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The structural power of reconfigurable circuits in the amoebot model. . <i>The Structural Power of Reconfigurable Circuits in the Amoebot Model. Nat. Comput. 23(4): 603-625 (2024)</i>, 603–625.","short":"C. Scheideler, A. Padalkin, D. Warner, The Structural Power of Reconfigurable Circuits in the Amoebot Model. Nat. Comput. 23(4): 603-625 (2024) (2024) 603–625.","bibtex":"@article{Scheideler_Padalkin_Warner_2024, title={The structural power of reconfigurable circuits in the amoebot model. }, journal={The structural power of reconfigurable circuits in the amoebot model. Nat. Comput. 23(4): 603-625 (2024)}, author={Scheideler, Christian and Padalkin, Andreas and Warner, Daniel}, year={2024}, pages={603–625} }","mla":"Scheideler, Christian, et al. “The Structural Power of Reconfigurable Circuits in the Amoebot Model. .” <i>The Structural Power of Reconfigurable Circuits in the Amoebot Model. Nat. Comput. 23(4): 603-625 (2024)</i>, 2024, pp. 603–25.","ieee":"C. Scheideler, A. Padalkin, and D. Warner, “The structural power of reconfigurable circuits in the amoebot model. ,” <i>The structural power of reconfigurable circuits in the amoebot model. Nat. Comput. 23(4): 603-625 (2024)</i>, pp. 603–625, 2024.","chicago":"Scheideler, Christian, Andreas Padalkin, and Daniel Warner. “The Structural Power of Reconfigurable Circuits in the Amoebot Model. .” <i>The Structural Power of Reconfigurable Circuits in the Amoebot Model. Nat. Comput. 23(4): 603-625 (2024)</i>, 2024, 603–25.","ama":"Scheideler C, Padalkin A, Warner D. The structural power of reconfigurable circuits in the amoebot model. . <i>The structural power of reconfigurable circuits in the amoebot model Nat Comput 23(4): 603-625 (2024)</i>. Published online 2024:603-625."},"page":"603 - 625","_id":"64100","user_id":"15578","department":[{"_id":"34"},{"_id":"7"},{"_id":"79"}],"language":[{"iso":"eng"}],"type":"journal_article","publication":"The structural power of reconfigurable circuits in the amoebot model. Nat. Comput. 23(4): 603-625 (2024)","status":"public"},{"title":"Routing schemes for hybrid communication networks. ","date_updated":"2026-02-11T09:12:57Z","date_created":"2026-02-10T10:00:43Z","author":[{"full_name":"Scheideler, Christian","id":"20792","last_name":"Scheideler","first_name":"Christian"},{"first_name":"Sam ","full_name":"Coy, Sam ","last_name":"Coy"},{"first_name":"Arthur ","last_name":"Czumaj","full_name":"Czumaj, Arthur "},{"full_name":"Schneider, Philipp ","last_name":"Schneider","first_name":"Philipp "},{"last_name":"Werthmann","full_name":"Werthmann, Julian","id":"50024","first_name":"Julian"}],"year":"2024","citation":{"ama":"Scheideler C, Coy S, Czumaj A, Schneider P, Werthmann J. Routing schemes for hybrid communication networks. . <i>Routing schemes for hybrid communication networks Theor Comput Sci 985: 114352 (2024)</i>. Published online 2024.","ieee":"C. Scheideler, S. Coy, A. Czumaj, P. Schneider, and J. Werthmann, “Routing schemes for hybrid communication networks. ,” <i>Routing schemes for hybrid communication networks. Theor. Comput. Sci. 985: 114352 (2024)</i>, 2024.","chicago":"Scheideler, Christian, Sam  Coy, Arthur  Czumaj, Philipp  Schneider, and Julian Werthmann. “Routing Schemes for Hybrid Communication Networks. .” <i>Routing Schemes for Hybrid Communication Networks. Theor. Comput. Sci. 985: 114352 (2024)</i>, 2024.","short":"C. Scheideler, S. Coy, A. Czumaj, P. Schneider, J. Werthmann, Routing Schemes for Hybrid Communication Networks. Theor. Comput. Sci. 985: 114352 (2024) (2024).","mla":"Scheideler, Christian, et al. “Routing Schemes for Hybrid Communication Networks. .” <i>Routing Schemes for Hybrid Communication Networks. Theor. Comput. Sci. 985: 114352 (2024)</i>, 2024.","bibtex":"@article{Scheideler_Coy_Czumaj_Schneider_Werthmann_2024, title={Routing schemes for hybrid communication networks. }, journal={Routing schemes for hybrid communication networks. Theor. Comput. Sci. 985: 114352 (2024)}, author={Scheideler, Christian and Coy, Sam  and Czumaj, Arthur  and Schneider, Philipp  and Werthmann, Julian}, year={2024} }","apa":"Scheideler, C., Coy, S., Czumaj, A., Schneider, P., &#38; Werthmann, J. (2024). Routing schemes for hybrid communication networks. . <i>Routing Schemes for Hybrid Communication Networks. Theor. Comput. Sci. 985: 114352 (2024)</i>."},"language":[{"iso":"eng"}],"_id":"64101","department":[{"_id":"34"},{"_id":"7"},{"_id":"79"}],"user_id":"15578","status":"public","publication":"Routing schemes for hybrid communication networks. Theor. Comput. Sci. 985: 114352 (2024)","type":"journal_article"},{"language":[{"iso":"eng"}],"department":[{"_id":"34"},{"_id":"7"},{"_id":"79"}],"user_id":"15578","_id":"64102","status":"public","type":"conference","title":"Invited Paper: Blockchains made Lightweight: A Median Rule for State Machine Replication. ","author":[{"first_name":"Christian","last_name":"Scheideler","id":"20792","full_name":"Scheideler, Christian"},{"full_name":"Dou, Jinfeng","id":"92888","last_name":"Dou","first_name":"Jinfeng"}],"date_created":"2026-02-10T10:04:11Z","publisher":"ApPLIED@PODC 2024","date_updated":"2026-02-11T09:12:28Z","citation":{"mla":"Scheideler, Christian, and Jinfeng Dou. <i>Invited Paper: Blockchains Made Lightweight: A Median Rule for State Machine Replication. </i>. ApPLIED@PODC 2024, 2024.","short":"C. Scheideler, J. Dou, in: ApPLIED@PODC 2024, 2024.","bibtex":"@inproceedings{Scheideler_Dou_2024, title={Invited Paper: Blockchains made Lightweight: A Median Rule for State Machine Replication. }, publisher={ApPLIED@PODC 2024}, author={Scheideler, Christian and Dou, Jinfeng}, year={2024} }","apa":"Scheideler, C., &#38; Dou, J. (2024). <i>Invited Paper: Blockchains made Lightweight: A Median Rule for State Machine Replication. </i>.","chicago":"Scheideler, Christian, and Jinfeng Dou. “Invited Paper: Blockchains Made Lightweight: A Median Rule for State Machine Replication. .” ApPLIED@PODC 2024, 2024.","ieee":"C. Scheideler and J. Dou, “Invited Paper: Blockchains made Lightweight: A Median Rule for State Machine Replication. ,” 2024.","ama":"Scheideler C, Dou J. Invited Paper: Blockchains made Lightweight: A Median Rule for State Machine Replication. . In: ApPLIED@PODC 2024; 2024."},"year":"2024"},{"status":"public","type":"conference","language":[{"iso":"eng"}],"_id":"64105","user_id":"15578","department":[{"_id":"34"},{"_id":"7"},{"_id":"79"}],"place":"SAND 2024: 18:1-18:20","year":"2024","citation":{"ama":"Scheideler C, Padalkin A, Kumar  M. Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. . In: ; 2024.","chicago":"Scheideler, Christian, Andreas Padalkin, and Manish  Kumar . “Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. .” SAND 2024: 18:1-18:20, 2024.","ieee":"C. Scheideler, A. Padalkin, and M. Kumar , “Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. ,” 2024.","mla":"Scheideler, Christian, et al. <i>Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. </i>. 2024.","short":"C. Scheideler, A. Padalkin, M. Kumar , in: SAND 2024: 18:1-18:20, 2024.","bibtex":"@inproceedings{Scheideler_Padalkin_Kumar _2024, place={SAND 2024: 18:1-18:20}, title={Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. }, author={Scheideler, Christian and Padalkin, Andreas and Kumar , Manish }, year={2024} }","apa":"Scheideler, C., Padalkin, A., &#38; Kumar , M. (2024). <i>Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. </i>."},"title":"Reconfiguration and Locomotion with Joint Movements in the Amoebot Model. ","date_updated":"2026-02-11T09:12:18Z","date_created":"2026-02-10T10:15:08Z","author":[{"last_name":"Scheideler","id":"20792","full_name":"Scheideler, Christian","first_name":"Christian"},{"first_name":"Andreas","last_name":"Padalkin","full_name":"Padalkin, Andreas","id":"88238"},{"first_name":"Manish ","last_name":"Kumar ","full_name":"Kumar , Manish "}]},{"user_id":"64060","_id":"59337","file_date_updated":"2025-08-26T08:38:40Z","language":[{"iso":"ger"}],"keyword":["Mathematikfortbildungen","analytische Geometrie","Expertise"],"ddc":["510"],"publication":"Beiträge zum Mathematikunterricht 2024","type":"conference","status":"public","file":[{"date_updated":"2025-08-26T08:38:40Z","date_created":"2025-08-26T08:38:40Z","creator":"herrmann","file_size":57284,"file_name":"BzMU24_HERRMANN_Geometriefortbildungen.pdf","access_level":"closed","file_id":"61019","content_type":"application/pdf","success":1,"relation":"main_file"}],"abstract":[{"lang":"eng","text":"Im Rahmen der Fortbildungsinitiative QuaMath beschäftige ich mich mit der Entwicklung von Fortbildungsaktivitäten für den Inhaltsbereich der analytischen Geometrie. Um dies zu realisieren, stellt sich zunächst die Frage: Über welche Expertise verfügen (angehende) Lehrkräfte zum verstehensorientierten Unterrichten von anaGeo.? Dazu spezifiziere ich ein gegenstandsbezogenes Expertisemodell (Prediger) für den Unterricht zur anaGeo., erhebe Vorwissen von (angehenden) Lehrkräften und erprobe Aus- und Fortbildungsaktivitäten in verschiedenen Stichproben zur Rekonstruktion von Orientierungen."}],"date_created":"2025-04-04T06:29:02Z","author":[{"last_name":"Herrmann","full_name":"Herrmann, Janine","first_name":"Janine"}],"publisher":"LibreCat University","date_updated":"2026-02-13T09:36:13Z","conference":{"end_date":"2024-03-08","location":"Duisburg/Essen","name":"57. Jahrestagung der GdM","start_date":"2024-03-04"},"title":"Ansprüche an eine Fortbildung zur analytischen Geometrie","has_accepted_license":"1","citation":{"ama":"Herrmann J. Ansprüche an eine Fortbildung zur analytischen Geometrie. In: <i>Beiträge zum Mathematikunterricht 2024</i>. LibreCat University; 2024.","ieee":"J. Herrmann, “Ansprüche an eine Fortbildung zur analytischen Geometrie,” presented at the 57. Jahrestagung der GdM, Duisburg/Essen, 2024.","chicago":"Herrmann, Janine. “Ansprüche an eine Fortbildung zur analytischen Geometrie.” In <i>Beiträge zum Mathematikunterricht 2024</i>. LibreCat University, 2024.","apa":"Herrmann, J. (2024). Ansprüche an eine Fortbildung zur analytischen Geometrie. <i>Beiträge zum Mathematikunterricht 2024</i>. 57. Jahrestagung der GdM, Duisburg/Essen.","mla":"Herrmann, Janine. “Ansprüche an eine Fortbildung zur analytischen Geometrie.” <i>Beiträge zum Mathematikunterricht 2024</i>, LibreCat University, 2024.","short":"J. Herrmann, in: Beiträge zum Mathematikunterricht 2024, LibreCat University, 2024.","bibtex":"@inproceedings{Herrmann_2024, title={Ansprüche an eine Fortbildung zur analytischen Geometrie}, booktitle={Beiträge zum Mathematikunterricht 2024}, publisher={LibreCat University}, author={Herrmann, Janine}, year={2024} }"},"jel":["C"],"year":"2024"},{"department":[{"_id":"300"}],"user_id":"76955","_id":"58228","language":[{"iso":"eng"}],"type":"conference_abstract","status":"public","author":[{"first_name":"Mats","id":"76955","full_name":"Vernholz, Mats","orcid":"0000-0001-5175-357X","last_name":"Vernholz"},{"first_name":"Gabriela","full_name":"Jonas-Ahrend, Gabriela","id":"77633","orcid":"0000-0003-3898-954X","last_name":"Jonas-Ahrend"}],"date_created":"2025-01-17T06:16:35Z","date_updated":"2026-02-17T07:52:16Z","conference":{"start_date":"2024-09-19","name":"Jahrestagung 2024 der DGTB","location":"Halle (an der Saale)","end_date":"2024-09-20"},"title":"„Und ich sag mal, Theorie und Praxis ist zweierlei” – Wie können Praxisphasen Lehramtsstudierende auf zukünftige Anforderungen vorbereiten?","citation":{"ama":"Vernholz M, Jonas-Ahrend G. „Und ich sag mal, Theorie und Praxis ist zweierlei” – Wie können Praxisphasen Lehramtsstudierende auf zukünftige Anforderungen vorbereiten? In: ; 2024.","ieee":"M. Vernholz and G. Jonas-Ahrend, “„Und ich sag mal, Theorie und Praxis ist zweierlei” – Wie können Praxisphasen Lehramtsstudierende auf zukünftige Anforderungen vorbereiten?,” presented at the Jahrestagung 2024 der DGTB, Halle (an der Saale), 2024.","chicago":"Vernholz, Mats, and Gabriela Jonas-Ahrend. “„Und Ich Sag Mal, Theorie Und Praxis Ist Zweierlei” – Wie Können Praxisphasen Lehramtsstudierende Auf Zukünftige Anforderungen Vorbereiten?,” 2024.","bibtex":"@inproceedings{Vernholz_Jonas-Ahrend_2024, title={„Und ich sag mal, Theorie und Praxis ist zweierlei” – Wie können Praxisphasen Lehramtsstudierende auf zukünftige Anforderungen vorbereiten?}, author={Vernholz, Mats and Jonas-Ahrend, Gabriela}, year={2024} }","short":"M. Vernholz, G. Jonas-Ahrend, in: 2024.","mla":"Vernholz, Mats, and Gabriela Jonas-Ahrend. <i>„Und Ich Sag Mal, Theorie Und Praxis Ist Zweierlei” – Wie Können Praxisphasen Lehramtsstudierende Auf Zukünftige Anforderungen Vorbereiten?</i> 2024.","apa":"Vernholz, M., &#38; Jonas-Ahrend, G. (2024). <i>„Und ich sag mal, Theorie und Praxis ist zweierlei” – Wie können Praxisphasen Lehramtsstudierende auf zukünftige Anforderungen vorbereiten?</i> Jahrestagung 2024 der DGTB, Halle (an der Saale)."},"year":"2024"},{"issue":"32","year":"2024","citation":{"mla":"Wunder, Clemens, et al. “Sodium 4-Styrenesulfonyl(Trifluoromethanesulfonyl)Imide-Based Single-Ion Conducting Polymer Electrolyte Incorporating Molecular Transporters for Quasi-Solid-State Sodium Batteries.” <i>Journal of Materials Chemistry A</i>, vol. 12, no. 32, The Royal Society of Chemistry, 2024, pp. 20935–20946, doi:<a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>.","bibtex":"@article{Wunder_Lai_Šić_Gutmann_Vito_Buntkowsky_Zarrabeitia_Passerini_2024, title={Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries}, volume={12}, DOI={<a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>}, number={32}, journal={Journal of Materials Chemistry A}, publisher={The Royal Society of Chemistry}, author={Wunder, Clemens and Lai, Thanh-Loan and Šić, Edina and Gutmann, Torsten and Vito, Eric and Buntkowsky, Gerd and Zarrabeitia, Maider and Passerini, Stefano}, year={2024}, pages={20935–20946} }","short":"C. Wunder, T.-L. Lai, E. Šić, T. Gutmann, E. Vito, G. Buntkowsky, M. Zarrabeitia, S. Passerini, Journal of Materials Chemistry A 12 (2024) 20935–20946.","apa":"Wunder, C., Lai, T.-L., Šić, E., Gutmann, T., Vito, E., Buntkowsky, G., Zarrabeitia, M., &#38; Passerini, S. (2024). Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries. <i>Journal of Materials Chemistry A</i>, <i>12</i>(32), 20935–20946. <a href=\"https://doi.org/10.1039/D4TA02329C\">https://doi.org/10.1039/D4TA02329C</a>","ieee":"C. Wunder <i>et al.</i>, “Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries,” <i>Journal of Materials Chemistry A</i>, vol. 12, no. 32, pp. 20935–20946, 2024, doi: <a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>.","chicago":"Wunder, Clemens, Thanh-Loan Lai, Edina Šić, Torsten Gutmann, Eric Vito, Gerd Buntkowsky, Maider Zarrabeitia, and Stefano Passerini. “Sodium 4-Styrenesulfonyl(Trifluoromethanesulfonyl)Imide-Based Single-Ion Conducting Polymer Electrolyte Incorporating Molecular Transporters for Quasi-Solid-State Sodium Batteries.” <i>Journal of Materials Chemistry A</i> 12, no. 32 (2024): 20935–20946. <a href=\"https://doi.org/10.1039/D4TA02329C\">https://doi.org/10.1039/D4TA02329C</a>.","ama":"Wunder C, Lai T-L, Šić E, et al. Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries. <i>Journal of Materials Chemistry A</i>. 2024;12(32):20935–20946. doi:<a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>"},"intvolume":"        12","page":"20935–20946","date_updated":"2026-02-17T16:12:37Z","publisher":"The Royal Society of Chemistry","author":[{"first_name":"Clemens","last_name":"Wunder","full_name":"Wunder, Clemens"},{"full_name":"Lai, Thanh-Loan","last_name":"Lai","first_name":"Thanh-Loan"},{"full_name":"Šić, Edina","last_name":"Šić","first_name":"Edina"},{"full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann","first_name":"Torsten"},{"first_name":"Eric","full_name":"Vito, Eric","last_name":"Vito"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"},{"full_name":"Zarrabeitia, Maider","last_name":"Zarrabeitia","first_name":"Maider"},{"full_name":"Passerini, Stefano","last_name":"Passerini","first_name":"Stefano"}],"date_created":"2026-02-07T16:19:39Z","volume":12,"title":"Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries","doi":"10.1039/D4TA02329C","type":"journal_article","publication":"Journal of Materials Chemistry A","abstract":[{"lang":"eng","text":"Sodium batteries are an attractive alternative for future energy storage as they can be produced with abundant and low-cost materials. Nonetheless, sodium-ion batteries (SIBs) are often composed of flammable and volatile carbonate-based liquid electrolytes. Polymer electrolytes have attracted significant attention as safer alternatives. Among polymer electrolytes, single-ion conductive polymer electrolytes (SIPEs) are considered particularly interesting because they can suppress dendrite growth, enabling high-performance (quasi)-solid-state sodium–(metal) batteries. In this work, a self-standing, flexible, quasi-solid-state SIPE is investigated, which is composed of sodium 4-styrene sulfonyl (trifluoromethanesulfonyl) imide (NaSTFSI), pentaerythritol tetrakis(3-mercaptopropionate) (PETMP) and pentaerythritol tetraacrylate (PET4A) blended with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP). The SIPE membrane, including 50 wt% of molecular transporter, exhibits ionic conductivity of 1.4 × 10−5 S cm−1 and 1.3 × 10−4 S cm−1 at 20 °C and 90 °C, respectively, thermal stability up to 280 °C, electrochemical stability window up to 4.5 V vs. Na/Na+, and Na plating/stripping reversibility in symmetric Na‖Na cells. The manufactured SIPE implemented in Prussian White (PW)‖Na cells enables the delivery of 147 mA h g−1 of PW at 15 mA g−1 with a Coulombic efficiency of over 99%, which is comparable with the PW‖Na cells using liquid carbonate electrolyte, confirming the suitability of the designed SIPE for sodium–(metal) batteries."}],"status":"public","_id":"64063","user_id":"100715","extern":"1","language":[{"iso":"eng"}]},{"title":"Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques","doi":"10.1002/cctc.202401511","date_updated":"2026-02-17T16:12:41Z","publisher":"John Wiley & Sons, Ltd","date_created":"2026-02-07T16:18:53Z","author":[{"first_name":"Till","full_name":"Wissel, Till","last_name":"Wissel"},{"last_name":"Rösler","full_name":"Rösler, Lorenz","first_name":"Lorenz"},{"first_name":"Martin","full_name":"Brodrecht, Martin","last_name":"Brodrecht"},{"first_name":"Mark V.","full_name":"Höfler, Mark V.","last_name":"Höfler"},{"full_name":"Herr, Kevin","last_name":"Herr","first_name":"Kevin"},{"first_name":"Marcos","last_name":"Oliveira Jr.","full_name":"Oliveira Jr., Marcos"},{"first_name":"Vytautas","last_name":"Klimavicius","full_name":"Klimavicius, Vytautas"},{"last_name":"Ebert","full_name":"Ebert, Martin","first_name":"Martin"},{"first_name":"Hergen","last_name":"Breitzke","full_name":"Breitzke, Hergen"},{"first_name":"Markus","last_name":"Hoffmann","full_name":"Hoffmann, Markus"},{"first_name":"Gerd","last_name":"Buntkowsky","full_name":"Buntkowsky, Gerd"},{"id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann","first_name":"Torsten"}],"volume":17,"year":"2024","citation":{"ama":"Wissel T, Rösler L, Brodrecht M, et al. Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques. <i>ChemCatChem</i>. 2024;17:e202401511. doi:<a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>","ieee":"T. Wissel <i>et al.</i>, “Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques,” <i>ChemCatChem</i>, vol. 17, p. e202401511, 2024, doi: <a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>.","chicago":"Wissel, Till, Lorenz Rösler, Martin Brodrecht, Mark V. Höfler, Kevin Herr, Marcos Oliveira Jr., Vytautas Klimavicius, et al. “Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques.” <i>ChemCatChem</i> 17 (2024): e202401511. <a href=\"https://doi.org/10.1002/cctc.202401511\">https://doi.org/10.1002/cctc.202401511</a>.","apa":"Wissel, T., Rösler, L., Brodrecht, M., Höfler, M. V., Herr, K., Oliveira Jr., M., Klimavicius, V., Ebert, M., Breitzke, H., Hoffmann, M., Buntkowsky, G., &#38; Gutmann, T. (2024). Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques. <i>ChemCatChem</i>, <i>17</i>, e202401511. <a href=\"https://doi.org/10.1002/cctc.202401511\">https://doi.org/10.1002/cctc.202401511</a>","mla":"Wissel, Till, et al. “Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques.” <i>ChemCatChem</i>, vol. 17, John Wiley &#38; Sons, Ltd, 2024, p. e202401511, doi:<a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>.","bibtex":"@article{Wissel_Rösler_Brodrecht_Höfler_Herr_Oliveira Jr._Klimavicius_Ebert_Breitzke_Hoffmann_et al._2024, title={Novel Heterogeneous Pd Catalysts for Cross-Coupling Reactions in Biocompatible Media: Structural Insights from Solid-State NMR Techniques}, volume={17}, DOI={<a href=\"https://doi.org/10.1002/cctc.202401511\">10.1002/cctc.202401511</a>}, journal={ChemCatChem}, publisher={John Wiley &#38; Sons, Ltd}, author={Wissel, Till and Rösler, Lorenz and Brodrecht, Martin and Höfler, Mark V. and Herr, Kevin and Oliveira Jr., Marcos and Klimavicius, Vytautas and Ebert, Martin and Breitzke, Hergen and Hoffmann, Markus and et al.}, year={2024}, pages={e202401511} }","short":"T. Wissel, L. Rösler, M. Brodrecht, M.V. Höfler, K. Herr, M. Oliveira Jr., V. Klimavicius, M. Ebert, H. Breitzke, M. Hoffmann, G. Buntkowsky, T. Gutmann, ChemCatChem 17 (2024) e202401511."},"intvolume":"        17","page":"e202401511","publication_identifier":{"issn":["1867-3880"]},"keyword":["SBA-15","Heterogeneous catalyst","Pd cross-coupling","Polyethylene glycol","Solid-state DNP NMR"],"extern":"1","language":[{"iso":"eng"}],"_id":"64062","user_id":"100715","abstract":[{"lang":"eng","text":"Abstract Novel SBA-15-supported heterogeneous catalysts are synthesized and applied in the Mizoroki?Heck and the Suzuki?Miyaura cross-coupling reactions in green solvents like PEG or water. The structural properties of the products after each synthesis step are monitored by different analytics. The amount of amine/carboxyl groups and vanillin/histidine methyl ester and thermal stability are determined by TGA and elemental analysis, while ICP-OES delivered the amount of palladium of the catalysts. The morphology is investigated by SEM and XPS and confirms the presence of coordinated palladium in the zero-oxidation state. Gas adsorption analysis is conducted, which indicates the presence of palladium clusters in one of the two catalysts, which is underlined by BSE images combined with EDX. A detailed 13C ssNMR and DNP-enhanced 15N ssNMR spectral analysis is presented, which provides ultimate proof of the successful syntheses of the catalysts. The coordination of the palladium onto the carrier material is shown by combining the NMR spectral results with the results of the other analytics. First catalytic tests show for the Mizoroki?Heck reaction yields up to nearly 100% and for the Suzuki-Miyaura up to 88% in the presence of PEG and water, respectively."}],"status":"public","type":"journal_article","publication":"ChemCatChem"},{"doi":"10.1007/s00723-024-01643-1","title":"Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells","date_created":"2026-02-07T16:10:40Z","author":[{"last_name":"Šić","full_name":"Šić, Edina","first_name":"Edina"},{"first_name":"Dominion","full_name":"Fredericks, Dominion","last_name":"Fredericks"},{"full_name":"Pecher, Oliver","last_name":"Pecher","first_name":"Oliver"},{"full_name":"Wegner, Sebastian","last_name":"Wegner","first_name":"Sebastian"},{"first_name":"Hergen","last_name":"Breitzke","full_name":"Breitzke, Hergen"},{"full_name":"Singh, Vickram","last_name":"Singh","first_name":"Vickram"},{"full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky","first_name":"Gerd"},{"first_name":"Torsten","last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten"}],"date_updated":"2026-02-17T16:13:13Z","citation":{"apa":"Šić, E., Fredericks, D., Pecher, O., Wegner, S., Breitzke, H., Singh, V., Buntkowsky, G., &#38; Gutmann, T. (2024). Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells. <i>Applied Magnetic Resonance</i>, <i>55</i>, 575–583. <a href=\"https://doi.org/10.1007/s00723-024-01643-1\">https://doi.org/10.1007/s00723-024-01643-1</a>","short":"E. Šić, D. Fredericks, O. Pecher, S. Wegner, H. Breitzke, V. Singh, G. Buntkowsky, T. Gutmann, Applied Magnetic Resonance (2024) 575–583.","mla":"Šić, Edina, et al. “Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells.” <i>Applied Magnetic Resonance</i>, no. 55, 2024, pp. 575–583, doi:<a href=\"https://doi.org/10.1007/s00723-024-01643-1\">10.1007/s00723-024-01643-1</a>.","bibtex":"@article{Šić_Fredericks_Pecher_Wegner_Breitzke_Singh_Buntkowsky_Gutmann_2024, title={Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells}, DOI={<a href=\"https://doi.org/10.1007/s00723-024-01643-1\">10.1007/s00723-024-01643-1</a>}, number={55}, journal={Applied Magnetic Resonance}, author={Šić, Edina and Fredericks, Dominion and Pecher, Oliver and Wegner, Sebastian and Breitzke, Hergen and Singh, Vickram and Buntkowsky, Gerd and Gutmann, Torsten}, year={2024}, pages={575–583} }","ieee":"E. Šić <i>et al.</i>, “Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells,” <i>Applied Magnetic Resonance</i>, no. 55, pp. 575–583, 2024, doi: <a href=\"https://doi.org/10.1007/s00723-024-01643-1\">10.1007/s00723-024-01643-1</a>.","chicago":"Šić, Edina, Dominion Fredericks, Oliver Pecher, Sebastian Wegner, Hergen Breitzke, Vickram Singh, Gerd Buntkowsky, and Torsten Gutmann. “Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells.” <i>Applied Magnetic Resonance</i>, no. 55 (2024): 575–583. <a href=\"https://doi.org/10.1007/s00723-024-01643-1\">https://doi.org/10.1007/s00723-024-01643-1</a>.","ama":"Šić E, Fredericks D, Pecher O, et al. Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li\\textbarLiPF6\\textbarLFP Cells. <i>Applied Magnetic Resonance</i>. 2024;(55):575–583. doi:<a href=\"https://doi.org/10.1007/s00723-024-01643-1\">10.1007/s00723-024-01643-1</a>"},"page":"575–583","year":"2024","issue":"55","publication_identifier":{"issn":["1613-7507"]},"extern":"1","language":[{"iso":"eng"}],"user_id":"100715","_id":"64043","status":"public","abstract":[{"lang":"eng","text":"In this study, electrochemical processes in a Li{\\textbar}LiPF6{\\textbar}LFP cell have been explored applying advanced solid-state NMR technologies. In situ solid-state NMR allows to monitor structural changes in local environments in commercially available cell components during galvanostatic cycling. In collaboration with Dragonfly Energy, ePROBE GmbH and Bruker BioSpin GmbH & Co. KG, we have demonstrated an experimental procedure for routine application of in situ solid-state NMR for battery research. This points out the high potential of this approach for use in the energy storage industry."}],"type":"journal_article","publication":"Applied Magnetic Resonance"},{"issue":"8","page":"e202300950","intvolume":"        19","citation":{"mla":"Nasemann, Sina, et al. “At the Limits of Bisphosphonio-Substituted Stannylenes.” <i>Chemistry - An Asian Journal</i>, vol. 19, no. 8, John Wiley &#38; Sons, Ltd, 2024, p. e202300950, doi:<a href=\"https://doi.org/10.1002/asia.202300950\">10.1002/asia.202300950</a>.","short":"S. Nasemann, R. Franz, D. Kargin, C. Bruhn, Z. Kelemen, T. Gutmann, R. Pietschnig, Chemistry - An Asian Journal 19 (2024) e202300950.","bibtex":"@article{Nasemann_Franz_Kargin_Bruhn_Kelemen_Gutmann_Pietschnig_2024, title={At the limits of bisphosphonio-substituted stannylenes}, volume={19}, DOI={<a href=\"https://doi.org/10.1002/asia.202300950\">10.1002/asia.202300950</a>}, number={8}, journal={Chemistry - An Asian Journal}, publisher={John Wiley &#38; Sons, Ltd}, author={Nasemann, Sina and Franz, Roman and Kargin, Denis and Bruhn, Clemens and Kelemen, Zsolt and Gutmann, Torsten and Pietschnig, Rudolf}, year={2024}, pages={e202300950} }","apa":"Nasemann, S., Franz, R., Kargin, D., Bruhn, C., Kelemen, Z., Gutmann, T., &#38; Pietschnig, R. (2024). At the limits of bisphosphonio-substituted stannylenes. <i>Chemistry - An Asian Journal</i>, <i>19</i>(8), e202300950. <a href=\"https://doi.org/10.1002/asia.202300950\">https://doi.org/10.1002/asia.202300950</a>","ama":"Nasemann S, Franz R, Kargin D, et al. At the limits of bisphosphonio-substituted stannylenes. <i>Chemistry - An Asian Journal</i>. 2024;19(8):e202300950. doi:<a href=\"https://doi.org/10.1002/asia.202300950\">10.1002/asia.202300950</a>","ieee":"S. Nasemann <i>et al.</i>, “At the limits of bisphosphonio-substituted stannylenes,” <i>Chemistry - An Asian Journal</i>, vol. 19, no. 8, p. e202300950, 2024, doi: <a href=\"https://doi.org/10.1002/asia.202300950\">10.1002/asia.202300950</a>.","chicago":"Nasemann, Sina, Roman Franz, Denis Kargin, Clemens Bruhn, Zsolt Kelemen, Torsten Gutmann, and Rudolf Pietschnig. “At the Limits of Bisphosphonio-Substituted Stannylenes.” <i>Chemistry - An Asian Journal</i> 19, no. 8 (2024): e202300950. <a href=\"https://doi.org/10.1002/asia.202300950\">https://doi.org/10.1002/asia.202300950</a>."},"year":"2024","volume":19,"date_created":"2026-02-07T16:01:49Z","author":[{"first_name":"Sina","last_name":"Nasemann","full_name":"Nasemann, Sina"},{"last_name":"Franz","full_name":"Franz, Roman","first_name":"Roman"},{"full_name":"Kargin, Denis","last_name":"Kargin","first_name":"Denis"},{"full_name":"Bruhn, Clemens","last_name":"Bruhn","first_name":"Clemens"},{"first_name":"Zsolt","last_name":"Kelemen","full_name":"Kelemen, Zsolt"},{"full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann","first_name":"Torsten"},{"first_name":"Rudolf","full_name":"Pietschnig, Rudolf","last_name":"Pietschnig"}],"publisher":"John Wiley & Sons, Ltd","date_updated":"2026-02-17T16:14:49Z","doi":"10.1002/asia.202300950","title":"At the limits of bisphosphonio-substituted stannylenes","publication":"Chemistry - An Asian Journal","type":"journal_article","status":"public","abstract":[{"lang":"eng","text":"Abstract Donor stabilization of Sn(II) and Pb(II) halides with 1,1?-ferrocenylene bridged bisphosphanes has been explored for Fe(C5H4P(C6H5)2)2 (dppf), and Fe(C5H4PH(C4H9))2. These bisphosphanes are reacted with SnBr2 and PbCl2 with and without additional Lewis acid (AlCl3) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations."}],"user_id":"100715","_id":"64017","language":[{"iso":"eng"}],"extern":"1","keyword":["ferrocene","lead","phosphorus","tetrylene","tin"]},{"_id":"64020","user_id":"100715","extern":"1","language":[{"iso":"eng"}],"publication":"RSC Sustainability","type":"journal_article","abstract":[{"text":"Porous organic polymers enable a novel approach to incorporate xantphos into a solid macroligand. Immobilizing a ruthenium complex on the xantphos framework results in an excellent catalyst for the hydrogenation of CO2 to formic acid. Recycling experiments indicate a minor partial degradation of the heterogenous catalyst after a certain induction period, which is referred to its structural changes.","lang":"eng"}],"status":"public","publisher":"RSC","date_updated":"2026-02-17T16:14:40Z","volume":2,"date_created":"2026-02-07T16:03:21Z","author":[{"first_name":"Arne","full_name":"Nisters, Arne","last_name":"Nisters"},{"last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten","first_name":"Torsten"},{"first_name":"Sun-Myung","full_name":"Kim, Sun-Myung","last_name":"Kim"},{"full_name":"Hofmann, Jan Philipp","last_name":"Hofmann","first_name":"Jan Philipp"},{"first_name":"Marcus","last_name":"Rose","full_name":"Rose, Marcus"}],"title":"A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2","doi":"10.1039/D4SU00164H","issue":"8","year":"2024","intvolume":"         2","page":"2213–2217","citation":{"short":"A. Nisters, T. Gutmann, S.-M. Kim, J.P. Hofmann, M. Rose, RSC Sustainability 2 (2024) 2213–2217.","bibtex":"@article{Nisters_Gutmann_Kim_Hofmann_Rose_2024, title={A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2}, volume={2}, DOI={<a href=\"https://doi.org/10.1039/D4SU00164H\">10.1039/D4SU00164H</a>}, number={8}, journal={RSC Sustainability}, publisher={RSC}, author={Nisters, Arne and Gutmann, Torsten and Kim, Sun-Myung and Hofmann, Jan Philipp and Rose, Marcus}, year={2024}, pages={2213–2217} }","mla":"Nisters, Arne, et al. “A Solid Xantphos Macroligand Based on Porous Organic Polymers for the Catalytic Hydrogenation of CO2.” <i>RSC Sustainability</i>, vol. 2, no. 8, RSC, 2024, pp. 2213–2217, doi:<a href=\"https://doi.org/10.1039/D4SU00164H\">10.1039/D4SU00164H</a>.","apa":"Nisters, A., Gutmann, T., Kim, S.-M., Hofmann, J. P., &#38; Rose, M. (2024). A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2. <i>RSC Sustainability</i>, <i>2</i>(8), 2213–2217. <a href=\"https://doi.org/10.1039/D4SU00164H\">https://doi.org/10.1039/D4SU00164H</a>","ama":"Nisters A, Gutmann T, Kim S-M, Hofmann JP, Rose M. A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2. <i>RSC Sustainability</i>. 2024;2(8):2213–2217. doi:<a href=\"https://doi.org/10.1039/D4SU00164H\">10.1039/D4SU00164H</a>","ieee":"A. Nisters, T. Gutmann, S.-M. Kim, J. P. Hofmann, and M. Rose, “A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2,” <i>RSC Sustainability</i>, vol. 2, no. 8, pp. 2213–2217, 2024, doi: <a href=\"https://doi.org/10.1039/D4SU00164H\">10.1039/D4SU00164H</a>.","chicago":"Nisters, Arne, Torsten Gutmann, Sun-Myung Kim, Jan Philipp Hofmann, and Marcus Rose. “A Solid Xantphos Macroligand Based on Porous Organic Polymers for the Catalytic Hydrogenation of CO2.” <i>RSC Sustainability</i> 2, no. 8 (2024): 2213–2217. <a href=\"https://doi.org/10.1039/D4SU00164H\">https://doi.org/10.1039/D4SU00164H</a>."}},{"date_updated":"2026-02-17T16:15:41Z","volume":432,"date_created":"2026-02-07T15:53:56Z","author":[{"first_name":"Benny","full_name":"Kunkel, Benny","last_name":"Kunkel"},{"full_name":"Seeburg, Dominik","last_name":"Seeburg","first_name":"Dominik"},{"first_name":"Anke","last_name":"Kabelitz","full_name":"Kabelitz, Anke"},{"last_name":"Witte","full_name":"Witte, Steffen","first_name":"Steffen"},{"first_name":"Torsten","full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann"},{"full_name":"Breitzke, Hergen","last_name":"Breitzke","first_name":"Hergen"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"},{"first_name":"Ana Guilherme","full_name":"Buzanich, Ana Guilherme","last_name":"Buzanich"},{"first_name":"Sebastian","last_name":"Wohlrab","full_name":"Wohlrab, Sebastian"}],"title":"Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane","doi":"10.1016/j.cattod.2024.114643","year":"2024","intvolume":"       432","page":"114643","citation":{"chicago":"Kunkel, Benny, Dominik Seeburg, Anke Kabelitz, Steffen Witte, Torsten Gutmann, Hergen Breitzke, Gerd Buntkowsky, Ana Guilherme Buzanich, and Sebastian Wohlrab. “Highly Productive V/Zn-SiO2 Catalysts for the Selective Oxidation of Methane.” <i>Catalysis Today</i> 432 (2024): 114643. <a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">https://doi.org/10.1016/j.cattod.2024.114643</a>.","ieee":"B. Kunkel <i>et al.</i>, “Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane,” <i>Catalysis Today</i>, vol. 432, p. 114643, 2024, doi: <a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>.","ama":"Kunkel B, Seeburg D, Kabelitz A, et al. Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane. <i>Catalysis Today</i>. 2024;432:114643. doi:<a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>","apa":"Kunkel, B., Seeburg, D., Kabelitz, A., Witte, S., Gutmann, T., Breitzke, H., Buntkowsky, G., Buzanich, A. G., &#38; Wohlrab, S. (2024). Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane. <i>Catalysis Today</i>, <i>432</i>, 114643. <a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">https://doi.org/10.1016/j.cattod.2024.114643</a>","short":"B. Kunkel, D. Seeburg, A. Kabelitz, S. Witte, T. Gutmann, H. Breitzke, G. Buntkowsky, A.G. Buzanich, S. Wohlrab, Catalysis Today 432 (2024) 114643.","mla":"Kunkel, Benny, et al. “Highly Productive V/Zn-SiO2 Catalysts for the Selective Oxidation of Methane.” <i>Catalysis Today</i>, vol. 432, 2024, p. 114643, doi:<a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>.","bibtex":"@article{Kunkel_Seeburg_Kabelitz_Witte_Gutmann_Breitzke_Buntkowsky_Buzanich_Wohlrab_2024, title={Highly productive V/Zn-SiO2 catalysts for the selective oxidation of methane}, volume={432}, DOI={<a href=\"https://doi.org/10.1016/j.cattod.2024.114643\">10.1016/j.cattod.2024.114643</a>}, journal={Catalysis Today}, author={Kunkel, Benny and Seeburg, Dominik and Kabelitz, Anke and Witte, Steffen and Gutmann, Torsten and Breitzke, Hergen and Buntkowsky, Gerd and Buzanich, Ana Guilherme and Wohlrab, Sebastian}, year={2024}, pages={114643} }"},"_id":"64002","user_id":"100715","keyword":["Formaldehyde","Local coordination","SBA-15","Vanadium oxo species","XANES","Zinc doped silica"],"language":[{"iso":"eng"}],"extern":"1","publication":"Catalysis Today","type":"journal_article","abstract":[{"text":"The production of formaldehyde on industrial scale requires huge amounts of energy due to the involvement of reforming processes in combination with the demand in the megaton scale. Hence, a direct route for the transformation of (bio)methane to formaldehyde would decrease costs and puts less pressure on the environment. Herein, we report on the use of zinc modified silicas as possible support materials for vanadium catalysts and the resulting consequences for the performance in the selective oxidation of methane to formaldehyde. After optimization of the Zn content and reaction conditions, a remarkably high space-time yield of 12.4 kgCH2O·kgcat−1·h−1 was achieved. As a result of the extensive characterization by means of UV–vis, Raman, XANES and NMR spectroscopy it was found that vanadium is in the vicinity of highly dispersed zinc atoms which promote the formation of active vanadium species as supposed by theoretical calculations. This work presents a further step of catalyst development towards direct industrial methane conversion which may help to overcome current limitations in the future.","lang":"eng"}],"status":"public"},{"publication_identifier":{"issn":["1433-7851"]},"citation":{"apa":"Hutsch, S., Leonard, A., Grätz, S., Höfler, M. V., Gutmann, T., &#38; Borchardt, L. (2024). Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode. <i>Angewandte Chemie-International Edition</i>. <a href=\"https://doi.org/10.1002/anie.202403649\">https://doi.org/10.1002/anie.202403649</a>","short":"S. Hutsch, A. Leonard, S. Grätz, M.V. Höfler, T. Gutmann, L. Borchardt, Angewandte Chemie-International Edition (2024).","bibtex":"@article{Hutsch_Leonard_Grätz_Höfler_Gutmann_Borchardt_2024, title={Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode}, DOI={<a href=\"https://doi.org/10.1002/anie.202403649\">10.1002/anie.202403649</a>}, journal={Angewandte Chemie-International Edition}, author={Hutsch, S. and Leonard, A. and Grätz, S. and Höfler, M. V. and Gutmann, Torsten and Borchardt, L.}, year={2024} }","mla":"Hutsch, S., et al. “Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode.” <i>Angewandte Chemie-International Edition</i>, 2024, doi:<a href=\"https://doi.org/10.1002/anie.202403649\">10.1002/anie.202403649</a>.","ama":"Hutsch S, Leonard A, Grätz S, Höfler MV, Gutmann T, Borchardt L. Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode. <i>Angewandte Chemie-International Edition</i>. Published online 2024. doi:<a href=\"https://doi.org/10.1002/anie.202403649\">10.1002/anie.202403649</a>","chicago":"Hutsch, S., A. Leonard, S. Grätz, M. V. Höfler, Torsten Gutmann, and L. Borchardt. “Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode.” <i>Angewandte Chemie-International Edition</i>, 2024. <a href=\"https://doi.org/10.1002/anie.202403649\">https://doi.org/10.1002/anie.202403649</a>.","ieee":"S. Hutsch, A. Leonard, S. Grätz, M. V. Höfler, T. Gutmann, and L. Borchardt, “Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode,” <i>Angewandte Chemie-International Edition</i>, 2024, doi: <a href=\"https://doi.org/10.1002/anie.202403649\">10.1002/anie.202403649</a>."},"year":"2024","author":[{"full_name":"Hutsch, S.","last_name":"Hutsch","first_name":"S."},{"first_name":"A.","full_name":"Leonard, A.","last_name":"Leonard"},{"first_name":"S.","last_name":"Grätz","full_name":"Grätz, S."},{"first_name":"M. V.","last_name":"Höfler","full_name":"Höfler, M. V."},{"first_name":"Torsten","last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165"},{"full_name":"Borchardt, L.","last_name":"Borchardt","first_name":"L."}],"date_created":"2026-02-07T15:46:50Z","date_updated":"2026-02-17T16:16:38Z","doi":"10.1002/anie.202403649","title":"Mechanochemical Cyclotrimerization: A Versatile Tool to Covalent Organic Frameworks with Tunable Stacking Mode","publication":"Angewandte Chemie-International Edition","type":"journal_article","status":"public","abstract":[{"lang":"eng","text":"We introduce the first mechanochemical cyclotrimerization of nitriles, a facile strategy for synthesizing triazine-containing molecules and materials, overcoming challenges related to carbonization and solubility. Conducting this solid-state approach in a mixer ball mill with 4-Methylbenzonitrile, we synthesize Tris(4-methylphenyl)-1,3,5-triazine quantitatively in as little as 90 minutes. Just as fast, this mechanochemical method facilitates the synthesis of the covalent triazine framework CTF-1 using 1,4 Dicyanobenzene. Material characterization confirms its porous (650 m2 g-1) and crystalline nature. Adjusting the induced mechanical energy allows control over the obtained stacking conformation of the resulting CTFs - from a staggered AB arrangement to an eclipsed AA stacking conformation. Finally, a substrate scope demonstrates the versatility of this approach, successfully yielding various CTFs. This work presents, for the first time, the mechanochemical cyclotrimerization of nitriles. Utilizing Trifluoromethanesulfonic acid and a ball mill, both small molecules and large organic frameworks could be obtained. Screening the reaction of 1,4-Dicyanobenzene by various parameters, such as reaction time, frequency, or temperature, significant impacts on the porosity of the polymer and its crystallinity were revealed. image"}],"user_id":"100715","_id":"63989","extern":"1","language":[{"iso":"eng"}]}]