---
_id: '13187'
abstract:
- lang: eng
  text: Abstract The reaction of Cu(I) bisguanidine complexes with nitric oxide and
    the formation of intermediate species were monitored via UV-vis spectroscopy at
    low temperature, with the occurrence of characteristic absorption bands. The origin
    of the emerging species and their character were substantiated by electron paramagnetic
    resonance (EPR) measurements and density functional theory (DFT) studies showing
    a delocalized {CuNO}11 radical species. Furthermore, this system was transferred
    to the SuperFocus mixer setup, which allows rapid mixing and the determination
    of decay constants at ambient temperatures of the thermally sensitive species.
    However, these experiments demonstrated the limits of these systems, such as the
    NO saturation in organic solvents and a preferably precise temperature control
    within the SuperFocus mixer, which should be addressed in the future.
author:
- first_name: Alexander
  full_name: Oppermann, Alexander
  last_name: Oppermann
- first_name: Larissa
  full_name: Laurini, Larissa
  last_name: Laurini
- first_name: Fabian
  full_name: Etscheidt, Fabian
  last_name: Etscheidt
- first_name: Katharina
  full_name: Hollmann, Katharina
  last_name: Hollmann
- first_name: Florian
  full_name: Strassl, Florian
  last_name: Strassl
- first_name: Alexander
  full_name: Hoffmann, Alexander
  last_name: Hoffmann
- first_name: Daniela
  full_name: Schurr, Daniela
  last_name: Schurr
- first_name: Roland
  full_name: Dittmeyer, Roland
  last_name: Dittmeyer
- first_name: Günter
  full_name: Rinke, Günter
  last_name: Rinke
- first_name: Sonja
  full_name: Herres-Pawlis, Sonja
  last_name: Herres-Pawlis
citation:
  ama: Oppermann A, Laurini L, Etscheidt F, et al. Detection of Copper Bisguanidine
    NO Adducts by UV-vis Spectroscopy and a SuperFocus Mixer. <i>Chemical Engineering
    \&#38; Technology</i>. 2017;40(8):1475-1483. doi:<a href="https://doi.org/10.1002/ceat.201600691">10.1002/ceat.201600691</a>
  apa: Oppermann, A., Laurini, L., Etscheidt, F., Hollmann, K., Strassl, F., Hoffmann,
    A., … Herres-Pawlis, S. (2017). Detection of Copper Bisguanidine NO Adducts by
    UV-vis Spectroscopy and a SuperFocus Mixer. <i>Chemical Engineering \&#38; Technology</i>,
    <i>40</i>(8), 1475–1483. <a href="https://doi.org/10.1002/ceat.201600691">https://doi.org/10.1002/ceat.201600691</a>
  bibtex: '@article{Oppermann_Laurini_Etscheidt_Hollmann_Strassl_Hoffmann_Schurr_Dittmeyer_Rinke_Herres-Pawlis_2017,
    title={Detection of Copper Bisguanidine NO Adducts by UV-vis Spectroscopy and
    a SuperFocus Mixer}, volume={40}, DOI={<a href="https://doi.org/10.1002/ceat.201600691">10.1002/ceat.201600691</a>},
    number={8}, journal={Chemical Engineering \&#38; Technology}, author={Oppermann,
    Alexander and Laurini, Larissa and Etscheidt, Fabian and Hollmann, Katharina and
    Strassl, Florian and Hoffmann, Alexander and Schurr, Daniela and Dittmeyer, Roland
    and Rinke, Günter and Herres-Pawlis, Sonja}, year={2017}, pages={1475–1483} }'
  chicago: 'Oppermann, Alexander, Larissa Laurini, Fabian Etscheidt, Katharina Hollmann,
    Florian Strassl, Alexander Hoffmann, Daniela Schurr, Roland Dittmeyer, Günter
    Rinke, and Sonja Herres-Pawlis. “Detection of Copper Bisguanidine NO Adducts by
    UV-Vis Spectroscopy and a SuperFocus Mixer.” <i>Chemical Engineering \&#38; Technology</i>
    40, no. 8 (2017): 1475–83. <a href="https://doi.org/10.1002/ceat.201600691">https://doi.org/10.1002/ceat.201600691</a>.'
  ieee: A. Oppermann <i>et al.</i>, “Detection of Copper Bisguanidine NO Adducts by
    UV-vis Spectroscopy and a SuperFocus Mixer,” <i>Chemical Engineering \&#38; Technology</i>,
    vol. 40, no. 8, pp. 1475–1483, 2017.
  mla: Oppermann, Alexander, et al. “Detection of Copper Bisguanidine NO Adducts by
    UV-Vis Spectroscopy and a SuperFocus Mixer.” <i>Chemical Engineering \&#38; Technology</i>,
    vol. 40, no. 8, 2017, pp. 1475–83, doi:<a href="https://doi.org/10.1002/ceat.201600691">10.1002/ceat.201600691</a>.
  short: A. Oppermann, L. Laurini, F. Etscheidt, K. Hollmann, F. Strassl, A. Hoffmann,
    D. Schurr, R. Dittmeyer, G. Rinke, S. Herres-Pawlis, Chemical Engineering \&#38;
    Technology 40 (2017) 1475–1483.
date_created: 2019-09-11T11:01:30Z
date_updated: 2022-01-06T06:51:30Z
doi: 10.1002/ceat.201600691
intvolume: '        40'
issue: '8'
keyword:
- Copper guanidine complexes
- Nitric oxide
- SuperFocus mixer
language:
- iso: eng
page: 1475-1483
project:
- _id: '52'
  name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Chemical Engineering \& Technology
status: public
title: Detection of Copper Bisguanidine NO Adducts by UV-vis Spectroscopy and a SuperFocus
  Mixer
type: journal_article
user_id: '40778'
volume: 40
year: '2017'
...