---
_id: '64017'
abstract:
- lang: eng
  text: Abstract Donor stabilization of Sn(II) and Pb(II) halides with 1,1?-ferrocenylene
    bridged bisphosphanes has been explored for Fe(C5H4P(C6H5)2)2 (dppf), and Fe(C5H4PH(C4H9))2.
    These bisphosphanes are reacted with SnBr2 and PbCl2 with and without additional
    Lewis acid (AlCl3) forming acyclic and cyclic donor adducts from which the latter
    represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed,
    characterization includes solution and solid-state NMR in addition to SC-XRD,
    amended by DFT calculations.
author:
- first_name: Sina
  full_name: Nasemann, Sina
  last_name: Nasemann
- first_name: Roman
  full_name: Franz, Roman
  last_name: Franz
- first_name: Denis
  full_name: Kargin, Denis
  last_name: Kargin
- first_name: Clemens
  full_name: Bruhn, Clemens
  last_name: Bruhn
- first_name: Zsolt
  full_name: Kelemen, Zsolt
  last_name: Kelemen
- first_name: Torsten
  full_name: Gutmann, Torsten
  id: '118165'
  last_name: Gutmann
- first_name: Rudolf
  full_name: Pietschnig, Rudolf
  last_name: Pietschnig
citation:
  ama: Nasemann S, Franz R, Kargin D, et al. At the limits of bisphosphonio-substituted
    stannylenes. <i>Chemistry - An Asian Journal</i>. 2024;19(8):e202300950. doi:<a
    href="https://doi.org/10.1002/asia.202300950">10.1002/asia.202300950</a>
  apa: Nasemann, S., Franz, R., Kargin, D., Bruhn, C., Kelemen, Z., Gutmann, T., &#38;
    Pietschnig, R. (2024). At the limits of bisphosphonio-substituted stannylenes.
    <i>Chemistry - An Asian Journal</i>, <i>19</i>(8), e202300950. <a href="https://doi.org/10.1002/asia.202300950">https://doi.org/10.1002/asia.202300950</a>
  bibtex: '@article{Nasemann_Franz_Kargin_Bruhn_Kelemen_Gutmann_Pietschnig_2024, title={At
    the limits of bisphosphonio-substituted stannylenes}, volume={19}, DOI={<a href="https://doi.org/10.1002/asia.202300950">10.1002/asia.202300950</a>},
    number={8}, journal={Chemistry - An Asian Journal}, publisher={John Wiley &#38;
    Sons, Ltd}, author={Nasemann, Sina and Franz, Roman and Kargin, Denis and Bruhn,
    Clemens and Kelemen, Zsolt and Gutmann, Torsten and Pietschnig, Rudolf}, year={2024},
    pages={e202300950} }'
  chicago: 'Nasemann, Sina, Roman Franz, Denis Kargin, Clemens Bruhn, Zsolt Kelemen,
    Torsten Gutmann, and Rudolf Pietschnig. “At the Limits of Bisphosphonio-Substituted
    Stannylenes.” <i>Chemistry - An Asian Journal</i> 19, no. 8 (2024): e202300950.
    <a href="https://doi.org/10.1002/asia.202300950">https://doi.org/10.1002/asia.202300950</a>.'
  ieee: 'S. Nasemann <i>et al.</i>, “At the limits of bisphosphonio-substituted stannylenes,”
    <i>Chemistry - An Asian Journal</i>, vol. 19, no. 8, p. e202300950, 2024, doi:
    <a href="https://doi.org/10.1002/asia.202300950">10.1002/asia.202300950</a>.'
  mla: Nasemann, Sina, et al. “At the Limits of Bisphosphonio-Substituted Stannylenes.”
    <i>Chemistry - An Asian Journal</i>, vol. 19, no. 8, John Wiley &#38; Sons, Ltd,
    2024, p. e202300950, doi:<a href="https://doi.org/10.1002/asia.202300950">10.1002/asia.202300950</a>.
  short: S. Nasemann, R. Franz, D. Kargin, C. Bruhn, Z. Kelemen, T. Gutmann, R. Pietschnig,
    Chemistry - An Asian Journal 19 (2024) e202300950.
date_created: 2026-02-07T16:01:49Z
date_updated: 2026-02-17T16:14:49Z
doi: 10.1002/asia.202300950
extern: '1'
intvolume: '        19'
issue: '8'
keyword:
- ferrocene
- lead
- phosphorus
- tetrylene
- tin
language:
- iso: eng
page: e202300950
publication: Chemistry - An Asian Journal
publisher: John Wiley & Sons, Ltd
status: public
title: At the limits of bisphosphonio-substituted stannylenes
type: journal_article
user_id: '100715'
volume: 19
year: '2024'
...