[{"_id":"62166","user_id":"48411","department":[{"_id":"9"},{"_id":"158"},{"_id":"321"}],"article_number":"131758","language":[{"iso":"eng"}],"type":"journal_article","publication":"Materials Chemistry and Physics","status":"public","publisher":"Elsevier BV","date_updated":"2025-11-12T07:34:26Z","date_created":"2025-11-12T07:33:04Z","author":[{"last_name":"Prüßner","full_name":"Prüßner, Tim","first_name":"Tim"},{"id":"48411","full_name":"Hoyer, Kay-Peter","last_name":"Hoyer","first_name":"Kay-Peter"},{"first_name":"Nadine","id":"1449","full_name":"Buitkamp, Nadine","last_name":"Buitkamp"},{"last_name":"Vieth","full_name":"Vieth, Pascal","first_name":"Pascal"},{"id":"194","full_name":"Grundmeier, Guido","last_name":"Grundmeier","first_name":"Guido"}],"volume":349,"title":"Surface functionalisation of additively manufactured AlSi10Mg by organophosphonic acid and PDMS grafting","doi":"10.1016/j.matchemphys.2025.131758","publication_status":"published","publication_identifier":{"issn":["0254-0584"]},"quality_controlled":"1","year":"2025","citation":{"ama":"Prüßner T, Hoyer K-P, Buitkamp N, Vieth P, Grundmeier G. Surface functionalisation of additively manufactured AlSi10Mg by organophosphonic acid and PDMS grafting. <i>Materials Chemistry and Physics</i>. 2025;349. doi:<a href=\"https://doi.org/10.1016/j.matchemphys.2025.131758\">10.1016/j.matchemphys.2025.131758</a>","chicago":"Prüßner, Tim, Kay-Peter Hoyer, Nadine Buitkamp, Pascal Vieth, and Guido Grundmeier. “Surface Functionalisation of Additively Manufactured AlSi10Mg by Organophosphonic Acid and PDMS Grafting.” <i>Materials Chemistry and Physics</i> 349 (2025). <a href=\"https://doi.org/10.1016/j.matchemphys.2025.131758\">https://doi.org/10.1016/j.matchemphys.2025.131758</a>.","ieee":"T. Prüßner, K.-P. Hoyer, N. Buitkamp, P. Vieth, and G. Grundmeier, “Surface functionalisation of additively manufactured AlSi10Mg by organophosphonic acid and PDMS grafting,” <i>Materials Chemistry and Physics</i>, vol. 349, Art. no. 131758, 2025, doi: <a href=\"https://doi.org/10.1016/j.matchemphys.2025.131758\">10.1016/j.matchemphys.2025.131758</a>.","bibtex":"@article{Prüßner_Hoyer_Buitkamp_Vieth_Grundmeier_2025, title={Surface functionalisation of additively manufactured AlSi10Mg by organophosphonic acid and PDMS grafting}, volume={349}, DOI={<a href=\"https://doi.org/10.1016/j.matchemphys.2025.131758\">10.1016/j.matchemphys.2025.131758</a>}, number={131758}, journal={Materials Chemistry and Physics}, publisher={Elsevier BV}, author={Prüßner, Tim and Hoyer, Kay-Peter and Buitkamp, Nadine and Vieth, Pascal and Grundmeier, Guido}, year={2025} }","mla":"Prüßner, Tim, et al. “Surface Functionalisation of Additively Manufactured AlSi10Mg by Organophosphonic Acid and PDMS Grafting.” <i>Materials Chemistry and Physics</i>, vol. 349, 131758, Elsevier BV, 2025, doi:<a href=\"https://doi.org/10.1016/j.matchemphys.2025.131758\">10.1016/j.matchemphys.2025.131758</a>.","short":"T. Prüßner, K.-P. Hoyer, N. Buitkamp, P. Vieth, G. Grundmeier, Materials Chemistry and Physics 349 (2025).","apa":"Prüßner, T., Hoyer, K.-P., Buitkamp, N., Vieth, P., &#38; Grundmeier, G. (2025). Surface functionalisation of additively manufactured AlSi10Mg by organophosphonic acid and PDMS grafting. <i>Materials Chemistry and Physics</i>, <i>349</i>, Article 131758. <a href=\"https://doi.org/10.1016/j.matchemphys.2025.131758\">https://doi.org/10.1016/j.matchemphys.2025.131758</a>"},"intvolume":"       349"},{"type":"journal_article","status":"public","department":[{"_id":"35"},{"_id":"302"},{"_id":"321"}],"user_id":"7266","_id":"20945","isi":"1","publication_identifier":{"issn":["0169-4332"],"eissn":["1873-5584"]},"publication_status":"published","intvolume":"       290","page":"207-214","citation":{"apa":"Ebbert, C., Grundmeier, G., Buitkamp, N., Kroeger, A., Messerschmidt, F., &#38; Thissen, P. (2014). Toward a microscopic understanding of the calcium-silicate-hydrates/water interface. <i>APPLIED SURFACE SCIENCE</i>, <i>290</i>, 207–214. <a href=\"https://doi.org/10.1016/j.apsusc.2013.11.045\">https://doi.org/10.1016/j.apsusc.2013.11.045</a>","bibtex":"@article{Ebbert_Grundmeier_Buitkamp_Kroeger_Messerschmidt_Thissen_2014, title={Toward a microscopic understanding of the calcium-silicate-hydrates/water interface}, volume={290}, DOI={<a href=\"https://doi.org/10.1016/j.apsusc.2013.11.045\">10.1016/j.apsusc.2013.11.045</a>}, journal={APPLIED SURFACE SCIENCE}, author={Ebbert, Christoph and Grundmeier, Guido and Buitkamp, Nadine and Kroeger, Alexander and Messerschmidt, Florian and Thissen, Peter}, year={2014}, pages={207–214} }","mla":"Ebbert, Christoph, et al. “Toward a Microscopic Understanding of the Calcium-Silicate-Hydrates/Water Interface.” <i>APPLIED SURFACE SCIENCE</i>, vol. 290, 2014, pp. 207–14, doi:<a href=\"https://doi.org/10.1016/j.apsusc.2013.11.045\">10.1016/j.apsusc.2013.11.045</a>.","short":"C. Ebbert, G. Grundmeier, N. Buitkamp, A. Kroeger, F. Messerschmidt, P. Thissen, APPLIED SURFACE SCIENCE 290 (2014) 207–214.","ieee":"C. Ebbert, G. Grundmeier, N. Buitkamp, A. Kroeger, F. Messerschmidt, and P. Thissen, “Toward a microscopic understanding of the calcium-silicate-hydrates/water interface,” <i>APPLIED SURFACE SCIENCE</i>, vol. 290, pp. 207–214, 2014, doi: <a href=\"https://doi.org/10.1016/j.apsusc.2013.11.045\">10.1016/j.apsusc.2013.11.045</a>.","chicago":"Ebbert, Christoph, Guido Grundmeier, Nadine Buitkamp, Alexander Kroeger, Florian Messerschmidt, and Peter Thissen. “Toward a Microscopic Understanding of the Calcium-Silicate-Hydrates/Water Interface.” <i>APPLIED SURFACE SCIENCE</i> 290 (2014): 207–14. <a href=\"https://doi.org/10.1016/j.apsusc.2013.11.045\">https://doi.org/10.1016/j.apsusc.2013.11.045</a>.","ama":"Ebbert C, Grundmeier G, Buitkamp N, Kroeger A, Messerschmidt F, Thissen P. Toward a microscopic understanding of the calcium-silicate-hydrates/water interface. <i>APPLIED SURFACE SCIENCE</i>. 2014;290:207-214. doi:<a href=\"https://doi.org/10.1016/j.apsusc.2013.11.045\">10.1016/j.apsusc.2013.11.045</a>"},"volume":290,"author":[{"first_name":"Christoph","last_name":"Ebbert","id":"7266","full_name":"Ebbert, Christoph"},{"first_name":"Guido","last_name":"Grundmeier","full_name":"Grundmeier, Guido","id":"194"},{"last_name":"Buitkamp","id":"1449","full_name":"Buitkamp, Nadine","first_name":"Nadine"},{"first_name":"Alexander","last_name":"Kroeger","full_name":"Kroeger, Alexander"},{"last_name":"Messerschmidt","full_name":"Messerschmidt, Florian","first_name":"Florian"},{"first_name":"Peter","full_name":"Thissen, Peter","last_name":"Thissen"}],"date_updated":"2025-11-18T12:05:39Z","doi":"10.1016/j.apsusc.2013.11.045","publication":"APPLIED SURFACE SCIENCE","abstract":[{"lang":"eng","text":"Calcium-Silicate-Hydrates (C-S-H) are the main binding phases in most concrete which is the primarily used composite construction material in the world. However, a big lack is cleaving between the actual knowledge about C-S-H, compared to what could be reached using state-of-the-art technologies of modern research. In this article, the formation of a C-S-H phase on a native oxide covered silicon wafer is investigated by means of in-situ attenuated total reflection infrared (ATR-IR) and ex-situ surface-enhanced Raman spectroscopy (SERS). The total thickness of the C-S-H phase is determined by X-ray photoelectron spectroscopy (XPS) to be 3 nm. The formation appears to be reversible depending on the environment pH value and can be performed at room temperature. Based on density functional theory (DFT) calculations, it is shown that the C-S-H phase in the presence of water will change its chemical composition in order to reach the thermodynamic ground state of the system. This change is achieved by a metal-proton exchange reaction. The stoichiometry of these metal-proton exchange reactions is nearly independent of the environment pH value. Electrokinetic measurements yield isoelectric points of 2.0 and 2.6 for the native oxide covered silicon wafer (SiO2) and the C-S-H phase. This is consistent with a predominance of Si-O sites at the C-S-H/water interface. (C) 2013 Elsevier B. V. All rights reserved."}],"external_id":{"isi":["000329060100032"]},"language":[{"iso":"eng"}],"quality_controlled":"1","year":"2014","date_created":"2021-01-13T10:12:51Z","title":"Toward a microscopic understanding of the calcium-silicate-hydrates/water interface"}]