---
_id: '51221'
abstract:
- lang: eng
  text: <jats:p>Charge transfer mechanism in the deprotonation-induced n-type doping
    of PCBM.</jats:p>
author:
- first_name: Chuan-Ding
  full_name: Dong, Chuan-Ding
  id: '67188'
  last_name: Dong
- first_name: Fabian
  full_name: Bauch, Fabian
  id: '61389'
  last_name: Bauch
  orcid: 0009-0008-6279-077X
- first_name: Yuanyuan
  full_name: Hu, Yuanyuan
  last_name: Hu
- first_name: Stefan
  full_name: Schumacher, Stefan
  id: '27271'
  last_name: Schumacher
  orcid: 0000-0003-4042-4951
citation:
  ama: Dong C-D, Bauch F, Hu Y, Schumacher S. Charge transfer in superbase n-type
    doping of PCBM induced by deprotonation. <i>Physical Chemistry Chemical Physics</i>.
    2024;26(5):4194-4199. doi:<a href="https://doi.org/10.1039/d3cp05105f">10.1039/d3cp05105f</a>
  apa: Dong, C.-D., Bauch, F., Hu, Y., &#38; Schumacher, S. (2024). Charge transfer
    in superbase n-type doping of PCBM induced by deprotonation. <i>Physical Chemistry
    Chemical Physics</i>, <i>26</i>(5), 4194–4199. <a href="https://doi.org/10.1039/d3cp05105f">https://doi.org/10.1039/d3cp05105f</a>
  bibtex: '@article{Dong_Bauch_Hu_Schumacher_2024, title={Charge transfer in superbase
    n-type doping of PCBM induced by deprotonation}, volume={26}, DOI={<a href="https://doi.org/10.1039/d3cp05105f">10.1039/d3cp05105f</a>},
    number={5}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society
    of Chemistry (RSC)}, author={Dong, Chuan-Ding and Bauch, Fabian and Hu, Yuanyuan
    and Schumacher, Stefan}, year={2024}, pages={4194–4199} }'
  chicago: 'Dong, Chuan-Ding, Fabian Bauch, Yuanyuan Hu, and Stefan Schumacher. “Charge
    Transfer in Superbase N-Type Doping of PCBM Induced by Deprotonation.” <i>Physical
    Chemistry Chemical Physics</i> 26, no. 5 (2024): 4194–99. <a href="https://doi.org/10.1039/d3cp05105f">https://doi.org/10.1039/d3cp05105f</a>.'
  ieee: 'C.-D. Dong, F. Bauch, Y. Hu, and S. Schumacher, “Charge transfer in superbase
    n-type doping of PCBM induced by deprotonation,” <i>Physical Chemistry Chemical
    Physics</i>, vol. 26, no. 5, pp. 4194–4199, 2024, doi: <a href="https://doi.org/10.1039/d3cp05105f">10.1039/d3cp05105f</a>.'
  mla: Dong, Chuan-Ding, et al. “Charge Transfer in Superbase N-Type Doping of PCBM
    Induced by Deprotonation.” <i>Physical Chemistry Chemical Physics</i>, vol. 26,
    no. 5, Royal Society of Chemistry (RSC), 2024, pp. 4194–99, doi:<a href="https://doi.org/10.1039/d3cp05105f">10.1039/d3cp05105f</a>.
  short: C.-D. Dong, F. Bauch, Y. Hu, S. Schumacher, Physical Chemistry Chemical Physics
    26 (2024) 4194–4199.
date_created: 2024-02-07T14:15:44Z
date_updated: 2024-02-07T14:35:55Z
department:
- _id: '35'
- _id: '15'
doi: 10.1039/d3cp05105f
intvolume: '        26'
issue: '5'
keyword:
- Physical and Theoretical Chemistry
- General Physics and Astronomy
language:
- iso: eng
page: 4194-4199
publication: Physical Chemistry Chemical Physics
publication_identifier:
  issn:
  - 1463-9076
  - 1463-9084
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Charge transfer in superbase n-type doping of PCBM induced by deprotonation
type: journal_article
user_id: '61389'
volume: 26
year: '2024'
...
---
_id: '52541'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>We conducted an investigation into
    the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene
    derivative and potassium thioacetate as a substitute for hydrogen sulfide. This
    investigation utilized kinetic and computational methods. We synthesized two palladium
    complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene
    (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF),
    as well as their tentative intermediates in the catalytic cycle. Reaction rates
    were measured and then compared to computational predictions.</jats:p>
author:
- first_name: Sebastian
  full_name: Peschtrich, Sebastian
  last_name: Peschtrich
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Dirk
  full_name: Kuckling, Dirk
  id: '287'
  last_name: Kuckling
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Peschtrich S, Schoch R, Kuckling D, Paradies J. A Comparative Kinetic and Computational
    Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and
    2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal
    of Organic Chemistry</i>. 2024;27(8). doi:<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>
  apa: Peschtrich, S., Schoch, R., Kuckling, D., &#38; Paradies, J. (2024). A Comparative
    Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of
    Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.
    <i>European Journal of Organic Chemistry</i>, <i>27</i>(8). <a href="https://doi.org/10.1002/ejoc.202301207">https://doi.org/10.1002/ejoc.202301207</a>
  bibtex: '@article{Peschtrich_Schoch_Kuckling_Paradies_2024, title={A Comparative
    Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of
    Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes},
    volume={27}, DOI={<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>},
    number={8}, journal={European Journal of Organic Chemistry}, publisher={Wiley},
    author={Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies,
    Jan}, year={2024} }'
  chicago: Peschtrich, Sebastian, Roland Schoch, Dirk Kuckling, and Jan Paradies.
    “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross
    Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine
    Complexes.” <i>European Journal of Organic Chemistry</i> 27, no. 8 (2024). <a
    href="https://doi.org/10.1002/ejoc.202301207">https://doi.org/10.1002/ejoc.202301207</a>.
  ieee: 'S. Peschtrich, R. Schoch, D. Kuckling, and J. Paradies, “A Comparative Kinetic
    and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium
    Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes,” <i>European
    Journal of Organic Chemistry</i>, vol. 27, no. 8, 2024, doi: <a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>.'
  mla: Peschtrich, Sebastian, et al. “A Comparative Kinetic and Computational Investigation
    of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene
    Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i>,
    vol. 27, no. 8, Wiley, 2024, doi:<a href="https://doi.org/10.1002/ejoc.202301207">10.1002/ejoc.202301207</a>.
  short: S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic
    Chemistry 27 (2024).
date_created: 2024-03-13T17:15:14Z
date_updated: 2024-03-13T17:17:37Z
department:
- _id: '2'
- _id: '389'
doi: 10.1002/ejoc.202301207
intvolume: '        27'
issue: '8'
keyword:
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
publication: European Journal of Organic Chemistry
publication_identifier:
  issn:
  - 1434-193X
  - 1099-0690
publication_status: published
publisher: Wiley
status: public
title: A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur
  Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine
  Complexes
type: journal_article
user_id: '53339'
volume: 27
year: '2024'
...
---
_id: '52534'
author:
- first_name: Fabian
  full_name: Bauch, Fabian
  id: '61389'
  last_name: Bauch
  orcid: 0009-0008-6279-077X
- first_name: Chuan-Ding
  full_name: Dong, Chuan-Ding
  id: '67188'
  last_name: Dong
- first_name: Stefan
  full_name: Schumacher, Stefan
  id: '27271'
  last_name: Schumacher
  orcid: 0000-0003-4042-4951
citation:
  ama: Bauch F, Dong C-D, Schumacher S. Dynamics of Electron–Hole Coulomb Attractive
    Energy and Dipole Moment of Hot Excitons in Donor–Acceptor Polymers. <i>The Journal
    of Physical Chemistry C</i>. 2024;128(8):3525-3532. doi:<a href="https://doi.org/10.1021/acs.jpcc.3c07513">10.1021/acs.jpcc.3c07513</a>
  apa: Bauch, F., Dong, C.-D., &#38; Schumacher, S. (2024). Dynamics of Electron–Hole
    Coulomb Attractive Energy and Dipole Moment of Hot Excitons in Donor–Acceptor
    Polymers. <i>The Journal of Physical Chemistry C</i>, <i>128</i>(8), 3525–3532.
    <a href="https://doi.org/10.1021/acs.jpcc.3c07513">https://doi.org/10.1021/acs.jpcc.3c07513</a>
  bibtex: '@article{Bauch_Dong_Schumacher_2024, title={Dynamics of Electron–Hole Coulomb
    Attractive Energy and Dipole Moment of Hot Excitons in Donor–Acceptor Polymers},
    volume={128}, DOI={<a href="https://doi.org/10.1021/acs.jpcc.3c07513">10.1021/acs.jpcc.3c07513</a>},
    number={8}, journal={The Journal of Physical Chemistry C}, publisher={American
    Chemical Society (ACS)}, author={Bauch, Fabian and Dong, Chuan-Ding and Schumacher,
    Stefan}, year={2024}, pages={3525–3532} }'
  chicago: 'Bauch, Fabian, Chuan-Ding Dong, and Stefan Schumacher. “Dynamics of Electron–Hole
    Coulomb Attractive Energy and Dipole Moment of Hot Excitons in Donor–Acceptor
    Polymers.” <i>The Journal of Physical Chemistry C</i> 128, no. 8 (2024): 3525–32.
    <a href="https://doi.org/10.1021/acs.jpcc.3c07513">https://doi.org/10.1021/acs.jpcc.3c07513</a>.'
  ieee: 'F. Bauch, C.-D. Dong, and S. Schumacher, “Dynamics of Electron–Hole Coulomb
    Attractive Energy and Dipole Moment of Hot Excitons in Donor–Acceptor Polymers,”
    <i>The Journal of Physical Chemistry C</i>, vol. 128, no. 8, pp. 3525–3532, 2024,
    doi: <a href="https://doi.org/10.1021/acs.jpcc.3c07513">10.1021/acs.jpcc.3c07513</a>.'
  mla: Bauch, Fabian, et al. “Dynamics of Electron–Hole Coulomb Attractive Energy
    and Dipole Moment of Hot Excitons in Donor–Acceptor Polymers.” <i>The Journal
    of Physical Chemistry C</i>, vol. 128, no. 8, American Chemical Society (ACS),
    2024, pp. 3525–32, doi:<a href="https://doi.org/10.1021/acs.jpcc.3c07513">10.1021/acs.jpcc.3c07513</a>.
  short: F. Bauch, C.-D. Dong, S. Schumacher, The Journal of Physical Chemistry C
    128 (2024) 3525–3532.
date_created: 2024-03-13T12:23:15Z
date_updated: 2024-03-14T09:27:57Z
department:
- _id: '35'
- _id: '15'
doi: 10.1021/acs.jpcc.3c07513
intvolume: '       128'
issue: '8'
keyword:
- Surfaces
- Coatings and Films
- Physical and Theoretical Chemistry
- General Energy
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
page: 3525-3532
publication: The Journal of Physical Chemistry C
publication_identifier:
  issn:
  - 1932-7447
  - 1932-7455
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Dynamics of Electron–Hole Coulomb Attractive Energy and Dipole Moment of Hot
  Excitons in Donor–Acceptor Polymers
type: journal_article
user_id: '61389'
volume: 128
year: '2024'
...
---
_id: '50726'
abstract:
- lang: eng
  text: <jats:p>Resistance spot‐welded joints containing press‐hardened steels are
    seen to exhibit a fracture mode called total dome failure, where the weld nugget
    completely separates from one steel sheet along the weld nugget edge. The effect
    of weld nugget shape and material property gradients is studied based on damage
    mechanics modeling and experimental validation to shed light on the underlying
    influencing factors. For a three‐steel‐sheet spot‐welded joint combining DP600
    (1.5 mm)–CR1900T (1.0 mm)–CR1900T (1.0 mm), experiments under shear loading reveal
    that fracture occurs in the DP600 sheet along the weld nugget edge. In subsequent
    numerical simulation studies with damage mechanics models whose parameters are
    independently calibrated for every involved material configuration, three variations
    of the geometrical joint configuration are considered—an approximation of the
    real joint, one variation with a steeper weld nugget shape, and one variation
    with a less pronounced gradient between weld nugget material and heat‐affected
    zone material properties. The results of the finite‐element simulations show that
    a shallower weld nugget and a more pronounced material gradient lead to a faster
    increase of plastic strain at the edge of the weld nugget and promote the occurrence
    of total dome failure.</jats:p>
author:
- first_name: Lilia
  full_name: Schuster, Lilia
  last_name: Schuster
- first_name: Viktoria
  full_name: Olfert, Viktoria
  id: '5974'
  last_name: Olfert
- first_name: Oleksii
  full_name: Sherepenko, Oleksii
  last_name: Sherepenko
- first_name: Clemens
  full_name: Fehrenbach, Clemens
  last_name: Fehrenbach
- first_name: Shiyuan
  full_name: Song, Shiyuan
  last_name: Song
- first_name: David
  full_name: Hein, David
  id: '7728'
  last_name: Hein
- first_name: Gerson
  full_name: Meschut, Gerson
  id: '32056'
  last_name: Meschut
  orcid: 0000-0002-2763-1246
- first_name: Elliot
  full_name: Biro, Elliot
  last_name: Biro
- first_name: Sebastian
  full_name: Münstermann, Sebastian
  last_name: Münstermann
citation:
  ama: Schuster L, Olfert V, Sherepenko O, et al. Influences of Weld Nugget Shape
    and Material Gradient on the Shear Strength of Resistance Spot‐Welded Joints.
    <i>steel research international</i>. Published online 2024. doi:<a href="https://doi.org/10.1002/srin.202300530">10.1002/srin.202300530</a>
  apa: Schuster, L., Olfert, V., Sherepenko, O., Fehrenbach, C., Song, S., Hein, D.,
    Meschut, G., Biro, E., &#38; Münstermann, S. (2024). Influences of Weld Nugget
    Shape and Material Gradient on the Shear Strength of Resistance Spot‐Welded Joints.
    <i>Steel Research International</i>. <a href="https://doi.org/10.1002/srin.202300530">https://doi.org/10.1002/srin.202300530</a>
  bibtex: '@article{Schuster_Olfert_Sherepenko_Fehrenbach_Song_Hein_Meschut_Biro_Münstermann_2024,
    title={Influences of Weld Nugget Shape and Material Gradient on the Shear Strength
    of Resistance Spot‐Welded Joints}, DOI={<a href="https://doi.org/10.1002/srin.202300530">10.1002/srin.202300530</a>},
    journal={steel research international}, publisher={Wiley}, author={Schuster, Lilia
    and Olfert, Viktoria and Sherepenko, Oleksii and Fehrenbach, Clemens and Song,
    Shiyuan and Hein, David and Meschut, Gerson and Biro, Elliot and Münstermann,
    Sebastian}, year={2024} }'
  chicago: Schuster, Lilia, Viktoria Olfert, Oleksii Sherepenko, Clemens Fehrenbach,
    Shiyuan Song, David Hein, Gerson Meschut, Elliot Biro, and Sebastian Münstermann.
    “Influences of Weld Nugget Shape and Material Gradient on the Shear Strength of
    Resistance Spot‐Welded Joints.” <i>Steel Research International</i>, 2024. <a
    href="https://doi.org/10.1002/srin.202300530">https://doi.org/10.1002/srin.202300530</a>.
  ieee: 'L. Schuster <i>et al.</i>, “Influences of Weld Nugget Shape and Material
    Gradient on the Shear Strength of Resistance Spot‐Welded Joints,” <i>steel research
    international</i>, 2024, doi: <a href="https://doi.org/10.1002/srin.202300530">10.1002/srin.202300530</a>.'
  mla: Schuster, Lilia, et al. “Influences of Weld Nugget Shape and Material Gradient
    on the Shear Strength of Resistance Spot‐Welded Joints.” <i>Steel Research International</i>,
    Wiley, 2024, doi:<a href="https://doi.org/10.1002/srin.202300530">10.1002/srin.202300530</a>.
  short: L. Schuster, V. Olfert, O. Sherepenko, C. Fehrenbach, S. Song, D. Hein, G.
    Meschut, E. Biro, S. Münstermann, Steel Research International (2024).
date_created: 2024-01-22T09:17:07Z
date_updated: 2024-03-18T12:49:31Z
department:
- _id: '157'
doi: 10.1002/srin.202300530
keyword:
- Materials Chemistry
- Metals and Alloys
- Physical and Theoretical Chemistry
- Condensed Matter Physics
language:
- iso: eng
publication: steel research international
publication_identifier:
  issn:
  - 1611-3683
  - 1869-344X
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Influences of Weld Nugget Shape and Material Gradient on the Shear Strength
  of Resistance Spot‐Welded Joints
type: journal_article
user_id: '5974'
year: '2024'
...
---
_id: '48639'
abstract:
- lang: eng
  text: The seven parallel dissociative ionization channels of benzonitrile yield
    highly stable fragment ions with commensurate abundance, underlining the potential
    role of the benzonitrile cation as hub species in the interstellar medium.
article_type: original
author:
- first_name: Jerry
  full_name: Kamer, Jerry
  last_name: Kamer
- first_name: Domenik
  full_name: Schleier, Domenik
  id: '98339'
  last_name: Schleier
- first_name: Merel
  full_name: Donker, Merel
  last_name: Donker
- first_name: Patrick
  full_name: Hemberger, Patrick
  last_name: Hemberger
- first_name: Andras
  full_name: Bodi, Andras
  last_name: Bodi
- first_name: Jordy
  full_name: Bouwman, Jordy
  last_name: Bouwman
citation:
  ama: Kamer J, Schleier D, Donker M, Hemberger P, Bodi A, Bouwman J. Threshold photoelectron
    spectroscopy and dissociative photoionization of benzonitrile. <i>Physical Chemistry
    Chemical Physics</i>. 2023;25(42):29070-29079. doi:<a href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>
  apa: Kamer, J., Schleier, D., Donker, M., Hemberger, P., Bodi, A., &#38; Bouwman,
    J. (2023). Threshold photoelectron spectroscopy and dissociative photoionization
    of benzonitrile. <i>Physical Chemistry Chemical Physics</i>, <i>25</i>(42), 29070–29079.
    <a href="https://doi.org/10.1039/d3cp03977c">https://doi.org/10.1039/d3cp03977c</a>
  bibtex: '@article{Kamer_Schleier_Donker_Hemberger_Bodi_Bouwman_2023, title={Threshold
    photoelectron spectroscopy and dissociative photoionization of benzonitrile},
    volume={25}, DOI={<a href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>},
    number={42}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society
    of Chemistry (RSC)}, author={Kamer, Jerry and Schleier, Domenik and Donker, Merel
    and Hemberger, Patrick and Bodi, Andras and Bouwman, Jordy}, year={2023}, pages={29070–29079}
    }'
  chicago: 'Kamer, Jerry, Domenik Schleier, Merel Donker, Patrick Hemberger, Andras
    Bodi, and Jordy Bouwman. “Threshold Photoelectron Spectroscopy and Dissociative
    Photoionization of Benzonitrile.” <i>Physical Chemistry Chemical Physics</i> 25,
    no. 42 (2023): 29070–79. <a href="https://doi.org/10.1039/d3cp03977c">https://doi.org/10.1039/d3cp03977c</a>.'
  ieee: 'J. Kamer, D. Schleier, M. Donker, P. Hemberger, A. Bodi, and J. Bouwman,
    “Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile,”
    <i>Physical Chemistry Chemical Physics</i>, vol. 25, no. 42, pp. 29070–29079,
    2023, doi: <a href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>.'
  mla: Kamer, Jerry, et al. “Threshold Photoelectron Spectroscopy and Dissociative
    Photoionization of Benzonitrile.” <i>Physical Chemistry Chemical Physics</i>,
    vol. 25, no. 42, Royal Society of Chemistry (RSC), 2023, pp. 29070–79, doi:<a
    href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>.
  short: J. Kamer, D. Schleier, M. Donker, P. Hemberger, A. Bodi, J. Bouwman, Physical
    Chemistry Chemical Physics 25 (2023) 29070–29079.
date_created: 2023-11-07T07:24:53Z
date_updated: 2023-11-13T08:00:52Z
department:
- _id: '728'
doi: 10.1039/d3cp03977c
intvolume: '        25'
issue: '42'
keyword:
- Physical and Theoretical Chemistry
- General Physics and Astronomy
language:
- iso: eng
page: 29070-29079
publication: Physical Chemistry Chemical Physics
publication_identifier:
  issn:
  - 1463-9076
  - 1463-9084
publication_status: published
publisher: Royal Society of Chemistry (RSC)
quality_controlled: '1'
status: public
title: Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile
type: journal_article
user_id: '98339'
volume: 25
year: '2023'
...
---
_id: '49356'
author:
- first_name: Stephanie L.
  full_name: Moffitt, Stephanie L.
  last_name: Moffitt
- first_name: Chuntian
  full_name: Cao, Chuntian
  last_name: Cao
- first_name: Maikel F. A. M.
  full_name: Van Hest, Maikel F. A. M.
  last_name: Van Hest
- first_name: Laura T.
  full_name: Schelhas, Laura T.
  last_name: Schelhas
- first_name: Hans-Georg
  full_name: Steinrück, Hans-Georg
  id: '84268'
  last_name: Steinrück
  orcid: 0000-0001-6373-0877
- first_name: Michael F.
  full_name: Toney, Michael F.
  last_name: Toney
citation:
  ama: Moffitt SL, Cao C, Van Hest MFAM, Schelhas LT, Steinrück H-G, Toney MF. Heterogeneous
    Structural Evolution of In–Zn–O Thin Films during Annealing. <i>The Journal of
    Physical Chemistry C</i>. 2023;127(47):23099–23108. doi:<a href="https://doi.org/10.1021/acs.jpcc.3c06410">10.1021/acs.jpcc.3c06410</a>
  apa: Moffitt, S. L., Cao, C., Van Hest, M. F. A. M., Schelhas, L. T., Steinrück,
    H.-G., &#38; Toney, M. F. (2023). Heterogeneous Structural Evolution of In–Zn–O
    Thin Films during Annealing. <i>The Journal of Physical Chemistry C</i>, <i>127</i>(47),
    23099–23108. <a href="https://doi.org/10.1021/acs.jpcc.3c06410">https://doi.org/10.1021/acs.jpcc.3c06410</a>
  bibtex: '@article{Moffitt_Cao_Van Hest_Schelhas_Steinrück_Toney_2023, title={Heterogeneous
    Structural Evolution of In–Zn–O Thin Films during Annealing}, volume={127}, DOI={<a
    href="https://doi.org/10.1021/acs.jpcc.3c06410">10.1021/acs.jpcc.3c06410</a>},
    number={47}, journal={The Journal of Physical Chemistry C}, publisher={American
    Chemical Society (ACS)}, author={Moffitt, Stephanie L. and Cao, Chuntian and Van
    Hest, Maikel F. A. M. and Schelhas, Laura T. and Steinrück, Hans-Georg and Toney,
    Michael F.}, year={2023}, pages={23099–23108} }'
  chicago: 'Moffitt, Stephanie L., Chuntian Cao, Maikel F. A. M. Van Hest, Laura T.
    Schelhas, Hans-Georg Steinrück, and Michael F. Toney. “Heterogeneous Structural
    Evolution of In–Zn–O Thin Films during Annealing.” <i>The Journal of Physical
    Chemistry C</i> 127, no. 47 (2023): 23099–23108. <a href="https://doi.org/10.1021/acs.jpcc.3c06410">https://doi.org/10.1021/acs.jpcc.3c06410</a>.'
  ieee: 'S. L. Moffitt, C. Cao, M. F. A. M. Van Hest, L. T. Schelhas, H.-G. Steinrück,
    and M. F. Toney, “Heterogeneous Structural Evolution of In–Zn–O Thin Films during
    Annealing,” <i>The Journal of Physical Chemistry C</i>, vol. 127, no. 47, pp.
    23099–23108, 2023, doi: <a href="https://doi.org/10.1021/acs.jpcc.3c06410">10.1021/acs.jpcc.3c06410</a>.'
  mla: Moffitt, Stephanie L., et al. “Heterogeneous Structural Evolution of In–Zn–O
    Thin Films during Annealing.” <i>The Journal of Physical Chemistry C</i>, vol.
    127, no. 47, American Chemical Society (ACS), 2023, pp. 23099–23108, doi:<a href="https://doi.org/10.1021/acs.jpcc.3c06410">10.1021/acs.jpcc.3c06410</a>.
  short: S.L. Moffitt, C. Cao, M.F.A.M. Van Hest, L.T. Schelhas, H.-G. Steinrück,
    M.F. Toney, The Journal of Physical Chemistry C 127 (2023) 23099–23108.
date_created: 2023-11-30T10:08:46Z
date_updated: 2023-11-30T10:09:26Z
department:
- _id: '633'
doi: 10.1021/acs.jpcc.3c06410
intvolume: '       127'
issue: '47'
keyword:
- Surfaces
- Coatings and Films
- Physical and Theoretical Chemistry
- General Energy
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
page: 23099–23108
publication: The Journal of Physical Chemistry C
publication_identifier:
  issn:
  - 1932-7447
  - 1932-7455
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Heterogeneous Structural Evolution of In–Zn–O Thin Films during Annealing
type: journal_article
user_id: '84268'
volume: 127
year: '2023'
...
---
_id: '50150'
abstract:
- lang: eng
  text: <jats:p>Covalent peptidomimetic protease inhibitors have gained a lot of attention
    in drug development in recent years. They are designed to covalently bind the
    catalytically active amino acids through electrophilic groups called warheads.
    Covalent inhibition has an advantage in terms of pharmacodynamic properties but
    can also bear toxicity risks due to non-selective off-target protein binding.
    Therefore, the right combination of a reactive warhead with a well-suited peptidomimetic
    sequence is of great importance. Herein, the selectivities of well-known warheads
    combined with peptidomimetic sequences suited for five different proteases were
    investigated, highlighting the impact of both structure parts (warhead and peptidomimetic
    sequence) for affinity and selectivity. Molecular docking gave insights into the
    predicted binding modes of the inhibitors inside the binding pockets of the different
    enzymes. Moreover, the warheads were investigated by NMR and LC-MS reactivity
    assays against serine/threonine and cysteine nucleophile models, as well as by
    quantum mechanics simulations.</jats:p>
article_number: '7226'
author:
- first_name: Patrick
  full_name: Müller, Patrick
  last_name: Müller
- first_name: Mergim
  full_name: Meta, Mergim
  last_name: Meta
- first_name: Jan Laurenz
  full_name: Meidner, Jan Laurenz
  last_name: Meidner
- first_name: Marvin
  full_name: Schwickert, Marvin
  last_name: Schwickert
- first_name: Jessica
  full_name: Meyr, Jessica
  last_name: Meyr
- first_name: Kevin
  full_name: Schwickert, Kevin
  last_name: Schwickert
- first_name: Christian
  full_name: Kersten, Christian
  last_name: Kersten
- first_name: Collin
  full_name: Zimmer, Collin
  last_name: Zimmer
- first_name: Stefan Josef
  full_name: Hammerschmidt, Stefan Josef
  last_name: Hammerschmidt
- first_name: Ariane
  full_name: Frey, Ariane
  last_name: Frey
- first_name: Albin
  full_name: Lahu, Albin
  last_name: Lahu
- first_name: Sergio
  full_name: de la Hoz-Rodríguez, Sergio
  last_name: de la Hoz-Rodríguez
- first_name: Laura
  full_name: Agost-Beltrán, Laura
  last_name: Agost-Beltrán
- first_name: Santiago
  full_name: Rodríguez, Santiago
  last_name: Rodríguez
- first_name: Kira
  full_name: Diemer, Kira
  last_name: Diemer
- first_name: Wilhelm
  full_name: Neumann, Wilhelm
  last_name: Neumann
- first_name: Florenci V.
  full_name: Gonzàlez, Florenci V.
  last_name: Gonzàlez
- first_name: Bernd
  full_name: Engels, Bernd
  last_name: Engels
- first_name: Tanja
  full_name: Schirmeister, Tanja
  last_name: Schirmeister
citation:
  ama: Müller P, Meta M, Meidner JL, et al. Investigation of the Compatibility between
    Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
    and Selectivity Study. <i>International Journal of Molecular Sciences</i>. 2023;24(8).
    doi:<a href="https://doi.org/10.3390/ijms24087226">10.3390/ijms24087226</a>
  apa: Müller, P., Meta, M., Meidner, J. L., Schwickert, M., Meyr, J., Schwickert,
    K., Kersten, C., Zimmer, C., Hammerschmidt, S. J., Frey, A., Lahu, A., de la Hoz-Rodríguez,
    S., Agost-Beltrán, L., Rodríguez, S., Diemer, K., Neumann, W., Gonzàlez, F. V.,
    Engels, B., &#38; Schirmeister, T. (2023). Investigation of the Compatibility
    between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive
    Reactivity and Selectivity Study. <i>International Journal of Molecular Sciences</i>,
    <i>24</i>(8), Article 7226. <a href="https://doi.org/10.3390/ijms24087226">https://doi.org/10.3390/ijms24087226</a>
  bibtex: '@article{Müller_Meta_Meidner_Schwickert_Meyr_Schwickert_Kersten_Zimmer_Hammerschmidt_Frey_et
    al._2023, title={Investigation of the Compatibility between Warheads and Peptidomimetic
    Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study},
    volume={24}, DOI={<a href="https://doi.org/10.3390/ijms24087226">10.3390/ijms24087226</a>},
    number={87226}, journal={International Journal of Molecular Sciences}, publisher={MDPI
    AG}, author={Müller, Patrick and Meta, Mergim and Meidner, Jan Laurenz and Schwickert,
    Marvin and Meyr, Jessica and Schwickert, Kevin and Kersten, Christian and Zimmer,
    Collin and Hammerschmidt, Stefan Josef and Frey, Ariane and et al.}, year={2023}
    }'
  chicago: Müller, Patrick, Mergim Meta, Jan Laurenz Meidner, Marvin Schwickert, Jessica
    Meyr, Kevin Schwickert, Christian Kersten, et al. “Investigation of the Compatibility
    between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive
    Reactivity and Selectivity Study.” <i>International Journal of Molecular Sciences</i>
    24, no. 8 (2023). <a href="https://doi.org/10.3390/ijms24087226">https://doi.org/10.3390/ijms24087226</a>.
  ieee: 'P. Müller <i>et al.</i>, “Investigation of the Compatibility between Warheads
    and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
    and Selectivity Study,” <i>International Journal of Molecular Sciences</i>, vol.
    24, no. 8, Art. no. 7226, 2023, doi: <a href="https://doi.org/10.3390/ijms24087226">10.3390/ijms24087226</a>.'
  mla: Müller, Patrick, et al. “Investigation of the Compatibility between Warheads
    and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
    and Selectivity Study.” <i>International Journal of Molecular Sciences</i>, vol.
    24, no. 8, 7226, MDPI AG, 2023, doi:<a href="https://doi.org/10.3390/ijms24087226">10.3390/ijms24087226</a>.
  short: P. Müller, M. Meta, J.L. Meidner, M. Schwickert, J. Meyr, K. Schwickert,
    C. Kersten, C. Zimmer, S.J. Hammerschmidt, A. Frey, A. Lahu, S. de la Hoz-Rodríguez,
    L. Agost-Beltrán, S. Rodríguez, K. Diemer, W. Neumann, F.V. Gonzàlez, B. Engels,
    T. Schirmeister, International Journal of Molecular Sciences 24 (2023).
date_created: 2024-01-04T08:24:31Z
date_updated: 2024-01-05T12:59:32Z
doi: 10.3390/ijms24087226
intvolume: '        24'
issue: '8'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
project:
- _id: '52'
  name: 'PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing'
publication: International Journal of Molecular Sciences
publication_identifier:
  issn:
  - 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Investigation of the Compatibility between Warheads and Peptidomimetic Sequences
  of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study
type: journal_article
user_id: '67287'
volume: 24
year: '2023'
...
---
_id: '46023'
abstract:
- lang: eng
  text: <jats:p>This article presents the potential-dependent adsorption of two proteins,
    bovine serum albumin (BSA) and lysozyme (LYZ), on Ti6Al4V alloy at pH 7.4 and
    37 °C. The adsorption process was studied on an electropolished alloy under cathodic
    and anodic overpotentials, compared to the open circuit potential (OCP). To analyze
    the adsorption process, various complementary interface analytical techniques
    were employed, including PM-IRRAS (polarization-modulation infrared reflection-absorption
    spectroscopy), AFM (atomic force microscopy), XPS (X-ray photoelectron spectroscopy),
    and E-QCM (electrochemical quartz crystal microbalance) measurements. The polarization
    experiments were conducted within a potential range where charging of the electric
    double layer dominates, and Faradaic currents can be disregarded. The findings
    highlight the significant influence of the interfacial charge distribution on
    the adsorption of BSA and LYZ onto the alloy surface. Furthermore, electrochemical
    analysis of the protein layers formed under applied overpotentials demonstrated
    improved corrosion protection properties. These studies provide valuable insights
    into protein adsorption on titanium alloys under physiological conditions, characterized
    by varying potentials of the passive alloy.</jats:p>
article_number: '5109'
author:
- first_name: Belma
  full_name: Duderija, Belma
  last_name: Duderija
- first_name: Alejandro
  full_name: González-Orive, Alejandro
  last_name: González-Orive
- first_name: Christoph
  full_name: Ebbert, Christoph
  last_name: Ebbert
- first_name: Vanessa
  full_name: Neßlinger, Vanessa
  last_name: Neßlinger
- first_name: Adrian
  full_name: Keller, Adrian
  last_name: Keller
- first_name: Guido
  full_name: Grundmeier, Guido
  last_name: Grundmeier
citation:
  ama: Duderija B, González-Orive A, Ebbert C, Neßlinger V, Keller A, Grundmeier G.
    Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy.
    <i>Molecules</i>. 2023;28(13). doi:<a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>
  apa: Duderija, B., González-Orive, A., Ebbert, C., Neßlinger, V., Keller, A., &#38;
    Grundmeier, G. (2023). Electrode Potential-Dependent Studies of Protein Adsorption
    on Ti6Al4V Alloy. <i>Molecules</i>, <i>28</i>(13), Article 5109. <a href="https://doi.org/10.3390/molecules28135109">https://doi.org/10.3390/molecules28135109</a>
  bibtex: '@article{Duderija_González-Orive_Ebbert_Neßlinger_Keller_Grundmeier_2023,
    title={Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V
    Alloy}, volume={28}, DOI={<a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>},
    number={135109}, journal={Molecules}, publisher={MDPI AG}, author={Duderija, Belma
    and González-Orive, Alejandro and Ebbert, Christoph and Neßlinger, Vanessa and
    Keller, Adrian and Grundmeier, Guido}, year={2023} }'
  chicago: Duderija, Belma, Alejandro González-Orive, Christoph Ebbert, Vanessa Neßlinger,
    Adrian Keller, and Guido Grundmeier. “Electrode Potential-Dependent Studies of
    Protein Adsorption on Ti6Al4V Alloy.” <i>Molecules</i> 28, no. 13 (2023). <a href="https://doi.org/10.3390/molecules28135109">https://doi.org/10.3390/molecules28135109</a>.
  ieee: 'B. Duderija, A. González-Orive, C. Ebbert, V. Neßlinger, A. Keller, and G.
    Grundmeier, “Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V
    Alloy,” <i>Molecules</i>, vol. 28, no. 13, Art. no. 5109, 2023, doi: <a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>.'
  mla: Duderija, Belma, et al. “Electrode Potential-Dependent Studies of Protein Adsorption
    on Ti6Al4V Alloy.” <i>Molecules</i>, vol. 28, no. 13, 5109, MDPI AG, 2023, doi:<a
    href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>.
  short: B. Duderija, A. González-Orive, C. Ebbert, V. Neßlinger, A. Keller, G. Grundmeier,
    Molecules 28 (2023).
date_created: 2023-07-12T07:55:40Z
date_updated: 2024-02-06T12:33:55Z
department:
- _id: '321'
- _id: '302'
doi: 10.3390/molecules28135109
intvolume: '        28'
issue: '13'
keyword:
- Chemistry (miscellaneous)
- Analytical Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Molecular Medicine
- Drug Discovery
- Pharmaceutical Science
language:
- iso: eng
publication: Molecules
publication_identifier:
  issn:
  - 1420-3049
publication_status: published
publisher: MDPI AG
status: public
title: Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy
type: journal_article
user_id: '54863'
volume: 28
year: '2023'
...
---
_id: '52345'
abstract:
- lang: eng
  text: Photoactive chromium(III) complexes saw a conceptual breakthrough with the
    discovery of the prototypical molecular ruby mer-[Cr(ddpd)2]3+ (ddpd = N,N′-dimethyl-N,N′-dipyridin-2-ylpyridine-2,6-diamine),
    which shows intense long-lived near-infrared (NIR) phosphorescence from metal-centered
    spin-flip states. In contrast to the numerous studies on chromium(III) photophysics,
    only 10 luminescent molybdenum(III) complexes have been reported so far. Here,
    we present the synthesis and characterization of mer-MoX3(ddpd) (1, X = Cl; 2,
    X = Br) and cisfac-[Mo(ddpd)2]3+ (cisfac-[3]3+), an isomeric heavy homologue of
    the prototypical molecular ruby. For cisfac-[3]3+, we found strong zero-field
    splitting using magnetic susceptibility measurements and electron paramagnetic
    resonance spectroscopy. Electronic spectra covering the spin-forbidden transitions
    show that the spin-flip states in mer-1, mer-2, and cisfac-[3]3+ are much lower
    in energy than those in comparable chromium(III) compounds. While all three complexes
    show weak spin-flip phosphorescence in NIR-II, the emission of cisfac-[3]3+ peaking
    at 1550 nm is particularly low in energy. Femtosecond transient absorption spectroscopy
    reveals a short excited-state lifetime of 1.4 ns, 6 orders of magnitude shorter
    than that of mer-[Cr(ddpd)2]3+. Using density functional theory and ab initio
    multireference calculations, we break down the reasons for this disparity and
    derive principles for the design of future stable photoactive molybdenum(III)
    complexes.
article_type: original
author:
- first_name: Winald R.
  full_name: Kitzmann, Winald R.
  last_name: Kitzmann
- first_name: David
  full_name: Hunger, David
  last_name: Hunger
- first_name: Antti-Pekka M.
  full_name: Reponen, Antti-Pekka M.
  last_name: Reponen
- first_name: Christoph
  full_name: Förster, Christoph
  last_name: Förster
- first_name: Roland
  full_name: Schoch, Roland
  id: '48467'
  last_name: Schoch
  orcid: 0000-0003-2061-7289
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
- first_name: Sascha
  full_name: Feldmann, Sascha
  last_name: Feldmann
- first_name: Joris
  full_name: van Slageren, Joris
  last_name: van Slageren
- first_name: Katja
  full_name: Heinze, Katja
  last_name: Heinze
citation:
  ama: Kitzmann WR, Hunger D, Reponen A-PM, et al. Electronic Structure and Excited-State
    Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby.
    <i>Inorganic Chemistry</i>. 2023;62(39):15797-15808. doi:<a href="https://doi.org/10.1021/acs.inorgchem.3c02186">10.1021/acs.inorgchem.3c02186</a>
  apa: Kitzmann, W. R., Hunger, D., Reponen, A.-P. M., Förster, C., Schoch, R., Bauer,
    M., Feldmann, S., van Slageren, J., &#38; Heinze, K. (2023). Electronic Structure
    and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III) Analogue to
    the Molecular Ruby. <i>Inorganic Chemistry</i>, <i>62</i>(39), 15797–15808. <a
    href="https://doi.org/10.1021/acs.inorgchem.3c02186">https://doi.org/10.1021/acs.inorgchem.3c02186</a>
  bibtex: '@article{Kitzmann_Hunger_Reponen_Förster_Schoch_Bauer_Feldmann_van Slageren_Heinze_2023,
    title={Electronic Structure and Excited-State Dynamics of the NIR-II Emissive
    Molybdenum(III) Analogue to the Molecular Ruby}, volume={62}, DOI={<a href="https://doi.org/10.1021/acs.inorgchem.3c02186">10.1021/acs.inorgchem.3c02186</a>},
    number={39}, journal={Inorganic Chemistry}, publisher={American Chemical Society
    (ACS)}, author={Kitzmann, Winald R. and Hunger, David and Reponen, Antti-Pekka
    M. and Förster, Christoph and Schoch, Roland and Bauer, Matthias and Feldmann,
    Sascha and van Slageren, Joris and Heinze, Katja}, year={2023}, pages={15797–15808}
    }'
  chicago: 'Kitzmann, Winald R., David Hunger, Antti-Pekka M. Reponen, Christoph Förster,
    Roland Schoch, Matthias Bauer, Sascha Feldmann, Joris van Slageren, and Katja
    Heinze. “Electronic Structure and Excited-State Dynamics of the NIR-II Emissive
    Molybdenum(III) Analogue to the Molecular Ruby.” <i>Inorganic Chemistry</i> 62,
    no. 39 (2023): 15797–808. <a href="https://doi.org/10.1021/acs.inorgchem.3c02186">https://doi.org/10.1021/acs.inorgchem.3c02186</a>.'
  ieee: 'W. R. Kitzmann <i>et al.</i>, “Electronic Structure and Excited-State Dynamics
    of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby,” <i>Inorganic
    Chemistry</i>, vol. 62, no. 39, pp. 15797–15808, 2023, doi: <a href="https://doi.org/10.1021/acs.inorgchem.3c02186">10.1021/acs.inorgchem.3c02186</a>.'
  mla: Kitzmann, Winald R., et al. “Electronic Structure and Excited-State Dynamics
    of the NIR-II Emissive Molybdenum(III) Analogue to the Molecular Ruby.” <i>Inorganic
    Chemistry</i>, vol. 62, no. 39, American Chemical Society (ACS), 2023, pp. 15797–808,
    doi:<a href="https://doi.org/10.1021/acs.inorgchem.3c02186">10.1021/acs.inorgchem.3c02186</a>.
  short: W.R. Kitzmann, D. Hunger, A.-P.M. Reponen, C. Förster, R. Schoch, M. Bauer,
    S. Feldmann, J. van Slageren, K. Heinze, Inorganic Chemistry 62 (2023) 15797–15808.
date_created: 2024-03-07T09:57:30Z
date_updated: 2024-03-07T10:02:58Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.3c02186
intvolume: '        62'
issue: '39'
keyword:
- Inorganic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 15797-15808
publication: Inorganic Chemistry
publication_identifier:
  issn:
  - 0020-1669
  - 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Electronic Structure and Excited-State Dynamics of the NIR-II Emissive Molybdenum(III)
  Analogue to the Molecular Ruby
type: journal_article
user_id: '48467'
volume: 62
year: '2023'
...
---
_id: '53078'
abstract:
- lang: eng
  text: In spray-flame synthesis of nanoparticles, a precise understanding of the
    reaction processes is necessary to find optimal process parameters for the formation
    of the desired products. Coupling the chemistries of flame, solvent, and gas-phase
    species initially formed from the particle precursor in combination with the complex
    flow geometry of the spray flame means a special challenge for the modeling of
    the reaction processes. A new burner has been developed that is capable to observe
    the reaction of precursor solutions frequently used in spray-flame synthesis.
    The burner provides an almost flat, laminar, and steady flame with homogeneous
    addition of a fine aerosol and thus enables detailed investigation and modeling
    of the coupled reactions inde-pendent of spray formation and turbulent mixing.
    With its two separate supply channel matrices, the burner also enables the use
    of reactants that would otherwise react with each other already before reaching
    the flame. These features enable the investigation of a wide range of flame-based
    synthesis methods for nanoparticles and, due to the flat-flame geometry, kinetics
    models for these processes can be developed and validated. This work describes
    the matrix burner development and its gas flow optimization by simulation. Droplet-size
    dis-tributions generated by ultrasonic nebulization and their interaction with
    the burner structure are investigated by phase-Doppler anemometry. As an example
    for nanoparticle-for ming flames from solutions, iron-oxide nanoparticle-generating
    flames using iron(III) nitrate nonahydrate dissolved in 1-butanol were investigated.
    This effort includes measurements of two-dimensional maps of the flame temperature
    by a thermocouple and height-dependent concentration profiles of the main species
    by time-of-flight mass spectrometry. Exper-imental data are compared with 1D simulations
    using a reduced reaction mechanism. The results show that the new burner is well
    suited for the development of reaction models for precursors supplied in the liquid
    phase usually applied in spray-flame synthesis configurations.& COPY; 2022 The
    Combustion Institute. Published by Elsevier Inc. All rights reserved.
article_type: original
author:
- first_name: Sascha
  full_name: Apazeller, Sascha
  last_name: Apazeller
- first_name: Munko
  full_name: Gonchikzhapov, Munko
  last_name: Gonchikzhapov
- first_name: Monika
  full_name: Nanjaiah, Monika
  last_name: Nanjaiah
- first_name: Tina
  full_name: Kasper, Tina
  last_name: Kasper
- first_name: Irenäus
  full_name: Wlokas, Irenäus
  last_name: Wlokas
- first_name: Hartmut
  full_name: Wiggers, Hartmut
  last_name: Wiggers
- first_name: Christof
  full_name: Schulz, Christof
  last_name: Schulz
citation:
  ama: Apazeller S, Gonchikzhapov M, Nanjaiah M, et al. A new dual matrix burner for
    one-dimensional investigation of aerosol flames. <i>Proceedings of the Combustion
    Institute</i>. 2023;39(1):909-918. doi:<a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>
  apa: Apazeller, S., Gonchikzhapov, M., Nanjaiah, M., Kasper, T., Wlokas, I., Wiggers,
    H., &#38; Schulz, C. (2023). A new dual matrix burner for one-dimensional investigation
    of aerosol flames. <i>Proceedings of the Combustion Institute</i>, <i>39</i>(1),
    909–918. <a href="https://doi.org/10.1016/j.proci.2022.07.166">https://doi.org/10.1016/j.proci.2022.07.166</a>
  bibtex: '@article{Apazeller_Gonchikzhapov_Nanjaiah_Kasper_Wlokas_Wiggers_Schulz_2023,
    title={A new dual matrix burner for one-dimensional investigation of aerosol flames},
    volume={39}, DOI={<a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>},
    number={1}, journal={Proceedings of the Combustion Institute}, publisher={Elsevier
    BV}, author={Apazeller, Sascha and Gonchikzhapov, Munko and Nanjaiah, Monika and
    Kasper, Tina and Wlokas, Irenäus and Wiggers, Hartmut and Schulz, Christof}, year={2023},
    pages={909–918} }'
  chicago: 'Apazeller, Sascha, Munko Gonchikzhapov, Monika Nanjaiah, Tina Kasper,
    Irenäus Wlokas, Hartmut Wiggers, and Christof Schulz. “A New Dual Matrix Burner
    for One-Dimensional Investigation of Aerosol Flames.” <i>Proceedings of the Combustion
    Institute</i> 39, no. 1 (2023): 909–18. <a href="https://doi.org/10.1016/j.proci.2022.07.166">https://doi.org/10.1016/j.proci.2022.07.166</a>.'
  ieee: 'S. Apazeller <i>et al.</i>, “A new dual matrix burner for one-dimensional
    investigation of aerosol flames,” <i>Proceedings of the Combustion Institute</i>,
    vol. 39, no. 1, pp. 909–918, 2023, doi: <a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>.'
  mla: Apazeller, Sascha, et al. “A New Dual Matrix Burner for One-Dimensional Investigation
    of Aerosol Flames.” <i>Proceedings of the Combustion Institute</i>, vol. 39, no.
    1, Elsevier BV, 2023, pp. 909–18, doi:<a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>.
  short: S. Apazeller, M. Gonchikzhapov, M. Nanjaiah, T. Kasper, I. Wlokas, H. Wiggers,
    C. Schulz, Proceedings of the Combustion Institute 39 (2023) 909–918.
date_created: 2024-03-27T16:14:34Z
date_updated: 2024-03-27T16:30:15Z
department:
- _id: '728'
doi: 10.1016/j.proci.2022.07.166
intvolume: '        39'
issue: '1'
keyword:
- Physical and Theoretical Chemistry
- Mechanical Engineering
- General Chemical Engineering
language:
- iso: eng
page: 909-918
publication: Proceedings of the Combustion Institute
publication_identifier:
  issn:
  - 1540-7489
publication_status: published
publisher: Elsevier BV
quality_controlled: '1'
status: public
title: A new dual matrix burner for one-dimensional investigation of aerosol flames
type: journal_article
user_id: '94562'
volume: 39
year: '2023'
...
---
_id: '36812'
author:
- first_name: Sascha
  full_name: Apazeller, Sascha
  last_name: Apazeller
- first_name: Munko
  full_name: Gonchikzhapov, Munko
  id: '94996'
  last_name: Gonchikzhapov
  orcid: https://orcid.org/0000-0002-7773-047X
- first_name: Monika
  full_name: Nanjaiah, Monika
  last_name: Nanjaiah
- first_name: Tina
  full_name: Kasper, Tina
  id: '94562'
  last_name: Kasper
  orcid: '0000-0003-3993-5316 '
- first_name: Irenäus
  full_name: Wlokas, Irenäus
  last_name: Wlokas
- first_name: Hartmut
  full_name: Wiggers, Hartmut
  last_name: Wiggers
- first_name: Christof
  full_name: Schulz, Christof
  last_name: Schulz
citation:
  ama: Apazeller S, Gonchikzhapov M, Nanjaiah M, et al. A new dual matrix burner for
    one-dimensional investigation of aerosol flames. <i>Proceedings of the Combustion
    Institute</i>. Published online 2023. doi:<a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>
  apa: Apazeller, S., Gonchikzhapov, M., Nanjaiah, M., Kasper, T., Wlokas, I., Wiggers,
    H., &#38; Schulz, C. (2023). A new dual matrix burner for one-dimensional investigation
    of aerosol flames. <i>Proceedings of the Combustion Institute</i>. <a href="https://doi.org/10.1016/j.proci.2022.07.166">https://doi.org/10.1016/j.proci.2022.07.166</a>
  bibtex: '@article{Apazeller_Gonchikzhapov_Nanjaiah_Kasper_Wlokas_Wiggers_Schulz_2023,
    title={A new dual matrix burner for one-dimensional investigation of aerosol flames},
    DOI={<a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>},
    journal={Proceedings of the Combustion Institute}, publisher={Elsevier BV}, author={Apazeller,
    Sascha and Gonchikzhapov, Munko and Nanjaiah, Monika and Kasper, Tina and Wlokas,
    Irenäus and Wiggers, Hartmut and Schulz, Christof}, year={2023} }'
  chicago: Apazeller, Sascha, Munko Gonchikzhapov, Monika Nanjaiah, Tina Kasper, Irenäus
    Wlokas, Hartmut Wiggers, and Christof Schulz. “A New Dual Matrix Burner for One-Dimensional
    Investigation of Aerosol Flames.” <i>Proceedings of the Combustion Institute</i>,
    2023. <a href="https://doi.org/10.1016/j.proci.2022.07.166">https://doi.org/10.1016/j.proci.2022.07.166</a>.
  ieee: 'S. Apazeller <i>et al.</i>, “A new dual matrix burner for one-dimensional
    investigation of aerosol flames,” <i>Proceedings of the Combustion Institute</i>,
    2023, doi: <a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>.'
  mla: Apazeller, Sascha, et al. “A New Dual Matrix Burner for One-Dimensional Investigation
    of Aerosol Flames.” <i>Proceedings of the Combustion Institute</i>, Elsevier BV,
    2023, doi:<a href="https://doi.org/10.1016/j.proci.2022.07.166">10.1016/j.proci.2022.07.166</a>.
  short: S. Apazeller, M. Gonchikzhapov, M. Nanjaiah, T. Kasper, I. Wlokas, H. Wiggers,
    C. Schulz, Proceedings of the Combustion Institute (2023).
date_created: 2023-01-13T16:28:59Z
date_updated: 2024-03-27T17:31:06Z
department:
- _id: '9'
- _id: '728'
doi: 10.1016/j.proci.2022.07.166
keyword:
- Physical and Theoretical Chemistry
- Mechanical Engineering
- General Chemical Engineering
language:
- iso: eng
publication: Proceedings of the Combustion Institute
publication_identifier:
  issn:
  - 1540-7489
publication_status: published
publisher: Elsevier BV
status: public
title: A new dual matrix burner for one-dimensional investigation of aerosol flames
type: journal_article
user_id: '94562'
year: '2023'
...
---
_id: '52344'
abstract:
- lang: eng
  text: Macrocyclization reactions are still challenging due to competing oligomerization,
    which requires the use of small substrate concentrations. Here, the cationic tungsten
    imido and tungsten oxo alkylidene N-heterocyclic carbene complexes [[W(N-2,6-Cl2-C6H3)(CHCMe2Ph(OC6F5)(pivalonitrile)(IMes)+
    B(ArF)4−] (W1) and [W(O)(CHCMe2Ph(OCMe(CF3)2)(IMes)(CH3CN)+ B(ArF)4−] (W2) (IMes=1,3-dimesitylimidazol-2-ylidene;
    B(ArF)4−=tetrakis(3,5-bis(trifluoromethyl)phenyl borate) have been immobilized
    inside the pores of ordered mesoporous silica (OMS) with pore diameters of 3.3
    and 6.8 nm, respectively, using a pore-selective immobilization protocol. X-ray
    absorption spectroscopy of W1@OMS showed that even though the catalyst structure
    is contracted due to confinement by the mesopores, both the oxidation state and
    structure of the catalyst stayed intact upon immobilization. Catalytic testing
    with four differently sized α,ω-dienes revealed a dramatically increased macrocyclization
    (MC) and Z-selectivity of the supported catalysts compared to the homogenous progenitors,
    allowing high substrate concentrations of 25 mM. With the supported complexes,
    a maximum increase in MC-selectivity from 27 to 81 % and in Z-selectivity from
    17 to 34 % was achieved. In general, smaller mesopores exhibited a stronger confinement
    effect. A comparison of the two supported tungsten-based catalysts showed that
    W1@OMS possesses a higher MC-selectivity, while W2@OMS exhibits a higher Z-selectivity
    which can be rationalized by the structures of the catalysts.
article_type: original
author:
- first_name: Felix
  full_name: Ziegler, Felix
  last_name: Ziegler
- first_name: Johanna R.
  full_name: Bruckner, Johanna R.
  last_name: Bruckner
- first_name: Michał
  full_name: Nowakowski, Michał
  id: '78878'
  last_name: Nowakowski
  orcid: 0000-0002-3734-7011
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
- first_name: Patrick
  full_name: Probst, Patrick
  last_name: Probst
- first_name: Boshra
  full_name: Atwi, Boshra
  last_name: Atwi
- first_name: Michael R.
  full_name: Buchmeiser, Michael R.
  last_name: Buchmeiser
citation:
  ama: Ziegler F, Bruckner JR, Nowakowski M, et al. Macrocyclization of Dienes under
    Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic
    Carbene Complexes. <i>ChemCatChem</i>. 2023;15(21). doi:<a href="https://doi.org/10.1002/cctc.202300871">10.1002/cctc.202300871</a>
  apa: Ziegler, F., Bruckner, J. R., Nowakowski, M., Bauer, M., Probst, P., Atwi,
    B., &#38; Buchmeiser, M. R. (2023). Macrocyclization of Dienes under Confinement
    with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes.
    <i>ChemCatChem</i>, <i>15</i>(21). <a href="https://doi.org/10.1002/cctc.202300871">https://doi.org/10.1002/cctc.202300871</a>
  bibtex: '@article{Ziegler_Bruckner_Nowakowski_Bauer_Probst_Atwi_Buchmeiser_2023,
    title={Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo
    Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes}, volume={15}, DOI={<a href="https://doi.org/10.1002/cctc.202300871">10.1002/cctc.202300871</a>},
    number={21}, journal={ChemCatChem}, publisher={Wiley}, author={Ziegler, Felix
    and Bruckner, Johanna R. and Nowakowski, Michał and Bauer, Matthias and Probst,
    Patrick and Atwi, Boshra and Buchmeiser, Michael R.}, year={2023} }'
  chicago: Ziegler, Felix, Johanna R. Bruckner, Michał Nowakowski, Matthias Bauer,
    Patrick Probst, Boshra Atwi, and Michael R. Buchmeiser. “Macrocyclization of Dienes
    under Confinement with Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic
    Carbene Complexes.” <i>ChemCatChem</i> 15, no. 21 (2023). <a href="https://doi.org/10.1002/cctc.202300871">https://doi.org/10.1002/cctc.202300871</a>.
  ieee: 'F. Ziegler <i>et al.</i>, “Macrocyclization of Dienes under Confinement with
    Cationic Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes,”
    <i>ChemCatChem</i>, vol. 15, no. 21, 2023, doi: <a href="https://doi.org/10.1002/cctc.202300871">10.1002/cctc.202300871</a>.'
  mla: Ziegler, Felix, et al. “Macrocyclization of Dienes under Confinement with Cationic
    Tungsten Imido/Oxo Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes.” <i>ChemCatChem</i>,
    vol. 15, no. 21, Wiley, 2023, doi:<a href="https://doi.org/10.1002/cctc.202300871">10.1002/cctc.202300871</a>.
  short: F. Ziegler, J.R. Bruckner, M. Nowakowski, M. Bauer, P. Probst, B. Atwi, M.R.
    Buchmeiser, ChemCatChem 15 (2023).
date_created: 2024-03-07T09:44:33Z
date_updated: 2024-05-07T11:41:51Z
department:
- _id: '306'
doi: 10.1002/cctc.202300871
intvolume: '        15'
issue: '21'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Catalysis
language:
- iso: eng
publication: ChemCatChem
publication_identifier:
  issn:
  - 1867-3880
  - 1867-3899
publication_status: published
publisher: Wiley
status: public
title: Macrocyclization of Dienes under Confinement with Cationic Tungsten Imido/Oxo
  Alkylidene <i>N</i>‐Heterocyclic Carbene Complexes
type: journal_article
user_id: '48467'
volume: 15
year: '2023'
...
---
_id: '43391'
abstract:
- lang: eng
  text: The technical importance of paraffins as phase change materials (PCM) in heat
    storage systems increases. Knowledge on the thermal conductivity of paraffins
    is necessary for the design and optimization of heat storage systems. However,
    for most paraffins solely the thermal conductivity of the liquid state has been
    sufficiently investigated. For the solid state, precise thermal conductivity data
    are only known for a few paraffins, while only generalized values are available
    for the remainder, some of which contradict each other. In this study, a measurement
    setup based on the modified guarded hot plate method is developed. It is used
    to investigate the thermal conductivity of several paraffines in the solid state,
    including pure n-docosane and its compounds with different types and concentrations
    of graphite. For n-docosane in the solid state, the thermal conductivity is determined
    to be 0.49 W/(m K). A particle size of 200 μm with a spherical shape turns out
    to be optimal to increase the thermal conductivity. This allows the thermal conductivity
    of a compound with 10% graphite to increase by a factor of three compared to the
    pure paraffin. Furthermore, significant differences to thermal conductivity data
    from the literature are found.
author:
- first_name: Andreas
  full_name: Paul, Andreas
  id: '7828'
  last_name: Paul
- first_name: Elmar
  full_name: Baumhögger, Elmar
  id: '15164'
  last_name: Baumhögger
- first_name: Mats-Ole
  full_name: Dewerth, Mats-Ole
  id: '49826'
  last_name: Dewerth
- first_name: Iman
  full_name: Hami Dindar, Iman
  id: '54836'
  last_name: Hami Dindar
- first_name: Gerrit
  full_name: Sonnenrein, Gerrit
  last_name: Sonnenrein
- first_name: Jadran
  full_name: Vrabec, Jadran
  last_name: Vrabec
citation:
  ama: Paul A, Baumhögger E, Dewerth M-O, Hami Dindar I, Sonnenrein G, Vrabec J. Thermal
    conductivity of solid paraffins and several n-docosane compounds with graphite.
    <i>Journal of Thermal Analysis and Calorimetry</i>. Published online 2023. doi:<a
    href="https://doi.org/10.1007/s10973-023-12107-2">10.1007/s10973-023-12107-2</a>
  apa: Paul, A., Baumhögger, E., Dewerth, M.-O., Hami Dindar, I., Sonnenrein, G.,
    &#38; Vrabec, J. (2023). Thermal conductivity of solid paraffins and several n-docosane
    compounds with graphite. <i>Journal of Thermal Analysis and Calorimetry</i>. <a
    href="https://doi.org/10.1007/s10973-023-12107-2">https://doi.org/10.1007/s10973-023-12107-2</a>
  bibtex: '@article{Paul_Baumhögger_Dewerth_Hami Dindar_Sonnenrein_Vrabec_2023, title={Thermal
    conductivity of solid paraffins and several n-docosane compounds with graphite},
    DOI={<a href="https://doi.org/10.1007/s10973-023-12107-2">10.1007/s10973-023-12107-2</a>},
    journal={Journal of Thermal Analysis and Calorimetry}, publisher={Springer Science
    and Business Media LLC}, author={Paul, Andreas and Baumhögger, Elmar and Dewerth,
    Mats-Ole and Hami Dindar, Iman and Sonnenrein, Gerrit and Vrabec, Jadran}, year={2023}
    }'
  chicago: Paul, Andreas, Elmar Baumhögger, Mats-Ole Dewerth, Iman Hami Dindar, Gerrit
    Sonnenrein, and Jadran Vrabec. “Thermal Conductivity of Solid Paraffins and Several
    N-Docosane Compounds with Graphite.” <i>Journal of Thermal Analysis and Calorimetry</i>,
    2023. <a href="https://doi.org/10.1007/s10973-023-12107-2">https://doi.org/10.1007/s10973-023-12107-2</a>.
  ieee: 'A. Paul, E. Baumhögger, M.-O. Dewerth, I. Hami Dindar, G. Sonnenrein, and
    J. Vrabec, “Thermal conductivity of solid paraffins and several n-docosane compounds
    with graphite,” <i>Journal of Thermal Analysis and Calorimetry</i>, 2023, doi:
    <a href="https://doi.org/10.1007/s10973-023-12107-2">10.1007/s10973-023-12107-2</a>.'
  mla: Paul, Andreas, et al. “Thermal Conductivity of Solid Paraffins and Several
    N-Docosane Compounds with Graphite.” <i>Journal of Thermal Analysis and Calorimetry</i>,
    Springer Science and Business Media LLC, 2023, doi:<a href="https://doi.org/10.1007/s10973-023-12107-2">10.1007/s10973-023-12107-2</a>.
  short: A. Paul, E. Baumhögger, M.-O. Dewerth, I. Hami Dindar, G. Sonnenrein, J.
    Vrabec, Journal of Thermal Analysis and Calorimetry (2023).
date_created: 2023-04-04T06:48:57Z
date_updated: 2023-04-27T11:10:32Z
department:
- _id: '728'
- _id: '145'
- _id: '393'
- _id: '9'
doi: 10.1007/s10973-023-12107-2
keyword:
- Physical and Theoretical Chemistry
- Condensed Matter Physics
language:
- iso: eng
publication: Journal of Thermal Analysis and Calorimetry
publication_identifier:
  issn:
  - 1388-6150
  - 1588-2926
publication_status: published
publisher: Springer Science and Business Media LLC
quality_controlled: '1'
status: public
title: Thermal conductivity of solid paraffins and several n-docosane compounds with
  graphite
type: journal_article
user_id: '7828'
year: '2023'
...
---
_id: '45828'
abstract:
- lang: eng
  text: <jats:p>This article presents the potential-dependent adsorption of two proteins,
    bovine serum albumin (BSA) and lysozyme (LYZ), on Ti6Al4V alloy at pH 7.4 and
    37 °C. The adsorption process was studied on an electropolished alloy under cathodic
    and anodic overpotentials, compared to the open circuit potential (OCP). To analyze
    the adsorption process, various complementary interface analytical techniques
    were employed, including PM-IRRAS (polarization-modulation infrared reflection-absorption
    spectroscopy), AFM (atomic force microscopy), XPS (X-ray photoelectron spectroscopy),
    and E-QCM (electrochemical quartz crystal microbalance) measurements. The polarization
    experiments were conducted within a potential range where charging of the electric
    double layer dominates, and Faradaic currents can be disregarded. The findings
    highlight the significant influence of the interfacial charge distribution on
    the adsorption of BSA and LYZ onto the alloy surface. Furthermore, electrochemical
    analysis of the protein layers formed under applied overpotentials demonstrated
    improved corrosion protection properties. These studies provide valuable insights
    into protein adsorption on titanium alloys under physiological conditions, characterized
    by varying potentials of the passive alloy.</jats:p>
author:
- first_name: Belma
  full_name: Duderija, Belma
  id: '54863'
  last_name: Duderija
- first_name: Alejandro
  full_name: González-Orive, Alejandro
  last_name: González-Orive
- first_name: Christoph
  full_name: Ebbert, Christoph
  id: '7266'
  last_name: Ebbert
- first_name: Vanessa
  full_name: Neßlinger, Vanessa
  last_name: Neßlinger
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
citation:
  ama: Duderija B, González-Orive A, Ebbert C, Neßlinger V, Keller A, Grundmeier G.
    Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy.
    <i>Molecules</i>. 2023;28(13):5109. doi:<a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>
  apa: Duderija, B., González-Orive, A., Ebbert, C., Neßlinger, V., Keller, A., &#38;
    Grundmeier, G. (2023). Electrode Potential-Dependent Studies of Protein Adsorption
    on Ti6Al4V Alloy. <i>Molecules</i>, <i>28</i>(13), 5109. <a href="https://doi.org/10.3390/molecules28135109">https://doi.org/10.3390/molecules28135109</a>
  bibtex: '@article{Duderija_González-Orive_Ebbert_Neßlinger_Keller_Grundmeier_2023,
    title={Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V
    Alloy}, volume={28}, DOI={<a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>},
    number={13}, journal={Molecules}, publisher={MDPI AG}, author={Duderija, Belma
    and González-Orive, Alejandro and Ebbert, Christoph and Neßlinger, Vanessa and
    Keller, Adrian and Grundmeier, Guido}, year={2023}, pages={5109} }'
  chicago: 'Duderija, Belma, Alejandro González-Orive, Christoph Ebbert, Vanessa Neßlinger,
    Adrian Keller, and Guido Grundmeier. “Electrode Potential-Dependent Studies of
    Protein Adsorption on Ti6Al4V Alloy.” <i>Molecules</i> 28, no. 13 (2023): 5109.
    <a href="https://doi.org/10.3390/molecules28135109">https://doi.org/10.3390/molecules28135109</a>.'
  ieee: 'B. Duderija, A. González-Orive, C. Ebbert, V. Neßlinger, A. Keller, and G.
    Grundmeier, “Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V
    Alloy,” <i>Molecules</i>, vol. 28, no. 13, p. 5109, 2023, doi: <a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>.'
  mla: Duderija, Belma, et al. “Electrode Potential-Dependent Studies of Protein Adsorption
    on Ti6Al4V Alloy.” <i>Molecules</i>, vol. 28, no. 13, MDPI AG, 2023, p. 5109,
    doi:<a href="https://doi.org/10.3390/molecules28135109">10.3390/molecules28135109</a>.
  short: B. Duderija, A. González-Orive, C. Ebbert, V. Neßlinger, A. Keller, G. Grundmeier,
    Molecules 28 (2023) 5109.
date_created: 2023-07-03T08:06:28Z
date_updated: 2023-07-03T08:07:55Z
department:
- _id: '302'
doi: 10.3390/molecules28135109
intvolume: '        28'
issue: '13'
keyword:
- Chemistry (miscellaneous)
- Analytical Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Molecular Medicine
- Drug Discovery
- Pharmaceutical Science
language:
- iso: eng
page: '5109'
publication: Molecules
publication_identifier:
  issn:
  - 1420-3049
publication_status: published
publisher: MDPI AG
status: public
title: Electrode Potential-Dependent Studies of Protein Adsorption on Ti6Al4V Alloy
type: journal_article
user_id: '48864'
volume: 28
year: '2023'
...
---
_id: '46480'
article_number: '147317'
author:
- first_name: Hendrik
  full_name: Müller, Hendrik
  last_name: Müller
- first_name: Christian
  full_name: Weinberger, Christian
  id: '11848'
  last_name: Weinberger
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Maria Teresa
  full_name: de los Arcos de Pedro, Maria Teresa
  id: '54556'
  last_name: de los Arcos de Pedro
citation:
  ama: Müller H, Weinberger C, Grundmeier G, de los Arcos de Pedro MT. UV-enhanced
    environmental charge compensation in near ambient pressure XPS. <i>Journal of
    Electron Spectroscopy and Related Phenomena</i>. 2023;264. doi:<a href="https://doi.org/10.1016/j.elspec.2023.147317">10.1016/j.elspec.2023.147317</a>
  apa: Müller, H., Weinberger, C., Grundmeier, G., &#38; de los Arcos de Pedro, M.
    T. (2023). UV-enhanced environmental charge compensation in near ambient pressure
    XPS. <i>Journal of Electron Spectroscopy and Related Phenomena</i>, <i>264</i>,
    Article 147317. <a href="https://doi.org/10.1016/j.elspec.2023.147317">https://doi.org/10.1016/j.elspec.2023.147317</a>
  bibtex: '@article{Müller_Weinberger_Grundmeier_de los Arcos de Pedro_2023, title={UV-enhanced
    environmental charge compensation in near ambient pressure XPS}, volume={264},
    DOI={<a href="https://doi.org/10.1016/j.elspec.2023.147317">10.1016/j.elspec.2023.147317</a>},
    number={147317}, journal={Journal of Electron Spectroscopy and Related Phenomena},
    publisher={Elsevier BV}, author={Müller, Hendrik and Weinberger, Christian and
    Grundmeier, Guido and de los Arcos de Pedro, Maria Teresa}, year={2023} }'
  chicago: Müller, Hendrik, Christian Weinberger, Guido Grundmeier, and Maria Teresa
    de los Arcos de Pedro. “UV-Enhanced Environmental Charge Compensation in near
    Ambient Pressure XPS.” <i>Journal of Electron Spectroscopy and Related Phenomena</i>
    264 (2023). <a href="https://doi.org/10.1016/j.elspec.2023.147317">https://doi.org/10.1016/j.elspec.2023.147317</a>.
  ieee: 'H. Müller, C. Weinberger, G. Grundmeier, and M. T. de los Arcos de Pedro,
    “UV-enhanced environmental charge compensation in near ambient pressure XPS,”
    <i>Journal of Electron Spectroscopy and Related Phenomena</i>, vol. 264, Art.
    no. 147317, 2023, doi: <a href="https://doi.org/10.1016/j.elspec.2023.147317">10.1016/j.elspec.2023.147317</a>.'
  mla: Müller, Hendrik, et al. “UV-Enhanced Environmental Charge Compensation in near
    Ambient Pressure XPS.” <i>Journal of Electron Spectroscopy and Related Phenomena</i>,
    vol. 264, 147317, Elsevier BV, 2023, doi:<a href="https://doi.org/10.1016/j.elspec.2023.147317">10.1016/j.elspec.2023.147317</a>.
  short: H. Müller, C. Weinberger, G. Grundmeier, M.T. de los Arcos de Pedro, Journal
    of Electron Spectroscopy and Related Phenomena 264 (2023).
date_created: 2023-08-11T14:11:57Z
date_updated: 2023-08-11T14:13:19Z
department:
- _id: '302'
doi: 10.1016/j.elspec.2023.147317
intvolume: '       264'
keyword:
- Physical and Theoretical Chemistry
- Spectroscopy
- Condensed Matter Physics
- Atomic and Molecular Physics
- and Optics
- Radiation
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
publication: Journal of Electron Spectroscopy and Related Phenomena
publication_identifier:
  issn:
  - 0368-2048
publication_status: published
publisher: Elsevier BV
status: public
title: UV-enhanced environmental charge compensation in near ambient pressure XPS
type: journal_article
user_id: '54556'
volume: 264
year: '2023'
...
---
_id: '46542'
abstract:
- lang: eng
  text: <jats:p>Multiprotein adsorption from complex body fluids represents a highly
    important and complicated phenomenon in medicine. In this work, multiprotein adsorption
    from diluted human serum at gold and oxidized iron surfaces is investigated at
    different serum concentrations and pH values. Adsorption-induced changes in surface
    topography and the total amount of adsorbed proteins are quantified by atomic
    force microscopy (AFM) and polarization-modulation infrared reflection absorption
    spectroscopy (PM-IRRAS), respectively. For both surfaces, stronger protein adsorption
    is observed at pH 6 compared to pH 7 and pH 8. PM-IRRAS furthermore provides some
    qualitative insights into the pH-dependent alterations in the composition of the
    adsorbed multiprotein films. Changes in the amide II/amide I band area ratio and
    in particular side-chain IR absorption suggest that the increased adsorption at
    pH 6 is accompanied by a change in protein film composition. Presumably, this
    is mostly driven by the adsorption of human serum albumin, which at pH 6 adsorbs
    more readily and thereby replaces other proteins with lower surface affinities
    in the resulting multiprotein film.</jats:p>
article_number: '6060'
author:
- first_name: Jingyuan
  full_name: Huang, Jingyuan
  last_name: Huang
- first_name: Yunshu
  full_name: Qiu, Yunshu
  last_name: Qiu
- first_name: Felix
  full_name: Lücke, Felix
  last_name: Lücke
- first_name: Jiangling
  full_name: Su, Jiangling
  last_name: Su
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Huang J, Qiu Y, Lücke F, Su J, Grundmeier G, Keller A. Multiprotein Adsorption
    from Human Serum at Gold and Oxidized Iron Surfaces Studied by Atomic Force Microscopy
    and Polarization-Modulation Infrared Reflection Absorption Spectroscopy. <i>Molecules</i>.
    2023;28(16). doi:<a href="https://doi.org/10.3390/molecules28166060">10.3390/molecules28166060</a>
  apa: Huang, J., Qiu, Y., Lücke, F., Su, J., Grundmeier, G., &#38; Keller, A. (2023).
    Multiprotein Adsorption from Human Serum at Gold and Oxidized Iron Surfaces Studied
    by Atomic Force Microscopy and Polarization-Modulation Infrared Reflection Absorption
    Spectroscopy. <i>Molecules</i>, <i>28</i>(16), Article 6060. <a href="https://doi.org/10.3390/molecules28166060">https://doi.org/10.3390/molecules28166060</a>
  bibtex: '@article{Huang_Qiu_Lücke_Su_Grundmeier_Keller_2023, title={Multiprotein
    Adsorption from Human Serum at Gold and Oxidized Iron Surfaces Studied by Atomic
    Force Microscopy and Polarization-Modulation Infrared Reflection Absorption Spectroscopy},
    volume={28}, DOI={<a href="https://doi.org/10.3390/molecules28166060">10.3390/molecules28166060</a>},
    number={166060}, journal={Molecules}, publisher={MDPI AG}, author={Huang, Jingyuan
    and Qiu, Yunshu and Lücke, Felix and Su, Jiangling and Grundmeier, Guido and Keller,
    Adrian}, year={2023} }'
  chicago: Huang, Jingyuan, Yunshu Qiu, Felix Lücke, Jiangling Su, Guido Grundmeier,
    and Adrian Keller. “Multiprotein Adsorption from Human Serum at Gold and Oxidized
    Iron Surfaces Studied by Atomic Force Microscopy and Polarization-Modulation Infrared
    Reflection Absorption Spectroscopy.” <i>Molecules</i> 28, no. 16 (2023). <a href="https://doi.org/10.3390/molecules28166060">https://doi.org/10.3390/molecules28166060</a>.
  ieee: 'J. Huang, Y. Qiu, F. Lücke, J. Su, G. Grundmeier, and A. Keller, “Multiprotein
    Adsorption from Human Serum at Gold and Oxidized Iron Surfaces Studied by Atomic
    Force Microscopy and Polarization-Modulation Infrared Reflection Absorption Spectroscopy,”
    <i>Molecules</i>, vol. 28, no. 16, Art. no. 6060, 2023, doi: <a href="https://doi.org/10.3390/molecules28166060">10.3390/molecules28166060</a>.'
  mla: Huang, Jingyuan, et al. “Multiprotein Adsorption from Human Serum at Gold and
    Oxidized Iron Surfaces Studied by Atomic Force Microscopy and Polarization-Modulation
    Infrared Reflection Absorption Spectroscopy.” <i>Molecules</i>, vol. 28, no. 16,
    6060, MDPI AG, 2023, doi:<a href="https://doi.org/10.3390/molecules28166060">10.3390/molecules28166060</a>.
  short: J. Huang, Y. Qiu, F. Lücke, J. Su, G. Grundmeier, A. Keller, Molecules 28
    (2023).
date_created: 2023-08-16T10:51:48Z
date_updated: 2023-08-16T10:53:08Z
department:
- _id: '302'
doi: 10.3390/molecules28166060
intvolume: '        28'
issue: '16'
keyword:
- Chemistry (miscellaneous)
- Analytical Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Molecular Medicine
- Drug Discovery
- Pharmaceutical Science
language:
- iso: eng
publication: Molecules
publication_identifier:
  issn:
  - 1420-3049
publication_status: published
publisher: MDPI AG
status: public
title: Multiprotein Adsorption from Human Serum at Gold and Oxidized Iron Surfaces
  Studied by Atomic Force Microscopy and Polarization-Modulation Infrared Reflection
  Absorption Spectroscopy
type: journal_article
user_id: '48864'
volume: 28
year: '2023'
...
---
_id: '46543'
abstract:
- lang: eng
  text: <jats:p>The influence of nanoscale surface topography on protein adsorption
    is highly important for numerous applications in medicine and technology. Herein,
    ferritin adsorption at flat and nanofaceted, single-crystalline Al2O3 surfaces
    is investigated using atomic force microscopy and X-ray photoelectron spectroscopy.
    The nanofaceted surfaces are generated by the thermal annealing of Al2O3 wafers
    at temperatures above 1000 °C, which leads to the formation of faceted saw-tooth-like
    surface topographies with periodicities of about 160 nm and amplitudes of about
    15 nm. Ferritin adsorption at these nanofaceted surfaces is notably suppressed
    compared to the flat surface at a concentration of 10 mg/mL, which is attributed
    to lower adsorption affinities of the newly formed facets. Consequently, adsorption
    is restricted mostly to the pattern grooves, where the proteins can maximize their
    contact area with the surface. However, this effect depends on the protein concentration,
    with an inverse trend being observed at 30 mg/mL. Furthermore, different ferritin
    adsorption behavior is observed at topographically similar nanofacet patterns
    fabricated at different annealing temperatures and attributed to different step
    and kink densities. These results demonstrate that while protein adsorption at
    solid surfaces can be notably affected by nanofacet patterns, fine-tuning protein
    adsorption in this way requires the precise control of facet properties.</jats:p>
article_number: '12808'
author:
- first_name: Bhanu K.
  full_name: Pothineni, Bhanu K.
  last_name: Pothineni
- first_name: Sabrina
  full_name: Kollmann, Sabrina
  last_name: Kollmann
- first_name: Xinyang
  full_name: Li, Xinyang
  last_name: Li
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Denise J.
  full_name: Erb, Denise J.
  last_name: Erb
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Pothineni BK, Kollmann S, Li X, Grundmeier G, Erb DJ, Keller A. Adsorption
    of Ferritin at Nanofaceted Al2O3 Surfaces. <i>International Journal of Molecular
    Sciences</i>. 2023;24(16). doi:<a href="https://doi.org/10.3390/ijms241612808">10.3390/ijms241612808</a>
  apa: Pothineni, B. K., Kollmann, S., Li, X., Grundmeier, G., Erb, D. J., &#38; Keller,
    A. (2023). Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces. <i>International
    Journal of Molecular Sciences</i>, <i>24</i>(16), Article 12808. <a href="https://doi.org/10.3390/ijms241612808">https://doi.org/10.3390/ijms241612808</a>
  bibtex: '@article{Pothineni_Kollmann_Li_Grundmeier_Erb_Keller_2023, title={Adsorption
    of Ferritin at Nanofaceted Al2O3 Surfaces}, volume={24}, DOI={<a href="https://doi.org/10.3390/ijms241612808">10.3390/ijms241612808</a>},
    number={1612808}, journal={International Journal of Molecular Sciences}, publisher={MDPI
    AG}, author={Pothineni, Bhanu K. and Kollmann, Sabrina and Li, Xinyang and Grundmeier,
    Guido and Erb, Denise J. and Keller, Adrian}, year={2023} }'
  chicago: Pothineni, Bhanu K., Sabrina Kollmann, Xinyang Li, Guido Grundmeier, Denise
    J. Erb, and Adrian Keller. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.”
    <i>International Journal of Molecular Sciences</i> 24, no. 16 (2023). <a href="https://doi.org/10.3390/ijms241612808">https://doi.org/10.3390/ijms241612808</a>.
  ieee: 'B. K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D. J. Erb, and A. Keller,
    “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces,” <i>International Journal
    of Molecular Sciences</i>, vol. 24, no. 16, Art. no. 12808, 2023, doi: <a href="https://doi.org/10.3390/ijms241612808">10.3390/ijms241612808</a>.'
  mla: Pothineni, Bhanu K., et al. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.”
    <i>International Journal of Molecular Sciences</i>, vol. 24, no. 16, 12808, MDPI
    AG, 2023, doi:<a href="https://doi.org/10.3390/ijms241612808">10.3390/ijms241612808</a>.
  short: B.K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D.J. Erb, A. Keller, International
    Journal of Molecular Sciences 24 (2023).
date_created: 2023-08-16T10:52:25Z
date_updated: 2023-08-16T10:53:00Z
department:
- _id: '302'
doi: 10.3390/ijms241612808
intvolume: '        24'
issue: '16'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
publication: International Journal of Molecular Sciences
publication_identifier:
  issn:
  - 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces
type: journal_article
user_id: '48864'
volume: 24
year: '2023'
...
---
_id: '53079'
article_type: original
author:
- first_name: Thomas
  full_name: Bierkandt, Thomas
  last_name: Bierkandt
- first_name: Patrick
  full_name: Hemberger, Patrick
  last_name: Hemberger
- first_name: Patrick
  full_name: Oßwald, Patrick
  last_name: Oßwald
- first_name: Nina
  full_name: Gaiser, Nina
  last_name: Gaiser
- first_name: Martin
  full_name: Hoener, Martin
  last_name: Hoener
- first_name: Dominik
  full_name: Krüger, Dominik
  last_name: Krüger
- first_name: Tina
  full_name: Kasper, Tina
  id: '94562'
  last_name: Kasper
  orcid: '0000-0003-3993-5316 '
- first_name: Markus
  full_name: Köhler, Markus
  last_name: Köhler
citation:
  ama: Bierkandt T, Hemberger P, Oßwald P, et al. A combustion chemistry study of
    tetramethylethylene in a laminar premixed low-pressure hydrogen flame. <i>Proceedings
    of the Combustion Institute</i>. 2023;39(2):1699-1708. doi:<a href="https://doi.org/10.1016/j.proci.2022.07.205">10.1016/j.proci.2022.07.205</a>
  apa: Bierkandt, T., Hemberger, P., Oßwald, P., Gaiser, N., Hoener, M., Krüger, D.,
    Kasper, T., &#38; Köhler, M. (2023). A combustion chemistry study of tetramethylethylene
    in a laminar premixed low-pressure hydrogen flame. <i>Proceedings of the Combustion
    Institute</i>, <i>39</i>(2), 1699–1708. <a href="https://doi.org/10.1016/j.proci.2022.07.205">https://doi.org/10.1016/j.proci.2022.07.205</a>
  bibtex: '@article{Bierkandt_Hemberger_Oßwald_Gaiser_Hoener_Krüger_Kasper_Köhler_2023,
    title={A combustion chemistry study of tetramethylethylene in a laminar premixed
    low-pressure hydrogen flame}, volume={39}, DOI={<a href="https://doi.org/10.1016/j.proci.2022.07.205">10.1016/j.proci.2022.07.205</a>},
    number={2}, journal={Proceedings of the Combustion Institute}, publisher={Elsevier
    BV}, author={Bierkandt, Thomas and Hemberger, Patrick and Oßwald, Patrick and
    Gaiser, Nina and Hoener, Martin and Krüger, Dominik and Kasper, Tina and Köhler,
    Markus}, year={2023}, pages={1699–1708} }'
  chicago: 'Bierkandt, Thomas, Patrick Hemberger, Patrick Oßwald, Nina Gaiser, Martin
    Hoener, Dominik Krüger, Tina Kasper, and Markus Köhler. “A Combustion Chemistry
    Study of Tetramethylethylene in a Laminar Premixed Low-Pressure Hydrogen Flame.”
    <i>Proceedings of the Combustion Institute</i> 39, no. 2 (2023): 1699–1708. <a
    href="https://doi.org/10.1016/j.proci.2022.07.205">https://doi.org/10.1016/j.proci.2022.07.205</a>.'
  ieee: 'T. Bierkandt <i>et al.</i>, “A combustion chemistry study of tetramethylethylene
    in a laminar premixed low-pressure hydrogen flame,” <i>Proceedings of the Combustion
    Institute</i>, vol. 39, no. 2, pp. 1699–1708, 2023, doi: <a href="https://doi.org/10.1016/j.proci.2022.07.205">10.1016/j.proci.2022.07.205</a>.'
  mla: Bierkandt, Thomas, et al. “A Combustion Chemistry Study of Tetramethylethylene
    in a Laminar Premixed Low-Pressure Hydrogen Flame.” <i>Proceedings of the Combustion
    Institute</i>, vol. 39, no. 2, Elsevier BV, 2023, pp. 1699–708, doi:<a href="https://doi.org/10.1016/j.proci.2022.07.205">10.1016/j.proci.2022.07.205</a>.
  short: T. Bierkandt, P. Hemberger, P. Oßwald, N. Gaiser, M. Hoener, D. Krüger, T.
    Kasper, M. Köhler, Proceedings of the Combustion Institute 39 (2023) 1699–1708.
date_created: 2024-03-27T16:16:17Z
date_updated: 2025-07-08T10:35:30Z
department:
- _id: '728'
doi: 10.1016/j.proci.2022.07.205
intvolume: '        39'
issue: '2'
keyword:
- Physical and Theoretical Chemistry
- Mechanical Engineering
- General Chemical Engineering
language:
- iso: eng
page: 1699-1708
publication: Proceedings of the Combustion Institute
publication_identifier:
  issn:
  - 1540-7489
publication_status: published
publisher: Elsevier BV
quality_controlled: '1'
status: public
title: A combustion chemistry study of tetramethylethylene in a laminar premixed low-pressure
  hydrogen flame
type: journal_article
user_id: '94562'
volume: 39
year: '2023'
...
---
_id: '30209'
abstract:
- lang: eng
  text: <jats:p>DNA origami technology enables the folding of DNA strands into complex
    nanoscale shapes whose properties and interactions with molecular species often
    deviate significantly from that of genomic DNA. Here, we investigate the salting-out
    of different DNA origami shapes by the kosmotropic salt ammonium sulfate that
    is routinely employed in protein precipitation. We find that centrifugation in
    the presence of 3 M ammonium sulfate results in notable precipitation of DNA origami
    nanostructures but not of double-stranded genomic DNA. The precipitated DNA origami
    nanostructures can be resuspended in ammonium sulfate-free buffer without apparent
    formation of aggregates or loss of structural integrity. Even though quasi-1D
    six-helix bundle DNA origami are slightly less susceptible toward salting-out
    than more compact DNA origami triangles and 24-helix bundles, precipitation and
    recovery yields appear to be mostly independent of DNA origami shape and superstructure.
    Exploiting the specificity of ammonium sulfate salting-out for DNA origami nanostructures,
    we further apply this method to separate DNA origami triangles from genomic DNA
    fragments in a complex mixture. Our results thus demonstrate the possibility of
    concentrating and purifying DNA origami nanostructures by ammonium sulfate-induced
    salting-out.</jats:p>
author:
- first_name: Marcel
  full_name: Hanke, Marcel
  last_name: Hanke
- first_name: Niklas
  full_name: Hansen, Niklas
  last_name: Hansen
- first_name: Ruiping
  full_name: Chen, Ruiping
  last_name: Chen
- first_name: Guido
  full_name: Grundmeier, Guido
  last_name: Grundmeier
- first_name: Karim
  full_name: Fahmy, Karim
  last_name: Fahmy
- first_name: Adrian
  full_name: Keller, Adrian
  last_name: Keller
citation:
  ama: Hanke M, Hansen N, Chen R, Grundmeier G, Fahmy K, Keller A. Salting-Out of
    DNA Origami Nanostructures by Ammonium Sulfate. <i>International Journal of Molecular
    Sciences</i>. 2022;23(5):2817. doi:<a href="https://doi.org/10.3390/ijms23052817">10.3390/ijms23052817</a>
  apa: Hanke, M., Hansen, N., Chen, R., Grundmeier, G., Fahmy, K., &#38; Keller, A.
    (2022). Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate. <i>International
    Journal of Molecular Sciences</i>, <i>23</i>(5), 2817. <a href="https://doi.org/10.3390/ijms23052817">https://doi.org/10.3390/ijms23052817</a>
  bibtex: '@article{Hanke_Hansen_Chen_Grundmeier_Fahmy_Keller_2022, title={Salting-Out
    of DNA Origami Nanostructures by Ammonium Sulfate}, volume={23}, DOI={<a href="https://doi.org/10.3390/ijms23052817">10.3390/ijms23052817</a>},
    number={5}, journal={International Journal of Molecular Sciences}, publisher={MDPI
    AG}, author={Hanke, Marcel and Hansen, Niklas and Chen, Ruiping and Grundmeier,
    Guido and Fahmy, Karim and Keller, Adrian}, year={2022}, pages={2817} }'
  chicago: 'Hanke, Marcel, Niklas Hansen, Ruiping Chen, Guido Grundmeier, Karim Fahmy,
    and Adrian Keller. “Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate.”
    <i>International Journal of Molecular Sciences</i> 23, no. 5 (2022): 2817. <a
    href="https://doi.org/10.3390/ijms23052817">https://doi.org/10.3390/ijms23052817</a>.'
  ieee: 'M. Hanke, N. Hansen, R. Chen, G. Grundmeier, K. Fahmy, and A. Keller, “Salting-Out
    of DNA Origami Nanostructures by Ammonium Sulfate,” <i>International Journal of
    Molecular Sciences</i>, vol. 23, no. 5, p. 2817, 2022, doi: <a href="https://doi.org/10.3390/ijms23052817">10.3390/ijms23052817</a>.'
  mla: Hanke, Marcel, et al. “Salting-Out of DNA Origami Nanostructures by Ammonium
    Sulfate.” <i>International Journal of Molecular Sciences</i>, vol. 23, no. 5,
    MDPI AG, 2022, p. 2817, doi:<a href="https://doi.org/10.3390/ijms23052817">10.3390/ijms23052817</a>.
  short: M. Hanke, N. Hansen, R. Chen, G. Grundmeier, K. Fahmy, A. Keller, International
    Journal of Molecular Sciences 23 (2022) 2817.
date_created: 2022-03-07T07:28:02Z
date_updated: 2022-03-07T07:29:27Z
department:
- _id: '302'
doi: 10.3390/ijms23052817
intvolume: '        23'
issue: '5'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
page: '2817'
publication: International Journal of Molecular Sciences
publication_identifier:
  issn:
  - 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate
type: journal_article
user_id: '48864'
volume: 23
year: '2022'
...
---
_id: '32589'
abstract:
- lang: eng
  text: <jats:p>Guanidinium (Gdm) undergoes interactions with both hydrophilic and
    hydrophobic groups and, thus, is a highly potent denaturant of biomolecular structure.
    However, our molecular understanding of the interaction of Gdm with proteins and
    DNA is still rather limited. Here, we investigated the denaturation of DNA origami
    nanostructures by three Gdm salts, i.e., guanidinium chloride (GdmCl), guanidinium
    sulfate (Gdm2SO4), and guanidinium thiocyanate (GdmSCN), at different temperatures
    and in dependence of incubation time. Using DNA origami nanostructures as sensors
    that translate small molecular transitions into nanostructural changes, the denaturing
    effects of the Gdm salts were directly visualized by atomic force microscopy.
    GdmSCN was the most potent DNA denaturant, which caused complete DNA origami denaturation
    at 50 °C already at a concentration of 2 M. Under such harsh conditions, denaturation
    occurred within the first 15 min of Gdm exposure, whereas much slower kinetics
    were observed for the more weakly denaturing salt Gdm2SO4 at 25 °C. Lastly, we
    observed a novel non-monotonous temperature dependence of DNA origami denaturation
    in Gdm2SO4 with the fraction of intact nanostructures having an intermediate minimum
    at about 40 °C. Our results, thus, provide further insights into the highly complex
    Gdm–DNA interaction and underscore the importance of the counteranion species.</jats:p>
author:
- first_name: Marcel
  full_name: Hanke, Marcel
  last_name: Hanke
- first_name: Niklas
  full_name: Hansen, Niklas
  last_name: Hansen
- first_name: Emilia
  full_name: Tomm, Emilia
  last_name: Tomm
- first_name: Guido
  full_name: Grundmeier, Guido
  id: '194'
  last_name: Grundmeier
- first_name: Adrian
  full_name: Keller, Adrian
  id: '48864'
  last_name: Keller
  orcid: 0000-0001-7139-3110
citation:
  ama: Hanke M, Hansen N, Tomm E, Grundmeier G, Keller A. Time-Dependent DNA Origami
    Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate.
    <i>International Journal of Molecular Sciences</i>. 2022;23(15):8547. doi:<a href="https://doi.org/10.3390/ijms23158547">10.3390/ijms23158547</a>
  apa: Hanke, M., Hansen, N., Tomm, E., Grundmeier, G., &#38; Keller, A. (2022). Time-Dependent
    DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium
    Thiocyanate. <i>International Journal of Molecular Sciences</i>, <i>23</i>(15),
    8547. <a href="https://doi.org/10.3390/ijms23158547">https://doi.org/10.3390/ijms23158547</a>
  bibtex: '@article{Hanke_Hansen_Tomm_Grundmeier_Keller_2022, title={Time-Dependent
    DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium
    Thiocyanate}, volume={23}, DOI={<a href="https://doi.org/10.3390/ijms23158547">10.3390/ijms23158547</a>},
    number={15}, journal={International Journal of Molecular Sciences}, publisher={MDPI
    AG}, author={Hanke, Marcel and Hansen, Niklas and Tomm, Emilia and Grundmeier,
    Guido and Keller, Adrian}, year={2022}, pages={8547} }'
  chicago: 'Hanke, Marcel, Niklas Hansen, Emilia Tomm, Guido Grundmeier, and Adrian
    Keller. “Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium
    Sulfate, and Guanidinium Thiocyanate.” <i>International Journal of Molecular Sciences</i>
    23, no. 15 (2022): 8547. <a href="https://doi.org/10.3390/ijms23158547">https://doi.org/10.3390/ijms23158547</a>.'
  ieee: 'M. Hanke, N. Hansen, E. Tomm, G. Grundmeier, and A. Keller, “Time-Dependent
    DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium
    Thiocyanate,” <i>International Journal of Molecular Sciences</i>, vol. 23, no.
    15, p. 8547, 2022, doi: <a href="https://doi.org/10.3390/ijms23158547">10.3390/ijms23158547</a>.'
  mla: Hanke, Marcel, et al. “Time-Dependent DNA Origami Denaturation by Guanidinium
    Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate.” <i>International
    Journal of Molecular Sciences</i>, vol. 23, no. 15, MDPI AG, 2022, p. 8547, doi:<a
    href="https://doi.org/10.3390/ijms23158547">10.3390/ijms23158547</a>.
  short: M. Hanke, N. Hansen, E. Tomm, G. Grundmeier, A. Keller, International Journal
    of Molecular Sciences 23 (2022) 8547.
date_created: 2022-08-08T06:39:20Z
date_updated: 2022-08-08T06:40:14Z
department:
- _id: '302'
doi: 10.3390/ijms23158547
intvolume: '        23'
issue: '15'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
page: '8547'
publication: International Journal of Molecular Sciences
publication_identifier:
  issn:
  - 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium
  Sulfate, and Guanidinium Thiocyanate
type: journal_article
user_id: '48864'
volume: 23
year: '2022'
...