[{"abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub> is reported and applied in reactions with arenes, allylic, vinylic and acetylenic silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>","lang":"eng"}],"publication":"Advanced Synthesis &amp; Catalysis","issue":"13","keyword":["fluoride","bond activation","borane","Lewis acid","C-C bond formation"],"type":"journal_article","department":[{"_id":"389"}],"date_created":"2025-04-22T05:59:08Z","publication_status":"published","date_updated":"2025-04-22T06:11:59Z","intvolume":"       366","title":"Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds","year":"2024","author":[{"id":"62844","full_name":"Hoppe, Axel","last_name":"Hoppe","first_name":"Axel"},{"full_name":"Stepen, Arne J.","last_name":"Stepen","first_name":"Arne J."},{"full_name":"Köring, Laura","first_name":"Laura","last_name":"Köring"},{"id":"53339","full_name":"Paradies, Jan","last_name":"Paradies","first_name":"Jan","orcid":"0000-0002-3698-668X"}],"publication_identifier":{"issn":["1615-4150","1615-4169"]},"doi":"10.1002/adsc.202400511","main_file_link":[{"url":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202400511","open_access":"1"}],"language":[{"iso":"eng"}],"quality_controlled":"1","citation":{"short":"A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp; Catalysis 366 (2024) 2933–2938.","chicago":"Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i> 366, no. 13 (2024): 2933–38. <a href=\"https://doi.org/10.1002/adsc.202400511\">https://doi.org/10.1002/adsc.202400511</a>.","ieee":"A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>.","apa":"Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>, <i>366</i>(13), 2933–2938. <a href=\"https://doi.org/10.1002/adsc.202400511\">https://doi.org/10.1002/adsc.202400511</a>","bibtex":"@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>}, number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley}, author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan}, year={2024}, pages={2933–2938} }","ama":"Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>. 2024;366(13):2933-2938. doi:<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>","mla":"Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366, no. 13, Wiley, 2024, pp. 2933–38, doi:<a href=\"https://doi.org/10.1002/adsc.202400511\">10.1002/adsc.202400511</a>."},"oa":"1","status":"public","user_id":"62844","volume":366,"page":"2933-2938","publisher":"Wiley","_id":"59616"}]