---
_id: '59901'
article_number: '113978'
article_type: original
author:
- first_name: Ewald
  full_name: Keksel, Ewald
  id: '67837'
  last_name: Keksel
- first_name: Sebastian
  full_name: Kluge, Sebastian
  last_name: Kluge
- first_name: Domenik
  full_name: Schleier, Domenik
  id: '98339'
  last_name: Schleier
- first_name: Martin
  full_name: Höner, Martin
  last_name: Höner
- first_name: Yasin
  full_name: Karakaya, Yasin
  id: '95069'
  last_name: Karakaya
- first_name: Thomas
  full_name: Bierkandt, Thomas
  last_name: Bierkandt
- first_name: Markus
  full_name: Köhler, Markus
  last_name: Köhler
- first_name: Tina
  full_name: Kasper, Tina
  id: '94562'
  last_name: Kasper
  orcid: '0000-0003-3993-5316 '
citation:
  ama: Keksel E, Kluge S, Schleier D, et al. Sensitizing effect of acetylene and 1,3-butadiene
    on toluene oxidation in laminar flames. <i>Combustion and Flame</i>. 2025;274.
    doi:<a href="https://doi.org/10.1016/j.combustflame.2025.113978">10.1016/j.combustflame.2025.113978</a>
  apa: Keksel, E., Kluge, S., Schleier, D., Höner, M., Karakaya, Y., Bierkandt, T.,
    Köhler, M., &#38; Kasper, T. (2025). Sensitizing effect of acetylene and 1,3-butadiene
    on toluene oxidation in laminar flames. <i>Combustion and Flame</i>, <i>274</i>,
    Article 113978. <a href="https://doi.org/10.1016/j.combustflame.2025.113978">https://doi.org/10.1016/j.combustflame.2025.113978</a>
  bibtex: '@article{Keksel_Kluge_Schleier_Höner_Karakaya_Bierkandt_Köhler_Kasper_2025,
    title={Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation
    in laminar flames}, volume={274}, DOI={<a href="https://doi.org/10.1016/j.combustflame.2025.113978">10.1016/j.combustflame.2025.113978</a>},
    number={113978}, journal={Combustion and Flame}, publisher={Elsevier BV}, author={Keksel,
    Ewald and Kluge, Sebastian and Schleier, Domenik and Höner, Martin and Karakaya,
    Yasin and Bierkandt, Thomas and Köhler, Markus and Kasper, Tina}, year={2025}
    }'
  chicago: Keksel, Ewald, Sebastian Kluge, Domenik Schleier, Martin Höner, Yasin Karakaya,
    Thomas Bierkandt, Markus Köhler, and Tina Kasper. “Sensitizing Effect of Acetylene
    and 1,3-Butadiene on Toluene Oxidation in Laminar Flames.” <i>Combustion and Flame</i>
    274 (2025). <a href="https://doi.org/10.1016/j.combustflame.2025.113978">https://doi.org/10.1016/j.combustflame.2025.113978</a>.
  ieee: 'E. Keksel <i>et al.</i>, “Sensitizing effect of acetylene and 1,3-butadiene
    on toluene oxidation in laminar flames,” <i>Combustion and Flame</i>, vol. 274,
    Art. no. 113978, 2025, doi: <a href="https://doi.org/10.1016/j.combustflame.2025.113978">10.1016/j.combustflame.2025.113978</a>.'
  mla: Keksel, Ewald, et al. “Sensitizing Effect of Acetylene and 1,3-Butadiene on
    Toluene Oxidation in Laminar Flames.” <i>Combustion and Flame</i>, vol. 274, 113978,
    Elsevier BV, 2025, doi:<a href="https://doi.org/10.1016/j.combustflame.2025.113978">10.1016/j.combustflame.2025.113978</a>.
  short: E. Keksel, S. Kluge, D. Schleier, M. Höner, Y. Karakaya, T. Bierkandt, M.
    Köhler, T. Kasper, Combustion and Flame 274 (2025).
date_created: 2025-05-14T13:43:19Z
date_updated: 2025-05-14T14:24:12Z
doi: 10.1016/j.combustflame.2025.113978
funded_apc: '1'
intvolume: '       274'
language:
- iso: eng
publication: Combustion and Flame
publication_identifier:
  issn:
  - 0010-2180
publication_status: published
publisher: Elsevier BV
quality_controlled: '1'
status: public
title: Sensitizing effect of acetylene and 1,3-butadiene on toluene oxidation in laminar
  flames
type: journal_article
user_id: '67837'
volume: 274
year: '2025'
...
---
_id: '60552'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>The incorporation of heteroatoms
    into the framework of polycyclic aromatic hydrocarbons (PAHs), in particular of
    nitrogen to yield polycyclic aromatic nitrogen heterocycles (PANHs), has been
    proposed for both astronomical and combustion environments, but no suitable precursors
    and pathways have been found. Analogous pathways to PAH formation are kinetically
    or energetically inhibited in the presence of a nitrogen heteroatom. We report
    on the reaction of phenylnitrene (<jats:sup>3</jats:sup>PhN, <jats:italic>c</jats:italic>‐C<jats:sub>6</jats:sub>H<jats:sub>5</jats:sub>N)
    with resonance‐stabilized propargyl radicals (C<jats:sub>3</jats:sub>H<jats:sub>3</jats:sub>)
    and find that the association reaction bifurcates depending on the orientation
    of the attacking propargyl radical and yields multiple isomeric products. Among
    them, we identify the condensed‐ring quinoline and conclude that nitrenes are
    viable candidates to drive the formation of PANHs.</jats:p>
article_type: original
author:
- first_name: Rahel
  full_name: Arns, Rahel
  last_name: Arns
- first_name: Rory
  full_name: McClish, Rory
  last_name: McClish
- first_name: Patrick
  full_name: Hemberger, Patrick
  last_name: Hemberger
- first_name: Andras
  full_name: Bodi, Andras
  last_name: Bodi
- first_name: Jordy
  full_name: Bouwman, Jordy
  last_name: Bouwman
- first_name: Tina
  full_name: Kasper, Tina
  id: '94562'
  last_name: Kasper
  orcid: '0000-0003-3993-5316 '
- first_name: Domenik
  full_name: Schleier, Domenik
  id: '98339'
  last_name: Schleier
citation:
  ama: Arns R, McClish R, Hemberger P, et al. Is Phenylnitrene a Missing Link in the
    Formation of Polycyclic Aromatic Nitrogen Heterocycles? <i>Angewandte Chemie International
    Edition</i>. Published online 2025. doi:<a href="https://doi.org/10.1002/anie.202503940">10.1002/anie.202503940</a>
  apa: Arns, R., McClish, R., Hemberger, P., Bodi, A., Bouwman, J., Kasper, T., &#38;
    Schleier, D. (2025). Is Phenylnitrene a Missing Link in the Formation of Polycyclic
    Aromatic Nitrogen Heterocycles? <i>Angewandte Chemie International Edition</i>.
    <a href="https://doi.org/10.1002/anie.202503940">https://doi.org/10.1002/anie.202503940</a>
  bibtex: '@article{Arns_McClish_Hemberger_Bodi_Bouwman_Kasper_Schleier_2025, title={Is
    Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen
    Heterocycles?}, DOI={<a href="https://doi.org/10.1002/anie.202503940">10.1002/anie.202503940</a>},
    journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Arns,
    Rahel and McClish, Rory and Hemberger, Patrick and Bodi, Andras and Bouwman, Jordy
    and Kasper, Tina and Schleier, Domenik}, year={2025} }'
  chicago: Arns, Rahel, Rory McClish, Patrick Hemberger, Andras Bodi, Jordy Bouwman,
    Tina Kasper, and Domenik Schleier. “Is Phenylnitrene a Missing Link in the Formation
    of Polycyclic Aromatic Nitrogen Heterocycles?” <i>Angewandte Chemie International
    Edition</i>, 2025. <a href="https://doi.org/10.1002/anie.202503940">https://doi.org/10.1002/anie.202503940</a>.
  ieee: 'R. Arns <i>et al.</i>, “Is Phenylnitrene a Missing Link in the Formation
    of Polycyclic Aromatic Nitrogen Heterocycles?,” <i>Angewandte Chemie International
    Edition</i>, 2025, doi: <a href="https://doi.org/10.1002/anie.202503940">10.1002/anie.202503940</a>.'
  mla: Arns, Rahel, et al. “Is Phenylnitrene a Missing Link in the Formation of Polycyclic
    Aromatic Nitrogen Heterocycles?” <i>Angewandte Chemie International Edition</i>,
    Wiley, 2025, doi:<a href="https://doi.org/10.1002/anie.202503940">10.1002/anie.202503940</a>.
  short: R. Arns, R. McClish, P. Hemberger, A. Bodi, J. Bouwman, T. Kasper, D. Schleier,
    Angewandte Chemie International Edition (2025).
date_created: 2025-07-08T10:27:46Z
date_updated: 2025-07-08T10:39:30Z
department:
- _id: '728'
doi: 10.1002/anie.202503940
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
  issn:
  - 1433-7851
  - 1521-3773
publication_status: published
publisher: Wiley
status: public
title: Is Phenylnitrene a Missing Link in the Formation of Polycyclic Aromatic Nitrogen
  Heterocycles?
type: journal_article
user_id: '94562'
year: '2025'
...
---
_id: '48639'
abstract:
- lang: eng
  text: The seven parallel dissociative ionization channels of benzonitrile yield
    highly stable fragment ions with commensurate abundance, underlining the potential
    role of the benzonitrile cation as hub species in the interstellar medium.
article_type: original
author:
- first_name: Jerry
  full_name: Kamer, Jerry
  last_name: Kamer
- first_name: Domenik
  full_name: Schleier, Domenik
  id: '98339'
  last_name: Schleier
- first_name: Merel
  full_name: Donker, Merel
  last_name: Donker
- first_name: Patrick
  full_name: Hemberger, Patrick
  last_name: Hemberger
- first_name: Andras
  full_name: Bodi, Andras
  last_name: Bodi
- first_name: Jordy
  full_name: Bouwman, Jordy
  last_name: Bouwman
citation:
  ama: Kamer J, Schleier D, Donker M, Hemberger P, Bodi A, Bouwman J. Threshold photoelectron
    spectroscopy and dissociative photoionization of benzonitrile. <i>Physical Chemistry
    Chemical Physics</i>. 2023;25(42):29070-29079. doi:<a href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>
  apa: Kamer, J., Schleier, D., Donker, M., Hemberger, P., Bodi, A., &#38; Bouwman,
    J. (2023). Threshold photoelectron spectroscopy and dissociative photoionization
    of benzonitrile. <i>Physical Chemistry Chemical Physics</i>, <i>25</i>(42), 29070–29079.
    <a href="https://doi.org/10.1039/d3cp03977c">https://doi.org/10.1039/d3cp03977c</a>
  bibtex: '@article{Kamer_Schleier_Donker_Hemberger_Bodi_Bouwman_2023, title={Threshold
    photoelectron spectroscopy and dissociative photoionization of benzonitrile},
    volume={25}, DOI={<a href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>},
    number={42}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society
    of Chemistry (RSC)}, author={Kamer, Jerry and Schleier, Domenik and Donker, Merel
    and Hemberger, Patrick and Bodi, Andras and Bouwman, Jordy}, year={2023}, pages={29070–29079}
    }'
  chicago: 'Kamer, Jerry, Domenik Schleier, Merel Donker, Patrick Hemberger, Andras
    Bodi, and Jordy Bouwman. “Threshold Photoelectron Spectroscopy and Dissociative
    Photoionization of Benzonitrile.” <i>Physical Chemistry Chemical Physics</i> 25,
    no. 42 (2023): 29070–79. <a href="https://doi.org/10.1039/d3cp03977c">https://doi.org/10.1039/d3cp03977c</a>.'
  ieee: 'J. Kamer, D. Schleier, M. Donker, P. Hemberger, A. Bodi, and J. Bouwman,
    “Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile,”
    <i>Physical Chemistry Chemical Physics</i>, vol. 25, no. 42, pp. 29070–29079,
    2023, doi: <a href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>.'
  mla: Kamer, Jerry, et al. “Threshold Photoelectron Spectroscopy and Dissociative
    Photoionization of Benzonitrile.” <i>Physical Chemistry Chemical Physics</i>,
    vol. 25, no. 42, Royal Society of Chemistry (RSC), 2023, pp. 29070–79, doi:<a
    href="https://doi.org/10.1039/d3cp03977c">10.1039/d3cp03977c</a>.
  short: J. Kamer, D. Schleier, M. Donker, P. Hemberger, A. Bodi, J. Bouwman, Physical
    Chemistry Chemical Physics 25 (2023) 29070–29079.
date_created: 2023-11-07T07:24:53Z
date_updated: 2023-11-13T08:00:52Z
department:
- _id: '728'
doi: 10.1039/d3cp03977c
intvolume: '        25'
issue: '42'
keyword:
- Physical and Theoretical Chemistry
- General Physics and Astronomy
language:
- iso: eng
page: 29070-29079
publication: Physical Chemistry Chemical Physics
publication_identifier:
  issn:
  - 1463-9076
  - 1463-9084
publication_status: published
publisher: Royal Society of Chemistry (RSC)
quality_controlled: '1'
status: public
title: Threshold photoelectron spectroscopy and dissociative photoionization of benzonitrile
type: journal_article
user_id: '98339'
volume: 25
year: '2023'
...
---
_id: '44231'
abstract:
- lang: eng
  text: <jats:p>A new decomposition mechanism for trimethylborane at high temperatures
    has been discovered.</jats:p>
author:
- first_name: Domenik
  full_name: Schleier, Domenik
  id: '98339'
  last_name: Schleier
- first_name: Marius
  full_name: Gerlach, Marius
  last_name: Gerlach
- first_name: Dorothee
  full_name: Schaffner, Dorothee
  last_name: Schaffner
- first_name: Deb Pratim
  full_name: Mukhopadhyay, Deb Pratim
  last_name: Mukhopadhyay
- first_name: Patrick
  full_name: Hemberger, Patrick
  last_name: Hemberger
- first_name: Ingo
  full_name: Fischer, Ingo
  last_name: Fischer
citation:
  ama: Schleier D, Gerlach M, Schaffner D, Mukhopadhyay DP, Hemberger P, Fischer I.
    Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products.
    <i>Physical Chemistry Chemical Physics</i>. 2022;25(6):4511-4518. doi:<a href="https://doi.org/10.1039/d2cp04513c">10.1039/d2cp04513c</a>
  apa: Schleier, D., Gerlach, M., Schaffner, D., Mukhopadhyay, D. P., Hemberger, P.,
    &#38; Fischer, I. (2022). Threshold photoelectron spectroscopy of trimethylborane
    and its pyrolysis products. <i>Physical Chemistry Chemical Physics</i>, <i>25</i>(6),
    4511–4518. <a href="https://doi.org/10.1039/d2cp04513c">https://doi.org/10.1039/d2cp04513c</a>
  bibtex: '@article{Schleier_Gerlach_Schaffner_Mukhopadhyay_Hemberger_Fischer_2022,
    title={Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis
    products}, volume={25}, DOI={<a href="https://doi.org/10.1039/d2cp04513c">10.1039/d2cp04513c</a>},
    number={6}, journal={Physical Chemistry Chemical Physics}, publisher={Royal Society
    of Chemistry (RSC)}, author={Schleier, Domenik and Gerlach, Marius and Schaffner,
    Dorothee and Mukhopadhyay, Deb Pratim and Hemberger, Patrick and Fischer, Ingo},
    year={2022}, pages={4511–4518} }'
  chicago: 'Schleier, Domenik, Marius Gerlach, Dorothee Schaffner, Deb Pratim Mukhopadhyay,
    Patrick Hemberger, and Ingo Fischer. “Threshold Photoelectron Spectroscopy of
    Trimethylborane and Its Pyrolysis Products.” <i>Physical Chemistry Chemical Physics</i>
    25, no. 6 (2022): 4511–18. <a href="https://doi.org/10.1039/d2cp04513c">https://doi.org/10.1039/d2cp04513c</a>.'
  ieee: 'D. Schleier, M. Gerlach, D. Schaffner, D. P. Mukhopadhyay, P. Hemberger,
    and I. Fischer, “Threshold photoelectron spectroscopy of trimethylborane and its
    pyrolysis products,” <i>Physical Chemistry Chemical Physics</i>, vol. 25, no.
    6, pp. 4511–4518, 2022, doi: <a href="https://doi.org/10.1039/d2cp04513c">10.1039/d2cp04513c</a>.'
  mla: Schleier, Domenik, et al. “Threshold Photoelectron Spectroscopy of Trimethylborane
    and Its Pyrolysis Products.” <i>Physical Chemistry Chemical Physics</i>, vol.
    25, no. 6, Royal Society of Chemistry (RSC), 2022, pp. 4511–18, doi:<a href="https://doi.org/10.1039/d2cp04513c">10.1039/d2cp04513c</a>.
  short: D. Schleier, M. Gerlach, D. Schaffner, D.P. Mukhopadhyay, P. Hemberger, I.
    Fischer, Physical Chemistry Chemical Physics 25 (2022) 4511–4518.
date_created: 2023-04-27T12:07:29Z
date_updated: 2023-11-13T08:00:47Z
doi: 10.1039/d2cp04513c
intvolume: '        25'
issue: '6'
keyword:
- Physical and Theoretical Chemistry
- General Physics and Astronomy
language:
- iso: eng
page: 4511-4518
publication: Physical Chemistry Chemical Physics
publication_identifier:
  issn:
  - 1463-9076
  - 1463-9084
publication_status: published
publisher: Royal Society of Chemistry (RSC)
quality_controlled: '1'
status: public
title: Threshold photoelectron spectroscopy of trimethylborane and its pyrolysis products
type: journal_article
user_id: '98339'
volume: 25
year: '2022'
...