@article{40981,
  abstract     = {{Room temperature sodium-sulfur (RT Na-S) batteries are considered potential candidates for stationary power storage applications due to their low cost, broad active material availability and low toxicity. Challenges, such as high volume expansion of the S-cathode upon discharge, low electronic conductivity of S as active material and herewith limited rate capability as well as the shuttling of polysulfides (PSs) as intermediates often impede the cycle stability and practical application of Na-S batteries. Sulfurized poly(acrylonitrile) (SPAN) inherently inhibits the shuttling of PSs and shows compatibility with carbonate-based electrolytes, however, its exact redox mechanism remained unclear to date. Herein, we implement a commercially available and simple electrolyte into the Na-SPAN cell chemistry and demonstrate its high rate and cycle stability. Through the application of in situ techniques utilizing electronic impedance spectroscopy (EIS) and X-ray absorption spectroscopy (XAS) at different depths of charge and discharge, an insight into SPAN’s redox chemistry is obtained.}},
  author       = {{Kappler, Julian and Tonbul, Güldeniz and Schoch, Roland and Murugan, Saravanakumar and Nowakowski, Michał and Lange, Pia Lena and Klostermann, Sina Vanessa and Bauer, Matthias and Schleid, Thomas and Kästner, Johannes and Buchmeiser, Michael Rudolf}},
  issn         = {{0013-4651}},
  journal      = {{Journal of The Electrochemical Society}},
  keywords     = {{Materials Chemistry, Electrochemistry, Surfaces, Coatings and Films, Condensed Matter Physics, Renewable Energy, Sustainability and the Environment, Electronic, Optical and Magnetic Materials}},
  number       = {{1}},
  publisher    = {{The Electrochemical Society}},
  title        = {{{Understanding the Redox Mechanism of Sulfurized Poly(acrylonitrile) as Highly Rate and Cycle Stable Cathode Material for Sodium-Sulfur Batteries}}},
  doi          = {{10.1149/1945-7111/acb2fa}},
  volume       = {{170}},
  year         = {{2023}},
}

@inproceedings{44380,
  author       = {{Tonbul, Güldeniz and Kappler, Julian  and Murugan, Saravanakumar  and Schoch, Roland  and Nowakowski, Michal  and Lange, Pia and Bauer, Matthias  and Buchmeiser, Michael R.}},
  location     = {{Aachen}},
  title        = {{{Characterization of Na-S Battery System Using X-ray Absorption Spectroscopy}}},
  year         = {{2023}},
}

@inproceedings{44376,
  author       = {{Tonbul, Güldeniz and Kappler, Julian  and Murugan, Saravanakumar  and Schoch, Roland  and Nowakowski, Michal  and Lange, Pia  and Bauer, Matthias and Buchmeiser, Michael R.}},
  location     = {{Edinburgh}},
  title        = {{{Development of Battery System Based on Na-S and Characterization Using X-ray Absorption Spectroscopy}}},
  year         = {{2022}},
}

@article{44375,
  author       = {{Chormey, Dotse Selali and Tonbul, Güldeniz and Soylu, Güneş and Saygılar, Ahmet and Bakırdere, Sezgin}},
  issn         = {{0003-2719}},
  journal      = {{Analytical Letters}},
  keywords     = {{Dispersive liquid-liquid microextraction (DLLME), gas chromatography – mass spectrometry (GC-MS), polycyclic aromatic hydrocarbons, QuEChERS}},
  number       = {{2}},
  pages        = {{237--245}},
  publisher    = {{Informa UK Limited}},
  title        = {{{Determination of Four Priority Polycyclic Aromatic Hydrocarbons in Food Samples by Gas Chromatography – Mass Spectrometry (GC-MS) after Vortex Assisted Dispersive Liquid-Liquid Microextraction (DLLME)}}},
  doi          = {{10.1080/00032719.2021.1922432}},
  volume       = {{55}},
  year         = {{2021}},
}

