[{"publication_identifier":{"issn":["1615-4150","1615-4169"]},"publication_status":"published","citation":{"bibtex":"@article{Medvaric_Paradies_Werner_2025, title={Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides}, DOI={<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>}, number={202500394}, journal={Advanced Synthesis and Catalysis}, publisher={Wiley}, author={Medvaric, Viktorija and Paradies, Jan and Werner, Thomas}, year={2025} }","mla":"Medvaric, Viktorija, et al. “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis and Catalysis</i>, 202500394, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>.","short":"V. Medvaric, J. Paradies, T. Werner, Advanced Synthesis and Catalysis (2025).","apa":"Medvaric, V., Paradies, J., &#38; Werner, T. (2025). Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis and Catalysis</i>, Article 202500394. <a href=\"https://doi.org/10.1002/adsc.70059\">https://doi.org/10.1002/adsc.70059</a>","ama":"Medvaric V, Paradies J, Werner T. Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides. <i>Advanced Synthesis and Catalysis</i>. Published online 2025. doi:<a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>","ieee":"V. Medvaric, J. Paradies, and T. Werner, “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides,” <i>Advanced Synthesis and Catalysis</i>, Art. no. 202500394, 2025, doi: <a href=\"https://doi.org/10.1002/adsc.70059\">10.1002/adsc.70059</a>.","chicago":"Medvaric, Viktorija, Jan Paradies, and Thomas Werner. “Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides.” <i>Advanced Synthesis and Catalysis</i>, 2025. <a href=\"https://doi.org/10.1002/adsc.70059\">https://doi.org/10.1002/adsc.70059</a>."},"year":"2025","author":[{"last_name":"Medvaric","id":"92677","full_name":"Medvaric, Viktorija","first_name":"Viktorija"},{"first_name":"Jan","orcid":"0000-0002-3698-668X","last_name":"Paradies","full_name":"Paradies, Jan","id":"53339"},{"id":"89271","full_name":"Werner, Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","first_name":"Thomas"}],"date_created":"2025-09-17T15:16:49Z","date_updated":"2025-11-10T08:44:04Z","publisher":"Wiley","doi":"10.1002/adsc.70059","title":"Synthesis of Amidines Via P(III)/P(V)=O Redox Catalyzed In Situ Formation of Imidoyl Chlorides From Amides","publication":"Advanced Synthesis and Catalysis","type":"journal_article","status":"public","abstract":[{"text":"<jats:p>Amidines are a ubiquitous class of bioactive compounds found in a wide variety of natural products; thus, efficient strategies for their preparation are in great demand. Herein, a novel protocol is reported for the synthesis of amidines based on P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O redox catalysis. This two‐step, one‐pot approach involves the activation of amides via P<jats:sup>III</jats:sup>/P<jats:sup>V</jats:sup>O catalyzed in situ formation of imidoyl chloride intermediates which are directly converted upon reaction with amines into the corresponding amidines. Instead of traditionally used toxic and corrosive chloride sources, hexachloroacetone (HCA) is successfully employed as a halide source. The reaction proceeds with low catalyst loading (2 mol%) in BuOAc as the solvent. Under the optimized conditions, 20 amidines are prepared in yields up to 99%. A feasible mechanism is proposed based on experimental results. The synthetic potential of this method is evaluated in the preparation of the tyrosine kinase inhibitor (TKI) Erlotinib.</jats:p>","lang":"eng"}],"department":[{"_id":"2"},{"_id":"389"}],"user_id":"89271","_id":"61335","language":[{"iso":"eng"}],"keyword":["T2","T","CSSD"],"article_number":"202500394"},{"year":"2010","citation":{"chicago":"Liebscher, Grit, Jennifer Dailey-O’Cain, Mareike Müller, and Tetyana Reichert. “Negotiating Identities through Pronouns of Address in an Immigrant Community.” <i>Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA)</i> 20, no. 3 (2010): 375–400. <a href=\"https://doi.org/10.1075/prag.20.3.04lie\">https://doi.org/10.1075/prag.20.3.04lie</a>.","ieee":"G. Liebscher, J. Dailey-O’Cain, M. Müller, and T. Reichert, “Negotiating identities through pronouns of address in an immigrant community,” <i>Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA)</i>, vol. 20, no. 3, pp. 375–400, 2010, doi: <a href=\"https://doi.org/10.1075/prag.20.3.04lie\">10.1075/prag.20.3.04lie</a>.","ama":"Liebscher G, Dailey-O’Cain J, Müller M, Reichert T. Negotiating identities through pronouns of address in an immigrant community. <i>Pragmatics Quarterly Publication of the International Pragmatics Association (IPrA)</i>. 2010;20(3):375-400. doi:<a href=\"https://doi.org/10.1075/prag.20.3.04lie\">10.1075/prag.20.3.04lie</a>","apa":"Liebscher, G., Dailey-O’Cain, J., Müller, M., &#38; Reichert, T. (2010). Negotiating identities through pronouns of address in an immigrant community. <i>Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA)</i>, <i>20</i>(3), 375–400. <a href=\"https://doi.org/10.1075/prag.20.3.04lie\">https://doi.org/10.1075/prag.20.3.04lie</a>","short":"G. Liebscher, J. Dailey-O’Cain, M. Müller, T. Reichert, Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA) 20 (2010) 375–400.","bibtex":"@article{Liebscher_Dailey-O’Cain_Müller_Reichert_2010, title={Negotiating identities through pronouns of address in an immigrant community}, volume={20}, DOI={<a href=\"https://doi.org/10.1075/prag.20.3.04lie\">10.1075/prag.20.3.04lie</a>}, number={3}, journal={Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA)}, author={Liebscher, Grit and Dailey-O’Cain, Jennifer and Müller, Mareike and Reichert, Tetyana}, year={2010}, pages={375–400} }","mla":"Liebscher, Grit, et al. “Negotiating Identities through Pronouns of Address in an Immigrant Community.” <i>Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA)</i>, vol. 20, no. 3, 2010, pp. 375–400, doi:<a href=\"https://doi.org/10.1075/prag.20.3.04lie\">10.1075/prag.20.3.04lie</a>."},"page":"375-400","intvolume":"        20","publication_status":"published","publication_identifier":{"issn":["1018-2101","2406-4238"]},"issue":"3","title":"Negotiating identities through pronouns of address in an immigrant community","doi":"10.1075/prag.20.3.04lie","date_updated":"2022-01-06T06:58:05Z","date_created":"2021-12-08T14:38:18Z","author":[{"first_name":"Grit","full_name":"Liebscher, Grit","last_name":"Liebscher"},{"full_name":"Dailey-O’Cain, Jennifer","last_name":"Dailey-O’Cain","first_name":"Jennifer"},{"id":"71540","full_name":"Müller, Mareike","last_name":"Müller","first_name":"Mareike"},{"first_name":"Tetyana","full_name":"Reichert, Tetyana","last_name":"Reichert"}],"volume":20,"abstract":[{"lang":"eng","text":"This article investigates forms of address, in particular the T/V distinction in German, in conversational interviews with German-speaking immigrants to English-speaking Canada and their descendants. From among 77 interviews conducted in two urban areas in Canada, we discuss instances of both the interactional use of and metalinguistic comments on forms of address. Our analysis is largely guided by conversation analysis and interactional sociolinguistics (e.g. Goodwin & Heritage 1990). Using Clyne, Norrby and Warren’s (2009) model of address as a backdrop, we investigate the construction of group identity and group socialization through the lens of positioning theory (e.g. van Langenhove & Harré 1993; Dailey-O’Cain & Liebscher 2009). This combination of analytical tools can explain shifts in both usage of and attitudes toward the T/V distinction that cannot be explained through language attrition arguments alone."}],"status":"public","type":"journal_article","publication":"Pragmatics. Quarterly Publication of the International Pragmatics Association (IPrA)","article_type":"original","keyword":["Forms of address","T/V distinction","Du vs. Sie","Conversation analysis","Language attitudes","Interviews","German in Canada","Migration studies","North American migration"],"extern":"1","language":[{"iso":"eng"}],"_id":"28449","user_id":"71540","department":[{"_id":"468"}]},{"status":"public","abstract":[{"text":"Am Beispiel bolivianischer Migrantinnen in der Global City Buenos Aires wird das Phänomen der Feminisierung der Migration in Lateinamerika und dessen Bedeutung für die Konstitution translokaler sozialer Räume untersucht. Im Mittelpunkt einer {\\glq}dichten Beschreibung’ pluri-lokaler Alltagswelten stehen dabei ökonomische Netzwerke und translokale Lebensentwürfe von Arbeiterinnen in illegalen Textilsweatshops und Frauen der Töchtergeneration. Analysiert werden einerseits die alltagsweltlichen sozialen Praktiken von Migrantinnen, die zu einer Kon-stitution eines translokalen und kulturell hybriden Raumes zwischen den beiden Nationalgesell-schaften Bolivien und Argentinien Raumes beitragen und andererseits Prozesse und Dynamiken der Neuaushandlung von ethnischen Identitäten in einem solchen Raum. Probing into the lives of female Bolivian migrants in the global city Buenos Aires, this empirical research explores feminisation of migration in Latin America analysing its significance for the constitution of translocal social spaces. Applying {\\grq}thick description’ to the migrants’ pluri-local life worlds, the study closely examines how Bolivian women in Buenos Aires, partly working in illegal sweatshops and partly second generation migrants, establish economic networks and set up their translocal life plans. Thus the analysis of the migrants’ everyday social practices, such as work and leisure, yields insight not only into the constitution of a translocal and cultur-ally hybrid social space between the two countries, but also into dynamics of re-negotiation of ethnic identities within this space.","lang":"eng"}],"type":"book","language":[{"iso":"eng"}],"extern":"1","keyword":["Alltag","Bolivianische Einwanderin","Buenos Aires","Ethnizität"],"department":[{"_id":"476"}],"user_id":"97205","_id":"41634","citation":{"ama":"Spiegel A. <i>Alltagswelten in Translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires</i>. IKO; 2005.","ieee":"A. Spiegel, <i>Alltagswelten in translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires</i>. IKO, 2005.","chicago":"Spiegel, Anna. <i>Alltagswelten in Translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires</i>. IKO, 2005.","mla":"Spiegel, Anna. <i>Alltagswelten in Translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires</i>. IKO, 2005.","bibtex":"@book{Spiegel_2005, title={Alltagswelten in translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires}, publisher={IKO}, author={Spiegel, Anna}, year={2005} }","short":"A. Spiegel, Alltagswelten in Translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires, IKO, 2005.","apa":"Spiegel, A. (2005). <i>Alltagswelten in translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires</i>. IKO."},"year":"2005","publication_identifier":{"isbn":["3-88939-764-6"]},"title":"Alltagswelten in translokalen Räumen : Bolivianische Migrantinnen in Buenos Aires","author":[{"first_name":"Anna","last_name":"Spiegel","orcid":"0000-0002-4326-8141","full_name":"Spiegel, Anna","id":"97205"}],"date_created":"2023-02-03T12:36:17Z","date_updated":"2023-02-06T11:29:34Z","publisher":"IKO"}]