@article{31828, author = {{Kupfer, Robert and Köhler, Daniel and Römisch, David and Wituschek, Simon and Ewenz, Lars and Kalich, Jan and Weiß, Deborah and Sadeghian, Behdad and Busch, Matthias and Krüger, Jan and Neuser, Moritz and Grydin, Olexandr and Böhnke, Max and Bielak, Christian Roman and Troschitz, Juliane}}, issn = {{2666-3309}}, journal = {{Journal of Advanced Joining Processes}}, keywords = {{Mechanical Engineering, Mechanics of Materials, Engineering (miscellaneous), Chemical Engineering (miscellaneous)}}, publisher = {{Elsevier BV}}, title = {{{Clinching of Aluminum Materials – Methods for the Continuous Characterization of Process, Microstructure and Properties}}}, doi = {{10.1016/j.jajp.2022.100108}}, volume = {{5}}, year = {{2022}}, } @article{31238, author = {{Kupfer, Robert and Köhler, Daniel and Römisch, David and Wituschek, Simon and Ewenz, Lars and Kalich, Jan and Weiß, Deborah and Sadeghian, Behdad and Busch, Matthias and Krüger, Jan Tobias and Neuser, Moritz and Grydin, Olexandr and Böhnke, Max and Bielak, Christian-Roman and Troschitz, Juliane}}, issn = {{2666-3309}}, journal = {{Journal of Advanced Joining Processes}}, keywords = {{Mechanical Engineering, Mechanics of Materials, Engineering (miscellaneous), Chemical Engineering (miscellaneous)}}, publisher = {{Elsevier BV}}, title = {{{Clinching of Aluminum Materials – Methods for the Continuous Characterization of Process, Microstructure and Properties}}}, doi = {{10.1016/j.jajp.2022.100108}}, year = {{2022}}, } @article{52613, abstract = {{During resistance spot welding of zinc-coated advanced high-strength steels (AHSSs) for automotive production, liquid metal embrittlement (LME) cracking may occur in the event of a combination of various unfavorable influences. In this study, the interactions of different welding current levels and weld times on the tendency for LME cracking in third-generation AHSSs were investigated. LME manifested itself as high-penetration cracks around the circumference of the spot welds for welding currents closely below the expulsion limit. At the same time, the observed tendency for LME cracking showed no direct correlation with the overall heat input of the investigated welding processes. To identify a reliable indicator of the tendency for LME cracking, the local strain rate at the origin of the observed cracks was analyzed over the course of the welding process via finite element simulation. While the local strain rate showed a good correlation with the process-specific LME cracking tendency, it was difficult to interpret due to its discontinuous course. Therefore, based on the experimental measurement of electrode displacement during welding, electrode indentation velocity was proposed as a descriptive indicator for quantifying cracking tendency.}}, author = {{Böhne, Christoph and Meschut, Gerson and BIEGLER, MAX and RETHMEIER, MICHAEL}}, issn = {{0043-2296}}, journal = {{Welding Journal}}, keywords = {{Metals and Alloys, Mechanical Engineering, Mechanics of Materials}}, number = {{7}}, pages = {{197--207}}, publisher = {{American Welding Society}}, title = {{{The Influence of Electrode Indentation Rate on LME Formation during RSW}}}, doi = {{10.29391/2022.101.015}}, volume = {{101}}, year = {{2022}}, } @article{34215, abstract = {{Clinching as a mechanical joining technique allows a fast and reliable joining of metal sheets in large-scale production. An efficient design and dimensioning of clinched joints requires a holistic understanding of the material, the joining process and the resulting properties of the joint. In this paper, the process chain for clinching metal sheets is described and experimental techniques are proposed to analyze the process-microstructure-property relationships from the sheet metal to the joined structure. At the example of clinching aluminum EN AW 6014, characterization methods are applied and discussed for the following characteristics: the mechanical properties of the sheet materials, the tribological behavior in the joining system, the joining process and the resulting material structure, the load-bearing behavior of the joint, the damage and degradation as well as the service life and crack growth behavior. The compilation of the characterization methods gives an overview on the advantages and weaknesses of the methods and the multiple interactions of material, process and properties during clinching. In addition, the results of the analyses on EN AW 6014 can be applied for parameterization and validation of simulations.}}, author = {{Kupfer, Robert and Köhler, Daniel and Römisch, David and Wituschek, Simon and Ewenz, Lars and Kalich, Jan and Weiß, Deborah and Sadeghian, Behdad and Busch, Matthias and Krüger, Jan Tobias and Neuser, Moritz and Grydin, Olexandr and Böhnke, Max and Bielak, Christian Roman and Troschitz, Juliane}}, issn = {{2666-3309}}, journal = {{Journal of Advanced Joining Processes}}, keywords = {{Mechanical Engineering, Mechanics of Materials, Engineering (miscellaneous), Chemical Engineering (miscellaneous)}}, publisher = {{Elsevier BV}}, title = {{{Clinching of Aluminum Materials – Methods for the Continuous Characterization of Process, Microstructure and Properties}}}, doi = {{10.1016/j.jajp.2022.100108}}, volume = {{5}}, year = {{2022}}, } @article{53084, abstract = {{AbstractThe thermal decomposition of Zr(acac)4 is studied in a SiC-microreactor on the micro-second time scale. By utilizing synchrotron radiation and photoelectron photoion coincidence spectroscopy, six important zirconium intermediates, as for instance Zr(C5H7O2)2(C5H6O2), and Zr(C5H6O2)2, are identified in the gas phase for the first time. The adiabatic ionization thresholds of intermediately formed zirconium species are estimated and the main products of their thermal decomposition, acetylacetone, acetylallene and acetone are characterized unambiguously and isomer-selectively. Based on all detected intermediates, we deduce the predominant pyrolysis pathways of the precursor in the temperature range from 400 to 900 K. Our findings are complemented by numerical simulations of the flow field in the microreactor, which show that the choice of dilution gas significantly influences the temperature profile and residence times in the microreactor, such that helium provides a more uniform flow field than argon and should preferentially be used. Graphical abstract Using a soft ionization method coupled to velocity map imaging (VMI), leads to valuable insights in the thermal decomposition of Zr(C5H7O2)4, used in the synthesis of functional nanomaterials and ceramic coatings. Thanks to the use of a microreactor, important gas}}, author = {{Grimm, Sebastian and Baik, Seung-Jin and Hemberger, Patrick and Kasper, Tina and Kempf, Andreas M. and Atakan, Burak}}, issn = {{0884-2914}}, journal = {{Journal of Materials Research}}, keywords = {{Mechanical Engineering, Mechanics of Materials, Condensed Matter Physics, General Materials Science}}, number = {{9}}, pages = {{1558--1575}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Insights into the decomposition of zirconium acetylacetonate using synchrotron radiation: Routes to the formation of volatile Zr-intermediates}}}, doi = {{10.1557/s43578-022-00566-6}}, volume = {{37}}, year = {{2022}}, } @article{53083, abstract = {{AbstractThe decomposition and reduction of ferrocene, an important precursor for iron chemical vapor deposition and catalyst for nanotube synthesis, is investigated in the gas‐phase. Reactive intermediates are detected to understand the underlying chemistry by using a microreactor coupled to a synchrotron light source. Utilizing soft photoionization coupled with photoelectron‐photoion coincidence detection enables us to characterize exclusive intermediates isomer‐selectively. A reaction mechanism for the ferrocene decomposition is proposed, which proceeds as a two‐step process. Initially, the molecule decomposes in a homogeneous surface reaction at temperatures <900 K, leading to products such as cyclopentadiene and cyclopentadienyl radicals that are immediately released to the gas‐phase. At higher temperatures, ferrocene rapidly decomposes in the gas‐phase, losing two cyclopentadienyl radicals in conjunction with iron. The addition of hydrogen to the reaction mixture reduces the decomposition temperature, and changes the branching ratio of the products. This change is mainly attributed to the H‐addition of cyclopentadienyl radicals on the surface, which leads to a release of cyclopentadiene into the gas‐phase. On the surface, ligand fragments may also undergo a series of catalytic H‐losses leading most probably to a high carbon content in the film. Finally, Arrhenius parameters for both global reactions are presented.}}, author = {{Grimm, Sebastian and Hemberger, Patrick and Kasper, Tina and Atakan, Burak}}, issn = {{2196-7350}}, journal = {{Advanced Materials Interfaces}}, keywords = {{Mechanical Engineering, Mechanics of Materials}}, number = {{22}}, publisher = {{Wiley}}, title = {{{Mechanism and Kinetics of the Thermal Decomposition of Fe(C5H5)2 in Inert and Reductive Atmosphere: A Synchrotron‐Assisted Investigation in A Microreactor}}}, doi = {{10.1002/admi.202200192}}, volume = {{9}}, year = {{2022}}, } @article{36872, author = {{Bobzin, K. and Kalscheuer, C. and Grundmeier, Guido and de los Arcos, T. and Kollmann, S. and Carlet, M.}}, issn = {{0257-8972}}, journal = {{Surface and Coatings Technology}}, keywords = {{Materials Chemistry, Surfaces, Coatings and Films, Surfaces and Interfaces, Condensed Matter Physics, General Chemistry}}, publisher = {{Elsevier BV}}, title = {{{Oxidation stability of chromium aluminum oxynitride hard coatings}}}, doi = {{10.1016/j.surfcoat.2022.128927}}, volume = {{449}}, year = {{2022}}, } @article{33002, abstract = {{Many mechanical material properties show a dependence on the strain rate, e.g. yield stress or elongation at fracture. The quantitative description of the material behavior under dynamic loading is of major importance for the evaluation of crash safety. This is carried out using numerical methods and requires characteristic values for the materials used. For the standardized determination of dynamic characteristic values in sheet metal materials, tensile tests performed according to the guideline from [1]. A particular challenge in dynamic tensile tests is the force measurement during the test. For this purpose, strain gauges are attached on each specimen, wired to the measuring equipment and calibrated. This is a common way to determine a force signal that is as low in vibration and as free of bending moments as possible. The preparation effort for the used strain gauges are enormous. For these reasons, an optical method to determine the force by strain measurement using DIC is presented. The experiments are carried out on a high speed tensile testing system. In combioantion with a 3D DIC high speed system for optical strain measurement. The elastic deformation of the specimen in the dynamometric section is measured using strain gauges and the optical method. The measured signals are then compared to validate the presented method. The investigations are conducted using the dual phase steel material HCT590X and the aluminum material EN AW-6014 T4. Strain rates of up to 240 s-1 are investigated.}}, author = {{Böhnke, Max and Unruh, Eduard and Sell, Stanislaw and Bobbert, Mathias and Hein, David and Meschut, Gerson}}, issn = {{1662-9795}}, journal = {{Key Engineering Materials}}, keywords = {{Mechanical Engineering, Mechanics of Materials, General Materials Science}}, location = {{Braga, Portugal}}, pages = {{1564--1572}}, publisher = {{Trans Tech Publications, Ltd.}}, title = {{{Functionality Study of an Optical Measurement Concept for Local Force Signal Determination in High Strain Rate Tensile Tests}}}, doi = {{10.4028/p-wpuzyw}}, volume = {{926}}, year = {{2022}}, } @article{34459, author = {{Schmelzle, Lars and Striewe, Marius and Mergheim, Julia and Meschut, Gerson and Possart, Gunnar and Teutenberg, Dominik and Hein, David and Steinmann, Paul}}, issn = {{0169-4243}}, journal = {{Journal of Adhesion Science and Technology}}, keywords = {{Materials Chemistry, Surfaces, Coatings and Films, Surfaces and Interfaces, Mechanics of Materials, General Chemistry}}, title = {{{Testing, modelling, and parameter identification for adhesively bonded joints under the influence of temperature}}}, doi = {{10.1080/01694243.2022.2125714}}, year = {{2022}}, } @article{30657, author = {{Henkes, Alexander and Wessels, Henning and Mahnken, Rolf}}, issn = {{0045-7825}}, journal = {{Computer Methods in Applied Mechanics and Engineering}}, keywords = {{Computer Science Applications, General Physics and Astronomy, Mechanical Engineering, Mechanics of Materials, Computational Mechanics}}, publisher = {{Elsevier BV}}, title = {{{Physics informed neural networks for continuum micromechanics}}}, doi = {{10.1016/j.cma.2022.114790}}, volume = {{393}}, year = {{2022}}, } @article{40564, abstract = {{The reported N-doped noble carbonaceous support provides strong stabilization of Mn(ii) sub-nanometric active sites as well as a convenient coordination environment to produce CO, HCOOH and CH3COOH from electrochemical CO2 reduction.}}, author = {{Kossmann, Janina and Sánchez-Manjavacas, Maria Luz Ortiz and Brandt, Jessica and Heil, Tobias and Lopez Salas, Nieves and Albero, Josep}}, issn = {{1359-7345}}, journal = {{Chemical Communications}}, keywords = {{Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis}}, number = {{31}}, pages = {{4841--4844}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Mn(ii) sub-nanometric site stabilization in noble, N-doped carbonaceous materials for electrochemical CO2 reduction}}}, doi = {{10.1039/d2cc00585a}}, volume = {{58}}, year = {{2022}}, } @article{40554, author = {{Rodríguez-Gómez, Alberto and Lepre, Enrico and Dorado, Fernando and Sanchez-Silva, Luz and Lopez Salas, Nieves and de la Osa, Ana Raquel}}, issn = {{2468-6069}}, journal = {{Materials Today Energy}}, keywords = {{Energy Engineering and Power Technology, Fuel Technology, Nuclear Energy and Engineering, Materials Science (miscellaneous), Renewable Energy, Sustainability and the Environment}}, publisher = {{Elsevier BV}}, title = {{{Efficient ethanol electro-reforming on bimetallic anodes supported on adenine-based noble carbons: hydrogen production and value-added chemicals}}}, doi = {{10.1016/j.mtener.2022.101231}}, volume = {{32}}, year = {{2022}}, } @article{40561, author = {{Lepre, Enrico and Heske, Julian and Nowakowski, Michal and Scoppola, Ernesto and Zizak, Ivo and Heil, Tobias and Kühne, Thomas D. and Antonietti, Markus and Lopez Salas, Nieves and Albero, Josep}}, issn = {{2211-2855}}, journal = {{Nano Energy}}, keywords = {{Electrical and Electronic Engineering, General Materials Science, Renewable Energy, Sustainability and the Environment}}, publisher = {{Elsevier BV}}, title = {{{Ni-based electrocatalysts for unconventional CO2 reduction reaction to formic acid}}}, doi = {{10.1016/j.nanoen.2022.107191}}, volume = {{97}}, year = {{2022}}, } @article{40984, abstract = {{A two-step seeded-growth method was refined to synthesize Au@Pd core@shell nanoparticles with thin Pd shells, which were then deposited onto alumina to obtain a supported Au@Pd/Al2O3 catalyst active for prototypical CO oxidation. By the strict control of temperature and Pd/Au molar ratio and the use of l-ascorbic acid for making both Au cores and Pd shells, a 1.5 nm Pd layer is formed around the Au core, as evidenced by transmission electron microscopy and energy-dispersive spectroscopy. The core@shell structure and the Pd shell remain intact upon deposition onto alumina and after being used for CO oxidation, as revealed by additional X-ray diffraction and X-ray photoemission spectroscopy before and after the reaction. The Pd shell surface was characterized with in situ infrared (IR) spectroscopy using CO as a chemical probe during CO adsorption–desorption. The IR bands for CO ad-species on the Pd shell suggest that the shell exposes mostly low-index surfaces, likely Pd(111) as the majority facet. Generally, the IR bands are blue-shifted as compared to conventional Pd/alumina catalysts, which may be due to the different support materials for Pd, Au versus Al2O3, and/or less strain of the Pd shell. Frequencies obtained from density functional calculations suggest the latter to be significant. Further, the catalytic CO oxidation ignition-extinction processes were followed by in situ IR, which shows the common CO poisoning and kinetic behavior associated with competitive adsorption of CO and O2 that is typically observed for noble metal catalysts.}}, author = {{Feng, Yanyue and Schaefer, Andreas and Hellman, Anders and Di, Mengqiao and Härelind, Hanna and Bauer, Matthias and Carlsson, Per-Anders}}, issn = {{0743-7463}}, journal = {{Langmuir}}, keywords = {{Electrochemistry, Spectroscopy, Surfaces and Interfaces, Condensed Matter Physics, General Materials Science}}, number = {{42}}, pages = {{12859--12870}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Synthesis and Characterization of Catalytically Active Au Core─Pd Shell Nanoparticles Supported on Alumina}}}, doi = {{10.1021/acs.langmuir.2c01834}}, volume = {{38}}, year = {{2022}}, } @article{40993, abstract = {{Understanding high-temperature unconventional superconductivity has become a long-lasting problem in which the cuprates stand as central reference materials. Given this impasse, the recent discovery of superconductivity in analogous nickelate thin films represents a fundamental breakthrough calling for the identification of additional materials in this class. In particular, thermodynamically more robust systems are required to “upgrade” nickelate superconductors from thin films to bulk samples. Here, we contribute in this direction by reporting the synthesis of the new single-layer T′ Pr2NiO3F compound, assessing this synthesis in relation to the only previous T′ nickelate La2NiO3F, and analyzing the electronic properties across the R2NiO3F series (R = La–Lu) via first-principles calculations. We find that these mixed anion systems have a comparatively high degree of stability and their synthesis enables a fine-tuning of their composition as inferred from their characterization. Furthermore, we find that these unprecedented square-planar nickelates hold great promise as prospective superconductors due to their exceptional electronic structure.}}, author = {{Wissel, Kerstin and Bernardini, Fabio and Oh, Heesu and Vasala, Sami and Schoch, Roland and Blaschkowski, Björn and Glatzel, Pieter and Bauer, Matthias and Clemens, Oliver and Cano, Andrés}}, issn = {{0897-4756}}, journal = {{Chemistry of Materials}}, keywords = {{Materials Chemistry, General Chemical Engineering, General Chemistry}}, number = {{16}}, pages = {{7201--7209}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Single-Layer T′ Nickelates: Synthesis of the La and Pr Members and Electronic Properties across the Rare-Earth Series}}}, doi = {{10.1021/acs.chemmater.2c00726}}, volume = {{34}}, year = {{2022}}, } @article{41320, author = {{Lepre, Enrico and Heske, Julian and Nowakowski, Michal and Scoppola, Ernesto and Zizak, Ivo and Heil, Tobias and Kühne, Thomas D. and Antonietti, Markus and López-Salas, Nieves and Albero, Josep}}, issn = {{2211-2855}}, journal = {{Nano Energy}}, keywords = {{Electrical and Electronic Engineering, General Materials Science, Renewable Energy, Sustainability and the Environment}}, publisher = {{Elsevier BV}}, title = {{{Ni-based electrocatalysts for unconventional CO2 reduction reaction to formic acid}}}, doi = {{10.1016/j.nanoen.2022.107191}}, volume = {{97}}, year = {{2022}}, } @article{40556, abstract = {{ In situ TEM heating experiments combined with extensive chemical, structural and sorption analysis reveal the nanoscale mechanism of porosity formation in carbonaceous materials obtained directly from molecular precursors.}}, author = {{Piankova, Diana and Kossmann, Janina and Zschiesche, Hannes and Antonietti, Markus and Lopez Salas, Nieves and Tarakina, Nadezda V.}}, issn = {{2050-7488}}, journal = {{Journal of Materials Chemistry A}}, keywords = {{General Materials Science, Renewable Energy, Sustainability and the Environment, General Chemistry}}, number = {{47}}, pages = {{25220--25229}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Following carbon condensation by in situ TEM: towards a rational understanding of the processes in the synthesis of nitrogen-doped carbonaceous materials}}}, doi = {{10.1039/d2ta05247d}}, volume = {{10}}, year = {{2022}}, } @article{40557, abstract = {{Laser patterning of different precursor mixtures allows modulating the selectivity of iron oxide supported on N-doped carbons for ORR electrocatalysis.}}, author = {{Wang, Huize and Jerigova, Maria and Hou, Jing and Tarakina, Nadezda V. and Delacroix, Simon and Lopez Salas, Nieves and Strauss, Volker}}, issn = {{2050-7488}}, journal = {{Journal of Materials Chemistry A}}, keywords = {{General Materials Science, Renewable Energy, Sustainability and the Environment, General Chemistry}}, number = {{45}}, pages = {{24156--24166}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Modulating between 2e− and 4e− pathways in the oxygen reduction reaction with laser-synthesized iron oxide-grafted nitrogen-doped carbon}}}, doi = {{10.1039/d2ta05838c}}, volume = {{10}}, year = {{2022}}, } @article{40558, author = {{Odziomek, Mateusz and Giusto, Paolo and Kossmann, Janina and Tarakina, Nadezda V. and Heske, Julian and Rivadeneira, Salvador M. and Keil, Waldemar and Schmidt, Claudia and Mazzanti, Stefano and Savateev, Oleksandr and Perdigón‐Toro, Lorena and Neher, Dieter and Kühne, Thomas D. and Antonietti, Markus and Lopez Salas, Nieves}}, issn = {{0935-9648}}, journal = {{Advanced Materials}}, keywords = {{Mechanical Engineering, Mechanics of Materials, General Materials Science}}, number = {{40}}, publisher = {{Wiley}}, title = {{{“Red Carbon”: A Rediscovered Covalent Crystalline Semiconductor}}}, doi = {{10.1002/adma.202206405}}, volume = {{34}}, year = {{2022}}, } @article{40559, author = {{Schulze Lammers, Bertram and Lopez Salas, Nieves and Stein Siena, Julya and Mirhosseini, Hossein and Yesilpinar, Damla and Heske, Julian and Kühne, Thomas D. and Fuchs, Harald and Antonietti, Markus and Mönig, Harry}}, issn = {{1936-0851}}, journal = {{ACS Nano}}, keywords = {{General Physics and Astronomy, General Engineering, General Materials Science}}, number = {{9}}, pages = {{14284--14296}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Real-Space Identification of Non-Noble Single Atomic Catalytic Sites within Metal-Coordinated Supramolecular Networks}}}, doi = {{10.1021/acsnano.2c04439}}, volume = {{16}}, year = {{2022}}, }