---
_id: '33681'
article_number: '120965'
author:
- first_name: Marcos A.R.
full_name: da Silva, Marcos A.R.
last_name: da Silva
- first_name: Ingrid F.
full_name: Silva, Ingrid F.
last_name: Silva
- first_name: Qi
full_name: Xue, Qi
last_name: Xue
- first_name: Benedict T.W.
full_name: Lo, Benedict T.W.
last_name: Lo
- first_name: Nadezda V.
full_name: Tarakina, Nadezda V.
last_name: Tarakina
- first_name: Barbara N.
full_name: Nunes, Barbara N.
last_name: Nunes
- first_name: Peter
full_name: Adler, Peter
last_name: Adler
- first_name: Sudhir K.
full_name: Sahoo, Sudhir K.
last_name: Sahoo
- first_name: Detlef W.
full_name: Bahnemann, Detlef W.
last_name: Bahnemann
- first_name: Nieves
full_name: López-Salas, Nieves
last_name: López-Salas
- first_name: Aleksandr
full_name: Savateev, Aleksandr
last_name: Savateev
- first_name: Caue
full_name: Ribeiro, Caue
last_name: Ribeiro
- first_name: Thomas
full_name: Kühne, Thomas
id: '49079'
last_name: Kühne
- first_name: Markus
full_name: Antonietti, Markus
last_name: Antonietti
- first_name: Ivo F.
full_name: Teixeira, Ivo F.
last_name: Teixeira
citation:
ama: 'da Silva MAR, Silva IF, Xue Q, et al. Sustainable oxidation catalysis supported
by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst.
Applied Catalysis B: Environmental. 2021;304. doi:10.1016/j.apcatb.2021.120965'
apa: 'da Silva, M. A. R., Silva, I. F., Xue, Q., Lo, B. T. W., Tarakina, N. V.,
Nunes, B. N., Adler, P., Sahoo, S. K., Bahnemann, D. W., López-Salas, N., Savateev,
A., Ribeiro, C., Kühne, T., Antonietti, M., & Teixeira, I. F. (2021). Sustainable
oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous
single-atom photocatalyst. Applied Catalysis B: Environmental, 304,
Article 120965. https://doi.org/10.1016/j.apcatb.2021.120965'
bibtex: '@article{da Silva_Silva_Xue_Lo_Tarakina_Nunes_Adler_Sahoo_Bahnemann_López-Salas_et
al._2021, title={Sustainable oxidation catalysis supported by light: Fe-poly (heptazine
imide) as a heterogeneous single-atom photocatalyst}, volume={304}, DOI={10.1016/j.apcatb.2021.120965},
number={120965}, journal={Applied Catalysis B: Environmental}, publisher={Elsevier
BV}, author={da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict
T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo,
Sudhir K. and Bahnemann, Detlef W. and López-Salas, Nieves and et al.}, year={2021}
}'
chicago: 'Silva, Marcos A.R. da, Ingrid F. Silva, Qi Xue, Benedict T.W. Lo, Nadezda
V. Tarakina, Barbara N. Nunes, Peter Adler, et al. “Sustainable Oxidation Catalysis
Supported by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.”
Applied Catalysis B: Environmental 304 (2021). https://doi.org/10.1016/j.apcatb.2021.120965.'
ieee: 'M. A. R. da Silva et al., “Sustainable oxidation catalysis supported
by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst,”
Applied Catalysis B: Environmental, vol. 304, Art. no. 120965, 2021, doi:
10.1016/j.apcatb.2021.120965.'
mla: 'da Silva, Marcos A. R., et al. “Sustainable Oxidation Catalysis Supported
by Light: Fe-Poly (Heptazine Imide) as a Heterogeneous Single-Atom Photocatalyst.”
Applied Catalysis B: Environmental, vol. 304, 120965, Elsevier BV, 2021,
doi:10.1016/j.apcatb.2021.120965.'
short: 'M.A.R. da Silva, I.F. Silva, Q. Xue, B.T.W. Lo, N.V. Tarakina, B.N. Nunes,
P. Adler, S.K. Sahoo, D.W. Bahnemann, N. López-Salas, A. Savateev, C. Ribeiro,
T. Kühne, M. Antonietti, I.F. Teixeira, Applied Catalysis B: Environmental 304
(2021).'
date_created: 2022-10-11T08:14:22Z
date_updated: 2022-10-11T08:14:47Z
department:
- _id: '613'
doi: 10.1016/j.apcatb.2021.120965
intvolume: ' 304'
keyword:
- Process Chemistry and Technology
- General Environmental Science
- Catalysis
language:
- iso: eng
publication: 'Applied Catalysis B: Environmental'
publication_identifier:
issn:
- 0926-3373
publication_status: published
publisher: Elsevier BV
status: public
title: 'Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide)
as a heterogeneous single-atom photocatalyst'
type: journal_article
user_id: '71051'
volume: 304
year: '2021'
...
---
_id: '33675'
abstract:
- lang: eng
text: The influence of different polymer side chains on the vapor phase
infiltration with TMA is investigated and supported by DFT-calculations.
author:
- first_name: Lukas
full_name: Mai, Lukas
last_name: Mai
- first_name: Dina
full_name: Maniar, Dina
last_name: Maniar
- first_name: Frederik
full_name: Zysk, Frederik
id: '14757'
last_name: Zysk
- first_name: Judith
full_name: Schöbel, Judith
last_name: Schöbel
- first_name: Thomas
full_name: Kühne, Thomas
id: '49079'
last_name: Kühne
- first_name: Katja
full_name: Loos, Katja
last_name: Loos
- first_name: Anjana
full_name: Devi, Anjana
last_name: Devi
citation:
ama: Mai L, Maniar D, Zysk F, et al. Influence of different ester side groups in
polymers on the vapor phase infiltration with trimethyl aluminum. Dalton Transactions.
2021;51(4):1384-1394. doi:10.1039/d1dt03753f
apa: Mai, L., Maniar, D., Zysk, F., Schöbel, J., Kühne, T., Loos, K., & Devi,
A. (2021). Influence of different ester side groups in polymers on the vapor phase
infiltration with trimethyl aluminum. Dalton Transactions, 51(4),
1384–1394. https://doi.org/10.1039/d1dt03753f
bibtex: '@article{Mai_Maniar_Zysk_Schöbel_Kühne_Loos_Devi_2021, title={Influence
of different ester side groups in polymers on the vapor phase infiltration with
trimethyl aluminum}, volume={51}, DOI={10.1039/d1dt03753f},
number={4}, journal={Dalton Transactions}, publisher={Royal Society of Chemistry
(RSC)}, author={Mai, Lukas and Maniar, Dina and Zysk, Frederik and Schöbel, Judith
and Kühne, Thomas and Loos, Katja and Devi, Anjana}, year={2021}, pages={1384–1394}
}'
chicago: 'Mai, Lukas, Dina Maniar, Frederik Zysk, Judith Schöbel, Thomas Kühne,
Katja Loos, and Anjana Devi. “Influence of Different Ester Side Groups in Polymers
on the Vapor Phase Infiltration with Trimethyl Aluminum.” Dalton Transactions
51, no. 4 (2021): 1384–94. https://doi.org/10.1039/d1dt03753f.'
ieee: 'L. Mai et al., “Influence of different ester side groups in polymers
on the vapor phase infiltration with trimethyl aluminum,” Dalton Transactions,
vol. 51, no. 4, pp. 1384–1394, 2021, doi: 10.1039/d1dt03753f.'
mla: Mai, Lukas, et al. “Influence of Different Ester Side Groups in Polymers on
the Vapor Phase Infiltration with Trimethyl Aluminum.” Dalton Transactions,
vol. 51, no. 4, Royal Society of Chemistry (RSC), 2021, pp. 1384–94, doi:10.1039/d1dt03753f.
short: L. Mai, D. Maniar, F. Zysk, J. Schöbel, T. Kühne, K. Loos, A. Devi, Dalton
Transactions 51 (2021) 1384–1394.
date_created: 2022-10-11T08:08:11Z
date_updated: 2022-10-11T08:08:35Z
department:
- _id: '613'
doi: 10.1039/d1dt03753f
intvolume: ' 51'
issue: '4'
keyword:
- Inorganic Chemistry
language:
- iso: eng
page: 1384-1394
publication: Dalton Transactions
publication_identifier:
issn:
- 1477-9226
- 1477-9234
publication_status: published
publisher: Royal Society of Chemistry (RSC)
status: public
title: Influence of different ester side groups in polymers on the vapor phase infiltration
with trimethyl aluminum
type: journal_article
user_id: '71051'
volume: 51
year: '2021'
...
---
_id: '47963'
abstract:
- lang: eng
text: Nonlinear and quantum optical devices based on periodically-poled thin film
lithium niobate (PP-TFLN) have gained considerable interest lately, due to their
significantly improved performance as compared to their bulk counterparts. Nevertheless,
performance parameters such as conversion efficiency, minimum pump power, and
spectral bandwidth strongly depend on the quality of the domain structure in these
PP-TFLN samples, e.g., their homogeneity and duty cycle, as well as on the overlap
and penetration depth of domains with the waveguide mode. Hence, in order to propose
improved fabrication protocols, a profound quality control of domain structures
is needed that allows quantifying and thoroughly analyzing these parameters. In
this paper, we propose to combine a set of nanometer-to-micrometer-scale imaging
techniques, i.e., piezoresponse force microscopy (PFM), second-harmonic generation
(SHG), and Raman spectroscopy (RS), to access the relevant and crucial sample
properties through cross-correlating these methods. Based on our findings, we
designate SHG to be the best-suited standard imaging technique for this purpose,
in particular when investigating the domain poling process in x-cut TFLNs. While
PFM is excellently recommended for near-surface high-resolution imaging, RS provides
thorough insights into stress and/or defect distributions, as associated with
these domain structures. In this context, our work here indicates unexpectedly
large signs for internal fields occurring in x-cut PP-TFLNs that are substantially
larger as compared to previous observations in bulk LN.
article_number: '288'
article_type: original
author:
- first_name: Sven
full_name: Reitzig, Sven
last_name: Reitzig
- first_name: Michael
full_name: Rüsing, Michael
id: '22501'
last_name: Rüsing
orcid: 0000-0003-4682-4577
- first_name: Jie
full_name: Zhao, Jie
last_name: Zhao
- first_name: Benjamin
full_name: Kirbus, Benjamin
last_name: Kirbus
- first_name: Shayan
full_name: Mookherjea, Shayan
last_name: Mookherjea
- first_name: Lukas M.
full_name: Eng, Lukas M.
last_name: Eng
citation:
ama: Reitzig S, Rüsing M, Zhao J, Kirbus B, Mookherjea S, Eng LM. “Seeing Is Believing”—In-Depth
Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium Niobate Thin Films.
Crystals. 2021;11(3). doi:10.3390/cryst11030288
apa: Reitzig, S., Rüsing, M., Zhao, J., Kirbus, B., Mookherjea, S., & Eng, L.
M. (2021). “Seeing Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled
X-Cut Lithium Niobate Thin Films. Crystals, 11(3), Article 288.
https://doi.org/10.3390/cryst11030288
bibtex: '@article{Reitzig_Rüsing_Zhao_Kirbus_Mookherjea_Eng_2021, title={“Seeing
Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut Lithium
Niobate Thin Films}, volume={11}, DOI={10.3390/cryst11030288},
number={3288}, journal={Crystals}, publisher={MDPI AG}, author={Reitzig, Sven
and Rüsing, Michael and Zhao, Jie and Kirbus, Benjamin and Mookherjea, Shayan
and Eng, Lukas M.}, year={2021} }'
chicago: Reitzig, Sven, Michael Rüsing, Jie Zhao, Benjamin Kirbus, Shayan Mookherjea,
and Lukas M. Eng. “‘Seeing Is Believing’—In-Depth Analysis by Co-Imaging of Periodically-Poled
X-Cut Lithium Niobate Thin Films.” Crystals 11, no. 3 (2021). https://doi.org/10.3390/cryst11030288.
ieee: 'S. Reitzig, M. Rüsing, J. Zhao, B. Kirbus, S. Mookherjea, and L. M. Eng,
“‘Seeing Is Believing’—In-Depth Analysis by Co-Imaging of Periodically-Poled X-Cut
Lithium Niobate Thin Films,” Crystals, vol. 11, no. 3, Art. no. 288, 2021,
doi: 10.3390/cryst11030288.'
mla: Reitzig, Sven, et al. “‘Seeing Is Believing’—In-Depth Analysis by Co-Imaging
of Periodically-Poled X-Cut Lithium Niobate Thin Films.” Crystals, vol.
11, no. 3, 288, MDPI AG, 2021, doi:10.3390/cryst11030288.
short: S. Reitzig, M. Rüsing, J. Zhao, B. Kirbus, S. Mookherjea, L.M. Eng, Crystals
11 (2021).
date_created: 2023-10-11T08:19:51Z
date_updated: 2023-10-11T08:20:25Z
doi: 10.3390/cryst11030288
extern: '1'
intvolume: ' 11'
issue: '3'
keyword:
- Inorganic Chemistry
- Condensed Matter Physics
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
publication: Crystals
publication_identifier:
issn:
- 2073-4352
publication_status: published
publisher: MDPI AG
quality_controlled: '1'
status: public
title: “Seeing Is Believing”—In-Depth Analysis by Co-Imaging of Periodically-Poled
X-Cut Lithium Niobate Thin Films
type: journal_article
user_id: '22501'
volume: 11
year: '2021'
...
---
_id: '47964'
abstract:
- lang: eng
text: In the last two decades, variably doped strontium barium niobate (SBN) has
attracted a lot of scientific interest mainly due to its specific non-linear optical
response. Comparably, the parental compound, i.e., undoped SBN, appears to be
less studied so far. Here, two different cuts of single-crystalline nominally
pure strontium barium niobate in the composition Sr0.61Ba0.39Nb2O6 (SBN61) are
comprehensively studied and analyzed with regard to their photoconductive responses.
We present conductance measurements under systematically varied illumination conditions
along either the polar z-axis or perpendicular to it (x-cut). Apart from a pronounced
photoconductance (PC) already under daylight and a large effect upon super-bandgap
illumination in general, we observe (i) distinct spectral features when sweeping
the excitation wavelength over the sub-bandgap region as then discussed in the
context of deep and shallow trap states, (ii) extremely slow long-term relaxation
for both light-on and light-off transients in the range of hours and days, (iii)
a critical dependence of the photoresponse on the pre-illumination history of
the sample, and (iv) a current–voltage hysteresis depending on both the illumination
and the electrical-measurement conditions in a complex manner.
article_number: '780'
article_type: original
author:
- first_name: Elke
full_name: Beyreuther, Elke
last_name: Beyreuther
- first_name: Julius
full_name: Ratzenberger, Julius
last_name: Ratzenberger
- first_name: Matthias
full_name: Roeper, Matthias
last_name: Roeper
- first_name: Benjamin
full_name: Kirbus, Benjamin
last_name: Kirbus
- first_name: Michael
full_name: Rüsing, Michael
id: '22501'
last_name: Rüsing
orcid: 0000-0003-4682-4577
- first_name: Liudmila I.
full_name: Ivleva, Liudmila I.
last_name: Ivleva
- first_name: Lukas M.
full_name: Eng, Lukas M.
last_name: Eng
citation:
ama: Beyreuther E, Ratzenberger J, Roeper M, et al. Photoconduction of Polar and
Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals. Crystals. 2021;11(7).
doi:10.3390/cryst11070780
apa: Beyreuther, E., Ratzenberger, J., Roeper, M., Kirbus, B., Rüsing, M., Ivleva,
L. I., & Eng, L. M. (2021). Photoconduction of Polar and Nonpolar Cuts of
Undoped Sr0.61Ba0.39Nb2O6 Single Crystals. Crystals, 11(7), Article
780. https://doi.org/10.3390/cryst11070780
bibtex: '@article{Beyreuther_Ratzenberger_Roeper_Kirbus_Rüsing_Ivleva_Eng_2021,
title={Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6
Single Crystals}, volume={11}, DOI={10.3390/cryst11070780},
number={7780}, journal={Crystals}, publisher={MDPI AG}, author={Beyreuther, Elke
and Ratzenberger, Julius and Roeper, Matthias and Kirbus, Benjamin and Rüsing,
Michael and Ivleva, Liudmila I. and Eng, Lukas M.}, year={2021} }'
chicago: Beyreuther, Elke, Julius Ratzenberger, Matthias Roeper, Benjamin Kirbus,
Michael Rüsing, Liudmila I. Ivleva, and Lukas M. Eng. “Photoconduction of Polar
and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals.” Crystals
11, no. 7 (2021). https://doi.org/10.3390/cryst11070780.
ieee: 'E. Beyreuther et al., “Photoconduction of Polar and Nonpolar Cuts
of Undoped Sr0.61Ba0.39Nb2O6 Single Crystals,” Crystals, vol. 11, no. 7,
Art. no. 780, 2021, doi: 10.3390/cryst11070780.'
mla: Beyreuther, Elke, et al. “Photoconduction of Polar and Nonpolar Cuts of Undoped
Sr0.61Ba0.39Nb2O6 Single Crystals.” Crystals, vol. 11, no. 7, 780, MDPI
AG, 2021, doi:10.3390/cryst11070780.
short: E. Beyreuther, J. Ratzenberger, M. Roeper, B. Kirbus, M. Rüsing, L.I. Ivleva,
L.M. Eng, Crystals 11 (2021).
date_created: 2023-10-11T08:20:40Z
date_updated: 2023-10-11T08:21:17Z
doi: 10.3390/cryst11070780
extern: '1'
funded_apc: '1'
intvolume: ' 11'
issue: '7'
keyword:
- Inorganic Chemistry
- Condensed Matter Physics
- General Materials Science
- General Chemical Engineering
language:
- iso: eng
main_file_link:
- open_access: '1'
url: https://doi.org/10.3390/cryst11070780
oa: '1'
publication: Crystals
publication_identifier:
issn:
- 2073-4352
publication_status: published
publisher: MDPI AG
quality_controlled: '1'
status: public
title: Photoconduction of Polar and Nonpolar Cuts of Undoped Sr0.61Ba0.39Nb2O6 Single
Crystals
type: journal_article
user_id: '22501'
volume: 11
year: '2021'
...
---
_id: '47965'
abstract:
- lang: eng
text: Exceptionally electron-rich, nearly trigonal-planar tricyanidometalate anions
[Fe(CN)3]7− and [Ru(CN)3]7− were stabilized in LiSr3[Fe(CN)3] and AE3.5[M(CN)3]
(AE=Sr, Ba; M=Fe, Ru). They are the first examples of group 8 elements with the
oxidation state of −IV. Microcrystalline powders were obtained by a solid-state
route, single crystals from alkali metal flux. While LiSr3[Fe(CN)3] crystallizes
in P63/m, the polar space group P63 with three-fold cell volume for AE3.5[M(CN)3]
is confirmed by second harmonic generation. X-ray diffraction, IR and Raman spectroscopy
reveal longer C−N distances (124–128 pm) and much lower stretching frequencies
(1484–1634 cm−1) than in classical cyanidometalates. Weak C−N bonds in combination
with strong M−C π-bonding is a scheme also known for carbonylmetalates. Instead
of the formal notation [Fe−IV(CN−)3]7−, quantum chemical calculations reveal non-innocent
intermediate-valent CN1.67− ligands and a closed-shell d10 configuration for Fe,
that is, Fe2−.
article_type: original
author:
- first_name: Franziska
full_name: Jach, Franziska
last_name: Jach
- first_name: Frank R.
full_name: Wagner, Frank R.
last_name: Wagner
- first_name: Zeeshan H.
full_name: Amber, Zeeshan H.
last_name: Amber
- first_name: Michael
full_name: Rüsing, Michael
id: '22501'
last_name: Rüsing
orcid: 0000-0003-4682-4577
- first_name: Jens
full_name: Hunger, Jens
last_name: Hunger
- first_name: Yurii
full_name: Prots, Yurii
last_name: Prots
- first_name: Martin
full_name: Kaiser, Martin
last_name: Kaiser
- first_name: Matej
full_name: Bobnar, Matej
last_name: Bobnar
- first_name: Anton
full_name: Jesche, Anton
last_name: Jesche
- first_name: Lukas M.
full_name: Eng, Lukas M.
last_name: Eng
- first_name: Michael
full_name: Ruck, Michael
last_name: Ruck
- first_name: Peter
full_name: Höhn, Peter
last_name: Höhn
citation:
ama: Jach F, Wagner FR, Amber ZH, et al. Tricyanidoferrates(−IV) and Ruthenates(−IV)
with Non‐Innocent Cyanido Ligands. Angewandte Chemie International Edition.
2021;60(29):15879-15885. doi:10.1002/anie.202103268
apa: Jach, F., Wagner, F. R., Amber, Z. H., Rüsing, M., Hunger, J., Prots, Y., Kaiser,
M., Bobnar, M., Jesche, A., Eng, L. M., Ruck, M., & Höhn, P. (2021). Tricyanidoferrates(−IV)
and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands. Angewandte Chemie International
Edition, 60(29), 15879–15885. https://doi.org/10.1002/anie.202103268
bibtex: '@article{Jach_Wagner_Amber_Rüsing_Hunger_Prots_Kaiser_Bobnar_Jesche_Eng_et
al._2021, title={Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent
Cyanido Ligands}, volume={60}, DOI={10.1002/anie.202103268},
number={29}, journal={Angewandte Chemie International Edition}, publisher={Wiley},
author={Jach, Franziska and Wagner, Frank R. and Amber, Zeeshan H. and Rüsing,
Michael and Hunger, Jens and Prots, Yurii and Kaiser, Martin and Bobnar, Matej
and Jesche, Anton and Eng, Lukas M. and et al.}, year={2021}, pages={15879–15885}
}'
chicago: 'Jach, Franziska, Frank R. Wagner, Zeeshan H. Amber, Michael Rüsing, Jens
Hunger, Yurii Prots, Martin Kaiser, et al. “Tricyanidoferrates(−IV) and Ruthenates(−IV)
with Non‐Innocent Cyanido Ligands.” Angewandte Chemie International Edition
60, no. 29 (2021): 15879–85. https://doi.org/10.1002/anie.202103268.'
ieee: 'F. Jach et al., “Tricyanidoferrates(−IV) and Ruthenates(−IV) with
Non‐Innocent Cyanido Ligands,” Angewandte Chemie International Edition,
vol. 60, no. 29, pp. 15879–15885, 2021, doi: 10.1002/anie.202103268.'
mla: Jach, Franziska, et al. “Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent
Cyanido Ligands.” Angewandte Chemie International Edition, vol. 60, no.
29, Wiley, 2021, pp. 15879–85, doi:10.1002/anie.202103268.
short: F. Jach, F.R. Wagner, Z.H. Amber, M. Rüsing, J. Hunger, Y. Prots, M. Kaiser,
M. Bobnar, A. Jesche, L.M. Eng, M. Ruck, P. Höhn, Angewandte Chemie International
Edition 60 (2021) 15879–15885.
date_created: 2023-10-11T08:21:55Z
date_updated: 2023-10-11T08:24:32Z
doi: 10.1002/anie.202103268
extern: '1'
intvolume: ' 60'
issue: '29'
keyword:
- General Chemistry
- Catalysis
language:
- iso: eng
page: 15879-15885
publication: Angewandte Chemie International Edition
publication_identifier:
issn:
- 1433-7851
- 1521-3773
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Tricyanidoferrates(−IV) and Ruthenates(−IV) with Non‐Innocent Cyanido Ligands
type: journal_article
user_id: '22501'
volume: 60
year: '2021'
...
---
_id: '47977'
abstract:
- lang: eng
text: Orange-colored crystals of the oxoferrate tellurate K12+6xFe6Te4−xO27 [x=0.222(4)]
were synthesized in a potassium hydroxide hydroflux with a molar water–base ratio
n(H2O)/n(KOH) of 1.5 starting from Fe(NO3)3 ⋅ 9H2O, TeO2 and H2O2 at about 200 °C.
By using (NH4)2TeO4 instead of TeO2, a fine powder consisting of microcrystalline
spheres of K12+6xFe6Te4−xO27 was obtained. K12+6xFe6Te4−xO27 crystallizes in the
acentric cubic space group Iurn:x-wiley:09476539:media:chem202102464:chem202102464-math-0001
3d. [FeIIIO5] pyramids share their apical atoms in [Fe2O9] groups and two of their
edges with [TeVIO6] octahedra to form an open framework that consists of two loosely
connected, but not interpenetrating, chiral networks. The flexibility of the hinged
oxometalate network manifests in a piezoelectric response similar to that of LiNbO3.The
potassium cations are mobile in channels that run along the <111> directions and
cross in cavities acting as nodes. The ion conductivity of cold-pressed pellets
of ball-milled K12+6xFe6Te4−xO27 is 2.3×10^(−4) S ⋅ cm^(−1) at room temperature.
Magnetization measurements and neutron diffraction indicate antiferromagnetic
coupling in the [Fe2O9] groups.
author:
- first_name: Ralf
full_name: Albrecht, Ralf
last_name: Albrecht
- first_name: Markus
full_name: Hoelzel, Markus
last_name: Hoelzel
- first_name: Henrik
full_name: Beccard, Henrik
last_name: Beccard
- first_name: Michael
full_name: Rüsing, Michael
id: '22501'
last_name: Rüsing
orcid: 0000-0003-4682-4577
- first_name: Lukas
full_name: Eng, Lukas
last_name: Eng
- first_name: Thomas
full_name: Doert, Thomas
last_name: Doert
- first_name: Michael
full_name: Ruck, Michael
last_name: Ruck
citation:
ama: Albrecht R, Hoelzel M, Beccard H, et al. Potassium Ion Conductivity in the
Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).
Chemistry – A European Journal. 2021;27(57):14299-14306. doi:10.1002/chem.202102464
apa: Albrecht, R., Hoelzel, M., Beccard, H., Rüsing, M., Eng, L., Doert, T., &
Ruck, M. (2021). Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric,
Antiferromagnetic Oxoferrate(III) Tellurate(VI). Chemistry – A European Journal,
27(57), 14299–14306. https://doi.org/10.1002/chem.202102464
bibtex: '@article{Albrecht_Hoelzel_Beccard_Rüsing_Eng_Doert_Ruck_2021, title={Potassium
Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic
Oxoferrate(III) Tellurate(VI)}, volume={27}, DOI={10.1002/chem.202102464},
number={57}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Albrecht,
Ralf and Hoelzel, Markus and Beccard, Henrik and Rüsing, Michael and Eng, Lukas
and Doert, Thomas and Ruck, Michael}, year={2021}, pages={14299–14306} }'
chicago: 'Albrecht, Ralf, Markus Hoelzel, Henrik Beccard, Michael Rüsing, Lukas
Eng, Thomas Doert, and Michael Ruck. “Potassium Ion Conductivity in the Cubic
Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).”
Chemistry – A European Journal 27, no. 57 (2021): 14299–306. https://doi.org/10.1002/chem.202102464.'
ieee: 'R. Albrecht et al., “Potassium Ion Conductivity in the Cubic Labyrinth
of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI),” Chemistry
– A European Journal, vol. 27, no. 57, pp. 14299–14306, 2021, doi: 10.1002/chem.202102464.'
mla: Albrecht, Ralf, et al. “Potassium Ion Conductivity in the Cubic Labyrinth of
a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI).” Chemistry
– A European Journal, vol. 27, no. 57, Wiley, 2021, pp. 14299–306, doi:10.1002/chem.202102464.
short: R. Albrecht, M. Hoelzel, H. Beccard, M. Rüsing, L. Eng, T. Doert, M. Ruck,
Chemistry – A European Journal 27 (2021) 14299–14306.
date_created: 2023-10-11T08:39:51Z
date_updated: 2023-10-11T08:41:35Z
doi: 10.1002/chem.202102464
extern: '1'
intvolume: ' 27'
issue: '57'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 14299-14306
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic
Oxoferrate(III) Tellurate(VI)
type: journal_article
user_id: '22501'
volume: 27
year: '2021'
...
---
_id: '47569'
abstract:
- lang: eng
text: AbstractThe trend of increasing product diversity
and decreasing production amounts led to the requirement of higher flexibility
of production processes of specialty chemicals. Conventional distillation columns,
mostly equipped with structured packings, lack the flexibility to handle product
changeovers and throughput. Thus, a newly designed distillation column for specialty
chemicals is presented. A numerical model was implemented to analyze the potential
of the wetted‐wall column. The simulation of the distillation of a binary methanol/water
mixture demonstrated that the wetted‐wall column can generate the desired concentration
and temperature profiles. Furthermore, analyses of the pressure drop and separation
efficiency with the test system chlorobenzene/ethylbenzene were conducted.
author:
- first_name: Arnulf
full_name: Reitze, Arnulf
last_name: Reitze
- first_name: Marcus
full_name: Grünewald, Marcus
last_name: Grünewald
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
citation:
ama: Reitze A, Grünewald M, Riese J. Concept of a Flexible Wetted‐Wall Column for
the Distillation of Specialty Chemicals. Chemical Engineering & Technology.
2021;44(7):1327-1335. doi:10.1002/ceat.202000468
apa: Reitze, A., Grünewald, M., & Riese, J. (2021). Concept of a Flexible Wetted‐Wall
Column for the Distillation of Specialty Chemicals. Chemical Engineering &
Technology, 44(7), 1327–1335. https://doi.org/10.1002/ceat.202000468
bibtex: '@article{Reitze_Grünewald_Riese_2021, title={Concept of a Flexible Wetted‐Wall
Column for the Distillation of Specialty Chemicals}, volume={44}, DOI={10.1002/ceat.202000468},
number={7}, journal={Chemical Engineering & Technology}, publisher={Wiley},
author={Reitze, Arnulf and Grünewald, Marcus and Riese, Julia}, year={2021}, pages={1327–1335}
}'
chicago: 'Reitze, Arnulf, Marcus Grünewald, and Julia Riese. “Concept of a Flexible
Wetted‐Wall Column for the Distillation of Specialty Chemicals.” Chemical Engineering
& Technology 44, no. 7 (2021): 1327–35. https://doi.org/10.1002/ceat.202000468.'
ieee: 'A. Reitze, M. Grünewald, and J. Riese, “Concept of a Flexible Wetted‐Wall
Column for the Distillation of Specialty Chemicals,” Chemical Engineering &
Technology, vol. 44, no. 7, pp. 1327–1335, 2021, doi: 10.1002/ceat.202000468.'
mla: Reitze, Arnulf, et al. “Concept of a Flexible Wetted‐Wall Column for the Distillation
of Specialty Chemicals.” Chemical Engineering & Technology, vol.
44, no. 7, Wiley, 2021, pp. 1327–35, doi:10.1002/ceat.202000468.
short: A. Reitze, M. Grünewald, J. Riese, Chemical Engineering & Technology
44 (2021) 1327–1335.
date_created: 2023-10-04T14:17:00Z
date_updated: 2024-03-08T11:37:39Z
doi: 10.1002/ceat.202000468
extern: '1'
intvolume: ' 44'
issue: '7'
keyword:
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 1327-1335
publication: Chemical Engineering & Technology
publication_identifier:
issn:
- 0930-7516
- 1521-4125
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Concept of a Flexible Wetted‐Wall Column for the Distillation of Specialty
Chemicals
type: journal_article
user_id: '101499'
volume: 44
year: '2021'
...
---
_id: '47564'
author:
- first_name: Arnulf
full_name: Reitze, Arnulf
last_name: Reitze
- first_name: Marcus
full_name: Grünewald, Marcus
last_name: Grünewald
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
citation:
ama: Reitze A, Grünewald M, Riese J. Characterization of Liquid-Phase Distribution
in 3D Printed Structured Packings with an Enclosed Column Wall. Industrial
& Engineering Chemistry Research. 2021;61(1):740-746. doi:10.1021/acs.iecr.1c03931
apa: Reitze, A., Grünewald, M., & Riese, J. (2021). Characterization of Liquid-Phase
Distribution in 3D Printed Structured Packings with an Enclosed Column Wall. Industrial
& Engineering Chemistry Research, 61(1), 740–746. https://doi.org/10.1021/acs.iecr.1c03931
bibtex: '@article{Reitze_Grünewald_Riese_2021, title={Characterization of Liquid-Phase
Distribution in 3D Printed Structured Packings with an Enclosed Column Wall},
volume={61}, DOI={10.1021/acs.iecr.1c03931},
number={1}, journal={Industrial & Engineering Chemistry Research}, publisher={American
Chemical Society (ACS)}, author={Reitze, Arnulf and Grünewald, Marcus and Riese,
Julia}, year={2021}, pages={740–746} }'
chicago: 'Reitze, Arnulf, Marcus Grünewald, and Julia Riese. “Characterization of
Liquid-Phase Distribution in 3D Printed Structured Packings with an Enclosed Column
Wall.” Industrial & Engineering Chemistry Research 61, no. 1 (2021):
740–46. https://doi.org/10.1021/acs.iecr.1c03931.'
ieee: 'A. Reitze, M. Grünewald, and J. Riese, “Characterization of Liquid-Phase
Distribution in 3D Printed Structured Packings with an Enclosed Column Wall,”
Industrial & Engineering Chemistry Research, vol. 61, no. 1, pp.
740–746, 2021, doi: 10.1021/acs.iecr.1c03931.'
mla: Reitze, Arnulf, et al. “Characterization of Liquid-Phase Distribution in 3D
Printed Structured Packings with an Enclosed Column Wall.” Industrial &
Engineering Chemistry Research, vol. 61, no. 1, American Chemical Society
(ACS), 2021, pp. 740–46, doi:10.1021/acs.iecr.1c03931.
short: A. Reitze, M. Grünewald, J. Riese, Industrial & Engineering Chemistry
Research 61 (2021) 740–746.
date_created: 2023-10-04T14:16:01Z
date_updated: 2024-03-08T11:38:39Z
doi: 10.1021/acs.iecr.1c03931
extern: '1'
intvolume: ' 61'
issue: '1'
keyword:
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 740-746
publication: Industrial & Engineering Chemistry Research
publication_identifier:
issn:
- 0888-5885
- 1520-5045
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Characterization of Liquid-Phase Distribution in 3D Printed Structured Packings
with an Enclosed Column Wall
type: journal_article
user_id: '101499'
volume: 61
year: '2021'
...
---
_id: '47567'
article_number: '116779'
author:
- first_name: Bastian
full_name: Bruns, Bastian
last_name: Bruns
- first_name: Alessandro
full_name: Di Pretoro, Alessandro
last_name: Di Pretoro
- first_name: Marcus
full_name: Grünewald, Marcus
last_name: Grünewald
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
citation:
ama: 'Bruns B, Di Pretoro A, Grünewald M, Riese J. Flexibility analysis for demand-side
management in large-scale chemical processes: An ethylene oxide production case
study. Chemical Engineering Science. 2021;243. doi:10.1016/j.ces.2021.116779'
apa: 'Bruns, B., Di Pretoro, A., Grünewald, M., & Riese, J. (2021). Flexibility
analysis for demand-side management in large-scale chemical processes: An ethylene
oxide production case study. Chemical Engineering Science, 243,
Article 116779. https://doi.org/10.1016/j.ces.2021.116779'
bibtex: '@article{Bruns_Di Pretoro_Grünewald_Riese_2021, title={Flexibility analysis
for demand-side management in large-scale chemical processes: An ethylene oxide
production case study}, volume={243}, DOI={10.1016/j.ces.2021.116779},
number={116779}, journal={Chemical Engineering Science}, publisher={Elsevier BV},
author={Bruns, Bastian and Di Pretoro, Alessandro and Grünewald, Marcus and Riese,
Julia}, year={2021} }'
chicago: 'Bruns, Bastian, Alessandro Di Pretoro, Marcus Grünewald, and Julia Riese.
“Flexibility Analysis for Demand-Side Management in Large-Scale Chemical Processes:
An Ethylene Oxide Production Case Study.” Chemical Engineering Science
243 (2021). https://doi.org/10.1016/j.ces.2021.116779.'
ieee: 'B. Bruns, A. Di Pretoro, M. Grünewald, and J. Riese, “Flexibility analysis
for demand-side management in large-scale chemical processes: An ethylene oxide
production case study,” Chemical Engineering Science, vol. 243, Art. no.
116779, 2021, doi: 10.1016/j.ces.2021.116779.'
mla: 'Bruns, Bastian, et al. “Flexibility Analysis for Demand-Side Management in
Large-Scale Chemical Processes: An Ethylene Oxide Production Case Study.” Chemical
Engineering Science, vol. 243, 116779, Elsevier BV, 2021, doi:10.1016/j.ces.2021.116779.'
short: B. Bruns, A. Di Pretoro, M. Grünewald, J. Riese, Chemical Engineering Science
243 (2021).
date_created: 2023-10-04T14:16:25Z
date_updated: 2024-03-08T11:38:05Z
doi: 10.1016/j.ces.2021.116779
extern: '1'
intvolume: ' 243'
keyword:
- Applied Mathematics
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
publication: Chemical Engineering Science
publication_identifier:
issn:
- 0009-2509
publication_status: published
publisher: Elsevier BV
quality_controlled: '1'
status: public
title: 'Flexibility analysis for demand-side management in large-scale chemical processes:
An ethylene oxide production case study'
type: journal_article
user_id: '101499'
volume: 243
year: '2021'
...
---
_id: '47565'
author:
- first_name: Bastian
full_name: Bruns, Bastian
last_name: Bruns
- first_name: Alessandro
full_name: Di Pretoro, Alessandro
last_name: Di Pretoro
- first_name: Marcus
full_name: Grünewald, Marcus
last_name: Grünewald
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
citation:
ama: Bruns B, Di Pretoro A, Grünewald M, Riese J. Indirect Demand Response Potential
of Large-Scale Chemical Processes. Industrial & Engineering Chemistry
Research. 2021;61(1):605-620. doi:10.1021/acs.iecr.1c03925
apa: Bruns, B., Di Pretoro, A., Grünewald, M., & Riese, J. (2021). Indirect
Demand Response Potential of Large-Scale Chemical Processes. Industrial &
Engineering Chemistry Research, 61(1), 605–620. https://doi.org/10.1021/acs.iecr.1c03925
bibtex: '@article{Bruns_Di Pretoro_Grünewald_Riese_2021, title={Indirect Demand
Response Potential of Large-Scale Chemical Processes}, volume={61}, DOI={10.1021/acs.iecr.1c03925},
number={1}, journal={Industrial & Engineering Chemistry Research}, publisher={American
Chemical Society (ACS)}, author={Bruns, Bastian and Di Pretoro, Alessandro and
Grünewald, Marcus and Riese, Julia}, year={2021}, pages={605–620} }'
chicago: 'Bruns, Bastian, Alessandro Di Pretoro, Marcus Grünewald, and Julia Riese.
“Indirect Demand Response Potential of Large-Scale Chemical Processes.” Industrial
& Engineering Chemistry Research 61, no. 1 (2021): 605–20. https://doi.org/10.1021/acs.iecr.1c03925.'
ieee: 'B. Bruns, A. Di Pretoro, M. Grünewald, and J. Riese, “Indirect Demand Response
Potential of Large-Scale Chemical Processes,” Industrial & Engineering
Chemistry Research, vol. 61, no. 1, pp. 605–620, 2021, doi: 10.1021/acs.iecr.1c03925.'
mla: Bruns, Bastian, et al. “Indirect Demand Response Potential of Large-Scale Chemical
Processes.” Industrial & Engineering Chemistry Research, vol. 61,
no. 1, American Chemical Society (ACS), 2021, pp. 605–20, doi:10.1021/acs.iecr.1c03925.
short: B. Bruns, A. Di Pretoro, M. Grünewald, J. Riese, Industrial & Engineering
Chemistry Research 61 (2021) 605–620.
date_created: 2023-10-04T14:16:10Z
date_updated: 2024-03-08T11:38:28Z
doi: 10.1021/acs.iecr.1c03925
extern: '1'
intvolume: ' 61'
issue: '1'
keyword:
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 605-620
publication: Industrial & Engineering Chemistry Research
publication_identifier:
issn:
- 0888-5885
- 1520-5045
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Indirect Demand Response Potential of Large-Scale Chemical Processes
type: journal_article
user_id: '101499'
volume: 61
year: '2021'
...
---
_id: '47568'
author:
- first_name: Bastian
full_name: Bruns, Bastian
last_name: Bruns
- first_name: Felix
full_name: Herrmann, Felix
last_name: Herrmann
- first_name: Marcus
full_name: Grünewald, Marcus
last_name: Grünewald
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
citation:
ama: Bruns B, Herrmann F, Grünewald M, Riese J. Dynamic Design Optimization for
Flexible Process Equipment. Industrial & Engineering Chemistry Research.
2021;60(20):7678-7688. doi:10.1021/acs.iecr.1c00306
apa: Bruns, B., Herrmann, F., Grünewald, M., & Riese, J. (2021). Dynamic Design
Optimization for Flexible Process Equipment. Industrial & Engineering
Chemistry Research, 60(20), 7678–7688. https://doi.org/10.1021/acs.iecr.1c00306
bibtex: '@article{Bruns_Herrmann_Grünewald_Riese_2021, title={Dynamic Design Optimization
for Flexible Process Equipment}, volume={60}, DOI={10.1021/acs.iecr.1c00306},
number={20}, journal={Industrial & Engineering Chemistry Research}, publisher={American
Chemical Society (ACS)}, author={Bruns, Bastian and Herrmann, Felix and Grünewald,
Marcus and Riese, Julia}, year={2021}, pages={7678–7688} }'
chicago: 'Bruns, Bastian, Felix Herrmann, Marcus Grünewald, and Julia Riese. “Dynamic
Design Optimization for Flexible Process Equipment.” Industrial & Engineering
Chemistry Research 60, no. 20 (2021): 7678–88. https://doi.org/10.1021/acs.iecr.1c00306.'
ieee: 'B. Bruns, F. Herrmann, M. Grünewald, and J. Riese, “Dynamic Design Optimization
for Flexible Process Equipment,” Industrial & Engineering Chemistry
Research, vol. 60, no. 20, pp. 7678–7688, 2021, doi: 10.1021/acs.iecr.1c00306.'
mla: Bruns, Bastian, et al. “Dynamic Design Optimization for Flexible Process Equipment.”
Industrial & Engineering Chemistry Research, vol. 60, no. 20, American
Chemical Society (ACS), 2021, pp. 7678–88, doi:10.1021/acs.iecr.1c00306.
short: B. Bruns, F. Herrmann, M. Grünewald, J. Riese, Industrial & Engineering
Chemistry Research 60 (2021) 7678–7688.
date_created: 2023-10-04T14:16:46Z
date_updated: 2024-03-08T11:37:55Z
doi: 10.1021/acs.iecr.1c00306
extern: '1'
intvolume: ' 60'
issue: '20'
keyword:
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 7678-7688
publication: Industrial & Engineering Chemistry Research
publication_identifier:
issn:
- 0888-5885
- 1520-5045
publication_status: published
publisher: American Chemical Society (ACS)
quality_controlled: '1'
status: public
title: Dynamic Design Optimization for Flexible Process Equipment
type: journal_article
user_id: '101499'
volume: 60
year: '2021'
...
---
_id: '47570'
abstract:
- lang: eng
text: AbstractShortened product life cycles and
increased demand for specialized products lead to more challenges in efficiently
satisfying customer needs. Customer demands are increasingly uncertain in terms
of type, location, and volume. As a result, more flexible chemical production
plants are required. Modular small‐scale plants can be installed in transportation
containers and, therefore, offer the flexibility of easy relocation, enabling
production close to the customer or supplier. In a mathematical optimization model,
the economic benefit of small‐scale plants in the specialty chemicals market of
polymer production is analyzed. Different scenarios created from the real data
of a chemical company show that the use of small‐scale plants may lead to a significant
reduction in total costs that is mainly due to the transportation costs of raw
materials and products.
author:
- first_name: Bastian
full_name: Bruns, Bastian
last_name: Bruns
- first_name: Tristan
full_name: Becker, Tristan
last_name: Becker
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
- first_name: Stefan
full_name: Lier, Stefan
last_name: Lier
- first_name: Brigitte
full_name: Werners, Brigitte
last_name: Werners
citation:
ama: Bruns B, Becker T, Riese J, Lier S, Werners B. Efficient Production of Specialized
Polymers with Highly Flexible Small‐Scale Plants. Chemical Engineering &
Technology. 2021;44(6):1148-1152. doi:10.1002/ceat.202000591
apa: Bruns, B., Becker, T., Riese, J., Lier, S., & Werners, B. (2021). Efficient
Production of Specialized Polymers with Highly Flexible Small‐Scale Plants. Chemical
Engineering & Technology, 44(6), 1148–1152. https://doi.org/10.1002/ceat.202000591
bibtex: '@article{Bruns_Becker_Riese_Lier_Werners_2021, title={Efficient Production
of Specialized Polymers with Highly Flexible Small‐Scale Plants}, volume={44},
DOI={10.1002/ceat.202000591},
number={6}, journal={Chemical Engineering & Technology}, publisher={Wiley},
author={Bruns, Bastian and Becker, Tristan and Riese, Julia and Lier, Stefan and
Werners, Brigitte}, year={2021}, pages={1148–1152} }'
chicago: 'Bruns, Bastian, Tristan Becker, Julia Riese, Stefan Lier, and Brigitte
Werners. “Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale
Plants.” Chemical Engineering & Technology 44, no. 6 (2021): 1148–52.
https://doi.org/10.1002/ceat.202000591.'
ieee: 'B. Bruns, T. Becker, J. Riese, S. Lier, and B. Werners, “Efficient Production
of Specialized Polymers with Highly Flexible Small‐Scale Plants,” Chemical
Engineering & Technology, vol. 44, no. 6, pp. 1148–1152, 2021, doi:
10.1002/ceat.202000591.'
mla: Bruns, Bastian, et al. “Efficient Production of Specialized Polymers with Highly
Flexible Small‐Scale Plants.” Chemical Engineering & Technology,
vol. 44, no. 6, Wiley, 2021, pp. 1148–52, doi:10.1002/ceat.202000591.
short: B. Bruns, T. Becker, J. Riese, S. Lier, B. Werners, Chemical Engineering
& Technology 44 (2021) 1148–1152.
date_created: 2023-10-04T14:17:08Z
date_updated: 2024-03-08T11:37:29Z
doi: 10.1002/ceat.202000591
extern: '1'
intvolume: ' 44'
issue: '6'
keyword:
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 1148-1152
publication: Chemical Engineering & Technology
publication_identifier:
issn:
- 0930-7516
- 1521-4125
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Efficient Production of Specialized Polymers with Highly Flexible Small‐Scale
Plants
type: journal_article
user_id: '101499'
volume: 44
year: '2021'
...
---
_id: '47571'
abstract:
- lang: eng
text: AbstractIm Rahmen dieses Beitrags werden
experimentelle Untersuchungen zur Tropfenabscheidung im Einleitbereich eines Stoffaustauschapparates
für zweiphasige Strömungen vorgestellt. Dafür wurde in einem Versuchsstand im
Pilotmaßstab der qualitative Tropfenmitriss für unterschiedliche Tropfenabscheider
eines Stoffaustauschapparates vermessen. Die daraus resultierenden Ergebnisse
werden in diesem Beitrag hinsichtlich ihrer Aussagekraft zur Vermeidung von Tropfenmitriss
diskutiert und bewertet. Darüber hinaus wird ein kurzer Ausblick über simulative
Arbeiten zur Bestimmung des Tropfenmitriss gegeben.
author:
- first_name: Henrik
full_name: Fasel, Henrik
last_name: Fasel
- first_name: Novin
full_name: Darvishsefat, Novin
last_name: Darvishsefat
- first_name: Julia
full_name: Riese, Julia
id: '101499'
last_name: Riese
orcid: 0000-0002-3053-0534
- first_name: Marcus
full_name: Grünewald, Marcus
last_name: Grünewald
citation:
ama: Fasel H, Darvishsefat N, Riese J, Grünewald M. Experimentelle Untersuchungen
zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen. Chemie
Ingenieur Technik. 2021;93(7):1100-1106. doi:10.1002/cite.202000242
apa: Fasel, H., Darvishsefat, N., Riese, J., & Grünewald, M. (2021). Experimentelle
Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen.
Chemie Ingenieur Technik, 93(7), 1100–1106. https://doi.org/10.1002/cite.202000242
bibtex: '@article{Fasel_Darvishsefat_Riese_Grünewald_2021, title={Experimentelle
Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen},
volume={93}, DOI={10.1002/cite.202000242},
number={7}, journal={Chemie Ingenieur Technik}, publisher={Wiley}, author={Fasel,
Henrik and Darvishsefat, Novin and Riese, Julia and Grünewald, Marcus}, year={2021},
pages={1100–1106} }'
chicago: 'Fasel, Henrik, Novin Darvishsefat, Julia Riese, and Marcus Grünewald.
“Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen.”
Chemie Ingenieur Technik 93, no. 7 (2021): 1100–1106. https://doi.org/10.1002/cite.202000242.'
ieee: 'H. Fasel, N. Darvishsefat, J. Riese, and M. Grünewald, “Experimentelle Untersuchungen
zum Tropfenmitriss im Feedeinleitbereich von Destillationskolonnen,” Chemie
Ingenieur Technik, vol. 93, no. 7, pp. 1100–1106, 2021, doi: 10.1002/cite.202000242.'
mla: Fasel, Henrik, et al. “Experimentelle Untersuchungen zum Tropfenmitriss im
Feedeinleitbereich von Destillationskolonnen.” Chemie Ingenieur Technik,
vol. 93, no. 7, Wiley, 2021, pp. 1100–06, doi:10.1002/cite.202000242.
short: H. Fasel, N. Darvishsefat, J. Riese, M. Grünewald, Chemie Ingenieur Technik
93 (2021) 1100–1106.
date_created: 2023-10-04T14:17:16Z
date_updated: 2024-03-08T11:37:17Z
doi: 10.1002/cite.202000242
extern: '1'
intvolume: ' 93'
issue: '7'
keyword:
- Industrial and Manufacturing Engineering
- General Chemical Engineering
- General Chemistry
language:
- iso: ger
page: 1100-1106
publication: Chemie Ingenieur Technik
publication_identifier:
issn:
- 0009-286X
- 1522-2640
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Experimentelle Untersuchungen zum Tropfenmitriss im Feedeinleitbereich von
Destillationskolonnen
type: journal_article
user_id: '101499'
volume: 93
year: '2021'
...
---
_id: '53086'
article_number: '111863'
author:
- first_name: Hao
full_name: Zhang, Hao
last_name: Zhang
- first_name: Dennis
full_name: Kaczmarek, Dennis
last_name: Kaczmarek
- first_name: Charlotte
full_name: Rudolph, Charlotte
last_name: Rudolph
- first_name: Steffen
full_name: Schmitt, Steffen
last_name: Schmitt
- first_name: Nina
full_name: Gaiser, Nina
last_name: Gaiser
- first_name: Patrick
full_name: Oßwald, Patrick
last_name: Oßwald
- first_name: Thomas
full_name: Bierkandt, Thomas
last_name: Bierkandt
- first_name: Tina
full_name: Kasper, Tina
id: '94562'
last_name: Kasper
orcid: '0000-0003-3993-5316 '
- first_name: Burak
full_name: Atakan, Burak
last_name: Atakan
- first_name: Katharina
full_name: Kohse-Höinghaus, Katharina
last_name: Kohse-Höinghaus
citation:
ama: 'Zhang H, Kaczmarek D, Rudolph C, et al. Dimethyl ether (DME) and dimethoxymethane
(DMM) as reaction enhancers for methane: Combining flame experiments with model-assisted
exploration of a polygeneration process. Combustion and Flame. 2021;237.
doi:10.1016/j.combustflame.2021.111863'
apa: 'Zhang, H., Kaczmarek, D., Rudolph, C., Schmitt, S., Gaiser, N., Oßwald, P.,
Bierkandt, T., Kasper, T., Atakan, B., & Kohse-Höinghaus, K. (2021). Dimethyl
ether (DME) and dimethoxymethane (DMM) as reaction enhancers for methane: Combining
flame experiments with model-assisted exploration of a polygeneration process.
Combustion and Flame, 237, Article 111863. https://doi.org/10.1016/j.combustflame.2021.111863'
bibtex: '@article{Zhang_Kaczmarek_Rudolph_Schmitt_Gaiser_Oßwald_Bierkandt_Kasper_Atakan_Kohse-Höinghaus_2021,
title={Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for
methane: Combining flame experiments with model-assisted exploration of a polygeneration
process}, volume={237}, DOI={10.1016/j.combustflame.2021.111863},
number={111863}, journal={Combustion and Flame}, publisher={Elsevier BV}, author={Zhang,
Hao and Kaczmarek, Dennis and Rudolph, Charlotte and Schmitt, Steffen and Gaiser,
Nina and Oßwald, Patrick and Bierkandt, Thomas and Kasper, Tina and Atakan, Burak
and Kohse-Höinghaus, Katharina}, year={2021} }'
chicago: 'Zhang, Hao, Dennis Kaczmarek, Charlotte Rudolph, Steffen Schmitt, Nina
Gaiser, Patrick Oßwald, Thomas Bierkandt, Tina Kasper, Burak Atakan, and Katharina
Kohse-Höinghaus. “Dimethyl Ether (DME) and Dimethoxymethane (DMM) as Reaction
Enhancers for Methane: Combining Flame Experiments with Model-Assisted Exploration
of a Polygeneration Process.” Combustion and Flame 237 (2021). https://doi.org/10.1016/j.combustflame.2021.111863.'
ieee: 'H. Zhang et al., “Dimethyl ether (DME) and dimethoxymethane (DMM)
as reaction enhancers for methane: Combining flame experiments with model-assisted
exploration of a polygeneration process,” Combustion and Flame, vol. 237,
Art. no. 111863, 2021, doi: 10.1016/j.combustflame.2021.111863.'
mla: 'Zhang, Hao, et al. “Dimethyl Ether (DME) and Dimethoxymethane (DMM) as Reaction
Enhancers for Methane: Combining Flame Experiments with Model-Assisted Exploration
of a Polygeneration Process.” Combustion and Flame, vol. 237, 111863, Elsevier
BV, 2021, doi:10.1016/j.combustflame.2021.111863.'
short: H. Zhang, D. Kaczmarek, C. Rudolph, S. Schmitt, N. Gaiser, P. Oßwald, T.
Bierkandt, T. Kasper, B. Atakan, K. Kohse-Höinghaus, Combustion and Flame 237
(2021).
date_created: 2024-03-27T17:51:19Z
date_updated: 2024-03-27T17:52:07Z
department:
- _id: '728'
doi: 10.1016/j.combustflame.2021.111863
extern: '1'
intvolume: ' 237'
keyword:
- General Physics and Astronomy
- Energy Engineering and Power Technology
- Fuel Technology
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
publication: Combustion and Flame
publication_identifier:
issn:
- 0010-2180
publication_status: published
publisher: Elsevier BV
status: public
title: 'Dimethyl ether (DME) and dimethoxymethane (DMM) as reaction enhancers for
methane: Combining flame experiments with model-assisted exploration of a polygeneration
process'
type: journal_article
user_id: '94562'
volume: 237
year: '2021'
...
---
_id: '53085'
article_number: '122650'
author:
- first_name: Nina
full_name: Gaiser, Nina
last_name: Gaiser
- first_name: Thomas
full_name: Bierkandt, Thomas
last_name: Bierkandt
- first_name: Patrick
full_name: Oßwald, Patrick
last_name: Oßwald
- first_name: Julia
full_name: Zinsmeister, Julia
last_name: Zinsmeister
- first_name: Trupti
full_name: Kathrotia, Trupti
last_name: Kathrotia
- first_name: Shkelqim
full_name: Shaqiri, Shkelqim
last_name: Shaqiri
- first_name: Patrick
full_name: Hemberger, Patrick
last_name: Hemberger
- first_name: Tina
full_name: Kasper, Tina
id: '94562'
last_name: Kasper
orcid: '0000-0003-3993-5316 '
- first_name: Manfred
full_name: Aigner, Manfred
last_name: Aigner
- first_name: Markus
full_name: Köhler, Markus
last_name: Köhler
citation:
ama: 'Gaiser N, Bierkandt T, Oßwald P, et al. Oxidation of oxymethylene ether (OME0−5):
An experimental systematic study by mass spectrometry and photoelectron photoion
coincidence spectroscopy. Fuel. 2021;313. doi:10.1016/j.fuel.2021.122650'
apa: 'Gaiser, N., Bierkandt, T., Oßwald, P., Zinsmeister, J., Kathrotia, T., Shaqiri,
S., Hemberger, P., Kasper, T., Aigner, M., & Köhler, M. (2021). Oxidation
of oxymethylene ether (OME0−5): An experimental systematic study by mass spectrometry
and photoelectron photoion coincidence spectroscopy. Fuel, 313,
Article 122650. https://doi.org/10.1016/j.fuel.2021.122650'
bibtex: '@article{Gaiser_Bierkandt_Oßwald_Zinsmeister_Kathrotia_Shaqiri_Hemberger_Kasper_Aigner_Köhler_2021,
title={Oxidation of oxymethylene ether (OME0−5): An experimental systematic study
by mass spectrometry and photoelectron photoion coincidence spectroscopy}, volume={313},
DOI={10.1016/j.fuel.2021.122650},
number={122650}, journal={Fuel}, publisher={Elsevier BV}, author={Gaiser, Nina
and Bierkandt, Thomas and Oßwald, Patrick and Zinsmeister, Julia and Kathrotia,
Trupti and Shaqiri, Shkelqim and Hemberger, Patrick and Kasper, Tina and Aigner,
Manfred and Köhler, Markus}, year={2021} }'
chicago: 'Gaiser, Nina, Thomas Bierkandt, Patrick Oßwald, Julia Zinsmeister, Trupti
Kathrotia, Shkelqim Shaqiri, Patrick Hemberger, Tina Kasper, Manfred Aigner, and
Markus Köhler. “Oxidation of Oxymethylene Ether (OME0−5): An Experimental Systematic
Study by Mass Spectrometry and Photoelectron Photoion Coincidence Spectroscopy.”
Fuel 313 (2021). https://doi.org/10.1016/j.fuel.2021.122650.'
ieee: 'N. Gaiser et al., “Oxidation of oxymethylene ether (OME0−5): An experimental
systematic study by mass spectrometry and photoelectron photoion coincidence spectroscopy,”
Fuel, vol. 313, Art. no. 122650, 2021, doi: 10.1016/j.fuel.2021.122650.'
mla: 'Gaiser, Nina, et al. “Oxidation of Oxymethylene Ether (OME0−5): An Experimental
Systematic Study by Mass Spectrometry and Photoelectron Photoion Coincidence Spectroscopy.”
Fuel, vol. 313, 122650, Elsevier BV, 2021, doi:10.1016/j.fuel.2021.122650.'
short: N. Gaiser, T. Bierkandt, P. Oßwald, J. Zinsmeister, T. Kathrotia, S. Shaqiri,
P. Hemberger, T. Kasper, M. Aigner, M. Köhler, Fuel 313 (2021).
date_created: 2024-03-27T17:50:11Z
date_updated: 2024-03-27T17:50:47Z
department:
- _id: '728'
doi: 10.1016/j.fuel.2021.122650
extern: '1'
intvolume: ' 313'
keyword:
- Organic Chemistry
- Energy Engineering and Power Technology
- Fuel Technology
- General Chemical Engineering
language:
- iso: eng
publication: Fuel
publication_identifier:
issn:
- 0016-2361
publication_status: published
publisher: Elsevier BV
status: public
title: 'Oxidation of oxymethylene ether (OME0−5): An experimental systematic study
by mass spectrometry and photoelectron photoion coincidence spectroscopy'
type: journal_article
user_id: '94562'
volume: 313
year: '2021'
...
---
_id: '41001'
abstract:
- lang: eng
text: For entropic reasons, the synthesis of macrocycles via olefin ring-closing
metathesis (RCM) is impeded by competing acyclic diene metathesis (ADMET) oligomerization.
With cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes
confined in tailored ordered mesoporous silica, RCM can be run with macrocyclization
selectivities up to 98% and high substrate concentrations up to 0.1 M. Molecular
dynamics simulations show that the high conversions are a direct result of the
proximity between the surface-bound catalyst, proven by extended X-ray absorption
spectroscopy, and the surface-located substrates. Back-diffusion of the macrocycles
decreases with decreasing pore diameter of the silica and is responsible for the
high macrocyclization efficiency. Also, Z-selectivity increases with decreasing
pore diameter and increasing Tolman electronic parameter of the NHC. Running reactions
at different concentrations allows for identifying the optimum substrate concentration
for each material and substrate combination.
article_type: original
author:
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Hamzeh
full_name: Kraus, Hamzeh
last_name: Kraus
- first_name: Mathis J.
full_name: Benedikter, Mathis J.
last_name: Benedikter
- first_name: Dongren
full_name: Wang, Dongren
last_name: Wang
- first_name: Johanna R.
full_name: Bruckner, Johanna R.
last_name: Bruckner
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Kilian
full_name: Weißer, Kilian
last_name: Weißer
- first_name: Helena
full_name: Solodenko, Helena
last_name: Solodenko
- first_name: Guido
full_name: Schmitz, Guido
last_name: Schmitz
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Niels
full_name: Hansen, Niels
last_name: Hansen
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient
Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene
N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578.
doi:10.1021/acscatal.1c03057
apa: Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski,
M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser,
M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with
Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.
ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057
bibtex: '@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et
al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions
with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene
Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057},
number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)},
author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren
and Bruckner, Johanna R. and Nowakowski, Michał and Weißer, Kilian and Solodenko,
Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578}
}'
chicago: 'Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna
R. Bruckner, Michał Nowakowski, Kilian Weißer, et al. “Confinement Effects for
Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido
Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11,
no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.'
ieee: 'F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021,
doi: 10.1021/acscatal.1c03057.'
mla: Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization
Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic
Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society
(ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057.
short: F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski,
K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS
Catalysis 11 (2021) 11570–11578.
date_created: 2023-01-30T16:49:07Z
date_updated: 2024-05-07T11:44:19Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acscatal.1c03057
intvolume: ' 11'
issue: '18'
keyword:
- Catalysis
- General Chemistry
language:
- iso: eng
page: 11570-11578
publication: ACS Catalysis
publication_identifier:
issn:
- 2155-5435
- 2155-5435
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Confinement Effects for Efficient Macrocyclization Reactions with Supported
Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
type: journal_article
user_id: '48467'
volume: 11
year: '2021'
...
---
_id: '40999'
abstract:
- lang: eng
text: Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl,
NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene)
are presented. Selected catalysts were selectively immobilized inside the mesopores
of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous
progenitors, the immobilized catalysts were used in the hydrosilylation of terminal
alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed
excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic
alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the
neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and
stereoselective catalysts, allowing for the formation of the thermodynamically
less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15
immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement,
showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes,
too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer
was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with
its homogenous counterpart. These are the first examples of high β(Z)-selectivity
in the hydrosilylation of alkynes by confinement generated upon immobilization
inside mesoporous silica.
article_type: original
author:
- first_name: Pradeep K. R.
full_name: Panyam, Pradeep K. R.
last_name: Panyam
- first_name: Boshra
full_name: Atwi, Boshra
last_name: Atwi
- first_name: Felix
full_name: Ziegler, Felix
last_name: Ziegler
- first_name: Wolfgang
full_name: Frey, Wolfgang
last_name: Frey
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Michael R.
full_name: Buchmeiser, Michael R.
last_name: Buchmeiser
citation:
ama: 'Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229.
doi:10.1002/chem.202103099'
apa: 'Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer,
M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68),
17220–17229. https://doi.org/10.1002/chem.202103099'
bibtex: '@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic
Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐
and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68},
journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep
K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał
and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229}
}'
chicago: 'Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michał
Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic
Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐
and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European
Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.'
ieee: 'P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol.
27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.'
mla: 'Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes:
Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity
in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol.
27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.'
short: P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R.
Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229.
date_created: 2023-01-30T16:48:41Z
date_updated: 2024-05-07T11:43:40Z
department:
- _id: '35'
- _id: '306'
doi: 10.1002/chem.202103099
intvolume: ' 27'
issue: '68'
keyword:
- General Chemistry
- Catalysis
- Organic Chemistry
language:
- iso: eng
page: 17220-17229
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: 'Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement
Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes'
type: journal_article
user_id: '48467'
volume: 27
year: '2021'
...
---
_id: '41009'
abstract:
- lang: eng
text: Platinum hydride species catalyze a number of interesting organic reactions.
However, their reactions typically involve the use of high loadings of noble metal
and are difficult to recycle, making them somewhat unsustainable. We have synthesized
surface-immobilized Pt–H species via oxidative addition of surface OH groups to
Pt(PtBu3)2 (1), a rarely used immobilization technique in surface organometallic
chemistry. The hydride species thus made were characterized by infrared, magic-angle
spinning nuclear magnetic resonance, and X-ray absorption spectroscopies and catalyzed
both olefin isomerization and cycloisomerization of a 1,6 enyne (5) with a high
selectivity and low Pt loading.
article_type: original
author:
- first_name: Sarah
full_name: Maier, Sarah
last_name: Maier
- first_name: Steve P.
full_name: Cronin, Steve P.
last_name: Cronin
- first_name: Manh-Anh
full_name: Vu Dinh, Manh-Anh
last_name: Vu Dinh
- first_name: Zheng
full_name: Li, Zheng
last_name: Li
- first_name: Michael
full_name: Dyballa, Michael
last_name: Dyballa
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Deven P.
full_name: Estes, Deven P.
last_name: Estes
citation:
ama: Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species
as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics.
2021;40(11):1751-1757. doi:10.1021/acs.organomet.1c00216
apa: Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski,
M., Bauer, M., & Estes, D. P. (2021). Immobilized Platinum Hydride Species
as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. Organometallics,
40(11), 1751–1757. https://doi.org/10.1021/acs.organomet.1c00216
bibtex: '@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized
Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations},
volume={40}, DOI={10.1021/acs.organomet.1c00216},
number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)},
author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng
and Dyballa, Michael and Nowakowski, Michał and Bauer, Matthias and Estes, Deven
P.}, year={2021}, pages={1751–1757} }'
chicago: 'Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa,
Michał Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride
Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.”
Organometallics 40, no. 11 (2021): 1751–57. https://doi.org/10.1021/acs.organomet.1c00216.'
ieee: 'S. Maier et al., “Immobilized Platinum Hydride Species as Catalysts
for Olefin Isomerizations and Enyne Cycloisomerizations,” Organometallics,
vol. 40, no. 11, pp. 1751–1757, 2021, doi: 10.1021/acs.organomet.1c00216.'
mla: Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for
Olefin Isomerizations and Enyne Cycloisomerizations.” Organometallics,
vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:10.1021/acs.organomet.1c00216.
short: S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M.
Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.
date_created: 2023-01-30T17:00:10Z
date_updated: 2024-05-07T11:43:17Z
department:
- _id: '35'
- _id: '306'
doi: 10.1021/acs.organomet.1c00216
intvolume: ' 40'
issue: '11'
keyword:
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
language:
- iso: eng
page: 1751-1757
publication: Organometallics
publication_identifier:
issn:
- 0276-7333
- 1520-6041
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations
and Enyne Cycloisomerizations
type: journal_article
user_id: '48467'
volume: 40
year: '2021'
...
---
_id: '30216'
author:
- first_name: Marina
full_name: Huber-Gedert, Marina
id: '38352'
last_name: Huber-Gedert
- first_name: Michał
full_name: Nowakowski, Michał
id: '78878'
last_name: Nowakowski
orcid: 0000-0002-3734-7011
- first_name: Ahmet
full_name: Kertmen, Ahmet
last_name: Kertmen
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Natalia
full_name: Lindner, Natalia
last_name: Lindner
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Regine
full_name: Herbst‐Irmer, Regine
last_name: Herbst‐Irmer
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Lennart
full_name: Schmitz, Lennart
last_name: Schmitz
- first_name: Tae‐Kyu
full_name: Choi, Tae‐Kyu
last_name: Choi
- first_name: Jacek
full_name: Kubicki, Jacek
last_name: Kubicki
- first_name: Wojciech
full_name: Gawelda, Wojciech
last_name: Gawelda
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Huber-Gedert M, Nowakowski M, Kertmen A, et al. Fundamental Characterization,
Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry
– A European Journal. 2021;27(38):9905-9918. doi:10.1002/chem.202100766
apa: Huber-Gedert, M., Nowakowski, M., Kertmen, A., Burkhardt, L., Lindner, N.,
Schoch, R., Herbst‐Irmer, R., Neuba, A., Schmitz, L., Choi, T., Kubicki, J., Gawelda,
W., & Bauer, M. (2021). Fundamental Characterization, Photophysics and Photocatalysis
of a Base Metal Iron(II)‐Cobalt(III) Dyad. Chemistry – A European Journal,
27(38), 9905–9918. https://doi.org/10.1002/chem.202100766
bibtex: '@article{Huber-Gedert_Nowakowski_Kertmen_Burkhardt_Lindner_Schoch_Herbst‐Irmer_Neuba_Schmitz_Choi_et
al._2021, title={Fundamental Characterization, Photophysics and Photocatalysis
of a Base Metal Iron(II)‐Cobalt(III) Dyad}, volume={27}, DOI={10.1002/chem.202100766},
number={38}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Huber-Gedert,
Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner,
Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz,
Lennart and Choi, Tae‐Kyu and et al.}, year={2021}, pages={9905–9918} }'
chicago: 'Huber-Gedert, Marina, Michał Nowakowski, Ahmet Kertmen, Lukas Burkhardt,
Natalia Lindner, Roland Schoch, Regine Herbst‐Irmer, et al. “Fundamental Characterization,
Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry
– A European Journal 27, no. 38 (2021): 9905–18. https://doi.org/10.1002/chem.202100766.'
ieee: 'M. Huber-Gedert et al., “Fundamental Characterization, Photophysics
and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad,” Chemistry –
A European Journal, vol. 27, no. 38, pp. 9905–9918, 2021, doi: 10.1002/chem.202100766.'
mla: Huber-Gedert, Marina, et al. “Fundamental Characterization, Photophysics and
Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad.” Chemistry – A European
Journal, vol. 27, no. 38, Wiley, 2021, pp. 9905–18, doi:10.1002/chem.202100766.
short: M. Huber-Gedert, M. Nowakowski, A. Kertmen, L. Burkhardt, N. Lindner, R.
Schoch, R. Herbst‐Irmer, A. Neuba, L. Schmitz, T. Choi, J. Kubicki, W. Gawelda,
M. Bauer, Chemistry – A European Journal 27 (2021) 9905–9918.
date_created: 2022-03-09T08:20:58Z
date_updated: 2024-05-07T11:44:08Z
department:
- _id: '306'
doi: 10.1002/chem.202100766
intvolume: ' 27'
issue: '38'
keyword:
- Photocatalytic Hydrogen Production
- Catalysis
- Inorganic Chemistry
language:
- iso: eng
page: 9905-9918
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal
Iron(II)‐Cobalt(III) Dyad
type: journal_article
user_id: '48467'
volume: 27
year: '2021'
...
---
_id: '35686'
abstract:
- lang: eng
text: AbstractThe development of the frustrated
Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed.
Detailed insight into our strategies in order to overcome challenges during the
reaction development process is provided. Furthermore, the developed chemistry
is extended to the hydrogenation of polyamides and of trifluoroacetamides for
the convenient introduction of trifluoroethyl groups into organic molecules.
author:
- first_name: Jan
full_name: Paradies, Jan
id: '53339'
last_name: Paradies
orcid: 0000-0002-3698-668X
- first_name: Laura
full_name: Köring, Laura
last_name: Köring
- first_name: Nikolai A.
full_name: Sitte, Nikolai A.
last_name: Sitte
citation:
ama: Paradies J, Köring L, Sitte NA. Towards the Development of Frustrated Lewis
Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.
Synthesis. 2021;54(05):1287-1300. doi:10.1055/a-1681-3972
apa: Paradies, J., Köring, L., & Sitte, N. A. (2021). Towards the Development
of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary
Carboxylic Amides. Synthesis, 54(05), 1287–1300. https://doi.org/10.1055/a-1681-3972
bibtex: '@article{Paradies_Köring_Sitte_2021, title={Towards the Development of
Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary
Carboxylic Amides}, volume={54}, DOI={10.1055/a-1681-3972},
number={05}, journal={Synthesis}, publisher={Georg Thieme Verlag KG}, author={Paradies,
Jan and Köring, Laura and Sitte, Nikolai A.}, year={2021}, pages={1287–1300} }'
chicago: 'Paradies, Jan, Laura Köring, and Nikolai A. Sitte. “Towards the Development
of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary
Carboxylic Amides.” Synthesis 54, no. 05 (2021): 1287–1300. https://doi.org/10.1055/a-1681-3972.'
ieee: 'J. Paradies, L. Köring, and N. A. Sitte, “Towards the Development of Frustrated
Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic
Amides,” Synthesis, vol. 54, no. 05, pp. 1287–1300, 2021, doi: 10.1055/a-1681-3972.'
mla: Paradies, Jan, et al. “Towards the Development of Frustrated Lewis Pair (FLP)
Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides.” Synthesis,
vol. 54, no. 05, Georg Thieme Verlag KG, 2021, pp. 1287–300, doi:10.1055/a-1681-3972.
short: J. Paradies, L. Köring, N.A. Sitte, Synthesis 54 (2021) 1287–1300.
date_created: 2023-01-10T08:56:44Z
date_updated: 2023-01-23T12:51:23Z
doi: 10.1055/a-1681-3972
intvolume: ' 54'
issue: '05'
keyword:
- Organic Chemistry
- Catalysis
language:
- iso: eng
page: 1287-1300
publication: Synthesis
publication_identifier:
issn:
- 0039-7881
- 1437-210X
publication_status: published
publisher: Georg Thieme Verlag KG
status: public
title: Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations
of Tertiary and Secondary Carboxylic Amides
type: journal_article
user_id: '53339'
volume: 54
year: '2021'
...