---
_id: '60815'
abstract:
- lang: eng
text: AbstractThe increasing demand for advanced
sensing technologies drives the development of chemical sensors using innovative
materials. In gas sensing, optical sensors are often used to detect gases such
as CO, NOx, and O2.
Oxygen sensors typically incorporate dyes into oxygen‐permeable matrices like
polymers, silica, or zeolites. Alternatively, semiconductor surface chemistry
can enable O2 detection. However, these approaches are often
limited by slow response and recovery times and low selectivity, restricting their
practical applications. The metal‐organic framework MOF‐76(Eu) and its yttrium‐modified
variant, MOF‐76(Eu/Y) are reported to exhibit highly reversible and fast optical
responses to varying O2 concentrations. Time‐resolved emission
measurements are performed over short (seconds) and long (hours) timescales using
N2 and synthetic air mixtures. Cross‐sensitivity to humidity
is analyzed. Multichannel scaling photon‐counting experiments confirm quenching
at the linker level, as the emission lifetime remains nearly constant. Yttrium
significantly improves stability and performance at room temperature. Structural
and optical changes induced by yttrium are investigated. Additionally, MIL‐78(Eu),
another Eu‐BTC‐based MOF with a different coordination environment, is synthesized.
Unlike MOF‐76(Eu), MIL‐78(Eu) exhibits distinct optical properties but lacks a
reversible response to O2. These results highlight the potential
of MOF‐76‐based materials for high‐performance O2 sensing.
article_number: e11190
article_type: original
author:
- first_name: Zhenyu
full_name: Zhao, Zhenyu
last_name: Zhao
- first_name: Christian
full_name: Weinberger, Christian
id: '11848'
last_name: Weinberger
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Martin
full_name: Brehm, Martin
id: '100167'
last_name: Brehm
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
citation:
ama: Zhao Z, Weinberger C, Steube J, Bauer M, Brehm M, Tiemann M. Fast‐Responding
O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks
(MOF‐76). Advanced Functional Materials. Published online 2025. doi:10.1002/adfm.202511190
apa: Zhao, Z., Weinberger, C., Steube, J., Bauer, M., Brehm, M., & Tiemann,
M. (2025). Fast‐Responding O2 Gas Sensor Based on Luminescent Europium
Metal‐Organic Frameworks (MOF‐76). Advanced Functional Materials, Article
e11190. https://doi.org/10.1002/adfm.202511190
bibtex: '@article{Zhao_Weinberger_Steube_Bauer_Brehm_Tiemann_2025, title={Fast‐Responding
O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks
(MOF‐76)}, DOI={10.1002/adfm.202511190},
number={e11190}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Zhao,
Zhenyu and Weinberger, Christian and Steube, Jakob and Bauer, Matthias and Brehm,
Martin and Tiemann, Michael}, year={2025} }'
chicago: Zhao, Zhenyu, Christian Weinberger, Jakob Steube, Matthias Bauer, Martin
Brehm, and Michael Tiemann. “Fast‐Responding O2 Gas Sensor Based on
Luminescent Europium Metal‐Organic Frameworks (MOF‐76).” Advanced Functional
Materials, 2025. https://doi.org/10.1002/adfm.202511190.
ieee: 'Z. Zhao, C. Weinberger, J. Steube, M. Bauer, M. Brehm, and M. Tiemann, “Fast‐Responding
O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks
(MOF‐76),” Advanced Functional Materials, Art. no. e11190, 2025, doi: 10.1002/adfm.202511190.'
mla: Zhao, Zhenyu, et al. “Fast‐Responding O2 Gas Sensor Based on Luminescent
Europium Metal‐Organic Frameworks (MOF‐76).” Advanced Functional Materials,
e11190, Wiley, 2025, doi:10.1002/adfm.202511190.
short: Z. Zhao, C. Weinberger, J. Steube, M. Bauer, M. Brehm, M. Tiemann, Advanced
Functional Materials (2025).
date_created: 2025-07-29T06:59:19Z
date_updated: 2025-07-29T07:02:22Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1002/adfm.202511190
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
publication: Advanced Functional Materials
publication_identifier:
issn:
- 1616-301X
- 1616-3028
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic
Frameworks (MOF‐76)
type: journal_article
user_id: '23547'
year: '2025'
...
---
_id: '60600'
abstract:
- lang: eng
text: In the search for noble metal free photocatalytic systems, iron is the dream
candidate. To increase excited state lifetimes of iron complexes, the multichromophoric
approach is promising, combining organic chromophores with photoactive iron complexes,
potentially enabling a reservoir effect. We present a series of chromophore-functionalized
complexes based on the parental FeIII complex [Fe(ImP)2][PF6] (HImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene)).
The four organic chromophores benzene, naphthalene, anthracene, and pyrene are
attached to the ImP-ligand in para-position to the coordination site to systematically
investigate the influence of the steric demand and electronic properties of the
chromophore on charge transfer lifetimes as well as photodynamics. A thorough
ground state characterization was conducted in addition to investigations of the
excited state dynamics by transient absorption spectroscopy and streak camera
emission measurements. The conclusions drawn are supported by extensive DFT calculations.
The emission coefficients could be significantly improved by the addition of chromophores.
After excitation of the complexes with larger chromophores, coplanarization of
the backbone and complex motif occurs to stabilize the formal charge. This results
in population of a superligand state that exhibits a much faster radiationless
relaxation to the ground state compared to the parent complex, hindering a reservoir
effect.
article_number: acs.inorgchem.5c00526
author:
- first_name: Lennart
full_name: Schmitz, Lennart
id: '53140'
last_name: Schmitz
- first_name: Miguel A.
full_name: Argüello Cordero, Miguel A.
last_name: Argüello Cordero
- first_name: Mohammed J.
full_name: Al-Marri, Mohammed J.
last_name: Al-Marri
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Bastian Johannes
full_name: Bracht, Bastian Johannes
id: '86707'
last_name: Bracht
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Schmitz L, Argüello Cordero MA, Al-Marri MJ, et al. Chromophore Induced Effects
in Iron(III) Complexes. Inorganic Chemistry. Published online 2025. doi:10.1021/acs.inorgchem.5c00526
apa: Schmitz, L., Argüello Cordero, M. A., Al-Marri, M. J., Schoch, R., Egold, H.,
Neuba, A., Steube, J., Bracht, B. J., Bokareva, O. S., Lochbrunner, S., &
Bauer, M. (2025). Chromophore Induced Effects in Iron(III) Complexes. Inorganic
Chemistry, Article acs. inorgchem.5c00526. https://doi.org/10.1021/acs.inorgchem.5c00526
bibtex: '@article{Schmitz_Argüello Cordero_Al-Marri_Schoch_Egold_Neuba_Steube_Bracht_Bokareva_Lochbrunner_et
al._2025, title={Chromophore Induced Effects in Iron(III) Complexes}, DOI={10.1021/acs.inorgchem.5c00526},
number={acs. inorgchem.5c00526}, journal={Inorganic Chemistry}, publisher={American
Chemical Society (ACS)}, author={Schmitz, Lennart and Argüello Cordero, Miguel
A. and Al-Marri, Mohammed J. and Schoch, Roland and Egold, Hans and Neuba, Adam
and Steube, Jakob and Bracht, Bastian Johannes and Bokareva, Olga S. and Lochbrunner,
Stefan and et al.}, year={2025} }'
chicago: Schmitz, Lennart, Miguel A. Argüello Cordero, Mohammed J. Al-Marri, Roland
Schoch, Hans Egold, Adam Neuba, Jakob Steube, et al. “Chromophore Induced Effects
in Iron(III) Complexes.” Inorganic Chemistry, 2025. https://doi.org/10.1021/acs.inorgchem.5c00526.
ieee: 'L. Schmitz et al., “Chromophore Induced Effects in Iron(III) Complexes,”
Inorganic Chemistry, Art. no. acs. inorgchem.5c00526, 2025, doi: 10.1021/acs.inorgchem.5c00526.'
mla: Schmitz, Lennart, et al. “Chromophore Induced Effects in Iron(III) Complexes.”
Inorganic Chemistry, acs. inorgchem.5c00526, American Chemical Society
(ACS), 2025, doi:10.1021/acs.inorgchem.5c00526.
short: L. Schmitz, M.A. Argüello Cordero, M.J. Al-Marri, R. Schoch, H. Egold, A.
Neuba, J. Steube, B.J. Bracht, O.S. Bokareva, S. Lochbrunner, M. Bauer, Inorganic
Chemistry (2025).
date_created: 2025-07-14T08:49:25Z
date_updated: 2025-08-15T12:18:08Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.5c00526
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Chromophore Induced Effects in Iron(III) Complexes
type: journal_article
user_id: '48467'
year: '2025'
...
---
_id: '58180'
abstract:
- lang: eng
text: 'A series of CoIII complexes [Co(RImP)2][PF6], with HMeImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene))
and R = Me, Et, iPr, nBu, is presented in this work. The influence of the strong
donor ligand on the ground and excited-state photophysical properties was investigated
in the context of different alkyl substituents at the imidazole nitrogen. X-ray
diffraction revealed no significant alterations of the structures and all differences
in the series emerge from the electronic structures. These were probed via cyclic
voltammetry and UV–vis spectroscopy, detailing the influence of the different
alkyl substituents on the ground-state properties. All complexes are emissive
at 77 K from a 3MC state, which exhibits lifetimes in the range of 1–5 ns at room
temperature, depending on the alkyl substituent. Therefore, it is clearly shown
that even small differences in the electronic structure have a large impact on
the details of the excited state landscape. The observed behavior was rationalized
by a detailed DFT analysis, which shows that the minimum-energy crossing point
to the ground-state is located only slightly above the MC energy: Consequently,
nonradiative decay to the ground state at room temperature is enabled, while at
77 K this path is prohibited, leading to low-temperature 3MC emission.'
author:
- first_name: Athul
full_name: Krishna, Athul
last_name: Krishna
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Miguel A.
full_name: Argüello Cordero, Miguel A.
last_name: Argüello Cordero
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Krishna A, Fritsch L, Steube J, et al. Low Temperature Emissive Cyclometalated
Cobalt(III) Complexes. Inorganic Chemistry. Published online 2025. doi:10.1021/acs.inorgchem.4c04479
apa: Krishna, A., Fritsch, L., Steube, J., Argüello Cordero, M. A., Schoch, R.,
Neuba, A., Lochbrunner, S., & Bauer, M. (2025). Low Temperature Emissive Cyclometalated
Cobalt(III) Complexes. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.4c04479
bibtex: '@article{Krishna_Fritsch_Steube_Argüello Cordero_Schoch_Neuba_Lochbrunner_Bauer_2025,
title={Low Temperature Emissive Cyclometalated Cobalt(III) Complexes}, DOI={10.1021/acs.inorgchem.4c04479},
journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Krishna,
Athul and Fritsch, Lorena and Steube, Jakob and Argüello Cordero, Miguel A. and
Schoch, Roland and Neuba, Adam and Lochbrunner, Stefan and Bauer, Matthias}, year={2025}
}'
chicago: Krishna, Athul, Lorena Fritsch, Jakob Steube, Miguel A. Argüello Cordero,
Roland Schoch, Adam Neuba, Stefan Lochbrunner, and Matthias Bauer. “Low Temperature
Emissive Cyclometalated Cobalt(III) Complexes.” Inorganic Chemistry, 2025.
https://doi.org/10.1021/acs.inorgchem.4c04479.
ieee: 'A. Krishna et al., “Low Temperature Emissive Cyclometalated Cobalt(III)
Complexes,” Inorganic Chemistry, 2025, doi: 10.1021/acs.inorgchem.4c04479.'
mla: Krishna, Athul, et al. “Low Temperature Emissive Cyclometalated Cobalt(III)
Complexes.” Inorganic Chemistry, American Chemical Society (ACS), 2025,
doi:10.1021/acs.inorgchem.4c04479.
short: A. Krishna, L. Fritsch, J. Steube, M.A. Argüello Cordero, R. Schoch, A. Neuba,
S. Lochbrunner, M. Bauer, Inorganic Chemistry (2025).
date_created: 2025-01-15T08:29:21Z
date_updated: 2025-08-15T12:30:18Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.4c04479
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Low Temperature Emissive Cyclometalated Cobalt(III) Complexes
type: journal_article
user_id: '48467'
year: '2025'
...
---
_id: '62816'
abstract:
- lang: eng
text: The increasing demand for advanced sensing technologies drives the development
of chemical sensors using innovative materials. In gas sensing, optical sensors
are often used to detect gases such as CO, NOx, and O2. Oxygen sensors typically
incorporate dyes into oxygen-permeable matrices like polymers, silica, or zeolites.
Alternatively, semiconductor surface chemistry can enable O2 detection. However,
these approaches are often limited by slow response and recovery times and low
selectivity, restricting their practical applications. The metal-organic framework
MOF-76(Eu) and its yttrium-modified variant, MOF-76(Eu/Y) are reported to exhibit
highly reversible and fast optical responses to varying O2 concentrations. Time-resolved
emission measurements are performed over short (seconds) and long (hours) timescales
using N2 and synthetic air mixtures. Cross-sensitivity to humidity is analyzed.
Multichannel scaling photon-counting experiments confirm quenching at the linker
level, as the emission lifetime remains nearly constant. Yttrium significantly
improves stability and performance at room temperature. Structural and optical
changes induced by yttrium are investigated. Additionally, MIL-78(Eu), another
Eu-BTC-based MOF with a different coordination environment, is synthesized. Unlike
MOF-76(Eu), MIL-78(Eu) exhibits distinct optical properties but lacks a reversible
response to O2. These results highlight the potential of MOF-76-based materials
for high-performance O2 sensing.
article_number: e11190
author:
- first_name: Zhenyu
full_name: Zhao, Zhenyu
last_name: Zhao
- first_name: Christian
full_name: Weinberger, Christian
id: '11848'
last_name: Weinberger
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Martin
full_name: Brehm, Martin
id: '100167'
last_name: Brehm
- first_name: Michael
full_name: Tiemann, Michael
id: '23547'
last_name: Tiemann
orcid: 0000-0003-1711-2722
citation:
ama: Zhao Z, Weinberger C, Steube J, Bauer M, Brehm M, Tiemann M. Fast‐Responding
O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76).
Advanced Functional Materials. Published online 2025. doi:10.1002/adfm.202511190
apa: Zhao, Z., Weinberger, C., Steube, J., Bauer, M., Brehm, M., & Tiemann,
M. (2025). Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic
Frameworks (MOF‐76). Advanced Functional Materials, Article e11190. https://doi.org/10.1002/adfm.202511190
bibtex: '@article{Zhao_Weinberger_Steube_Bauer_Brehm_Tiemann_2025, title={Fast‐Responding
O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76)},
DOI={10.1002/adfm.202511190},
number={e11190}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Zhao,
Zhenyu and Weinberger, Christian and Steube, Jakob and Bauer, Matthias and Brehm,
Martin and Tiemann, Michael}, year={2025} }'
chicago: Zhao, Zhenyu, Christian Weinberger, Jakob Steube, Matthias Bauer, Martin
Brehm, and Michael Tiemann. “Fast‐Responding O2 Gas Sensor Based on Luminescent
Europium Metal‐Organic Frameworks (MOF‐76).” Advanced Functional Materials,
2025. https://doi.org/10.1002/adfm.202511190.
ieee: 'Z. Zhao, C. Weinberger, J. Steube, M. Bauer, M. Brehm, and M. Tiemann, “Fast‐Responding
O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks (MOF‐76),”
Advanced Functional Materials, Art. no. e11190, 2025, doi: 10.1002/adfm.202511190.'
mla: Zhao, Zhenyu, et al. “Fast‐Responding O2 Gas Sensor Based on Luminescent Europium
Metal‐Organic Frameworks (MOF‐76).” Advanced Functional Materials, e11190,
Wiley, 2025, doi:10.1002/adfm.202511190.
short: Z. Zhao, C. Weinberger, J. Steube, M. Bauer, M. Brehm, M. Tiemann, Advanced
Functional Materials (2025).
date_created: 2025-12-03T17:09:28Z
date_updated: 2025-12-03T17:11:15Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1002/adfm.202511190
language:
- iso: eng
main_file_link:
- open_access: '1'
oa: '1'
publication: Advanced Functional Materials
publication_identifier:
issn:
- 1616-301X
- 1616-3028
publication_status: published
publisher: Wiley
quality_controlled: '1'
status: public
title: Fast‐Responding O2 Gas Sensor Based on Luminescent Europium Metal‐Organic Frameworks
(MOF‐76)
type: journal_article
user_id: '23547'
year: '2025'
...
---
_id: '56075'
abstract:
- lang: eng
text: An isostructural series of FeII, FeIII, and Fe(IV)complexes [Fe(ImP)2]0/+/2+
utilizing the ImP 1,1′-(1,3-phenylene)-bis(3-methyl-1-imidazol-2-ylidene) ligand,
combining N-heterocy-clic carbenes and cyclometalating functions, is presented.
The strong donor motif stabilizes the high-valent Fe(IV) oxidation state yet keeps
the FeII oxidation state accessible from the parent Fe(III)compound. Chemical
oxidation of [Fe(ImP)2]+ yields stable [FeIV(ImP)2]2+. In contrast, [FeII(ImP)2]0,
obtained by reduction,is highly sensitive toward oxygen. Exhaustive ground state
characterization by single-crystal X-ray diffraction, 1H NMR,Mössbauer spectroscopy,
temperature-dependent magnetic measurements, a combination of X-ray absorption
near edge structureand valence-to-core, as well as core-to-core X-ray emission
spectroscopy, complemented by detailed density functional theory (DFT) analysis,
reveals that the three complexes[Fe(ImP)2]0/+/2+ can be unequivocally attributed
to low-spin d6, d5, and d4 complexes. The excited state landscape of the Fe(II)
and Fe(IV) complexes is characterized by short-lived 3MLCT and 3LMCT states, with
lifetimes of 5.1 and 1.4 ps, respectively. In the FeII-compound, an energetically
low-lying MC state leads to fast deactivation of the MLCT state. The distorted
square-pyramidal state, where one carbene is dissociated, can not only relax into
the ground state, but also into a singlet dissociated state. Its formation was
investigated with time-dependent optical spectroscopy, while insights into its
structure were gained by NMR spectroscopy.
author:
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Hossam
full_name: Elgabarty, Hossam
id: '60250'
last_name: Elgabarty
orcid: 0000-0002-4945-1481
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Mohammad
full_name: Alaraby, Mohammad
last_name: Alaraby
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Bastian Johannes
full_name: Bracht, Bastian Johannes
id: '86707'
last_name: Bracht
- first_name: Lennart
full_name: Schmitz, Lennart
id: '53140'
last_name: Schmitz
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Thomas D.
full_name: Kühne, Thomas D.
last_name: Kühne
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Steube J, Fritsch L, Kruse A, et al. Isostructural Series of a Cyclometalated
Iron Complex in Three Oxidation States. Inorganic Chemistry. Published
online 2024. doi:10.1021/acs.inorgchem.4c02576
apa: Steube, J., Fritsch, L., Kruse, A., Bokareva, O. S., Demeshko, S., Elgabarty,
H., Schoch, R., Alaraby, M., Egold, H., Bracht, B. J., Schmitz, L., Hohloch, S.,
Kühne, T. D., Meyer, F., Kühn, O., Lochbrunner, S., & Bauer, M. (2024). Isostructural
Series of a Cyclometalated Iron Complex in Three Oxidation States. Inorganic
Chemistry. https://doi.org/10.1021/acs.inorgchem.4c02576
bibtex: '@article{Steube_Fritsch_Kruse_Bokareva_Demeshko_Elgabarty_Schoch_Alaraby_Egold_Bracht_et
al._2024, title={Isostructural Series of a Cyclometalated Iron Complex in Three
Oxidation States}, DOI={10.1021/acs.inorgchem.4c02576},
journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Steube,
Jakob and Fritsch, Lorena and Kruse, Ayla and Bokareva, Olga S. and Demeshko,
Serhiy and Elgabarty, Hossam and Schoch, Roland and Alaraby, Mohammad and Egold,
Hans and Bracht, Bastian Johannes and et al.}, year={2024} }'
chicago: Steube, Jakob, Lorena Fritsch, Ayla Kruse, Olga S. Bokareva, Serhiy Demeshko,
Hossam Elgabarty, Roland Schoch, et al. “Isostructural Series of a Cyclometalated
Iron Complex in Three Oxidation States.” Inorganic Chemistry, 2024. https://doi.org/10.1021/acs.inorgchem.4c02576.
ieee: 'J. Steube et al., “Isostructural Series of a Cyclometalated Iron Complex
in Three Oxidation States,” Inorganic Chemistry, 2024, doi: 10.1021/acs.inorgchem.4c02576.'
mla: Steube, Jakob, et al. “Isostructural Series of a Cyclometalated Iron Complex
in Three Oxidation States.” Inorganic Chemistry, American Chemical Society
(ACS), 2024, doi:10.1021/acs.inorgchem.4c02576.
short: J. Steube, L. Fritsch, A. Kruse, O.S. Bokareva, S. Demeshko, H. Elgabarty,
R. Schoch, M. Alaraby, H. Egold, B.J. Bracht, L. Schmitz, S. Hohloch, T.D. Kühne,
F. Meyer, O. Kühn, S. Lochbrunner, M. Bauer, Inorganic Chemistry (2024).
date_created: 2024-09-05T11:34:20Z
date_updated: 2025-08-15T12:17:35Z
department:
- _id: '306'
doi: 10.1021/acs.inorgchem.4c02576
keyword:
- Photo
language:
- iso: eng
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
publisher: American Chemical Society (ACS)
status: public
title: Isostructural Series of a Cyclometalated Iron Complex in Three Oxidation States
type: journal_article
user_id: '48467'
year: '2024'
...
---
_id: '46481'
abstract:
- lang: eng
text: AbstractAlthough iron is a dream candidate
to substitute noble metals in photoactive complexes, realization of emissive and
photoactive iron compounds is demanding due to the fast deactivation of their
charge-transfer states. Emissive iron compounds are scarce and dual emission has
not been observed before. Here we report the FeIII complex
[Fe(ImP)2][PF6] (HImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene)),
showing a Janus-type dual emission from ligand-to-metal charge transfer (LMCT)-
and metal-to-ligand charge transfer (MLCT)-dominated states. This behaviour is
achieved by a ligand design that combines four N-heterocyclic
carbenes with two cyclometalating aryl units. The low-lying π*
levels of the cyclometalating units lead to energetically accessible MLCT states
that cannot evolve into LMCT states. With a lifetime of 4.6 ns, the strongly reducing
and oxidizing MLCT-dominated state can initiate electron transfer reactions, which
could constitute a basis for future applications of iron in photoredox catalysis.
author:
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Ayla
full_name: Kruse, Ayla
last_name: Kruse
- first_name: Olga S.
full_name: Bokareva, Olga S.
last_name: Bokareva
- first_name: Thomas
full_name: Reuter, Thomas
last_name: Reuter
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Miguel A.
full_name: Argüello Cordero, Miguel A.
last_name: Argüello Cordero
- first_name: Athul
full_name: Krishna, Athul
last_name: Krishna
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Steube J, Kruse A, Bokareva OS, et al. Janus-type emission from a cyclometalated
iron(iii) complex. Nature Chemistry. 2023;15(4):468-474. doi:10.1038/s41557-023-01137-w
apa: Steube, J., Kruse, A., Bokareva, O. S., Reuter, T., Demeshko, S., Schoch, R.,
Argüello Cordero, M. A., Krishna, A., Hohloch, S., Meyer, F., Heinze, K., Kühn,
O., Lochbrunner, S., & Bauer, M. (2023). Janus-type emission from a cyclometalated
iron(iii) complex. Nature Chemistry, 15(4), 468–474. https://doi.org/10.1038/s41557-023-01137-w
bibtex: '@article{Steube_Kruse_Bokareva_Reuter_Demeshko_Schoch_Argüello Cordero_Krishna_Hohloch_Meyer_et
al._2023, title={Janus-type emission from a cyclometalated iron(iii) complex},
volume={15}, DOI={10.1038/s41557-023-01137-w},
number={4}, journal={Nature Chemistry}, publisher={Springer Science and Business
Media LLC}, author={Steube, Jakob and Kruse, Ayla and Bokareva, Olga S. and Reuter,
Thomas and Demeshko, Serhiy and Schoch, Roland and Argüello Cordero, Miguel A.
and Krishna, Athul and Hohloch, Stephan and Meyer, Franc and et al.}, year={2023},
pages={468–474} }'
chicago: 'Steube, Jakob, Ayla Kruse, Olga S. Bokareva, Thomas Reuter, Serhiy Demeshko,
Roland Schoch, Miguel A. Argüello Cordero, et al. “Janus-Type Emission from a
Cyclometalated Iron(Iii) Complex.” Nature Chemistry 15, no. 4 (2023): 468–74.
https://doi.org/10.1038/s41557-023-01137-w.'
ieee: 'J. Steube et al., “Janus-type emission from a cyclometalated iron(iii)
complex,” Nature Chemistry, vol. 15, no. 4, pp. 468–474, 2023, doi: 10.1038/s41557-023-01137-w.'
mla: Steube, Jakob, et al. “Janus-Type Emission from a Cyclometalated Iron(Iii)
Complex.” Nature Chemistry, vol. 15, no. 4, Springer Science and Business
Media LLC, 2023, pp. 468–74, doi:10.1038/s41557-023-01137-w.
short: J. Steube, A. Kruse, O.S. Bokareva, T. Reuter, S. Demeshko, R. Schoch, M.A.
Argüello Cordero, A. Krishna, S. Hohloch, F. Meyer, K. Heinze, O. Kühn, S. Lochbrunner,
M. Bauer, Nature Chemistry 15 (2023) 468–474.
date_created: 2023-08-11T19:57:32Z
date_updated: 2024-09-05T11:44:07Z
department:
- _id: '306'
doi: 10.1038/s41557-023-01137-w
intvolume: ' 15'
issue: '4'
keyword:
- General Chemical Engineering
- General Chemistry
language:
- iso: eng
page: 468-474
publication: Nature Chemistry
publication_identifier:
issn:
- 1755-4330
- 1755-4349
publication_status: published
publisher: Springer Science and Business Media LLC
status: public
title: Janus-type emission from a cyclometalated iron(iii) complex
type: journal_article
user_id: '48467'
volume: 15
year: '2023'
...
---
_id: '46548'
abstract:
- lang: eng
text: The use of iron as a replacement for noble metals in photochemical
and photophysical applications is challenging due to the typically fast deactivation
of short-lived catalytically active states. Recent success of a cyclometalated
iron(III) complex utilizing a bis-tridentate ligand motif inspired the use of
phenyl-1H-pyrazole as a bidentate ligand. Five complexes using the tris(1-phenylpyrazolato-N,C2)iron(III)
complex scaffold are presented. In addition to the parent complex, four derivatives
with functionalization in the meta-position of the phenyl ring are thoroughly
investigated by single crystal diffractometry, UV-Vis-spectroscopy, and cyclic
voltammetry. Advanced X-ray spectroscopy in the form of X-ray absorption and emission
spectroscopy allows unique insights into the electronic structure as well as DFT
calculations. The ligand design leads to overlapping MLCT and LMCT absorption
bands, and emissive behavior is suppressed by low-lying MC states.
article_number: '282'
author:
- first_name: Tanja
full_name: Hirschhausen, Tanja
last_name: Hirschhausen
- first_name: Lorena
full_name: Fritsch, Lorena
id: '44418'
last_name: Fritsch
- first_name: Franziska
full_name: Lux, Franziska
last_name: Lux
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Hans
full_name: Egold, Hans
id: '101'
last_name: Egold
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Hirschhausen T, Fritsch L, Lux F, et al. Iron(III)-Complexes with N-Phenylpyrazole-Based
Ligands. Inorganics. 2023;11(7). doi:10.3390/inorganics11070282
apa: Hirschhausen, T., Fritsch, L., Lux, F., Steube, J., Schoch, R., Neuba, A.,
Egold, H., & Bauer, M. (2023). Iron(III)-Complexes with N-Phenylpyrazole-Based
Ligands. Inorganics, 11(7), Article 282. https://doi.org/10.3390/inorganics11070282
bibtex: '@article{Hirschhausen_Fritsch_Lux_Steube_Schoch_Neuba_Egold_Bauer_2023,
title={Iron(III)-Complexes with N-Phenylpyrazole-Based Ligands}, volume={11},
DOI={10.3390/inorganics11070282},
number={7282}, journal={Inorganics}, publisher={MDPI AG}, author={Hirschhausen,
Tanja and Fritsch, Lorena and Lux, Franziska and Steube, Jakob and Schoch, Roland
and Neuba, Adam and Egold, Hans and Bauer, Matthias}, year={2023} }'
chicago: Hirschhausen, Tanja, Lorena Fritsch, Franziska Lux, Jakob Steube, Roland
Schoch, Adam Neuba, Hans Egold, and Matthias Bauer. “Iron(III)-Complexes with
N-Phenylpyrazole-Based Ligands.” Inorganics 11, no. 7 (2023). https://doi.org/10.3390/inorganics11070282.
ieee: 'T. Hirschhausen et al., “Iron(III)-Complexes with N-Phenylpyrazole-Based
Ligands,” Inorganics, vol. 11, no. 7, Art. no. 282, 2023, doi: 10.3390/inorganics11070282.'
mla: Hirschhausen, Tanja, et al. “Iron(III)-Complexes with N-Phenylpyrazole-Based
Ligands.” Inorganics, vol. 11, no. 7, 282, MDPI AG, 2023, doi:10.3390/inorganics11070282.
short: T. Hirschhausen, L. Fritsch, F. Lux, J. Steube, R. Schoch, A. Neuba, H. Egold,
M. Bauer, Inorganics 11 (2023).
date_created: 2023-08-16T14:44:37Z
date_updated: 2025-08-15T12:54:21Z
doi: 10.3390/inorganics11070282
intvolume: ' 11'
issue: '7'
keyword:
- Photo
language:
- iso: eng
publication: Inorganics
publication_identifier:
issn:
- 2304-6740
publication_status: published
publisher: MDPI AG
status: public
title: Iron(III)-Complexes with N-Phenylpyrazole-Based Ligands
type: journal_article
user_id: '48467'
volume: 11
year: '2023'
...
---
_id: '40994'
abstract:
- lang: eng
text: Photoactive compounds are essential for photocatalytic and luminescent applications,
such as photoredox catalysis or light emitting diodes. However, the substitution
of noble metals, which are almost exclusively used, by base metals remains a major
challenge on the way to a more sustainable world.1 Iron is a dream candidate for
this ambitious aim.2 But compared to noble metal complexes that show long-lived
metal-to-ligand charge-transfer (MLCT) states, realization of emissive and photoactive
iron complexes is demanding, due to the fast deactivation of charge transfer states
into non-emissive inactive states. No MLCT emission has been observed for monometallic
iron complexes before. Consequently, dual emission could also not yet be realized
with iron complexes, as it is a very rare property even of noble metal compounds.
Here we report the FeIII complex [Fe(ImP)2][PF6]
(HImP = 1,1’-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene)), showing Janus-type
dual emission by combining LMCT (ligand-to-metal charge transfer) with MLCT luminescence.
The respective excited states are characterized by a record lifetime of τMLCT
= 4.2 ns, and a moderate τLMCT = 0.2 ns. Only two emissive
FeIII compounds are known so far and they show LMCT luminescence
only.3,4 The unique properties of the presented complex are caused by the specific
ligand design combining four N-heterocyclic carbenes with two cyclometalating
groups, using the σ-donor strength of six carbon atoms and the acceptor capabilities
of the central phenyl rings. Spectroscopically, doublet manifolds could be identified
in the deactivation process, while (TD)DFT analysis revealed the presence of quartets
as well. With three key advancements of realizing the first iron complex showing
dual luminescence, a MLCT luminescence and a world record MLCT lifetime, the results
constitute a basis for future application of iron complexes as white light emitters
and new photocatalytic reactions making use of the Janus-type properties of the
developed complex.
author:
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Olga
full_name: Bokareva, Olga
last_name: Bokareva
- first_name: Thomas
full_name: Reuter, Thomas
last_name: Reuter
- first_name: Serhiy
full_name: Demeshko, Serhiy
last_name: Demeshko
- first_name: Roland
full_name: Schoch, Roland
id: '48467'
last_name: Schoch
orcid: 0000-0003-2061-7289
- first_name: Stephan
full_name: Hohloch, Stephan
last_name: Hohloch
- first_name: Franc
full_name: Meyer, Franc
last_name: Meyer
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Oliver
full_name: Kühn, Oliver
last_name: Kühn
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
citation:
ama: Bauer M, Steube J, Päpcke A, et al. Janus-type dual emission of a Cyclometalated
Iron(III) complex. Published online 2020.
apa: Bauer, M., Steube, J., Päpcke, A., Bokareva, O., Reuter, T., Demeshko, S.,
Schoch, R., Hohloch, S., Meyer, F., Heinze, K., Kühn, O., & Lochbrunner, S.
(2020). Janus-type dual emission of a Cyclometalated Iron(III) complex.
Research Square Platform LLC.
bibtex: '@article{Bauer_Steube_Päpcke_Bokareva_Reuter_Demeshko_Schoch_Hohloch_Meyer_Heinze_et
al._2020, title={Janus-type dual emission of a Cyclometalated Iron(III) complex},
publisher={Research Square Platform LLC}, author={Bauer, Matthias and Steube,
Jakob and Päpcke, Ayla and Bokareva, Olga and Reuter, Thomas and Demeshko, Serhiy
and Schoch, Roland and Hohloch, Stephan and Meyer, Franc and Heinze, Katja and
et al.}, year={2020} }'
chicago: Bauer, Matthias, Jakob Steube, Ayla Päpcke, Olga Bokareva, Thomas Reuter,
Serhiy Demeshko, Roland Schoch, et al. “Janus-Type Dual Emission of a Cyclometalated
Iron(III) Complex.” Research Square Platform LLC, 2020.
ieee: M. Bauer et al., “Janus-type dual emission of a Cyclometalated Iron(III)
complex.” Research Square Platform LLC, 2020.
mla: Bauer, Matthias, et al. Janus-Type Dual Emission of a Cyclometalated Iron(III)
Complex. Research Square Platform LLC, 2020.
short: M. Bauer, J. Steube, A. Päpcke, O. Bokareva, T. Reuter, S. Demeshko, R. Schoch,
S. Hohloch, F. Meyer, K. Heinze, O. Kühn, S. Lochbrunner, (2020).
date_created: 2023-01-30T16:45:05Z
date_updated: 2023-08-09T12:51:46Z
department:
- _id: '35'
- _id: '306'
language:
- iso: eng
publication_status: published
publisher: Research Square Platform LLC
status: public
title: Janus-type dual emission of a Cyclometalated Iron(III) complex
type: preprint
user_id: '48467'
year: '2020'
...
---
_id: '16312'
author:
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Ayla
full_name: Päpcke, Ayla
last_name: Päpcke
- first_name: Johannes
full_name: Moll, Johannes
last_name: Moll
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Roland
full_name: Schoch, Roland
last_name: Schoch
- first_name: Christoph
full_name: Wölper, Christoph
last_name: Wölper
- first_name: Katja
full_name: Heinze, Katja
last_name: Heinze
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Steube J, Burkhardt L, Päpcke A, et al. Excited‐State Kinetics of an Air‐Stable
Cyclometalated Iron(II) Complex. Chemistry – A European Journal. Published
online 2019:11826-11830. doi:10.1002/chem.201902488
apa: Steube, J., Burkhardt, L., Päpcke, A., Moll, J., Zimmer, P., Schoch, R., Wölper,
C., Heinze, K., Lochbrunner, S., & Bauer, M. (2019). Excited‐State Kinetics
of an Air‐Stable Cyclometalated Iron(II) Complex. Chemistry – A European Journal,
11826–11830. https://doi.org/10.1002/chem.201902488
bibtex: '@article{Steube_Burkhardt_Päpcke_Moll_Zimmer_Schoch_Wölper_Heinze_Lochbrunner_Bauer_2019,
title={Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex},
DOI={10.1002/chem.201902488},
journal={Chemistry – A European Journal}, author={Steube, Jakob and Burkhardt,
Lukas and Päpcke, Ayla and Moll, Johannes and Zimmer, Peter and Schoch, Roland
and Wölper, Christoph and Heinze, Katja and Lochbrunner, Stefan and Bauer, Matthias},
year={2019}, pages={11826–11830} }'
chicago: Steube, Jakob, Lukas Burkhardt, Ayla Päpcke, Johannes Moll, Peter Zimmer,
Roland Schoch, Christoph Wölper, Katja Heinze, Stefan Lochbrunner, and Matthias
Bauer. “Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex.”
Chemistry – A European Journal, 2019, 11826–30. https://doi.org/10.1002/chem.201902488.
ieee: 'J. Steube et al., “Excited‐State Kinetics of an Air‐Stable Cyclometalated
Iron(II) Complex,” Chemistry – A European Journal, pp. 11826–11830, 2019,
doi: 10.1002/chem.201902488.'
mla: Steube, Jakob, et al. “Excited‐State Kinetics of an Air‐Stable Cyclometalated
Iron(II) Complex.” Chemistry – A European Journal, 2019, pp. 11826–30,
doi:10.1002/chem.201902488.
short: J. Steube, L. Burkhardt, A. Päpcke, J. Moll, P. Zimmer, R. Schoch, C. Wölper,
K. Heinze, S. Lochbrunner, M. Bauer, Chemistry – A European Journal (2019) 11826–11830.
date_created: 2020-03-23T10:39:00Z
date_updated: 2023-08-09T12:52:17Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1002/chem.201902488
language:
- iso: eng
page: 11826-11830
publication: Chemistry – A European Journal
publication_identifier:
issn:
- 0947-6539
- 1521-3765
publication_status: published
status: public
title: Excited‐State Kinetics of an Air‐Stable Cyclometalated Iron(II) Complex
type: journal_article
user_id: '48467'
year: '2019'
...
---
_id: '16317'
author:
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Aleksej
full_name: Friedrich, Aleksej
last_name: Friedrich
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Rahel
full_name: Schepper, Rahel
last_name: Schepper
- first_name: Patrick
full_name: Müller, Patrick
id: '54037'
last_name: Müller
orcid: 0000-0003-1103-4073
- first_name: Ulrich
full_name: Flörke, Ulrich
last_name: Flörke
- first_name: Marina
full_name: Huber, Marina
last_name: Huber
- first_name: Stefan
full_name: Lochbrunner, Stefan
last_name: Lochbrunner
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: 'Zimmer P, Burkhardt L, Friedrich A, et al. The Connection between NHC Ligand
Count and Photophysical Properties in Fe(II) Photosensitizers: An Experimental
Study. Inorganic Chemistry. Published online 2017:360-373. doi:10.1021/acs.inorgchem.7b02624'
apa: 'Zimmer, P., Burkhardt, L., Friedrich, A., Steube, J., Neuba, A., Schepper,
R., Müller, P., Flörke, U., Huber, M., Lochbrunner, S., & Bauer, M. (2017).
The Connection between NHC Ligand Count and Photophysical Properties in Fe(II)
Photosensitizers: An Experimental Study. Inorganic Chemistry, 360–373.
https://doi.org/10.1021/acs.inorgchem.7b02624'
bibtex: '@article{Zimmer_Burkhardt_Friedrich_Steube_Neuba_Schepper_Müller_Flörke_Huber_Lochbrunner_et
al._2017, title={The Connection between NHC Ligand Count and Photophysical Properties
in Fe(II) Photosensitizers: An Experimental Study}, DOI={10.1021/acs.inorgchem.7b02624},
journal={Inorganic Chemistry}, author={Zimmer, Peter and Burkhardt, Lukas and
Friedrich, Aleksej and Steube, Jakob and Neuba, Adam and Schepper, Rahel and Müller,
Patrick and Flörke, Ulrich and Huber, Marina and Lochbrunner, Stefan and et al.},
year={2017}, pages={360–373} }'
chicago: 'Zimmer, Peter, Lukas Burkhardt, Aleksej Friedrich, Jakob Steube, Adam
Neuba, Rahel Schepper, Patrick Müller, et al. “The Connection between NHC Ligand
Count and Photophysical Properties in Fe(II) Photosensitizers: An Experimental
Study.” Inorganic Chemistry, 2017, 360–73. https://doi.org/10.1021/acs.inorgchem.7b02624.'
ieee: 'P. Zimmer et al., “The Connection between NHC Ligand Count and Photophysical
Properties in Fe(II) Photosensitizers: An Experimental Study,” Inorganic Chemistry,
pp. 360–373, 2017, doi: 10.1021/acs.inorgchem.7b02624.'
mla: 'Zimmer, Peter, et al. “The Connection between NHC Ligand Count and Photophysical
Properties in Fe(II) Photosensitizers: An Experimental Study.” Inorganic Chemistry,
2017, pp. 360–73, doi:10.1021/acs.inorgchem.7b02624.'
short: P. Zimmer, L. Burkhardt, A. Friedrich, J. Steube, A. Neuba, R. Schepper,
P. Müller, U. Flörke, M. Huber, S. Lochbrunner, M. Bauer, Inorganic Chemistry
(2017) 360–373.
date_created: 2020-03-23T10:40:15Z
date_updated: 2023-08-09T12:52:44Z
department:
- _id: '43'
- _id: '35'
- _id: '306'
doi: 10.1021/acs.inorgchem.7b02624
language:
- iso: eng
page: 360-373
project:
- _id: '52'
name: Computing Resources Provided by the Paderborn Center for Parallel Computing
publication: Inorganic Chemistry
publication_identifier:
issn:
- 0020-1669
- 1520-510X
publication_status: published
status: public
title: 'The Connection between NHC Ligand Count and Photophysical Properties in Fe(II)
Photosensitizers: An Experimental Study'
type: journal_article
user_id: '48467'
year: '2017'
...
---
_id: '16319'
author:
- first_name: Peter
full_name: Zimmer, Peter
last_name: Zimmer
- first_name: Patrick
full_name: Müller, Patrick
id: '54037'
last_name: Müller
orcid: 0000-0003-1103-4073
- first_name: Lukas
full_name: Burkhardt, Lukas
id: '54038'
last_name: Burkhardt
orcid: 0000-0003-0747-9811
- first_name: Rahel
full_name: Schepper, Rahel
last_name: Schepper
- first_name: Adam
full_name: Neuba, Adam
last_name: Neuba
- first_name: Jakob
full_name: Steube, Jakob
id: '40342'
last_name: Steube
orcid: 0000-0003-3178-4429
- first_name: Fabian
full_name: Dietrich, Fabian
last_name: Dietrich
- first_name: Ulrich
full_name: Flörke, Ulrich
last_name: Flörke
- first_name: Stefan
full_name: Mangold, Stefan
last_name: Mangold
- first_name: Markus
full_name: Gerhards, Markus
last_name: Gerhards
- first_name: Matthias
full_name: Bauer, Matthias
id: '47241'
last_name: Bauer
orcid: 0000-0002-9294-6076
citation:
ama: Zimmer P, Müller P, Burkhardt L, et al. N-Heterocyclic Carbene Complexes of
Iron as Photosensitizers for Light-Induced Water Reduction. European Journal
of Inorganic Chemistry. Published online 2017:1504-1509. doi:10.1002/ejic.201700064
apa: Zimmer, P., Müller, P., Burkhardt, L., Schepper, R., Neuba, A., Steube, J.,
Dietrich, F., Flörke, U., Mangold, S., Gerhards, M., & Bauer, M. (2017). N-Heterocyclic
Carbene Complexes of Iron as Photosensitizers for Light-Induced Water Reduction.
European Journal of Inorganic Chemistry, 1504–1509. https://doi.org/10.1002/ejic.201700064
bibtex: '@article{Zimmer_Müller_Burkhardt_Schepper_Neuba_Steube_Dietrich_Flörke_Mangold_Gerhards_et
al._2017, title={N-Heterocyclic Carbene Complexes of Iron as Photosensitizers
for Light-Induced Water Reduction}, DOI={10.1002/ejic.201700064},
journal={European Journal of Inorganic Chemistry}, author={Zimmer, Peter and Müller,
Patrick and Burkhardt, Lukas and Schepper, Rahel and Neuba, Adam and Steube, Jakob
and Dietrich, Fabian and Flörke, Ulrich and Mangold, Stefan and Gerhards, Markus
and et al.}, year={2017}, pages={1504–1509} }'
chicago: Zimmer, Peter, Patrick Müller, Lukas Burkhardt, Rahel Schepper, Adam Neuba,
Jakob Steube, Fabian Dietrich, et al. “N-Heterocyclic Carbene Complexes of Iron
as Photosensitizers for Light-Induced Water Reduction.” European Journal of
Inorganic Chemistry, 2017, 1504–9. https://doi.org/10.1002/ejic.201700064.
ieee: 'P. Zimmer et al., “N-Heterocyclic Carbene Complexes of Iron as Photosensitizers
for Light-Induced Water Reduction,” European Journal of Inorganic Chemistry,
pp. 1504–1509, 2017, doi: 10.1002/ejic.201700064.'
mla: Zimmer, Peter, et al. “N-Heterocyclic Carbene Complexes of Iron as Photosensitizers
for Light-Induced Water Reduction.” European Journal of Inorganic Chemistry,
2017, pp. 1504–09, doi:10.1002/ejic.201700064.
short: P. Zimmer, P. Müller, L. Burkhardt, R. Schepper, A. Neuba, J. Steube, F.
Dietrich, U. Flörke, S. Mangold, M. Gerhards, M. Bauer, European Journal of Inorganic
Chemistry (2017) 1504–1509.
date_created: 2020-03-23T10:40:43Z
date_updated: 2023-08-09T12:53:31Z
department:
- _id: '43'
- _id: '306'
- _id: '304'
- _id: '35'
doi: 10.1002/ejic.201700064
language:
- iso: eng
page: 1504-1509
publication: European Journal of Inorganic Chemistry
publication_identifier:
issn:
- 1434-1948
publication_status: published
status: public
title: N-Heterocyclic Carbene Complexes of Iron as Photosensitizers for Light-Induced
Water Reduction
type: journal_article
user_id: '48467'
year: '2017'
...