[{"keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Computer Science Applications","Spectroscopy","Molecular Biology","General Medicine","Catalysis"],"user_id":"48864","abstract":[{"lang":"eng","text":"Guanidinium (Gdm) undergoes interactions with both hydrophilic and hydrophobic groups and, thus, is a highly potent denaturant of biomolecular structure. However, our molecular understanding of the interaction of Gdm with proteins and DNA is still rather limited. Here, we investigated the denaturation of DNA origami nanostructures by three Gdm salts, i.e., guanidinium chloride (GdmCl), guanidinium sulfate (Gdm2SO4), and guanidinium thiocyanate (GdmSCN), at different temperatures and in dependence of incubation time. Using DNA origami nanostructures as sensors that translate small molecular transitions into nanostructural changes, the denaturing effects of the Gdm salts were directly visualized by atomic force microscopy. GdmSCN was the most potent DNA denaturant, which caused complete DNA origami denaturation at 50 °C already at a concentration of 2 M. Under such harsh conditions, denaturation occurred within the first 15 min of Gdm exposure, whereas much slower kinetics were observed for the more weakly denaturing salt Gdm2SO4 at 25 °C. Lastly, we observed a novel non-monotonous temperature dependence of DNA origami denaturation in Gdm2SO4 with the fraction of intact nanostructures having an intermediate minimum at about 40 °C. Our results, thus, provide further insights into the highly complex Gdm–DNA interaction and underscore the importance of the counteranion species."}],"doi":"10.3390/ijms23158547","title":"Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate","issue":"15","volume":23,"page":"8547","type":"journal_article","publication":"International Journal of Molecular Sciences","department":[{"_id":"302"}],"publication_status":"published","citation":{"ama":"Hanke M, Hansen N, Tomm E, Grundmeier G, Keller A. Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate. International Journal of Molecular Sciences. 2022;23(15):8547. doi:10.3390/ijms23158547","apa":"Hanke, M., Hansen, N., Tomm, E., Grundmeier, G., & Keller, A. (2022). Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate. International Journal of Molecular Sciences, 23(15), 8547. https://doi.org/10.3390/ijms23158547","chicago":"Hanke, Marcel, Niklas Hansen, Emilia Tomm, Guido Grundmeier, and Adrian Keller. “Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate.” International Journal of Molecular Sciences 23, no. 15 (2022): 8547. https://doi.org/10.3390/ijms23158547.","ieee":"M. Hanke, N. Hansen, E. Tomm, G. Grundmeier, and A. Keller, “Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate,” International Journal of Molecular Sciences, vol. 23, no. 15, p. 8547, 2022, doi: 10.3390/ijms23158547.","mla":"Hanke, Marcel, et al. “Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate.” International Journal of Molecular Sciences, vol. 23, no. 15, MDPI AG, 2022, p. 8547, doi:10.3390/ijms23158547.","bibtex":"@article{Hanke_Hansen_Tomm_Grundmeier_Keller_2022, title={Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate}, volume={23}, DOI={10.3390/ijms23158547}, number={15}, journal={International Journal of Molecular Sciences}, publisher={MDPI AG}, author={Hanke, Marcel and Hansen, Niklas and Tomm, Emilia and Grundmeier, Guido and Keller, Adrian}, year={2022}, pages={8547} }","short":"M. Hanke, N. Hansen, E. Tomm, G. Grundmeier, A. Keller, International Journal of Molecular Sciences 23 (2022) 8547."},"intvolume":" 23","author":[{"last_name":"Hanke","first_name":"Marcel","full_name":"Hanke, Marcel"},{"last_name":"Hansen","first_name":"Niklas","full_name":"Hansen, Niklas"},{"full_name":"Tomm, Emilia","first_name":"Emilia","last_name":"Tomm"},{"last_name":"Grundmeier","id":"194","full_name":"Grundmeier, Guido","first_name":"Guido"},{"full_name":"Keller, Adrian","first_name":"Adrian","id":"48864","last_name":"Keller","orcid":"0000-0001-7139-3110"}],"date_updated":"2022-08-08T06:40:14Z","_id":"32589","status":"public","language":[{"iso":"eng"}],"year":"2022","publication_identifier":{"issn":["1422-0067"]},"publisher":"MDPI AG","date_created":"2022-08-08T06:39:20Z"},{"intvolume":" 8","article_type":"review","author":[{"last_name":"Völlmecke","full_name":"Völlmecke, Katharina","first_name":"Katharina"},{"last_name":"Afroz","full_name":"Afroz, Rowshon","first_name":"Rowshon"},{"last_name":"Bierbach","first_name":"Sascha","full_name":"Bierbach, Sascha"},{"last_name":"Brenker","first_name":"Lee Josephine","full_name":"Brenker, Lee Josephine"},{"last_name":"Frücht","full_name":"Frücht, Sebastian","first_name":"Sebastian"},{"last_name":"Glass","first_name":"Alexandra","full_name":"Glass, Alexandra"},{"full_name":"Giebelhaus, Ryland","first_name":"Ryland","last_name":"Giebelhaus"},{"first_name":"Axel","full_name":"Hoppe, Axel","last_name":"Hoppe"},{"last_name":"Kanemaru","first_name":"Karen","full_name":"Kanemaru, Karen"},{"last_name":"Lazarek","first_name":"Michal","full_name":"Lazarek, Michal"},{"last_name":"Rabbe","full_name":"Rabbe, Lukas","first_name":"Lukas"},{"full_name":"Song, Longfei","first_name":"Longfei","last_name":"Song"},{"full_name":"Velasco Suarez, Andrea","first_name":"Andrea","last_name":"Velasco Suarez"},{"last_name":"Wu","first_name":"Shuang","full_name":"Wu, Shuang"},{"last_name":"Serpe","first_name":"Michael","full_name":"Serpe, Michael"},{"id":"287","last_name":"Kuckling","first_name":"Dirk","full_name":"Kuckling, Dirk"}],"department":[{"_id":"163"}],"citation":{"bibtex":"@article{Völlmecke_Afroz_Bierbach_Brenker_Frücht_Glass_Giebelhaus_Hoppe_Kanemaru_Lazarek_et al._2022, title={Hydrogel-Based Biosensors}, volume={8}, DOI={10.3390/gels8120768}, number={12768}, journal={Gels}, publisher={MDPI AG}, author={Völlmecke, Katharina and Afroz, Rowshon and Bierbach, Sascha and Brenker, Lee Josephine and Frücht, Sebastian and Glass, Alexandra and Giebelhaus, Ryland and Hoppe, Axel and Kanemaru, Karen and Lazarek, Michal and et al.}, year={2022} }","mla":"Völlmecke, Katharina, et al. “Hydrogel-Based Biosensors.” Gels, vol. 8, no. 12, 768, MDPI AG, 2022, doi:10.3390/gels8120768.","short":"K. Völlmecke, R. Afroz, S. Bierbach, L.J. Brenker, S. Frücht, A. Glass, R. Giebelhaus, A. Hoppe, K. Kanemaru, M. Lazarek, L. Rabbe, L. Song, A. Velasco Suarez, S. Wu, M. Serpe, D. Kuckling, Gels 8 (2022).","ama":"Völlmecke K, Afroz R, Bierbach S, et al. Hydrogel-Based Biosensors. Gels. 2022;8(12). doi:10.3390/gels8120768","apa":"Völlmecke, K., Afroz, R., Bierbach, S., Brenker, L. J., Frücht, S., Glass, A., Giebelhaus, R., Hoppe, A., Kanemaru, K., Lazarek, M., Rabbe, L., Song, L., Velasco Suarez, A., Wu, S., Serpe, M., & Kuckling, D. (2022). Hydrogel-Based Biosensors. Gels, 8(12), Article 768. https://doi.org/10.3390/gels8120768","ieee":"K. Völlmecke et al., “Hydrogel-Based Biosensors,” Gels, vol. 8, no. 12, Art. no. 768, 2022, doi: 10.3390/gels8120768.","chicago":"Völlmecke, Katharina, Rowshon Afroz, Sascha Bierbach, Lee Josephine Brenker, Sebastian Frücht, Alexandra Glass, Ryland Giebelhaus, et al. “Hydrogel-Based Biosensors.” Gels 8, no. 12 (2022). https://doi.org/10.3390/gels8120768."},"publication_status":"published","language":[{"iso":"eng"}],"publication_identifier":{"issn":["2310-2861"]},"year":"2022","status":"public","date_created":"2023-01-10T08:02:50Z","publisher":"MDPI AG","date_updated":"2023-01-10T08:05:30Z","_id":"35642","abstract":[{"text":"There is an increasing interest in sensing applications for a variety of analytes in aqueous environments, as conventional methods do not work reliably under humid conditions or they require complex equipment with experienced operators. Hydrogel sensors are easy to fabricate, are incredibly sensitive, and have broad dynamic ranges. Experiments on their robustness, reliability, and reusability have indicated the possible long-term applications of these systems in a variety of fields, including disease diagnosis, detection of pharmaceuticals, and in environmental testing. It is possible to produce hydrogels, which, upon sensing a specific analyte, can adsorb it onto their 3D-structure and can therefore be used to remove them from a given environment. High specificity can be obtained by using molecularly imprinted polymers. Typical detection principles involve optical methods including fluorescence and chemiluminescence, and volume changes in colloidal photonic crystals, as well as electrochemical methods. Here, we explore the current research utilizing hydrogel-based sensors in three main areas: (1) biomedical applications, (2) for detecting and quantifying pharmaceuticals of interest, and (3) detecting and quantifying environmental contaminants in aqueous environments.","lang":"eng"}],"doi":"10.3390/gels8120768","title":"Hydrogel-Based Biosensors","keyword":["Polymers and Plastics","Organic Chemistry","Biomaterials","Bioengineering"],"main_file_link":[{"url":"https://www.mdpi.com/2310-2861/8/12/768"}],"user_id":"94","type":"journal_article","publication":"Gels","article_number":"768","issue":"12","volume":8},{"title":"Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation","author":[{"last_name":"Weber","full_name":"Weber, Sebastian","first_name":"Sebastian"},{"first_name":"Ronny T.","full_name":"Zimmermann, Ronny T.","last_name":"Zimmermann"},{"first_name":"Jens","full_name":"Bremer, Jens","last_name":"Bremer"},{"full_name":"Abel, Ken L.","first_name":"Ken L.","last_name":"Abel"},{"full_name":"Poppitz, David","first_name":"David","last_name":"Poppitz"},{"full_name":"Prinz, Nils","first_name":"Nils","last_name":"Prinz"},{"first_name":"Jan","full_name":"Ilsemann, Jan","last_name":"Ilsemann"},{"full_name":"Wendholt, Sven","first_name":"Sven","last_name":"Wendholt"},{"last_name":"Yang","full_name":"Yang, Qingxin","first_name":"Qingxin"},{"first_name":"Reihaneh","full_name":"Pashminehazar, Reihaneh","last_name":"Pashminehazar"},{"first_name":"Federico","full_name":"Monaco, Federico","last_name":"Monaco"},{"full_name":"Cloetens, Peter","first_name":"Peter","last_name":"Cloetens"},{"last_name":"Huang","first_name":"Xiaohui","full_name":"Huang, Xiaohui"},{"last_name":"Kübel","first_name":"Christian","full_name":"Kübel, Christian"},{"last_name":"Kondratenko","full_name":"Kondratenko, Evgenii","first_name":"Evgenii"},{"orcid":"0000-0002-9294-6076","first_name":"Matthias","full_name":"Bauer, Matthias","id":"47241","last_name":"Bauer"},{"last_name":"Bäumer","full_name":"Bäumer, Marcus","first_name":"Marcus"},{"last_name":"Zobel","first_name":"Mirijam","full_name":"Zobel, Mirijam"},{"first_name":"Roger","full_name":"Gläser, Roger","last_name":"Gläser"},{"last_name":"Sundmacher","full_name":"Sundmacher, Kai","first_name":"Kai"},{"first_name":"Thomas L.","full_name":"Sheppard, Thomas L.","last_name":"Sheppard"}],"doi":"10.1002/cctc.202101878","intvolume":" 14","abstract":[{"lang":"eng","text":"Increasing the metal-to-ligand charge transfer (MLCT) excited state lifetime of polypyridine iron(II) complexes can be achieved by lowering the ligand's π* orbital energy and by increasing the ligand field splitting. In the homo- and heteroleptic complexes [Fe(cpmp)2]2+ (12+) and [Fe(cpmp)(ddpd)]2+ (22+) with the tridentate ligands 6,2’’-carboxypyridyl-2,2’-methylamine-pyridyl-pyridine (cpmp) and N,N’-dimethyl-N,N’-di-pyridin-2-ylpyridine-2,6-diamine (ddpd) two or one dipyridyl ketone moieties provide low energy π* acceptor orbitals. A good metal-ligand orbital overlap to increase the ligand field splitting is achieved by optimizing the octahedricity through CO and NMe units between the coordinating pyridines which enable the formation of six-membered chelate rings. The push-pull ligand cpmp provides intra-ligand and ligand-to-ligand charge transfer (ILCT, LL'CT) excited states in addition to MLCT excited states. Ground and excited state properties of 12+ and 22+ were accessed by X-ray diffraction analyses, resonance Raman spectroscopy, (spectro)electrochemistry, EPR spectroscopy, X-ray emission spectroscopy, static and time-resolved IR and UV/Vis/NIR absorption spectroscopy as well as quantum chemical calculations."}],"citation":{"mla":"Weber, Sebastian, et al. “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation.” ChemCatChem, vol. 14, no. 8, Wiley, 2022, doi:10.1002/cctc.202101878.","bibtex":"@article{Weber_Zimmermann_Bremer_Abel_Poppitz_Prinz_Ilsemann_Wendholt_Yang_Pashminehazar_et al._2022, title={Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation}, volume={14}, DOI={10.1002/cctc.202101878}, number={8}, journal={ChemCatChem}, publisher={Wiley}, author={Weber, Sebastian and Zimmermann, Ronny T. and Bremer, Jens and Abel, Ken L. and Poppitz, David and Prinz, Nils and Ilsemann, Jan and Wendholt, Sven and Yang, Qingxin and Pashminehazar, Reihaneh and et al.}, year={2022} }","short":"S. Weber, R.T. Zimmermann, J. Bremer, K.L. Abel, D. Poppitz, N. Prinz, J. Ilsemann, S. Wendholt, Q. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X. Huang, C. Kübel, E. Kondratenko, M. Bauer, M. Bäumer, M. Zobel, R. Gläser, K. Sundmacher, T.L. Sheppard, ChemCatChem 14 (2022).","ama":"Weber S, Zimmermann RT, Bremer J, et al. Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation. ChemCatChem. 2022;14(8). doi:10.1002/cctc.202101878","apa":"Weber, S., Zimmermann, R. T., Bremer, J., Abel, K. L., Poppitz, D., Prinz, N., Ilsemann, J., Wendholt, S., Yang, Q., Pashminehazar, R., Monaco, F., Cloetens, P., Huang, X., Kübel, C., Kondratenko, E., Bauer, M., Bäumer, M., Zobel, M., Gläser, R., … Sheppard, T. L. (2022). Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation. ChemCatChem, 14(8). https://doi.org/10.1002/cctc.202101878","chicago":"Weber, Sebastian, Ronny T. Zimmermann, Jens Bremer, Ken L. Abel, David Poppitz, Nils Prinz, Jan Ilsemann, et al. “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation.” ChemCatChem 14, no. 8 (2022). https://doi.org/10.1002/cctc.202101878.","ieee":"S. Weber et al., “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3 Reference Catalyst for CO2 Methanation,” ChemCatChem, vol. 14, no. 8, 2022, doi: 10.1002/cctc.202101878."},"user_id":"48467","publication_status":"published","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"department":[{"_id":"35"},{"_id":"306"}],"publication":"ChemCatChem","date_created":"2023-01-30T16:25:02Z","publisher":"Wiley","year":"2022","type":"journal_article","publication_identifier":{"issn":["1867-3880","1867-3899"]},"language":[{"iso":"eng"}],"status":"public","_id":"40988","volume":14,"date_updated":"2024-05-08T13:03:51Z","issue":"8"},{"publisher":"Wiley","date_created":"2023-01-10T09:10:15Z","publication":"Chemistry – A European Journal","status":"public","language":[{"iso":"eng"}],"type":"journal_article","publication_identifier":{"issn":["0947-6539","1521-3765"]},"year":"2022","volume":28,"_id":"35703","issue":"23","date_updated":"2023-01-23T12:47:43Z","author":[{"last_name":"Hou","first_name":"Peng","full_name":"Hou, Peng"},{"first_name":"Sebastian","full_name":"Peschtrich, Sebastian","last_name":"Peschtrich"},{"full_name":"Huber, Nils","first_name":"Nils","last_name":"Huber"},{"full_name":"Feuerstein, Wolfram","first_name":"Wolfram","last_name":"Feuerstein"},{"last_name":"Bihlmeier","first_name":"Angela","full_name":"Bihlmeier, Angela"},{"last_name":"Krummenacher","full_name":"Krummenacher, Ivo","first_name":"Ivo"},{"first_name":"Roland","full_name":"Schoch, Roland","last_name":"Schoch"},{"last_name":"Klopper","full_name":"Klopper, Wim","first_name":"Wim"},{"last_name":"Breher","full_name":"Breher, Frank","first_name":"Frank"},{"first_name":"Jan","full_name":"Paradies, Jan","last_name":"Paradies","id":"53339","orcid":"0000-0002-3698-668X"}],"title":"Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022)","doi":"10.1002/chem.202200982","intvolume":" 28","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication_status":"published","user_id":"53339","citation":{"ama":"Hou P, Peschtrich S, Huber N, et al. Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022). Chemistry – A European Journal. 2022;28(23). doi:10.1002/chem.202200982","apa":"Hou, P., Peschtrich, S., Huber, N., Feuerstein, W., Bihlmeier, A., Krummenacher, I., Schoch, R., Klopper, W., Breher, F., & Paradies, J. (2022). Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022). Chemistry – A European Journal, 28(23). https://doi.org/10.1002/chem.202200982","chicago":"Hou, Peng, Sebastian Peschtrich, Nils Huber, Wolfram Feuerstein, Angela Bihlmeier, Ivo Krummenacher, Roland Schoch, Wim Klopper, Frank Breher, and Jan Paradies. “Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022).” Chemistry – A European Journal 28, no. 23 (2022). https://doi.org/10.1002/chem.202200982.","ieee":"P. Hou et al., “Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022),” Chemistry – A European Journal, vol. 28, no. 23, 2022, doi: 10.1002/chem.202200982.","mla":"Hou, Peng, et al. “Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022).” Chemistry – A European Journal, vol. 28, no. 23, Wiley, 2022, doi:10.1002/chem.202200982.","bibtex":"@article{Hou_Peschtrich_Huber_Feuerstein_Bihlmeier_Krummenacher_Schoch_Klopper_Breher_Paradies_2022, title={Cover Feature: Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives (Chem. Eur. J. 23/2022)}, volume={28}, DOI={10.1002/chem.202200982}, number={23}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Hou, Peng and Peschtrich, Sebastian and Huber, Nils and Feuerstein, Wolfram and Bihlmeier, Angela and Krummenacher, Ivo and Schoch, Roland and Klopper, Wim and Breher, Frank and Paradies, Jan}, year={2022} }","short":"P. Hou, S. Peschtrich, N. Huber, W. Feuerstein, A. Bihlmeier, I. Krummenacher, R. Schoch, W. Klopper, F. Breher, J. Paradies, Chemistry – A European Journal 28 (2022)."},"department":[{"_id":"2"},{"_id":"389"}]},{"language":[{"iso":"eng"}],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"type":"journal_article","year":"2022","status":"public","date_created":"2023-01-10T08:57:45Z","publication":"Chemistry – A European Journal","publisher":"Wiley","issue":"23","date_updated":"2023-01-23T12:51:33Z","_id":"35688","volume":28,"intvolume":" 28","doi":"10.1002/chem.202200478","title":"Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives","author":[{"last_name":"Hou","full_name":"Hou, Peng","first_name":"Peng"},{"full_name":"Peschtrich, Sebastian","first_name":"Sebastian","last_name":"Peschtrich"},{"first_name":"Nils","full_name":"Huber, Nils","last_name":"Huber"},{"last_name":"Feuerstein","full_name":"Feuerstein, Wolfram","first_name":"Wolfram"},{"last_name":"Bihlmeier","full_name":"Bihlmeier, Angela","first_name":"Angela"},{"last_name":"Krummenacher","first_name":"Ivo","full_name":"Krummenacher, Ivo"},{"first_name":"Roland","full_name":"Schoch, Roland","last_name":"Schoch"},{"first_name":"Wim","full_name":"Klopper, Wim","last_name":"Klopper"},{"first_name":"Frank","full_name":"Breher, Frank","last_name":"Breher"},{"last_name":"Paradies","id":"53339","full_name":"Paradies, Jan","first_name":"Jan","orcid":"0000-0002-3698-668X"}],"citation":{"ama":"Hou P, Peschtrich S, Huber N, et al. Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives. Chemistry – A European Journal. 2022;28(23). doi:10.1002/chem.202200478","apa":"Hou, P., Peschtrich, S., Huber, N., Feuerstein, W., Bihlmeier, A., Krummenacher, I., Schoch, R., Klopper, W., Breher, F., & Paradies, J. (2022). Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives. Chemistry – A European Journal, 28(23). https://doi.org/10.1002/chem.202200478","chicago":"Hou, Peng, Sebastian Peschtrich, Nils Huber, Wolfram Feuerstein, Angela Bihlmeier, Ivo Krummenacher, Roland Schoch, Wim Klopper, Frank Breher, and Jan Paradies. “Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives.” Chemistry – A European Journal 28, no. 23 (2022). https://doi.org/10.1002/chem.202200478.","ieee":"P. Hou et al., “Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives,” Chemistry – A European Journal, vol. 28, no. 23, 2022, doi: 10.1002/chem.202200478.","mla":"Hou, Peng, et al. “Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives.” Chemistry – A European Journal, vol. 28, no. 23, Wiley, 2022, doi:10.1002/chem.202200478.","bibtex":"@article{Hou_Peschtrich_Huber_Feuerstein_Bihlmeier_Krummenacher_Schoch_Klopper_Breher_Paradies_2022, title={Impact of Heterocycle Annulation on NIR Absorbance in Quinoid Thioacene Derivatives}, volume={28}, DOI={10.1002/chem.202200478}, number={23}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Hou, Peng and Peschtrich, Sebastian and Huber, Nils and Feuerstein, Wolfram and Bihlmeier, Angela and Krummenacher, Ivo and Schoch, Roland and Klopper, Wim and Breher, Frank and Paradies, Jan}, year={2022} }","short":"P. Hou, S. Peschtrich, N. Huber, W. Feuerstein, A. Bihlmeier, I. Krummenacher, R. Schoch, W. Klopper, F. Breher, J. Paradies, Chemistry – A European Journal 28 (2022)."},"publication_status":"published","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"user_id":"53339"},{"issue":"57","date_updated":"2023-01-31T08:00:32Z","volume":28,"_id":"40985","status":"public","language":[{"iso":"eng"}],"year":"2022","publication_identifier":{"issn":["0947-6539","1521-3765"]},"type":"journal_article","publisher":"Wiley","date_created":"2023-01-30T16:23:37Z","publication":"Chemistry – A European Journal","department":[{"_id":"35"},{"_id":"306"}],"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication_status":"published","user_id":"48467","citation":{"mla":"Moll, Johannes, et al. “Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry.” Chemistry – A European Journal, vol. 28, no. 57, Wiley, 2022, doi:10.1002/chem.202201858.","bibtex":"@article{Moll_Naumann_Sorge_Förster_Gessner_Burkhardt_Ugur_Nuernberger_Seidel_Ramanan_et al._2022, title={Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry}, volume={28}, DOI={10.1002/chem.202201858}, number={57}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Moll, Johannes and Naumann, Robert and Sorge, Lukas and Förster, Christoph and Gessner, Niklas and Burkhardt, Lukas and Ugur, Naz and Nuernberger, Patrick and Seidel, Wolfram and Ramanan, Charusheela and et al.}, year={2022} }","short":"J. Moll, R. Naumann, L. Sorge, C. Förster, N. Gessner, L. Burkhardt, N. Ugur, P. Nuernberger, W. Seidel, C. Ramanan, M. Bauer, K. Heinze, Chemistry – A European Journal 28 (2022).","apa":"Moll, J., Naumann, R., Sorge, L., Förster, C., Gessner, N., Burkhardt, L., Ugur, N., Nuernberger, P., Seidel, W., Ramanan, C., Bauer, M., & Heinze, K. (2022). Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry. Chemistry – A European Journal, 28(57). https://doi.org/10.1002/chem.202201858","ama":"Moll J, Naumann R, Sorge L, et al. Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry. Chemistry – A European Journal. 2022;28(57). doi:10.1002/chem.202201858","chicago":"Moll, Johannes, Robert Naumann, Lukas Sorge, Christoph Förster, Niklas Gessner, Lukas Burkhardt, Naz Ugur, et al. “Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry.” Chemistry – A European Journal 28, no. 57 (2022). https://doi.org/10.1002/chem.202201858.","ieee":"J. Moll et al., “Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry,” Chemistry – A European Journal, vol. 28, no. 57, 2022, doi: 10.1002/chem.202201858."},"doi":"10.1002/chem.202201858","intvolume":" 28","author":[{"last_name":"Moll","first_name":"Johannes","full_name":"Moll, Johannes"},{"last_name":"Naumann","full_name":"Naumann, Robert","first_name":"Robert"},{"last_name":"Sorge","first_name":"Lukas","full_name":"Sorge, Lukas"},{"full_name":"Förster, Christoph","first_name":"Christoph","last_name":"Förster"},{"first_name":"Niklas","full_name":"Gessner, Niklas","last_name":"Gessner"},{"last_name":"Burkhardt","id":"54038","first_name":"Lukas","full_name":"Burkhardt, Lukas","orcid":"0000-0003-0747-9811"},{"full_name":"Ugur, Naz","first_name":"Naz","last_name":"Ugur"},{"last_name":"Nuernberger","full_name":"Nuernberger, Patrick","first_name":"Patrick"},{"first_name":"Wolfram","full_name":"Seidel, Wolfram","last_name":"Seidel"},{"full_name":"Ramanan, Charusheela","first_name":"Charusheela","last_name":"Ramanan"},{"full_name":"Bauer, Matthias","first_name":"Matthias","last_name":"Bauer","id":"47241","orcid":"0000-0002-9294-6076"},{"last_name":"Heinze","full_name":"Heinze, Katja","first_name":"Katja"}],"title":"Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry"},{"language":[{"iso":"eng"}],"year":"2022","publication_identifier":{"issn":["1867-3880","1867-3899"]},"type":"journal_article","status":"public","date_created":"2023-01-31T14:04:55Z","publication":"ChemCatChem","publisher":"Wiley","issue":"8","date_updated":"2023-01-31T14:05:50Z","_id":"41208","volume":14,"intvolume":" 14","doi":"10.1002/cctc.202101878","title":"Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation","author":[{"last_name":"Weber","full_name":"Weber, Sebastian","first_name":"Sebastian"},{"full_name":"Zimmermann, Ronny T.","first_name":"Ronny T.","last_name":"Zimmermann"},{"first_name":"Jens","full_name":"Bremer, Jens","last_name":"Bremer"},{"last_name":"Abel","first_name":"Ken L.","full_name":"Abel, Ken L."},{"last_name":"Poppitz","first_name":"David","full_name":"Poppitz, David"},{"full_name":"Prinz, Nils","first_name":"Nils","last_name":"Prinz"},{"last_name":"Ilsemann","full_name":"Ilsemann, Jan","first_name":"Jan"},{"first_name":"Sven","full_name":"Strübbe, Sven","id":"76968","last_name":"Strübbe"},{"last_name":"Yang","full_name":"Yang, Qingxin","first_name":"Qingxin"},{"full_name":"Pashminehazar, Reihaneh","first_name":"Reihaneh","last_name":"Pashminehazar"},{"last_name":"Monaco","first_name":"Federico","full_name":"Monaco, Federico"},{"first_name":"Peter","full_name":"Cloetens, Peter","last_name":"Cloetens"},{"last_name":"Huang","full_name":"Huang, Xiaohui","first_name":"Xiaohui"},{"last_name":"Kübel","full_name":"Kübel, Christian","first_name":"Christian"},{"first_name":"Evgenii","full_name":"Kondratenko, Evgenii","last_name":"Kondratenko"},{"first_name":"Matthias","full_name":"Bauer, Matthias","last_name":"Bauer"},{"full_name":"Bäumer, Marcus","first_name":"Marcus","last_name":"Bäumer"},{"first_name":"Mirijam","full_name":"Zobel, Mirijam","last_name":"Zobel"},{"first_name":"Roger","full_name":"Gläser, Roger","last_name":"Gläser"},{"first_name":"Kai","full_name":"Sundmacher, Kai","last_name":"Sundmacher"},{"last_name":"Sheppard","first_name":"Thomas L.","full_name":"Sheppard, Thomas L."}],"citation":{"ama":"Weber S, Zimmermann RT, Bremer J, et al. Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation. ChemCatChem. 2022;14(8). doi:10.1002/cctc.202101878","apa":"Weber, S., Zimmermann, R. T., Bremer, J., Abel, K. L., Poppitz, D., Prinz, N., Ilsemann, J., Strübbe, S., Yang, Q., Pashminehazar, R., Monaco, F., Cloetens, P., Huang, X., Kübel, C., Kondratenko, E., Bauer, M., Bäumer, M., Zobel, M., Gläser, R., … Sheppard, T. L. (2022). Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation. ChemCatChem, 14(8). https://doi.org/10.1002/cctc.202101878","chicago":"Weber, Sebastian, Ronny T. Zimmermann, Jens Bremer, Ken L. Abel, David Poppitz, Nils Prinz, Jan Ilsemann, et al. “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation.” ChemCatChem 14, no. 8 (2022). https://doi.org/10.1002/cctc.202101878.","ieee":"S. Weber et al., “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation,” ChemCatChem, vol. 14, no. 8, 2022, doi: 10.1002/cctc.202101878.","mla":"Weber, Sebastian, et al. “Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation.” ChemCatChem, vol. 14, no. 8, Wiley, 2022, doi:10.1002/cctc.202101878.","bibtex":"@article{Weber_Zimmermann_Bremer_Abel_Poppitz_Prinz_Ilsemann_Strübbe_Yang_Pashminehazar_et al._2022, title={Digitization in Catalysis Research: Towards a Holistic Description of a Ni/Al2O3Reference Catalyst for CO2Methanation}, volume={14}, DOI={10.1002/cctc.202101878}, number={8}, journal={ChemCatChem}, publisher={Wiley}, author={Weber, Sebastian and Zimmermann, Ronny T. and Bremer, Jens and Abel, Ken L. and Poppitz, David and Prinz, Nils and Ilsemann, Jan and Strübbe, Sven and Yang, Qingxin and Pashminehazar, Reihaneh and et al.}, year={2022} }","short":"S. Weber, R.T. Zimmermann, J. Bremer, K.L. Abel, D. Poppitz, N. Prinz, J. Ilsemann, S. Strübbe, Q. Yang, R. Pashminehazar, F. Monaco, P. Cloetens, X. Huang, C. Kübel, E. Kondratenko, M. Bauer, M. Bäumer, M. Zobel, R. Gläser, K. Sundmacher, T.L. Sheppard, ChemCatChem 14 (2022)."},"publication_status":"published","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry","Catalysis"],"user_id":"76968"},{"keyword":["Materials Chemistry","Organic Chemistry","Surfaces","Coatings and Films","General Chemical Engineering"],"publication_status":"published","user_id":"32","citation":{"ama":"Dogan D, Ruthmann S, Seewald O, Bremser W. Tuning of antifouling active PDMS domains tethered to epoxy/amine surface. Progress in Organic Coatings. 2022;170. doi:10.1016/j.porgcoat.2022.106977","apa":"Dogan, D., Ruthmann, S., Seewald, O., & Bremser, W. (2022). Tuning of antifouling active PDMS domains tethered to epoxy/amine surface. Progress in Organic Coatings, 170, Article 106977. https://doi.org/10.1016/j.porgcoat.2022.106977","chicago":"Dogan, Deniz, Simon Ruthmann, Oliver Seewald, and Wolfgang Bremser. “Tuning of Antifouling Active PDMS Domains Tethered to Epoxy/Amine Surface.” Progress in Organic Coatings 170 (2022). https://doi.org/10.1016/j.porgcoat.2022.106977.","ieee":"D. Dogan, S. Ruthmann, O. Seewald, and W. Bremser, “Tuning of antifouling active PDMS domains tethered to epoxy/amine surface,” Progress in Organic Coatings, vol. 170, Art. no. 106977, 2022, doi: 10.1016/j.porgcoat.2022.106977.","mla":"Dogan, Deniz, et al. “Tuning of Antifouling Active PDMS Domains Tethered to Epoxy/Amine Surface.” Progress in Organic Coatings, vol. 170, 106977, Elsevier BV, 2022, doi:10.1016/j.porgcoat.2022.106977.","bibtex":"@article{Dogan_Ruthmann_Seewald_Bremser_2022, title={Tuning of antifouling active PDMS domains tethered to epoxy/amine surface}, volume={170}, DOI={10.1016/j.porgcoat.2022.106977}, number={106977}, journal={Progress in Organic Coatings}, publisher={Elsevier BV}, author={Dogan, Deniz and Ruthmann, Simon and Seewald, Oliver and Bremser, Wolfgang}, year={2022} }","short":"D. Dogan, S. Ruthmann, O. Seewald, W. Bremser, Progress in Organic Coatings 170 (2022)."},"department":[{"_id":"35"},{"_id":"301"},{"_id":"321"}],"author":[{"last_name":"Dogan","full_name":"Dogan, Deniz","first_name":"Deniz"},{"full_name":"Ruthmann, Simon","first_name":"Simon","last_name":"Ruthmann"},{"first_name":"Oliver","full_name":"Seewald, Oliver","last_name":"Seewald"},{"full_name":"Bremser, Wolfgang","first_name":"Wolfgang","last_name":"Bremser"}],"title":"Tuning of antifouling active PDMS domains tethered to epoxy/amine surface","doi":"10.1016/j.porgcoat.2022.106977","intvolume":" 170","volume":170,"_id":"36425","date_updated":"2023-02-06T09:58:55Z","article_number":"106977","publisher":"Elsevier BV","date_created":"2023-01-12T12:45:39Z","publication":"Progress in Organic Coatings","status":"public","language":[{"iso":"eng"}],"publication_identifier":{"issn":["0300-9440"]},"type":"journal_article","year":"2022"},{"citation":{"short":"D. Menge, H.-J. Schmid, Macromolecular Symposia 404 (2022).","mla":"Menge, Dennis, and Hans-Joachim Schmid. “Low Temperature Laser Sintering with PA12 and PA6 on a Standard System.” Macromolecular Symposia, vol. 404, no. 1, 2100397, Wiley, 2022, doi:10.1002/masy.202100397.","bibtex":"@article{Menge_Schmid_2022, title={Low Temperature Laser Sintering with PA12 and PA6 on a Standard System}, volume={404}, DOI={10.1002/masy.202100397}, number={12100397}, journal={Macromolecular Symposia}, publisher={Wiley}, author={Menge, Dennis and Schmid, Hans-Joachim}, year={2022} }","chicago":"Menge, Dennis, and Hans-Joachim Schmid. “Low Temperature Laser Sintering with PA12 and PA6 on a Standard System.” Macromolecular Symposia 404, no. 1 (2022). https://doi.org/10.1002/masy.202100397.","ieee":"D. Menge and H.-J. Schmid, “Low Temperature Laser Sintering with PA12 and PA6 on a Standard System,” Macromolecular Symposia, vol. 404, no. 1, Art. no. 2100397, 2022, doi: 10.1002/masy.202100397.","ama":"Menge D, Schmid H-J. Low Temperature Laser Sintering with PA12 and PA6 on a Standard System. Macromolecular Symposia. 2022;404(1). doi:10.1002/masy.202100397","apa":"Menge, D., & Schmid, H.-J. (2022). Low Temperature Laser Sintering with PA12 and PA6 on a Standard System. Macromolecular Symposia, 404(1), Article 2100397. https://doi.org/10.1002/masy.202100397"},"publication_status":"published","keyword":["Materials Chemistry","Polymers and Plastics","Organic Chemistry","Condensed Matter Physics"],"user_id":"3959","department":[{"_id":"150"}],"title":"Low Temperature Laser Sintering with PA12 and PA6 on a Standard System","author":[{"full_name":"Menge, Dennis","first_name":"Dennis","id":"29240","last_name":"Menge"},{"orcid":"000-0001-8590-1921","full_name":"Schmid, Hans-Joachim","first_name":"Hans-Joachim","last_name":"Schmid","id":"464"}],"doi":"10.1002/masy.202100397","intvolume":" 404","_id":"44469","volume":404,"article_number":"2100397","issue":"1","date_updated":"2023-05-04T08:24:10Z","date_created":"2023-05-04T08:21:02Z","quality_controlled":"1","publication":"Macromolecular Symposia","publisher":"Wiley","language":[{"iso":"eng"}],"type":"journal_article","publication_identifier":{"issn":["1022-1360","1521-3900"]},"year":"2022","status":"public"},{"author":[{"last_name":"Albrecht","full_name":"Albrecht, Ralf","first_name":"Ralf"},{"first_name":"Markus","full_name":"Hoelzel, Markus","last_name":"Hoelzel"},{"full_name":"Beccard, Henrik","first_name":"Henrik","last_name":"Beccard"},{"full_name":"Rüsing, Michael","first_name":"Michael","id":"22501","last_name":"Rüsing","orcid":"0000-0003-4682-4577"},{"first_name":"Lukas","full_name":"Eng, Lukas","last_name":"Eng"},{"first_name":"Thomas","full_name":"Doert, Thomas","last_name":"Doert"},{"last_name":"Ruck","full_name":"Ruck, Michael","first_name":"Michael"}],"intvolume":" 27","citation":{"chicago":"Albrecht, Ralf, Markus Hoelzel, Henrik Beccard, Michael Rüsing, Lukas Eng, Thomas Doert, and Michael Ruck. “Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).” Chemistry – A European Journal 27, no. 57 (2021): 14299–306. https://doi.org/10.1002/chem.202102464.","ieee":"R. Albrecht et al., “Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI),” Chemistry – A European Journal, vol. 27, no. 57, pp. 14299–14306, 2021, doi: 10.1002/chem.202102464.","ama":"Albrecht R, Hoelzel M, Beccard H, et al. Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI). Chemistry – A European Journal. 2021;27(57):14299-14306. doi:10.1002/chem.202102464","apa":"Albrecht, R., Hoelzel, M., Beccard, H., Rüsing, M., Eng, L., Doert, T., & Ruck, M. (2021). Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI). Chemistry – A European Journal, 27(57), 14299–14306. https://doi.org/10.1002/chem.202102464","short":"R. Albrecht, M. Hoelzel, H. Beccard, M. Rüsing, L. Eng, T. Doert, M. Ruck, Chemistry – A European Journal 27 (2021) 14299–14306.","mla":"Albrecht, Ralf, et al. “Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).” Chemistry – A European Journal, vol. 27, no. 57, Wiley, 2021, pp. 14299–306, doi:10.1002/chem.202102464.","bibtex":"@article{Albrecht_Hoelzel_Beccard_Rüsing_Eng_Doert_Ruck_2021, title={Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI)}, volume={27}, DOI={10.1002/chem.202102464}, number={57}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Albrecht, Ralf and Hoelzel, Markus and Beccard, Henrik and Rüsing, Michael and Eng, Lukas and Doert, Thomas and Ruck, Michael}, year={2021}, pages={14299–14306} }"},"publication_status":"published","date_created":"2023-10-11T08:39:51Z","publisher":"Wiley","year":"2021","publication_identifier":{"issn":["0947-6539","1521-3765"]},"language":[{"iso":"eng"}],"status":"public","_id":"47977","date_updated":"2023-10-11T08:41:35Z","title":"Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI)","extern":"1","doi":"10.1002/chem.202102464","abstract":[{"lang":"eng","text":"Orange-colored crystals of the oxoferrate tellurate K12+6xFe6Te4−xO27 [x=0.222(4)] were synthesized in a potassium hydroxide hydroflux with a molar water–base ratio n(H2O)/n(KOH) of 1.5 starting from Fe(NO3)3 ⋅ 9H2O, TeO2 and H2O2 at about 200 °C. By using (NH4)2TeO4 instead of TeO2, a fine powder consisting of microcrystalline spheres of K12+6xFe6Te4−xO27 was obtained. K12+6xFe6Te4−xO27 crystallizes in the acentric cubic space group Iurn:x-wiley:09476539:media:chem202102464:chem202102464-math-0001 3d. [FeIIIO5] pyramids share their apical atoms in [Fe2O9] groups and two of their edges with [TeVIO6] octahedra to form an open framework that consists of two loosely connected, but not interpenetrating, chiral networks. The flexibility of the hinged oxometalate network manifests in a piezoelectric response similar to that of LiNbO3.The potassium cations are mobile in channels that run along the <111> directions and cross in cavities acting as nodes. The ion conductivity of cold-pressed pellets of ball-milled K12+6xFe6Te4−xO27 is 2.3×10^(−4) S ⋅ cm^(−1) at room temperature. Magnetization measurements and neutron diffraction indicate antiferromagnetic coupling in the [Fe2O9] groups."}],"user_id":"22501","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication":"Chemistry – A European Journal","quality_controlled":"1","type":"journal_article","page":"14299-14306","volume":27,"issue":"57"},{"author":[{"first_name":"Nina","full_name":"Gaiser, Nina","last_name":"Gaiser"},{"first_name":"Thomas","full_name":"Bierkandt, Thomas","last_name":"Bierkandt"},{"last_name":"Oßwald","first_name":"Patrick","full_name":"Oßwald, Patrick"},{"last_name":"Zinsmeister","full_name":"Zinsmeister, Julia","first_name":"Julia"},{"first_name":"Trupti","full_name":"Kathrotia, Trupti","last_name":"Kathrotia"},{"last_name":"Shaqiri","full_name":"Shaqiri, Shkelqim","first_name":"Shkelqim"},{"first_name":"Patrick","full_name":"Hemberger, Patrick","last_name":"Hemberger"},{"orcid":"0000-0003-3993-5316 ","full_name":"Kasper, Tina","first_name":"Tina","id":"94562","last_name":"Kasper"},{"full_name":"Aigner, Manfred","first_name":"Manfred","last_name":"Aigner"},{"full_name":"Köhler, Markus","first_name":"Markus","last_name":"Köhler"}],"extern":"1","title":"Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy","doi":"10.1016/j.fuel.2021.122650","intvolume":" 313","user_id":"94562","publication_status":"published","keyword":["Organic Chemistry","Energy Engineering and Power Technology","Fuel Technology","General Chemical Engineering"],"citation":{"bibtex":"@article{Gaiser_Bierkandt_Oßwald_Zinsmeister_Kathrotia_Shaqiri_Hemberger_Kasper_Aigner_Köhler_2021, title={Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy}, volume={313}, DOI={10.1016/j.fuel.2021.122650}, number={122650}, journal={Fuel}, publisher={Elsevier BV}, author={Gaiser, Nina and Bierkandt, Thomas and Oßwald, Patrick and Zinsmeister, Julia and Kathrotia, Trupti and Shaqiri, Shkelqim and Hemberger, Patrick and Kasper, Tina and Aigner, Manfred and Köhler, Markus}, year={2021} }","mla":"Gaiser, Nina, et al. “Oxidation of Oxymethylene Ether (OME0−5): An Experimental Systematic Study by Mass Spectrometry and Photoelectron Photoion Coincidence Spectroscopy.” Fuel, vol. 313, 122650, Elsevier BV, 2021, doi:10.1016/j.fuel.2021.122650.","short":"N. Gaiser, T. Bierkandt, P. Oßwald, J. Zinsmeister, T. Kathrotia, S. Shaqiri, P. Hemberger, T. Kasper, M. Aigner, M. Köhler, Fuel 313 (2021).","ama":"Gaiser N, Bierkandt T, Oßwald P, et al. Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy. Fuel. 2021;313. doi:10.1016/j.fuel.2021.122650","apa":"Gaiser, N., Bierkandt, T., Oßwald, P., Zinsmeister, J., Kathrotia, T., Shaqiri, S., Hemberger, P., Kasper, T., Aigner, M., & Köhler, M. (2021). Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy. Fuel, 313, Article 122650. https://doi.org/10.1016/j.fuel.2021.122650","ieee":"N. Gaiser et al., “Oxidation of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy,” Fuel, vol. 313, Art. no. 122650, 2021, doi: 10.1016/j.fuel.2021.122650.","chicago":"Gaiser, Nina, Thomas Bierkandt, Patrick Oßwald, Julia Zinsmeister, Trupti Kathrotia, Shkelqim Shaqiri, Patrick Hemberger, Tina Kasper, Manfred Aigner, and Markus Köhler. “Oxidation of Oxymethylene Ether (OME0−5): An Experimental Systematic Study by Mass Spectrometry and Photoelectron Photoion Coincidence Spectroscopy.” Fuel 313 (2021). https://doi.org/10.1016/j.fuel.2021.122650."},"department":[{"_id":"728"}],"publisher":"Elsevier BV","publication":"Fuel","date_created":"2024-03-27T17:50:11Z","status":"public","publication_identifier":{"issn":["0016-2361"]},"year":"2021","type":"journal_article","language":[{"iso":"eng"}],"volume":313,"_id":"53085","date_updated":"2024-03-27T17:50:47Z","article_number":"122650"},{"title":"Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes","abstract":[{"lang":"eng","text":"Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica."}],"doi":"10.1002/chem.202103099","user_id":"48467","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication":"Chemistry – A European Journal","type":"journal_article","volume":27,"page":"17220-17229","issue":"68","author":[{"full_name":"Panyam, Pradeep K. R.","first_name":"Pradeep K. R.","last_name":"Panyam"},{"full_name":"Atwi, Boshra","first_name":"Boshra","last_name":"Atwi"},{"last_name":"Ziegler","first_name":"Felix","full_name":"Ziegler, Felix"},{"last_name":"Frey","full_name":"Frey, Wolfgang","first_name":"Wolfgang"},{"orcid":"0000-0002-3734-7011","id":"78878","last_name":"Nowakowski","first_name":"Michał","full_name":"Nowakowski, Michał"},{"full_name":"Bauer, Matthias","first_name":"Matthias","last_name":"Bauer","id":"47241","orcid":"0000-0002-9294-6076"},{"full_name":"Buchmeiser, Michael R.","first_name":"Michael R.","last_name":"Buchmeiser"}],"article_type":"original","intvolume":" 27","publication_status":"published","citation":{"chicago":"Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michał Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.","ieee":"P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol. 27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.","ama":"Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229. doi:10.1002/chem.202103099","apa":"Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68), 17220–17229. https://doi.org/10.1002/chem.202103099","short":"P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.","mla":"Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.","bibtex":"@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }"},"department":[{"_id":"35"},{"_id":"306"}],"publisher":"Wiley","date_created":"2023-01-30T16:48:41Z","status":"public","year":"2021","publication_identifier":{"issn":["0947-6539","1521-3765"]},"language":[{"iso":"eng"}],"_id":"40999","date_updated":"2024-05-07T11:43:40Z"},{"year":"2021","publication_identifier":{"issn":["0276-7333","1520-6041"]},"language":[{"iso":"eng"}],"status":"public","date_created":"2023-01-30T17:00:10Z","publisher":"American Chemical Society (ACS)","date_updated":"2024-05-07T11:43:17Z","_id":"41009","intvolume":" 40","article_type":"original","author":[{"last_name":"Maier","first_name":"Sarah","full_name":"Maier, Sarah"},{"last_name":"Cronin","full_name":"Cronin, Steve P.","first_name":"Steve P."},{"last_name":"Vu Dinh","full_name":"Vu Dinh, Manh-Anh","first_name":"Manh-Anh"},{"first_name":"Zheng","full_name":"Li, Zheng","last_name":"Li"},{"full_name":"Dyballa, Michael","first_name":"Michael","last_name":"Dyballa"},{"orcid":"0000-0002-3734-7011","first_name":"Michał","full_name":"Nowakowski, Michał","last_name":"Nowakowski","id":"78878"},{"id":"47241","last_name":"Bauer","full_name":"Bauer, Matthias","first_name":"Matthias","orcid":"0000-0002-9294-6076"},{"last_name":"Estes","first_name":"Deven P.","full_name":"Estes, Deven P."}],"department":[{"_id":"35"},{"_id":"306"}],"citation":{"short":"S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M. Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.","bibtex":"@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations}, volume={40}, DOI={10.1021/acs.organomet.1c00216}, number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)}, author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng and Dyballa, Michael and Nowakowski, Michał and Bauer, Matthias and Estes, Deven P.}, year={2021}, pages={1751–1757} }","mla":"Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics, vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:10.1021/acs.organomet.1c00216.","ieee":"S. Maier et al., “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations,” Organometallics, vol. 40, no. 11, pp. 1751–1757, 2021, doi: 10.1021/acs.organomet.1c00216.","chicago":"Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa, Michał Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics 40, no. 11 (2021): 1751–57. https://doi.org/10.1021/acs.organomet.1c00216.","ama":"Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics. 2021;40(11):1751-1757. doi:10.1021/acs.organomet.1c00216","apa":"Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski, M., Bauer, M., & Estes, D. P. (2021). Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics, 40(11), 1751–1757. https://doi.org/10.1021/acs.organomet.1c00216"},"publication_status":"published","type":"journal_article","publication":"Organometallics","issue":"11","page":"1751-1757","volume":40,"doi":"10.1021/acs.organomet.1c00216","abstract":[{"text":"Platinum hydride species catalyze a number of interesting organic reactions. However, their reactions typically involve the use of high loadings of noble metal and are difficult to recycle, making them somewhat unsustainable. We have synthesized surface-immobilized Pt–H species via oxidative addition of surface OH groups to Pt(PtBu3)2 (1), a rarely used immobilization technique in surface organometallic chemistry. The hydride species thus made were characterized by infrared, magic-angle spinning nuclear magnetic resonance, and X-ray absorption spectroscopies and catalyzed both olefin isomerization and cycloisomerization of a 1,6 enyne (5) with a high selectivity and low Pt loading.","lang":"eng"}],"title":"Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations","user_id":"48467","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry"]},{"intvolume":" 54","author":[{"orcid":"0000-0002-3698-668X","full_name":"Paradies, Jan","first_name":"Jan","id":"53339","last_name":"Paradies"},{"last_name":"Köring","full_name":"Köring, Laura","first_name":"Laura"},{"last_name":"Sitte","full_name":"Sitte, Nikolai A.","first_name":"Nikolai A."}],"citation":{"short":"J. Paradies, L. Köring, N.A. Sitte, Synthesis 54 (2021) 1287–1300.","bibtex":"@article{Paradies_Köring_Sitte_2021, title={Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides}, volume={54}, DOI={10.1055/a-1681-3972}, number={05}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Paradies, Jan and Köring, Laura and Sitte, Nikolai A.}, year={2021}, pages={1287–1300} }","mla":"Paradies, Jan, et al. “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” Synthesis, vol. 54, no. 05, Georg Thieme Verlag KG, 2021, pp. 1287–300, doi:10.1055/a-1681-3972.","ieee":"J. Paradies, L. Köring, and N. A. Sitte, “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides,” Synthesis, vol. 54, no. 05, pp. 1287–1300, 2021, doi: 10.1055/a-1681-3972.","chicago":"Paradies, Jan, Laura Köring, and Nikolai A. Sitte. “Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” Synthesis 54, no. 05 (2021): 1287–1300. https://doi.org/10.1055/a-1681-3972.","ama":"Paradies J, Köring L, Sitte NA. Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides. Synthesis. 2021;54(05):1287-1300. doi:10.1055/a-1681-3972","apa":"Paradies, J., Köring, L., & Sitte, N. A. (2021). Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides. Synthesis, 54(05), 1287–1300. https://doi.org/10.1055/a-1681-3972"},"publication_status":"published","language":[{"iso":"eng"}],"year":"2021","publication_identifier":{"issn":["0039-7881","1437-210X"]},"status":"public","date_created":"2023-01-10T08:56:44Z","publisher":"Georg Thieme Verlag KG","date_updated":"2023-01-23T12:51:23Z","_id":"35686","abstract":[{"lang":"eng","text":"AbstractThe development of the frustrated Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed. Detailed insight into our strategies in order to overcome challenges during the reaction development process is provided. Furthermore, the developed chemistry is extended to the hydrogenation of polyamides and of trifluoroacetamides for the convenient introduction of trifluoroethyl groups into organic molecules."}],"doi":"10.1055/a-1681-3972","title":"Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides","keyword":["Organic Chemistry","Catalysis"],"user_id":"53339","type":"journal_article","publication":"Synthesis","issue":"05","page":"1287-1300","volume":54},{"citation":{"mla":"Zhou, Rundong, and Jan Paradies. “Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?” European Journal of Organic Chemistry, vol. 2021, no. 46, Wiley, 2021, pp. 6334–39, doi:10.1002/ejoc.202100883.","bibtex":"@article{Zhou_Paradies_2021, title={Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?}, volume={2021}, DOI={10.1002/ejoc.202100883}, number={46}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Zhou, Rundong and Paradies, Jan}, year={2021}, pages={6334–6339} }","short":"R. Zhou, J. Paradies, European Journal of Organic Chemistry 2021 (2021) 6334–6339.","apa":"Zhou, R., & Paradies, J. (2021). Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration? European Journal of Organic Chemistry, 2021(46), 6334–6339. https://doi.org/10.1002/ejoc.202100883","ama":"Zhou R, Paradies J. Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration? European Journal of Organic Chemistry. 2021;2021(46):6334-6339. doi:10.1002/ejoc.202100883","chicago":"Zhou, Rundong, and Jan Paradies. “Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?” European Journal of Organic Chemistry 2021, no. 46 (2021): 6334–39. https://doi.org/10.1002/ejoc.202100883.","ieee":"R. Zhou and J. Paradies, “Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?,” European Journal of Organic Chemistry, vol. 2021, no. 46, pp. 6334–6339, 2021, doi: 10.1002/ejoc.202100883."},"publication_status":"published","intvolume":" 2021","author":[{"last_name":"Zhou","full_name":"Zhou, Rundong","first_name":"Rundong"},{"full_name":"Paradies, Jan","first_name":"Jan","id":"53339","last_name":"Paradies","orcid":"0000-0002-3698-668X"}],"date_updated":"2023-01-23T12:51:27Z","_id":"35687","language":[{"iso":"eng"}],"publication_identifier":{"issn":["1434-193X","1099-0690"]},"year":"2021","status":"public","date_created":"2023-01-10T08:57:10Z","publisher":"Wiley","keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"user_id":"53339","doi":"10.1002/ejoc.202100883","title":"Borane Catalyzed Redox Isomerization of 2‐Amino Chalcones: Hydride Abstraction or Hydride Migration?","issue":"46","page":"6334-6339","volume":2021,"type":"journal_article","publication":"European Journal of Organic Chemistry"},{"author":[{"full_name":"Huber‐Gedert, Marina","first_name":"Marina","last_name":"Huber‐Gedert"},{"last_name":"Nowakowski","first_name":"Michał","full_name":"Nowakowski, Michał"},{"last_name":"Kertmen","full_name":"Kertmen, Ahmet","first_name":"Ahmet"},{"first_name":"Lukas","full_name":"Burkhardt, Lukas","last_name":"Burkhardt"},{"last_name":"Lindner","first_name":"Natalia","full_name":"Lindner, Natalia"},{"full_name":"Schoch, Roland","first_name":"Roland","last_name":"Schoch"},{"last_name":"Herbst‐Irmer","full_name":"Herbst‐Irmer, Regine","first_name":"Regine"},{"last_name":"Neuba","full_name":"Neuba, Adam","first_name":"Adam"},{"full_name":"Schmitz, Lennart","first_name":"Lennart","last_name":"Schmitz"},{"last_name":"Choi","first_name":"Tae‐Kyu","full_name":"Choi, Tae‐Kyu"},{"last_name":"Kubicki","full_name":"Kubicki, Jacek","first_name":"Jacek"},{"last_name":"Gawelda","first_name":"Wojciech","full_name":"Gawelda, Wojciech"},{"last_name":"Bauer","full_name":"Bauer, Matthias","first_name":"Matthias"}],"intvolume":" 27","publication_status":"published","citation":{"mla":"Huber‐Gedert, Marina, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European Journal, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:10.1002/chem.202100766.","bibtex":"@article{Huber‐Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={10.1002/chem.202100766}, number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber‐Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }","ama":"Huber‐Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal. 2021;27(38):9905-9918. doi:10.1002/chem.202100766","apa":"Huber‐Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N., Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda, W., & Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal, 27(38), 9905–9918. https://doi.org/10.1002/chem.202100766","chicago":"Huber‐Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt, Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European Journal 27, no. 38 (2021): 9905–18. https://doi.org/10.1002/chem.202100766.","short":"M. Huber‐Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R. Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda, M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.","ieee":"M. Huber‐Gedert et al., “Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” Chemistry – A European Journal, vol. 27, no. 38, pp. 9905–9918, 2021, doi: 10.1002/chem.202100766."},"publisher":"Wiley","date_created":"2023-01-31T22:51:06Z","status":"public","publication_identifier":{"issn":["0947-6539","1521-3765"]},"year":"2021","language":[{"iso":"eng"}],"_id":"41325","date_updated":"2023-02-01T08:50:53Z","title":"Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad","doi":"10.1002/chem.202100766","user_id":"78878","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication":"Chemistry – A European Journal","type":"journal_article","volume":27,"page":"9905-9918","issue":"38"},{"author":[{"first_name":"Pradeep K. R.","full_name":"Panyam, Pradeep K. R.","last_name":"Panyam"},{"full_name":"Atwi, Boshra","first_name":"Boshra","last_name":"Atwi"},{"last_name":"Ziegler","full_name":"Ziegler, Felix","first_name":"Felix"},{"full_name":"Frey, Wolfgang","first_name":"Wolfgang","last_name":"Frey"},{"last_name":"Nowakowski","full_name":"Nowakowski, Michal","first_name":"Michal"},{"first_name":"Matthias","full_name":"Bauer, Matthias","last_name":"Bauer"},{"last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R.","first_name":"Michael R."}],"intvolume":" 27","citation":{"bibtex":"@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michal and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }","mla":"Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.","short":"P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.","apa":"Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68), 17220–17229. https://doi.org/10.1002/chem.202103099","ama":"Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229. doi:10.1002/chem.202103099","ieee":"P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol. 27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.","chicago":"Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michal Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099."},"publication_status":"published","date_created":"2023-01-31T22:50:03Z","publisher":"Wiley","publication_identifier":{"issn":["0947-6539","1521-3765"]},"year":"2021","language":[{"iso":"eng"}],"status":"public","_id":"41322","date_updated":"2023-02-01T08:51:03Z","title":"Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes","doi":"10.1002/chem.202103099","user_id":"78878","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication":"Chemistry – A European Journal","type":"journal_article","page":"17220-17229","volume":27,"issue":"68"},{"publication":"Organometallics","type":"journal_article","page":"1751-1757","volume":40,"issue":"11","title":"Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations","doi":"10.1021/acs.organomet.1c00216","user_id":"78878","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry"],"date_created":"2023-01-31T22:50:43Z","publisher":"American Chemical Society (ACS)","publication_identifier":{"issn":["0276-7333","1520-6041"]},"year":"2021","language":[{"iso":"eng"}],"status":"public","_id":"41324","date_updated":"2023-02-01T08:50:56Z","author":[{"first_name":"Sarah","full_name":"Maier, Sarah","last_name":"Maier"},{"first_name":"Steve P.","full_name":"Cronin, Steve P.","last_name":"Cronin"},{"first_name":"Manh-Anh","full_name":"Vu Dinh, Manh-Anh","last_name":"Vu Dinh"},{"first_name":"Zheng","full_name":"Li, Zheng","last_name":"Li"},{"last_name":"Dyballa","full_name":"Dyballa, Michael","first_name":"Michael"},{"last_name":"Nowakowski","first_name":"Michal","full_name":"Nowakowski, Michal"},{"last_name":"Bauer","full_name":"Bauer, Matthias","first_name":"Matthias"},{"full_name":"Estes, Deven P.","first_name":"Deven P.","last_name":"Estes"}],"intvolume":" 40","citation":{"bibtex":"@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations}, volume={40}, DOI={10.1021/acs.organomet.1c00216}, number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)}, author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng and Dyballa, Michael and Nowakowski, Michal and Bauer, Matthias and Estes, Deven P.}, year={2021}, pages={1751–1757} }","mla":"Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics, vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:10.1021/acs.organomet.1c00216.","short":"S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M. Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.","apa":"Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski, M., Bauer, M., & Estes, D. P. (2021). Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics, 40(11), 1751–1757. https://doi.org/10.1021/acs.organomet.1c00216","ama":"Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics. 2021;40(11):1751-1757. doi:10.1021/acs.organomet.1c00216","ieee":"S. Maier et al., “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations,” Organometallics, vol. 40, no. 11, pp. 1751–1757, 2021, doi: 10.1021/acs.organomet.1c00216.","chicago":"Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa, Michal Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics 40, no. 11 (2021): 1751–57. https://doi.org/10.1021/acs.organomet.1c00216."},"publication_status":"published"},{"title":"Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity","doi":"10.1002/chem.202104108","abstract":[{"lang":"eng","text":"Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and growing range of applications. While COFs are well-established as heterogeneous catalysts, so far, their high and ordered porosity has scarcely been utilized to its full potential when it comes to spatially confined reactions in COF pores to alter the outcome of reactions. Here, we present a highly porous and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation reaction provides a molecularly precise heterogeneous olefin metathesis catalyst. An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O) for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency in selectivity, pointing to diffusion limitations induced by the pore confinement."}],"user_id":"48467","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"publication":"Chemistry – A European Journal","type":"journal_article","volume":28,"issue":"8","article_type":"original","author":[{"last_name":"Emmerling","first_name":"Sebastian T.","full_name":"Emmerling, Sebastian T."},{"full_name":"Ziegler, Felix","first_name":"Felix","last_name":"Ziegler"},{"last_name":"Fischer","full_name":"Fischer, Felix R.","first_name":"Felix R."},{"orcid":"0000-0003-2061-7289","full_name":"Schoch, Roland","first_name":"Roland","last_name":"Schoch","id":"48467"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","id":"47241","full_name":"Bauer, Matthias","first_name":"Matthias"},{"last_name":"Plietker","first_name":"Bernd","full_name":"Plietker, Bernd"},{"last_name":"Buchmeiser","full_name":"Buchmeiser, Michael R.","first_name":"Michael R."},{"full_name":"Lotsch, Bettina V.","first_name":"Bettina V.","last_name":"Lotsch"}],"intvolume":" 28","citation":{"chicago":"Emmerling, Sebastian T., Felix Ziegler, Felix R. Fischer, Roland Schoch, Matthias Bauer, Bernd Plietker, Michael R. Buchmeiser, and Bettina V. Lotsch. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” Chemistry – A European Journal 28, no. 8 (2021). https://doi.org/10.1002/chem.202104108.","ieee":"S. T. Emmerling et al., “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity,” Chemistry – A European Journal, vol. 28, no. 8, 2021, doi: 10.1002/chem.202104108.","ama":"Emmerling ST, Ziegler F, Fischer FR, et al. Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. Chemistry – A European Journal. 2021;28(8). doi:10.1002/chem.202104108","apa":"Emmerling, S. T., Ziegler, F., Fischer, F. R., Schoch, R., Bauer, M., Plietker, B., Buchmeiser, M. R., & Lotsch, B. V. (2021). Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. Chemistry – A European Journal, 28(8). https://doi.org/10.1002/chem.202104108","short":"S.T. Emmerling, F. Ziegler, F.R. Fischer, R. Schoch, M. Bauer, B. Plietker, M.R. Buchmeiser, B.V. Lotsch, Chemistry – A European Journal 28 (2021).","mla":"Emmerling, Sebastian T., et al. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” Chemistry – A European Journal, vol. 28, no. 8, Wiley, 2021, doi:10.1002/chem.202104108.","bibtex":"@article{Emmerling_Ziegler_Fischer_Schoch_Bauer_Plietker_Buchmeiser_Lotsch_2021, title={Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity}, volume={28}, DOI={10.1002/chem.202104108}, number={8}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Emmerling, Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer, Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.}, year={2021} }"},"publication_status":"published","department":[{"_id":"35"},{"_id":"306"}],"date_created":"2023-01-30T16:48:22Z","publisher":"Wiley","publication_identifier":{"issn":["0947-6539","1521-3765"]},"year":"2021","language":[{"iso":"eng"}],"status":"public","_id":"40998","date_updated":"2023-01-31T08:05:07Z"},{"status":"public","year":"2021","publication_identifier":{"issn":["0024-9297","1520-5835"]},"language":[{"iso":"eng"}],"publisher":"American Chemical Society (ACS)","date_created":"2023-02-06T12:02:19Z","date_updated":"2023-02-06T12:05:32Z","_id":"41816","intvolume":" 54","author":[{"last_name":"Wagner","first_name":"Maximilian","full_name":"Wagner, Maximilian"},{"first_name":"Anja","full_name":"Krieger, Anja","last_name":"Krieger"},{"full_name":"Minameyer, Martin","first_name":"Martin","last_name":"Minameyer"},{"first_name":"Benjamin","full_name":"Hämisch, Benjamin","last_name":"Hämisch"},{"last_name":"Huber","id":"237","full_name":"Huber, Klaus","first_name":"Klaus"},{"first_name":"Thomas","full_name":"Drewello, Thomas","last_name":"Drewello"},{"last_name":"Gröhn","full_name":"Gröhn, Franziska","first_name":"Franziska"}],"department":[{"_id":"314"}],"publication_status":"published","citation":{"short":"M. Wagner, A. Krieger, M. Minameyer, B. Hämisch, K. Huber, T. Drewello, F. Gröhn, Macromolecules 54 (2021) 2899–2911.","bibtex":"@article{Wagner_Krieger_Minameyer_Hämisch_Huber_Drewello_Gröhn_2021, title={Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds}, volume={54}, DOI={10.1021/acs.macromol.1c00299}, number={6}, journal={Macromolecules}, publisher={American Chemical Society (ACS)}, author={Wagner, Maximilian and Krieger, Anja and Minameyer, Martin and Hämisch, Benjamin and Huber, Klaus and Drewello, Thomas and Gröhn, Franziska}, year={2021}, pages={2899–2911} }","mla":"Wagner, Maximilian, et al. “Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds.” Macromolecules, vol. 54, no. 6, American Chemical Society (ACS), 2021, pp. 2899–911, doi:10.1021/acs.macromol.1c00299.","ieee":"M. Wagner et al., “Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds,” Macromolecules, vol. 54, no. 6, pp. 2899–2911, 2021, doi: 10.1021/acs.macromol.1c00299.","chicago":"Wagner, Maximilian, Anja Krieger, Martin Minameyer, Benjamin Hämisch, Klaus Huber, Thomas Drewello, and Franziska Gröhn. “Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds.” Macromolecules 54, no. 6 (2021): 2899–2911. https://doi.org/10.1021/acs.macromol.1c00299.","ama":"Wagner M, Krieger A, Minameyer M, et al. Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds. Macromolecules. 2021;54(6):2899-2911. doi:10.1021/acs.macromol.1c00299","apa":"Wagner, M., Krieger, A., Minameyer, M., Hämisch, B., Huber, K., Drewello, T., & Gröhn, F. (2021). Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds. Macromolecules, 54(6), 2899–2911. https://doi.org/10.1021/acs.macromol.1c00299"},"type":"journal_article","publication":"Macromolecules","issue":"6","volume":54,"page":"2899-2911","doi":"10.1021/acs.macromol.1c00299","title":"Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds","user_id":"237","keyword":["Materials Chemistry","Inorganic Chemistry","Polymers and Plastics","Organic Chemistry"]}]