---
_id: '54024'
abstract:
- lang: eng
  text: Transition metal complexes, particularly copper hydrides, play an important
    role in various catalytic processes and molecular inorganic chemistry. This study
    employs synchrotron hard X‐ray spectroscopy to gain insights into the geometric
    and electronic properties of copper hydrides as potential catalysts for CO2 hydrogenation.
    The potential of high energy resolution X‐ray absorption near‐edge structure (HERFD‐XANES)
    and valence‐to‐core X‐ray emission (VtC‐XES) is demonstrated with measurement
    on Stryker's reagent (Cu6H6) and [Cu3(μ3‐H)(dpmppe)2](PF6)2 (Cu3H), alongside
    a non‐hydride copper compound (Cu‐I). The XANES analysis reveals that coordination
    geometries strongly influence the spectra, providing only indirect details about
    hydride coordination. The VtC‐XES analysis exhibits a distinct signal around 8975
    eV, offering a diagnostic tool to identify hydride ligands. Theoretical calculations
    support and extend these findings by comparing hydride‐containing complexes with
    their hydride‐free counterparts.
article_type: original
author:
- first_name: Lorena
  full_name: Fritsch, Lorena
  id: '44418'
  last_name: Fritsch
- first_name: Pia
  full_name: Rehsies, Pia
  id: '46959'
  last_name: Rehsies
- first_name: Wael
  full_name: Barakat, Wael
  last_name: Barakat
- first_name: Deven P.
  full_name: Estes, Deven P.
  last_name: Estes
- first_name: Matthias
  full_name: Bauer, Matthias
  id: '47241'
  last_name: Bauer
  orcid: 0000-0002-9294-6076
citation:
  ama: Fritsch L, Rehsies P, Barakat W, Estes DP, Bauer M. Detection and Characterization
    of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy. <i>Chemistry
    – A European Journal</i>. 2024;30(36). doi:<a href="https://doi.org/10.1002/chem.202400357">10.1002/chem.202400357</a>
  apa: Fritsch, L., Rehsies, P., Barakat, W., Estes, D. P., &#38; Bauer, M. (2024).
    Detection and Characterization of Hydride Ligands in Copper Complexes by Hard
    X‐ray Spectroscopy. <i>Chemistry – A European Journal</i>, <i>30</i>(36). <a href="https://doi.org/10.1002/chem.202400357">https://doi.org/10.1002/chem.202400357</a>
  bibtex: '@article{Fritsch_Rehsies_Barakat_Estes_Bauer_2024, title={Detection and
    Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy},
    volume={30}, DOI={<a href="https://doi.org/10.1002/chem.202400357">10.1002/chem.202400357</a>},
    number={36}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Fritsch,
    Lorena and Rehsies, Pia and Barakat, Wael and Estes, Deven P. and Bauer, Matthias},
    year={2024} }'
  chicago: Fritsch, Lorena, Pia Rehsies, Wael Barakat, Deven P. Estes, and Matthias
    Bauer. “Detection and Characterization of Hydride Ligands in Copper Complexes
    by Hard X‐ray Spectroscopy.” <i>Chemistry – A European Journal</i> 30, no. 36
    (2024). <a href="https://doi.org/10.1002/chem.202400357">https://doi.org/10.1002/chem.202400357</a>.
  ieee: 'L. Fritsch, P. Rehsies, W. Barakat, D. P. Estes, and M. Bauer, “Detection
    and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy,”
    <i>Chemistry – A European Journal</i>, vol. 30, no. 36, 2024, doi: <a href="https://doi.org/10.1002/chem.202400357">10.1002/chem.202400357</a>.'
  mla: Fritsch, Lorena, et al. “Detection and Characterization of Hydride Ligands
    in Copper Complexes by Hard X‐ray Spectroscopy.” <i>Chemistry – A European Journal</i>,
    vol. 30, no. 36, Wiley, 2024, doi:<a href="https://doi.org/10.1002/chem.202400357">10.1002/chem.202400357</a>.
  short: L. Fritsch, P. Rehsies, W. Barakat, D.P. Estes, M. Bauer, Chemistry – A European
    Journal 30 (2024).
date_created: 2024-05-07T08:41:11Z
date_updated: 2025-08-15T12:51:10Z
department:
- _id: '306'
doi: 10.1002/chem.202400357
intvolume: '        30'
issue: '36'
keyword:
- Xray
language:
- iso: eng
publication: Chemistry – A European Journal
publication_identifier:
  issn:
  - 0947-6539
  - 1521-3765
publication_status: published
publisher: Wiley
status: public
title: Detection and Characterization of Hydride Ligands in Copper Complexes by Hard
  X‐ray Spectroscopy
type: journal_article
user_id: '48467'
volume: 30
year: '2024'
...