---
_id: '62814'
abstract:
- lang: eng
text: Porous carbons are prominent electrode materials in energy storage applications
such as supercapacitors. However, rational materials development is hampered by
difficulties in interpreting electrochemical impedance spectra (EIS) and drawing
conclusions about promising aspects of device improvement. Here, we characterized
electrodes consisting of activated carbon with polyacrylic acid binder in four
different concentrations of sulfuric acid, using cyclic voltammetry and electrochemical
impedance spectroscopy. Both datasets were evaluated with simple equivalent circuits
and comparatively analyzed. Conductivity of the electrolyte was independently
measured. Cyclic voltammograms (CV) show larger resistance and capacitance at
low scan rates. Resistances obtained from EIS are in good agreement with those
obtained by cyclic voltammograms particularly at high scan rates. The comparison
against specific electrolyte resistance can reveal whether resistances within
the solid electrode architecture or resistances within the electrolyte, partially
confined by pores, are the dominant cause of increased resistance at low scan
rate. Comparison between CV and EIS points to the main electrode capacitance being
described by a constant phase element (CPE) used to fit the low-frequency region
of EIS.
author:
- first_name: Sebastian
full_name: Reinke, Sebastian
id: '117727'
last_name: Reinke
- first_name: Vera
full_name: Khamitsevich, Vera
last_name: Khamitsevich
- first_name: Julia
full_name: Linnemann, Julia
id: '116779'
last_name: Linnemann
orcid: 0000-0001-6883-5424
citation:
ama: 'Reinke S, Khamitsevich V, Linnemann J. Complementary Analysis of Cyclic Voltammograms
and Impedance Spectra of Porous Carbon Electrodes. In: 2024 International Workshop
on Impedance Spectroscopy (IWIS). IEEE; 2025. doi:10.1109/iwis63047.2024.10847115'
apa: Reinke, S., Khamitsevich, V., & Linnemann, J. (2025). Complementary Analysis
of Cyclic Voltammograms and Impedance Spectra of Porous Carbon Electrodes. 2024
International Workshop on Impedance Spectroscopy (IWIS). https://doi.org/10.1109/iwis63047.2024.10847115
bibtex: '@inproceedings{Reinke_Khamitsevich_Linnemann_2025, title={Complementary
Analysis of Cyclic Voltammograms and Impedance Spectra of Porous Carbon Electrodes},
DOI={10.1109/iwis63047.2024.10847115},
booktitle={2024 International Workshop on Impedance Spectroscopy (IWIS)}, publisher={IEEE},
author={Reinke, Sebastian and Khamitsevich, Vera and Linnemann, Julia}, year={2025}
}'
chicago: Reinke, Sebastian, Vera Khamitsevich, and Julia Linnemann. “Complementary
Analysis of Cyclic Voltammograms and Impedance Spectra of Porous Carbon Electrodes.”
In 2024 International Workshop on Impedance Spectroscopy (IWIS). IEEE,
2025. https://doi.org/10.1109/iwis63047.2024.10847115.
ieee: 'S. Reinke, V. Khamitsevich, and J. Linnemann, “Complementary Analysis of
Cyclic Voltammograms and Impedance Spectra of Porous Carbon Electrodes,” 2025,
doi: 10.1109/iwis63047.2024.10847115.'
mla: Reinke, Sebastian, et al. “Complementary Analysis of Cyclic Voltammograms and
Impedance Spectra of Porous Carbon Electrodes.” 2024 International Workshop
on Impedance Spectroscopy (IWIS), IEEE, 2025, doi:10.1109/iwis63047.2024.10847115.
short: 'S. Reinke, V. Khamitsevich, J. Linnemann, in: 2024 International Workshop
on Impedance Spectroscopy (IWIS), IEEE, 2025.'
date_created: 2025-12-03T16:06:09Z
date_updated: 2026-01-19T15:41:43Z
department:
- _id: '985'
doi: 10.1109/iwis63047.2024.10847115
extern: '1'
keyword:
- electrochemical impedance spectroscopy
- distorted cyclic voltammograms
- supercapacitors
- carbon
language:
- iso: eng
publication: 2024 International Workshop on Impedance Spectroscopy (IWIS)
publication_status: published
publisher: IEEE
quality_controlled: '1'
status: public
title: Complementary Analysis of Cyclic Voltammograms and Impedance Spectra of Porous
Carbon Electrodes
type: conference
user_id: '116779'
year: '2025'
...
---
_id: '50150'
abstract:
- lang: eng
text: Covalent peptidomimetic protease inhibitors have gained a lot of attention
in drug development in recent years. They are designed to covalently bind the
catalytically active amino acids through electrophilic groups called warheads.
Covalent inhibition has an advantage in terms of pharmacodynamic properties but
can also bear toxicity risks due to non-selective off-target protein binding.
Therefore, the right combination of a reactive warhead with a well-suited peptidomimetic
sequence is of great importance. Herein, the selectivities of well-known warheads
combined with peptidomimetic sequences suited for five different proteases were
investigated, highlighting the impact of both structure parts (warhead and peptidomimetic
sequence) for affinity and selectivity. Molecular docking gave insights into the
predicted binding modes of the inhibitors inside the binding pockets of the different
enzymes. Moreover, the warheads were investigated by NMR and LC-MS reactivity
assays against serine/threonine and cysteine nucleophile models, as well as by
quantum mechanics simulations.
article_number: '7226'
author:
- first_name: Patrick
full_name: Müller, Patrick
last_name: Müller
- first_name: Mergim
full_name: Meta, Mergim
last_name: Meta
- first_name: Jan Laurenz
full_name: Meidner, Jan Laurenz
last_name: Meidner
- first_name: Marvin
full_name: Schwickert, Marvin
last_name: Schwickert
- first_name: Jessica
full_name: Meyr, Jessica
last_name: Meyr
- first_name: Kevin
full_name: Schwickert, Kevin
last_name: Schwickert
- first_name: Christian
full_name: Kersten, Christian
last_name: Kersten
- first_name: Collin
full_name: Zimmer, Collin
last_name: Zimmer
- first_name: Stefan Josef
full_name: Hammerschmidt, Stefan Josef
last_name: Hammerschmidt
- first_name: Ariane
full_name: Frey, Ariane
last_name: Frey
- first_name: Albin
full_name: Lahu, Albin
last_name: Lahu
- first_name: Sergio
full_name: de la Hoz-Rodríguez, Sergio
last_name: de la Hoz-Rodríguez
- first_name: Laura
full_name: Agost-Beltrán, Laura
last_name: Agost-Beltrán
- first_name: Santiago
full_name: Rodríguez, Santiago
last_name: Rodríguez
- first_name: Kira
full_name: Diemer, Kira
last_name: Diemer
- first_name: Wilhelm
full_name: Neumann, Wilhelm
last_name: Neumann
- first_name: Florenci V.
full_name: Gonzàlez, Florenci V.
last_name: Gonzàlez
- first_name: Bernd
full_name: Engels, Bernd
last_name: Engels
- first_name: Tanja
full_name: Schirmeister, Tanja
last_name: Schirmeister
citation:
ama: Müller P, Meta M, Meidner JL, et al. Investigation of the Compatibility between
Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
and Selectivity Study. International Journal of Molecular Sciences. 2023;24(8).
doi:10.3390/ijms24087226
apa: Müller, P., Meta, M., Meidner, J. L., Schwickert, M., Meyr, J., Schwickert,
K., Kersten, C., Zimmer, C., Hammerschmidt, S. J., Frey, A., Lahu, A., de la Hoz-Rodríguez,
S., Agost-Beltrán, L., Rodríguez, S., Diemer, K., Neumann, W., Gonzàlez, F. V.,
Engels, B., & Schirmeister, T. (2023). Investigation of the Compatibility
between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive
Reactivity and Selectivity Study. International Journal of Molecular Sciences,
24(8), Article 7226. https://doi.org/10.3390/ijms24087226
bibtex: '@article{Müller_Meta_Meidner_Schwickert_Meyr_Schwickert_Kersten_Zimmer_Hammerschmidt_Frey_et
al._2023, title={Investigation of the Compatibility between Warheads and Peptidomimetic
Sequences of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study},
volume={24}, DOI={10.3390/ijms24087226},
number={87226}, journal={International Journal of Molecular Sciences}, publisher={MDPI
AG}, author={Müller, Patrick and Meta, Mergim and Meidner, Jan Laurenz and Schwickert,
Marvin and Meyr, Jessica and Schwickert, Kevin and Kersten, Christian and Zimmer,
Collin and Hammerschmidt, Stefan Josef and Frey, Ariane and et al.}, year={2023}
}'
chicago: Müller, Patrick, Mergim Meta, Jan Laurenz Meidner, Marvin Schwickert, Jessica
Meyr, Kevin Schwickert, Christian Kersten, et al. “Investigation of the Compatibility
between Warheads and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive
Reactivity and Selectivity Study.” International Journal of Molecular Sciences
24, no. 8 (2023). https://doi.org/10.3390/ijms24087226.
ieee: 'P. Müller et al., “Investigation of the Compatibility between Warheads
and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
and Selectivity Study,” International Journal of Molecular Sciences, vol.
24, no. 8, Art. no. 7226, 2023, doi: 10.3390/ijms24087226.'
mla: Müller, Patrick, et al. “Investigation of the Compatibility between Warheads
and Peptidomimetic Sequences of Protease Inhibitors—A Comprehensive Reactivity
and Selectivity Study.” International Journal of Molecular Sciences, vol.
24, no. 8, 7226, MDPI AG, 2023, doi:10.3390/ijms24087226.
short: P. Müller, M. Meta, J.L. Meidner, M. Schwickert, J. Meyr, K. Schwickert,
C. Kersten, C. Zimmer, S.J. Hammerschmidt, A. Frey, A. Lahu, S. de la Hoz-Rodríguez,
L. Agost-Beltrán, S. Rodríguez, K. Diemer, W. Neumann, F.V. Gonzàlez, B. Engels,
T. Schirmeister, International Journal of Molecular Sciences 24 (2023).
date_created: 2024-01-04T08:24:31Z
date_updated: 2024-01-05T12:59:32Z
doi: 10.3390/ijms24087226
intvolume: ' 24'
issue: '8'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
project:
- _id: '52'
name: 'PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing'
publication: International Journal of Molecular Sciences
publication_identifier:
issn:
- 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Investigation of the Compatibility between Warheads and Peptidomimetic Sequences
of Protease Inhibitors—A Comprehensive Reactivity and Selectivity Study
type: journal_article
user_id: '67287'
volume: 24
year: '2023'
...
---
_id: '46480'
article_number: '147317'
author:
- first_name: Hendrik
full_name: Müller, Hendrik
last_name: Müller
- first_name: Christian
full_name: Weinberger, Christian
id: '11848'
last_name: Weinberger
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Maria Teresa
full_name: de los Arcos de Pedro, Maria Teresa
id: '54556'
last_name: de los Arcos de Pedro
citation:
ama: Müller H, Weinberger C, Grundmeier G, de los Arcos de Pedro MT. UV-enhanced
environmental charge compensation in near ambient pressure XPS. Journal of
Electron Spectroscopy and Related Phenomena. 2023;264. doi:10.1016/j.elspec.2023.147317
apa: Müller, H., Weinberger, C., Grundmeier, G., & de los Arcos de Pedro, M.
T. (2023). UV-enhanced environmental charge compensation in near ambient pressure
XPS. Journal of Electron Spectroscopy and Related Phenomena, 264,
Article 147317. https://doi.org/10.1016/j.elspec.2023.147317
bibtex: '@article{Müller_Weinberger_Grundmeier_de los Arcos de Pedro_2023, title={UV-enhanced
environmental charge compensation in near ambient pressure XPS}, volume={264},
DOI={10.1016/j.elspec.2023.147317},
number={147317}, journal={Journal of Electron Spectroscopy and Related Phenomena},
publisher={Elsevier BV}, author={Müller, Hendrik and Weinberger, Christian and
Grundmeier, Guido and de los Arcos de Pedro, Maria Teresa}, year={2023} }'
chicago: Müller, Hendrik, Christian Weinberger, Guido Grundmeier, and Maria Teresa
de los Arcos de Pedro. “UV-Enhanced Environmental Charge Compensation in near
Ambient Pressure XPS.” Journal of Electron Spectroscopy and Related Phenomena
264 (2023). https://doi.org/10.1016/j.elspec.2023.147317.
ieee: 'H. Müller, C. Weinberger, G. Grundmeier, and M. T. de los Arcos de Pedro,
“UV-enhanced environmental charge compensation in near ambient pressure XPS,”
Journal of Electron Spectroscopy and Related Phenomena, vol. 264, Art.
no. 147317, 2023, doi: 10.1016/j.elspec.2023.147317.'
mla: Müller, Hendrik, et al. “UV-Enhanced Environmental Charge Compensation in near
Ambient Pressure XPS.” Journal of Electron Spectroscopy and Related Phenomena,
vol. 264, 147317, Elsevier BV, 2023, doi:10.1016/j.elspec.2023.147317.
short: H. Müller, C. Weinberger, G. Grundmeier, M.T. de los Arcos de Pedro, Journal
of Electron Spectroscopy and Related Phenomena 264 (2023).
date_created: 2023-08-11T14:11:57Z
date_updated: 2023-08-11T14:13:19Z
department:
- _id: '302'
doi: 10.1016/j.elspec.2023.147317
intvolume: ' 264'
keyword:
- Physical and Theoretical Chemistry
- Spectroscopy
- Condensed Matter Physics
- Atomic and Molecular Physics
- and Optics
- Radiation
- Electronic
- Optical and Magnetic Materials
language:
- iso: eng
publication: Journal of Electron Spectroscopy and Related Phenomena
publication_identifier:
issn:
- 0368-2048
publication_status: published
publisher: Elsevier BV
status: public
title: UV-enhanced environmental charge compensation in near ambient pressure XPS
type: journal_article
user_id: '54556'
volume: 264
year: '2023'
...
---
_id: '46543'
abstract:
- lang: eng
text: The influence of nanoscale surface topography on protein adsorption
is highly important for numerous applications in medicine and technology. Herein,
ferritin adsorption at flat and nanofaceted, single-crystalline Al2O3 surfaces
is investigated using atomic force microscopy and X-ray photoelectron spectroscopy.
The nanofaceted surfaces are generated by the thermal annealing of Al2O3 wafers
at temperatures above 1000 °C, which leads to the formation of faceted saw-tooth-like
surface topographies with periodicities of about 160 nm and amplitudes of about
15 nm. Ferritin adsorption at these nanofaceted surfaces is notably suppressed
compared to the flat surface at a concentration of 10 mg/mL, which is attributed
to lower adsorption affinities of the newly formed facets. Consequently, adsorption
is restricted mostly to the pattern grooves, where the proteins can maximize their
contact area with the surface. However, this effect depends on the protein concentration,
with an inverse trend being observed at 30 mg/mL. Furthermore, different ferritin
adsorption behavior is observed at topographically similar nanofacet patterns
fabricated at different annealing temperatures and attributed to different step
and kink densities. These results demonstrate that while protein adsorption at
solid surfaces can be notably affected by nanofacet patterns, fine-tuning protein
adsorption in this way requires the precise control of facet properties.
article_number: '12808'
author:
- first_name: Bhanu K.
full_name: Pothineni, Bhanu K.
last_name: Pothineni
- first_name: Sabrina
full_name: Kollmann, Sabrina
last_name: Kollmann
- first_name: Xinyang
full_name: Li, Xinyang
last_name: Li
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Denise J.
full_name: Erb, Denise J.
last_name: Erb
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
citation:
ama: Pothineni BK, Kollmann S, Li X, Grundmeier G, Erb DJ, Keller A. Adsorption
of Ferritin at Nanofaceted Al2O3 Surfaces. International Journal of Molecular
Sciences. 2023;24(16). doi:10.3390/ijms241612808
apa: Pothineni, B. K., Kollmann, S., Li, X., Grundmeier, G., Erb, D. J., & Keller,
A. (2023). Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces. International
Journal of Molecular Sciences, 24(16), Article 12808. https://doi.org/10.3390/ijms241612808
bibtex: '@article{Pothineni_Kollmann_Li_Grundmeier_Erb_Keller_2023, title={Adsorption
of Ferritin at Nanofaceted Al2O3 Surfaces}, volume={24}, DOI={10.3390/ijms241612808},
number={1612808}, journal={International Journal of Molecular Sciences}, publisher={MDPI
AG}, author={Pothineni, Bhanu K. and Kollmann, Sabrina and Li, Xinyang and Grundmeier,
Guido and Erb, Denise J. and Keller, Adrian}, year={2023} }'
chicago: Pothineni, Bhanu K., Sabrina Kollmann, Xinyang Li, Guido Grundmeier, Denise
J. Erb, and Adrian Keller. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.”
International Journal of Molecular Sciences 24, no. 16 (2023). https://doi.org/10.3390/ijms241612808.
ieee: 'B. K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D. J. Erb, and A. Keller,
“Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces,” International Journal
of Molecular Sciences, vol. 24, no. 16, Art. no. 12808, 2023, doi: 10.3390/ijms241612808.'
mla: Pothineni, Bhanu K., et al. “Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces.”
International Journal of Molecular Sciences, vol. 24, no. 16, 12808, MDPI
AG, 2023, doi:10.3390/ijms241612808.
short: B.K. Pothineni, S. Kollmann, X. Li, G. Grundmeier, D.J. Erb, A. Keller, International
Journal of Molecular Sciences 24 (2023).
date_created: 2023-08-16T10:52:25Z
date_updated: 2023-08-16T10:53:00Z
department:
- _id: '302'
doi: 10.3390/ijms241612808
intvolume: ' 24'
issue: '16'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
publication: International Journal of Molecular Sciences
publication_identifier:
issn:
- 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Adsorption of Ferritin at Nanofaceted Al2O3 Surfaces
type: journal_article
user_id: '48864'
volume: 24
year: '2023'
...
---
_id: '62812'
abstract:
- lang: eng
text: Attributing features of electrochemical impedance spectra to electrochemical
phenomena is both crucial and frequently ambiguous. To elucidate the origin of
the ohmic part of the spectrum, activated carbon electrodes were prepared with
different contents of polyacrylic acid as binder. Their impedance spectra and
cyclic voltammograms were recorded using sulfuric acid of five different concentrations
as the electrolyte. To distinguish electrolyte resistance and resistances related
to the activated carbon layer of the electrode, the specific electrolyte conductivity
was independently measured and compared against the ohmic part of the electrochemical
impedance spectra (EIS). The capacitive cyclic voltammograms show larger resistive
contributions with higher scan rate and lower electrolyte conductivity. Comparing
the ohmic part of the EIS to the specific resistance of the electrolyte, a linear
function with no statistically significant offset was found. The ohmic part of
the EIS, thus, reflects the electrolyte resistance, not that of the carbon electrode.
author:
- first_name: Sebastian
full_name: Reinke, Sebastian
id: '117727'
last_name: Reinke
- first_name: Vera
full_name: Khamitsevich, Vera
last_name: Khamitsevich
- first_name: Oliver
full_name: Röth, Oliver
id: '117786'
last_name: Röth
- first_name: Julia
full_name: Linnemann, Julia
id: '116779'
last_name: Linnemann
orcid: 0000-0001-6883-5424
citation:
ama: 'Reinke S, Khamitsevich V, Röth O, Linnemann J. Assessment of the Physicochemical
Meaning of the Ohmic Series Resistance Observed for High Frequencies in Electrochemical
Impedance Spectra. In: 2023 International Workshop on Impedance Spectroscopy
(IWIS). IEEE; 2023. doi:10.1109/iwis61214.2023.10302764'
apa: Reinke, S., Khamitsevich, V., Röth, O., & Linnemann, J. (2023). Assessment
of the Physicochemical Meaning of the Ohmic Series Resistance Observed for High
Frequencies in Electrochemical Impedance Spectra. 2023 International Workshop
on Impedance Spectroscopy (IWIS). https://doi.org/10.1109/iwis61214.2023.10302764
bibtex: '@inproceedings{Reinke_Khamitsevich_Röth_Linnemann_2023, title={Assessment
of the Physicochemical Meaning of the Ohmic Series Resistance Observed for High
Frequencies in Electrochemical Impedance Spectra}, DOI={10.1109/iwis61214.2023.10302764},
booktitle={2023 International Workshop on Impedance Spectroscopy (IWIS)}, publisher={IEEE},
author={Reinke, Sebastian and Khamitsevich, Vera and Röth, Oliver and Linnemann,
Julia}, year={2023} }'
chicago: Reinke, Sebastian, Vera Khamitsevich, Oliver Röth, and Julia Linnemann.
“Assessment of the Physicochemical Meaning of the Ohmic Series Resistance Observed
for High Frequencies in Electrochemical Impedance Spectra.” In 2023 International
Workshop on Impedance Spectroscopy (IWIS). IEEE, 2023. https://doi.org/10.1109/iwis61214.2023.10302764.
ieee: 'S. Reinke, V. Khamitsevich, O. Röth, and J. Linnemann, “Assessment of the
Physicochemical Meaning of the Ohmic Series Resistance Observed for High Frequencies
in Electrochemical Impedance Spectra,” 2023, doi: 10.1109/iwis61214.2023.10302764.'
mla: Reinke, Sebastian, et al. “Assessment of the Physicochemical Meaning of the
Ohmic Series Resistance Observed for High Frequencies in Electrochemical Impedance
Spectra.” 2023 International Workshop on Impedance Spectroscopy (IWIS),
IEEE, 2023, doi:10.1109/iwis61214.2023.10302764.
short: 'S. Reinke, V. Khamitsevich, O. Röth, J. Linnemann, in: 2023 International
Workshop on Impedance Spectroscopy (IWIS), IEEE, 2023.'
date_created: 2025-12-03T15:58:28Z
date_updated: 2026-01-19T15:40:41Z
department:
- _id: '985'
doi: 10.1109/iwis61214.2023.10302764
extern: '1'
keyword:
- electrochemical impedance spectroscopy
- supercapacitors
- carbon
language:
- iso: eng
publication: 2023 International Workshop on Impedance Spectroscopy (IWIS)
publication_status: published
publisher: IEEE
quality_controlled: '1'
status: public
title: Assessment of the Physicochemical Meaning of the Ohmic Series Resistance Observed
for High Frequencies in Electrochemical Impedance Spectra
type: conference
user_id: '116779'
year: '2023'
...
---
_id: '64044'
abstract:
- lang: eng
text: Abstract Polymer-derived silicon oxycarbide ceramics (SiCO) have been considered
as potential anode materials for lithium- and sodium-ion batteries. To understand
their electrochemical storage behavior, detailed insights into structural sites
present in SiCO are required. In this work, the study of local structures in SiCO
ceramics containing different amounts of carbon is presented. 13C and 29Si solid-state
MAS?NMR spectroscopy combined with DFT calculations, atomistic modeling, and EPR
investigations, suggest significant changes in the local structures of SiCO ceramics
even by small changes in the material composition. The provided findings on SiCO
structures will contribute to the research field of polymer-derived ceramics,
especially to understand electrochemical storage processes of alkali metal/ions
such as Na/Na+ inside such networks in the future.
author:
- first_name: Edina
full_name: Šić, Edina
last_name: Šić
- first_name: Jochen
full_name: Rohrer, Jochen
last_name: Rohrer
- first_name: Emmanuel
full_name: Ricohermoso, Emmanuel
last_name: Ricohermoso
- first_name: Karsten
full_name: Albe, Karsten
last_name: Albe
- first_name: Emmanuel
full_name: Ionescu, Emmanuel
last_name: Ionescu
- first_name: Ralf
full_name: Riedel, Ralf
last_name: Riedel
- first_name: Hergen
full_name: Breitzke, Hergen
last_name: Breitzke
- first_name: Torsten
full_name: Gutmann, Torsten
id: '118165'
last_name: Gutmann
- first_name: Gerd
full_name: Buntkowsky, Gerd
last_name: Buntkowsky
citation:
ama: 'Šić E, Rohrer J, Ricohermoso E, et al. SiCO Ceramics as Storage Materials
for Alkali Metals/Ions: Insights on Structure Moieties from Solid-State NMR and
DFT Calculations. Chemsuschem. 2023;16:e202202241. doi:10.1002/cssc.202202241'
apa: 'Šić, E., Rohrer, J., Ricohermoso, E., Albe, K., Ionescu, E., Riedel, R., Breitzke,
H., Gutmann, T., & Buntkowsky, G. (2023). SiCO Ceramics as Storage Materials
for Alkali Metals/Ions: Insights on Structure Moieties from Solid-State NMR and
DFT Calculations. Chemsuschem, 16, e202202241. https://doi.org/10.1002/cssc.202202241'
bibtex: '@article{Šić_Rohrer_Ricohermoso_Albe_Ionescu_Riedel_Breitzke_Gutmann_Buntkowsky_2023,
title={SiCO Ceramics as Storage Materials for Alkali Metals/Ions: Insights on
Structure Moieties from Solid-State NMR and DFT Calculations}, volume={16}, DOI={10.1002/cssc.202202241}, journal={Chemsuschem},
publisher={John Wiley & Sons, Ltd}, author={Šić, Edina and Rohrer, Jochen
and Ricohermoso, Emmanuel and Albe, Karsten and Ionescu, Emmanuel and Riedel,
Ralf and Breitzke, Hergen and Gutmann, Torsten and Buntkowsky, Gerd}, year={2023},
pages={e202202241} }'
chicago: 'Šić, Edina, Jochen Rohrer, Emmanuel Ricohermoso, Karsten Albe, Emmanuel
Ionescu, Ralf Riedel, Hergen Breitzke, Torsten Gutmann, and Gerd Buntkowsky. “SiCO
Ceramics as Storage Materials for Alkali Metals/Ions: Insights on Structure Moieties
from Solid-State NMR and DFT Calculations.” Chemsuschem 16 (2023): e202202241.
https://doi.org/10.1002/cssc.202202241.'
ieee: 'E. Šić et al., “SiCO Ceramics as Storage Materials for Alkali Metals/Ions:
Insights on Structure Moieties from Solid-State NMR and DFT Calculations,” Chemsuschem,
vol. 16, p. e202202241, 2023, doi: 10.1002/cssc.202202241.'
mla: 'Šić, Edina, et al. “SiCO Ceramics as Storage Materials for Alkali Metals/Ions:
Insights on Structure Moieties from Solid-State NMR and DFT Calculations.” Chemsuschem,
vol. 16, John Wiley & Sons, Ltd, 2023, p. e202202241, doi:10.1002/cssc.202202241.'
short: E. Šić, J. Rohrer, E. Ricohermoso, K. Albe, E. Ionescu, R. Riedel, H. Breitzke,
T. Gutmann, G. Buntkowsky, Chemsuschem 16 (2023) e202202241.
date_created: 2026-02-07T16:11:46Z
date_updated: 2026-02-17T16:13:11Z
doi: 10.1002/cssc.202202241
extern: '1'
intvolume: ' 16'
keyword:
- NMR spectroscopy
- Ceramics
- defects
- density functional calculations
- EPR spectroscopy
language:
- iso: eng
page: e202202241
publication: Chemsuschem
publication_identifier:
issn:
- 1864-5631
publisher: John Wiley & Sons, Ltd
status: public
title: 'SiCO Ceramics as Storage Materials for Alkali Metals/Ions: Insights on Structure
Moieties from Solid-State NMR and DFT Calculations'
type: journal_article
user_id: '100715'
volume: 16
year: '2023'
...
---
_id: '30209'
abstract:
- lang: eng
text: DNA origami technology enables the folding of DNA strands into complex
nanoscale shapes whose properties and interactions with molecular species often
deviate significantly from that of genomic DNA. Here, we investigate the salting-out
of different DNA origami shapes by the kosmotropic salt ammonium sulfate that
is routinely employed in protein precipitation. We find that centrifugation in
the presence of 3 M ammonium sulfate results in notable precipitation of DNA origami
nanostructures but not of double-stranded genomic DNA. The precipitated DNA origami
nanostructures can be resuspended in ammonium sulfate-free buffer without apparent
formation of aggregates or loss of structural integrity. Even though quasi-1D
six-helix bundle DNA origami are slightly less susceptible toward salting-out
than more compact DNA origami triangles and 24-helix bundles, precipitation and
recovery yields appear to be mostly independent of DNA origami shape and superstructure.
Exploiting the specificity of ammonium sulfate salting-out for DNA origami nanostructures,
we further apply this method to separate DNA origami triangles from genomic DNA
fragments in a complex mixture. Our results thus demonstrate the possibility of
concentrating and purifying DNA origami nanostructures by ammonium sulfate-induced
salting-out.
author:
- first_name: Marcel
full_name: Hanke, Marcel
last_name: Hanke
- first_name: Niklas
full_name: Hansen, Niklas
last_name: Hansen
- first_name: Ruiping
full_name: Chen, Ruiping
last_name: Chen
- first_name: Guido
full_name: Grundmeier, Guido
last_name: Grundmeier
- first_name: Karim
full_name: Fahmy, Karim
last_name: Fahmy
- first_name: Adrian
full_name: Keller, Adrian
last_name: Keller
citation:
ama: Hanke M, Hansen N, Chen R, Grundmeier G, Fahmy K, Keller A. Salting-Out of
DNA Origami Nanostructures by Ammonium Sulfate. International Journal of Molecular
Sciences. 2022;23(5):2817. doi:10.3390/ijms23052817
apa: Hanke, M., Hansen, N., Chen, R., Grundmeier, G., Fahmy, K., & Keller, A.
(2022). Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate. International
Journal of Molecular Sciences, 23(5), 2817. https://doi.org/10.3390/ijms23052817
bibtex: '@article{Hanke_Hansen_Chen_Grundmeier_Fahmy_Keller_2022, title={Salting-Out
of DNA Origami Nanostructures by Ammonium Sulfate}, volume={23}, DOI={10.3390/ijms23052817},
number={5}, journal={International Journal of Molecular Sciences}, publisher={MDPI
AG}, author={Hanke, Marcel and Hansen, Niklas and Chen, Ruiping and Grundmeier,
Guido and Fahmy, Karim and Keller, Adrian}, year={2022}, pages={2817} }'
chicago: 'Hanke, Marcel, Niklas Hansen, Ruiping Chen, Guido Grundmeier, Karim Fahmy,
and Adrian Keller. “Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate.”
International Journal of Molecular Sciences 23, no. 5 (2022): 2817. https://doi.org/10.3390/ijms23052817.'
ieee: 'M. Hanke, N. Hansen, R. Chen, G. Grundmeier, K. Fahmy, and A. Keller, “Salting-Out
of DNA Origami Nanostructures by Ammonium Sulfate,” International Journal of
Molecular Sciences, vol. 23, no. 5, p. 2817, 2022, doi: 10.3390/ijms23052817.'
mla: Hanke, Marcel, et al. “Salting-Out of DNA Origami Nanostructures by Ammonium
Sulfate.” International Journal of Molecular Sciences, vol. 23, no. 5,
MDPI AG, 2022, p. 2817, doi:10.3390/ijms23052817.
short: M. Hanke, N. Hansen, R. Chen, G. Grundmeier, K. Fahmy, A. Keller, International
Journal of Molecular Sciences 23 (2022) 2817.
date_created: 2022-03-07T07:28:02Z
date_updated: 2022-03-07T07:29:27Z
department:
- _id: '302'
doi: 10.3390/ijms23052817
intvolume: ' 23'
issue: '5'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
page: '2817'
publication: International Journal of Molecular Sciences
publication_identifier:
issn:
- 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Salting-Out of DNA Origami Nanostructures by Ammonium Sulfate
type: journal_article
user_id: '48864'
volume: 23
year: '2022'
...
---
_id: '32432'
author:
- first_name: Yu
full_name: Yang, Yu
last_name: Yang
- first_name: Jingyuan
full_name: Huang, Jingyuan
last_name: Huang
- first_name: Daniel
full_name: Dornbusch, Daniel
last_name: Dornbusch
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Karim
full_name: Fahmy, Karim
last_name: Fahmy
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
- first_name: David L.
full_name: Cheung, David L.
last_name: Cheung
citation:
ama: Yang Y, Huang J, Dornbusch D, et al. Effect of Surface Hydrophobicity on the
Adsorption of a Pilus-Derived Adhesin-like Peptide. Langmuir. 2022;38:9257–9265.
doi:10.1021/acs.langmuir.2c01016
apa: Yang, Y., Huang, J., Dornbusch, D., Grundmeier, G., Fahmy, K., Keller, A.,
& Cheung, D. L. (2022). Effect of Surface Hydrophobicity on the Adsorption
of a Pilus-Derived Adhesin-like Peptide. Langmuir, 38, 9257–9265.
https://doi.org/10.1021/acs.langmuir.2c01016
bibtex: '@article{Yang_Huang_Dornbusch_Grundmeier_Fahmy_Keller_Cheung_2022, title={Effect
of Surface Hydrophobicity on the Adsorption of a Pilus-Derived Adhesin-like Peptide},
volume={38}, DOI={10.1021/acs.langmuir.2c01016},
journal={Langmuir}, publisher={American Chemical Society (ACS)}, author={Yang,
Yu and Huang, Jingyuan and Dornbusch, Daniel and Grundmeier, Guido and Fahmy,
Karim and Keller, Adrian and Cheung, David L.}, year={2022}, pages={9257–9265}
}'
chicago: 'Yang, Yu, Jingyuan Huang, Daniel Dornbusch, Guido Grundmeier, Karim Fahmy,
Adrian Keller, and David L. Cheung. “Effect of Surface Hydrophobicity on the Adsorption
of a Pilus-Derived Adhesin-like Peptide.” Langmuir 38 (2022): 9257–9265.
https://doi.org/10.1021/acs.langmuir.2c01016.'
ieee: 'Y. Yang et al., “Effect of Surface Hydrophobicity on the Adsorption
of a Pilus-Derived Adhesin-like Peptide,” Langmuir, vol. 38, pp. 9257–9265,
2022, doi: 10.1021/acs.langmuir.2c01016.'
mla: Yang, Yu, et al. “Effect of Surface Hydrophobicity on the Adsorption of a Pilus-Derived
Adhesin-like Peptide.” Langmuir, vol. 38, American Chemical Society (ACS),
2022, pp. 9257–9265, doi:10.1021/acs.langmuir.2c01016.
short: Y. Yang, J. Huang, D. Dornbusch, G. Grundmeier, K. Fahmy, A. Keller, D.L.
Cheung, Langmuir 38 (2022) 9257–9265.
date_created: 2022-07-27T07:45:51Z
date_updated: 2022-08-08T06:39:04Z
department:
- _id: '302'
doi: 10.1021/acs.langmuir.2c01016
intvolume: ' 38'
keyword:
- Electrochemistry
- Spectroscopy
- Surfaces and Interfaces
- Condensed Matter Physics
- General Materials Science
language:
- iso: eng
page: 9257–9265
publication: Langmuir
publication_identifier:
issn:
- 0743-7463
- 1520-5827
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Effect of Surface Hydrophobicity on the Adsorption of a Pilus-Derived Adhesin-like
Peptide
type: journal_article
user_id: '48864'
volume: 38
year: '2022'
...
---
_id: '32589'
abstract:
- lang: eng
text: Guanidinium (Gdm) undergoes interactions with both hydrophilic and
hydrophobic groups and, thus, is a highly potent denaturant of biomolecular structure.
However, our molecular understanding of the interaction of Gdm with proteins and
DNA is still rather limited. Here, we investigated the denaturation of DNA origami
nanostructures by three Gdm salts, i.e., guanidinium chloride (GdmCl), guanidinium
sulfate (Gdm2SO4), and guanidinium thiocyanate (GdmSCN), at different temperatures
and in dependence of incubation time. Using DNA origami nanostructures as sensors
that translate small molecular transitions into nanostructural changes, the denaturing
effects of the Gdm salts were directly visualized by atomic force microscopy.
GdmSCN was the most potent DNA denaturant, which caused complete DNA origami denaturation
at 50 °C already at a concentration of 2 M. Under such harsh conditions, denaturation
occurred within the first 15 min of Gdm exposure, whereas much slower kinetics
were observed for the more weakly denaturing salt Gdm2SO4 at 25 °C. Lastly, we
observed a novel non-monotonous temperature dependence of DNA origami denaturation
in Gdm2SO4 with the fraction of intact nanostructures having an intermediate minimum
at about 40 °C. Our results, thus, provide further insights into the highly complex
Gdm–DNA interaction and underscore the importance of the counteranion species.
author:
- first_name: Marcel
full_name: Hanke, Marcel
last_name: Hanke
- first_name: Niklas
full_name: Hansen, Niklas
last_name: Hansen
- first_name: Emilia
full_name: Tomm, Emilia
last_name: Tomm
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
- first_name: Adrian
full_name: Keller, Adrian
id: '48864'
last_name: Keller
orcid: 0000-0001-7139-3110
citation:
ama: Hanke M, Hansen N, Tomm E, Grundmeier G, Keller A. Time-Dependent DNA Origami
Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate.
International Journal of Molecular Sciences. 2022;23(15):8547. doi:10.3390/ijms23158547
apa: Hanke, M., Hansen, N., Tomm, E., Grundmeier, G., & Keller, A. (2022). Time-Dependent
DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium
Thiocyanate. International Journal of Molecular Sciences, 23(15),
8547. https://doi.org/10.3390/ijms23158547
bibtex: '@article{Hanke_Hansen_Tomm_Grundmeier_Keller_2022, title={Time-Dependent
DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium
Thiocyanate}, volume={23}, DOI={10.3390/ijms23158547},
number={15}, journal={International Journal of Molecular Sciences}, publisher={MDPI
AG}, author={Hanke, Marcel and Hansen, Niklas and Tomm, Emilia and Grundmeier,
Guido and Keller, Adrian}, year={2022}, pages={8547} }'
chicago: 'Hanke, Marcel, Niklas Hansen, Emilia Tomm, Guido Grundmeier, and Adrian
Keller. “Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium
Sulfate, and Guanidinium Thiocyanate.” International Journal of Molecular Sciences
23, no. 15 (2022): 8547. https://doi.org/10.3390/ijms23158547.'
ieee: 'M. Hanke, N. Hansen, E. Tomm, G. Grundmeier, and A. Keller, “Time-Dependent
DNA Origami Denaturation by Guanidinium Chloride, Guanidinium Sulfate, and Guanidinium
Thiocyanate,” International Journal of Molecular Sciences, vol. 23, no.
15, p. 8547, 2022, doi: 10.3390/ijms23158547.'
mla: Hanke, Marcel, et al. “Time-Dependent DNA Origami Denaturation by Guanidinium
Chloride, Guanidinium Sulfate, and Guanidinium Thiocyanate.” International
Journal of Molecular Sciences, vol. 23, no. 15, MDPI AG, 2022, p. 8547, doi:10.3390/ijms23158547.
short: M. Hanke, N. Hansen, E. Tomm, G. Grundmeier, A. Keller, International Journal
of Molecular Sciences 23 (2022) 8547.
date_created: 2022-08-08T06:39:20Z
date_updated: 2022-08-08T06:40:14Z
department:
- _id: '302'
doi: 10.3390/ijms23158547
intvolume: ' 23'
issue: '15'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Computer Science Applications
- Spectroscopy
- Molecular Biology
- General Medicine
- Catalysis
language:
- iso: eng
page: '8547'
publication: International Journal of Molecular Sciences
publication_identifier:
issn:
- 1422-0067
publication_status: published
publisher: MDPI AG
status: public
title: Time-Dependent DNA Origami Denaturation by Guanidinium Chloride, Guanidinium
Sulfate, and Guanidinium Thiocyanate
type: journal_article
user_id: '48864'
volume: 23
year: '2022'
...
---
_id: '40986'
abstract:
- lang: eng
text: Currently, chemistry and physics are strongly dependent on the concept of
the oxidation state. While the formal oxidation state is easily evaluated, the
real physical oxidation state value is often difficult to determine and significantly
varies from the formal values. Determination of the ionization threshold in X-ray
absorption spectroscopy (XANES) relies on the absorption edge position and sometimes
poses limitations, mainly due to the edge resonances. Moreover, the lower energy
states can be probed only within x-soft or XUV photons providing only surface
state information of probed materials. Here, we employ high energy resolution
off-resonant spectroscopy to determine both 1s and 3p binding energies of Fe-based
materials and therefore correlate to their physical oxidation state. The results
are compared to the ones obtained with classical X-ray absorption, X-ray emission,
and photoelectron spectroscopies. The observed differences in binding energies
are discussed in a frame of initial and final state interactions with the atom's
electronic configurations. The presented methodology is discussed towards potential
use to single-shot experiments and application at X-ray free-electron lasers.
Alternatively, core level X-ray emission spectroscopy can be used, but the emission
line positions are strongly affected by spin-orbit interaction. However, due to
the energy transfer from the photon to the excited core electron, the same information
as in XANES is probed in high energy resolution off-resonant spectroscopy (HEROS).
Based on the Kramers–Heisenberg theory, we propose a new approach for ionization
threshold determination which is free of the limitations encountered in XANES-based
determination of the core state energy. Namely, the value of core state energy
can be determined analytically using a few HEROS spectra recorded with significantly
higher spectral resolution. This approach provides a basis for the universal physical
oxidation state determination method.
author:
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Jakub
full_name: Szlachetko, Jakub
last_name: Szlachetko
- first_name: Rafał
full_name: Fanselow, Rafał
last_name: Fanselow
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Nowakowski M, Kalinko A, Szlachetko J, Fanselow R, Bauer M. High resolution
off resonant spectroscopy as a probe of the oxidation state. Journal of Analytical
Atomic Spectrometry. 2022;37(11):2383-2391. doi:10.1039/d2ja00232a
apa: Nowakowski, M., Kalinko, A., Szlachetko, J., Fanselow, R., & Bauer, M.
(2022). High resolution off resonant spectroscopy as a probe of the oxidation
state. Journal of Analytical Atomic Spectrometry, 37(11), 2383–2391.
https://doi.org/10.1039/d2ja00232a
bibtex: '@article{Nowakowski_Kalinko_Szlachetko_Fanselow_Bauer_2022, title={High
resolution off resonant spectroscopy as a probe of the oxidation state}, volume={37},
DOI={10.1039/d2ja00232a}, number={11},
journal={Journal of Analytical Atomic Spectrometry}, publisher={Royal Society
of Chemistry (RSC)}, author={Nowakowski, Michał and Kalinko, Aleksandr and Szlachetko,
Jakub and Fanselow, Rafał and Bauer, Matthias}, year={2022}, pages={2383–2391}
}'
chicago: 'Nowakowski, Michał, Aleksandr Kalinko, Jakub Szlachetko, Rafał Fanselow,
and Matthias Bauer. “High Resolution off Resonant Spectroscopy as a Probe of the
Oxidation State.” Journal of Analytical Atomic Spectrometry 37, no. 11
(2022): 2383–91. https://doi.org/10.1039/d2ja00232a.'
ieee: 'M. Nowakowski, A. Kalinko, J. Szlachetko, R. Fanselow, and M. Bauer, “High
resolution off resonant spectroscopy as a probe of the oxidation state,” Journal
of Analytical Atomic Spectrometry, vol. 37, no. 11, pp. 2383–2391, 2022, doi:
10.1039/d2ja00232a.'
mla: Nowakowski, Michał, et al. “High Resolution off Resonant Spectroscopy as a
Probe of the Oxidation State.” Journal of Analytical Atomic Spectrometry,
vol. 37, no. 11, Royal Society of Chemistry (RSC), 2022, pp. 2383–91, doi:10.1039/d2ja00232a.
short: M. Nowakowski, A. Kalinko, J. Szlachetko, R. Fanselow, M. Bauer, Journal
of Analytical Atomic Spectrometry 37 (2022) 2383–2391.
date_created: 2023-01-30T16:24:06Z
date_updated: 2024-05-07T11:43:54Z
department:
- _id: '35'
- _id: '306'
doi: 10.1039/d2ja00232a
intvolume: ' 37'
issue: '11'
keyword:
- Spectroscopy
- Analytical Chemistry
language:
- iso: eng
page: 2383-2391
publication: Journal of Analytical Atomic Spectrometry
publication_identifier:
issn:
- 0267-9477
- 1364-5544
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: High resolution off resonant spectroscopy as a probe of the oxidation state
type: journal_article
user_id: '48467'
volume: 37
year: '2022'
...
---
_id: '40984'
abstract:
- lang: eng
text: A two-step seeded-growth method was refined to synthesize Au@Pd core@shell
nanoparticles with thin Pd shells, which were then deposited onto alumina to obtain
a supported Au@Pd/Al2O3 catalyst active for prototypical CO oxidation. By the
strict control of temperature and Pd/Au molar ratio and the use of l-ascorbic
acid for making both Au cores and Pd shells, a 1.5 nm Pd layer is formed around
the Au core, as evidenced by transmission electron microscopy and energy-dispersive
spectroscopy. The core@shell structure and the Pd shell remain intact upon deposition
onto alumina and after being used for CO oxidation, as revealed by additional
X-ray diffraction and X-ray photoemission spectroscopy before and after the reaction.
The Pd shell surface was characterized with in situ infrared (IR) spectroscopy
using CO as a chemical probe during CO adsorption–desorption. The IR bands for
CO ad-species on the Pd shell suggest that the shell exposes mostly low-index
surfaces, likely Pd(111) as the majority facet. Generally, the IR bands are blue-shifted
as compared to conventional Pd/alumina catalysts, which may be due to the different
support materials for Pd, Au versus Al2O3, and/or less strain of the Pd shell.
Frequencies obtained from density functional calculations suggest the latter to
be significant. Further, the catalytic CO oxidation ignition-extinction processes
were followed by in situ IR, which shows the common CO poisoning and kinetic behavior
associated with competitive adsorption of CO and O2 that is typically observed
for noble metal catalysts.
author:
- first_name: Yanyue
full_name: Feng, Yanyue
last_name: Feng
- first_name: Andreas
full_name: Schaefer, Andreas
last_name: Schaefer
- first_name: Anders
full_name: Hellman, Anders
last_name: Hellman
- first_name: Mengqiao
full_name: Di, Mengqiao
last_name: Di
- first_name: Hanna
full_name: Härelind, Hanna
last_name: Härelind
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Per-Anders
full_name: Carlsson, Per-Anders
last_name: Carlsson
citation:
ama: Feng Y, Schaefer A, Hellman A, et al. Synthesis and Characterization of Catalytically
Active Au Core─Pd Shell Nanoparticles Supported on Alumina. Langmuir. 2022;38(42):12859-12870.
doi:10.1021/acs.langmuir.2c01834
apa: Feng, Y., Schaefer, A., Hellman, A., Di, M., Härelind, H., Bauer, M., &
Carlsson, P.-A. (2022). Synthesis and Characterization of Catalytically Active
Au Core─Pd Shell Nanoparticles Supported on Alumina. Langmuir, 38(42),
12859–12870. https://doi.org/10.1021/acs.langmuir.2c01834
bibtex: '@article{Feng_Schaefer_Hellman_Di_Härelind_Bauer_Carlsson_2022, title={Synthesis
and Characterization of Catalytically Active Au Core─Pd Shell Nanoparticles Supported
on Alumina}, volume={38}, DOI={10.1021/acs.langmuir.2c01834},
number={42}, journal={Langmuir}, publisher={American Chemical Society (ACS)},
author={Feng, Yanyue and Schaefer, Andreas and Hellman, Anders and Di, Mengqiao
and Härelind, Hanna and Bauer, Matthias and Carlsson, Per-Anders}, year={2022},
pages={12859–12870} }'
chicago: 'Feng, Yanyue, Andreas Schaefer, Anders Hellman, Mengqiao Di, Hanna Härelind,
Matthias Bauer, and Per-Anders Carlsson. “Synthesis and Characterization of Catalytically
Active Au Core─Pd Shell Nanoparticles Supported on Alumina.” Langmuir 38,
no. 42 (2022): 12859–70. https://doi.org/10.1021/acs.langmuir.2c01834.'
ieee: 'Y. Feng et al., “Synthesis and Characterization of Catalytically Active
Au Core─Pd Shell Nanoparticles Supported on Alumina,” Langmuir, vol. 38,
no. 42, pp. 12859–12870, 2022, doi: 10.1021/acs.langmuir.2c01834.'
mla: Feng, Yanyue, et al. “Synthesis and Characterization of Catalytically Active
Au Core─Pd Shell Nanoparticles Supported on Alumina.” Langmuir, vol. 38,
no. 42, American Chemical Society (ACS), 2022, pp. 12859–70, doi:10.1021/acs.langmuir.2c01834.
short: Y. Feng, A. Schaefer, A. Hellman, M. Di, H. Härelind, M. Bauer, P.-A. Carlsson,
Langmuir 38 (2022) 12859–12870.
date_created: 2023-01-30T16:22:57Z
date_updated: 2023-01-31T08:00:11Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.langmuir.2c01834
intvolume: ' 38'
issue: '42'
keyword:
- Electrochemistry
- Spectroscopy
- Surfaces and Interfaces
- Condensed Matter Physics
- General Materials Science
language:
- iso: eng
page: 12859-12870
publication: Langmuir
publication_identifier:
issn:
- 0743-7463
- 1520-5827
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Synthesis and Characterization of Catalytically Active Au Core─Pd Shell Nanoparticles
Supported on Alumina
type: journal_article
user_id: '48467'
volume: 38
year: '2022'
...
---
_id: '41319'
abstract:
- lang: eng
text: The direct conversion between HEROS-XES and XANES edge position (E0)
without need of measuring absorption spectra.
author:
- first_name: Michal
full_name: Nowakowski, Michal
last_name: Nowakowski
- first_name: Aleksandr
full_name: Kalinko, Aleksandr
last_name: Kalinko
- first_name: Jakub
full_name: Szlachetko, Jakub
last_name: Szlachetko
- first_name: Rafał
full_name: Fanselow, Rafał
last_name: Fanselow
- first_name: Matthias
full_name: Bauer, Matthias
last_name: Bauer
citation:
ama: Nowakowski M, Kalinko A, Szlachetko J, Fanselow R, Bauer M. High resolution
off resonant spectroscopy as a probe of the oxidation state. Journal of Analytical
Atomic Spectrometry. 2022;37(11):2383-2391. doi:10.1039/d2ja00232a
apa: Nowakowski, M., Kalinko, A., Szlachetko, J., Fanselow, R., & Bauer, M.
(2022). High resolution off resonant spectroscopy as a probe of the oxidation
state. Journal of Analytical Atomic Spectrometry, 37(11), 2383–2391.
https://doi.org/10.1039/d2ja00232a
bibtex: '@article{Nowakowski_Kalinko_Szlachetko_Fanselow_Bauer_2022, title={High
resolution off resonant spectroscopy as a probe of the oxidation state}, volume={37},
DOI={10.1039/d2ja00232a}, number={11},
journal={Journal of Analytical Atomic Spectrometry}, publisher={Royal Society
of Chemistry (RSC)}, author={Nowakowski, Michal and Kalinko, Aleksandr and Szlachetko,
Jakub and Fanselow, Rafał and Bauer, Matthias}, year={2022}, pages={2383–2391}
}'
chicago: 'Nowakowski, Michal, Aleksandr Kalinko, Jakub Szlachetko, Rafał Fanselow,
and Matthias Bauer. “High Resolution off Resonant Spectroscopy as a Probe of the
Oxidation State.” Journal of Analytical Atomic Spectrometry 37, no. 11
(2022): 2383–91. https://doi.org/10.1039/d2ja00232a.'
ieee: 'M. Nowakowski, A. Kalinko, J. Szlachetko, R. Fanselow, and M. Bauer, “High
resolution off resonant spectroscopy as a probe of the oxidation state,” Journal
of Analytical Atomic Spectrometry, vol. 37, no. 11, pp. 2383–2391, 2022, doi:
10.1039/d2ja00232a.'
mla: Nowakowski, Michal, et al. “High Resolution off Resonant Spectroscopy as a
Probe of the Oxidation State.” Journal of Analytical Atomic Spectrometry,
vol. 37, no. 11, Royal Society of Chemistry (RSC), 2022, pp. 2383–91, doi:10.1039/d2ja00232a.
short: M. Nowakowski, A. Kalinko, J. Szlachetko, R. Fanselow, M. Bauer, Journal
of Analytical Atomic Spectrometry 37 (2022) 2383–2391.
date_created: 2023-01-31T22:47:06Z
date_updated: 2023-02-01T08:50:34Z
doi: 10.1039/d2ja00232a
intvolume: ' 37'
issue: '11'
keyword:
- Spectroscopy
- Analytical Chemistry
language:
- iso: eng
page: 2383-2391
publication: Journal of Analytical Atomic Spectrometry
publication_identifier:
issn:
- 0267-9477
- 1364-5544
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: High resolution off resonant spectroscopy as a probe of the oxidation state
type: journal_article
user_id: '78878'
volume: 37
year: '2022'
...
---
_id: '62801'
abstract:
- lang: eng
text: The three-dimensional (3D) distribution of individual atoms on the surface
of catalyst nanoparticles plays a vital role in their activity and stability.
Optimising the performance of electrocatalysts requires atomic-scale information,
but it is difficult to obtain. Here, we use atom probe tomography to elucidate
the 3D structure of 10 nm sized Co2FeO4 and CoFe2O4 nanoparticles during oxygen
evolution reaction (OER). We reveal nanoscale spinodal decomposition in pristine
Co2FeO4. The interfaces of Co-rich and Fe-rich nanodomains of Co2FeO4 become trapping
sites for hydroxyl groups, contributing to a higher OER activity compared to that
of CoFe2O4. However, the activity of Co2FeO4 drops considerably due to concurrent
irreversible transformation towards CoIVO2 and pronounced Fe dissolution. In contrast,
there is negligible elemental redistribution for CoFe2O4 after OER, except for
surface structural transformation towards (FeIII, CoIII)2O3. Overall, our study
provides a unique 3D compositional distribution of mixed Co-Fe spinel oxides,
which gives atomic-scale insights into active sites and the deactivation of electrocatalysts
during OER.
article_number: '179'
article_type: original
author:
- first_name: Weikai
full_name: Xiang, Weikai
last_name: Xiang
- first_name: Nating
full_name: Yang, Nating
last_name: Yang
- first_name: Xiaopeng
full_name: Li, Xiaopeng
last_name: Li
- first_name: Julia
full_name: Linnemann, Julia
id: '116779'
last_name: Linnemann
orcid: 0000-0001-6883-5424
- first_name: Ulrich
full_name: Hagemann, Ulrich
last_name: Hagemann
- first_name: Olaf
full_name: Ruediger, Olaf
last_name: Ruediger
- first_name: Markus
full_name: Heidelmann, Markus
last_name: Heidelmann
- first_name: Tobias
full_name: Falk, Tobias
last_name: Falk
- first_name: Matteo
full_name: Aramini, Matteo
last_name: Aramini
- first_name: Serena
full_name: DeBeer, Serena
last_name: DeBeer
- first_name: Martin
full_name: Muhler, Martin
last_name: Muhler
- first_name: Kristina
full_name: Tschulik, Kristina
last_name: Tschulik
- first_name: Tong
full_name: Li, Tong
last_name: Li
citation:
ama: Xiang W, Yang N, Li X, et al. 3D atomic-scale imaging of mixed Co-Fe spinel
oxide nanoparticles during oxygen evolution reaction. Nature Communications.
2022;13(1). doi:10.1038/s41467-021-27788-2
apa: Xiang, W., Yang, N., Li, X., Linnemann, J., Hagemann, U., Ruediger, O., Heidelmann,
M., Falk, T., Aramini, M., DeBeer, S., Muhler, M., Tschulik, K., & Li, T.
(2022). 3D atomic-scale imaging of mixed Co-Fe spinel oxide nanoparticles during
oxygen evolution reaction. Nature Communications, 13(1), Article
179. https://doi.org/10.1038/s41467-021-27788-2
bibtex: '@article{Xiang_Yang_Li_Linnemann_Hagemann_Ruediger_Heidelmann_Falk_Aramini_DeBeer_et
al._2022, title={3D atomic-scale imaging of mixed Co-Fe spinel oxide nanoparticles
during oxygen evolution reaction}, volume={13}, DOI={10.1038/s41467-021-27788-2},
number={1179}, journal={Nature Communications}, publisher={Springer Science and
Business Media LLC}, author={Xiang, Weikai and Yang, Nating and Li, Xiaopeng and
Linnemann, Julia and Hagemann, Ulrich and Ruediger, Olaf and Heidelmann, Markus
and Falk, Tobias and Aramini, Matteo and DeBeer, Serena and et al.}, year={2022}
}'
chicago: Xiang, Weikai, Nating Yang, Xiaopeng Li, Julia Linnemann, Ulrich Hagemann,
Olaf Ruediger, Markus Heidelmann, et al. “3D Atomic-Scale Imaging of Mixed Co-Fe
Spinel Oxide Nanoparticles during Oxygen Evolution Reaction.” Nature Communications
13, no. 1 (2022). https://doi.org/10.1038/s41467-021-27788-2.
ieee: 'W. Xiang et al., “3D atomic-scale imaging of mixed Co-Fe spinel oxide
nanoparticles during oxygen evolution reaction,” Nature Communications,
vol. 13, no. 1, Art. no. 179, 2022, doi: 10.1038/s41467-021-27788-2.'
mla: Xiang, Weikai, et al. “3D Atomic-Scale Imaging of Mixed Co-Fe Spinel Oxide
Nanoparticles during Oxygen Evolution Reaction.” Nature Communications,
vol. 13, no. 1, 179, Springer Science and Business Media LLC, 2022, doi:10.1038/s41467-021-27788-2.
short: W. Xiang, N. Yang, X. Li, J. Linnemann, U. Hagemann, O. Ruediger, M. Heidelmann,
T. Falk, M. Aramini, S. DeBeer, M. Muhler, K. Tschulik, T. Li, Nature Communications
13 (2022).
date_created: 2025-12-03T15:22:16Z
date_updated: 2025-12-03T16:30:12Z
department:
- _id: '985'
doi: 10.1038/s41467-021-27788-2
extern: '1'
intvolume: ' 13'
issue: '1'
keyword:
- electrocatalysis
- oxygen evolution reaction
- cobalt spinel
- electrochemical impedance spectroscopy
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://www.nature.com/articles/s41467-021-27788-2
oa: '1'
publication: Nature Communications
publication_identifier:
issn:
- 2041-1723
publication_status: published
publisher: Springer Science and Business Media LLC
quality_controlled: '1'
status: public
title: 3D atomic-scale imaging of mixed Co-Fe spinel oxide nanoparticles during oxygen
evolution reaction
type: journal_article
user_id: '116779'
volume: 13
year: '2022'
...
---
_id: '34087'
author:
- first_name: Steffen
full_name: Knust, Steffen
last_name: Knust
- first_name: Lukas
full_name: Ruhm, Lukas
last_name: Ruhm
- first_name: Andreas
full_name: Kuhlmann, Andreas
last_name: Kuhlmann
- first_name: Dennis
full_name: Meinderink, Dennis
id: '32378'
last_name: Meinderink
orcid: 0000-0002-2755-6514
- first_name: Julius
full_name: Bürger, Julius
id: '46952'
last_name: Bürger
- first_name: Jörg
full_name: Lindner, Jörg
id: '20797'
last_name: Lindner
- first_name: Maria Teresa
full_name: de los Arcos de Pedro, Maria Teresa
id: '54556'
last_name: de los Arcos de Pedro
- first_name: Guido
full_name: Grundmeier, Guido
id: '194'
last_name: Grundmeier
citation:
ama: Knust S, Ruhm L, Kuhlmann A, et al. In situ backside Raman spectroscopy of
zinc oxide nanorods in an atmospheric‐pressure dielectric barrier discharge plasma.
Journal of Raman Spectroscopy. 2021;52(7):1237-1245. doi:10.1002/jrs.6123
apa: Knust, S., Ruhm, L., Kuhlmann, A., Meinderink, D., Bürger, J., Lindner, J.,
de los Arcos de Pedro, M. T., & Grundmeier, G. (2021). In situ backside Raman
spectroscopy of zinc oxide nanorods in an atmospheric‐pressure dielectric barrier
discharge plasma. Journal of Raman Spectroscopy, 52(7), 1237–1245.
https://doi.org/10.1002/jrs.6123
bibtex: '@article{Knust_Ruhm_Kuhlmann_Meinderink_Bürger_Lindner_de los Arcos de
Pedro_Grundmeier_2021, title={In situ backside Raman spectroscopy of zinc oxide
nanorods in an atmospheric‐pressure dielectric barrier discharge plasma}, volume={52},
DOI={10.1002/jrs.6123}, number={7},
journal={Journal of Raman Spectroscopy}, publisher={Wiley}, author={Knust, Steffen
and Ruhm, Lukas and Kuhlmann, Andreas and Meinderink, Dennis and Bürger, Julius
and Lindner, Jörg and de los Arcos de Pedro, Maria Teresa and Grundmeier, Guido},
year={2021}, pages={1237–1245} }'
chicago: 'Knust, Steffen, Lukas Ruhm, Andreas Kuhlmann, Dennis Meinderink, Julius
Bürger, Jörg Lindner, Maria Teresa de los Arcos de Pedro, and Guido Grundmeier.
“In Situ Backside Raman Spectroscopy of Zinc Oxide Nanorods in an Atmospheric‐pressure
Dielectric Barrier Discharge Plasma.” Journal of Raman Spectroscopy 52,
no. 7 (2021): 1237–45. https://doi.org/10.1002/jrs.6123.'
ieee: 'S. Knust et al., “In situ backside Raman spectroscopy of zinc oxide
nanorods in an atmospheric‐pressure dielectric barrier discharge plasma,” Journal
of Raman Spectroscopy, vol. 52, no. 7, pp. 1237–1245, 2021, doi: 10.1002/jrs.6123.'
mla: Knust, Steffen, et al. “In Situ Backside Raman Spectroscopy of Zinc Oxide Nanorods
in an Atmospheric‐pressure Dielectric Barrier Discharge Plasma.” Journal of
Raman Spectroscopy, vol. 52, no. 7, Wiley, 2021, pp. 1237–45, doi:10.1002/jrs.6123.
short: S. Knust, L. Ruhm, A. Kuhlmann, D. Meinderink, J. Bürger, J. Lindner, M.T.
de los Arcos de Pedro, G. Grundmeier, Journal of Raman Spectroscopy 52 (2021)
1237–1245.
date_created: 2022-11-15T14:08:53Z
date_updated: 2023-01-04T14:51:10Z
department:
- _id: '15'
doi: 10.1002/jrs.6123
intvolume: ' 52'
issue: '7'
keyword:
- Spectroscopy
- General Materials Science
language:
- iso: eng
page: 1237-1245
publication: Journal of Raman Spectroscopy
publication_identifier:
issn:
- 0377-0486
- 1097-4555
publication_status: published
publisher: Wiley
status: public
title: In situ backside Raman spectroscopy of zinc oxide nanorods in an atmospheric‐pressure
dielectric barrier discharge plasma
type: journal_article
user_id: '77496'
volume: 52
year: '2021'
...
---
_id: '19823'
abstract:
- lang: eng
text: 'Individual grains of chalcopyrite solar cell absorbers can facet in different
crystallographic directions at their surfaces. To gain a deeper understanding
of the junction formation in these devices, we correlate variations in the surface
facet orientation with the defect electronic properties. We use a combined analytical
approach based on scanning tunneling spectroscopy (STS), scanning electron microscopy,
and electron back scatter diffraction (EBSD), where we perform these experiments
on identical surface areas as small as 2 × 2 µm2 with a lateral resolution well
below 50 nm. The topography of the absorber surfaces indicates two main morphological
features: micro-faceted, long basalt-like columns and their short nano-faceted
terminations. Our STS results reveal that the long columns exhibit spectral signatures
typical for the presence of pronounced oxidation-induced surface dipoles in conjunction
with an increased density of electronic defect levels. In contrast, the nano-faceted
terminations of the basalt-like columns are largely passivated in terms of electronic
defect levels within the band gap region. Corresponding crystallographic data
based on EBSD experiments show that the surface of the basalt-like columns can
be assigned to intrinsically polar facet orientations, while the passivated terminations
are assigned to non-polar planes. Ab-initio calculations suggest that the polar
surfaces are more prone to oxidation and resulting O-induced defects, in comparison
to non-polar planes. Our results emphasize the correlation between morphology,
surface facet orientations and surface electronic properties. Furthermore, this
work aids in gaining a fundamental understanding of oxidation induced lateral
inhomogeneities in view of the p-n junction formation in chalcopyrite thin-film
solar cells.'
author:
- first_name: Amala
full_name: Elizabeth, Amala
last_name: Elizabeth
- first_name: Hauke
full_name: Conradi, Hauke
last_name: Conradi
- first_name: Sudhir
full_name: K. Sahoo, Sudhir
last_name: K. Sahoo
- first_name: Tim
full_name: Kodalle, Tim
last_name: Kodalle
- first_name: Christian
full_name: A. Kaufmann, Christian
last_name: A. Kaufmann
- first_name: Thomas
full_name: Kühne, Thomas
id: '49079'
last_name: Kühne
- first_name: Hossein
full_name: Mirhosseini, Hossein
id: '71051'
last_name: Mirhosseini
orcid: https://orcid.org/0000-0001-6179-1545
- first_name: Daniel
full_name: Abou-Ras, Daniel
last_name: Abou-Ras
- first_name: Harry
full_name: Mönig, Harry
last_name: Mönig
citation:
ama: Elizabeth A, Conradi H, K. Sahoo S, et al. Correlating facet orientation, defect-level
density and dipole layer formation at the surface of polycrystalline CuInSe2 thin
films. Acta Materialia. 2020;200. doi:https://doi.org/10.1016/j.actamat.2020.09.028
apa: Elizabeth, A., Conradi, H., K. Sahoo, S., Kodalle, T., A. Kaufmann, C., Kühne,
T., … Mönig, H. (2020). Correlating facet orientation, defect-level density and
dipole layer formation at the surface of polycrystalline CuInSe2 thin films. Acta
Materialia, 200. https://doi.org/10.1016/j.actamat.2020.09.028
bibtex: '@article{Elizabeth_Conradi_K. Sahoo_Kodalle_A. Kaufmann_Kühne_Mirhosseini_Abou-Ras_Mönig_2020,
title={Correlating facet orientation, defect-level density and dipole layer formation
at the surface of polycrystalline CuInSe2 thin films}, volume={200}, DOI={https://doi.org/10.1016/j.actamat.2020.09.028},
journal={Acta Materialia}, author={Elizabeth, Amala and Conradi, Hauke and K.
Sahoo, Sudhir and Kodalle, Tim and A. Kaufmann, Christian and Kühne, Thomas and
Mirhosseini, Hossein and Abou-Ras, Daniel and Mönig, Harry}, year={2020} }'
chicago: Elizabeth, Amala, Hauke Conradi, Sudhir K. Sahoo, Tim Kodalle, Christian
A. Kaufmann, Thomas Kühne, Hossein Mirhosseini, Daniel Abou-Ras, and Harry Mönig.
“Correlating Facet Orientation, Defect-Level Density and Dipole Layer Formation
at the Surface of Polycrystalline CuInSe2 Thin Films.” Acta Materialia
200 (2020). https://doi.org/10.1016/j.actamat.2020.09.028.
ieee: A. Elizabeth et al., “Correlating facet orientation, defect-level density
and dipole layer formation at the surface of polycrystalline CuInSe2 thin films,”
Acta Materialia, vol. 200, 2020.
mla: Elizabeth, Amala, et al. “Correlating Facet Orientation, Defect-Level Density
and Dipole Layer Formation at the Surface of Polycrystalline CuInSe2 Thin Films.”
Acta Materialia, vol. 200, 2020, doi:https://doi.org/10.1016/j.actamat.2020.09.028.
short: A. Elizabeth, H. Conradi, S. K. Sahoo, T. Kodalle, C. A. Kaufmann, T. Kühne,
H. Mirhosseini, D. Abou-Ras, H. Mönig, Acta Materialia 200 (2020).
date_created: 2020-10-01T09:19:55Z
date_updated: 2022-01-06T06:54:13Z
department:
- _id: '613'
doi: https://doi.org/10.1016/j.actamat.2020.09.028
intvolume: ' 200'
keyword:
- Chalcopyrite absorber
- Scanning tunneling spectroscopy
- Electron backscatter diffraction
- Density functional theory
- Surface dipole
language:
- iso: eng
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Acta Materialia
publication_identifier:
issn:
- 1359-6454
status: public
title: Correlating facet orientation, defect-level density and dipole layer formation
at the surface of polycrystalline CuInSe2 thin films
type: journal_article
user_id: '71692'
volume: 200
year: '2020'
...
---
_id: '41024'
article_number: '034101'
author:
- first_name: Jure
full_name: Gujt, Jure
last_name: Gujt
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Frederik
full_name: Zysk, Frederik
id: '14757'
last_name: Zysk
- first_name: Vicky
full_name: Süß, Vicky
last_name: Süß
- first_name: Claudia
full_name: Felser, Claudia
last_name: Felser
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Thomas
full_name: Kühne, Thomas
id: '49079'
last_name: Kühne
citation:
ama: Gujt J, Zimmer P, Zysk F, et al. Water structure near the surface of Weyl semimetals
as catalysts in photocatalytic proton reduction. Structural Dynamics. 2020;7(3).
doi:10.1063/4.0000008
apa: Gujt, J., Zimmer, P., Zysk, F., Süß, V., Felser, C., Bauer, M., & Kühne,
T. (2020). Water structure near the surface of Weyl semimetals as catalysts in
photocatalytic proton reduction. Structural Dynamics, 7(3), Article
034101. https://doi.org/10.1063/4.0000008
bibtex: '@article{Gujt_Zimmer_Zysk_Süß_Felser_Bauer_Kühne_2020, title={Water structure
near the surface of Weyl semimetals as catalysts in photocatalytic proton reduction},
volume={7}, DOI={10.1063/4.0000008},
number={3034101}, journal={Structural Dynamics}, publisher={AIP Publishing}, author={Gujt,
Jure and Zimmer, Peter and Zysk, Frederik and Süß, Vicky and Felser, Claudia and
Bauer, Matthias and Kühne, Thomas}, year={2020} }'
chicago: Gujt, Jure, Peter Zimmer, Frederik Zysk, Vicky Süß, Claudia Felser, Matthias
Bauer, and Thomas Kühne. “Water Structure near the Surface of Weyl Semimetals
as Catalysts in Photocatalytic Proton Reduction.” Structural Dynamics 7,
no. 3 (2020). https://doi.org/10.1063/4.0000008.
ieee: 'J. Gujt et al., “Water structure near the surface of Weyl semimetals
as catalysts in photocatalytic proton reduction,” Structural Dynamics,
vol. 7, no. 3, Art. no. 034101, 2020, doi: 10.1063/4.0000008.'
mla: Gujt, Jure, et al. “Water Structure near the Surface of Weyl Semimetals as
Catalysts in Photocatalytic Proton Reduction.” Structural Dynamics, vol.
7, no. 3, 034101, AIP Publishing, 2020, doi:10.1063/4.0000008.
short: J. Gujt, P. Zimmer, F. Zysk, V. Süß, C. Felser, M. Bauer, T. Kühne, Structural
Dynamics 7 (2020).
date_created: 2023-01-30T17:40:53Z
date_updated: 2023-01-31T08:23:35Z
department:
- _id: '35'
- _id: '306'
doi: 10.1063/4.0000008
intvolume: ' 7'
issue: '3'
keyword:
- Spectroscopy
- Condensed Matter Physics
- Instrumentation
- Radiation
language:
- iso: eng
publication: Structural Dynamics
publication_identifier:
issn:
- 2329-7778
publication_status: published
publisher: AIP Publishing
status: public
title: Water structure near the surface of Weyl semimetals as catalysts in photocatalytic
proton reduction
type: journal_article
user_id: '27611'
volume: 7
year: '2020'
...
---
_id: '40580'
abstract:
- lang: eng
text: A gas sensor comprising of a planar electrode device covered with a thin
layer of gel polymer electrolyte gave accurate and fast sensing responses for
oxygen and ammonia detection in both the cathodic and anodic potential regions.
author:
- first_name: Junqiao
full_name: Lee, Junqiao
last_name: Lee
- first_name: Ghulam
full_name: Hussain, Ghulam
last_name: Hussain
- first_name: Nieves
full_name: Lopez Salas, Nieves
id: '98120'
last_name: Lopez Salas
orcid: https://orcid.org/0000-0002-8438-9548
- first_name: Douglas R.
full_name: MacFarlane, Douglas R.
last_name: MacFarlane
- first_name: Debbie S.
full_name: Silvester, Debbie S.
last_name: Silvester
citation:
ama: Lee J, Hussain G, Lopez Salas N, MacFarlane DR, Silvester DS. Thin films of
poly(vinylidene fluoride-co-hexafluoropropylene)-ionic liquid mixtures
as amperometric gas sensing materials for oxygen and ammonia. The Analyst.
2020;145(5):1915-1924. doi:10.1039/c9an02153a
apa: Lee, J., Hussain, G., Lopez Salas, N., MacFarlane, D. R., & Silvester,
D. S. (2020). Thin films of poly(vinylidene fluoride-co-hexafluoropropylene)-ionic
liquid mixtures as amperometric gas sensing materials for oxygen and ammonia.
The Analyst, 145(5), 1915–1924. https://doi.org/10.1039/c9an02153a
bibtex: '@article{Lee_Hussain_Lopez Salas_MacFarlane_Silvester_2020, title={Thin
films of poly(vinylidene fluoride-co-hexafluoropropylene)-ionic liquid
mixtures as amperometric gas sensing materials for oxygen and ammonia}, volume={145},
DOI={10.1039/c9an02153a}, number={5},
journal={The Analyst}, publisher={Royal Society of Chemistry (RSC)}, author={Lee,
Junqiao and Hussain, Ghulam and Lopez Salas, Nieves and MacFarlane, Douglas R.
and Silvester, Debbie S.}, year={2020}, pages={1915–1924} }'
chicago: 'Lee, Junqiao, Ghulam Hussain, Nieves Lopez Salas, Douglas R. MacFarlane,
and Debbie S. Silvester. “Thin Films of Poly(Vinylidene Fluoride-Co-Hexafluoropropylene)-Ionic
Liquid Mixtures as Amperometric Gas Sensing Materials for Oxygen and Ammonia.”
The Analyst 145, no. 5 (2020): 1915–24. https://doi.org/10.1039/c9an02153a.'
ieee: 'J. Lee, G. Hussain, N. Lopez Salas, D. R. MacFarlane, and D. S. Silvester,
“Thin films of poly(vinylidene fluoride-co-hexafluoropropylene)-ionic liquid
mixtures as amperometric gas sensing materials for oxygen and ammonia,” The
Analyst, vol. 145, no. 5, pp. 1915–1924, 2020, doi: 10.1039/c9an02153a.'
mla: Lee, Junqiao, et al. “Thin Films of Poly(Vinylidene Fluoride-Co-Hexafluoropropylene)-Ionic
Liquid Mixtures as Amperometric Gas Sensing Materials for Oxygen and Ammonia.”
The Analyst, vol. 145, no. 5, Royal Society of Chemistry (RSC), 2020, pp.
1915–24, doi:10.1039/c9an02153a.
short: J. Lee, G. Hussain, N. Lopez Salas, D.R. MacFarlane, D.S. Silvester, The
Analyst 145 (2020) 1915–1924.
date_created: 2023-01-27T16:21:25Z
date_updated: 2023-01-27T16:29:21Z
doi: 10.1039/c9an02153a
intvolume: ' 145'
issue: '5'
keyword:
- Electrochemistry
- Spectroscopy
- Environmental Chemistry
- Biochemistry
- Analytical Chemistry
language:
- iso: eng
page: 1915-1924
publication: The Analyst
publication_identifier:
issn:
- 0003-2654
- 1364-5528
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Thin films of poly(vinylidene fluoride-co-hexafluoropropylene)-ionic
liquid mixtures as amperometric gas sensing materials for oxygen and ammonia
type: journal_article
user_id: '98120'
volume: 145
year: '2020'
...
---
_id: '41822'
author:
- first_name: Nico
full_name: Carl, Nico
last_name: Carl
- first_name: Wenke
full_name: Müller, Wenke
last_name: Müller
- first_name: Ralf
full_name: Schweins, Ralf
last_name: Schweins
- first_name: Klaus
full_name: Huber, Klaus
id: '237'
last_name: Huber
citation:
ama: Carl N, Müller W, Schweins R, Huber K. Controlling Self-Assembly with Light
and Temperature. Langmuir. 2019;36(1):223-231. doi:10.1021/acs.langmuir.9b03040
apa: Carl, N., Müller, W., Schweins, R., & Huber, K. (2019). Controlling Self-Assembly
with Light and Temperature. Langmuir, 36(1), 223–231. https://doi.org/10.1021/acs.langmuir.9b03040
bibtex: '@article{Carl_Müller_Schweins_Huber_2019, title={Controlling Self-Assembly
with Light and Temperature}, volume={36}, DOI={10.1021/acs.langmuir.9b03040},
number={1}, journal={Langmuir}, publisher={American Chemical Society (ACS)}, author={Carl,
Nico and Müller, Wenke and Schweins, Ralf and Huber, Klaus}, year={2019}, pages={223–231}
}'
chicago: 'Carl, Nico, Wenke Müller, Ralf Schweins, and Klaus Huber. “Controlling
Self-Assembly with Light and Temperature.” Langmuir 36, no. 1 (2019): 223–31.
https://doi.org/10.1021/acs.langmuir.9b03040.'
ieee: 'N. Carl, W. Müller, R. Schweins, and K. Huber, “Controlling Self-Assembly
with Light and Temperature,” Langmuir, vol. 36, no. 1, pp. 223–231, 2019,
doi: 10.1021/acs.langmuir.9b03040.'
mla: Carl, Nico, et al. “Controlling Self-Assembly with Light and Temperature.”
Langmuir, vol. 36, no. 1, American Chemical Society (ACS), 2019, pp. 223–31,
doi:10.1021/acs.langmuir.9b03040.
short: N. Carl, W. Müller, R. Schweins, K. Huber, Langmuir 36 (2019) 223–231.
date_created: 2023-02-06T12:15:47Z
date_updated: 2023-02-06T12:23:04Z
department:
- _id: '314'
doi: 10.1021/acs.langmuir.9b03040
intvolume: ' 36'
issue: '1'
keyword:
- Electrochemistry
- Spectroscopy
- Surfaces and Interfaces
- Condensed Matter Physics
- General Materials Science
language:
- iso: eng
page: 223-231
publication: Langmuir
publication_identifier:
issn:
- 0743-7463
- 1520-5827
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Controlling Self-Assembly with Light and Temperature
type: journal_article
user_id: '237'
volume: 36
year: '2019'
...
---
_id: '41828'
author:
- first_name: Benjamin
full_name: Hämisch, Benjamin
last_name: Hämisch
- first_name: Anne
full_name: Büngeler, Anne
last_name: Büngeler
- first_name: Charlotte
full_name: Kielar, Charlotte
last_name: Kielar
- first_name: Adrian
full_name: Keller, Adrian
last_name: Keller
- first_name: Oliver
full_name: Strube, Oliver
last_name: Strube
- first_name: Klaus
full_name: Huber, Klaus
id: '237'
last_name: Huber
citation:
ama: Hämisch B, Büngeler A, Kielar C, Keller A, Strube O, Huber K. Self-Assembly
of Fibrinogen in Aqueous, Thrombin-Free Solutions of Variable Ionic Strengths.
Langmuir. 2019;35(37):12113-12122. doi:10.1021/acs.langmuir.9b01515
apa: Hämisch, B., Büngeler, A., Kielar, C., Keller, A., Strube, O., & Huber,
K. (2019). Self-Assembly of Fibrinogen in Aqueous, Thrombin-Free Solutions of
Variable Ionic Strengths. Langmuir, 35(37), 12113–12122. https://doi.org/10.1021/acs.langmuir.9b01515
bibtex: '@article{Hämisch_Büngeler_Kielar_Keller_Strube_Huber_2019, title={Self-Assembly
of Fibrinogen in Aqueous, Thrombin-Free Solutions of Variable Ionic Strengths},
volume={35}, DOI={10.1021/acs.langmuir.9b01515},
number={37}, journal={Langmuir}, publisher={American Chemical Society (ACS)},
author={Hämisch, Benjamin and Büngeler, Anne and Kielar, Charlotte and Keller,
Adrian and Strube, Oliver and Huber, Klaus}, year={2019}, pages={12113–12122}
}'
chicago: 'Hämisch, Benjamin, Anne Büngeler, Charlotte Kielar, Adrian Keller, Oliver
Strube, and Klaus Huber. “Self-Assembly of Fibrinogen in Aqueous, Thrombin-Free
Solutions of Variable Ionic Strengths.” Langmuir 35, no. 37 (2019): 12113–22.
https://doi.org/10.1021/acs.langmuir.9b01515.'
ieee: 'B. Hämisch, A. Büngeler, C. Kielar, A. Keller, O. Strube, and K. Huber, “Self-Assembly
of Fibrinogen in Aqueous, Thrombin-Free Solutions of Variable Ionic Strengths,”
Langmuir, vol. 35, no. 37, pp. 12113–12122, 2019, doi: 10.1021/acs.langmuir.9b01515.'
mla: Hämisch, Benjamin, et al. “Self-Assembly of Fibrinogen in Aqueous, Thrombin-Free
Solutions of Variable Ionic Strengths.” Langmuir, vol. 35, no. 37, American
Chemical Society (ACS), 2019, pp. 12113–22, doi:10.1021/acs.langmuir.9b01515.
short: B. Hämisch, A. Büngeler, C. Kielar, A. Keller, O. Strube, K. Huber, Langmuir
35 (2019) 12113–12122.
date_created: 2023-02-06T12:30:54Z
date_updated: 2023-02-06T12:39:16Z
department:
- _id: '314'
doi: 10.1021/acs.langmuir.9b01515
intvolume: ' 35'
issue: '37'
keyword:
- Electrochemistry
- Spectroscopy
- Surfaces and Interfaces
- Condensed Matter Physics
- General Materials Science
language:
- iso: eng
page: 12113-12122
publication: Langmuir
publication_identifier:
issn:
- 0743-7463
- 1520-5827
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Self-Assembly of Fibrinogen in Aqueous, Thrombin-Free Solutions of Variable
Ionic Strengths
type: journal_article
user_id: '237'
volume: 35
year: '2019'
...
---
_id: '63969'
abstract:
- lang: eng
text: A number of Ir-N-heterocyclic carbene (Ir-NHC) complexes with asymmetric N-heterocyclic
carbene (NHC) ligands have been prepared and examined for signal amplification
by reversible exchange (SABRE). Pyridine was chosen as model compound for hyperpolarization
experiments. This substrate was examined in a solvent mixture using several Ir-NHC
complexes, which differ in their NHC ligands. The SABRE polarization was created
at 6mT and the H-1 nuclear magnetic resonancesignals were detected at 7T. We show
that asymmetric NHC ligands, because of their favorable chemistry, can adapt the
SABREactive complexes to different chemical scenarios.
author:
- first_name: S.
full_name: Hadjiali, S.
last_name: Hadjiali
- first_name: R.
full_name: Savka, R.
last_name: Savka
- first_name: M.
full_name: Plaumann, M.
last_name: Plaumann
- first_name: U.
full_name: Bommerich, U.
last_name: Bommerich
- first_name: S.
full_name: Bothe, S.
last_name: Bothe
- first_name: Torsten
full_name: Gutmann, Torsten
id: '118165'
last_name: Gutmann
- first_name: T.
full_name: Ratajczyk, T.
last_name: Ratajczyk
- first_name: J.
full_name: Bernarding, J.
last_name: Bernarding
- first_name: H. H.
full_name: Limbach, H. H.
last_name: Limbach
- first_name: H.
full_name: Plenio, H.
last_name: Plenio
- first_name: G.
full_name: Buntkowsky, G.
last_name: Buntkowsky
citation:
ama: Hadjiali S, Savka R, Plaumann M, et al. Substituent Influences on the NMR Signal
Amplification of Ir Complexes with Heterocyclic Carbene Ligands. Applied Magnetic
Resonance. 2019;50(7):895–902. doi:10.1007/s00723-019-01115-x
apa: Hadjiali, S., Savka, R., Plaumann, M., Bommerich, U., Bothe, S., Gutmann, T.,
Ratajczyk, T., Bernarding, J., Limbach, H. H., Plenio, H., & Buntkowsky, G.
(2019). Substituent Influences on the NMR Signal Amplification of Ir Complexes
with Heterocyclic Carbene Ligands. Applied Magnetic Resonance, 50(7),
895–902. https://doi.org/10.1007/s00723-019-01115-x
bibtex: '@article{Hadjiali_Savka_Plaumann_Bommerich_Bothe_Gutmann_Ratajczyk_Bernarding_Limbach_Plenio_et
al._2019, title={Substituent Influences on the NMR Signal Amplification of Ir
Complexes with Heterocyclic Carbene Ligands}, volume={50}, DOI={10.1007/s00723-019-01115-x},
number={7}, journal={Applied Magnetic Resonance}, author={Hadjiali, S. and Savka,
R. and Plaumann, M. and Bommerich, U. and Bothe, S. and Gutmann, Torsten and Ratajczyk,
T. and Bernarding, J. and Limbach, H. H. and Plenio, H. and et al.}, year={2019},
pages={895–902} }'
chicago: 'Hadjiali, S., R. Savka, M. Plaumann, U. Bommerich, S. Bothe, Torsten Gutmann,
T. Ratajczyk, et al. “Substituent Influences on the NMR Signal Amplification of
Ir Complexes with Heterocyclic Carbene Ligands.” Applied Magnetic Resonance
50, no. 7 (2019): 895–902. https://doi.org/10.1007/s00723-019-01115-x.'
ieee: 'S. Hadjiali et al., “Substituent Influences on the NMR Signal Amplification
of Ir Complexes with Heterocyclic Carbene Ligands,” Applied Magnetic Resonance,
vol. 50, no. 7, pp. 895–902, 2019, doi: 10.1007/s00723-019-01115-x.'
mla: Hadjiali, S., et al. “Substituent Influences on the NMR Signal Amplification
of Ir Complexes with Heterocyclic Carbene Ligands.” Applied Magnetic Resonance,
vol. 50, no. 7, 2019, pp. 895–902, doi:10.1007/s00723-019-01115-x.
short: S. Hadjiali, R. Savka, M. Plaumann, U. Bommerich, S. Bothe, T. Gutmann, T.
Ratajczyk, J. Bernarding, H.H. Limbach, H. Plenio, G. Buntkowsky, Applied Magnetic
Resonance 50 (2019) 895–902.
date_created: 2026-02-07T15:40:18Z
date_updated: 2026-02-17T16:17:34Z
doi: 10.1007/s00723-019-01115-x
extern: '1'
intvolume: ' 50'
issue: '7'
keyword:
- dynamic nuclear-polarization
- hyperpolarization
- enhancement
- hydrogen induced polarization
- olefin-metathesis catalysts
- parahydrogen-induced polarization
- peptides
- Physics
- sabre
- spectroscopy
language:
- iso: eng
page: 895–902
publication: Applied Magnetic Resonance
publication_identifier:
issn:
- 1613-7507
status: public
title: Substituent Influences on the NMR Signal Amplification of Ir Complexes with
Heterocyclic Carbene Ligands
type: journal_article
user_id: '100715'
volume: 50
year: '2019'
...