@article{40999,
  abstract     = {{Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica.}},
  author       = {{Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{General Chemistry, Catalysis, Organic Chemistry}},
  number       = {{68}},
  pages        = {{17220--17229}},
  publisher    = {{Wiley}},
  title        = {{{Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}}},
  doi          = {{10.1002/chem.202103099}},
  volume       = {{27}},
  year         = {{2021}},
}

@article{30216,
  author       = {{Huber-Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and Kubicki, Jacek and Gawelda, Wojciech and Bauer, Matthias}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{Photocatalytic Hydrogen Production, Catalysis, Inorganic Chemistry}},
  number       = {{38}},
  pages        = {{9905--9918}},
  publisher    = {{Wiley}},
  title        = {{{Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}}},
  doi          = {{10.1002/chem.202100766}},
  volume       = {{27}},
  year         = {{2021}},
}

@article{35686,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>The development of the frustrated Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed. Detailed insight into our strategies in order to overcome challenges during the reaction development process is provided. Furthermore, the developed chemistry is extended to the hydrogenation of polyamides and of trifluoroacetamides for the convenient introduction of trifluoroethyl groups into organic molecules.</jats:p>}},
  author       = {{Paradies, Jan and Köring, Laura and Sitte, Nikolai A.}},
  issn         = {{0039-7881}},
  journal      = {{Synthesis}},
  keywords     = {{Organic Chemistry, Catalysis}},
  number       = {{05}},
  pages        = {{1287--1300}},
  publisher    = {{Georg Thieme Verlag KG}},
  title        = {{{Towards the Development of Frustrated Lewis Pair (FLP) Catalyzed Hydrogenations of Tertiary and Secondary Carboxylic Amides}}},
  doi          = {{10.1055/a-1681-3972}},
  volume       = {{54}},
  year         = {{2021}},
}

@article{40562,
  author       = {{da Silva, Marcos A.R. and Silva, Ingrid F. and Xue, Qi and Lo, Benedict T.W. and Tarakina, Nadezda V. and Nunes, Barbara N. and Adler, Peter and Sahoo, Sudhir K. and Bahnemann, Detlef W. and Lopez Salas, Nieves and Savateev, Aleksandr and Ribeiro, Caue and Kühne, Thomas D. and Antonietti, Markus and Teixeira, Ivo F.}},
  issn         = {{0926-3373}},
  journal      = {{Applied Catalysis B: Environmental}},
  keywords     = {{Process Chemistry and Technology, General Environmental Science, Catalysis}},
  publisher    = {{Elsevier BV}},
  title        = {{{Sustainable oxidation catalysis supported by light: Fe-poly (heptazine imide) as a heterogeneous single-atom photocatalyst}}},
  doi          = {{10.1016/j.apcatb.2021.120965}},
  volume       = {{304}},
  year         = {{2021}},
}

@article{41323,
  author       = {{Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren and Bruckner, Johanna R. and Nowakowski, Michal and Weißer, Kilian and Solodenko, Helena and Schmitz, Guido and Bauer, Matthias and Hansen, Niels and Buchmeiser, Michael R.}},
  issn         = {{2155-5435}},
  journal      = {{ACS Catalysis}},
  keywords     = {{Catalysis, General Chemistry}},
  number       = {{18}},
  pages        = {{11570--11578}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes}}},
  doi          = {{10.1021/acscatal.1c03057}},
  volume       = {{11}},
  year         = {{2021}},
}

@article{41325,
  author       = {{Huber‐Gedert, Marina and Nowakowski, Michał and Kertmen, Ahmet and Burkhardt, Lukas and Lindner, Natalia and Schoch, Roland and Herbst‐Irmer, Regine and Neuba, Adam and Schmitz, Lennart and Choi, Tae‐Kyu and Kubicki, Jacek and Gawelda, Wojciech and Bauer, Matthias}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{General Chemistry, Catalysis, Organic Chemistry}},
  number       = {{38}},
  pages        = {{9905--9918}},
  publisher    = {{Wiley}},
  title        = {{{Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron(II)‐Cobalt(III) Dyad}}},
  doi          = {{10.1002/chem.202100766}},
  volume       = {{27}},
  year         = {{2021}},
}

@article{41322,
  author       = {{Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michal and Bauer, Matthias and Buchmeiser, Michael R.}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{General Chemistry, Catalysis, Organic Chemistry}},
  number       = {{68}},
  pages        = {{17220--17229}},
  publisher    = {{Wiley}},
  title        = {{{Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}}},
  doi          = {{10.1002/chem.202103099}},
  volume       = {{27}},
  year         = {{2021}},
}

@article{40998,
  abstract     = {{Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and growing range of applications. While COFs are well-established as heterogeneous catalysts, so far, their high and ordered porosity has scarcely been utilized to its full potential when it comes to spatially confined reactions in COF pores to alter the outcome of reactions. Here, we present a highly porous and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation reaction provides a molecularly precise heterogeneous olefin metathesis catalyst. An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O) for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency in selectivity, pointing to diffusion limitations induced by the pore confinement.}},
  author       = {{Emmerling, Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer, Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{General Chemistry, Catalysis, Organic Chemistry}},
  number       = {{8}},
  publisher    = {{Wiley}},
  title        = {{{Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity}}},
  doi          = {{10.1002/chem.202104108}},
  volume       = {{28}},
  year         = {{2021}},
}

@article{41003,
  abstract     = {{Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap}},
  author       = {{Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}},
  issn         = {{1359-7345}},
  journal      = {{Chemical Communications}},
  keywords     = {{Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis}},
  number       = {{61}},
  pages        = {{7541--7544}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion}}},
  doi          = {{10.1039/d1cc02173g}},
  volume       = {{57}},
  year         = {{2021}},
}

@article{41000,
  abstract     = {{Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts.}},
  author       = {{Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{1}},
  publisher    = {{Wiley}},
  title        = {{{Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}}},
  doi          = {{10.1002/anie.202110821}},
  volume       = {{61}},
  year         = {{2021}},
}

@article{41010,
  abstract     = {{We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)]. Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2 (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the [SCP]− coordination mode is mainly governed by electronic, rather than steric factors. Quantum mechanical investigations reveal large contributions of the antibonding π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)} (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization is proposed based on DFT calculations.}},
  author       = {{Watt, Fabian A. and Burkhardt, Lukas and Schoch, Roland and Mitzinger, Stefan and Bauer, Matthias and Weigend, Florian and Goicoechea, Jose M. and Tambornino, Frank and Hohloch, Stephan}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{17}},
  pages        = {{9534--9539}},
  publisher    = {{Wiley}},
  title        = {{{η            <sup>3</sup>            ‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**}}},
  doi          = {{10.1002/anie.202100559}},
  volume       = {{60}},
  year         = {{2021}},
}

@article{46000,
  author       = {{Su, Ran and Wang, Zhipeng and Zhu, Lina and Pan, Ying and Zhang, Dawei and Wen, Hui and Luo, Zheng‐Dong and Li, Linglong and Li, Fa‐tang and Wu, Ming and He, Liqiang and Sharma, Pankaj and Seidel, Jan}},
  issn         = {{1433-7851}},
  journal      = {{Angewandte Chemie International Edition}},
  keywords     = {{General Chemistry, Catalysis}},
  number       = {{29}},
  pages        = {{16019--16026}},
  publisher    = {{Wiley}},
  title        = {{{Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting}}},
  doi          = {{10.1002/anie.202103112}},
  volume       = {{60}},
  year         = {{2021}},
}

@article{41007,
  abstract     = {{Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+ pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with four mesoionic carbenes.}},
  author       = {{Dierks, Philipp and Kruse, Ayla and Bokareva, Olga S. and Al-Marri, Mohammed J. and Kalmbach, Jens and Baltrun, Marc and Neuba, Adam and Schoch, Roland and Hohloch, Stephan and Heinze, Katja and Seitz, Michael and Kühn, Oliver and Lochbrunner, Stefan and Bauer, Matthias}},
  issn         = {{1359-7345}},
  journal      = {{Chemical Communications}},
  keywords     = {{Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composite, Metallkomplexe, Optical and Magnetic Materials, Catalysis}},
  number       = {{54}},
  pages        = {{6640--6643}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes}}},
  doi          = {{10.1039/d1cc01716k}},
  volume       = {{57}},
  year         = {{2021}},
}

@article{41015,
  author       = {{Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz, K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker, Bernd and Frey, Wolfgang and Kästner, Johannes and Winkler, Mario and van Slageren, Joris and Nowakowski, Michał and Bauer, Matthias and Buchmeiser, Michael R.}},
  issn         = {{2155-5435}},
  journal      = {{ACS Catalysis}},
  keywords     = {{Catalysis, General Chemistry}},
  number       = {{24}},
  pages        = {{14810--14823}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach}}},
  doi          = {{10.1021/acscatal.0c03978}},
  volume       = {{10}},
  year         = {{2020}},
}

@article{41020,
  author       = {{Gregori, Bernhard J. and Nowakowski, Michał and Schoch, Anke and Pöllath, Simon and Zweck, Josef and Bauer, Matthias and Jacobi von Wangelin, Axel}},
  issn         = {{1867-3880}},
  journal      = {{ChemCatChem}},
  keywords     = {{Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Catalysis}},
  number       = {{21}},
  pages        = {{5359--5363}},
  publisher    = {{Wiley}},
  title        = {{{Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}}},
  doi          = {{10.1002/cctc.202000994}},
  volume       = {{12}},
  year         = {{2020}},
}

@article{41327,
  author       = {{Benedikter, Mathis and Musso, Janis and Kesharwani, Manoj K. and Sterz, K. Leonard and Elser, Iris and Ziegler, Felix and Fischer, Felix and Plietker, Bernd and Frey, Wolfgang and Kästner, Johannes and Winkler, Mario and van Slageren, Joris and Nowakowski, Michal and Bauer, Matthias and Buchmeiser, Michael R.}},
  issn         = {{2155-5435}},
  journal      = {{ACS Catalysis}},
  keywords     = {{Catalysis, General Chemistry}},
  number       = {{24}},
  pages        = {{14810--14823}},
  publisher    = {{American Chemical Society (ACS)}},
  title        = {{{Charge Distribution in Cationic Molybdenum Imido Alkylidene <i>N</i>-Heterocyclic Carbene Complexes: A Combined X-ray, XAS, XES, DFT, Mössbauer, and Catalysis Approach}}},
  doi          = {{10.1021/acscatal.0c03978}},
  volume       = {{10}},
  year         = {{2020}},
}

@article{41329,
  author       = {{Gregori, Bernhard J. and Nowakowski, Michal and Schoch, Anke and Pöllath, Simon and Zweck, Josef and Bauer, Matthias and Jacobi von Wangelin, Axel}},
  issn         = {{1867-3880}},
  journal      = {{ChemCatChem}},
  keywords     = {{Inorganic Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Catalysis}},
  number       = {{21}},
  pages        = {{5359--5363}},
  publisher    = {{Wiley}},
  title        = {{{Stereoselective Chromium‐Catalyzed Semi‐Hydrogenation of Alkynes}}},
  doi          = {{10.1002/cctc.202000994}},
  volume       = {{12}},
  year         = {{2020}},
}

@article{41820,
  author       = {{Hämisch, Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{General Chemistry, Catalysis, Organic Chemistry}},
  number       = {{31}},
  pages        = {{7041--7050}},
  publisher    = {{Wiley}},
  title        = {{{Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo}}},
  doi          = {{10.1002/chem.202000113}},
  volume       = {{26}},
  year         = {{2020}},
}

@article{41824,
  author       = {{Hämisch, Benjamin and Pollak, Roland and Ebbinghaus, Simon and Huber, Klaus}},
  issn         = {{0947-6539}},
  journal      = {{Chemistry – A European Journal}},
  keywords     = {{General Chemistry, Catalysis, Organic Chemistry}},
  number       = {{31}},
  pages        = {{7041--7050}},
  publisher    = {{Wiley}},
  title        = {{{Self‐Assembly of Pseudo‐Isocyanine Chloride as a Sensor for Macromolecular Crowding In Vitro and In Vivo}}},
  doi          = {{10.1002/chem.202000113}},
  volume       = {{26}},
  year         = {{2020}},
}

@article{41025,
  abstract     = {{We investigate the structure-activity correlations of methanation catalysts obtained by thermal decomposition of a Ni-based metal-organic framework, using pair distribution function, X-ray absorption spectroscopy and X-ray diffraction.}},
  author       = {{Prinz, Nils and Schwensow, Leif and Strübbe, Sven and Jentys, Andreas and Bauer, Matthias and Kleist, Wolfgang and Zobel, Mirijam}},
  issn         = {{2040-3364}},
  journal      = {{Nanoscale}},
  keywords     = {{Xray, Catalysis}},
  number       = {{29}},
  pages        = {{15800--15813}},
  publisher    = {{Royal Society of Chemistry (RSC)}},
  title        = {{{Hard X-ray-based techniques for structural investigations of CO2 methanation catalysts prepared by MOF decomposition}}},
  doi          = {{10.1039/d0nr01750g}},
  volume       = {{12}},
  year         = {{2020}},
}