---
_id: '63970'
abstract:
- lang: eng
  text: Abstract Recent advances in solid-state nuclear magnetic resonance (NMR) spectroscopy,
    combined with dynamic nuclear polarization (DNP), quantum chemical DFT calculations,
    and gas-phase NMR spectroscopy investigating the structure and reactivity of heterogeneous
    catalysts are reviewed. The investigated catalysts range from classical mononuclear
    catalysts, like immobilized derivates of Wilkinson’s catalysts over binuclear
    catalysts such as the dirhodium paddlewheel catalyst to catalytic nanoparticles,
    employing various support materials, such as mesoporous silica gels, coordination
    polymers, and biomaterials such as cellulose.
author:
- first_name: Nadia
  full_name: Haro Mares, Nadia
  last_name: Haro Mares
- first_name: Millena
  full_name: Logrado, Millena
  last_name: Logrado
- first_name: Jan
  full_name: Kergassner, Jan
  last_name: Kergassner
- first_name: Bingyu
  full_name: Zhang, Bingyu
  last_name: Zhang
- first_name: Torsten
  full_name: Gutmann, Torsten
  id: '118165'
  last_name: Gutmann
- first_name: Gerd
  full_name: Buntkowsky, Gerd
  last_name: Buntkowsky
citation:
  ama: Haro Mares N, Logrado M, Kergassner J, Zhang B, Gutmann T, Buntkowsky G. Solid-State
    NMR of Heterogeneous Catalysts. <i>ChemCatChem</i>. Published online 2024:e202401159.
    doi:<a href="https://doi.org/10.1002/cctc.202401159">10.1002/cctc.202401159</a>
  apa: Haro Mares, N., Logrado, M., Kergassner, J., Zhang, B., Gutmann, T., &#38;
    Buntkowsky, G. (2024). Solid-State NMR of Heterogeneous Catalysts. <i>ChemCatChem</i>,
    e202401159. <a href="https://doi.org/10.1002/cctc.202401159">https://doi.org/10.1002/cctc.202401159</a>
  bibtex: '@article{Haro Mares_Logrado_Kergassner_Zhang_Gutmann_Buntkowsky_2024, title={Solid-State
    NMR of Heterogeneous Catalysts}, DOI={<a href="https://doi.org/10.1002/cctc.202401159">10.1002/cctc.202401159</a>},
    journal={ChemCatChem}, publisher={John Wiley &#38; Sons, Ltd}, author={Haro Mares,
    Nadia and Logrado, Millena and Kergassner, Jan and Zhang, Bingyu and Gutmann,
    Torsten and Buntkowsky, Gerd}, year={2024}, pages={e202401159} }'
  chicago: Haro Mares, Nadia, Millena Logrado, Jan Kergassner, Bingyu Zhang, Torsten
    Gutmann, and Gerd Buntkowsky. “Solid-State NMR of Heterogeneous Catalysts.” <i>ChemCatChem</i>,
    2024, e202401159. <a href="https://doi.org/10.1002/cctc.202401159">https://doi.org/10.1002/cctc.202401159</a>.
  ieee: 'N. Haro Mares, M. Logrado, J. Kergassner, B. Zhang, T. Gutmann, and G. Buntkowsky,
    “Solid-State NMR of Heterogeneous Catalysts,” <i>ChemCatChem</i>, p. e202401159,
    2024, doi: <a href="https://doi.org/10.1002/cctc.202401159">10.1002/cctc.202401159</a>.'
  mla: Haro Mares, Nadia, et al. “Solid-State NMR of Heterogeneous Catalysts.” <i>ChemCatChem</i>,
    John Wiley &#38; Sons, Ltd, 2024, p. e202401159, doi:<a href="https://doi.org/10.1002/cctc.202401159">10.1002/cctc.202401159</a>.
  short: N. Haro Mares, M. Logrado, J. Kergassner, B. Zhang, T. Gutmann, G. Buntkowsky,
    ChemCatChem (2024) e202401159.
date_created: 2026-02-07T15:40:38Z
date_updated: 2026-02-17T16:17:30Z
doi: 10.1002/cctc.202401159
extern: '1'
keyword:
- solid-state nmr
- heterogeneous catalysis
- dynamic nuclear polarization
- Nanocatalysis
- Surface-reactions
language:
- iso: eng
page: e202401159
publication: ChemCatChem
publication_identifier:
  issn:
  - 1867-3880
publisher: John Wiley & Sons, Ltd
status: public
title: Solid-State NMR of Heterogeneous Catalysts
type: journal_article
user_id: '100715'
year: '2024'
...
---
_id: '63960'
abstract:
- lang: eng
  text: Recent advances in solid-state nuclear magnetic resonance (NMR) spectroscopy
    and dynamic nuclear polarization (DNP) of nanostructured materials are reviewed.
    A first group of materials is based on crystalline nanocellulose (CNC) or microcrystalline
    cellulose (MCC), which are used as carrier materials for dye molecules, catalysts
    or in combination with heterocyclic molecules as ion conducting membranes. These
    materials have widespread applications in sensorics, optics, catalysis or fuel
    cell research. A second group are metal oxides such as V-Mo-W oxides, which are
    of enormous importance in the manufacturing process of basic chemicals. The third
    group are catalytically active nanocrystalline metal nanoparticles, coated with
    protectants or embedded in polymers. The last group includes of lead-free perovskite
    materials, which are employed as environmentally benign substitution materials
    for conventional lead-based electronics materials. These materials are discussed
    in terms of their application and physico-chemical characterization by solid-state
    NMR techniques, combined with gas-phase NMR and quantum-chemical modelling on
    the density functional theory (DFT) level. The application of multinuclear 1H,
    2H, 13C, 15N and 23Na solid state NMR techniques under static or MAS conditions
    for the characterization of these materials, their surfaces and processes on their
    surfaces is discussed. Moreover, the analytic power of the combination of these
    techniques with DNP for the identification of low-concentrated carbon and nitrogen
    containing surface species in natural abundance is reviewed. Finally, approaches
    for sensitivity enhancement by DNP of quadrupolar nuclei such as 17O and 51V are
    presented that enable the identification of catalytic sites in metal oxide catalysts.
author:
- first_name: Torsten
  full_name: Gutmann, Torsten
  id: '118165'
  last_name: Gutmann
- first_name: Pedro B.
  full_name: Groszewicz, Pedro B.
  last_name: Groszewicz
- first_name: Gerd
  full_name: Buntkowsky, Gerd
  last_name: Buntkowsky
citation:
  ama: Gutmann T, Groszewicz PB, Buntkowsky G. Solid-state NMR of nanocrystals. <i>Annual
    Reports on NMR Spectroscopy</i>. 2019;97:1–82. doi:<a href="https://doi.org/10.1016/bs.arnmr.2018.12.001">10.1016/bs.arnmr.2018.12.001</a>
  apa: Gutmann, T., Groszewicz, P. B., &#38; Buntkowsky, G. (2019). Solid-state NMR
    of nanocrystals. <i>Annual Reports on NMR Spectroscopy</i>, <i>97</i>, 1–82. <a
    href="https://doi.org/10.1016/bs.arnmr.2018.12.001">https://doi.org/10.1016/bs.arnmr.2018.12.001</a>
  bibtex: '@article{Gutmann_Groszewicz_Buntkowsky_2019, title={Solid-state NMR of
    nanocrystals}, volume={97}, DOI={<a href="https://doi.org/10.1016/bs.arnmr.2018.12.001">10.1016/bs.arnmr.2018.12.001</a>},
    journal={Annual Reports on NMR Spectroscopy}, author={Gutmann, Torsten and Groszewicz,
    Pedro B. and Buntkowsky, Gerd}, year={2019}, pages={1–82} }'
  chicago: 'Gutmann, Torsten, Pedro B. Groszewicz, and Gerd Buntkowsky. “Solid-State
    NMR of Nanocrystals.” <i>Annual Reports on NMR Spectroscopy</i> 97 (2019): 1–82.
    <a href="https://doi.org/10.1016/bs.arnmr.2018.12.001">https://doi.org/10.1016/bs.arnmr.2018.12.001</a>.'
  ieee: 'T. Gutmann, P. B. Groszewicz, and G. Buntkowsky, “Solid-state NMR of nanocrystals,”
    <i>Annual Reports on NMR Spectroscopy</i>, vol. 97, pp. 1–82, 2019, doi: <a href="https://doi.org/10.1016/bs.arnmr.2018.12.001">10.1016/bs.arnmr.2018.12.001</a>.'
  mla: Gutmann, Torsten, et al. “Solid-State NMR of Nanocrystals.” <i>Annual Reports
    on NMR Spectroscopy</i>, vol. 97, 2019, pp. 1–82, doi:<a href="https://doi.org/10.1016/bs.arnmr.2018.12.001">10.1016/bs.arnmr.2018.12.001</a>.
  short: T. Gutmann, P.B. Groszewicz, G. Buntkowsky, Annual Reports on NMR Spectroscopy
    97 (2019) 1–82.
date_created: 2026-02-07T15:37:03Z
date_updated: 2026-02-17T16:17:56Z
doi: 10.1016/bs.arnmr.2018.12.001
extern: '1'
intvolume: '        97'
keyword:
- solid-state nmr
- heterogeneous catalysis
- dynamic nuclear polarization
- Ferroelectrics
- Nanocatalysis
- Surface reactions
language:
- iso: eng
page: 1–82
publication: Annual Reports on NMR Spectroscopy
status: public
title: Solid-state NMR of nanocrystals
type: journal_article
user_id: '100715'
volume: 97
year: '2019'
...