@article{52372, abstract = {{Due to the hydrolytic instability of LiPF6 in carbonate-based solvents, HF is a typical impurity in Li-ion battery electrolytes. HF significantly influences the performance of Li-ion batteries, for example by impacting the formation of the solid electrolyte interphase at the anode and by affecting transition metal dissolution at the cathode. Additionally, HF complicates studying fundamental interfacial electrochemistry of Li-ion battery electrolytes, such as direct anion reduction, because it is electrocatalytically relatively unstable, resulting in LiF passivation layers. Methods to selectively remove ppm levels of HF from LiPF6-containing carbonate-based electrolytes are limited. We introduce and benchmark a simple yet efficient electrochemical in situ method to selectively remove ppm amounts of HF from LiPF6-containing carbonate-based electrolytes. The basic idea is the application of a suitable potential to a high surface-area metallic electrode upon which only HF reacts (electrocatalytically) while all other electrolyte components are unaffected under the respective conditions.}}, author = {{Ge, Xiaokun and Huck, Marten and Kuhlmann, Andreas and Tiemann, Michael and Weinberger, Christian and Xu, Xiaodan and Zhao, Zhenyu and Steinrueck, Hans-Georg}}, issn = {{0013-4651}}, journal = {{Journal of The Electrochemical Society}}, keywords = {{Materials Chemistry, Electrochemistry, Surfaces, Coatings and Films, Condensed Matter Physics, Renewable Energy, Sustainability and the Environment, Electronic, Optical and Magnetic Materials}}, pages = {{030552}}, publisher = {{The Electrochemical Society}}, title = {{{Electrochemical Removal of HF from Carbonate-based LiPF6-containing Li-ion Battery Electrolytes}}}, doi = {{10.1149/1945-7111/ad30d3}}, volume = {{171}}, year = {{2024}}, } @article{52958, author = {{Boeddeker, Christoph and Subramanian, Aswin Shanmugam and Wichern, Gordon and Haeb-Umbach, Reinhold and Le Roux, Jonathan}}, issn = {{2329-9290}}, journal = {{IEEE/ACM Transactions on Audio, Speech, and Language Processing}}, keywords = {{Electrical and Electronic Engineering, Acoustics and Ultrasonics, Computer Science (miscellaneous), Computational Mathematics}}, pages = {{1185--1197}}, publisher = {{Institute of Electrical and Electronics Engineers (IEEE)}}, title = {{{TS-SEP: Joint Diarization and Separation Conditioned on Estimated Speaker Embeddings}}}, doi = {{10.1109/taslp.2024.3350887}}, volume = {{32}}, year = {{2024}}, } @inproceedings{53069, author = {{Banh, Ngoc Chi and Scharlau, Ingrid}}, location = {{Regensburg}}, title = {{{Effects of task difficulty on visual processing speed}}}, year = {{2024}}, } @article{53101, abstract = {{In this work, we consider optimal control problems for mechanical systems with fixed initial and free final state and a quadratic Lagrange term. Specifically, the dynamics is described by a second order ODE containing an affine control term. Classically, Pontryagin's maximum principle gives necessary optimality conditions for the optimal control problem. For smooth problems, alternatively, a variational approach based on an augmented objective can be followed. Here, we propose a new Lagrangian approach leading to equivalent necessary optimality conditions in the form of Euler-Lagrange equations. Thus, the differential geometric structure (similar to classical Lagrangian dynamics) can be exploited in the framework of optimal control problems. In particular, the formulation enables the symplectic discretisation of the optimal control problem via variational integrators in a straightforward way.}}, author = {{Leyendecker, Sigrid and Maslovskaya, Sofya and Ober-Blöbaum, Sina and Almagro, Rodrigo T. Sato Martín de and Szemenyei, Flóra Orsolya}}, issn = {{2158-2491}}, journal = {{Journal of Computational Dynamics}}, keywords = {{Optimal control problem, Lagrangian system, Hamiltonian system, Variations, Pontryagin's maximum principle.}}, pages = {{0--0}}, publisher = {{American Institute of Mathematical Sciences (AIMS)}}, title = {{{A new Lagrangian approach to control affine systems with a quadratic Lagrange term}}}, doi = {{10.3934/jcd.2024017}}, year = {{2024}}, } @book{34544, abstract = {{Tax evasion, tax avoidance and tax resistance are widespread phenomena in political, economic, social and fiscal history from antiquity through medieval, early modern and modern times. Histories of Tax Evasion, Avoidance and Resistance shows how different groups and individuals around the globe have succeeded or failed in not paying their due taxes, whether in kind or in cash, on their properties or on their crops. It analyses how, throughout history, wealthy and poor taxpayers have tried to avoid or reduce their tax burden by negotiating with tax authorities, through practices of legal or illegal tax evasion, by filing lawsuits, seeking armed resistance or by migration, and how state authorities have dealt with such acts of claim making, defiance, open resistance or elusion. It fills an important research gap in tax history, addressing questions of tax morale and fairness, and how social and political inequality was negotiated through taxation. It gives rich insights into the development of citizen-state relationships throughout the course of history. The book comprises case studies from Ancient Athens, Roman Egypt, Medieval Europe, Early Modern Mexico, the Ottoman Empire, Nigeria under British colonial rule, the United Kingdom of the early 20th century, Greece during the Second World War, as well as West Germany, Switzerland, Sweden and the United States in the 20th century, including transnational entanglements in the world of late-modern offshore finance and taxation. The authors are experts in fiscal, economic, financial, legal, social and/or cultural history. The book is intended for students, researchers and scholars of economic and financial history, social and world history and political economy. The Open Access version of this book, available at www.taylorfrancis.com, has been made available under a Creative Commons Attribution-Share Alike 4.0 license.}}, author = {{Schönhärl, Korinna and Hürlimann, Gisela and Rohde, Dorothea}}, isbn = {{9781003333197}}, keywords = {{Tax History, Financial History}}, publisher = {{Routledge}}, title = {{{Histories of Tax Evasion, Avoidance and Resistance}}}, doi = {{10.4324/9781003333197}}, year = {{2023}}, } @inbook{34546, abstract = {{Jean Bodin's list on how the absolutist monarchical state could raise its revenue ranked taxation only in seventh place. From a modern legal perspective, taxes are compulsory transfers of resources that households and enterprises pay to one or several government bodies without receiving an individual, specific benefit in return. Historians have dealt with not paying taxes in various contexts, such as analysing tax resistance and tax resistance movements in history. Tax law is best understood as an outcome of long-term, often conflictual, negotiations and as an expression of specific political mentalities and ideologies. As a consequence, tax law and sometimes even the tax juridical system have a strongly politicised character. Loopholes in tax legislation that enable or facilitate avoidance or evasion can thus be regarded as a result of the interest-driven politics of parliamentary majorities, as the success of concerted lobby pressure.}}, author = {{Schönhärl, Korinna and Hürlimann, Gisela and Rohde, Dorothea}}, booktitle = {{Histories of Tax Evasion, Avoidance and Resistance }}, editor = {{Schönhärl, Korinna and Hürlimann, Gisela and Rohde, Dorothea}}, pages = {{1--15}}, publisher = {{Routledge}}, title = {{{ The Ability and Intention of Not Paying Taxes in History. Some Introductory Observations}}}, doi = {{10.4324/9781003333197}}, year = {{2023}}, } @inbook{34547, abstract = {{As a case study, this chapter examines two tax education films that were produced 11 years apart in the USA and Western Germany during and after World War II: “The New Spirit” and “Putzke wants to know”. In contrast to America's most popular cartoon character 11 years earlier, Erwin Putzke is in a terrible mood at the beginning of the short film “Putzke wants to know”. The family father and electrician with a workshop of his own is annoyed and upset by the duty of filling in his tax return, grumbling at his wife and daughter and even at their budgie. The film's tax morale message is conveyed to its audience against the backdrop of a sober post-war reality characterised by allied occupation and the Allies' say in West German tax policies during a period of laborious economic build-up after a lost war.}}, author = {{Schönhärl, Korinna}}, booktitle = {{Histories of Tax Evasion, Avoidance and Resistance}}, editor = {{Schönhärl, Korinna and Hürlimann, Gisela and Rohde, Dorothea}}, pages = {{154--167}}, publisher = {{Routledge}}, title = {{{ How to Create a Taxpaying Spirit. A Transnational Examination of an US American and a Western German Tax Education Film in and after World War II}}}, doi = {{10.4324/9781003333197}}, year = {{2023}}, } @article{21199, abstract = {{As in almost every other branch of science, the major advances in data science and machine learning have also resulted in significant improvements regarding the modeling and simulation of nonlinear dynamical systems. It is nowadays possible to make accurate medium to long-term predictions of highly complex systems such as the weather, the dynamics within a nuclear fusion reactor, of disease models or the stock market in a very efficient manner. In many cases, predictive methods are advertised to ultimately be useful for control, as the control of high-dimensional nonlinear systems is an engineering grand challenge with huge potential in areas such as clean and efficient energy production, or the development of advanced medical devices. However, the question of how to use a predictive model for control is often left unanswered due to the associated challenges, namely a significantly higher system complexity, the requirement of much larger data sets and an increased and often problem-specific modeling effort. To solve these issues, we present a universal framework (which we call QuaSiModO: Quantization-Simulation-Modeling-Optimization) to transform arbitrary predictive models into control systems and use them for feedback control. The advantages of our approach are a linear increase in data requirements with respect to the control dimension, performance guarantees that rely exclusively on the accuracy of the predictive model, and only little prior knowledge requirements in control theory to solve complex control problems. In particular the latter point is of key importance to enable a large number of researchers and practitioners to exploit the ever increasing capabilities of predictive models for control in a straight-forward and systematic fashion.}}, author = {{Peitz, Sebastian and Bieker, Katharina}}, journal = {{Automatica}}, publisher = {{Elsevier}}, title = {{{On the Universal Transformation of Data-Driven Models to Control Systems}}}, doi = {{10.1016/j.automatica.2022.110840}}, volume = {{149}}, year = {{2023}}, } @article{35831, abstract = {{Videografien eigenen Unterrichts sind ein mögliches methodisches Werkzeug zur Förderung der professionellen Kompetenz angehender Lehrkräfte, das allerdings innerhalb der Lehramtsausbildung noch nicht breit implementiert ist. Ein möglicher Grund hierfür könnte neben organisatorischen Herausforderungen auch in einer geringen Akzeptanz von Eigenvideografien durch Lehramtsstudierende liegen. Um besser abschätzen zu können, mit welchen Voraussetzungen affektiv-emotionaler Art bei einer breiteren Implementierung im Lehramtsstudium gerechnet werden kann, wurden N = 938 Lehramtsstudierende im Masterstudium an der Universität Paderborn zu ihren Emotionen und Bereitschaften zur Arbeit mit Eigenvideografien befragt. Dabei wurde auch erfasst, wie sich diese je nach bestehenden Erfahrungen zur Arbeit mit Videografien unterscheiden. In den Ergebnissen zeigen sich kaum affektiv-emotionale Reaktionen zur Eigenvideografie, und wenn, vor allem Gefühle der Unsicherheit. Zu beachten ist, dass zwar bei gut der Hälfte der Studierenden eine eher hohe generelle Bereitschaft zur Eigenvideografie besteht, eine konkrete Intention bzw. eine konkrete Volition zur Videografie aber geringer ist. Die ca. 10 % der Studierenden mit Eigenvideografieerfahrung im Studium zeigen erwartungsgemäß höhere Bereitschaften, aber unerwartet keine signifikant positiveren Emotionen. Insgesamt verdeutlichen die Ergebnisse, dass bzgl. der Akzeptanz der Studierenden ein höheres Potenzial zur Implementation von Eigenvideografien im Studium vorliegt, als aktuell ausgeschöpft wird.}}, author = {{Vogelsang, Christoph and Pollmeier, Pascal and Gockeln, Theresa and Rogge, Tim}}, journal = {{Zeitschrift für Bildungsforschung}}, keywords = {{Lehrerbildung, Videografie, Praxissemester, Emotionen, Akzeptanz}}, publisher = {{Springer}}, title = {{{Zu unangenehm, zu viel Aufwand oder keine Möglichkeit? – Emotionen und Bereitschaft von Lehramtsstudierenden zur Videografie eigenen Unterrichts}}}, doi = {{10.1007/s35834-022-00378-y}}, year = {{2023}}, } @article{36800, abstract = {{Abstract. The miniaturisation of components leads to new demands on measurement systems. One of these is the resolution. As a volumetric analysis method and method of non-destructive testing, industrial X-ray computed tomography (XCT) has the ability to measure geometrical features and their corresponding dimensions without destroying them and can therefore be used for quality assurance. However, the concept of resolution is not trivial for XCT and has not yet been finally clarified. In particular, the interface structural resolution, the detectability of two surfaces facing each other after surface segmentation, faces a lack of a test specimen, a corresponding measurand and a reliable method. Simulation-based XCT investigations of a method to determine this type of resolution are presented in this article using the geometry of a test specimen that contains several radially arranged holes of the same size. The borehole diameters correspond to the distance between the holes to investigate the resolvability of surfaces and interfaces. The evaluation is based on mean and extreme values of grey value profiles between the individual boreholes of the reconstructed volume. It is shown that the geometrical detectability of the test specimen surface and interface can be extended by a reasonable choice of the threshold value for surface segmentation within a defined interval. With regard to the resolving capability, a distinction is made between assured detectability and possible detectability, as well as the threshold value used when using the ISO50 threshold for surface segmentation and measurement chain completion. }}, author = {{Busch, Matthias and Hausotte, Tino}}, issn = {{2194-878X}}, journal = {{Journal of Sensors and Sensor Systems}}, keywords = {{Electrical and Electronic Engineering, Instrumentation}}, number = {{1}}, pages = {{1--8}}, publisher = {{Copernicus GmbH}}, title = {{{Simulation-based investigation of the metrological interface structural resolution capability of X-ray computed tomography scanners}}}, doi = {{10.5194/jsss-12-1-2023}}, volume = {{12}}, year = {{2023}}, } @inproceedings{35426, author = {{Richter, Cedric and Haltermann, Jan Frederik and Jakobs, Marie-Christine and Pauck, Felix and Schott, Stefan and Wehrheim, Heike}}, booktitle = {{37th IEEE/ACM International Conference on Automated Software Engineering}}, publisher = {{ACM}}, title = {{{Are Neural Bug Detectors Comparable to Software Developers on Variable Misuse Bugs?}}}, doi = {{10.1145/3551349.3561156}}, year = {{2023}}, } @inproceedings{35427, author = {{Pauck, Felix}}, booktitle = {{37th IEEE/ACM International Conference on Automated Software Engineering}}, publisher = {{ACM}}, title = {{{Scaling Arbitrary Android App Analyses}}}, doi = {{10.1145/3551349.3561339}}, year = {{2023}}, } @article{37613, abstract = {{Chemical phenomena are only observable on a macroscopic level, whereas they are explained by entities on a non-visible level. Students often demonstrate limited ability to link these different levels. Augmented reality (AR) offers the possibility to increase contiguity by embedding virtual models into hands-on experiments. Therefore, this paper presents a pre- and post-test study investigating how learning and cognitive load are influenced by AR during hands-on experiments. Three comparison groups (AR, animation and filmstrip), with a total of N = 104 German secondary school students, conducted and explained two hands-on experiments. Whereas the AR group was allowed to use an AR app showing virtual models of the processes on the submicroscopic level during the experiments, the two other groups were provided with the same dynamic or static models after experimenting. Results indicate no significant learning gain for the AR group in contrast to the two other groups. The perceived intrinsic cognitive load was higher for the AR group in both experiments as well as the extraneous load in the second experiment. It can be concluded that AR could not unleash its theoretically derived potential in the present study.}}, author = {{Peeters, Hendrik and Habig, Sebastian and Fechner, Sabine}}, issn = {{2414-4088}}, journal = {{Multimodal Technologies and Interaction}}, keywords = {{augmented reality, chemistry education, models, experiment, cognitive load}}, number = {{2}}, publisher = {{MDPI AG}}, title = {{{Does Augmented Reality Help to Understand Chemical Phenomena during Hands-On Experiments?–Implications for Cognitive Load and Learning}}}, doi = {{10.3390/mti7020009}}, volume = {{7}}, year = {{2023}}, } @phdthesis{37645, abstract = {{Für den Erwerb fachmethodischer Fähigkeiten stellen Laborpraktika eine zentrale Lerngelegenheiten des Physikstudiums dar. Trotz ihrer hohen Bedeutung fehlt ein hochschulfachdidaktischer Diskurs zu einer lehr-lerntheoretischen Fundierung. Zudem wird ihre Lernwirksamkeit aufgrund der bestehenden didaktischen Gestaltung kritisiert. Die weit verbreiteten engmaschigen Aufgabenstellungen enthalten keine Anreize zur tiefergehenden Auseinandersetzung mit den Inhalten. Um der Diskrepanz zwischen den Zielsetzungen und den von den Lernenden erworbenen Fähigkeiten entgegenzuwirken, liegen aktuell nur wenige und zudem nur punktuelle Grundlagen für eine evidenzbasierte Überarbeitung dieses Veranstaltungsformates vor. Ziel dieser Arbeit ist daher, einen Vorschlag für ein performanzorientiertes Kompetenzstrukturmodell auf universitärem Niveau zu entwickeln, das die Inhaltsbereiche, die experimentellen Fähigkeiten und Fertigkeiten sowie die Qualitätsausprägungen experimenteller Handlungen systematisiert.Die Modellierung ist auf Basis der Analyse videografierter experimenteller Performanz von 16 unterschiedlich fähigen Proband:innen realisiert worden. Für die Entwicklung der Dimensionen Fachmethodik und Qualitätsausprägung werden unter Nutzung der qualitativen Forschungsansätze Dokumentarische Methode und Typenbildung die charakteristischen Merkmale universitären Experimentierens identifiziert und anschließend systematisiert. Zur Prüfung der Passung des Modells zur Perspektive der Wissenschaft Physik ist ein Interrating mit einem Fachwissenschaftler durchgeführt worden, das sehr gute Übereinstimmungswerte liefert. Die Passung des Modells zur Perspektive der Praktikumsleiter:innen ist durch ein Expertenrating erfolgt. Ein Rangfolgen-Vergleich zeigt hohe Übereinstimmungswerte.}}, author = {{Bauer, Anna Brigitte}}, publisher = {{LibreCat University}}, title = {{{Experimentelle Kompetenz Physikstudierender}}}, doi = {{10.17619/UNIPB/1-1652}}, year = {{2023}}, } @unpublished{38031, abstract = {{We consider the data-driven approximation of the Koopman operator for stochastic differential equations on reproducing kernel Hilbert spaces (RKHS). Our focus is on the estimation error if the data are collected from long-term ergodic simulations. We derive both an exact expression for the variance of the kernel cross-covariance operator, measured in the Hilbert-Schmidt norm, and probabilistic bounds for the finite-data estimation error. Moreover, we derive a bound on the prediction error of observables in the RKHS using a finite Mercer series expansion. Further, assuming Koopman-invariance of the RKHS, we provide bounds on the full approximation error. Numerical experiments using the Ornstein-Uhlenbeck process illustrate our results.}}, author = {{Philipp, Friedrich and Schaller, Manuel and Worthmann, Karl and Peitz, Sebastian and Nüske, Feliks}}, booktitle = {{arXiv:2301.08637}}, title = {{{Error bounds for kernel-based approximations of the Koopman operator}}}, year = {{2023}}, } @inproceedings{36522, abstract = {{Jupyter notebooks enable developers to interleave code snippets with rich-text and in-line visualizations. Data scientists use Jupyter notebook as the de-facto standard for creating and sharing machine-learning based solutions, primarily written in Python. Recent studies have demonstrated, however, that a large portion of Jupyter notebooks available on public platforms are undocumented and lacks a narrative structure. This reduces the readability of these notebooks. To address this shortcoming, this paper presents HeaderGen, a novel tool-based approach that automatically annotates code cells with categorical markdown headers based on a taxonomy of machine-learning operations, and classifies and displays function calls according to this taxonomy. For this functionality to be realized, HeaderGen enhances an existing call graph analysis in PyCG. To improve precision, HeaderGen extends PyCG's analysis with support for handling external library code and flow-sensitivity. The former is realized by facilitating the resolution of function return-types. Furthermore, HeaderGen uses type information to perform pattern matching on code syntax to annotate code cells. The evaluation on 15 real-world Jupyter notebooks from Kaggle shows that HeaderGen's underlying call graph analysis yields high accuracy (96.4% precision and 95.9% recall). This is because HeaderGen can resolve return-types of external libraries where existing type inference tools such as pytype (by Google), pyright (by Microsoft), and Jedi fall short. The header generation has a precision of 82.2% and a recall rate of 96.8% with regard to headers created manually by experts. In a user study, HeaderGen helps participants finish comprehension and navigation tasks faster. All participants clearly perceive HeaderGen as useful to their task.}}, author = {{Shivarpatna Venkatesh, Ashwin Prasad and Wang, Jiawei and Li, Li and Bodden, Eric}}, keywords = {{static analysis, python, code comprehension, annotation, literate programming, jupyter notebook}}, publisher = {{IEEE SANER 2023 (International Conference on Software Analysis, Evolution and Reengineering)}}, title = {{{Enhancing Comprehension and Navigation in Jupyter Notebooks with Static Analysis}}}, doi = {{10.48550/ARXIV.2301.04419}}, year = {{2023}}, } @article{41874, author = {{Pfeiffer, Jella and Gutschow, Julia and Haas, Christian and Möslein, Florian and Maspfuhl, Oliver and Borgers, Frederik and Alpsancar, Suzana}}, issn = {{2363-7005}}, journal = {{Business & Information Systems Engineering}}, keywords = {{Information Systems}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Algorithmic Fairness in AI}}}, doi = {{10.1007/s12599-023-00787-x}}, year = {{2023}}, } @misc{41948, author = {{Süßmann, Johannes}}, booktitle = {{wissen/leben. Die Zeitung der WWU Münster}}, pages = {{6}}, title = {{{Zu »wahrer Glückseligkeit« anleiten. WWU-Gründervater Franz von Fürstenberg wollte vor allem den Fortbestand des Landes sichern – ein Gastbeitrag}}}, volume = {{17/1}}, year = {{2023}}, } @article{42154, author = {{Matthias Philipper}}, journal = {{Quick And Easy Journal Title}}, title = {{{New Quick And Easy Publication - Will be edited by LibreCat team}}}, year = {{2023}}, } @unpublished{42160, abstract = {{The goal of this paper is to make a strong point for the usage of dynamical models when using reinforcement learning (RL) for feedback control of dynamical systems governed by partial differential equations (PDEs). To breach the gap between the immense promises we see in RL and the applicability in complex engineering systems, the main challenges are the massive requirements in terms of the training data, as well as the lack of performance guarantees. We present a solution for the first issue using a data-driven surrogate model in the form of a convolutional LSTM with actuation. We demonstrate that learning an actuated model in parallel to training the RL agent significantly reduces the total amount of required data sampled from the real system. Furthermore, we show that iteratively updating the model is of major importance to avoid biases in the RL training. Detailed ablation studies reveal the most important ingredients of the modeling process. We use the chaotic Kuramoto-Sivashinsky equation do demonstarte our findings.}}, author = {{Werner, Stefan and Peitz, Sebastian}}, booktitle = {{arXiv:2302.07160}}, title = {{{Learning a model is paramount for sample efficiency in reinforcement learning control of PDEs}}}, year = {{2023}}, } @article{27426, abstract = {{Regularization is used in many different areas of optimization when solutions are sought which not only minimize a given function, but also possess a certain degree of regularity. Popular applications are image denoising, sparse regression and machine learning. Since the choice of the regularization parameter is crucial but often difficult, path-following methods are used to approximate the entire regularization path, i.e., the set of all possible solutions for all regularization parameters. Due to their nature, the development of these methods requires structural results about the regularization path. The goal of this article is to derive these results for the case of a smooth objective function which is penalized by a piecewise differentiable regularization term. We do this by treating regularization as a multiobjective optimization problem. Our results suggest that even in this general case, the regularization path is piecewise smooth. Moreover, our theory allows for a classification of the nonsmooth features that occur in between smooth parts. This is demonstrated in two applications, namely support-vector machines and exact penalty methods.}}, author = {{Gebken, Bennet and Bieker, Katharina and Peitz, Sebastian}}, journal = {{Journal of Global Optimization}}, number = {{3}}, pages = {{709--741}}, title = {{{On the structure of regularization paths for piecewise differentiable regularization terms}}}, doi = {{10.1007/s10898-022-01223-2}}, volume = {{85}}, year = {{2023}}, } @article{43018, author = {{Alhaddad, Samer and Förstner, Jens and Grynko, Yevgen}}, issn = {{0022-4073}}, journal = {{Journal of Quantitative Spectroscopy and Radiative Transfer}}, keywords = {{tet_topic_scattering}}, publisher = {{Elsevier BV}}, title = {{{Numerical study of light backscattering from layers of absorbing irregular particles larger than the wavelength}}}, doi = {{10.1016/j.jqsrt.2023.108557}}, volume = {{302}}, year = {{2023}}, } @inproceedings{31849, author = {{Hoffmann, Max and Biehler, Rolf}}, booktitle = {{Proceedings of the Fourth Conference of the International Network for Didactic Research in University Mathematics (INDRUM 2022, 19-22 October 2022)}}, editor = {{Trigueros, Marı́a and Barquero, Berta and Hochmuth, Reinhard and Peters, Jana}}, keywords = {{Teaching and learning of specific topics in university mathematics, Transition to, across and from university mathematics, Student Teachers, Geometry, Congruence, Double Discontinuity.}}, publisher = {{University of Hannover and INDRUM.}}, title = {{{Student Teachers ’ Knowledge of Congruence before a University Course on Geometry}}}, year = {{2023}}, } @inproceedings{43097, author = {{Florensa, Ignasio and Hoffmann, Max and Romo Vázquez, Avenilde and Zandieh, Michelle and Martínez-Planell, Rafael}}, booktitle = {{Proceedings of the Fourth Conference of the International Network for Didactic Research in University Mathematics (INDRUM 2022, 19-22 October 2022)}}, editor = {{Trigueros, Marı́a and Barquero, Berta and Hochmuth, Reinhard and Peters, Jana}}, title = {{{Innovations in university teaching based on mathematic education research}}}, year = {{2023}}, } @misc{43186, author = {{Süßmann, Johannes}}, title = {{{Pantheon}}}, year = {{2023}}, } @article{43464, abstract = {{Lightweight design is a common approach to reduce energy demand in the use stage of vehicles. The production of lightweight materials is usually associated with an increase in energy demand, so the environmental impacts of lightweight structures need to be assessed holistically using a life cycle assessment. To estimate the life cycle environmental impacts of a product in its developmental stage, for example, by life cycle engineering, future changes in relevant influencing factors must be considered. Prospective life cycle assessment provides methods for integrating future scenarios into life cycle assessment studies. However, approaches for integrating prospective life cycle assessment into product development are limited. The objective of this work is to provide the methodological foundation for integrating future scenarios of relevant influencing factors in the development of lightweight structures. The applicability of the novel methodology is demonstrated by a case study of a structural component in a steel, aluminium, and hybrid design. The results show that appropriate decarbonisation measures can reduce the life cycle greenhouse gas emissions by up to 95 percent until 2050. We also found that shifts in the environmentally optimal design are possible in future scenarios. Therefore, the methodology and data provided contribute to improved decision-making in product development.}}, author = {{Ostermann, Moritz and Grenz, Julian and Triebus, Marcel and Cerdas, Felipe and Marten, Thorsten and Tröster, Thomas and Herrmann, Christoph}}, issn = {{1996-1073}}, journal = {{Energies}}, keywords = {{Life Cycle Engineering, Life Cycle Assessment, Lightweight Design, Prospective LCA, Future-oriented LCA, Energy System, Material production, Sustainable production}}, number = {{8}}, publisher = {{MDPI AG}}, title = {{{Integrating Prospective Scenarios in Life Cycle Engineering: Case Study of Lightweight Structures}}}, doi = {{10.3390/en16083371}}, volume = {{16}}, year = {{2023}}, } @article{44058, abstract = {{A relatively small body of research has been conducted on the near- and long-term effects of study abroad (SA) to date. This existing research suggests that SA effects on language skills tend to be volatile, while the impact on various aspects of learners’ personal, academic, and professional development may be longer-lasting. Yet, learner perspectives on the dynamics and durability of such effects, in particular in the context of short-term SA programs, remain largely unexplored. This study hence investigates the near-term impact of short-term SA programs as experienced by students within the first months and years following their sojourns. A qualitative case-study design is employed to examine the accounts of four American students of German, who studied abroad in Austria for four weeks and were interviewed repeatedly over a period of up to 40 months after their sojourns. The results suggest that, from the students’ perspective, many effects deteriorate in the near term, although the overall sojourn experience still appears influential. Abstract in German Nur wenige Forschungsvorhaben haben sich bislang den mittel- bis langfristigen Auswirkungen studentischer Auslandsaufenthalte gewidmet; die bisherige Datenlage deutet jedoch darauf hin, dass die Auswirkungen auf sprachliche Kompetenzen eher unbeständig sind, wohingegen die persönliche, studiums- und berufsbezogene Entwicklung der Lernenden länger von einem Auslandsaufenthalt beeinflusst wird. Die Dynamik und Beständigkeit derartiger Auswirkungen wurden jedoch kaum mit Blick auf kurze Auslandsaufenthalte (≤ acht Wochen) sowie aus der Perspektive der Studierenden erforscht, was die vorliegende Studie insbesondere hinsichtlich mittelfristiger Effekte fokussiert. Mittels eines qualitativen Fallstudiendesigns werden die Interviewdaten vier amerikanischer Deutschlernender untersucht, die sich vier Wochen in Österreich aufhielten und in einem Zeitraum von bis zu 40 Monaten nach ihrem Aufenthalt wiederholt befragt wurden. Die Ergebnisse zeigen, dass viele Auswirkungen eines solchen Aufenthalts aus studentischer Perspektive mittelfristig verblassen, auch wenn der Auslandsaufenthalt im Gesamten weiterhin als einflussreiche Erfahrung wahrgenommen wird.}}, author = {{Müller, Mareike}}, issn = {{2380-8144}}, journal = {{Frontiers: The Interdisciplinary Journal of Study Abroad}}, number = {{1}}, pages = {{275--304}}, publisher = {{The Forum on Education Abroad}}, title = {{{Near-Term Effects of Short-Term Study Abroad: A Longitudinal Examination of Learner Perceptions}}}, doi = {{10.36366/frontiers.v35i1.684}}, volume = {{35}}, year = {{2023}}, } @article{42252, abstract = {{Die Wirtschaftlichkeit von Wärmemotoren wird maßgeblich durch die Rückführung von Wärme in Rekuperatoren beeinflusst. Beim isobaren Expansionsmotor vom Bush-Typ, einem Wärmemotor, welcher bereits mit Wärmequellen ab 60°C betrieben werden kann, steigt der thermische Wirkungsgrad durch den Einsatz von Rekuperatoren signifikant. Gleichzeitig wirken sich das Fluidvolumen des Wärmeübertragers sowie der beim Betrieb auftretende Druckverlust negativ auf den thermischen Wirkungsrad aus. In dieser Arbeit wird der Zusammenhang von Totvolumen, Druckverlust und Wärmerückgewinnung untersucht und Empfehlungen für den Betrieb von Rekuperatoren am isobaren Expansionsmotor gegeben.}}, author = {{Mügge, Nils and Kronberg, Alexander and Glushenkov, Maxim and Kenig, Eugeny Y.}}, journal = {{Chemie Ingenieur Technik}}, keywords = {{Isobarer Expansionsmotor, Dynamische Wärmeübertragungsmodellierung, Phasenwechsel, dichte Arbeitsmedien}}, number = {{5}}, publisher = {{Wiley}}, title = {{{Untersuchung überlagerter Effekte von Druckverlust und Totvolumen durch Rekuperation am isobaren Expansionsmotor}}}, doi = {{10.1002/cite.202200243}}, volume = {{95}}, year = {{2023}}, } @article{36983, abstract = {{AbstractThe use of structured measuring systems to prevent wall slip is a common approach to obtain absolute rheological values. Typically, only the minimum distance between the measuring surfaces is used for further calculation, implying that no flow occurs between the structural elements. But this assumption is misleading, and a gap correction is necessary. To determine the radius correction $$\Delta r$$ Δ r for specific geometries, we conducted investigations on three Newtonian fluids (two silicon oils and one suspension considered to be Newtonian in the relevant shear rate range). The results show that $$\Delta r$$ Δ r is not only shear- and material-independent, but geometry-dependent, providing a Newtonian flow behaviour in a similar viscosity range. Therefore, a correction value can be determined with only minute deviations in different Newtonian fluids. As the conducted laboratory measurements are very time-consuming and expensive, a CFD-approach with only very small deviations was additionally developed and compared for validation purposes. Therefore, simulation is an effective and resource-efficient alternative to the presented laboratory measurements to determine $$\Delta r$$ Δ r for the correction of structured coaxial geometries even for non-Newtonian fluids in the future.}}, author = {{Josch, Sebastian and Jesinghausen, Steffen and Dechert, Christopher and Schmid, Hans-Joachim}}, issn = {{0035-4511}}, journal = {{Rheologica Acta}}, keywords = {{rheology, rheometry, suspension, coaxial, correction}}, publisher = {{Springer Science and Business Media LLC}}, title = {{{Experimental and simulative determination and correction of the effective gap extension in structured coaxial measuring systems}}}, doi = {{10.1007/s00397-023-01383-2}}, year = {{2023}}, } @inproceedings{30125, abstract = {{We present an approach for guaranteed constraint satisfaction by means of data-based optimal control, where the model is unknown and has to be obtained from measurement data. To this end, we utilize the Koopman framework and an eDMD-based bilinear surrogate modeling approach for control systems to show an error bound on predicted observables, i.e., functions of the state. This result is then applied to the constraints of the optimal control problem to show that satisfaction of tightened constraints in the purely data-based surrogate model implies constraint satisfaction for the original system.}}, author = {{Schaller, Manuel and Worthmann, Karl and Philipp, Friedrich and Peitz, Sebastian and Nüske, Feliks}}, booktitle = {{IFAC-PapersOnLine}}, number = {{1}}, pages = {{169--174}}, title = {{{Towards reliable data-based optimal and predictive control using extended DMD}}}, doi = {{10.1016/j.ifacol.2023.02.029}}, volume = {{56}}, year = {{2023}}, } @article{43094, abstract = {{}}, author = {{Heck, Tamara and Steinhardt, Isabel and Rahal, Rima-Maria and Schubotz, Moritz and Scholl, Dominik and Behrens, Sarah}}, issn = {{2367-7163}}, journal = {{Research Ideas and Outcomes}}, keywords = {{Open Science}}, publisher = {{Pensoft Publishers}}, title = {{{Bootstrapping the Open Science culture: The fellowship approach}}}, doi = {{10.3897/rio.9.e103675}}, volume = {{9}}, year = {{2023}}, } @proceedings{35062, editor = {{Meine, Sabine and Otto, Arnold and Süßmann, Johannes}}, isbn = {{978-3-8260-7218-5}}, publisher = {{Königshausen & Neumann}}, title = {{{Musiklandschaften zwischen Rhein und Weser. Pluralisierung und Verflechtung entlang des Hellwegs in der Frühen Neuzeit. Unter Mitarbeit v. Markus Lauert}}}, doi = {{https://doi.org/10.36202/9783826077920}}, volume = {{13}}, year = {{2023}}, } @article{43245, abstract = {{High-contrast slab waveguide Bragg gratings with 1D periodicity are investigated. For specific oblique excitation by semi-guided waves at sufficiently high angles of incidence, the idealized structures do not exhibit any radiative losses, such that reflectance and transmittance for the single port mode add strictly up to one. We consider a series of symmetric, fully and partly etched finite gratings, for parameters found in integrated silicon photonics. These can act as spectral filters with a reasonably flattop response. Apodization can lead to more box shaped reflectance and transmittance spectra. Together with a narrowband Fabry–Perot filter, these configurations are characterized by reflection bands, or transmittance peaks, with widths that span three orders of magnitude.}}, author = {{Hammer, Manfred and Farheen, Henna and Förstner, Jens}}, issn = {{0740-3224}}, journal = {{Journal of the Optical Society of America B}}, keywords = {{tet_topic_waveguide}}, number = {{4}}, pages = {{862}}, publisher = {{Optica Publishing Group}}, title = {{{How to suppress radiative losses in high-contrast integrated Bragg gratings}}}, doi = {{10.1364/josab.485725}}, volume = {{40}}, year = {{2023}}, } @unpublished{43132, author = {{Meier, Torsten and Grisard, S. and Trifonov, A.V. and Rose, Hendrik and Reichhardt, R. and Reichelt, Matthias and Schneider, C. and Kamp, M. and Höfling, S. and Bayer, M. and Akimov, I.A}}, booktitle = {{arxiv:2302.02480}}, title = {{{Temporal sorting of optical multi-wave-mixing processes in semiconductor quantum dots}}}, year = {{2023}}, } @article{44097, abstract = {{We present strong enhancement of third harmonic generation in an amorphous silicon metasurface consisting of elliptical nano resonators. We show that this enhancement originates from a new type of multi-mode Fano mechanism. These ‘Super-Fano’ resonances are investigated numerically in great detail using full-wave simulations. The theoretically predicted behavior of the metasurface is experimentally verified by linear and nonlinear transmission spectroscopy. Moreover, quantitative nonlinear measurements are performed, in which an absolute conversion efficiency as high as ηmax ≈ 2.8 × 10−7 a peak power intensity of 1.2 GW cm−2 is found. Compared to an unpatterned silicon film of the same thickness amplification factors of up to ~900 are demonstrated. Our results pave the way to exploiting a strong Fano-type multi-mode coupling in metasurfaces for high THG in potential applications.}}, author = {{Hähnel, David and Golla, Christian and Albert, Maximilian and Zentgraf, Thomas and Myroshnychenko, Viktor and Förstner, Jens and Meier, Cedrik}}, issn = {{2047-7538}}, journal = {{Light: Science & Applications}}, keywords = {{tet_topic_meta}}, number = {{1}}, pages = {{97}}, publisher = {{Springer Nature}}, title = {{{A multi-mode super-fano mechanism for enhanced third harmonic generation in silicon metasurfaces}}}, doi = {{https://doi.org/10.1038/s41377-023-01134-1}}, volume = {{12}}, year = {{2023}}, } @book{44083, author = {{Bauer, Anna Brigitte}}, isbn = {{978-3-8325-5625-9}}, publisher = {{Logos Verlag Berlin GmbH}}, title = {{{Experimentelle Kompetenz Physikstudierender. Entwicklung und erste Erprobung eines performanzorientierten Kompetenzstrukturmodells unter Nutzung qualitativer Methoden}}}, doi = {{10.30819/5625}}, volume = {{352}}, year = {{2023}}, } @misc{43374, author = {{Schürmann, Patrick}}, title = {{{ A Formal Comparison of Advanced Digital Signature Primitives}}}, year = {{2023}}, } @article{42515, abstract = {{ Microcellular wood fiber reinforced polymers offer the possibility to reduce the use of fossil raw materials. In particular, thick-walled structures with thicknesses greater than 6 mm offer a high potential for weight savings. This study investigates the cell structures and mechanical properties of injection-molded test specimens. The influence of different thicknesses (6–10 mm) along with different chemical blowing agents (endothermic, exothermic) with varying dosages (0–2 wt%) is analyzed. The investigations reveal that exothermic chemical blowing agents form finer cells consistently to thin-walled structures than endothermic ones. Higher foaming agent content leads to higher pore fractions, with many small cells coalescing into a large open-pore cell network. The mechanical properties depend mainly on the pore content of the sample. The specific tensile properties deteriorate with the use of chemical blowing agents (CFA), whereas the sandwich structure produced with compact edge layers has a positive influence on the specific flexural properties. }}, author = {{Moritzer, Elmar and Flachmann, Felix}}, issn = {{0021-955X}}, journal = {{Journal of Cellular Plastics}}, keywords = {{Materials Chemistry, Polymers and Plastics, General Chemistry}}, number = {{3}}, pages = {{187--199}}, publisher = {{SAGE Publications}}, title = {{{Morphological and mechanical properties of foamed thick-walled Wood-Plastic-Composite structures}}}, doi = {{10.1177/0021955x231161175}}, volume = {{59}}, year = {{2023}}, } @article{42179, author = {{Burmeister, Sascha Christian and Schryen, Guido}}, journal = {{Energy Systems}}, publisher = {{Springer}}, title = {{{Distribution Network Optimization: Predicting computation times to design scenario analysis for network operators}}}, doi = {{10.1007/s12667-023-00572-5}}, year = {{2023}}, } @article{43034, abstract = {{Abstract The accessibility to rheological parameters for concrete is becoming more and more relevant. This is mainly related to the constantly emerging challenges, such as not only the development of high-strength concretes is progressing very fast but also the simulation of the flow behaviour is of high importance. The main problem, however, is that the rheological characterisation of fresh concrete is not possible via commercial rheometers. The so-called concrete rheometers provide valuable relative values for comparing different concretes, but they cannot measure absolute values. Therefore, we developed an adaptive coaxial concrete rheometer (ACCR) that allows the measurement of fresh concrete with particles up to d max = 5.5 mm {d}_{{\rm{\max }}}=5.5\hspace{.5em}{\rm{mm}} . The comparison of the ACCR with a commercial rheometer showed very good agreement for selected test materials (Newtonian fluid, shear thinning fluid, suspension, and yield stress fluid), so that self-compacting concrete was subsequently measured. Since these measurements showed a very high reproducibility, the rheological properties of the fresh concrete could be determined with high accuracy. The common flow models (Bingham (B), Herschel–Bulkley, modified Bingham (MB) models) were also tested for their applicability, with the Bingham and the modified Bingham model proving to be the best suitable ones.}}, author = {{Josch, Sebastian and Jesinghausen, Steffen and Schmid, Hans-Joachim}}, issn = {{1617-8106}}, journal = {{Applied Rheology}}, keywords = {{Condensed Matter Physics, General Materials Science}}, number = {{1}}, publisher = {{Walter de Gruyter GmbH}}, title = {{{Development of an adaptive coaxial concrete rheometer and rheological characterisation of fresh concrete}}}, doi = {{10.1515/arh-2022-0140}}, volume = {{33}}, year = {{2023}}, } @inbook{44249, abstract = {{State education in honest tax payment can be understood as a facet of training in citizenship, i.e. as an attempt by the modern state to standardize the behavior of its citizens and to prevent deviations. Based on this Foucauldian understanding, this exploratory article examines tax education in the United States, Spain, and West Germany from the mid-1940s to the late 1980s. During this period, the USA asserted itself as the champion of tax education and Spain consistently tried to emulate this example, albeit with more modest means and different semantic strategies from as early as the 1960s, when it was still under a autoritarian regime. The FRG, however, completely discontinued its few early attempts at tax education from the mid-1950s onwards. Even during the economic crises and tax scandals of the 1970s, there was no relaunch of the programs. The article locates the reasons for this highly uneven development in the different ideal images of the citizen in the three states.}}, author = {{Schönhärl, Korinna and Düll, Nasrin and Ramírez Lugo , Nadya Melina}}, booktitle = {{Tax Evasion and Tax Havens since the Nineteenth Century }}, editor = {{Sébastien, Guex and Hadrien, Buclin}}, pages = {{355--376}}, publisher = {{Springer}}, title = {{{Tax Education After WWII: How Spain, the USA, and West Germany Tried to Make Their Citizens Pay Honestly}}}, year = {{2023}}, } @article{44321, author = {{Neumann, Phillip}}, issn = {{0513-9066}}, journal = {{Zeitschrift für Heilpädagogik}}, keywords = {{Inklusion, Sonderpädagogik, Bildung, Bildungsstudien, Integration}}, number = {{5}}, pages = {{230--232}}, title = {{{Studien zu Schulleistungen und ihre Aufbereitung}}}, volume = {{74}}, year = {{2023}}, } @inbook{35063, author = {{Meine, Sabine and Otto, Arnold and Süßmann, Johannes}}, booktitle = {{Musiklandschaften zwischen Rhein und Weser. Pluralisierung und Verflechtung entlang des Hellwegs in der Frühen Neuzeit. Unter Mitarbeit v. Markus Lauert}}, isbn = {{978-3-8260-7218-5}}, pages = {{7–42}}, publisher = {{Königshausen & Neumann}}, title = {{{Musiklandschaften zwischen Rhein und Weser – Einführung}}}, doi = {{https://doi.org/10.36202/9783826077920}}, year = {{2023}}, } @inproceedings{20841, author = {{Gharibian, Sevag and Watson, James and Bausch, Johannes}}, booktitle = {{Proceedings of the 40th International Symposium on Theoretical Aspects of Computer Science (STACS)}}, pages = {{54:1--54:21}}, title = {{{The Complexity of Translationally Invariant Problems beyond Ground State Energies}}}, doi = {{https://doi.org/10.4230/LIPIcs.STACS.2023.54}}, volume = {{254}}, year = {{2023}}, } @unpublished{44512, abstract = {{For open world applications, deep neural networks (DNNs) need to be aware of previously unseen data and adaptable to evolving environments. Furthermore, it is desirable to detect and learn novel classes which are not included in the DNNs underlying set of semantic classes in an unsupervised fashion. The method proposed in this article builds upon anomaly detection to retrieve out-of-distribution (OoD) data as candidates for new classes. We thereafter extend the DNN by $k$ empty classes and fine-tune it on the OoD data samples. To this end, we introduce two loss functions, which 1) entice the DNN to assign OoD samples to the empty classes and 2) to minimize the inner-class feature distances between them. Thus, instead of ground truth which contains labels for the different novel classes, the DNN obtains a single OoD label together with a distance matrix, which is computed in advance. We perform several experiments for image classification and semantic segmentation, which demonstrate that a DNN can extend its own semantic space by multiple classes without having access to ground truth.}}, author = {{Uhlemeyer, Svenja and Lienen, Julian and Hüllermeier, Eyke and Gottschalk, Hanno}}, booktitle = {{arXiv:2305.00983}}, title = {{{Detecting Novelties with Empty Classes}}}, year = {{2023}}, } @article{44672, abstract = {{With enhancing digitalization, condition monitoring is used in an increasing number of application fields across various industrial sectors. By its application, increased reliability as well as reduced risks and costs can be achieved. Based on different approaches, technical systems are monitored and measured data is analyzed to enable condition-based or predictive maintenance. To this end, machine learning approaches are usually implemented to diagnose the health states or predict the health index of the monitored system. However, these trained models are often black-box models, not intuitively explainable for a human. To overcome this shortcoming, a model-based approach based on physics is developed for piezoelectric bending actuators. Such a model enables a transparent representation of the system. Moreover, the model-based approach is extended by a parameter-estimation to account for sudden changes in behavior e. g. caused by occurring cracks.}}, author = {{Bender, Amelie}}, issn = {{0924-4247}}, journal = {{Sensors and Actuators A: Physical}}, keywords = {{Condition Monitoring, Model-based approach Diagnostics, Varying conditions, Explainability, Piezoelectric bending actuators}}, publisher = {{Elsevier BV}}, title = {{{Model-based condition monitoring of piezoelectric bending actuators}}}, doi = {{10.1016/j.sna.2023.114399}}, volume = {{357}}, year = {{2023}}, } @inproceedings{44194, author = {{Ahmed, Qazi Arbab and Awais, Muhammad and Platzner, Marco}}, booktitle = {{The 24th International Symposium on Quality Electronic Design (ISQED'23), San Francisco, Califorina USA}}, location = {{San Fransico CA 94023-0607, USA}}, title = {{{MAAS: Hiding Trojans in Approximate Circuits}}}, year = {{2023}}, } @article{44044, abstract = {{Dispersion is present in every optical setup and is often an undesired effect, especially in nonlinear-optical experiments where ultrashort laser pulses are needed. Typically, bulky pulse compressors consisting of gratings or prisms are used to address this issue by precompensating the dispersion of the optical components. However, these devices are only able to compensate for a part of the dispersion (second-order dispersion). Here, we present a compact pulse-shaping device that uses plasmonic metasurfaces to apply an arbitrarily designed spectral phase delay allowing for a full dispersion control. Furthermore, with specific phase encodings, this device can be used to temporally reshape the incident laser pulses into more complex pulse forms such as a double pulse. We verify the performance of our device by using an SHG-FROG measurement setup together with a retrieval algorithm to extract the dispersion that our device applies to an incident laser pulse.}}, author = {{Geromel, René and Georgi, Philip and Protte, Maximilian and Lei, Shiwei and Bartley, Tim and Huang, Lingling and Zentgraf, Thomas}}, issn = {{1530-6984}}, journal = {{Nano Letters}}, keywords = {{Mechanical Engineering, Condensed Matter Physics, General Materials Science, General Chemistry, Bioengineering}}, number = {{8}}, pages = {{3196 -- 3201}}, publisher = {{American Chemical Society (ACS)}}, title = {{{Compact Metasurface-Based Optical Pulse-Shaping Device}}}, doi = {{10.1021/acs.nanolett.2c04980}}, volume = {{23}}, year = {{2023}}, } @article{44837, abstract = {{Hydrothermal carbonization (HTC) is an efficient thermochemical method for the conversion of organic feedstock to carbonaceous solids. HTC of different saccharides is known to produce microspheres (MS) with mostly Gaussian size distribution, which are utilized as functional materials in various applications, both as pristine MS and as a precursor for hard carbon MS. Although the average size of the MS can be influenced by adjusting the process parameters, there is no reliable mechanism to affect their size distribution. Our results demonstrate that HTC of trehalose, in contrast to other saccharides, results in a distinctly bimodal sphere diameter distribution consisting of small spheres with diameters of (2.1 ± 0.2) μm and of large spheres with diameters of (10.4 ± 2.6) μm. Remarkably, after pyrolytic post-carbonization at 1000 °C the MS develop a multimodal pore size distribution with abundant macropores > 100 nm, mesopores > 10 nm and micropores < 2 nm, which were examined by small-angle X-ray scattering and visualized by charge-compensated helium ion microscopy. The bimodal size distribution and hierarchical porosity provide an extraordinary set of properties and potential variables for the tailored synthesis of hierarchical porous carbons, making trehalose-derived hard carbon MS a highly promising material for applications in catalysis, filtration, and energy storage devices.}}, author = {{Wortmann, Martin and Keil, Waldemar and Diestelhorst, Elise and Westphal, Michael and Haverkamp, René and Brockhagen, Bennet and Biedinger, Jan and Bondzio, Laila and Weinberger, Christian and Baier, Dominik and Tiemann, Michael and Hütten, Andreas and Hellweg, Thomas and Reiss, Günter and Schmidt, Claudia and Sattler, Klaus and Frese, Natalie}}, issn = {{2046-2069}}, journal = {{RSC Advances}}, keywords = {{General Chemical Engineering, General Chemistry}}, number = {{21}}, pages = {{14181--14189}}, publisher = {{Royal Society of Chemistry (RSC)}}, title = {{{Hard carbon microspheres with bimodal size distribution and hierarchical porosity via hydrothermal carbonization of trehalose}}}, doi = {{10.1039/d3ra01301d}}, volume = {{13}}, year = {{2023}}, } @inproceedings{45205, author = {{Dreiling, Dmitrij and Itner, Dominik and Hetkämper, Tim and Birk, Carolin and Gravenkamp, Hauke and Henning, Bernd}}, booktitle = {{SMSI 2023 Conference}}, isbn = {{978-3-9819376-8-8}}, location = {{Nürnberg}}, pages = {{394 -- 395}}, publisher = {{AMA Association For Sensors And Measurement}}, title = {{{Improved determination of viscoelastic material parameters using a pulse-echo measurement setup}}}, doi = {{10.5162/SMSI2023/P59}}, year = {{2023}}, }