---
_id: '41971'
abstract:
- lang: ger
  text: "Ultraschall-Drahtbonden ist eine Standardtechnologie im Bereich der Aufbau-
    und Verbindungstechnik von Leistungshalbleitermodulen. Um Prozessschritte und
    damit wertvolle Zeit zu sparen, sollen die Kupferdickdrähte für die Leistungshalbleiter
    auch für die Kontaktierung von eingespritzten Anschlusssteckern im Modulrahmen
    verwendet werden. Das Kontaktierungsverfahren mit diesen Drähten auf Steckern
    in dünnwandigen Kunststoffrahmen führt häufig zu unzureichender Bondqualität.
    In dieser Arbeit wird das Bonden von Anschlusssteckern experimentell und anhand
    von Simulationen untersucht, um die Prozessstabilität zu steigern.\r\n\r\nZunächst
    wurden Experimente auf Untergründen mit hoher Steifigkeit durchgeführt, um Störgrößen
    von Untergrundeigenschaften zu verringern. Die gewonnenen Erkenntnisse erlaubten
    die Entwicklung eines Simulationsmodells für die Vorhersage der Bondqualität.
    Dieses basiert auf einer flächenaufgelösten Reibarbeitsbestimmung im Fügebereich
    unter Berücksichtigung des Ultraschallerweichungseffektes und der hierdurch entstehenden
    hohen Drahtverformung.\r\n\r\nExperimente an den Anschlusssteckern im Modulrahmen
    zeigten eine verringerte Relativverschiebung zwischen Draht und Stecker, was zu
    einer deutlichen Verringerung der Reibarbeit führt. Außerdem wurden verminderte
    Schwingamplituden des Bondwerkzeugs nachgewiesen. Dies führt zu einer weiteren
    Reduktion der Reibarbeit. Beide Effekte wurden mithilfe eines Mehrmassenschwingers
    modelliert. Die gewonnenen Erkenntnisse und die erstellten Simulationsmodelle
    ermöglichen die Entwicklung von Klemmvorrichtungen, welche die identifizierten
    Störgrößen gezielt kompensieren und so ein verlässliches Bonden der Anschlussstecker
    im gleichen Prozessschritt ermöglichen, in dem auch die Leistungshalbleiter kontaktiert
    werden."
author:
- first_name: Simon
  full_name: Althoff, Simon
  last_name: Althoff
citation:
  ama: Althoff S. <i>Predicting the Bond Quality of Heavy Copper Wire Bonds Using
    a Friction Model Approach</i>. Vol 15. Shaker; 2023.
  apa: Althoff, S. (2023). <i>Predicting the Bond Quality of Heavy Copper Wire Bonds
    using a Friction Model Approach</i> (Vol. 15). Shaker.
  bibtex: '@book{Althoff_2023, series={Schriften des Lehrstuhls für Dynamik und Mechatronik},
    title={Predicting the Bond Quality of Heavy Copper Wire Bonds using a Friction
    Model Approach}, volume={15}, publisher={Shaker}, author={Althoff, Simon}, year={2023},
    collection={Schriften des Lehrstuhls für Dynamik und Mechatronik} }'
  chicago: Althoff, Simon. <i>Predicting the Bond Quality of Heavy Copper Wire Bonds
    Using a Friction Model Approach</i>. Vol. 15. Schriften Des Lehrstuhls Für Dynamik
    Und Mechatronik. Shaker, 2023.
  ieee: S. Althoff, <i>Predicting the Bond Quality of Heavy Copper Wire Bonds using
    a Friction Model Approach</i>, vol. 15. Shaker, 2023.
  mla: Althoff, Simon. <i>Predicting the Bond Quality of Heavy Copper Wire Bonds Using
    a Friction Model Approach</i>. Shaker, 2023.
  short: S. Althoff, Predicting the Bond Quality of Heavy Copper Wire Bonds Using
    a Friction Model Approach, Shaker, 2023.
date_created: 2023-02-10T13:05:19Z
date_updated: 2023-02-10T13:05:42Z
department:
- _id: '151'
extern: '1'
intvolume: '        15'
keyword:
- heavy copper bonding
- wire bonding
- quality prediction
- friction model
- point-contact-element
language:
- iso: eng
main_file_link:
- url: https://katalog.ub.uni-paderborn.de/local/r/9925085762506463?sr[q,any]=Simon%20Althoff
page: '192'
publication_identifier:
  isbn:
  - 978-3-8440-8903-5
publication_status: published
publisher: Shaker
related_material:
  link:
  - relation: confirmation
    url: https://www.shaker.de/de/content/catalogue/index.asp?lang=de&ID=8&ISBN=978-3-8440-8903-5&search=yes
series_title: Schriften des Lehrstuhls für Dynamik und Mechatronik
status: public
supervisor:
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
title: Predicting the Bond Quality of Heavy Copper Wire Bonds using a Friction Model
  Approach
type: dissertation
user_id: '55222'
volume: 15
year: '2023'
...
---
_id: '21436'
abstract:
- lang: eng
  text: Ultrasonic wire bonding is a solid-state joining process, used in the electronics
    industry to form electrical connections, e.g. to connect electrical terminals
    within semiconductor modules. Many process parameters affect the bond strength,
    such like the bond normal force, ultrasonic power, wire material and bonding frequency.
    Today, process design, development, and optimization is most likely based on the
    knowledge of process engineers and is mainly performed by experimental testing.
    In this contribution, a newly developed simulation tool is presented, to reduce
    time and costs and efficiently determine optimized process parameter. Based on
    a co-simulation of MATLAB and ANSYS, the different physical phenomena of the wire
    bonding process are considered using finite element simulation for the complex
    plastic deformation of the wire and reduced order models for the transient dynamics
    of the transducer, wire, substrate and bond formation. The model parameters such
    as the coefficients of friction between bond tool and wire and between wire and
    substrate were determined for aluminium and copper wire in experiments with a
    test rig specially developed for the requirements of heavy wire bonding. To reduce
    simulation time, for the finite element simulation a restart analysis and high
    performance computing is utilized. Detailed analysis of the bond formation showed,
    that the normal pressure distribution in the contact between wire and substrate
    has high impact on bond formation and distribution of welded areas in the contact
    area.
author:
- first_name: Reinhard
  full_name: Schemmel, Reinhard
  id: '28647'
  last_name: Schemmel
- first_name: Viktor
  full_name: Krieger, Viktor
  last_name: Krieger
- first_name: Tobias
  full_name: Hemsel, Tobias
  id: '210'
  last_name: Hemsel
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
citation:
  ama: Schemmel R, Krieger V, Hemsel T, Sextro W. Co-simulation of MATLAB and ANSYS
    for ultrasonic wire bonding process optimization. <i>Microelectronics Reliability</i>.
    2021;119:114077. doi:<a href="https://doi.org/10.1016/j.microrel.2021.114077">https://doi.org/10.1016/j.microrel.2021.114077</a>
  apa: Schemmel, R., Krieger, V., Hemsel, T., &#38; Sextro, W. (2021). Co-simulation
    of MATLAB and ANSYS for ultrasonic wire bonding process optimization. <i>Microelectronics
    Reliability</i>, <i>119</i>, 114077. <a href="https://doi.org/10.1016/j.microrel.2021.114077">https://doi.org/10.1016/j.microrel.2021.114077</a>
  bibtex: '@article{Schemmel_Krieger_Hemsel_Sextro_2021, title={Co-simulation of MATLAB
    and ANSYS for ultrasonic wire bonding process optimization}, volume={119}, DOI={<a
    href="https://doi.org/10.1016/j.microrel.2021.114077">https://doi.org/10.1016/j.microrel.2021.114077</a>},
    journal={Microelectronics Reliability}, author={Schemmel, Reinhard and Krieger,
    Viktor and Hemsel, Tobias and Sextro, Walter}, year={2021}, pages={114077} }'
  chicago: 'Schemmel, Reinhard, Viktor Krieger, Tobias Hemsel, and Walter Sextro.
    “Co-Simulation of MATLAB and ANSYS for Ultrasonic Wire Bonding Process Optimization.”
    <i>Microelectronics Reliability</i> 119 (2021): 114077. <a href="https://doi.org/10.1016/j.microrel.2021.114077">https://doi.org/10.1016/j.microrel.2021.114077</a>.'
  ieee: 'R. Schemmel, V. Krieger, T. Hemsel, and W. Sextro, “Co-simulation of MATLAB
    and ANSYS for ultrasonic wire bonding process optimization,” <i>Microelectronics
    Reliability</i>, vol. 119, p. 114077, 2021, doi: <a href="https://doi.org/10.1016/j.microrel.2021.114077">https://doi.org/10.1016/j.microrel.2021.114077</a>.'
  mla: Schemmel, Reinhard, et al. “Co-Simulation of MATLAB and ANSYS for Ultrasonic
    Wire Bonding Process Optimization.” <i>Microelectronics Reliability</i>, vol.
    119, 2021, p. 114077, doi:<a href="https://doi.org/10.1016/j.microrel.2021.114077">https://doi.org/10.1016/j.microrel.2021.114077</a>.
  short: R. Schemmel, V. Krieger, T. Hemsel, W. Sextro, Microelectronics Reliability
    119 (2021) 114077.
date_created: 2021-03-10T09:37:02Z
date_updated: 2023-09-21T14:15:33Z
department:
- _id: '151'
doi: https://doi.org/10.1016/j.microrel.2021.114077
intvolume: '       119'
keyword:
- Ultrasonic heavy wire bonding
- Co-simulation
- ANSYS
- MATLAB
- Process optimization
- Friction coefficient
- Copper-copper
- Aluminium-copper
language:
- iso: eng
page: '114077'
publication: Microelectronics Reliability
publication_identifier:
  issn:
  - 0026-2714
publication_status: published
quality_controlled: '1'
status: public
title: Co-simulation of MATLAB and ANSYS for ultrasonic wire bonding process optimization
type: journal_article
user_id: '210'
volume: 119
year: '2021'
...
---
_id: '9999'
abstract:
- lang: eng
  text: Ultrasonic wire bonding is an indispensable process in the industrial manufacturing
    of semiconductor devices. Copper wire is increasingly replacing the well-established
    aluminium wire because of its superior electrical, thermal and mechanical properties.
    Copper wire processes differ significantly from aluminium processes and are more
    sensitive to disturbances, which reduces the range of parameter values suitable
    for a stable process. Disturbances can be compensated by an adaption of process
    parameters, but finding suitable parameters manually is difficult and time-consuming.
    This paper presents a physical model of the ultrasonic wire bonding process including
    the friction contact between tool and wire. This model yields novel insights into
    the process. A prototype of a multi-objective optimizing bonding machine (MOBM)
    is presented. It uses multi-objective optimization, based on the complete process
    model, to automatically select the best operating point as a compromise of concurrent
    objectives.
author:
- first_name: Andreas
  full_name: Unger, Andreas
  last_name: Unger
- first_name: Matthias
  full_name: Hunstig, Matthias
  last_name: Hunstig
- first_name: Tobias
  full_name: Meyer, Tobias
  last_name: Meyer
- first_name: Michael
  full_name: Brökelmann, Michael
  last_name: Brökelmann
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
citation:
  ama: 'Unger A, Hunstig M, Meyer T, Brökelmann M, Sextro W. Intelligent Production
    of Wire Bonds using Multi-Objective Optimization – Insights, Opportunities and
    Challenges. In: <i>In Proceedings of IMAPS 2018 – 51st Symposium on Microelectronics,
    Pasadena, CA, 2018</i>. Vol Vol. 2018, No. 1, pp. 000572-000577. ; 2018. doi:<a
    href="https://doi.org/10.4071/2380-4505-2018.1.000572">10.4071/2380-4505-2018.1.000572</a>'
  apa: Unger, A., Hunstig, M., Meyer, T., Brökelmann, M., &#38; Sextro, W. (2018).
    Intelligent Production of Wire Bonds using Multi-Objective Optimization – Insights,
    Opportunities and Challenges. In <i>In Proceedings of IMAPS 2018 – 51st Symposium
    on Microelectronics, Pasadena, CA, 2018</i> (Vol. Vol. 2018, No. 1, pp. 000572-000577.).
    <a href="https://doi.org/10.4071/2380-4505-2018.1.000572">https://doi.org/10.4071/2380-4505-2018.1.000572</a>
  bibtex: '@inproceedings{Unger_Hunstig_Meyer_Brökelmann_Sextro_2018, title={Intelligent
    Production of Wire Bonds using Multi-Objective Optimization – Insights, Opportunities
    and Challenges}, volume={Vol. 2018, No. 1, pp. 000572-000577.}, DOI={<a href="https://doi.org/10.4071/2380-4505-2018.1.000572">10.4071/2380-4505-2018.1.000572</a>},
    booktitle={In Proceedings of IMAPS 2018 – 51st Symposium on Microelectronics,
    Pasadena, CA, 2018}, author={Unger, Andreas and Hunstig, Matthias and Meyer, Tobias
    and Brökelmann, Michael and Sextro, Walter}, year={2018} }'
  chicago: Unger, Andreas, Matthias Hunstig, Tobias Meyer, Michael Brökelmann, and
    Walter Sextro. “Intelligent Production of Wire Bonds Using Multi-Objective Optimization
    – Insights, Opportunities and Challenges.” In <i>In Proceedings of IMAPS 2018
    – 51st Symposium on Microelectronics, Pasadena, CA, 2018</i>, Vol. Vol. 2018,
    No. 1, pp. 000572-000577., 2018. <a href="https://doi.org/10.4071/2380-4505-2018.1.000572">https://doi.org/10.4071/2380-4505-2018.1.000572</a>.
  ieee: A. Unger, M. Hunstig, T. Meyer, M. Brökelmann, and W. Sextro, “Intelligent
    Production of Wire Bonds using Multi-Objective Optimization – Insights, Opportunities
    and Challenges,” in <i>In Proceedings of IMAPS 2018 – 51st Symposium on Microelectronics,
    Pasadena, CA, 2018</i>, 2018, vol. Vol. 2018, No. 1, pp. 000572-000577.
  mla: Unger, Andreas, et al. “Intelligent Production of Wire Bonds Using Multi-Objective
    Optimization – Insights, Opportunities and Challenges.” <i>In Proceedings of IMAPS
    2018 – 51st Symposium on Microelectronics, Pasadena, CA, 2018</i>, vol. Vol. 2018,
    No. 1, pp. 000572-000577., 2018, doi:<a href="https://doi.org/10.4071/2380-4505-2018.1.000572">10.4071/2380-4505-2018.1.000572</a>.
  short: 'A. Unger, M. Hunstig, T. Meyer, M. Brökelmann, W. Sextro, in: In Proceedings
    of IMAPS 2018 – 51st Symposium on Microelectronics, Pasadena, CA, 2018, 2018.'
date_created: 2019-05-27T10:27:45Z
date_updated: 2020-05-07T05:33:56Z
department:
- _id: '151'
doi: 10.4071/2380-4505-2018.1.000572
keyword:
- wire bonding
- multi-objective optimization
- process model
- copper wire
- self-optimization
language:
- iso: eng
project:
- _id: '92'
  grant_number: 02 PQ2210
  name: Intelligente Herstellung zuverlässiger Kupferbondverbindungen
publication: In Proceedings of IMAPS 2018 – 51st Symposium on Microelectronics, Pasadena,
  CA, 2018
quality_controlled: '1'
status: public
title: Intelligent Production of Wire Bonds using Multi-Objective Optimization – Insights,
  Opportunities and Challenges
type: conference
user_id: '210'
volume: Vol. 2018, No. 1, pp. 000572-000577.
year: '2018'
...
---
_id: '13186'
abstract:
- lang: eng
  text: Ligands DMEG6etqu, TMG6etqu, DMEG6buqu, and TMG6buqu were developed on the
    basis of guanidine quinoline (GUAqu) ligands 1,3-dimethyl-N-(quinolin-8-yl)imidazolidin-2-imine
    (DMEGqu) and 1,1,3,3-tetramethyl-2-(quinolin-8-yl)guanidine (TMGqu). These ligands
    feature an alkyl substituent at the C6 of the quinoline backbone. The synthetic
    strategy developed here enables inexpensive syntheses of any kind of C6-substituted
    GUAqu ligands. On one hand, the alkylation increases the solubility of corresponding
    copper complexes in apolar atom transfer radical polymerization (ATRP) monomers
    like styrene. On the other hand, it has a significant electronic influence and
    thus an effect on the donor properties of the new ligands. Seven CuI and CuII
    complexes of DMEG6etqu and TMG6etqu have been crystallized and were studied with
    regard to their structural and electrochemical properties. CuI and CuII complexes
    of DMEG6buqu and TMG6buqu turned out to be perfectly soluble in pure styrene even
    at room temperature, which makes them excellent catalysts in the ATRP of apolar
    monomers. The key characteristics of the ATRP equilibrium, KATRP and kact, were
    determined for the new complexes. In addition, we used our recently developed
    DFT methodology, NBO analysis, and isodesmic reactions to predict the influence
    of the introduced alkyl substituents. It turned out that high conformational freedom
    in the complex structures leads to a significant uncertainty in prediction of
    the thermodynamic properties.
author:
- first_name: Thomas
  full_name: Rösener, Thomas
  last_name: Rösener
- first_name: Alexander
  full_name: Hoffmann, Alexander
  last_name: Hoffmann
- first_name: Sonja
  full_name: Herres-Pawlis, Sonja
  last_name: Herres-Pawlis
citation:
  ama: 'Rösener T, Hoffmann A, Herres-Pawlis S. Next Generation of Guanidine Quinoline
    Copper Complexes for Highly Controlled ATRP: Influence of Backbone Substitution
    on Redox Chemistry and Solubility. <i>European Journal of Inorganic Chemistry</i>.
    2018;2018(27):3164-3175. doi:<a href="https://doi.org/10.1002/ejic.201800511">10.1002/ejic.201800511</a>'
  apa: 'Rösener, T., Hoffmann, A., &#38; Herres-Pawlis, S. (2018). Next Generation
    of Guanidine Quinoline Copper Complexes for Highly Controlled ATRP: Influence
    of Backbone Substitution on Redox Chemistry and Solubility. <i>European Journal
    of Inorganic Chemistry</i>, <i>2018</i>(27), 3164–3175. <a href="https://doi.org/10.1002/ejic.201800511">https://doi.org/10.1002/ejic.201800511</a>'
  bibtex: '@article{Rösener_Hoffmann_Herres-Pawlis_2018, title={Next Generation of
    Guanidine Quinoline Copper Complexes for Highly Controlled ATRP: Influence of
    Backbone Substitution on Redox Chemistry and Solubility}, volume={2018}, DOI={<a
    href="https://doi.org/10.1002/ejic.201800511">10.1002/ejic.201800511</a>}, number={27},
    journal={European Journal of Inorganic Chemistry}, author={Rösener, Thomas and
    Hoffmann, Alexander and Herres-Pawlis, Sonja}, year={2018}, pages={3164–3175}
    }'
  chicago: 'Rösener, Thomas, Alexander Hoffmann, and Sonja Herres-Pawlis. “Next Generation
    of Guanidine Quinoline Copper Complexes for Highly Controlled ATRP: Influence
    of Backbone Substitution on Redox Chemistry and Solubility.” <i>European Journal
    of Inorganic Chemistry</i> 2018, no. 27 (2018): 3164–75. <a href="https://doi.org/10.1002/ejic.201800511">https://doi.org/10.1002/ejic.201800511</a>.'
  ieee: 'T. Rösener, A. Hoffmann, and S. Herres-Pawlis, “Next Generation of Guanidine
    Quinoline Copper Complexes for Highly Controlled ATRP: Influence of Backbone Substitution
    on Redox Chemistry and Solubility,” <i>European Journal of Inorganic Chemistry</i>,
    vol. 2018, no. 27, pp. 3164–3175, 2018.'
  mla: 'Rösener, Thomas, et al. “Next Generation of Guanidine Quinoline Copper Complexes
    for Highly Controlled ATRP: Influence of Backbone Substitution on Redox Chemistry
    and Solubility.” <i>European Journal of Inorganic Chemistry</i>, vol. 2018, no.
    27, 2018, pp. 3164–75, doi:<a href="https://doi.org/10.1002/ejic.201800511">10.1002/ejic.201800511</a>.'
  short: T. Rösener, A. Hoffmann, S. Herres-Pawlis, European Journal of Inorganic
    Chemistry 2018 (2018) 3164–3175.
date_created: 2019-09-11T11:00:06Z
date_updated: 2022-01-06T06:51:30Z
doi: 10.1002/ejic.201800511
intvolume: '      2018'
issue: '27'
keyword:
- Copper
- Polymerization
- Redox chemistry
- Structure elucidation
- Ligand effects
language:
- iso: eng
page: 3164-3175
project:
- _id: '52'
  name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: European Journal of Inorganic Chemistry
status: public
title: 'Next Generation of Guanidine Quinoline Copper Complexes for Highly Controlled
  ATRP: Influence of Backbone Substitution on Redox Chemistry and Solubility'
type: journal_article
user_id: '40778'
volume: 2018
year: '2018'
...
---
_id: '13187'
abstract:
- lang: eng
  text: Abstract The reaction of Cu(I) bisguanidine complexes with nitric oxide and
    the formation of intermediate species were monitored via UV-vis spectroscopy at
    low temperature, with the occurrence of characteristic absorption bands. The origin
    of the emerging species and their character were substantiated by electron paramagnetic
    resonance (EPR) measurements and density functional theory (DFT) studies showing
    a delocalized {CuNO}11 radical species. Furthermore, this system was transferred
    to the SuperFocus mixer setup, which allows rapid mixing and the determination
    of decay constants at ambient temperatures of the thermally sensitive species.
    However, these experiments demonstrated the limits of these systems, such as the
    NO saturation in organic solvents and a preferably precise temperature control
    within the SuperFocus mixer, which should be addressed in the future.
author:
- first_name: Alexander
  full_name: Oppermann, Alexander
  last_name: Oppermann
- first_name: Larissa
  full_name: Laurini, Larissa
  last_name: Laurini
- first_name: Fabian
  full_name: Etscheidt, Fabian
  last_name: Etscheidt
- first_name: Katharina
  full_name: Hollmann, Katharina
  last_name: Hollmann
- first_name: Florian
  full_name: Strassl, Florian
  last_name: Strassl
- first_name: Alexander
  full_name: Hoffmann, Alexander
  last_name: Hoffmann
- first_name: Daniela
  full_name: Schurr, Daniela
  last_name: Schurr
- first_name: Roland
  full_name: Dittmeyer, Roland
  last_name: Dittmeyer
- first_name: Günter
  full_name: Rinke, Günter
  last_name: Rinke
- first_name: Sonja
  full_name: Herres-Pawlis, Sonja
  last_name: Herres-Pawlis
citation:
  ama: Oppermann A, Laurini L, Etscheidt F, et al. Detection of Copper Bisguanidine
    NO Adducts by UV-vis Spectroscopy and a SuperFocus Mixer. <i>Chemical Engineering
    \&#38; Technology</i>. 2017;40(8):1475-1483. doi:<a href="https://doi.org/10.1002/ceat.201600691">10.1002/ceat.201600691</a>
  apa: Oppermann, A., Laurini, L., Etscheidt, F., Hollmann, K., Strassl, F., Hoffmann,
    A., … Herres-Pawlis, S. (2017). Detection of Copper Bisguanidine NO Adducts by
    UV-vis Spectroscopy and a SuperFocus Mixer. <i>Chemical Engineering \&#38; Technology</i>,
    <i>40</i>(8), 1475–1483. <a href="https://doi.org/10.1002/ceat.201600691">https://doi.org/10.1002/ceat.201600691</a>
  bibtex: '@article{Oppermann_Laurini_Etscheidt_Hollmann_Strassl_Hoffmann_Schurr_Dittmeyer_Rinke_Herres-Pawlis_2017,
    title={Detection of Copper Bisguanidine NO Adducts by UV-vis Spectroscopy and
    a SuperFocus Mixer}, volume={40}, DOI={<a href="https://doi.org/10.1002/ceat.201600691">10.1002/ceat.201600691</a>},
    number={8}, journal={Chemical Engineering \&#38; Technology}, author={Oppermann,
    Alexander and Laurini, Larissa and Etscheidt, Fabian and Hollmann, Katharina and
    Strassl, Florian and Hoffmann, Alexander and Schurr, Daniela and Dittmeyer, Roland
    and Rinke, Günter and Herres-Pawlis, Sonja}, year={2017}, pages={1475–1483} }'
  chicago: 'Oppermann, Alexander, Larissa Laurini, Fabian Etscheidt, Katharina Hollmann,
    Florian Strassl, Alexander Hoffmann, Daniela Schurr, Roland Dittmeyer, Günter
    Rinke, and Sonja Herres-Pawlis. “Detection of Copper Bisguanidine NO Adducts by
    UV-Vis Spectroscopy and a SuperFocus Mixer.” <i>Chemical Engineering \&#38; Technology</i>
    40, no. 8 (2017): 1475–83. <a href="https://doi.org/10.1002/ceat.201600691">https://doi.org/10.1002/ceat.201600691</a>.'
  ieee: A. Oppermann <i>et al.</i>, “Detection of Copper Bisguanidine NO Adducts by
    UV-vis Spectroscopy and a SuperFocus Mixer,” <i>Chemical Engineering \&#38; Technology</i>,
    vol. 40, no. 8, pp. 1475–1483, 2017.
  mla: Oppermann, Alexander, et al. “Detection of Copper Bisguanidine NO Adducts by
    UV-Vis Spectroscopy and a SuperFocus Mixer.” <i>Chemical Engineering \&#38; Technology</i>,
    vol. 40, no. 8, 2017, pp. 1475–83, doi:<a href="https://doi.org/10.1002/ceat.201600691">10.1002/ceat.201600691</a>.
  short: A. Oppermann, L. Laurini, F. Etscheidt, K. Hollmann, F. Strassl, A. Hoffmann,
    D. Schurr, R. Dittmeyer, G. Rinke, S. Herres-Pawlis, Chemical Engineering \&#38;
    Technology 40 (2017) 1475–1483.
date_created: 2019-09-11T11:01:30Z
date_updated: 2022-01-06T06:51:30Z
doi: 10.1002/ceat.201600691
intvolume: '        40'
issue: '8'
keyword:
- Copper guanidine complexes
- Nitric oxide
- SuperFocus mixer
language:
- iso: eng
page: 1475-1483
project:
- _id: '52'
  name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Chemical Engineering \& Technology
status: public
title: Detection of Copper Bisguanidine NO Adducts by UV-vis Spectroscopy and a SuperFocus
  Mixer
type: journal_article
user_id: '40778'
volume: 40
year: '2017'
...
---
_id: '9959'
abstract:
- lang: eng
  text: Ultrasonic heavy wire bonding is a commonly used technology to conduct electrical
    devices in power electronics. In order to facilitate powerful solutions combined
    with an increased efficiency, involving a material change from aluminum to copper
    wire as conductor material takes place in recent years. Due to the material related
    properties, copper wire bonding requires significant higher bond processing parameters
    such as bond force and ultrasonic power compared to aluminum which can lead to
    damages or a failure of the bonded component. Therefore, a profound knowledge
    of the processes prevailing during wire bonding is essential to optimize the application
    of the copper wires and consequently to achieve the demands on quality and reliability.
    The behavior of different natural surface oxides of aluminum and copper are assumed
    to be one reason for the deviation in the required bond parameters. Accordingly,
    the impact of differently pre-treated substrates surfaces on which the bonding
    is applied were investigated in this study. First, all conditions investigated
    (as-received, oxidefree, AlOx and the CuOx) were characterized by utilizing scanning
    electron microscopy, energy dispersive X-ray spectroscopy, focused ion beam microscopy
    and atomic force microscopy. In addition, hardness tests were performed as well
    as perthometer measurements. Afterwards, a 500 $\mu$ m copper wire was bonded
    on the generated surfaces investigated. In consideration of the roughness, shear
    test of various bond times and microscopic images were evaluated. Finally, the
    results were compared and discussed. Overall, the current study indicates that
    an Al-oxide layer is beneficial for welding process in Cu wire bonding. On the
    contrary, the Cu-oxide is detrimental and leads to a delayed welding of the joining
    parts. Based on the obtained results, it can be expected that due to an ideal
    set of Al-oxide layers, lower optimal bond parameters can used to reach high bond
    strength with good reliability properties.
author:
- first_name: Florian
  full_name: Eacock, Florian
  last_name: Eacock
- first_name: Andreas
  full_name: Unger, Andreas
  last_name: Unger
- first_name: Paul
  full_name: Eichwald, Paul
  last_name: Eichwald
- first_name: Olexandr
  full_name: Grydin, Olexandr
  last_name: Grydin
- first_name: Florian
  full_name: Hengsbach, Florian
  last_name: Hengsbach
- first_name: Simon
  full_name: Althoff, Simon
  last_name: Althoff
- first_name: Mirko
  full_name: Schaper, Mirko
  last_name: Schaper
- first_name: Karsten
  full_name: Guth, Karsten
  last_name: Guth
citation:
  ama: 'Eacock F, Unger A, Eichwald P, et al. Effect of different oxide layers on
    the ultrasonic copper wire bond process. In: <i>IEEE 66th Electronic Components
    and Technology Conference</i>. ; 2016:2111-2118. doi:<a href="https://doi.org/10.1109/ECTC.2016.91">10.1109/ECTC.2016.91</a>'
  apa: Eacock, F., Unger, A., Eichwald, P., Grydin, O., Hengsbach, F., Althoff, S.,
    … Guth, K. (2016). Effect of different oxide layers on the ultrasonic copper wire
    bond process. In <i>IEEE 66th Electronic Components and Technology Conference</i>
    (pp. 2111–2118). <a href="https://doi.org/10.1109/ECTC.2016.91">https://doi.org/10.1109/ECTC.2016.91</a>
  bibtex: '@inproceedings{Eacock_Unger_Eichwald_Grydin_Hengsbach_Althoff_Schaper_Guth_2016,
    title={Effect of different oxide layers on the ultrasonic copper wire bond process},
    DOI={<a href="https://doi.org/10.1109/ECTC.2016.91">10.1109/ECTC.2016.91</a>},
    booktitle={IEEE 66th Electronic Components and Technology Conference}, author={Eacock,
    Florian and Unger, Andreas and Eichwald, Paul and Grydin, Olexandr and Hengsbach,
    Florian and Althoff, Simon and Schaper, Mirko and Guth, Karsten}, year={2016},
    pages={2111–2118} }'
  chicago: Eacock, Florian, Andreas Unger, Paul Eichwald, Olexandr Grydin, Florian
    Hengsbach, Simon Althoff, Mirko Schaper, and Karsten Guth. “Effect of Different
    Oxide Layers on the Ultrasonic Copper Wire Bond Process.” In <i>IEEE 66th Electronic
    Components and Technology Conference</i>, 2111–18, 2016. <a href="https://doi.org/10.1109/ECTC.2016.91">https://doi.org/10.1109/ECTC.2016.91</a>.
  ieee: F. Eacock <i>et al.</i>, “Effect of different oxide layers on the ultrasonic
    copper wire bond process,” in <i>IEEE 66th Electronic Components and Technology
    Conference</i>, 2016, pp. 2111–2118.
  mla: Eacock, Florian, et al. “Effect of Different Oxide Layers on the Ultrasonic
    Copper Wire Bond Process.” <i>IEEE 66th Electronic Components and Technology Conference</i>,
    2016, pp. 2111–18, doi:<a href="https://doi.org/10.1109/ECTC.2016.91">10.1109/ECTC.2016.91</a>.
  short: 'F. Eacock, A. Unger, P. Eichwald, O. Grydin, F. Hengsbach, S. Althoff, M.
    Schaper, K. Guth, in: IEEE 66th Electronic Components and Technology Conference,
    2016, pp. 2111–2118.'
date_created: 2019-05-27T09:00:50Z
date_updated: 2019-09-16T10:38:59Z
department:
- _id: '151'
doi: 10.1109/ECTC.2016.91
keyword:
- Ultrasonic copper wire bonding
- Al-oxide
- Cuoxide
- oxide-free
- roughness
- morphology
language:
- iso: eng
page: 2111-2118
publication: IEEE 66th Electronic Components and Technology Conference
quality_controlled: '1'
status: public
title: Effect of different oxide layers on the ultrasonic copper wire bond process
type: conference
user_id: '55222'
year: '2016'
...
---
_id: '9966'
abstract:
- lang: eng
  text: Usage of copper wire bonds allows to push power boundaries imposed by aluminum
    wire bonds. Copper allows higher electrical, thermal and mechanical loads than
    aluminum, which currently is the most commonly used material in heavy wire bonding.
    This is the main driving factor for increased usage of copper in high power applications
    such as wind turbines, locomotives or electric vehicles. At the same time, usage
    of copper also increases tool wear and reduces the range of parameter values for
    a stable process, making the process more challenging. To overcome these drawbacks,
    parameter adaptation at runtime using self-optimization is desired. A self-optimizing
    system is based on system objectives that evaluate and quantify system performance.
    System parameters can be changed at runtime such that pre-selected objective values
    are reached. For adaptation of bond process parameters, model-based self-optimization
    is employed. Since it is based on a model of the system, the bond process was
    modeled. In addition to static model parameters such as wire and substrate material
    properties and vibration characteristics of transducer and tool, variable model
    inputs are process parameters. Main simulation result is bonded area in the wiresubstrate
    contact. This model is then used to find valid and optimal working points before
    operation. The working point is composed of normal force and ultrasonic voltage
    trajectories, which are usually determined experimentally. Instead, multiobjective
    optimalization is used to compute trajectories that simultaneously optimize bond
    quality, process duration, tool wear and probability of tool-substrate contacts.
    The values of these objectives are computed using the process model. At runtime,
    selection among pre-determined optimal working points is sufficient to prioritize
    individual objectives. This way, the computationally expensive process of numerically
    solving a multiobjective optimal control problem and the demanding high speed
    bonding process are separated. To evaluate to what extent the pre-defined goals
    of self-optimization are met, an offthe- shelf heavy wire bonding machine was
    modified to allow for parameter adaptation and for transmitting of measurement
    data at runtime. This data is received by an external computer system and evaluated
    to select a new working point. Then, new process parameters are sent to the modified
    bonding machine for use for subsequent bonds. With these components, a full self-optimizing
    system has been implemented.
author:
- first_name: Tobias
  full_name: Meyer , Tobias
  last_name: 'Meyer '
- first_name: Andreas
  full_name: Unger, Andreas
  last_name: Unger
- first_name: Simon
  full_name: Althoff, Simon
  last_name: Althoff
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
- first_name: Michael
  full_name: Brökelmann, Michael
  last_name: Brökelmann
- first_name: Matthias
  full_name: Hunstig, Matthias
  last_name: Hunstig
- first_name: Karsten
  full_name: Guth, Karsten
  last_name: Guth
citation:
  ama: 'Meyer  T, Unger A, Althoff S, et al. Reliable Manufacturing of Heavy Copper
    Wire Bonds Using Online Parameter Adaptation. In: <i>IEEE 66th Electronic Components
    and Technology Conference</i>. ; 2016:622-628. doi:<a href="https://doi.org/10.1109/ECTC.2016.215">10.1109/ECTC.2016.215</a>'
  apa: Meyer , T., Unger, A., Althoff, S., Sextro, W., Brökelmann, M., Hunstig, M.,
    &#38; Guth, K. (2016). Reliable Manufacturing of Heavy Copper Wire Bonds Using
    Online Parameter Adaptation. In <i>IEEE 66th Electronic Components and Technology
    Conference</i> (pp. 622–628). <a href="https://doi.org/10.1109/ECTC.2016.215">https://doi.org/10.1109/ECTC.2016.215</a>
  bibtex: '@inproceedings{Meyer _Unger_Althoff_Sextro_Brökelmann_Hunstig_Guth_2016,
    title={Reliable Manufacturing of Heavy Copper Wire Bonds Using Online Parameter
    Adaptation}, DOI={<a href="https://doi.org/10.1109/ECTC.2016.215">10.1109/ECTC.2016.215</a>},
    booktitle={IEEE 66th Electronic Components and Technology Conference}, author={Meyer
    , Tobias and Unger, Andreas and Althoff, Simon and Sextro, Walter and Brökelmann,
    Michael and Hunstig, Matthias and Guth, Karsten}, year={2016}, pages={622–628}
    }'
  chicago: Meyer , Tobias, Andreas Unger, Simon Althoff, Walter Sextro, Michael Brökelmann,
    Matthias Hunstig, and Karsten Guth. “Reliable Manufacturing of Heavy Copper Wire
    Bonds Using Online Parameter Adaptation.” In <i>IEEE 66th Electronic Components
    and Technology Conference</i>, 622–28, 2016. <a href="https://doi.org/10.1109/ECTC.2016.215">https://doi.org/10.1109/ECTC.2016.215</a>.
  ieee: T. Meyer  <i>et al.</i>, “Reliable Manufacturing of Heavy Copper Wire Bonds
    Using Online Parameter Adaptation,” in <i>IEEE 66th Electronic Components and
    Technology Conference</i>, 2016, pp. 622–628.
  mla: Meyer , Tobias, et al. “Reliable Manufacturing of Heavy Copper Wire Bonds Using
    Online Parameter Adaptation.” <i>IEEE 66th Electronic Components and Technology
    Conference</i>, 2016, pp. 622–28, doi:<a href="https://doi.org/10.1109/ECTC.2016.215">10.1109/ECTC.2016.215</a>.
  short: 'T. Meyer , A. Unger, S. Althoff, W. Sextro, M. Brökelmann, M. Hunstig, K.
    Guth, in: IEEE 66th Electronic Components and Technology Conference, 2016, pp.
    622–628.'
date_created: 2019-05-27T09:17:26Z
date_updated: 2020-05-07T05:33:53Z
department:
- _id: '151'
doi: 10.1109/ECTC.2016.215
keyword:
- Self-optimization
- adaptive system
- bond process
- copper wire
language:
- iso: eng
page: 622-628
project:
- _id: '92'
  grant_number: 02 PQ2210
  name: Intelligente Herstellung zuverlässiger Kupferbondverbindungen
publication: IEEE 66th Electronic Components and Technology Conference
quality_controlled: '1'
status: public
title: Reliable Manufacturing of Heavy Copper Wire Bonds Using Online Parameter Adaptation
type: conference
user_id: '210'
year: '2016'
...
---
_id: '9868'
abstract:
- lang: eng
  text: In order to increase mechanical strength, heat dissipation and ampacity and
    to decrease failure through fatigue fracture, wedge copper wire bonding is being
    introduced as a standard interconnection method for mass production. To achieve
    the same process stability when using copper wire instead of aluminum wire a profound
    understanding of the bonding process is needed. Due to the higher hardness of
    copper compared to aluminum wire it is more difficult to approach the surfaces
    of wire and substrate to a level where van der Waals forces are able to arise
    between atoms. Also, enough friction energy referred to the total contact area
    has to be generated to activate the surfaces. Therefore, a friction model is used
    to simulate the joining process. This model calculates the resulting energy of
    partial areas in the contact surface and provides information about the adhesion
    process of each area. The focus here is on the arising of micro joints in the
    contact area depending on the location in the contact and time. To validate the
    model, different touchdown forces are used to vary the initial contact areas of
    wire and substrate. Additionally, a piezoelectric tri-axial force sensor is built
    up to identify the known phases of pre-deforming, cleaning, adhering and diffusing
    for the real bonding process to map with the model. Test substrates as DBC and
    copper plate are used to show the different formations of a wedge bond connection
    due to hardness and reaction propensity. The experiments were done by using 500
    $\mu$m copper wire and a standard V-groove tool.
author:
- first_name: Simon
  full_name: Althoff, Simon
  last_name: Althoff
- first_name: Jan
  full_name: Neuhaus, Jan
  last_name: Neuhaus
- first_name: Tobias
  full_name: Hemsel, Tobias
  id: '210'
  last_name: Hemsel
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
citation:
  ama: 'Althoff S, Neuhaus J, Hemsel T, Sextro W. Improving the bond quality of copper
    wire bonds using a friction model approach. In: <i>Electronic Components and Technology
    Conference (ECTC), 2014 IEEE 64th</i>. ; 2014:1549-1555. doi:<a href="https://doi.org/10.1109/ECTC.2014.6897500">10.1109/ECTC.2014.6897500</a>'
  apa: Althoff, S., Neuhaus, J., Hemsel, T., &#38; Sextro, W. (2014). Improving the
    bond quality of copper wire bonds using a friction model approach. In <i>Electronic
    Components and Technology Conference (ECTC), 2014 IEEE 64th</i> (pp. 1549–1555).
    <a href="https://doi.org/10.1109/ECTC.2014.6897500">https://doi.org/10.1109/ECTC.2014.6897500</a>
  bibtex: '@inproceedings{Althoff_Neuhaus_Hemsel_Sextro_2014, title={Improving the
    bond quality of copper wire bonds using a friction model approach}, DOI={<a href="https://doi.org/10.1109/ECTC.2014.6897500">10.1109/ECTC.2014.6897500</a>},
    booktitle={Electronic Components and Technology Conference (ECTC), 2014 IEEE 64th},
    author={Althoff, Simon and Neuhaus, Jan and Hemsel, Tobias and Sextro, Walter},
    year={2014}, pages={1549–1555} }'
  chicago: Althoff, Simon, Jan Neuhaus, Tobias Hemsel, and Walter Sextro. “Improving
    the Bond Quality of Copper Wire Bonds Using a Friction Model Approach.” In <i>Electronic
    Components and Technology Conference (ECTC), 2014 IEEE 64th</i>, 1549–55, 2014.
    <a href="https://doi.org/10.1109/ECTC.2014.6897500">https://doi.org/10.1109/ECTC.2014.6897500</a>.
  ieee: S. Althoff, J. Neuhaus, T. Hemsel, and W. Sextro, “Improving the bond quality
    of copper wire bonds using a friction model approach,” in <i>Electronic Components
    and Technology Conference (ECTC), 2014 IEEE 64th</i>, 2014, pp. 1549–1555.
  mla: Althoff, Simon, et al. “Improving the Bond Quality of Copper Wire Bonds Using
    a Friction Model Approach.” <i>Electronic Components and Technology Conference
    (ECTC), 2014 IEEE 64th</i>, 2014, pp. 1549–55, doi:<a href="https://doi.org/10.1109/ECTC.2014.6897500">10.1109/ECTC.2014.6897500</a>.
  short: 'S. Althoff, J. Neuhaus, T. Hemsel, W. Sextro, in: Electronic Components
    and Technology Conference (ECTC), 2014 IEEE 64th, 2014, pp. 1549–1555.'
date_created: 2019-05-20T12:11:44Z
date_updated: 2019-09-16T10:57:58Z
department:
- _id: '151'
doi: 10.1109/ECTC.2014.6897500
keyword:
- adhesion
- circuit reliability
- deformation
- diffusion
- fatigue cracks
- friction
- interconnections
- lead bonding
- van der Waals forces
- Cu
- adhering process
- adhesion process
- ampacity improvement
- bond quality improvement
- cleaning process
- diffusing process
- fatigue fracture failure
- friction energy
- friction model
- heat dissipation
- mechanical strength
- piezoelectric triaxial force sensor
- predeforming process
- size 500 mum
- total contact area
- van der Waals forces
- wedge copper wire bonding
- Bonding
- Copper
- Finite element analysis
- Force
- Friction
- Substrates
- Wires
language:
- iso: eng
page: 1549-1555
publication: Electronic Components and Technology Conference (ECTC), 2014 IEEE 64th
quality_controlled: '1'
status: public
title: Improving the bond quality of copper wire bonds using a friction model approach
type: conference
user_id: '55222'
year: '2014'
...
---
_id: '9870'
abstract:
- lang: eng
  text: Nowadays wire bonding is a widely-used technology for interconnecting chips
    in the packaging industry. Thereby, it is known that the bond quality massively
    depends upon the microstructure prevailing in the bond and consequently the materials
    used as well as the bonding parameters. However the actually used materials such
    as aluminum and gold are either characterized by comparibly poor conductivity
    or high costs, respectively. Due to its outstanding properties copper is a more
    attractive candidate. Still, a thorough investigation on the interrelationship
    between the material combinations, the processing parameters and the resulting
    microstructure for copper and aluminum wire bonding was not carried out yet. Depending
    on the aforementioned factors the microstructural evolution can be completely
    different during the bonding process. Therefore, this study focuses on the microstructural
    evolution of heavy copper and heavy aluminum wires bonded on copper substrates.
    The evolution of the wire microstructure as well as the wire-substrate-interface
    was investigated by scanning electron microscope in combination with electron
    backscatter diffraction and microhardness measurements. Various samples were extracted
    at different points of the bonding process, namely the as-received condition,
    after touchdown and after completed bonding. The results of the aluminum and copper
    wires were compared to each other in both longitudinal and transversal direction.
    It was found, that the two wire materials were completely different in the as-received
    condition regarding the grain size, the grain morphology, the texture and the
    microhardness. After touchdown the microstructure did not show significant changes
    in both materials, yet a strain-hardening was observed in the copper wire resulting
    from the touchdown force. When the bonding process was completed a different microstructure
    could be observed in both the wire as well as the layer for the materials investigated.
    Furthermore, a destinctive increase in the wire hardness could be found in case
    of copper, which was not observed for the aluminum wire. The ramifications between
    the two wire materials presented in this work will be discussed with the objective
    of optimizing the quality of the bonds.
author:
- first_name: Florian
  full_name: Eacock , Florian
  last_name: 'Eacock '
- first_name: Mirko
  full_name: Schaper, Mirko
  last_name: Schaper
- first_name: Simon
  full_name: Althoff, Simon
  last_name: Althoff
- first_name: Andreas
  full_name: Unger, Andreas
  last_name: Unger
- first_name: Paul
  full_name: Eichwald, Paul
  last_name: Eichwald
- first_name: Florian
  full_name: Hengsbach, Florian
  last_name: Hengsbach
- first_name: Carolin
  full_name: Zinn, Carolin
  last_name: Zinn
- first_name: ' Martin Joachim'
  full_name: Holzweissig,  Martin Joachim
  last_name: Holzweissig
- first_name: Karsten
  full_name: Guth, Karsten
  last_name: Guth
citation:
  ama: 'Eacock  F, Schaper M, Althoff S, et al. Microstructural investigations of
    aluminum and copper wire bonds. In: <i>Proceedings of the 47th International Symposium
    on Microelectronics</i>. ; 2014. doi:<a href="https://doi.org/10.4071/isom-THP32">10.4071/isom-THP32</a>'
  apa: Eacock , F., Schaper, M., Althoff, S., Unger, A., Eichwald, P., Hengsbach,
    F., … Guth, K. (2014). Microstructural investigations of aluminum and copper wire
    bonds. In <i>Proceedings of the 47th International Symposium on Microelectronics</i>.
    <a href="https://doi.org/10.4071/isom-THP32">https://doi.org/10.4071/isom-THP32</a>
  bibtex: '@inproceedings{Eacock _Schaper_Althoff_Unger_Eichwald_Hengsbach_Zinn_Holzweissig_Guth_2014,
    title={Microstructural investigations of aluminum and copper wire bonds}, DOI={<a
    href="https://doi.org/10.4071/isom-THP32">10.4071/isom-THP32</a>}, booktitle={Proceedings
    of the 47th International Symposium on Microelectronics}, author={Eacock , Florian
    and Schaper, Mirko and Althoff, Simon and Unger, Andreas and Eichwald, Paul and
    Hengsbach, Florian and Zinn, Carolin and Holzweissig,  Martin Joachim and Guth,
    Karsten}, year={2014} }'
  chicago: Eacock , Florian, Mirko Schaper, Simon Althoff, Andreas Unger, Paul Eichwald,
    Florian Hengsbach, Carolin Zinn,  Martin Joachim Holzweissig, and Karsten Guth.
    “Microstructural Investigations of Aluminum and Copper Wire Bonds.” In <i>Proceedings
    of the 47th International Symposium on Microelectronics</i>, 2014. <a href="https://doi.org/10.4071/isom-THP32">https://doi.org/10.4071/isom-THP32</a>.
  ieee: F. Eacock  <i>et al.</i>, “Microstructural investigations of aluminum and
    copper wire bonds,” in <i>Proceedings of the 47th International Symposium on Microelectronics</i>,
    2014.
  mla: Eacock , Florian, et al. “Microstructural Investigations of Aluminum and Copper
    Wire Bonds.” <i>Proceedings of the 47th International Symposium on Microelectronics</i>,
    2014, doi:<a href="https://doi.org/10.4071/isom-THP32">10.4071/isom-THP32</a>.
  short: 'F. Eacock , M. Schaper, S. Althoff, A. Unger, P. Eichwald, F. Hengsbach,
    C. Zinn,  Martin Joachim Holzweissig, K. Guth, in: Proceedings of the 47th International
    Symposium on Microelectronics, 2014.'
date_created: 2019-05-20T12:14:11Z
date_updated: 2019-09-16T10:58:50Z
department:
- _id: '151'
doi: 10.4071/isom-THP32
keyword:
- Bonding
- Copper
- Microstructure evolution
language:
- iso: eng
publication: Proceedings of the 47th International Symposium on Microelectronics
quality_controlled: '1'
status: public
title: Microstructural investigations of aluminum and copper wire bonds
type: conference
user_id: '55222'
year: '2014'
...
---
_id: '9871'
abstract:
- lang: eng
  text: 'Wire bonding is the most common technology for connecting electronic components.
    Due to their efficiency bond interconnections made of copper wire are used for
    example in the aerospace and medical technology as well as in the fields of renewable
    energies. One of the main cost factors in the manufacturing process is the consumables
    like bonding tools. The technological transition to copper as wire material causes
    significant wear on the millimeter large effective contact area of the bonding
    tool. This wear leads to a loss by a factor of 30 of the number of reliable interconnections
    which can be produced by a single tool. To reduce setting-up time in the production
    and minimizing costs, an enlarged bonding tool lifetime is desirable. Consequently
    a better understanding of wear and recognition of wear pattern is required. Therefore,
    the paper presents an analyzing method of the tool topography change of a heavy
    wire bonding tool by using a confocal microscope. Furthermore, the paper discusses
    the identification of the main wear indicators by the help of the named topography
    change for different bond parameters, like ultrasonic power and tool geometry.
    Reference topography has been carried out by choosing typical parameters of the
    production line. To judge whether the quality requirement of the bond connections
    made by a single tool cannot be fulfilled shear test of the source bond have been
    carried out after a defined number of produced bond connections. Main steps of
    analysis: (I)Topography of the tool surface is sampled after a defined number
    of bonds by means of a confocal microscope to detect the wear progress.(II)The
    recorded data is filtered using Matlab. So, measurement errors can be eliminated
    and the topography can be overlaid more easy to identify differences between diverse
    tools or differences in wear stages of the same tool.(III)The subsequent discretization
    of the topography into sub volumes allows to (IV)describe the loss of volume depending
    on the position in the groove. Thereby, intermediate status of wear of one tool
    can be used to obtain a persistent description of the topography change over the
    number of produced bonds by interpolating the confocal data. Afterwards the persistent
    change of the groove flank has been analyzed for the named test series to identify
    the main wear indicators and their effect on shear forces. All worn tools show
    dominant areas for volume loss especially for plastic deformation and accordingly
    abrasion. These wear mechanism can be referred to the change of main parts of
    the groove geometry like the rounding of the front and back radius. The most volume
    loss was identified in the upper part of the tool flanks or rather at the transition
    from the groove flank to the front or back radius. Furthermore the observation
    of the center of the groove flank shows just a little change in volume. All in
    all, the identification of the wear indicators will be discussed with the objective
    of increasing the tool lifetime by optimizing the tool geometry without losses
    in bond quality and reliability.'
author:
- first_name: Paul
  full_name: Eichwald, Paul
  last_name: Eichwald
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
- first_name: Simon
  full_name: Althof, Simon
  last_name: Althof
- first_name: Florian
  full_name: Eacock, Florian
  last_name: Eacock
- first_name: Andreas
  full_name: Unger, Andreas
  last_name: Unger
- first_name: Tobias
  full_name: Meyer, Tobias
  last_name: Meyer
- first_name: Karsten
  full_name: Guth, Karsten
  last_name: Guth
citation:
  ama: 'Eichwald P, Sextro W, Althof S, et al. Analysis Method of Tool Topography
    Change and Identification of Wear Indicators for Heavy Copper Wire Wedge Bonding.
    In: <i>Proceedings of the 47th International Symposium on Microelectronics</i>.
    ; 2014:856-861. doi:<a href="https://doi.org/10.4071/isom-THP34">10.4071/isom-THP34</a>'
  apa: Eichwald, P., Sextro, W., Althof, S., Eacock, F., Unger, A., Meyer, T., &#38;
    Guth, K. (2014). Analysis Method of Tool Topography Change and Identification
    of Wear Indicators for Heavy Copper Wire Wedge Bonding. In <i>Proceedings of the
    47th International Symposium on Microelectronics</i> (pp. 856–861). <a href="https://doi.org/10.4071/isom-THP34">https://doi.org/10.4071/isom-THP34</a>
  bibtex: '@inproceedings{Eichwald_Sextro_Althof_Eacock_Unger_Meyer_Guth_2014, title={Analysis
    Method of Tool Topography Change and Identification of Wear Indicators for Heavy
    Copper Wire Wedge Bonding}, DOI={<a href="https://doi.org/10.4071/isom-THP34">10.4071/isom-THP34</a>},
    booktitle={Proceedings of the 47th International Symposium on Microelectronics},
    author={Eichwald, Paul and Sextro, Walter and Althof, Simon and Eacock, Florian
    and Unger, Andreas and Meyer, Tobias and Guth, Karsten}, year={2014}, pages={856–861}
    }'
  chicago: Eichwald, Paul, Walter Sextro, Simon Althof, Florian Eacock, Andreas Unger,
    Tobias Meyer, and Karsten Guth. “Analysis Method of Tool Topography Change and
    Identification of Wear Indicators for Heavy Copper Wire Wedge Bonding.” In <i>Proceedings
    of the 47th International Symposium on Microelectronics</i>, 856–61, 2014. <a
    href="https://doi.org/10.4071/isom-THP34">https://doi.org/10.4071/isom-THP34</a>.
  ieee: P. Eichwald <i>et al.</i>, “Analysis Method of Tool Topography Change and
    Identification of Wear Indicators for Heavy Copper Wire Wedge Bonding,” in <i>Proceedings
    of the 47th International Symposium on Microelectronics</i>, 2014, pp. 856–861.
  mla: Eichwald, Paul, et al. “Analysis Method of Tool Topography Change and Identification
    of Wear Indicators for Heavy Copper Wire Wedge Bonding.” <i>Proceedings of the
    47th International Symposium on Microelectronics</i>, 2014, pp. 856–61, doi:<a
    href="https://doi.org/10.4071/isom-THP34">10.4071/isom-THP34</a>.
  short: 'P. Eichwald, W. Sextro, S. Althof, F. Eacock, A. Unger, T. Meyer, K. Guth,
    in: Proceedings of the 47th International Symposium on Microelectronics, 2014,
    pp. 856–861.'
date_created: 2019-05-20T12:18:55Z
date_updated: 2020-05-07T05:33:45Z
department:
- _id: '151'
doi: 10.4071/isom-THP34
keyword:
- wedge/wedge bonding
- copper wire
- tool wear
language:
- iso: eng
page: 856-861
project:
- _id: '92'
  grant_number: 02 PQ2210
  name: Intelligente Herstellung zuverlässiger Kupferbondverbindungen
publication: Proceedings of the 47th International Symposium on Microelectronics
status: public
title: Analysis Method of Tool Topography Change and Identification of Wear Indicators
  for Heavy Copper Wire Wedge Bonding
type: conference
user_id: '210'
year: '2014'
...
---
_id: '9895'
abstract:
- lang: eng
  text: Power semiconductor modules are used to control and switch high electrical
    currents and voltages. Within the power module package wire bonding is used as
    an interconnection technology. In recent years, aluminum wire has been used preferably,
    but an ever-growing market of powerful and efficient power modules requires a
    material with better mechanical and electrical properties. For this reason, a
    technology change from aluminum to copper is indispensable. However, the copper
    wire bonding process reacts more sensitive to parameter changes. This makes manufacturing
    reliable copper bond connections a challenging task. The aim of the BMBF funded
    project Itsowl-InCuB is the development of self-optimizing techniques to enable
    the reliable production of copper bond connections under varying conditions. A
    model of the process is essential to achieve this aim. This model needs to include
    the dynamic elasto-plastic deformation, the ultrasonic softening effect and the
    proceeding adhesion between wire and substrate. This paper focusses on the pre-deformation
    process. In the touchdown phase, the wire is pressed into the V-groove of the
    tool and a small initial contact area between wire and substrate arise. The local
    characteristics of the material change abruptly because of the cold forming. Consequently,
    the pre-deformation has a strong effect on the joining process. In [1], a pre-cleaning
    effect during the touchdown process of aluminum wires by cracking of oxide layers
    was presented. These interactions of the process parameters are still largely
    unknown for copper. In a first step, this paper validates the importance of modeling
    the pre-deformation by showing its impact on the wire deformation characteristic
    experimentally. Creating cross-section views of pre-deformed copper wires has
    shown a low deformation degree compared to aluminum. By using a digital microscope
    and a scanning confocal microscope an analysis about the contact areas and penetration
    depths after touchdown has been made. Additionally, it has to be taken into account
    that the dynamical touchdown force depends on the touchdown speed and the touchdown
    force set in the bonding machine. In order to measure the overshoot in the force
    signals, a strain gauge sensor has been used. Subsequently, the affecting factors
    have been interpreted independently Furthermore, the material properties of copper
    wire have been investigated with tensile tests and hardness measurements. In a
    second step, the paper presents finite element models of the touchdown process
    for source and destination bonds. These models take the measured overshoot in
    the touchdown forces into account. A multi-linear, isotropic material model has
    been selected to map the material properties of the copper. A validation of the
    model with the experimental determined contact areas, normal pressures and penetration
    depths reveals the high model quality. Thus, the simulation is able to calculate
    and visualize the three dimensional pre-deformation with an integrated material
    parameter of the wire if the touchdown parameters of the bonding machine are known.
    Based on the calculated deformation degrees of wire and substrate, it is probably
    possible to investigate the effect of the pre-deformation on the pre-cleaning
    phase in the copper wire bonding.
author:
- first_name: Andreas
  full_name: Unger, Andreas
  last_name: Unger
- first_name: Walter
  full_name: Sextro, Walter
  id: '21220'
  last_name: Sextro
- first_name: Simon
  full_name: Althoff, Simon
  last_name: Althoff
- first_name: Paul
  full_name: Eichwald, Paul
  last_name: Eichwald
- first_name: Tobias
  full_name: Meyer, Tobias
  last_name: Meyer
- first_name: Florian
  full_name: Eacock, Florian
  last_name: Eacock
- first_name: Michael
  full_name: Brökelmann, Michael
  last_name: Brökelmann
citation:
  ama: 'Unger A, Sextro W, Althoff S, et al. Experimental and Numerical Simulation
    Study of Pre-Deformed Heavy Copper Wire Wedge Bonds. In: <i>Proceedings of the
    47th International Symposium on Microelectronics (IMAPS)</i>. San Diego, CA, US;
    2014:289-294.'
  apa: Unger, A., Sextro, W., Althoff, S., Eichwald, P., Meyer, T., Eacock, F., &#38;
    Brökelmann, M. (2014). Experimental and Numerical Simulation Study of Pre-Deformed
    Heavy Copper Wire Wedge Bonds. In <i>Proceedings of the 47th International Symposium
    on Microelectronics (IMAPS)</i> (pp. 289–294). San Diego, CA, US.
  bibtex: '@inproceedings{Unger_Sextro_Althoff_Eichwald_Meyer_Eacock_Brökelmann_2014,
    place={San Diego, CA, US}, title={Experimental and Numerical Simulation Study
    of Pre-Deformed Heavy Copper Wire Wedge Bonds}, booktitle={Proceedings of the
    47th International Symposium on Microelectronics (IMAPS)}, author={Unger, Andreas
    and Sextro, Walter and Althoff, Simon and Eichwald, Paul and Meyer, Tobias and
    Eacock, Florian and Brökelmann, Michael}, year={2014}, pages={289–294} }'
  chicago: Unger, Andreas, Walter Sextro, Simon Althoff, Paul Eichwald, Tobias Meyer,
    Florian Eacock, and Michael Brökelmann. “Experimental and Numerical Simulation
    Study of Pre-Deformed Heavy Copper Wire Wedge Bonds.” In <i>Proceedings of the
    47th International Symposium on Microelectronics (IMAPS)</i>, 289–94. San Diego,
    CA, US, 2014.
  ieee: A. Unger <i>et al.</i>, “Experimental and Numerical Simulation Study of Pre-Deformed
    Heavy Copper Wire Wedge Bonds,” in <i>Proceedings of the 47th International Symposium
    on Microelectronics (IMAPS)</i>, 2014, pp. 289–294.
  mla: Unger, Andreas, et al. “Experimental and Numerical Simulation Study of Pre-Deformed
    Heavy Copper Wire Wedge Bonds.” <i>Proceedings of the 47th International Symposium
    on Microelectronics (IMAPS)</i>, 2014, pp. 289–94.
  short: 'A. Unger, W. Sextro, S. Althoff, P. Eichwald, T. Meyer, F. Eacock, M. Brökelmann,
    in: Proceedings of the 47th International Symposium on Microelectronics (IMAPS),
    San Diego, CA, US, 2014, pp. 289–294.'
date_created: 2019-05-20T13:35:09Z
date_updated: 2020-05-07T05:33:47Z
department:
- _id: '151'
keyword:
- pre-deformation
- copper wire bonding
- finite element model
language:
- iso: eng
page: 289-294
place: San Diego, CA, US
project:
- _id: '92'
  grant_number: 02 PQ2210
  name: Intelligente Herstellung zuverlässiger Kupferbondverbindungen
publication: Proceedings of the 47th International Symposium on Microelectronics (IMAPS)
status: public
title: Experimental and Numerical Simulation Study of Pre-Deformed Heavy Copper Wire
  Wedge Bonds
type: conference
user_id: '210'
year: '2014'
...
---
_id: '4548'
abstract:
- lang: eng
  text: "A fluorescence study of acetonitrile solutions of bis(tetramethylguanidine)propane,
    copper(I)-iodide and [Cu(btmgp)I] was performed and the chemical reaction of the
    latter species with O2 was investigated at room temperature. The actual quenching
    process via O2 gassing was studied and an exponential dependence of the fluorescence
    intensity with respect to the complex concentration was observed.\r\nFurthermore
    the survey was deepened on time resolved fluorescence properties of solved [Cu(btmgp)I]
    in a wider concentration range. The applicability of this complex for O2 sensing
    inside a microreactor system was proven by confocal fluorescence measurements.
    It was shown that the investigated system can be used for oxygen sensing in the
    copper concentration range from 10−2 to 10−9 mol/l."
article_type: original
author:
- first_name: Sonja
  full_name: Herres-Pawlis, Sonja
  last_name: Herres-Pawlis
- first_name: Gerhard
  full_name: Berth, Gerhard
  id: '53'
  last_name: Berth
- first_name: Volker
  full_name: Wiedemeier, Volker
  last_name: Wiedemeier
- first_name: Ludger
  full_name: Schmidt, Ludger
  last_name: Schmidt
- first_name: Artur
  full_name: Zrenner, Artur
  id: '606'
  last_name: Zrenner
  orcid: 0000-0002-5190-0944
- first_name: Hans-Joachim
  full_name: Warnecke, Hans-Joachim
  last_name: Warnecke
citation:
  ama: Herres-Pawlis S, Berth G, Wiedemeier V, Schmidt L, Zrenner A, Warnecke H-J.
    Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]. <i>Journal of Luminescence</i>.
    2010;130(10):1958-1962. doi:<a href="https://doi.org/10.1016/j.jlumin.2010.05.012">10.1016/j.jlumin.2010.05.012</a>
  apa: Herres-Pawlis, S., Berth, G., Wiedemeier, V., Schmidt, L., Zrenner, A., &#38;
    Warnecke, H.-J. (2010). Oxygen sensing by fluorescence quenching of [Cu(btmgp)I].
    <i>Journal of Luminescence</i>, <i>130</i>(10), 1958–1962. <a href="https://doi.org/10.1016/j.jlumin.2010.05.012">https://doi.org/10.1016/j.jlumin.2010.05.012</a>
  bibtex: '@article{Herres-Pawlis_Berth_Wiedemeier_Schmidt_Zrenner_Warnecke_2010,
    title={Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]}, volume={130},
    DOI={<a href="https://doi.org/10.1016/j.jlumin.2010.05.012">10.1016/j.jlumin.2010.05.012</a>},
    number={10}, journal={Journal of Luminescence}, publisher={Elsevier BV}, author={Herres-Pawlis,
    Sonja and Berth, Gerhard and Wiedemeier, Volker and Schmidt, Ludger and Zrenner,
    Artur and Warnecke, Hans-Joachim}, year={2010}, pages={1958–1962} }'
  chicago: 'Herres-Pawlis, Sonja, Gerhard Berth, Volker Wiedemeier, Ludger Schmidt,
    Artur Zrenner, and Hans-Joachim Warnecke. “Oxygen Sensing by Fluorescence Quenching
    of [Cu(Btmgp)I].” <i>Journal of Luminescence</i> 130, no. 10 (2010): 1958–62.
    <a href="https://doi.org/10.1016/j.jlumin.2010.05.012">https://doi.org/10.1016/j.jlumin.2010.05.012</a>.'
  ieee: S. Herres-Pawlis, G. Berth, V. Wiedemeier, L. Schmidt, A. Zrenner, and H.-J.
    Warnecke, “Oxygen sensing by fluorescence quenching of [Cu(btmgp)I],” <i>Journal
    of Luminescence</i>, vol. 130, no. 10, pp. 1958–1962, 2010.
  mla: Herres-Pawlis, Sonja, et al. “Oxygen Sensing by Fluorescence Quenching of [Cu(Btmgp)I].”
    <i>Journal of Luminescence</i>, vol. 130, no. 10, Elsevier BV, 2010, pp. 1958–62,
    doi:<a href="https://doi.org/10.1016/j.jlumin.2010.05.012">10.1016/j.jlumin.2010.05.012</a>.
  short: S. Herres-Pawlis, G. Berth, V. Wiedemeier, L. Schmidt, A. Zrenner, H.-J.
    Warnecke, Journal of Luminescence 130 (2010) 1958–1962.
date_created: 2018-09-20T12:31:16Z
date_updated: 2022-01-06T07:01:09Z
department:
- _id: '15'
- _id: '230'
- _id: '35'
doi: 10.1016/j.jlumin.2010.05.012
intvolume: '       130'
issue: '10'
keyword:
- Copper Oxygen Fluorescence quenching N donor ligands
language:
- iso: eng
page: 1958-1962
publication: Journal of Luminescence
publication_identifier:
  issn:
  - 0022-2313
publication_status: published
publisher: Elsevier BV
status: public
title: Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]
type: journal_article
user_id: '49428'
volume: 130
year: '2010'
...
