[{"publisher":"John Wiley & Sons, Ltd","date_updated":"2026-02-17T16:12:41Z","author":[{"full_name":"Wissel, Till","last_name":"Wissel","first_name":"Till"},{"full_name":"Rösler, Lorenz","last_name":"Rösler","first_name":"Lorenz"},{"first_name":"Martin","full_name":"Brodrecht, Martin","last_name":"Brodrecht"},{"first_name":"Mark V.","last_name":"Höfler","full_name":"Höfler, Mark V."},{"first_name":"Kevin","last_name":"Herr","full_name":"Herr, Kevin"},{"last_name":"Oliveira Jr.","full_name":"Oliveira Jr., Marcos","first_name":"Marcos"},{"full_name":"Klimavicius, Vytautas","last_name":"Klimavicius","first_name":"Vytautas"},{"first_name":"Martin","last_name":"Ebert","full_name":"Ebert, Martin"},{"last_name":"Breitzke","full_name":"Breitzke, Hergen","first_name":"Hergen"},{"first_name":"Markus","last_name":"Hoffmann","full_name":"Hoffmann, Markus"},{"last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd","first_name":"Gerd"},{"id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann","first_name":"Torsten"}],"date_created":"2026-02-07T16:18:53Z","volume":17,"title":"Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques","doi":"10.1002/cctc.202401511","publication_identifier":{"issn":["1867-3880"]},"year":"2024","citation":{"apa":"Wissel, T., Rösler, L., Brodrecht, M., Höfler, M. V., Herr, K., Oliveira Jr., M., Klimavicius, V., Ebert, M., Breitzke, H., Hoffmann, M., Buntkowsky, G., &#38; Gutmann, T. (2024). Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques. <i>ChemCatChem</i>, <i>17</i>, e202401511. <a href=\"https://doi.org/10.1002/cctc.202401511\">https://doi.org/10.1002/cctc.202401511</a>","short":"T. Wissel, L. Rösler, M. Brodrecht, M.V. Höfler, K. Herr, M. Oliveira Jr., V. Klimavicius, M. Ebert, H. Breitzke, M. Hoffmann, G. Buntkowsky, T. Gutmann, ChemCatChem 17 (2024) e202401511.","mla":"Wissel, Till, et al. “Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques.” <i>ChemCatChem</i>, vol. 17, John Wiley &#38; Sons, Ltd, 2024, p. e202401511, doi:<a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>.","bibtex":"@article{Wissel_Rösler_Brodrecht_Höfler_Herr_Oliveira Jr._Klimavicius_Ebert_Breitzke_Hoffmann_et al._2024, title={Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques}, volume={17}, DOI={<a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>}, journal={ChemCatChem}, publisher={John Wiley &#38; Sons, Ltd}, author={Wissel, Till and Rösler, Lorenz and Brodrecht, Martin and Höfler, Mark V. and Herr, Kevin and Oliveira Jr., Marcos and Klimavicius, Vytautas and Ebert, Martin and Breitzke, Hergen and Hoffmann, Markus and et al.}, year={2024}, pages={e202401511} }","ieee":"T. Wissel <i>et al.</i>, “Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques,” <i>ChemCatChem</i>, vol. 17, p. e202401511, 2024, doi: <a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>.","chicago":"Wissel, Till, Lorenz Rösler, Martin Brodrecht, Mark V. Höfler, Kevin Herr, Marcos Oliveira Jr., Vytautas Klimavicius, et al. “Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques.” <i>ChemCatChem</i> 17 (2024): e202401511. <a href=\"https://doi.org/10.1002/cctc.202401511\">https://doi.org/10.1002/cctc.202401511</a>.","ama":"Wissel T, Rösler L, Brodrecht M, et al. Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques. <i>ChemCatChem</i>. 2024;17:e202401511. doi:<a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>"},"page":"e202401511","intvolume":"        17","_id":"64062","user_id":"100715","keyword":["SBA-15","Heterogeneous catalyst","Pd cross-coupling","Polyethylene glycol","Solid-state DNP NMR"],"language":[{"iso":"eng"}],"extern":"1","type":"journal_article","publication":"ChemCatChem","abstract":[{"lang":"eng","text":"Abstract Novel SBA-15-supported heterogeneous catalysts are synthesized and applied in the Mizoroki?Heck and the Suzuki?Miyaura cross-coupling reactions in green solvents like PEG or water. The structural properties of the products after each synthesis step are monitored by different analytics. The amount of amine/carboxyl groups and vanillin/histidine methyl ester and thermal stability are determined by TGA and elemental analysis, while ICP-OES delivered the amount of palladium of the catalysts. The morphology is investigated by SEM and XPS and confirms the presence of coordinated palladium in the zero-oxidation state. Gas adsorption analysis is conducted, which indicates the presence of palladium clusters in one of the two catalysts, which is underlined by BSE images combined with EDX. A detailed 13C ssNMR and DNP-enhanced 15N ssNMR spectral analysis is presented, which provides ultimate proof of the successful syntheses of the catalysts. The coordination of the palladium onto the carrier material is shown by combining the NMR spectral results with the results of the other analytics. First catalytic tests show for the Mizoroki?Heck reaction yields up to nearly 100% and for the Suzuki-Miyaura up to 88% in the presence of PEG and water, respectively."}],"status":"public"},{"user_id":"100715","_id":"64002","language":[{"iso":"eng"}],"extern":"1","keyword":["Formaldehyde","Local coordination","SBA-15","Vanadium oxo species","XANES","Zinc doped silica"],"publication":"Catalysis Today","type":"journal_article","status":"public","abstract":[{"lang":"eng","text":"The production of formaldehyde on industrial scale requires huge amounts of energy due to the involvement of reforming processes in combination with the demand in the megaton scale. Hence, a direct route for the transformation of (bio)methane to formaldehyde would decrease costs and puts less pressure on the environment. Herein, we report on the use of zinc modified silicas as possible support materials for vanadium catalysts and the resulting consequences for the performance in the selective oxidation of methane to formaldehyde. After optimization of the Zn content and reaction conditions, a remarkably high space-time yield of 12.4 kgCH2O·kgcat−1·h−1 was achieved. As a result of the extensive characterization by means of UV–vis, Raman, XANES and NMR spectroscopy it was found that vanadium is in the vicinity of highly dispersed zinc atoms which promote the formation of active vanadium species as supposed by theoretical calculations. This work presents a further step of catalyst development towards direct industrial methane conversion which may help to overcome current limitations in the future."}],"volume":432,"author":[{"last_name":"Kunkel","full_name":"Kunkel, Benny","first_name":"Benny"},{"first_name":"Dominik","full_name":"Seeburg, Dominik","last_name":"Seeburg"},{"first_name":"Anke","full_name":"Kabelitz, Anke","last_name":"Kabelitz"},{"full_name":"Witte, Steffen","last_name":"Witte","first_name":"Steffen"},{"full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann","first_name":"Torsten"},{"last_name":"Breitzke","full_name":"Breitzke, Hergen","first_name":"Hergen"},{"last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd","first_name":"Gerd"},{"first_name":"Ana Guilherme","last_name":"Buzanich","full_name":"Buzanich, Ana Guilherme"},{"first_name":"Sebastian","full_name":"Wohlrab, Sebastian","last_name":"Wohlrab"}],"date_created":"2026-02-07T15:53:56Z","date_updated":"2026-02-17T16:15:41Z","doi":"10.1016/j.cattod.2024.114643","title":"Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane","intvolume":"       432","page":"114643","citation":{"ama":"Kunkel B, Seeburg D, Kabelitz A, et al. Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane. <i>Catalysis Today</i>. 2024;432:114643. doi:<a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>","chicago":"Kunkel, Benny, Dominik Seeburg, Anke Kabelitz, Steffen Witte, Torsten Gutmann, Hergen Breitzke, Gerd Buntkowsky, Ana Guilherme Buzanich, and Sebastian Wohlrab. “Highly Productive V/Zn-SiO2 Catalysts for the Selective Oxidation of Methane.” <i>Catalysis Today</i> 432 (2024): 114643. <a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">https://doi.org/10.1016/j.cattod.2024.114643</a>.","ieee":"B. Kunkel <i>et al.</i>, “Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane,” <i>Catalysis Today</i>, vol. 432, p. 114643, 2024, doi: <a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>.","apa":"Kunkel, B., Seeburg, D., Kabelitz, A., Witte, S., Gutmann, T., Breitzke, H., Buntkowsky, G., Buzanich, A. G., &#38; Wohlrab, S. (2024). Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane. <i>Catalysis Today</i>, <i>432</i>, 114643. <a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">https://doi.org/10.1016/j.cattod.2024.114643</a>","mla":"Kunkel, Benny, et al. “Highly Productive V/Zn-SiO2 Catalysts for the Selective Oxidation of Methane.” <i>Catalysis Today</i>, vol. 432, 2024, p. 114643, doi:<a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>.","short":"B. Kunkel, D. Seeburg, A. Kabelitz, S. Witte, T. Gutmann, H. Breitzke, G. Buntkowsky, A.G. Buzanich, S. Wohlrab, Catalysis Today 432 (2024) 114643.","bibtex":"@article{Kunkel_Seeburg_Kabelitz_Witte_Gutmann_Breitzke_Buntkowsky_Buzanich_Wohlrab_2024, title={Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane}, volume={432}, DOI={<a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>}, journal={Catalysis Today}, author={Kunkel, Benny and Seeburg, Dominik and Kabelitz, Anke and Witte, Steffen and Gutmann, Torsten and Breitzke, Hergen and Buntkowsky, Gerd and Buzanich, Ana Guilherme and Wohlrab, Sebastian}, year={2024}, pages={114643} }"},"year":"2024"}]