---
_id: '59616'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F
    bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub>
    is reported and applied in reactions with arenes, allylic, vinylic and acetylenic
    silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>
author:
- first_name: Axel
  full_name: Hoppe, Axel
  id: '62844'
  last_name: Hoppe
- first_name: Arne J.
  full_name: Stepen, Arne J.
  last_name: Stepen
- first_name: Laura
  full_name: Köring, Laura
  last_name: Köring
- first_name: Jan
  full_name: Paradies, Jan
  id: '53339'
  last_name: Paradies
  orcid: 0000-0002-3698-668X
citation:
  ama: Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>.
    2024;366(13):2933-2938. doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>
  apa: Hoppe, A., Stepen, A. J., Köring, L., &#38; Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    <i>366</i>(13), 2933–2938. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>
  bibtex: '@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>},
    number={13}, journal={Advanced Synthesis &#38;amp; Catalysis}, publisher={Wiley},
    author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan},
    year={2024}, pages={2933–2938} }'
  chicago: 'Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>
    366, no. 13 (2024): 2933–38. <a href="https://doi.org/10.1002/adsc.202400511">https://doi.org/10.1002/adsc.202400511</a>.'
  ieee: 'A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed
    Functionalization of Benzylic C−F Bonds,” <i>Advanced Synthesis &#38;amp; Catalysis</i>,
    vol. 366, no. 13, pp. 2933–2938, 2024, doi: <a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.'
  mla: Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization
    of Benzylic C−F Bonds.” <i>Advanced Synthesis &#38;amp; Catalysis</i>, vol. 366,
    no. 13, Wiley, 2024, pp. 2933–38, doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a>.
  short: A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis &#38;amp;
    Catalysis 366 (2024) 2933–2938.
date_created: 2025-04-22T05:59:08Z
date_updated: 2025-04-22T06:11:59Z
department:
- _id: '389'
doi: 10.1002/adsc.202400511
intvolume: '       366'
issue: '13'
keyword:
- fluoride
- bond activation
- borane
- Lewis acid
- C-C bond formation
language:
- iso: eng
main_file_link:
- open_access: '1'
  url: https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsc.202400511
oa: '1'
page: 2933-2938
publication: Advanced Synthesis &amp; Catalysis
publication_identifier:
  issn:
  - 1615-4150
  - 1615-4169
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds
type: journal_article
user_id: '62844'
volume: 366
year: '2024'
...