[{"_id":"59901","user_id":"67837","article_type":"original","article_number":"113978","language":[{"iso":"eng"}],"funded_apc":"1","publication":"Combustion and Flame","type":"journal_article","status":"public","publisher":"Elsevier BV","date_updated":"2025-05-14T14:24:12Z","volume":274,"date_created":"2025-05-14T13:43:19Z","author":[{"id":"67837","full_name":"Keksel, Ewald","last_name":"Keksel","first_name":"Ewald"},{"first_name":"Sebastian","full_name":"Kluge, Sebastian","last_name":"Kluge"},{"first_name":"Domenik","last_name":"Schleier","full_name":"Schleier, Domenik","id":"98339"},{"full_name":"Höner, Martin","last_name":"Höner","first_name":"Martin"},{"first_name":"Yasin","last_name":"Karakaya","id":"95069","full_name":"Karakaya, Yasin"},{"first_name":"Thomas","full_name":"Bierkandt, Thomas","last_name":"Bierkandt"},{"last_name":"Köhler","full_name":"Köhler, Markus","first_name":"Markus"},{"last_name":"Kasper","orcid":"0000-0003-3993-5316 ","id":"94562","full_name":"Kasper, Tina","first_name":"Tina"}],"title":"Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation in laminar flames","doi":"10.1016/j.combustflame.2025.113978","quality_controlled":"1","publication_identifier":{"issn":["0010-2180"]},"publication_status":"published","year":"2025","intvolume":"       274","citation":{"ama":"Keksel E, Kluge S, Schleier D, et al. Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation in laminar flames. <i>Combustion and Flame</i>. 2025;274. doi:<a href=\"https://doi.org/10.1016/j.combustflame.2025.113978\">10.1016/j.combustflame.2025.113978</a>","chicago":"Keksel, Ewald, Sebastian Kluge, Domenik Schleier, Martin Höner, Yasin Karakaya, Thomas Bierkandt, Markus Köhler, and Tina Kasper. “Sensitizing Effect of Acetylene and 1,3-Butadiene on Toluene Oxidation in Laminar Flames.” <i>Combustion and Flame</i> 274 (2025). <a href=\"https://doi.org/10.1016/j.combustflame.2025.113978\">https://doi.org/10.1016/j.combustflame.2025.113978</a>.","ieee":"E. Keksel <i>et al.</i>, “Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation in laminar flames,” <i>Combustion and Flame</i>, vol. 274, Art. no. 113978, 2025, doi: <a href=\"https://doi.org/10.1016/j.combustflame.2025.113978\">10.1016/j.combustflame.2025.113978</a>.","apa":"Keksel, E., Kluge, S., Schleier, D., Höner, M., Karakaya, Y., Bierkandt, T., Köhler, M., &#38; Kasper, T. (2025). Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation in laminar flames. <i>Combustion and Flame</i>, <i>274</i>, Article 113978. <a href=\"https://doi.org/10.1016/j.combustflame.2025.113978\">https://doi.org/10.1016/j.combustflame.2025.113978</a>","short":"E. Keksel, S. Kluge, D. Schleier, M. Höner, Y. Karakaya, T. Bierkandt, M. Köhler, T. Kasper, Combustion and Flame 274 (2025).","bibtex":"@article{Keksel_Kluge_Schleier_Höner_Karakaya_Bierkandt_Köhler_Kasper_2025, title={Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation in laminar flames}, volume={274}, DOI={<a href=\"https://doi.org/10.1016/j.combustflame.2025.113978\">10.1016/j.combustflame.2025.113978</a>}, number={113978}, journal={Combustion and Flame}, publisher={Elsevier BV}, author={Keksel, Ewald and Kluge, Sebastian and Schleier, Domenik and Höner, Martin and Karakaya, Yasin and Bierkandt, Thomas and Köhler, Markus and Kasper, Tina}, year={2025} }","mla":"Keksel, Ewald, et al. “Sensitizing Effect of Acetylene and 1,3-Butadiene on Toluene Oxidation in Laminar Flames.” <i>Combustion and Flame</i>, vol. 274, 113978, Elsevier BV, 2025, doi:<a href=\"https://doi.org/10.1016/j.combustflame.2025.113978\">10.1016/j.combustflame.2025.113978</a>."}},{"type":"journal_article","publication":"Angewandte Chemie International Edition","status":"public","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The incorporation of heteroatoms into the framework of polycyclic aromatic hydrocarbons (PAHs), in particular of nitrogen to yield polycyclic aromatic nitrogen heterocycles (PANHs), has been proposed for both astronomical and combustion environments, but no suitable precursors and pathways have been found. Analogous pathways to PAH formation are kinetically or energetically inhibited in the presence of a nitrogen heteroatom. We report on the reaction of phenylnitrene (<jats:sup>3</jats:sup>PhN, <jats:italic>c</jats:italic>‐C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>N) with resonance‐stabilized propargyl radicals (C<jats:sub>3</jats:sub>H<jats:sub>3</jats:sub>) and find that the association reaction bifurcates depending on the orientation of the attacking propargyl radical and yields multiple isomeric products. Among them, we identify the condensed‐ring quinoline and conclude that nitrenes are viable candidates to drive the formation of PANHs.</jats:p>"}],"user_id":"94562","department":[{"_id":"728"}],"_id":"60552","language":[{"iso":"eng"}],"article_type":"original","publication_status":"published","publication_identifier":{"issn":["1433-7851","1521-3773"]},"citation":{"apa":"Arns, R., McClish, R., Hemberger, P., Bodi, A., Bouwman, J., Kasper, T., &#38; Schleier, D. (2025). Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles? <i>Angewandte Chemie International Edition</i>. <a href=\"https://doi.org/10.1002/anie.202503940\">https://doi.org/10.1002/anie.202503940</a>","short":"R. Arns, R. McClish, P. Hemberger, A. Bodi, J. Bouwman, T. Kasper, D. Schleier, Angewandte Chemie International Edition (2025).","bibtex":"@article{Arns_McClish_Hemberger_Bodi_Bouwman_Kasper_Schleier_2025, title={Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?}, DOI={<a href=\"https://doi.org/10.1002/anie.202503940\">10.1002/anie.202503940</a>}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Arns, Rahel and McClish, Rory and Hemberger, Patrick and Bodi, Andras and Bouwman, Jordy and Kasper, Tina and Schleier, Domenik}, year={2025} }","mla":"Arns, Rahel, et al. “Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?” <i>Angewandte Chemie International Edition</i>, Wiley, 2025, doi:<a href=\"https://doi.org/10.1002/anie.202503940\">10.1002/anie.202503940</a>.","ama":"Arns R, McClish R, Hemberger P, et al. Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles? <i>Angewandte Chemie International Edition</i>. Published online 2025. doi:<a href=\"https://doi.org/10.1002/anie.202503940\">10.1002/anie.202503940</a>","ieee":"R. Arns <i>et al.</i>, “Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?,” <i>Angewandte Chemie International Edition</i>, 2025, doi: <a href=\"https://doi.org/10.1002/anie.202503940\">10.1002/anie.202503940</a>.","chicago":"Arns, Rahel, Rory McClish, Patrick Hemberger, Andras Bodi, Jordy Bouwman, Tina Kasper, and Domenik Schleier. “Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?” <i>Angewandte Chemie International Edition</i>, 2025. <a href=\"https://doi.org/10.1002/anie.202503940\">https://doi.org/10.1002/anie.202503940</a>."},"year":"2025","author":[{"full_name":"Arns, Rahel","last_name":"Arns","first_name":"Rahel"},{"full_name":"McClish, Rory","last_name":"McClish","first_name":"Rory"},{"first_name":"Patrick","last_name":"Hemberger","full_name":"Hemberger, Patrick"},{"last_name":"Bodi","full_name":"Bodi, Andras","first_name":"Andras"},{"first_name":"Jordy","last_name":"Bouwman","full_name":"Bouwman, Jordy"},{"full_name":"Kasper, Tina","id":"94562","last_name":"Kasper","orcid":"0000-0003-3993-5316 ","first_name":"Tina"},{"last_name":"Schleier","id":"98339","full_name":"Schleier, Domenik","first_name":"Domenik"}],"date_created":"2025-07-08T10:27:46Z","date_updated":"2025-07-08T10:39:30Z","publisher":"Wiley","doi":"10.1002/anie.202503940","title":"Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen Heterocycles?"},{"author":[{"last_name":"Kamer","full_name":"Kamer, Jerry","first_name":"Jerry"},{"last_name":"Schleier","full_name":"Schleier, Domenik","id":"98339","first_name":"Domenik"},{"last_name":"Donker","full_name":"Donker, Merel","first_name":"Merel"},{"last_name":"Hemberger","full_name":"Hemberger, Patrick","first_name":"Patrick"},{"last_name":"Bodi","full_name":"Bodi, Andras","first_name":"Andras"},{"full_name":"Bouwman, Jordy","last_name":"Bouwman","first_name":"Jordy"}],"volume":25,"date_updated":"2023-11-13T08:00:52Z","doi":"10.1039/d3cp03977c","publication_status":"published","publication_identifier":{"issn":["1463-9076","1463-9084"]},"citation":{"chicago":"Kamer, Jerry, Domenik Schleier, Merel Donker, Patrick Hemberger, Andras Bodi, and Jordy Bouwman. “Threshold Photoelectron Spectroscopy and Dissociative Photoionization of Benzonitrile.” <i>Physical Chemistry Chemical Physics</i> 25, no. 42 (2023): 29070–79. <a href=\"https://doi.org/10.1039/d3cp03977c\">https://doi.org/10.1039/d3cp03977c</a>.","ieee":"J. Kamer, D. Schleier, M. Donker, P. Hemberger, A. Bodi, and J. Bouwman, “Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile,” <i>Physical Chemistry Chemical Physics</i>, vol. 25, no. 42, pp. 29070–29079, 2023, doi: <a href=\"https://doi.org/10.1039/d3cp03977c\">10.1039/d3cp03977c</a>.","ama":"Kamer J, Schleier D, Donker M, Hemberger P, Bodi A, Bouwman J. Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile. <i>Physical Chemistry Chemical Physics</i>. 2023;25(42):29070-29079. doi:<a href=\"https://doi.org/10.1039/d3cp03977c\">10.1039/d3cp03977c</a>","apa":"Kamer, J., Schleier, D., Donker, M., Hemberger, P., Bodi, A., &#38; Bouwman, J. (2023). Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile. <i>Physical Chemistry Chemical Physics</i>, <i>25</i>(42), 29070–29079. <a href=\"https://doi.org/10.1039/d3cp03977c\">https://doi.org/10.1039/d3cp03977c</a>","short":"J. Kamer, D. Schleier, M. Donker, P. Hemberger, A. Bodi, J. Bouwman, Physical Chemistry Chemical Physics 25 (2023) 29070–29079.","mla":"Kamer, Jerry, et al. “Threshold Photoelectron Spectroscopy and Dissociative Photoionization of Benzonitrile.” <i>Physical Chemistry Chemical Physics</i>, vol. 25, no. 42, Royal Society of Chemistry (RSC), 2023, pp. 29070–79, doi:<a href=\"https://doi.org/10.1039/d3cp03977c\">10.1039/d3cp03977c</a>.","bibtex":"@article{Kamer_Schleier_Donker_Hemberger_Bodi_Bouwman_2023, title={Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile}, volume={25}, DOI={<a href=\"https://doi.org/10.1039/d3cp03977c\">10.1039/d3cp03977c</a>}, number={42}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society of Chemistry (RSC)}, author={Kamer, Jerry and Schleier, Domenik and Donker, Merel and Hemberger, Patrick and Bodi, Andras and Bouwman, Jordy}, year={2023}, pages={29070–29079} }"},"intvolume":"        25","page":"29070-29079","user_id":"98339","department":[{"_id":"728"}],"_id":"48639","article_type":"original","type":"journal_article","status":"public","date_created":"2023-11-07T07:24:53Z","publisher":"Royal Society of Chemistry (RSC)","title":"Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile","issue":"42","quality_controlled":"1","year":"2023","language":[{"iso":"eng"}],"keyword":["Physical and Theoretical Chemistry","General Physics and Astronomy"],"publication":"Physical Chemistry Chemical Physics","abstract":[{"text":"The seven parallel dissociative ionization channels of benzonitrile yield highly stable fragment ions with commensurate abundance, underlining the potential role of the benzonitrile cation as hub species in the interstellar medium.","lang":"eng"}]},{"date_created":"2023-04-27T12:07:29Z","publisher":"Royal Society of Chemistry (RSC)","title":"Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products","issue":"6","quality_controlled":"1","year":"2022","language":[{"iso":"eng"}],"keyword":["Physical and Theoretical Chemistry","General Physics and Astronomy"],"publication":"Physical Chemistry Chemical Physics","abstract":[{"lang":"eng","text":"<jats:p>A new decomposition mechanism for trimethylborane at high temperatures has been discovered.</jats:p>"}],"volume":25,"author":[{"first_name":"Domenik","last_name":"Schleier","full_name":"Schleier, Domenik","id":"98339"},{"last_name":"Gerlach","full_name":"Gerlach, Marius","first_name":"Marius"},{"full_name":"Schaffner, Dorothee","last_name":"Schaffner","first_name":"Dorothee"},{"full_name":"Mukhopadhyay, Deb Pratim","last_name":"Mukhopadhyay","first_name":"Deb Pratim"},{"last_name":"Hemberger","full_name":"Hemberger, Patrick","first_name":"Patrick"},{"last_name":"Fischer","full_name":"Fischer, Ingo","first_name":"Ingo"}],"date_updated":"2023-11-13T08:00:47Z","doi":"10.1039/d2cp04513c","publication_identifier":{"issn":["1463-9076","1463-9084"]},"publication_status":"published","intvolume":"        25","page":"4511-4518","citation":{"apa":"Schleier, D., Gerlach, M., Schaffner, D., Mukhopadhyay, D. P., Hemberger, P., &#38; Fischer, I. (2022). Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products. <i>Physical Chemistry Chemical Physics</i>, <i>25</i>(6), 4511–4518. <a href=\"https://doi.org/10.1039/d2cp04513c\">https://doi.org/10.1039/d2cp04513c</a>","mla":"Schleier, Domenik, et al. “Threshold Photoelectron Spectroscopy of Trimethylborane and Its Pyrolysis Products.” <i>Physical Chemistry Chemical Physics</i>, vol. 25, no. 6, Royal Society of Chemistry (RSC), 2022, pp. 4511–18, doi:<a href=\"https://doi.org/10.1039/d2cp04513c\">10.1039/d2cp04513c</a>.","bibtex":"@article{Schleier_Gerlach_Schaffner_Mukhopadhyay_Hemberger_Fischer_2022, title={Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products}, volume={25}, DOI={<a href=\"https://doi.org/10.1039/d2cp04513c\">10.1039/d2cp04513c</a>}, number={6}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society of Chemistry (RSC)}, author={Schleier, Domenik and Gerlach, Marius and Schaffner, Dorothee and Mukhopadhyay, Deb Pratim and Hemberger, Patrick and Fischer, Ingo}, year={2022}, pages={4511–4518} }","short":"D. Schleier, M. Gerlach, D. Schaffner, D.P. Mukhopadhyay, P. Hemberger, I. Fischer, Physical Chemistry Chemical Physics 25 (2022) 4511–4518.","ama":"Schleier D, Gerlach M, Schaffner D, Mukhopadhyay DP, Hemberger P, Fischer I. Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products. <i>Physical Chemistry Chemical Physics</i>. 2022;25(6):4511-4518. doi:<a href=\"https://doi.org/10.1039/d2cp04513c\">10.1039/d2cp04513c</a>","ieee":"D. Schleier, M. Gerlach, D. Schaffner, D. P. Mukhopadhyay, P. Hemberger, and I. Fischer, “Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products,” <i>Physical Chemistry Chemical Physics</i>, vol. 25, no. 6, pp. 4511–4518, 2022, doi: <a href=\"https://doi.org/10.1039/d2cp04513c\">10.1039/d2cp04513c</a>.","chicago":"Schleier, Domenik, Marius Gerlach, Dorothee Schaffner, Deb Pratim Mukhopadhyay, Patrick Hemberger, and Ingo Fischer. “Threshold Photoelectron Spectroscopy of Trimethylborane and Its Pyrolysis Products.” <i>Physical Chemistry Chemical Physics</i> 25, no. 6 (2022): 4511–18. <a href=\"https://doi.org/10.1039/d2cp04513c\">https://doi.org/10.1039/d2cp04513c</a>."},"user_id":"98339","_id":"44231","type":"journal_article","status":"public"}]