@article{40601, abstract = {{Abstract Background and aims One reason for the controversial discussion of whether the dual task (DT) walking paradigm has an added value for diagnosis in clinical conditions might be the use of different gait measurement systems. Therefore, the purpose was 1) to detect DT effects of central gait parameters obtained from five different gait analysis devices in young and old adults, 2) to assess the consistency of the measurement systems, and 3) to determine if the absolut and proportional DT costs (DTC) are greater than the system-measurement error under ST. Methods Twelve old (72.2 ± 7.9y) and 14 young adults (28.3 ± 6.2y) walked a 14.7-m distance under ST and DT at a self-selected gait velocity. Interrater reliability, precision of the measurement and sensitivity to change were calculated under ST and DT. Results An age effect was observed in almost all gait parameters for the ST condition. For DT only differences for stride length (p < .029, ɳ2p = .239) as well as single and double limb support (p = .036, ɳ2p = .227; p = .034, ɳ2p = .218) remained. The measurement systems showed a lower absolute agreement compared to consistency across all systems. Conclusions When reporting DT effects, the real changes in performance and random measurement errors should always be accounted for. These findings have strong implications for interpreting DT effects. }}, author = {{Klotzbier, Thomas Jürgen and Wollesen, Bettina and Vogel, Oliver and Rudisch, Julian and Cordes, Thomas and Jöllenbeck, Thomas and Vogt, Lutz}}, issn = {{1813-7253}}, journal = {{European Review of Aging and Physical Activity}}, keywords = {{Geriatrics and Gerontology}}, number = {{1}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{An interrater reliability study of gait analysis systems with the dual task paradigm in healthy young and older adults}}}, doi = {{10.1186/s11556-021-00271-z}}, volume = {{18}}, year = {{2021}}, } @article{40598, author = {{Rudisch, Julian and Jöllenbeck, Thomas and Vogt, Lutz and Cordes, Thomas and Klotzbier, Thomas Jürgen and Vogel, Oliver and Wollesen, Bettina}}, issn = {{0966-6362}}, journal = {{Gait & Posture}}, keywords = {{Rehabilitation, Orthopedics and Sports Medicine, Biophysics}}, pages = {{55--64}}, publisher = {{Elsevier BV}}, title = {{{Agreement and consistency of five different clinical gait analysis systems in the assessment of spatiotemporal gait parameters}}}, doi = {{10.1016/j.gaitpost.2021.01.013}}, volume = {{85}}, year = {{2021}}, } @article{37936, author = {{Pelucchi, Emanuele and Fagas, Giorgos and Aharonovich, Igor and Englund, Dirk and Figueroa, Eden and Gong, Qihuang and Hannes, Hübel and Liu, Jin and Lu, Chao-Yang and Matsuda, Nobuyuki and Pan, Jian-Wei and Schreck, Florian and Sciarrino, Fabio and Silberhorn, Christine and Wang, Jianwei and Jöns, Klaus}}, issn = {{2522-5820}}, journal = {{Nature Reviews Physics}}, keywords = {{General Physics and Astronomy}}, number = {{3}}, pages = {{194--208}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{The potential and global outlook of integrated photonics for quantum technologies}}}, doi = {{10.1038/s42254-021-00398-z}}, volume = {{4}}, year = {{2021}}, } @article{41002, abstract = {{Homogeneous catalysts immobilized on metal oxides often have different catalytic properties than in homogeneous solution. This can be either activating or deactivating and is often attributed to interactions of catalyst species with the metal oxide surface. However, few studies have ever demonstrated the effect that close associations of active sites with surfaces have on the catalytic activity. In this paper, we immobilize H2Ru(PPh3)2(Ph2P)2N–C3H6–Si(OEt)3 (3) on SiO2, Al2O3, and ZnO and interrogate the relationship to the surface using IR, MAS NMR, 1H–31P HETCOR, and XAS spectroscopies. We found that while there are close contacts between the P atoms of the complex and all three metal oxide surfaces, the Ru–H bond only reacts with oxygen bridges on SiO2 and Al2O3, forming new Ru–O bonds. In contrast, complex 3 stays intact on ZnO. Comparison of the catalytic activities of our immobilized species for CO2 hydrogenation to ethyl formate showed that Lewis acidic metal oxides activate, rather than deactivate, complex 3 in the order Al2O3 > ZnO > SiO2. The Lewis acidic sites on the metal oxide surfaces most likely increase the productivity by increasing the rate of esterification of formate intermediates.}}, author = {{Nguyen, Hoang-Huy and Li, Zheng and Enenkel, Toni and Hildebrand, Joachim and Bauer, Matthias and Dyballa, Michael and Estes, Deven P.}}, issn = {{1932-7447}}, journal = {{The Journal of Physical Chemistry C}}, keywords = {{Surfaces, Coatings and Films, Physical and Theoretical Chemistry, General Energy, Electronic, Optical and Magnetic Materials}}, number = {{27}}, pages = {{14627--14635}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation}}}, doi = {{10.1021/acs.jpcc.1c02074}}, volume = {{125}}, year = {{2021}}, } @article{41003, abstract = {{Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap}}, author = {{Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}}, issn = {{1359-7345}}, journal = {{Chemical Communications}}, keywords = {{Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis}}, number = {{61}}, pages = {{7541--7544}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Higher MLCT lifetime of carbene iron(ii) complexes by chelate ring expansion}}}, doi = {{10.1039/d1cc02173g}}, volume = {{57}}, year = {{2021}}, } @article{41012, abstract = {{Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+ [10/+; dppf = 1,1′-bis(diphenylphosphino)ferrocene] in two oxidation states by an advanced multitechnique experimental approach. A combination of magnetic circular dichroism, X-ray absorption and emission, high-frequency electron paramagnetic resonance (EPR), and Mössbauer spectroscopies is used to establish that oxidation of 10 occurs on the carbonyl iron ion, resulting in a low-spin iron(I) ion. It is shown that an unequivocal result is obtained by combining several methods. Compound 1+ displays slow spin dynamics, which is used here to study its geometric structure by means of pulsed EPR methods. Surprisingly, these data show an association of the tetrakis[3,5-bis(trifluoromethylphenyl)]borate counterion with 1+.}}, author = {{Winkler, Mario and Schnierle, Marc and Ehrlich, Felix and Mehnert, Kim-Isabelle and Hunger, David and Sheveleva, Alena M. and Burkhardt, Lukas and Bauer, Matthias and Tuna, Floriana and Ringenberg, Mark R. and van Slageren, Joris}}, issn = {{0020-1669}}, journal = {{Inorganic Chemistry}}, keywords = {{Inorganic Chemistry, Physical and Theoretical Chemistry}}, number = {{5}}, pages = {{2856--2865}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) 3]+/0}}}, doi = {{10.1021/acs.inorgchem.0c03259}}, volume = {{60}}, year = {{2021}}, } @book{40920, editor = {{Standke, Jan and Topalovic, Elvira}}, issn = {{0418-9426}}, keywords = {{General Earth and Planetary Sciences, General Environmental Science}}, publisher = {{Vandenhoeck & Ruprecht GmbH & Co, KG, Göttingen}}, title = {{{In Krisen erzählen – von Krisen erzählen. Sprachliche, literarische und mediale Dimensionen.}}}, doi = {{10.14220/mdge.2021.68.2.0}}, volume = {{68}}, year = {{2021}}, } @book{37092, editor = {{Plien, Christian and Topalovic, Elvira}}, issn = {{0418-9426}}, keywords = {{General Earth and Planetary Sciences, General Environmental Science}}, publisher = {{Vandenhoeck & Ruprecht GmbH & Co, KG, Göttingen}}, title = {{{Mehrdeutigkeiten}}}, doi = {{10.14220/mdge.2021.68.4.0}}, volume = {{68}}, year = {{2021}}, } @article{41326, author = {{Wojtaszek, Klaudia and Błachucki, Wojciech and Tyrała, Krzysztof and Nowakowski, Michał and Zaja̧c, Marcin and Stȩpień, Joanna and Jagodziński, Paweł and Banaś, Dariusz and Stańczyk, Wiktoria and Czapla-Masztafiak, Joanna and Kwiatek, Wojciech M. and Szlachetko, Jakub and Wach, Anna}}, issn = {{1089-5639}}, journal = {{The Journal of Physical Chemistry A}}, keywords = {{Physical and Theoretical Chemistry}}, number = {{1}}, pages = {{50--56}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Determination of Crystal-Field Splitting Induced by Thermal Oxidation of Titanium}}}, doi = {{10.1021/acs.jpca.0c07955}}, volume = {{125}}, year = {{2021}}, } @article{35326, abstract = {{Thermostable compartmentalized sodium-water sites through intercalated γ-aminopropyl-dimethyl-ethoxy silane in synthetic hectorite.}}, author = {{Keil, Waldemar and Zhao, Kai and Oswald, Arthur and Bremser, Wolfgang and Schmidt, Claudia and Hintze-Bruening, Horst}}, issn = {{1463-9076}}, journal = {{Physical Chemistry Chemical Physics}}, keywords = {{Physical and Theoretical Chemistry, General Physics and Astronomy}}, number = {{1}}, pages = {{477--487}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Thermostable water reservoirs in the interlayer space of a sodium hectorite clay through the intercalation of γ-aminopropyl(dimethyl)ethoxysilane in toluene}}}, doi = {{10.1039/d1cp03321b}}, volume = {{24}}, year = {{2021}}, } @article{41818, author = {{Hense, Dominik and Büngeler, Anne and Kollmann, Fabian and Hanke, Marcel and Orive, Alejandro and Keller, Adrian and Grundmeier, Guido and Huber, Klaus and Strube, Oliver I.}}, issn = {{1525-7797}}, journal = {{Biomacromolecules}}, keywords = {{Materials Chemistry, Polymers and Plastics, Biomaterials, Bioengineering}}, number = {{10}}, pages = {{4084--4094}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Self-Assembled Fibrinogen Hydro- and Aerogels with Fibrin-like 3D Structures}}}, doi = {{10.1021/acs.biomac.1c00489}}, volume = {{22}}, year = {{2021}}, } @article{41816, author = {{Wagner, Maximilian and Krieger, Anja and Minameyer, Martin and Hämisch, Benjamin and Huber, Klaus and Drewello, Thomas and Gröhn, Franziska}}, issn = {{0024-9297}}, journal = {{Macromolecules}}, keywords = {{Materials Chemistry, Inorganic Chemistry, Polymers and Plastics, Organic Chemistry}}, number = {{6}}, pages = {{2899--2911}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Multiresponsive Polymer Nanoparticles Based on Disulfide Bonds}}}, doi = {{10.1021/acs.macromol.1c00299}}, volume = {{54}}, year = {{2021}}, } @article{41815, author = {{Hämisch, Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}}, issn = {{2570-4206}}, journal = {{ChemSystemsChem}}, keywords = {{General Earth and Planetary Sciences, General Environmental Science}}, number = {{3}}, publisher = {{Wiley}}, title = {{{Thermodynamic Analysis of the Self‐Assembly of Pseudo Isocyanine Chloride in the Presence of Crowding Agents}}}, doi = {{10.1002/syst.202000051}}, volume = {{3}}, year = {{2021}}, } @article{29780, abstract = {{A central tenet of theoretical cryptography is the study of the minimal assumptions required to implement a given cryptographic primitive. One such primitive is the one-time memory (OTM), introduced by Goldwasser, Kalai, and Rothblum [CRYPTO 2008], which is a classical functionality modeled after a non-interactive 1-out-of-2 oblivious transfer, and which is complete for one-time classical and quantum programs. It is known that secure OTMs do not exist in the standard model in both the classical and quantum settings. Here, we propose a scheme for using quantum information, together with the assumption of stateless (i.e., reusable) hardware tokens, to build statistically secure OTMs. Via the semidefinite programming-based quantum games framework of Gutoski and Watrous [STOC 2007], we prove security for a malicious receiver making at most 0.114n adaptive queries to the token (for n the key size), in the quantum universal composability framework, but leave open the question of security against a polynomial amount of queries. Compared to alternative schemes derived from the literature on quantum money, our scheme is technologically simple since it is of the "prepare-and-measure" type. We also give two impossibility results showing certain assumptions in our scheme cannot be relaxed.}}, author = {{Broadbent, Anne and Gharibian, Sevag and Zhou, Hong-Sheng}}, issn = {{2521-327X}}, journal = {{Quantum}}, keywords = {{Physics and Astronomy (miscellaneous), Atomic and Molecular Physics, and Optics}}, publisher = {{Verein zur Forderung des Open Access Publizierens in den Quantenwissenschaften}}, title = {{{Towards Quantum One-Time Memories from Stateless Hardware}}}, doi = {{10.22331/q-2021-04-08-429}}, volume = {{5}}, year = {{2021}}, } @article{34840, abstract = {{In this paper we obtain a complete list of imaginary n-quadratic fields with class groups of exponent 3 and 5 under ERH for every positive integer n where an n-quadratic field is a number field of degree 2ⁿ represented as the composite of n quadratic fields. }}, author = {{Klüners, Jürgen and Komatsu, Toru}}, issn = {{0025-5718}}, journal = {{Mathematics of Computation}}, keywords = {{Applied Mathematics, Computational Mathematics, Algebra and Number Theory}}, number = {{329}}, pages = {{1483--1497}}, publisher = {{American Mathematical Society (AMS)}}, title = {{{Imaginary multiquadratic number fields with class group of exponent $3$ and $5$}}}, doi = {{10.1090/mcom/3609}}, volume = {{90}}, year = {{2021}}, } @article{43159, author = {{Damm, Jannis and Albiez, Matthias and Göddecke, Johannes and Meschut, Gerson and Ummenhofer, Thomas}}, issn = {{1619-1919}}, journal = {{adhäsion KLEBEN & DICHTEN}}, keywords = {{Polymers and Plastics, General Chemical Engineering, General Chemistry}}, number = {{9}}, pages = {{14--23}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Dämpfungseigenschaften geklebter Verbindungen - Potenzialanalyse und Klebstoffcharakterisierung}}}, doi = {{10.1007/s35145-021-0520-8}}, volume = {{65}}, year = {{2021}}, } @article{29748, author = {{Slawig, Diana and Gruschwitz, Markus and Gerstmann, Uwe and Rauls, Eva and Tegenkamp, Christoph}}, issn = {{1932-7447}}, journal = {{The Journal of Physical Chemistry C}}, keywords = {{Surfaces, Coatings and Films, Physical and Theoretical Chemistry, General Energy, Electronic, Optical and Magnetic Materials}}, number = {{36}}, pages = {{20087--20093}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Adsorption and Reaction of PbPc on Hydrogenated Epitaxial Graphene}}}, doi = {{10.1021/acs.jpcc.1c06320}}, volume = {{125}}, year = {{2021}}, } @article{37338, abstract = {{AbstractMethylammonium lead iodide perovskite (MAPbI3) is renowned for an impressive power conversion efficiency rise and cost-effective fabrication for photovoltaics. In this work, we demonstrate that polycrystalline MAPbI3s undergo drastic changes in optical properties at moderate field strengths with an ultrafast response time, via transient Wannier Stark localization. The distinct band structure of this material - the large lattice periodicity, the narrow electronic energy bandwidths, and the coincidence of these two along the same high-symmetry direction – enables relatively weak fields to bring this material into the Wannier Stark regime. Its polycrystalline nature is not detrimental to the optical switching performance of the material, since the least dispersive direction of the band structure dominates the contribution to the optical response, which favors low-cost fabrication. Together with the outstanding photophysical properties of MAPbI3, this finding highlights the great potential of this material in ultrafast light modulation and novel photonic applications.}}, author = {{Berghoff, Daniel and Bühler, Johannes and Bonn, Mischa and Leitenstorfer, Alfred and Meier, Torsten and Kim, Heejae}}, issn = {{2041-1723}}, journal = {{Nature Communications}}, keywords = {{General Physics and Astronomy, General Biochemistry, Genetics and Molecular Biology, General Chemistry, Multidisciplinary}}, number = {{1}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Low-field onset of Wannier-Stark localization in a polycrystalline hybrid organic inorganic perovskite}}}, doi = {{10.1038/s41467-021-26021-4}}, volume = {{12}}, year = {{2021}}, } @article{30674, abstract = {{AbstractIn addition to the classical strength calculation, it is important to design components with regard to fracture mechanics because defects and cracks in a component can drastically influence its strength or fatigue behavior. Cracks can propagate due to operational loads and consequently lead to component failure. The fracture mechanical analysis provides information on stable or unstable crack growth as well as about the direction and the growth rate of a crack. For this purpose, sufficient information has to be available about the crack location, the crack length, the component geometry, the component loading and the fracture mechanical material parameters. The fracture mechanical properties are determined experimentally with standardized specimens as defined by the guidelines of the American Society for Testing and Materials. In practice, however, especially in the context with damage cases or formed material fracture mechanical parameters directly for a component are of interest. However, standard specimens often cannot be extracted at all due to the complexity of the component geometry. Therefore, the development of special specimens is required whereby certain arrangements have to be made in advance. These arrangements are presented in the present paper in order to contribute to a holistic investigation chain for the experimental determination of fracture mechanical material parameters with special specimens.}}, author = {{Weiß, Deborah and Schramm, Britta and Kullmer, Gunter}}, issn = {{0944-6524}}, journal = {{Production Engineering}}, keywords = {{Industrial and Manufacturing Engineering, Mechanical Engineering}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Holistic investigation chain for the experimental determination of fracture mechanical material parameters with special specimens}}}, doi = {{10.1007/s11740-021-01096-6}}, year = {{2021}}, } @article{34024, abstract = {{Abstract Objective External focus (EF) of attention leads to improved balance performance. Consideration of the neuromodulatory effects of EF may inform its clinical utility in addressing neuroplastic impairments after musculoskeletal injuries. We aimed to determine whether electrocortical activity and balance performance changed with attentional foci that prioritized differing sensory feedback and whether changes in electrocortical activity and balance were associated. Methods Individuals who were healthy (n = 15) performed a single-limb balance task under 3 conditions: internal focus (IF), somatosensory focus [EF with a baton (EF-baton)], and visual focus [EF with a laser (EF-laser)]. Electrocortical activity and postural sway were recorded concurrently using electroencephalography and a triaxial force plate. Electroencephalographic signals were decomposed, localized, and clustered to generate power spectral density in θ and α-2 frequency bands. Postural sway signals were analyzed with center-of-pressure sway metrics (eg, area, distance, velocity) and knee angle. The relationship between percent change in clustered brain activity and task performance metrics was assessed. Results Both EF conditions resulted in increased cortical activity and improved balance performance compared to IF. EF-laser had the largest effect, demonstrating increased frontal θ power (d = 0.64), decreased central θ power (d = −0.30), and decreased bilateral motor, bilateral parietal, and occipital α-2 power (d = −1.38 to −4.27) as well as a shorter path distance (d = −0.94) and a deeper (d = 0.70) and less variable (d = −1.15) knee angle than IF. Weak to moderate associations exist between increases in cortical activity and improved balance performance (ρ = 0.405–0.584). Conclusions EF resulted in increased cortical activity associated with cognitive, motor, somatosensory, and visual processing. EF-laser, which prioritized visual feedback, had the largest and broadest effects. Changes in cortical activity resulting from EF were independently associated with improved balance performance. Impact This study demonstrates that goal-oriented attention results in functional increases in brain activity compared to internally directed self-focus. These results suggest EF may target neurophysiologic impairments and improve balance in clinical populations. }}, author = {{Sherman, David A and Lehmann, Tim and Baumeister, Jochen and Gokeler, Alli and Donovan, Luke and Norte, Grant E}}, issn = {{0031-9023}}, journal = {{Physical Therapy}}, keywords = {{Physical Therapy, Sports Therapy and Rehabilitation}}, publisher = {{Oxford University Press (OUP)}}, title = {{{External Focus of Attention Influences Cortical Activity Associated with Single Limb Balance Performance}}}, doi = {{10.1093/ptj/pzab223}}, year = {{2021}}, }