@article{42953, author = {{Cara, Eleonora and Hönicke, Philipp and Kayser, Yves and Lindner, Jörg K. N. and Castellino, Micaela and Murataj, Irdi and Porro, Samuele and Angelini, Angelo and De Leo, Natascia and Pirri, Candido Fabrizio and Beckhoff, Burkhard and Boarino, Luca and Ferrarese Lupi, Federico}}, issn = {{2637-6105}}, journal = {{ACS Applied Polymer Materials}}, keywords = {{Organic Chemistry, Polymers and Plastics, Process Chemistry and Technology}}, number = {{3}}, pages = {{2079--2087}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Developing Quantitative Nondestructive Characterization of Nanomaterials: A Case Study on Sequential Infiltration Synthesis of Block Copolymers}}}, doi = {{10.1021/acsapm.2c02094}}, volume = {{5}}, year = {{2023}}, } @article{43457, abstract = {{The production of hydrogen and the utilization of biomass for sustainable concepts of energy conversion and storage require gas sensors that discriminate between hydrogen (H2) and carbon monoxide (CO). Mesoporous copper–ceria (Cu–CeO2) materials with large specific surface areas and uniform porosity are prepared by nanocasting, and their textural properties are characterized by N2 physisorption, powder XRD, scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The oxidation states of copper (Cu+, Cu2+) and cerium (Ce3+, Ce4+) are investigated by XPS. The materials are used as resistive gas sensors for H2 and CO. The sensors show a stronger response to CO than to H2 and low cross-sensitivity to humidity. Copper turns out to be a necessary component; copper-free ceria materials prepared by the same method show only poor sensing performance. By measuring both gases (CO and H2) simultaneously, it is shown that this behavior can be utilized for selective sensing of CO in the presence of H2.}}, author = {{Baier, Dominik and Priamushko, Tatiana and Weinberger, Christian and Kleitz, Freddy and Tiemann, Michael}}, issn = {{2379-3694}}, journal = {{ACS Sensors}}, keywords = {{Fluid Flow and Transfer Processes, Process Chemistry and Technology, Instrumentation, Bioengineering}}, number = {{4}}, pages = {{1616 -- 1623}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Selective Discrimination between CO and H2 with Copper–Ceria-Resistive Gas Sensors}}}, doi = {{10.1021/acssensors.2c02739}}, volume = {{8}}, year = {{2023}}, } @article{34223, abstract = {{In this study, quasi-unidirectional continuous fiber reinforced thermoplastics (CFRTs) are joined with metal sheets via cold formed cylindrical, elliptical and polygonal pin structures which are directly pressed into the CFRT component after local infrared heating. In comparison to already available studies, the unique novelty is the use of non-rotational symmetric pin structures for the CFRT/metal hybrid joining. Thus, a variation in the fiber orientation in the CFRT component as well as a variation in the non-rotational symmetric pins’ orientation in relation to the sample orientation is conducted. The created samples are consequently mechanically tested via single lap shear experiments in a quasi-static state. Finally, the failure behavior of the single lap shear samples is investigated with the help of microscopic images and detailed photographs. In the single lap shear tests, it could be shown that non-rotational symmetric pin structures lead to an increase in maximum testing forces of up to 74% when compared to cylindrical pins. However, when normalized to the pin foot print related joint strength, only one polygonal pin variation showed increased joint strength in comparison to cylindrical pin structures. The investigation of the failure behavior showed two distinct failure modes. The first failure mode was failure of the CFRT component due to an exceedance of the maximum bearing strength of the pin-hole leading to significant damage in the CFRT component. The second failure mode was pin-deflection due to the applied testing load and a subsequent pin extraction from the CFRT component resulting in significantly less visible damage in the CFRT component. Generally, CFRT failure is more likely with a fiber orientation of 0° in relation to the load direction while pin extraction typically occurs with a fiber orientation of 90°. It is assumed that for future investigations, pin structures with an undercutting shape that creates an interlocking joint could counteract the tendency for pin-extraction and consequently lead to increased maximum joint strengths.}}, author = {{Popp, Julian and Römisch, David and Merklein, Marion and Drummer, Dietmar}}, issn = {{2076-3417}}, journal = {{Applied Sciences}}, keywords = {{Fluid Flow and Transfer Processes, Computer Science Applications, Process Chemistry and Technology, General Engineering, Instrumentation, General Materials Science}}, number = {{10}}, publisher = {{MDPI AG}}, title = {{{Joining of CFRT/Steel Hybrid Parts via Direct Pressing of Cold Formed Non-Rotational Symmetric Pin Structures}}}, doi = {{10.3390/app12104962}}, volume = {{12}}, year = {{2022}}, } @article{47560, abstract = {{As a part of the worldwide efforts to substantially reduce CO2 emissions, power-to-fuel technologies offer a promising path to make the transport sector CO2-free, complementing the electrification of vehicles. This study focused on the coupling of Fischer–Tropsch synthesis for the production of synthetic diesel and kerosene with a high-temperature electrolysis unit. For this purpose, a process model was set up consisting of several modules including a high-temperature co-electrolyzer and a steam electrolyzer, both of which were based on solid oxide electrolysis cell technology, Fischer–Tropsch synthesis, a hydrocracker, and a carrier steam distillation. The integration of the fuel synthesis reduced the electrical energy demand of the co-electrolysis process by more than 20%. The results from the process simulations indicated a power-to-fuel efficiency that varied between 46% and 67%, with a decisive share of the energy consumption of the co-electrolysis process within the energy balance. Moreover, the utilization of excess heat can substantially to completely cover the energy demand for CO2 separation. The economic analysis suggests production costs of 1.85 €/lDE for the base case and the potential to cut the costs to 0.94 €/lDE in the best case scenario. These results underline the huge potential of the developed power-to-fuel technology.}}, author = {{Peters, Ralf and Wegener, Nils and Samsun, Remzi Can and Schorn, Felix and Riese, Julia and Grünewald, Marcus and Stolten, Detlef}}, issn = {{2227-9717}}, journal = {{Processes}}, keywords = {{Process Chemistry and Technology, Chemical Engineering (miscellaneous), Bioengineering}}, number = {{4}}, publisher = {{MDPI AG}}, title = {{{A Techno-Economic Assessment of Fischer–Tropsch Fuels Based on Syngas from Co-Electrolysis}}}, doi = {{10.3390/pr10040699}}, volume = {{10}}, year = {{2022}}, } @article{34224, abstract = {{Crack growth in structures depends on the cyclic loads applied on it, such as mechanical, thermal and contact, as well as residual stresses, etc. To provide an accurate simulation of crack growth in structures, it is of high importance to integrate all kinds of loading situations in the simulations. Adapcrack3D is a simulation program that can accurately predict the propagation of cracks in real structures. However, until now, this three-dimensional program has only considered mechanical loads and static thermal loads. Therefore, the features of Adapcrack3D have been extended by including contact loading in crack growth simulations. The numerical simulation of crack propagation with Adapcrack3D is generally carried out using FE models of structures provided by the user. For simulating models with contact loading situations, Adapcrack3D has been updated to work with FE models containing multiple parts and necessary features such as coupling and surface interactions. Because Adapcrack3D uses the submodel technique for fracture mechanical evaluations, the architecture of the submodel is also modified to simulate models with contact definitions between the crack surfaces. This paper discusses the newly implemented attribute of the program with the help of illustrative examples. The results confirm that the contact simulation in Adapcrack3D is a major step in improving the functionality of the program.}}, author = {{Joy, Tintu David and Weiß, Deborah and Schramm, Britta and Kullmer, Gunter}}, issn = {{2076-3417}}, journal = {{Applied Sciences}}, keywords = {{Fluid Flow and Transfer Processes, Computer Science Applications, Process Chemistry and Technology, General Engineering, Instrumentation, General Materials Science}}, number = {{15}}, publisher = {{MDPI AG}}, title = {{{Further Development of 3D Crack Growth Simulation Program to Include Contact Loading Situations}}}, doi = {{10.3390/app12157557}}, volume = {{12}}, year = {{2022}}, } @article{30213, abstract = {{Requirement changes and cascading effects of change propagation are major sources of inefficiencies in product development and increase the risk of project failure. Proactive change management of requirement changes yields the potential to handle such changes efficiently. A systematic approach is required for proactive change management to assess and reduce the risk of a requirement change with appropriate effort in industrial application. Within the paper at hand, a novel method for Proactive Management of Requirement Changes (ProMaRC) is presented. It is developed in close collaboration with industry experts and evaluated based on workshops, pilot users’ feedback, three industrial case studies from the automotive industry and five development projects from research. To limit the application effort, an automated approach for dependency analysis based on the machine learning technique BERT and semi-automated assessment of change likelihood and impact using a modified PageRank algorithm is developed. Applying the method, the risks of requirement changes are assessed systematically and reduced by means of proactive change measures. Evaluation shows high performance of dependency analysis and confirms the applicability and usefulness of the method. This contribution opens up the research space of proactive risk management for requirement changes which is currently almost unexploited. It enables more efficient product development.}}, author = {{Gräßler, Iris and Oleff, Christian and Preuß, Daniel}}, issn = {{2076-3417}}, journal = {{Applied Sciences}}, keywords = {{Fluid Flow and Transfer Processes, Computer Science Applications, Process Chemistry and Technology, General Engineering, Instrumentation, General Materials Science}}, number = {{4}}, publisher = {{MDPI AG}}, title = {{{Proactive Management of Requirement Changes in the Development of Complex Technical Systems}}}, doi = {{10.3390/app12041874}}, volume = {{12}}, year = {{2022}}, } @article{33681, author = {{da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo, Sudhir K. and Bahnemann, Detlef W. and López-Salas, Nieves and Savateev, Aleksandr and Ribeiro, Caue and Kühne, Thomas and Antonietti, Markus and Teixeira, Ivo F.}}, issn = {{0926-3373}}, journal = {{Applied Catalysis B: Environmental}}, keywords = {{Process Chemistry and Technology, General Environmental Science, Catalysis}}, publisher = {{Elsevier BV}}, title = {{{Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}}}, doi = {{10.1016/j.apcatb.2021.120965}}, volume = {{304}}, year = {{2021}}, } @article{40562, author = {{da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo, Sudhir K. and Bahnemann, Detlef W. and Lopez Salas, Nieves and Savateev, Aleksandr and Ribeiro, Caue and Kühne, Thomas D. and Antonietti, Markus and Teixeira, Ivo F.}}, issn = {{0926-3373}}, journal = {{Applied Catalysis B: Environmental}}, keywords = {{Process Chemistry and Technology, General Environmental Science, Catalysis}}, publisher = {{Elsevier BV}}, title = {{{Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}}}, doi = {{10.1016/j.apcatb.2021.120965}}, volume = {{304}}, year = {{2021}}, } @article{46013, author = {{Liu, Dan and Zhai, Haichao and Hu, Jie and Pan, Ying and Xu, Gengsheng and Zhu, Chuhong and Yuan, Yupeng}}, issn = {{0272-8842}}, journal = {{Ceramics International}}, keywords = {{Materials Chemistry, Surfaces, Coatings and Films, Process Chemistry and Technology, Ceramics and Composites, Electronic, Optical and Magnetic Materials}}, number = {{4}}, pages = {{5759--5765}}, publisher = {{Elsevier BV}}, title = {{{A composite consisting of intermetallic Ni3Fe and nitrogen-doped carbon for electrocatalytic water oxidation: The effect of increased pyridinic nitrogen dopant}}}, doi = {{10.1016/j.ceramint.2021.11.123}}, volume = {{48}}, year = {{2021}}, } @article{35328, author = {{Wortmann, Martin and Frese, Natalie and Keil, Waldemar and Brikmann, Johannes and Biedinger, Jan and Brockhagen, Bennet and Reiss, Günter and Schmidt, Claudia and Gölzhäuser, Armin and Moritzer, Elmar and Hüsgen, Bruno}}, issn = {{2637-6105}}, journal = {{ACS Applied Polymer Materials}}, keywords = {{Organic Chemistry, Polymers and Plastics, Process Chemistry and Technology}}, number = {{11}}, pages = {{4719--4732}}, publisher = {{American Chemical Society (ACS)}}, title = {{{The Deterioration Mechanism of Silicone Molds in Polyurethane Vacuum Casting}}}, doi = {{10.1021/acsapm.0c00744}}, volume = {{2}}, year = {{2020}}, } @article{47572, abstract = {{AbstractDue to high energy‐intensive processes and a dependence on carbon‐based materials, the process industry plays a major role in climate change. Therefore, the substitution of fossil resources by bio‐based resources is indispensable. This leads to challenges arising from accompanying changes of the type, amount and location of resources. At the same time, transformable production systems are currently in the focus of research addressing the required flexibility. These systems which consist of modular production and logistics units offer the possibility to adapt flexibly in volatile conditions within dynamic supply chains. Hence, this work compiles elements for environmental sustainability, which minimize the carbon footprint in the process industry: transformable production systems, the utilization of bio‐based resources, carbon dioxide and renewable energy as well as the application of these elements in decentral production networks. Finally, possible use cases are determined based on the combination of these elements through a multi‐criteria analysis.}}, author = {{Pannok, Maik and Finkbeiner, Marco and Fasel, Henrik and Riese, Julia and Lier, Stefan}}, issn = {{2196-9744}}, journal = {{ChemBioEng Reviews}}, keywords = {{Industrial and Manufacturing Engineering, Filtration and Separation, Process Chemistry and Technology, Biochemistry, Chemical Engineering (miscellaneous), Bioengineering}}, number = {{6}}, pages = {{216--228}}, publisher = {{Wiley}}, title = {{{Transformable Decentral Production for Local Economies with Minimized Carbon Footprint}}}, doi = {{10.1002/cben.202000008}}, volume = {{7}}, year = {{2020}}, } @article{47582, abstract = {{AbstractModeling of heat and mass transfer in fixed‐bed reactors for heterogeneously catalyzed gas phase reactions is possible using different methods. Homogeneous and heterogeneous continuum models as well as particle resolved modeling of fixed‐bed reactors show high potential for application. Considering those approaches, advantages and disadvantages as well as underlying assumptions and boundary conditions are discussed. Additionally, methods for experimental validation are presented and discussed focusing on the two‐dimensional homogeneous models.}}, author = {{Stegehake, Carolin and Riese, Julia and Grünewald, Marcus}}, issn = {{2196-9744}}, journal = {{ChemBioEng Reviews}}, keywords = {{Industrial and Manufacturing Engineering, Filtration and Separation, Process Chemistry and Technology, Biochemistry, Chemical Engineering (miscellaneous), Bioengineering}}, number = {{2}}, pages = {{28--44}}, publisher = {{Wiley}}, title = {{{Modeling and Validating Fixed‐Bed Reactors: A State‐of‐the‐Art Review}}}, doi = {{10.1002/cben.201900002}}, volume = {{6}}, year = {{2019}}, } @article{47586, author = {{Lier, Stefan and Riese, Julia and Cvetanoska, Gordana and Lesniak, Anna Katharina and Müller, Stephan and Paul, Sarah and Sengen, Laura and Grünewald, Marcus}}, issn = {{0255-2701}}, journal = {{Chemical Engineering and Processing - Process Intensification}}, keywords = {{Industrial and Manufacturing Engineering, Process Chemistry and Technology, Energy Engineering and Power Technology, General Chemical Engineering, General Chemistry}}, pages = {{111--125}}, publisher = {{Elsevier BV}}, title = {{{Innovative scaling strategies for a fast development of apparatuses by modular process engineering}}}, doi = {{10.1016/j.cep.2017.10.026}}, volume = {{123}}, year = {{2017}}, } @article{32478, issn = {{0430-6228}}, journal = {{Физика горения и взрыва}}, keywords = {{Process Chemistry and Technology, Mechanical Engineering}}, number = {{3}}, publisher = {{Publishing House SB RAS}}, title = {{{Structure of Ultrahigh Molecular Weight Polyethylene-Air Counterflow Flame}}}, doi = {{10.15372/fgv20160302}}, year = {{2016}}, } @article{41234, abstract = {{AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.}}, author = {{Alex, Hannes and Steinfeldt, Norbert and Jähnisch, Klaus and Bauer, Matthias and Hübner, Sandra}}, issn = {{2191-9097}}, journal = {{Nanotechnology Reviews}}, keywords = {{Surfaces, Coatings and Films, Process Chemistry and Technology, Energy Engineering and Power Technology, Biomaterials, Medicine (miscellaneous), Biotechnology}}, number = {{1}}, pages = {{99--110}}, publisher = {{Walter de Gruyter GmbH}}, title = {{{On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow}}}, doi = {{10.1515/ntrev-2012-0085}}, volume = {{3}}, year = {{2013}}, }