14:16:46Z","volume":60,"date_updated":"2024-03-08T11:37:55Z","publisher":"American Chemical Society (ACS)"},{"citation":{"ama":"Bruns B, Becker T, Riese J, Lier S, Werners B. Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants. Chemical Engineering &amp; Technology. 2021;44(6):1148-1152. doi:10.1002/ceat.202000591","ieee":"B. Bruns, T. Becker, J. Riese, S. Lier, and B. Werners, “Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants,” Chemical Engineering &amp; Technology, vol. 44, no. 6, pp. 1148–1152, 2021, doi: 10.1002/ceat.202000591.","chicago":"Bruns, Bastian, Tristan Becker, Julia Riese, Stefan Lier, and Brigitte Werners. “Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants.” Chemical Engineering &amp; Technology 44, no. 6 (2021): 1148–52. https://doi.org/10.1002/ceat.202000591.","short":"B. Bruns, T. Becker, J. Riese, S. Lier, B. Werners, Chemical Engineering &amp; Technology 44 (2021) 1148–1152.","mla":"Bruns, Bastian, et al. “Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants.” Chemical Engineering &amp; Technology, vol. 44, no. 6, Wiley, 2021, pp. 1148–52, doi:10.1002/ceat.202000591.","bibtex":"@article{Bruns_Becker_Riese_Lier_Werners_2021, title={Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants}, volume={44}, DOI={10.1002/ceat.202000591}, number={6}, journal={Chemical Engineering &amp; Technology}, publisher={Wiley}, author={Bruns, Bastian and Becker, Tristan and Riese, Julia and Lier, Stefan and Werners, Brigitte}, year={2021}, pages={1148–1152} }","apa":"Bruns, B., Becker, T., Riese, J., Lier, S., & Werners, B. (2021). Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants. Chemical Engineering &amp; Technology, 44(6), 1148–1152. https://doi.org/10.1002/ceat.202000591"},"page":"1148-1152","intvolume":" 44","year":"2021","issue":"6","publication_status":"published","publication_identifier":{"issn":["0930-7516","1521-4125"]},"quality_controlled":"1","doi":"10.1002/ceat.202000591","title":"Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale Plants","author":[{"last_name":"Bruns","full_name":"Bruns, Bastian","first_name":"Bastian"},{"last_name":"Becker","full_name":"Becker, Tristan","first_name":"Tristan"},{"orcid":"0000-0002-3053-0534","last_name":"Riese","id":"101499","full_name":"Riese, Julia","first_name":"Julia"},{"last_name":"Lier","full_name":"Lier, Stefan","first_name":"Stefan"},{"last_name":"Werners","full_name":"Werners, Brigitte","first_name":"Brigitte"}],"date_created":"2023-10-04T14:17:08Z","volume":44,"publisher":"Wiley","date_updated":"2024-03-08T11:37:29Z","status":"public","abstract":[{"lang":"eng","text":"AbstractShortened product life cycles and increased demand for specialized products lead to more challenges in efficiently satisfying customer needs. Customer demands are increasingly uncertain in terms of type, location, and volume. As a result, more flexible chemical production plants are required. Modular small‐scale plants can be installed in transportation containers and, therefore, offer the flexibility of easy relocation, enabling production close to the customer or supplier. In a mathematical optimization model, the economic benefit of small‐scale plants in the specialty chemicals market of polymer production is analyzed. Different scenarios created from the real data of a chemical company show that the use of small‐scale plants may lead to a significant reduction in total costs that is mainly due to the transportation costs of raw materials and products."}],"type":"journal_article","publication":"Chemical Engineering & Technology","extern":"1","language":[{"iso":"eng"}],"keyword":["Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"user_id":"101499","_id":"47570"},{"intvolume":" 93","page":"1100-1106","citation":{"ieee":"H. Fasel, N. Darvishsefat, J. Riese, and M. Grünewald, “Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen,” Chemie Ingenieur Technik, vol. 93, no. 7, pp. 1100–1106, 2021, doi: 10.1002/cite.202000242.","chicago":"Fasel, Henrik, Novin Darvishsefat, Julia Riese, and Marcus Grünewald. “Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen.” Chemie Ingenieur Technik 93, no. 7 (2021): 1100–1106. https://doi.org/10.1002/cite.202000242.","ama":"Fasel H, Darvishsefat N, Riese J, Grünewald M. Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen. Chemie Ingenieur Technik. 2021;93(7):1100-1106. doi:10.1002/cite.202000242","apa":"Fasel, H., Darvishsefat, N., Riese, J., & Grünewald, M. (2021). Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen. Chemie Ingenieur Technik, 93(7), 1100–1106. https://doi.org/10.1002/cite.202000242","mla":"Fasel, Henrik, et al. “Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen.” Chemie Ingenieur Technik, vol. 93, no. 7, Wiley, 2021, pp. 1100–06, doi:10.1002/cite.202000242.","bibtex":"@article{Fasel_Darvishsefat_Riese_Grünewald_2021, title={Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen}, volume={93}, DOI={10.1002/cite.202000242}, number={7}, journal={Chemie Ingenieur Technik}, publisher={Wiley}, author={Fasel, Henrik and Darvishsefat, Novin and Riese, Julia and Grünewald, Marcus}, year={2021}, pages={1100–1106} }","short":"H. Fasel, N. Darvishsefat, J. Riese, M. Grünewald, Chemie Ingenieur Technik 93 (2021) 1100–1106."},"year":"2021","issue":"7","publication_identifier":{"issn":["0009-286X","1522-2640"]},"quality_controlled":"1","publication_status":"published","doi":"10.1002/cite.202000242","title":"Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen","volume":93,"author":[{"first_name":"Henrik","last_name":"Fasel","full_name":"Fasel, Henrik"},{"first_name":"Novin","last_name":"Darvishsefat","full_name":"Darvishsefat, Novin"},{"first_name":"Julia","orcid":"0000-0002-3053-0534","last_name":"Riese","id":"101499","full_name":"Riese, Julia"},{"first_name":"Marcus","last_name":"Grünewald","full_name":"Grünewald, Marcus"}],"date_created":"2023-10-04T14:17:16Z","publisher":"Wiley","date_updated":"2024-03-08T11:37:17Z","status":"public","abstract":[{"text":"AbstractIm Rahmen dieses Beitrags werden experimentelle Untersuchungen zur Tropfenabscheidung im Einleitbereich eines Stoffaustauschapparates für zweiphasige Strömungen vorgestellt. Dafür wurde in einem Versuchsstand im Pilotmaßstab der qualitative Tropfenmitriss für unterschiedliche Tropfenabscheider eines Stoffaustauschapparates vermessen. Die daraus resultierenden Ergebnisse werden in diesem Beitrag hinsichtlich ihrer Aussagekraft zur Vermeidung von Tropfenmitriss diskutiert und bewertet. Darüber hinaus wird ein kurzer Ausblick über simulative Arbeiten zur Bestimmung des Tropfenmitriss gegeben.","lang":"eng"}],"publication":"Chemie Ingenieur Technik","type":"journal_article","extern":"1","language":[{"iso":"ger"}],"keyword":["Industrial and Manufacturing Engineering","General Chemical Engineering","General Chemistry"],"user_id":"101499","_id":"47571"},{"year":"2021","citation":{"mla":"Zhang, Hao, et al. “Dimethyl Ether (DME) and Dimethoxymethane (DMM) as Reaction Enhancers for Methane: Combining Flame Experiments with Model-Assisted Exploration of a Polygeneration Process.” Combustion and Flame, vol. 237, 111863, Elsevier BV, 2021, doi:10.1016/j.combustflame.2021.111863.","short":"H. Zhang, D. Kaczmarek, C. Rudolph, S. Schmitt, N. Gaiser, P. Oßwald, T. Bierkandt, T. Kasper, B. Atakan, K. Kohse-Höinghaus, Combustion and Flame 237 (2021).","bibtex":"@article{Zhang_Kaczmarek_Rudolph_Schmitt_Gaiser_Oßwald_Bierkandt_Kasper_Atakan_Kohse-Höinghaus_2021, title={Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted exploration of a polygeneration process}, volume={237}, DOI={10.1016/j.combustflame.2021.111863}, number={111863}, journal={Combustion and Flame}, publisher={Elsevier BV}, author={Zhang, Hao and Kaczmarek, Dennis and Rudolph, Charlotte and Schmitt, Steffen and Gaiser, Nina and Oßwald, Patrick and Bierkandt, Thomas and Kasper, Tina and Atakan, Burak and Kohse-Höinghaus, Katharina}, year={2021} }","apa":"Zhang, H., Kaczmarek, D., Rudolph, C., Schmitt, S., Gaiser, N., Oßwald, P., Bierkandt, T., Kasper, T., Atakan, B., & Kohse-Höinghaus, K. (2021). Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted exploration of a polygeneration process. Combustion and Flame, 237, Article 111863. https://doi.org/10.1016/j.combustflame.2021.111863","chicago":"Zhang, Hao, Dennis Kaczmarek, Charlotte Rudolph, Steffen Schmitt, Nina Gaiser, Patrick Oßwald, Thomas Bierkandt, Tina Kasper, Burak Atakan, and Katharina Kohse-Höinghaus. “Dimethyl Ether (DME) and Dimethoxymethane (DMM) as Reaction Enhancers for Methane: Combining Flame Experiments with Model-Assisted Exploration of a Polygeneration Process.” Combustion and Flame 237 (2021). https://doi.org/10.1016/j.combustflame.2021.111863.","ieee":"H. Zhang et al., “Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted exploration of a polygeneration process,” Combustion and Flame, vol. 237, Art. no. 111863, 2021, doi: 10.1016/j.combustflame.2021.111863.","ama":"Zhang H, Kaczmarek D, Rudolph C, et al. Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted exploration of a polygeneration process. Combustion and Flame. 2021;237. doi:10.1016/j.combustflame.2021.111863"},"intvolume":" 237","publication_status":"published","publication_identifier":{"issn":["0010-2180"]},"title":"Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted exploration of a polygeneration process","doi":"10.1016/j.combustflame.2021.111863","date_updated":"2024-03-27T17:52:07Z","publisher":"Elsevier BV","author":[{"last_name":"Zhang","full_name":"Zhang, Hao","first_name":"Hao"},{"last_name":"Kaczmarek","full_name":"Kaczmarek, Dennis","first_name":"Dennis"},{"first_name":"Charlotte","last_name":"Rudolph","full_name":"Rudolph, Charlotte"},{"full_name":"Schmitt, Steffen","last_name":"Schmitt","first_name":"Steffen"},{"full_name":"Gaiser, Nina","last_name":"Gaiser","first_name":"Nina"},{"full_name":"Oßwald, Patrick","last_name":"Oßwald","first_name":"Patrick"},{"first_name":"Thomas","last_name":"Bierkandt","full_name":"Bierkandt, Thomas"},{"orcid":"0000-0003-3993-5316 ","last_name":"Kasper","id":"94562","full_name":"Kasper, Tina","first_name":"Tina"},{"first_name":"Burak","full_name":"Atakan, Burak","last_name":"Atakan"},{"first_name":"Katharina","full_name":"Kohse-Höinghaus, Katharina","last_name":"Kohse-Höinghaus"}],"date_created":"2024-03-27T17:51:19Z","volume":237,"status":"public","type":"journal_article","publication":"Combustion and Flame","article_number":"111863","keyword":["General Physics and Astronomy","Energy Engineering and Power Technology","Fuel Technology","General Chemical Engineering","General Chemistry"],"extern":"1","language":[{"iso":"eng"}],"_id":"53086","user_id":"94562","department":[{"_id":"728"}]},{"title":"Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy","date_created":"2024-03-27T17:50:11Z","publisher":"Elsevier BV","year":"2021","language":[{"iso":"eng"}],"keyword":["Organic Chemistry","Energy Engineering and Power Technology","Fuel Technology","General Chemical Engineering"],"publication":"Fuel","doi":"10.1016/j.fuel.2021.122650","author":[{"full_name":"Gaiser, Nina","last_name":"Gaiser","first_name":"Nina"},{"first_name":"Thomas","last_name":"Bierkandt","full_name":"Bierkandt, Thomas"},{"first_name":"Patrick","last_name":"Oßwald","full_name":"Oßwald, Patrick"},{"full_name":"Zinsmeister, Julia","last_name":"Zinsmeister","first_name":"Julia"},{"first_name":"Trupti","full_name":"Kathrotia, Trupti","last_name":"Kathrotia"},{"first_name":"Shkelqim","last_name":"Shaqiri","full_name":"Shaqiri, Shkelqim"},{"first_name":"Patrick","full_name":"Hemberger, Patrick","last_name":"Hemberger"},{"orcid":"0000-0003-3993-5316 ","last_name":"Kasper","full_name":"Kasper, Tina","id":"94562","first_name":"Tina"},{"last_name":"Aigner","full_name":"Aigner, Manfred","first_name":"Manfred"},{"first_name":"Markus","full_name":"Köhler, Markus","last_name":"Köhler"}],"volume":313,"date_updated":"2024-03-27T17:50:47Z","citation":{"ieee":"N. Gaiser et al., “Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy,” Fuel, vol. 313, Art. no. 122650, 2021, doi: 10.1016/j.fuel.2021.122650.","chicago":"Gaiser, Nina, Thomas Bierkandt, Patrick Oßwald, Julia Zinsmeister, Trupti Kathrotia, Shkelqim Shaqiri, Patrick Hemberger, Tina Kasper, Manfred Aigner, and Markus Köhler. “Oxidation of Oxymethylene Ether (OME0−5): An Experimental Systematic Study by Mass Spectrometry and Photoelectron Photoion Coincidence Spectroscopy.” Fuel 313 (2021). https://doi.org/10.1016/j.fuel.2021.122650.","ama":"Gaiser N, Bierkandt T, Oßwald P, et al. Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy. Fuel. 2021;313. doi:10.1016/j.fuel.2021.122650","apa":"Gaiser, N., Bierkandt, T., Oßwald, P., Zinsmeister, J., Kathrotia, T., Shaqiri, S., Hemberger, P., Kasper, T., Aigner, M., & Köhler, M. (2021). Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy. Fuel, 313, Article 122650. https://doi.org/10.1016/j.fuel.2021.122650","bibtex":"@article{Gaiser_Bierkandt_Oßwald_Zinsmeister_Kathrotia_Shaqiri_Hemberger_Kasper_Aigner_Köhler_2021, title={Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy}, volume={313}, DOI={10.1016/j.fuel.2021.122650}, number={122650}, journal={Fuel}, publisher={Elsevier BV}, author={Gaiser, Nina and Bierkandt, Thomas and Oßwald, Patrick and Zinsmeister, Julia and Kathrotia, Trupti and Shaqiri, Shkelqim and Hemberger, Patrick and Kasper, Tina and Aigner, Manfred and Köhler, Markus}, year={2021} }","short":"N. Gaiser, T. Bierkandt, P. Oßwald, J. Zinsmeister, T. Kathrotia, S. Shaqiri, P. Hemberger, T. Kasper, M. Aigner, M. Köhler, Fuel 313 (2021).","mla":"Gaiser, Nina, et al. “Oxidation of Oxymethylene Ether (OME0−5): An Experimental Systematic Study by Mass Spectrometry and Photoelectron Photoion Coincidence Spectroscopy.” Fuel, vol. 313, 122650, Elsevier BV, 2021, doi:10.1016/j.fuel.2021.122650."},"intvolume":" 313","publication_status":"published","publication_identifier":{"issn":["0016-2361"]},"extern":"1","article_number":"122650","user_id":"94562","department":[{"_id":"728"}],"_id":"53085","status":"public","type":"journal_article"},{"type":"journal_article","status":"public","_id":"41001","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"article_type":"original","publication_status":"published","publication_identifier":{"issn":["2155-5435","2155-5435"]},"citation":{"short":"F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski, K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS Catalysis 11 (2021) 11570–11578.","mla":"Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society (ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057.","bibtex":"@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057}, number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren and Bruckner, Johanna R. and Nowakowski, Michał and Weißer, Kilian and Solodenko, Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578} }","apa":"Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski, M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser, M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes. ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057","ama":"Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578. doi:10.1021/acscatal.1c03057","chicago":"Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna R. Bruckner, Michał Nowakowski, Kilian Weißer, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11, no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.","ieee":"F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021, doi: 10.1021/acscatal.1c03057."},"intvolume":" 11","page":"11570-11578","date_updated":"2024-05-07T11:44:19Z","author":[{"full_name":"Ziegler, Felix","last_name":"Ziegler","first_name":"Felix"},{"last_name":"Kraus","full_name":"Kraus, Hamzeh","first_name":"Hamzeh"},{"full_name":"Benedikter, Mathis J.","last_name":"Benedikter","first_name":"Mathis J."},{"first_name":"Dongren","last_name":"Wang","full_name":"Wang, Dongren"},{"first_name":"Johanna R.","full_name":"Bruckner, Johanna R.","last_name":"Bruckner"},{"id":"78878","full_name":"Nowakowski, Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011","first_name":"Michał"},{"first_name":"Kilian","last_name":"Weißer","full_name":"Weißer, Kilian"},{"last_name":"Solodenko","full_name":"Solodenko, Helena","first_name":"Helena"},{"first_name":"Guido","last_name":"Schmitz","full_name":"Schmitz, Guido"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer","orcid":"0000-0002-9294-6076"},{"first_name":"Niels","last_name":"Hansen","full_name":"Hansen, Niels"},{"first_name":"Michael R.","last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R."}],"volume":11,"doi":"10.1021/acscatal.1c03057","publication":"ACS Catalysis","abstract":[{"lang":"eng","text":"For entropic reasons, the synthesis of macrocycles via olefin ring-closing metathesis (RCM) is impeded by competing acyclic diene metathesis (ADMET) oligomerization. With cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes confined in tailored ordered mesoporous silica, RCM can be run with macrocyclization selectivities up to 98% and high substrate concentrations up to 0.1 M. Molecular dynamics simulations show that the high conversions are a direct result of the proximity between the surface-bound catalyst, proven by extended X-ray absorption spectroscopy, and the surface-located substrates. Back-diffusion of the macrocycles decreases with decreasing pore diameter of the silica and is responsible for the high macrocyclization efficiency. Also, Z-selectivity increases with decreasing pore diameter and increasing Tolman electronic parameter of the NHC. Running reactions at different concentrations allows for identifying the optimum substrate concentration for each material and substrate combination."}],"keyword":["Catalysis","General Chemistry"],"language":[{"iso":"eng"}],"issue":"18","year":"2021","publisher":"American Chemical Society (ACS)","date_created":"2023-01-30T16:49:07Z","title":"Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes"},{"citation":{"ama":"Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229. doi:10.1002/chem.202103099","chicago":"Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michał Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.","ieee":"P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol. 27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.","apa":"Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68), 17220–17229. https://doi.org/10.1002/chem.202103099","bibtex":"@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }","short":"P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.","mla":"Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099."},"page":"17220-17229","intvolume":" 27","publication_status":"published","publication_identifier":{"issn":["0947-6539","1521-3765"]},"doi":"10.1002/chem.202103099","date_updated":"2024-05-07T11:43:40Z","author":[{"first_name":"Pradeep K. R.","last_name":"Panyam","full_name":"Panyam, Pradeep K. R."},{"first_name":"Boshra","full_name":"Atwi, Boshra","last_name":"Atwi"},{"last_name":"Ziegler","full_name":"Ziegler, Felix","first_name":"Felix"},{"first_name":"Wolfgang","full_name":"Frey, Wolfgang","last_name":"Frey"},{"first_name":"Michał","last_name":"Nowakowski","orcid":"0000-0002-3734-7011","full_name":"Nowakowski, Michał","id":"78878"},{"full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer","first_name":"Matthias"},{"full_name":"Buchmeiser, Michael R.","last_name":"Buchmeiser","first_name":"Michael R."}],"volume":27,"status":"public","type":"journal_article","article_type":"original","_id":"40999","user_id":"48467","department":[{"_id":"35"},{"_id":"306"}],"year":"2021","issue":"68","title":"Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes","publisher":"Wiley","date_created":"2023-01-30T16:48:41Z","abstract":[{"text":"Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica.","lang":"eng"}],"publication":"Chemistry – A European Journal","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"language":[{"iso":"eng"}]},{"article_type":"original","department":[{"_id":"35"},{"_id":"306"}],"user_id":"48467","_id":"41009","status":"public","type":"journal_article","doi":"10.1021/acs.organomet.1c00216","volume":40,"author":[{"first_name":"Sarah","full_name":"Maier, Sarah","last_name":"Maier"},{"last_name":"Cronin","full_name":"Cronin, Steve P.","first_name":"Steve P."},{"last_name":"Vu Dinh","full_name":"Vu Dinh, Manh-Anh","first_name":"Manh-Anh"},{"first_name":"Zheng","last_name":"Li","full_name":"Li, Zheng"},{"first_name":"Michael","last_name":"Dyballa","full_name":"Dyballa, Michael"},{"orcid":"0000-0002-3734-7011","last_name":"Nowakowski","id":"78878","full_name":"Nowakowski, Michał","first_name":"Michał"},{"id":"47241","full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","first_name":"Matthias"},{"full_name":"Estes, Deven P.","last_name":"Estes","first_name":"Deven P."}],"date_updated":"2024-05-07T11:43:17Z","intvolume":" 40","page":"1751-1757","citation":{"chicago":"Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa, Michał Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics 40, no. 11 (2021): 1751–57. https://doi.org/10.1021/acs.organomet.1c00216.","ieee":"S. Maier et al., “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations,” Organometallics, vol. 40, no. 11, pp. 1751–1757, 2021, doi: 10.1021/acs.organomet.1c00216.","ama":"Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics. 2021;40(11):1751-1757. doi:10.1021/acs.organomet.1c00216","mla":"Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics, vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:10.1021/acs.organomet.1c00216.","short":"S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M. Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.","bibtex":"@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations}, volume={40}, DOI={10.1021/acs.organomet.1c00216}, number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)}, author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng and Dyballa, Michael and Nowakowski, Michał and Bauer, Matthias and Estes, Deven P.}, year={2021}, pages={1751–1757} }","apa":"Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski, M., Bauer, M., & Estes, D. P. (2021). Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics, 40(11), 1751–1757. https://doi.org/10.1021/acs.organomet.1c00216"},"publication_identifier":{"issn":["0276-7333","1520-6041"]},"publication_status":"published","language":[{"iso":"eng"}],"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry"],"abstract":[{"lang":"eng","text":"Platinum hydride species catalyze a number of interesting organic reactions. However, their reactions typically involve the use of high loadings of noble metal and are difficult to recycle, making them somewhat unsustainable. We have synthesized surface-immobilized Pt–H species via oxidative addition of surface OH groups to Pt(PtBu3)2 (1), a rarely used immobilization technique in surface organometallic chemistry. The hydride species thus made were characterized by infrared, magic-angle spinning nuclear magnetic resonance, and X-ray absorption spectroscopies and catalyzed both olefin isomerization and cycloisomerization of a 1,6 enyne (5) with a high selectivity and low Pt loading."}],"publication":"Organometallics","title":"Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations","date_created":"2023-01-30T17:00:10Z","publisher":"American Chemical Society (ACS)","year":"2021","issue":"11"},{"issue":"38","year":"2021","date_created":"2022-03-09T08:20:58Z","publisher":"Wiley","title":"Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad","publication":"Chemistry – A European Journal","language":[{"iso":"eng"}],"keyword":["Photocatalytic Hydrogen Production","Catalysis","Inorganic Chemistry"],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"publication_status":"published","page":"9905-9918","intvolume":" 27","citation":{"ama":"Huber-Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal. 2021;27(38):9905-9918. doi:10.1002/chem.202100766","ieee":"M. Huber-Gedert et al., “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” Chemistry – A European Journal, vol. 27, no. 38, pp. 9905–9918, 2021, doi: 10.1002/chem.202100766.","chicago":"Huber-Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt, Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European Journal 27, no. 38 (2021): 9905–18. https://doi.org/10.1002/chem.202100766.","apa":"Huber-Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N., Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda, W., & Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal, 27(38), 9905–9918. https://doi.org/10.1002/chem.202100766","mla":"Huber-Gedert, Marina, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European Journal, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:10.1002/chem.202100766.","short":"M. Huber-Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R. Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda, M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.","bibtex":"@article{Huber-Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={10.1002/chem.202100766}, number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber-Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }"},"volume":27,"author":[{"id":"38352","full_name":"Huber-Gedert, Marina","last_name":"Huber-Gedert","first_name":"Marina"},{"full_name":"Nowakowski, Michał","id":"78878","orcid":"0000-0002-3734-7011","last_name":"Nowakowski","first_name":"Michał"},{"first_name":"Ahmet","last_name":"Kertmen","full_name":"Kertmen, Ahmet"},{"first_name":"Lukas","last_name":"Burkhardt","orcid":"0000-0003-0747-9811","id":"54038","full_name":"Burkhardt, Lukas"},{"first_name":"Natalia","full_name":"Lindner, Natalia","last_name":"Lindner"},{"last_name":"Schoch","full_name":"Schoch, Roland","first_name":"Roland"},{"last_name":"Herbst‐Irmer","full_name":"Herbst‐Irmer, Regine","first_name":"Regine"},{"last_name":"Neuba","full_name":"Neuba, Adam","first_name":"Adam"},{"first_name":"Lennart","last_name":"Schmitz","full_name":"Schmitz, Lennart"},{"last_name":"Choi","full_name":"Choi, Tae‐Kyu","first_name":"Tae‐Kyu"},{"last_name":"Kubicki","full_name":"Kubicki, Jacek","first_name":"Jacek"},{"first_name":"Wojciech","full_name":"Gawelda, Wojciech","last_name":"Gawelda"},{"first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer"}],"date_updated":"2024-05-07T11:44:08Z","doi":"10.1002/chem.202100766","type":"journal_article","status":"public","department":[{"_id":"306"}],"user_id":"48467","_id":"30216"},{"user_id":"53339","_id":"35686","language":[{"iso":"eng"}],"keyword":["Organic Chemistry","Catalysis"],"type":"journal_article","publication":"Synthesis","status":"public","abstract":[{"text":"AbstractThe development of the frustrated Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed. Detailed insight into our strategies in order to overcome challenges during the reaction development process is provided. Furthermore, the developed chemistry is extended to the hydrogenation of polyamides and of trifluoroacetamides for the convenient introduction of trifluoroethyl groups into organic molecules.","lang":"eng"}],"date_created":"2023-01-10T08:56:44Z","author":[{"first_name":"Jan","full_name":"Paradies, Jan","id":"53339","last_name":"Paradies","orcid":"0000-0002-3698-668X"},{"first_name":"Laura","last_name":"Köring","full_name":"Köring, Laura"},{"first_name":"Nikolai A.","full_name":"Sitte, Nikolai A.","last_name":"Sitte"}],"volume":54,"publisher":"Georg Thieme Verlag KG","date_updated":"2023-01-23T12:51:23Z","doi":"10.1055/a-1681-3972","title":"Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides","issue":"05","publication_status":"published","publication_identifier":{"issn":["0039-7881","1437-210X"]},"citation":{"ama":"Paradies J, Köring L, Sitte NA. Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides. Synthesis. 2021;54(05):1287-1300. doi:10.1055/a-1681-3972","chicago":"Paradies, Jan, Laura Köring, and Nikolai A. Sitte. “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” Synthesis 54, no. 05 (2021): 1287–1300. https://doi.org/10.1055/a-1681-3972.","ieee":"J. Paradies, L. Köring, and N. A. Sitte, “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides,” Synthesis, vol. 54, no. 05, pp. 1287–1300, 2021, doi: 10.1055/a-1681-3972.","mla":"Paradies, Jan, et al. “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” Synthesis, vol. 54, no. 05, Georg Thieme Verlag KG, 2021, pp. 1287–300, doi:10.1055/a-1681-3972.","bibtex":"@article{Paradies_Köring_Sitte_2021, title={Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides}, volume={54}, DOI={10.1055/a-1681-3972}, number={05}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Paradies, Jan and Köring, Laura and Sitte, Nikolai A.}, year={2021}, pages={1287–1300} }","short":"J. Paradies, L. Köring, N.A. Sitte, Synthesis 54 (2021) 1287–1300.","apa":"Paradies, J., Köring, L., & Sitte, N. A. (2021). Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides. Synthesis, 54(05), 1287–1300. https://doi.org/10.1055/a-1681-3972"},"intvolume":" 54","page":"1287-1300","year":"2021"}]