---
_id: '64044'
abstract:
- lang: eng
  text: Abstract Polymer-derived silicon oxycarbide ceramics (SiCO) have been considered
    as potential anode materials for lithium- and sodium-ion batteries. To understand
    their electrochemical storage behavior, detailed insights into structural sites
    present in SiCO are required. In this work, the study of local structures in SiCO
    ceramics containing different amounts of carbon is presented. 13C and 29Si solid-state
    MAS?NMR spectroscopy combined with DFT calculations, atomistic modeling, and EPR
    investigations, suggest significant changes in the local structures of SiCO ceramics
    even by small changes in the material composition. The provided findings on SiCO
    structures will contribute to the research field of polymer-derived ceramics,
    especially to understand electrochemical storage processes of alkali metal/ions
    such as Na/Na+ inside such networks in the future.
author:
- first_name: Edina
  full_name: Šić, Edina
  last_name: Šić
- first_name: Jochen
  full_name: Rohrer, Jochen
  last_name: Rohrer
- first_name: Emmanuel
  full_name: Ricohermoso, Emmanuel
  last_name: Ricohermoso
- first_name: Karsten
  full_name: Albe, Karsten
  last_name: Albe
- first_name: Emmanuel
  full_name: Ionescu, Emmanuel
  last_name: Ionescu
- first_name: Ralf
  full_name: Riedel, Ralf
  last_name: Riedel
- first_name: Hergen
  full_name: Breitzke, Hergen
  last_name: Breitzke
- first_name: Torsten
  full_name: Gutmann, Torsten
  id: '118165'
  last_name: Gutmann
- first_name: Gerd
  full_name: Buntkowsky, Gerd
  last_name: Buntkowsky
citation:
  ama: 'Šić E, Rohrer J, Ricohermoso E, et al. SiCO Ceramics as Storage Materials
    for Alkali Metals/Ions: Insights on Structure Moieties from Solid-State NMR and
    DFT Calculations. <i>Chemsuschem</i>. 2023;16:e202202241. doi:<a href="https://doi.org/10.1002/cssc.202202241">10.1002/cssc.202202241</a>'
  apa: 'Šić, E., Rohrer, J., Ricohermoso, E., Albe, K., Ionescu, E., Riedel, R., Breitzke,
    H., Gutmann, T., &#38; Buntkowsky, G. (2023). SiCO Ceramics as Storage Materials
    for Alkali Metals/Ions: Insights on Structure Moieties from Solid-State NMR and
    DFT Calculations. <i>Chemsuschem</i>, <i>16</i>, e202202241. <a href="https://doi.org/10.1002/cssc.202202241">https://doi.org/10.1002/cssc.202202241</a>'
  bibtex: '@article{Šić_Rohrer_Ricohermoso_Albe_Ionescu_Riedel_Breitzke_Gutmann_Buntkowsky_2023,
    title={SiCO Ceramics as Storage Materials for Alkali Metals/Ions: Insights on
    Structure Moieties from Solid-State NMR and DFT Calculations}, volume={16}, DOI={<a
    href="https://doi.org/10.1002/cssc.202202241">10.1002/cssc.202202241</a>}, journal={Chemsuschem},
    publisher={John Wiley &#38; Sons, Ltd}, author={Šić, Edina and Rohrer, Jochen
    and Ricohermoso, Emmanuel and Albe, Karsten and Ionescu, Emmanuel and Riedel,
    Ralf and Breitzke, Hergen and Gutmann, Torsten and Buntkowsky, Gerd}, year={2023},
    pages={e202202241} }'
  chicago: 'Šić, Edina, Jochen Rohrer, Emmanuel Ricohermoso, Karsten Albe, Emmanuel
    Ionescu, Ralf Riedel, Hergen Breitzke, Torsten Gutmann, and Gerd Buntkowsky. “SiCO
    Ceramics as Storage Materials for Alkali Metals/Ions: Insights on Structure Moieties
    from Solid-State NMR and DFT Calculations.” <i>Chemsuschem</i> 16 (2023): e202202241.
    <a href="https://doi.org/10.1002/cssc.202202241">https://doi.org/10.1002/cssc.202202241</a>.'
  ieee: 'E. Šić <i>et al.</i>, “SiCO Ceramics as Storage Materials for Alkali Metals/Ions:
    Insights on Structure Moieties from Solid-State NMR and DFT Calculations,” <i>Chemsuschem</i>,
    vol. 16, p. e202202241, 2023, doi: <a href="https://doi.org/10.1002/cssc.202202241">10.1002/cssc.202202241</a>.'
  mla: 'Šić, Edina, et al. “SiCO Ceramics as Storage Materials for Alkali Metals/Ions:
    Insights on Structure Moieties from Solid-State NMR and DFT Calculations.” <i>Chemsuschem</i>,
    vol. 16, John Wiley &#38; Sons, Ltd, 2023, p. e202202241, doi:<a href="https://doi.org/10.1002/cssc.202202241">10.1002/cssc.202202241</a>.'
  short: E. Šić, J. Rohrer, E. Ricohermoso, K. Albe, E. Ionescu, R. Riedel, H. Breitzke,
    T. Gutmann, G. Buntkowsky, Chemsuschem 16 (2023) e202202241.
date_created: 2026-02-07T16:11:46Z
date_updated: 2026-02-17T16:13:11Z
doi: 10.1002/cssc.202202241
extern: '1'
intvolume: '        16'
keyword:
- NMR spectroscopy
- Ceramics
- defects
- density functional calculations
- EPR spectroscopy
language:
- iso: eng
page: e202202241
publication: Chemsuschem
publication_identifier:
  issn:
  - 1864-5631
publisher: John Wiley & Sons, Ltd
status: public
title: 'SiCO Ceramics as Storage Materials for Alkali Metals/Ions: Insights on Structure
  Moieties from Solid-State NMR and DFT Calculations'
type: journal_article
user_id: '100715'
volume: 16
year: '2023'
...