--- _id: '40598' author: - first_name: Julian full_name: Rudisch, Julian last_name: Rudisch - first_name: Thomas full_name: Jöllenbeck, Thomas last_name: Jöllenbeck - first_name: Lutz full_name: Vogt, Lutz last_name: Vogt - first_name: Thomas full_name: Cordes, Thomas last_name: Cordes - first_name: Thomas Jürgen full_name: Klotzbier, Thomas Jürgen last_name: Klotzbier - first_name: Oliver full_name: Vogel, Oliver last_name: Vogel - first_name: Bettina full_name: Wollesen, Bettina last_name: Wollesen citation: ama: Rudisch J, Jöllenbeck T, Vogt L, et al. Agreement and consistency of five different clinical gait analysis systems in the assessment of spatiotemporal gait parameters. Gait &amp; Posture. 2021;85:55-64. doi:10.1016/j.gaitpost.2021.01.013 apa: Rudisch, J., Jöllenbeck, T., Vogt, L., Cordes, T., Klotzbier, T. J., Vogel, O., & Wollesen, B. (2021). Agreement and consistency of five different clinical gait analysis systems in the assessment of spatiotemporal gait parameters. Gait &amp; Posture, 85, 55–64. https://doi.org/10.1016/j.gaitpost.2021.01.013 bibtex: '@article{Rudisch_Jöllenbeck_Vogt_Cordes_Klotzbier_Vogel_Wollesen_2021, title={Agreement and consistency of five different clinical gait analysis systems in the assessment of spatiotemporal gait parameters}, volume={85}, DOI={10.1016/j.gaitpost.2021.01.013}, journal={Gait &amp; Posture}, publisher={Elsevier BV}, author={Rudisch, Julian and Jöllenbeck, Thomas and Vogt, Lutz and Cordes, Thomas and Klotzbier, Thomas Jürgen and Vogel, Oliver and Wollesen, Bettina}, year={2021}, pages={55–64} }' chicago: 'Rudisch, Julian, Thomas Jöllenbeck, Lutz Vogt, Thomas Cordes, Thomas Jürgen Klotzbier, Oliver Vogel, and Bettina Wollesen. “Agreement and Consistency of Five Different Clinical Gait Analysis Systems in the Assessment of Spatiotemporal Gait Parameters.” Gait &amp; Posture 85 (2021): 55–64. https://doi.org/10.1016/j.gaitpost.2021.01.013.' ieee: 'J. Rudisch et al., “Agreement and consistency of five different clinical gait analysis systems in the assessment of spatiotemporal gait parameters,” Gait &amp; Posture, vol. 85, pp. 55–64, 2021, doi: 10.1016/j.gaitpost.2021.01.013.' mla: Rudisch, Julian, et al. “Agreement and Consistency of Five Different Clinical Gait Analysis Systems in the Assessment of Spatiotemporal Gait Parameters.” Gait &amp; Posture, vol. 85, Elsevier BV, 2021, pp. 55–64, doi:10.1016/j.gaitpost.2021.01.013. short: J. Rudisch, T. Jöllenbeck, L. Vogt, T. Cordes, T.J. Klotzbier, O. Vogel, B. Wollesen, Gait &amp; Posture 85 (2021) 55–64. date_created: 2023-01-27T16:37:34Z date_updated: 2023-01-27T16:37:56Z department: - _id: '266' doi: 10.1016/j.gaitpost.2021.01.013 intvolume: ' 85' keyword: - Rehabilitation - Orthopedics and Sports Medicine - Biophysics language: - iso: eng page: 55-64 publication: Gait & Posture publication_identifier: issn: - 0966-6362 publication_status: published publisher: Elsevier BV status: public title: Agreement and consistency of five different clinical gait analysis systems in the assessment of spatiotemporal gait parameters type: journal_article user_id: '75770' volume: 85 year: '2021' ... --- _id: '39794' abstract: - lang: ger text: "In der Herausforderung Unterricht inklusionsbezogen weiterzuentwickeln, manifestiert sich unter anderem die Forderung nach der Qualifizierung von (angehenden) Lehrkräften bzgl. der Anwendung und Umsetzung einer alltagsintegrierten Diagnostik mit dem Ziel, Kinder individualisiert und gleichzeitig mit Bezug auf einen gemeinsamen Lerngegenstand zu unterrichten. Dabei ist ein didaktisch-diagnostisches Handeln aller Lehrkräfte gefordert, welches im Kontext einer professionellen und inklusionsorientierten Gestaltung sowie einer angemessenen Begleitung und Förderung von Lern- und Entwicklungsprozessen steht. In der Konzeption entsprechender Aus- und Weiterbildungsformate setzt das geplante Projekt DiPoSa (Didaktisch-diagnostische Potentiale des inklusionsorientierten Sachunterrichts) an. Ziel ist es durch einen Design-Based-Research-Ansatz (DBR) Videovignetten zu erstellen und zu evaluieren, mittels derer entsprechende Kompetenzen von (angehenden) Lehrkräften im Sachunterricht weiterentwickelt werden können. Dabei bietet insbesondere der Sachunterricht als vielperspektivisches Integrationsfach der Grundschule einen passenden Rahmen, kindliche Lernpotentiale als Ausgangspunkt für didaktisch-diagnostisches Handeln nutzbar zu machen. Denn in aktuellen inklusionsorientierten Ansätzen des Sachunterrichts sind sowohl reformpädagogisch orientierte als auch offene Konzepte und Modelle des adaptiven Unterrichts zu finden, die sich an den unterschiedlichen Programmatiken der Umsetzung von individueller Förderung orientieren. Im folgenden Beitrag werden die dem geplanten Projekt zugrundeliegenden theoretischen und empirischen Zugänge erläutert und die forschungsmethodische Umsetzung durch einen DBR-Ansatz als methodologische Basis für eine Theorie-Praxis-verzahnende Forschungsperspektive auf diagnostisches Handeln sowie die Förderung diagnostischer Handlungskompetenzen durch Videovignetten im Kontext der Aus- und Weiterbildung von (Sachunterrichts-)Lehrkräften diskutiert.\r\n \r\nAbstract\r\nThe challenge to further promote practices of inclusive teaching, requires the development of assessment literacy. Combined with the aim to teach all children in a collaborative learning environment, qualification of teachers (in training) in the application and implementation of formative assessment as an integrated daily routine is needed. Therefore, the project DiPoSa focuses on the development of appropriate training and qualification formats. The project heads to create and evaluate video vignettes using a design-based-research approach (DBR), which can then be used to further develop assessment literacy of teachers in social studies and science in primary education. As a multi-perspective integrative subject in elementary school social studies and science in primary education offers a suitable framework for practices of formative assessment taking children's learning potentials as a serious concern. Foundations can be seen in current inclusive approaches to social studies and science in primary education, where reform pedagogically orientation and open concepts can as well be found as models of adaptive teaching. Although there are different theoretical and programmatic implementations, both perspectives share an orientation towards individual support of children. With this in mind the following article tries to lay down the theoretical and empirical approaches of the planed project DiPoSa and discusses methodological foundations of the project. The discussion focuses on how assessment practices as well as assessment literacy can be promoted through a DBR research-design using video vignettes in the context of teacher education and qualification and rooting in a deepened science-practice partnership.Zusammenfassung englisch" alternative_title: - Potentials of formative assessment practices in social studies and science in inclusive primary education. Conceptual and methodological implications of a design-based-research-based approach for teacher education author: - first_name: René full_name: Schroeder, René last_name: Schroeder - first_name: Eva full_name: Blumberg, Eva last_name: Blumberg - first_name: Brigitte full_name: Kottmann, Brigitte id: '82466' last_name: Kottmann - first_name: Susanne full_name: Miller, Susanne last_name: Miller - first_name: Anne full_name: Reh, Anne last_name: Reh citation: ama: Schroeder R, Blumberg E, Kottmann B, Miller S, Reh A. Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung. QfI - Qualifizierung für Inklusion Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte. 2021;3(2). doi:10.21248/qfi.74 apa: Schroeder, R., Blumberg, E., Kottmann, B., Miller, S., & Reh, A. (2021). Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung. QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte, 3(2). https://doi.org/10.21248/qfi.74 bibtex: '@article{Schroeder_Blumberg_Kottmann_Miller_Reh_2021, title={Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung}, volume={3}, DOI={10.21248/qfi.74}, number={2}, journal={QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte}, author={Schroeder, René and Blumberg, Eva and Kottmann, Brigitte and Miller, Susanne and Reh, Anne}, year={2021} }' chicago: Schroeder, René, Eva Blumberg, Brigitte Kottmann, Susanne Miller, and Anne Reh. “Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung.” QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte 3, no. 2 (2021). https://doi.org/10.21248/qfi.74. ieee: 'R. Schroeder, E. Blumberg, B. Kottmann, S. Miller, and A. Reh, “Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung,” QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte, vol. 3, no. 2, 2021, doi: 10.21248/qfi.74.' mla: Schroeder, René, et al. “Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung.” QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte, vol. 3, no. 2, 2021, doi:10.21248/qfi.74. short: R. Schroeder, E. Blumberg, B. Kottmann, S. Miller, A. Reh, QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte 3 (2021). date_created: 2023-01-24T20:03:43Z date_updated: 2023-01-29T13:41:59Z ddc: - '370' department: - _id: '479' doi: 10.21248/qfi.74 has_accepted_license: '1' intvolume: ' 3' issue: '2' language: - iso: ger publication: QfI - Qualifizierung für Inklusion. Online-Zeitschrift zur Forschung über Aus-, Fort- und Weiterbildung pädagogischer Fachkräfte publication_identifier: eissn: - 2699-2477 publication_status: published status: public title: Chancen des inklusionsorientierten Sachunterrichts für didaktisch-diagnostisches Handeln. Konzeptionelle und methodologisch-methodische Grundlagen eines forschungsbasierten Entwicklungsansatzes für die Lehrer*innenbildung type: journal_article user_id: '77753' volume: 3 year: '2021' ... --- _id: '39809' abstract: - lang: ger text: "In dem Beitrag wird ausgehend von der Notwendigkeit einer inklusionspädagogischen Professionalisierung im Lehramtsstudium ein erziehungswissenschaftliches Projekt dargestellt, das es den teilnehmenden Bachelor-Studierenden in besonderer Weise ermöglicht, berufsspezifische Reflexionsprozesse zu durchlaufen. In dem Projekt übernehmen Studierende die einjährige pädagogische Förderung von Grundschulkindern mit bildungsrelevanten Benachteiligungsfaktoren, die häufig von Selektionspraktiken und -maßnahmen bedroht sind. Die Bearbeitung von vorliegenden Common-Sense-Theorien im inklusiven Kontext gilt dabei als ein relevantes Professionalisierungsziel in der Lehramtsausbildung. Konkret werden Ausschnitte aus Praktikumsberichten von zwei Studierenden mittels der dokumentarischen Methode ausgewertet und einander gegenübergestellt, um daran herauszuarbeiten, inwiefern sich die Reflexionen unterscheiden. Es zeigt sich anhand der Analysen, dass im Rahmen der Praxisphase eine Reflection-on-Action und auch die vertiefte Reflexion eigener Common-Sense-Theorien grundsätzlich möglich, jedoch nicht voraussetzungslos ist. Insbesondere kann auch anhand der gewählten Einzelfälle verdeutlicht werden, wie individuell inklusionsbezogene Professionalisierungsprozesse im Rahmen der vorliegenden Praxisphase verlaufen können. Die Analyse offenbart multiple Professionalisierungschancen in Abhängigkeit von den Rahmenbedingungen des Projekts, den individuellen Schwerpunkten der pädagogischen Arbeit oder den individuellen Reflexionen der Studierenden.\r\nAbstract\r\nBased on the necessity of an inclusive pedagogical professionalisation in the teacher training program, this article presents an educational science project that enables the participating Bachelor students in a unique manner to go through profession-specific reflection processes. In the project, students take on the one-year pedagogical support of primary school children with educational disadvantage factors, who are often threatened by selection practices and measures. In this context, working through present common-sense theories in an inclusive context is considered a relevant professionalization goal in teacher education. Specifically, excerpts from internship reports of two students are analysed by means of the documentary method and compared to each other in order to work out the extent to which the reflections differ. The analyses show that reflection-on-action and in-depth reflection on one's own common-sense theories are generally possible during the practical phase, but not without preconditions. In particular, the selected individual cases can be used to illustrate how individual inclusion-related professionalisation processes can take place within the framework of the present practical phase. The analysis reveals multiple opportunities for professionalisation depending on the general framework of the project, the individual focal points of the pedagogical work or the individual reflections of the students." author: - first_name: Anne full_name: Reh, Anne last_name: Reh - first_name: Brigitte full_name: Kottmann, Brigitte id: '82466' last_name: Kottmann - first_name: Susanne full_name: Miller, Susanne last_name: Miller citation: ama: 'Reh A, Kottmann B, Miller S. Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode. QfI - Qualifizierung für Inklusion. 2021;3(1). doi:10.21248/qfi.56' apa: 'Reh, A., Kottmann, B., & Miller, S. (2021). Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode. QfI - Qualifizierung für Inklusion, 3(1). https://doi.org/10.21248/qfi.56' bibtex: '@article{Reh_Kottmann_Miller_2021, title={Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode}, volume={3}, DOI={10.21248/qfi.56}, number={1}, journal={QfI - Qualifizierung für Inklusion}, author={Reh, Anne and Kottmann, Brigitte and Miller, Susanne}, year={2021} }' chicago: 'Reh, Anne, Brigitte Kottmann, and Susanne Miller. “Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode.” QfI - Qualifizierung für Inklusion 3, no. 1 (2021). https://doi.org/10.21248/qfi.56.' ieee: 'A. Reh, B. Kottmann, and S. Miller, “Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode,” QfI - Qualifizierung für Inklusion, vol. 3, no. 1, 2021, doi: 10.21248/qfi.56.' mla: 'Reh, Anne, et al. “Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode.” QfI - Qualifizierung für Inklusion, vol. 3, no. 1, 2021, doi:10.21248/qfi.56.' short: A. Reh, B. Kottmann, S. Miller, QfI - Qualifizierung für Inklusion 3 (2021). date_created: 2023-01-24T20:30:10Z date_updated: 2023-01-29T13:41:18Z ddc: - '370' department: - _id: '479' doi: 10.21248/qfi.56 has_accepted_license: '1' intvolume: ' 3' issue: '1' language: - iso: ger publication: QfI - Qualifizierung für Inklusion publication_status: published status: public title: 'Berufsspezifische Reflexionsprozesse durch Einzelfallarbeit im Projekt „Schule für alle": Analyse von zwei Praxisberichten mittels der Dokumentarischen Methode' type: journal_article user_id: '77753' volume: 3 year: '2021' ... --- _id: '39804' author: - first_name: Brigitte full_name: Kottmann, Brigitte id: '82466' last_name: Kottmann citation: ama: 'Kottmann B. Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf. In: Streese B, Werning R, eds. Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen. Vol 3. ; 2021:32-34.' apa: Kottmann, B. (2021). Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf. In B. Streese & R. Werning (Eds.), Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen (Vol. 3, pp. 32–34). bibtex: '@inbook{Kottmann_2021, title={Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf}, volume={3}, booktitle={Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen}, author={Kottmann, Brigitte}, editor={Streese, Bettina and Werning, Rolf}, year={2021}, pages={32–34} }' chicago: Kottmann, Brigitte. “Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf.” In Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen, edited by Bettina Streese and Rolf Werning, 3:32–34, 2021. ieee: B. Kottmann, “Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf,” in Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen, vol. 3, B. Streese and R. Werning, Eds. 2021, pp. 32–34. mla: Kottmann, Brigitte. “Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf.” Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen, edited by Bettina Streese and Rolf Werning, vol. 3, 2021, pp. 32–34. short: 'B. Kottmann, in: B. Streese, R. Werning (Eds.), Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen, 2021, pp. 32–34.' date_created: 2023-01-24T20:27:40Z date_updated: 2023-01-29T13:44:51Z department: - _id: '479' editor: - first_name: Bettina full_name: Streese, Bettina last_name: Streese - first_name: Rolf full_name: Werning, Rolf last_name: Werning intvolume: ' 3' language: - iso: ger page: 32-34 publication: Schule inklusiv - Vielfalt nutzen - Bildungsgerechtigkeit schaffen publication_status: published status: public title: Übergänge begleiten. Peer-Beratung beim Übergang für Lernende mit Förderbedarf type: book_chapter user_id: '77753' volume: 3 year: '2021' ... --- _id: '39814' author: - first_name: Brigitte full_name: Kottmann, Brigitte id: '82466' last_name: Kottmann citation: ama: 'Kottmann B. Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019). Zeitschrift für Heilpädagogik. 2021;4(2021):211-212.' apa: 'Kottmann, B. (2021). Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019). Zeitschrift für Heilpädagogik, 4(2021), 211–212.' bibtex: '@article{Kottmann_2021, title={Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019)}, volume={4}, number={2021}, journal={Zeitschrift für Heilpädagogik}, author={Kottmann, Brigitte}, year={2021}, pages={211–212} }' chicago: 'Kottmann, Brigitte. “Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019).” Zeitschrift für Heilpädagogik 4, no. 2021 (2021): 211–12.' ieee: 'B. Kottmann, “Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019),” Zeitschrift für Heilpädagogik, vol. 4, no. 2021, pp. 211–212, 2021.' mla: 'Kottmann, Brigitte. “Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019).” Zeitschrift für Heilpädagogik, vol. 4, no. 2021, 2021, pp. 211–12.' short: B. Kottmann, Zeitschrift für Heilpädagogik 4 (2021) 211–212. date_created: 2023-01-24T20:45:20Z date_updated: 2023-01-29T13:43:58Z department: - _id: '479' intvolume: ' 4' issue: '2021' language: - iso: ger page: 211-212 publication: Zeitschrift für Heilpädagogik publication_status: published status: public title: 'Rezension des Buches: "Sonderschule im Nationalsozialismus. Die Magdeburger Hilfsschule als Modell von Dagmar Hänsel (2019)' type: journal_article user_id: '77753' volume: 4 year: '2021' ... --- _id: '35758' author: - first_name: Elnaz full_name: Meydani, Elnaz last_name: Meydani - first_name: Christoph full_name: Düsing, Christoph last_name: Düsing - first_name: Matthias full_name: Trier, Matthias id: '72744' last_name: Trier citation: ama: 'Meydani E, Düsing C, Trier M. Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism. In: Lecture Notes in Information Systems and Organisation. Springer International Publishing; 2021. doi:10.1007/978-3-030-86797-3_5' apa: Meydani, E., Düsing, C., & Trier, M. (2021). Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism. In Lecture Notes in Information Systems and Organisation. Springer International Publishing. https://doi.org/10.1007/978-3-030-86797-3_5 bibtex: '@inbook{Meydani_Düsing_Trier_2021, place={Cham}, title={Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism}, DOI={10.1007/978-3-030-86797-3_5}, booktitle={Lecture Notes in Information Systems and Organisation}, publisher={Springer International Publishing}, author={Meydani, Elnaz and Düsing, Christoph and Trier, Matthias}, year={2021} }' chicago: 'Meydani, Elnaz, Christoph Düsing, and Matthias Trier. “Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism.” In Lecture Notes in Information Systems and Organisation. Cham: Springer International Publishing, 2021. https://doi.org/10.1007/978-3-030-86797-3_5.' ieee: 'E. Meydani, C. Düsing, and M. Trier, “Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism,” in Lecture Notes in Information Systems and Organisation, Cham: Springer International Publishing, 2021.' mla: Meydani, Elnaz, et al. “Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism.” Lecture Notes in Information Systems and Organisation, Springer International Publishing, 2021, doi:10.1007/978-3-030-86797-3_5. short: 'E. Meydani, C. Düsing, M. Trier, in: Lecture Notes in Information Systems and Organisation, Springer International Publishing, Cham, 2021.' date_created: 2023-01-10T10:27:20Z date_updated: 2023-01-29T23:19:40Z department: - _id: '198' doi: 10.1007/978-3-030-86797-3_5 language: - iso: eng place: Cham publication: Lecture Notes in Information Systems and Organisation publication_identifier: isbn: - '9783030867966' - '9783030867973' issn: - 2195-4968 - 2195-4976 publication_status: published publisher: Springer International Publishing status: public title: Towards a Trust-Aware Item Recommendation System on a Graph Autoencoder with Attention Mechanism type: book_chapter user_id: '14931' year: '2021' ... --- _id: '37936' author: - first_name: Emanuele full_name: Pelucchi, Emanuele last_name: Pelucchi - first_name: Giorgos full_name: Fagas, Giorgos last_name: Fagas - first_name: Igor full_name: Aharonovich, Igor last_name: Aharonovich - first_name: Dirk full_name: Englund, Dirk last_name: Englund - first_name: Eden full_name: Figueroa, Eden last_name: Figueroa - first_name: Qihuang full_name: Gong, Qihuang last_name: Gong - first_name: Hübel full_name: Hannes, Hübel last_name: Hannes - first_name: Jin full_name: Liu, Jin last_name: Liu - first_name: Chao-Yang full_name: Lu, Chao-Yang last_name: Lu - first_name: Nobuyuki full_name: Matsuda, Nobuyuki last_name: Matsuda - first_name: Jian-Wei full_name: Pan, Jian-Wei last_name: Pan - first_name: Florian full_name: Schreck, Florian last_name: Schreck - first_name: Fabio full_name: Sciarrino, Fabio last_name: Sciarrino - first_name: Christine full_name: Silberhorn, Christine id: '26263' last_name: Silberhorn - first_name: Jianwei full_name: Wang, Jianwei last_name: Wang - first_name: Klaus full_name: Jöns, Klaus id: '85353' last_name: Jöns citation: ama: Pelucchi E, Fagas G, Aharonovich I, et al. The potential and global outlook of integrated photonics for quantum technologies. Nature Reviews Physics. 2021;4(3):194-208. doi:10.1038/s42254-021-00398-z apa: Pelucchi, E., Fagas, G., Aharonovich, I., Englund, D., Figueroa, E., Gong, Q., Hannes, H., Liu, J., Lu, C.-Y., Matsuda, N., Pan, J.-W., Schreck, F., Sciarrino, F., Silberhorn, C., Wang, J., & Jöns, K. (2021). The potential and global outlook of integrated photonics for quantum technologies. Nature Reviews Physics, 4(3), 194–208. https://doi.org/10.1038/s42254-021-00398-z bibtex: '@article{Pelucchi_Fagas_Aharonovich_Englund_Figueroa_Gong_Hannes_Liu_Lu_Matsuda_et al._2021, title={The potential and global outlook of integrated photonics for quantum technologies}, volume={4}, DOI={10.1038/s42254-021-00398-z}, number={3}, journal={Nature Reviews Physics}, publisher={Springer Science and Business Media LLC}, author={Pelucchi, Emanuele and Fagas, Giorgos and Aharonovich, Igor and Englund, Dirk and Figueroa, Eden and Gong, Qihuang and Hannes, Hübel and Liu, Jin and Lu, Chao-Yang and Matsuda, Nobuyuki and et al.}, year={2021}, pages={194–208} }' chicago: 'Pelucchi, Emanuele, Giorgos Fagas, Igor Aharonovich, Dirk Englund, Eden Figueroa, Qihuang Gong, Hübel Hannes, et al. “The Potential and Global Outlook of Integrated Photonics for Quantum Technologies.” Nature Reviews Physics 4, no. 3 (2021): 194–208. https://doi.org/10.1038/s42254-021-00398-z.' ieee: 'E. Pelucchi et al., “The potential and global outlook of integrated photonics for quantum technologies,” Nature Reviews Physics, vol. 4, no. 3, pp. 194–208, 2021, doi: 10.1038/s42254-021-00398-z.' mla: Pelucchi, Emanuele, et al. “The Potential and Global Outlook of Integrated Photonics for Quantum Technologies.” Nature Reviews Physics, vol. 4, no. 3, Springer Science and Business Media LLC, 2021, pp. 194–208, doi:10.1038/s42254-021-00398-z. short: E. Pelucchi, G. Fagas, I. Aharonovich, D. Englund, E. Figueroa, Q. Gong, H. Hannes, J. Liu, C.-Y. Lu, N. Matsuda, J.-W. Pan, F. Schreck, F. Sciarrino, C. Silberhorn, J. Wang, K. Jöns, Nature Reviews Physics 4 (2021) 194–208. date_created: 2023-01-22T17:46:36Z date_updated: 2023-01-30T11:13:42Z department: - _id: '288' - _id: '15' - _id: '623' - _id: '230' doi: 10.1038/s42254-021-00398-z intvolume: ' 4' issue: '3' keyword: - General Physics and Astronomy language: - iso: eng page: 194-208 publication: Nature Reviews Physics publication_identifier: issn: - 2522-5820 publication_status: published publisher: Springer Science and Business Media LLC status: public title: The potential and global outlook of integrated photonics for quantum technologies type: journal_article user_id: '26263' volume: 4 year: '2021' ... --- _id: '40673' author: - first_name: Mohammad full_name: Soleymani, Mohammad last_name: Soleymani - first_name: Ignacio full_name: Santamaria, Ignacio last_name: Santamaria - first_name: Peter J full_name: Schreier, Peter J last_name: Schreier citation: ama: Soleymani M, Santamaria I, Schreier PJ. Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels. IEEE Access. 2021;9:96948–96963. apa: Soleymani, M., Santamaria, I., & Schreier, P. J. (2021). Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels. IEEE Access, 9, 96948–96963. bibtex: '@article{Soleymani_Santamaria_Schreier_2021, title={Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels}, volume={9}, journal={IEEE Access}, publisher={IEEE}, author={Soleymani, Mohammad and Santamaria, Ignacio and Schreier, Peter J}, year={2021}, pages={96948–96963} }' chicago: 'Soleymani, Mohammad, Ignacio Santamaria, and Peter J Schreier. “Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels.” IEEE Access 9 (2021): 96948–96963.' ieee: M. Soleymani, I. Santamaria, and P. J. Schreier, “Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels,” IEEE Access, vol. 9, pp. 96948–96963, 2021. mla: Soleymani, Mohammad, et al. “Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels.” IEEE Access, vol. 9, IEEE, 2021, pp. 96948–96963. short: M. Soleymani, I. Santamaria, P.J. Schreier, IEEE Access 9 (2021) 96948–96963. date_created: 2023-01-30T11:51:35Z date_updated: 2023-01-30T12:03:37Z department: - _id: '263' intvolume: ' 9' page: 96948–96963 publication: IEEE Access publisher: IEEE status: public title: Distributed Algorithms for Spectral and Energy-Efficiency Maximization of $K$-User Interference Channels type: journal_article user_id: '43497' volume: 9 year: '2021' ... --- _id: '40677' author: - first_name: Mohammad full_name: Soleymani, Mohammad last_name: Soleymani - first_name: Ignacio full_name: Santamaria, Ignacio last_name: Santamaria - first_name: Behrouz full_name: Maham, Behrouz last_name: Maham - first_name: Peter J full_name: Schreier, Peter J last_name: Schreier citation: ama: 'Soleymani M, Santamaria I, Maham B, Schreier PJ. Rate Region of the $K$-user MIMO Interference Channel with Imperfect Transmitters. In: Proc. 28th European Signal Processing Conference (EUSIPCO). ; 2021:1638–1642.' apa: Soleymani, M., Santamaria, I., Maham, B., & Schreier, P. J. (2021). Rate Region of the $K$-user MIMO Interference Channel with Imperfect Transmitters. Proc. 28th European Signal Processing Conference (EUSIPCO), 1638–1642. bibtex: '@inproceedings{Soleymani_Santamaria_Maham_Schreier_2021, title={Rate Region of the $K$-user MIMO Interference Channel with Imperfect Transmitters}, booktitle={Proc. 28th European Signal Processing Conference (EUSIPCO)}, author={Soleymani, Mohammad and Santamaria, Ignacio and Maham, Behrouz and Schreier, Peter J}, year={2021}, pages={1638–1642} }' chicago: Soleymani, Mohammad, Ignacio Santamaria, Behrouz Maham, and Peter J Schreier. “Rate Region of the $K$-User MIMO Interference Channel with Imperfect Transmitters.” In Proc. 28th European Signal Processing Conference (EUSIPCO), 1638–1642, 2021. ieee: M. Soleymani, I. Santamaria, B. Maham, and P. J. Schreier, “Rate Region of the $K$-user MIMO Interference Channel with Imperfect Transmitters,” in Proc. 28th European Signal Processing Conference (EUSIPCO), 2021, pp. 1638–1642. mla: Soleymani, Mohammad, et al. “Rate Region of the $K$-User MIMO Interference Channel with Imperfect Transmitters.” Proc. 28th European Signal Processing Conference (EUSIPCO), 2021, pp. 1638–1642. short: 'M. Soleymani, I. Santamaria, B. Maham, P.J. Schreier, in: Proc. 28th European Signal Processing Conference (EUSIPCO), 2021, pp. 1638–1642.' date_created: 2023-01-30T11:51:35Z date_updated: 2023-01-30T12:03:35Z department: - _id: '263' page: 1638–1642 publication: Proc. 28th European Signal Processing Conference (EUSIPCO) status: public title: Rate Region of the $K$-user MIMO Interference Channel with Imperfect Transmitters type: conference user_id: '43497' year: '2021' ... --- _id: '41092' author: - first_name: Harald full_name: Schroeter-Wittke, Harald id: '480' last_name: Schroeter-Wittke citation: ama: 'Schroeter-Wittke H. Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S. Praktische Theologie. 2021;56(2):61-62.' apa: 'Schroeter-Wittke, H. (2021). Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S. In Praktische Theologie (Vol. 56, Issue 2, pp. 61–62).' bibtex: '@article{Schroeter-Wittke_2021, title={Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S}, volume={56}, number={2}, journal={Praktische Theologie}, author={Schroeter-Wittke, Harald}, year={2021}, pages={61–62} }' chicago: 'Schroeter-Wittke, Harald. “Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S.” Praktische Theologie, 2021.' ieee: 'H. Schroeter-Wittke, “Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S,” Praktische Theologie, vol. 56, no. 2. pp. 61–62, 2021.' mla: 'Schroeter-Wittke, Harald. “Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S.” Praktische Theologie, vol. 56, no. 2, 2021, pp. 61–62.' short: H. Schroeter-Wittke, Praktische Theologie 56 (2021) 61–62. date_created: 2023-01-31T00:47:34Z date_updated: 2023-01-31T01:42:35Z intvolume: ' 56' issue: '2' language: - iso: ger page: 61-62 publication: Praktische Theologie publication_identifier: eissn: - 2198-0462 issn: - 0946-3518 publication_status: published status: public title: 'Nihil est sine sono (1. Kor. 14,10). Musik in interkulturellen Begegnungen. Reinhold Bernhardt / Verena Grüter (Hg.): Musik in interreligiösen Begegnungen, TVZ Zürich 2019, 216 S' type: review user_id: '480' volume: 56 year: '2021' ... --- _id: '41095' author: - first_name: Harald full_name: Schroeter-Wittke, Harald id: '480' last_name: Schroeter-Wittke citation: ama: 'Schroeter-Wittke H. 4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders. Göttinger Predigtmeditationen. 2021;75(3):391-397.' apa: 'Schroeter-Wittke, H. (2021). 4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders. Göttinger Predigtmeditationen, 75(3), 391–397.' bibtex: '@article{Schroeter-Wittke_2021, title={4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders}, volume={75}, number={3}, journal={Göttinger Predigtmeditationen}, author={Schroeter-Wittke, Harald}, year={2021}, pages={391–397} }' chicago: 'Schroeter-Wittke, Harald. “4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders.” Göttinger Predigtmeditationen 75, no. 3 (2021): 391–97.' ieee: 'H. Schroeter-Wittke, “4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders,” Göttinger Predigtmeditationen, vol. 75, no. 3, pp. 391–397, 2021.' mla: 'Schroeter-Wittke, Harald. “4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders.” Göttinger Predigtmeditationen, vol. 75, no. 3, 2021, pp. 391–97.' short: H. Schroeter-Wittke, Göttinger Predigtmeditationen 75 (2021) 391–397. date_created: 2023-01-31T00:54:13Z date_updated: 2023-01-31T01:42:29Z intvolume: ' 75' issue: '3' language: - iso: ger page: 391-397 publication: Göttinger Predigtmeditationen publication_identifier: eissn: - 2197-0815 issn: - 0340-6083 publication_status: published status: public title: '4. Sonntag nach Trinitatis (27.6.2021). Gen 50,15-21: Diplomatische Wahrheit oder : Am Ziel der Träume – alles anders' type: journal_article user_id: '480' volume: 75 year: '2021' ... --- _id: '41093' author: - first_name: Harald full_name: Schroeter-Wittke, Harald id: '480' last_name: Schroeter-Wittke citation: ama: 'Schroeter-Wittke H. Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021. Zeitschrift für Pädagogik und Theologie. 2021;73:319-326.' apa: 'Schroeter-Wittke, H. (2021). Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021. In Zeitschrift für Pädagogik und Theologie (Vol. 73, pp. 319–326).' bibtex: '@article{Schroeter-Wittke_2021, title={Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021}, volume={73}, journal={Zeitschrift für Pädagogik und Theologie}, author={Schroeter-Wittke, Harald}, year={2021}, pages={319–326} }' chicago: 'Schroeter-Wittke, Harald. “Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021.” Zeitschrift für Pädagogik und Theologie, 2021.' ieee: 'H. Schroeter-Wittke, “Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021,” Zeitschrift für Pädagogik und Theologie, vol. 73. pp. 319–326, 2021.' mla: 'Schroeter-Wittke, Harald. “Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021.” Zeitschrift für Pädagogik und Theologie, vol. 73, 2021, pp. 319–26.' short: H. Schroeter-Wittke, Zeitschrift für Pädagogik und Theologie 73 (2021) 319–326. date_created: 2023-01-31T00:48:59Z date_updated: 2023-01-31T01:42:25Z intvolume: ' 73' language: - iso: ger page: 319-326 publication: Zeitschrift für Pädagogik und Theologie publication_identifier: eissn: - 2366-7796 issn: - 1437-7160 publication_status: published status: public title: 'Das besondere Buch. Ralf Koerrenz und Tobias Nicklas (Hg.): Bildung. Jahrbuch für Biblische Theologie 35, Göttingen 2021' type: review user_id: '480' volume: 73 year: '2021' ... --- _id: '41002' abstract: - lang: eng text: Homogeneous catalysts immobilized on metal oxides often have different catalytic properties than in homogeneous solution. This can be either activating or deactivating and is often attributed to interactions of catalyst species with the metal oxide surface. However, few studies have ever demonstrated the effect that close associations of active sites with surfaces have on the catalytic activity. In this paper, we immobilize H2Ru(PPh3)2(Ph2P)2N–C3H6–Si(OEt)3 (3) on SiO2, Al2O3, and ZnO and interrogate the relationship to the surface using IR, MAS NMR, 1H–31P HETCOR, and XAS spectroscopies. We found that while there are close contacts between the P atoms of the complex and all three metal oxide surfaces, the Ru–H bond only reacts with oxygen bridges on SiO2 and Al2O3, forming new Ru–O bonds. In contrast, complex 3 stays intact on ZnO. Comparison of the catalytic activities of our immobilized species for CO2 hydrogenation to ethyl formate showed that Lewis acidic metal oxides activate, rather than deactivate, complex 3 in the order Al2O3 > ZnO > SiO2. The Lewis acidic sites on the metal oxide surfaces most likely increase the productivity by increasing the rate of esterification of formate intermediates. article_type: original author: - first_name: Hoang-Huy full_name: Nguyen, Hoang-Huy last_name: Nguyen - first_name: Zheng full_name: Li, Zheng last_name: Li - first_name: Toni full_name: Enenkel, Toni last_name: Enenkel - first_name: Joachim full_name: Hildebrand, Joachim last_name: Hildebrand - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Michael full_name: Dyballa, Michael last_name: Dyballa - first_name: Deven P. full_name: Estes, Deven P. last_name: Estes citation: ama: 'Nguyen H-H, Li Z, Enenkel T, et al. Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation. The Journal of Physical Chemistry C. 2021;125(27):14627-14635. doi:10.1021/acs.jpcc.1c02074' apa: 'Nguyen, H.-H., Li, Z., Enenkel, T., Hildebrand, J., Bauer, M., Dyballa, M., & Estes, D. P. (2021). Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation. The Journal of Physical Chemistry C, 125(27), 14627–14635. https://doi.org/10.1021/acs.jpcc.1c02074' bibtex: '@article{Nguyen_Li_Enenkel_Hildebrand_Bauer_Dyballa_Estes_2021, title={Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation}, volume={125}, DOI={10.1021/acs.jpcc.1c02074}, number={27}, journal={The Journal of Physical Chemistry C}, publisher={American Chemical Society (ACS)}, author={Nguyen, Hoang-Huy and Li, Zheng and Enenkel, Toni and Hildebrand, Joachim and Bauer, Matthias and Dyballa, Michael and Estes, Deven P.}, year={2021}, pages={14627–14635} }' chicago: 'Nguyen, Hoang-Huy, Zheng Li, Toni Enenkel, Joachim Hildebrand, Matthias Bauer, Michael Dyballa, and Deven P. Estes. “Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation.” The Journal of Physical Chemistry C 125, no. 27 (2021): 14627–35. https://doi.org/10.1021/acs.jpcc.1c02074.' ieee: 'H.-H. Nguyen et al., “Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation,” The Journal of Physical Chemistry C, vol. 125, no. 27, pp. 14627–14635, 2021, doi: 10.1021/acs.jpcc.1c02074.' mla: 'Nguyen, Hoang-Huy, et al. “Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation.” The Journal of Physical Chemistry C, vol. 125, no. 27, American Chemical Society (ACS), 2021, pp. 14627–35, doi:10.1021/acs.jpcc.1c02074.' short: H.-H. Nguyen, Z. Li, T. Enenkel, J. Hildebrand, M. Bauer, M. Dyballa, D.P. Estes, The Journal of Physical Chemistry C 125 (2021) 14627–14635. date_created: 2023-01-30T16:49:18Z date_updated: 2023-01-31T08:06:00Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.jpcc.1c02074 intvolume: ' 125' issue: '27' keyword: - Surfaces - Coatings and Films - Physical and Theoretical Chemistry - General Energy - Electronic - Optical and Magnetic Materials language: - iso: eng page: 14627-14635 publication: The Journal of Physical Chemistry C publication_identifier: issn: - 1932-7447 - 1932-7455 publication_status: published publisher: American Chemical Society (ACS) status: public title: 'Probing the Interactions of Immobilized Ruthenium Dihydride Complexes with Metal Oxide Surfaces by MAS NMR: Effects on CO2 Hydrogenation' type: journal_article user_id: '48467' volume: 125 year: '2021' ... --- _id: '40999' abstract: - lang: eng text: Rh(I) NHC and Rh(III) Cp* NHC complexes (Cp*=pentamethylcyclopentadienyl, NHC=N-heterocyclic carbene=pyrid-2-ylimidazol-2-ylidene (Py−Im), thiophen-2-ylimidazol-2-ylidene) are presented. Selected catalysts were selectively immobilized inside the mesopores of SBA-15 with average pore diameters of 5.0 and 6.2 nm. Together with their homogenous progenitors, the immobilized catalysts were used in the hydrosilylation of terminal alkynes. For aromatic alkynes, both the neutral and cationic Rh(I) complexes showed excellent reactivity with exclusive formation of the β(E)-isomer. For aliphatic alkynes, however, selectivity of the Rh(I) complexes was low. By contrast, the neutral and cationic Rh(III) Cp* NHC complexes proved to be highly regio- and stereoselective catalysts, allowing for the formation of the thermodynamically less stable β-(Z)-vinylsilane isomers at room temperature. Notably, the SBA-15 immobilized Rh(I) catalysts, in which the pore walls provide an additional confinement, showed excellent β-(Z)-selectivity in the hydrosilylation of aliphatic alkynes, too. Also, in the case of 4-aminophenylacetylene, selective formation of the β(Z)-isomer was observed with a neutral SBA-15 supported Rh(III) Cp* NHC complex but not with its homogenous counterpart. These are the first examples of high β(Z)-selectivity in the hydrosilylation of alkynes by confinement generated upon immobilization inside mesoporous silica. article_type: original author: - first_name: Pradeep K. R. full_name: Panyam, Pradeep K. R. last_name: Panyam - first_name: Boshra full_name: Atwi, Boshra last_name: Atwi - first_name: Felix full_name: Ziegler, Felix last_name: Ziegler - first_name: Wolfgang full_name: Frey, Wolfgang last_name: Frey - first_name: Michal full_name: Nowakowski, Michal last_name: Nowakowski - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Michael R. full_name: Buchmeiser, Michael R. last_name: Buchmeiser citation: ama: 'Panyam PKR, Atwi B, Ziegler F, et al. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal. 2021;27(68):17220-17229. doi:10.1002/chem.202103099' apa: 'Panyam, P. K. R., Atwi, B., Ziegler, F., Frey, W., Nowakowski, M., Bauer, M., & Buchmeiser, M. R. (2021). Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes. Chemistry – A European Journal, 27(68), 17220–17229. https://doi.org/10.1002/chem.202103099' bibtex: '@article{Panyam_Atwi_Ziegler_Frey_Nowakowski_Bauer_Buchmeiser_2021, title={Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes}, volume={27}, DOI={10.1002/chem.202103099}, number={68}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Panyam, Pradeep K. R. and Atwi, Boshra and Ziegler, Felix and Frey, Wolfgang and Nowakowski, Michal and Bauer, Matthias and Buchmeiser, Michael R.}, year={2021}, pages={17220–17229} }' chicago: 'Panyam, Pradeep K. R., Boshra Atwi, Felix Ziegler, Wolfgang Frey, Michal Nowakowski, Matthias Bauer, and Michael R. Buchmeiser. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal 27, no. 68 (2021): 17220–29. https://doi.org/10.1002/chem.202103099.' ieee: 'P. K. R. Panyam et al., “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes,” Chemistry – A European Journal, vol. 27, no. 68, pp. 17220–17229, 2021, doi: 10.1002/chem.202103099.' mla: 'Panyam, Pradeep K. R., et al. “Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes.” Chemistry – A European Journal, vol. 27, no. 68, Wiley, 2021, pp. 17220–29, doi:10.1002/chem.202103099.' short: P.K.R. Panyam, B. Atwi, F. Ziegler, W. Frey, M. Nowakowski, M. Bauer, M.R. Buchmeiser, Chemistry – A European Journal 27 (2021) 17220–17229. date_created: 2023-01-30T16:48:41Z date_updated: 2023-01-31T08:05:18Z department: - _id: '35' - _id: '306' doi: 10.1002/chem.202103099 intvolume: ' 27' issue: '68' keyword: - General Chemistry - Catalysis - Organic Chemistry language: - iso: eng page: 17220-17229 publication: Chemistry – A European Journal publication_identifier: issn: - 0947-6539 - 1521-3765 publication_status: published publisher: Wiley status: public title: 'Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes' type: journal_article user_id: '48467' volume: 27 year: '2021' ... --- _id: '41001' abstract: - lang: eng text: For entropic reasons, the synthesis of macrocycles via olefin ring-closing metathesis (RCM) is impeded by competing acyclic diene metathesis (ADMET) oligomerization. With cationic molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes confined in tailored ordered mesoporous silica, RCM can be run with macrocyclization selectivities up to 98% and high substrate concentrations up to 0.1 M. Molecular dynamics simulations show that the high conversions are a direct result of the proximity between the surface-bound catalyst, proven by extended X-ray absorption spectroscopy, and the surface-located substrates. Back-diffusion of the macrocycles decreases with decreasing pore diameter of the silica and is responsible for the high macrocyclization efficiency. Also, Z-selectivity increases with decreasing pore diameter and increasing Tolman electronic parameter of the NHC. Running reactions at different concentrations allows for identifying the optimum substrate concentration for each material and substrate combination. article_type: original author: - first_name: Felix full_name: Ziegler, Felix last_name: Ziegler - first_name: Hamzeh full_name: Kraus, Hamzeh last_name: Kraus - first_name: Mathis J. full_name: Benedikter, Mathis J. last_name: Benedikter - first_name: Dongren full_name: Wang, Dongren last_name: Wang - first_name: Johanna R. full_name: Bruckner, Johanna R. last_name: Bruckner - first_name: Michal full_name: Nowakowski, Michal last_name: Nowakowski - first_name: Kilian full_name: Weißer, Kilian last_name: Weißer - first_name: Helena full_name: Solodenko, Helena last_name: Solodenko - first_name: Guido full_name: Schmitz, Guido last_name: Schmitz - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Niels full_name: Hansen, Niels last_name: Hansen - first_name: Michael R. full_name: Buchmeiser, Michael R. last_name: Buchmeiser citation: ama: Ziegler F, Kraus H, Benedikter MJ, et al. Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes. ACS Catalysis. 2021;11(18):11570-11578. doi:10.1021/acscatal.1c03057 apa: Ziegler, F., Kraus, H., Benedikter, M. J., Wang, D., Bruckner, J. R., Nowakowski, M., Weißer, K., Solodenko, H., Schmitz, G., Bauer, M., Hansen, N., & Buchmeiser, M. R. (2021). Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes. ACS Catalysis, 11(18), 11570–11578. https://doi.org/10.1021/acscatal.1c03057 bibtex: '@article{Ziegler_Kraus_Benedikter_Wang_Bruckner_Nowakowski_Weißer_Solodenko_Schmitz_Bauer_et al._2021, title={Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes}, volume={11}, DOI={10.1021/acscatal.1c03057}, number={18}, journal={ACS Catalysis}, publisher={American Chemical Society (ACS)}, author={Ziegler, Felix and Kraus, Hamzeh and Benedikter, Mathis J. and Wang, Dongren and Bruckner, Johanna R. and Nowakowski, Michal and Weißer, Kilian and Solodenko, Helena and Schmitz, Guido and Bauer, Matthias and et al.}, year={2021}, pages={11570–11578} }' chicago: 'Ziegler, Felix, Hamzeh Kraus, Mathis J. Benedikter, Dongren Wang, Johanna R. Bruckner, Michal Nowakowski, Kilian Weißer, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis 11, no. 18 (2021): 11570–78. https://doi.org/10.1021/acscatal.1c03057.' ieee: 'F. Ziegler et al., “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes,” ACS Catalysis, vol. 11, no. 18, pp. 11570–11578, 2021, doi: 10.1021/acscatal.1c03057.' mla: Ziegler, Felix, et al. “Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes.” ACS Catalysis, vol. 11, no. 18, American Chemical Society (ACS), 2021, pp. 11570–78, doi:10.1021/acscatal.1c03057. short: F. Ziegler, H. Kraus, M.J. Benedikter, D. Wang, J.R. Bruckner, M. Nowakowski, K. Weißer, H. Solodenko, G. Schmitz, M. Bauer, N. Hansen, M.R. Buchmeiser, ACS Catalysis 11 (2021) 11570–11578. date_created: 2023-01-30T16:49:07Z date_updated: 2023-01-31T08:05:40Z department: - _id: '35' - _id: '306' doi: 10.1021/acscatal.1c03057 intvolume: ' 11' issue: '18' keyword: - Catalysis - General Chemistry language: - iso: eng page: 11570-11578 publication: ACS Catalysis publication_identifier: issn: - 2155-5435 - 2155-5435 publication_status: published publisher: American Chemical Society (ACS) status: public title: Confinement Effects for Efficient Macrocyclization Reactions with Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes type: journal_article user_id: '48467' volume: 11 year: '2021' ... --- _id: '40998' abstract: - lang: eng text: Covalent organic frameworks (COFs) offer vast structural and chemical diversity enabling a wide and growing range of applications. While COFs are well-established as heterogeneous catalysts, so far, their high and ordered porosity has scarcely been utilized to its full potential when it comes to spatially confined reactions in COF pores to alter the outcome of reactions. Here, we present a highly porous and crystalline, large-pore COF as catalytic support in α,ω-diene ring-closing metathesis reactions, leading to increased macrocyclization selectivity. COF pore-wall modification by immobilization of a Grubbs-Hoveyda-type catalyst via a mild silylation reaction provides a molecularly precise heterogeneous olefin metathesis catalyst. An increased macro(mono)cyclization (MMC) selectivity over oligomerization (O) for the heterogeneous COF-catalyst (MMC:O=1.35) of up to 51 % compared to the homogeneous catalyst (MMC:O=0.90) was observed along with a substrate-size dependency in selectivity, pointing to diffusion limitations induced by the pore confinement. article_type: original author: - first_name: Sebastian T. full_name: Emmerling, Sebastian T. last_name: Emmerling - first_name: Felix full_name: Ziegler, Felix last_name: Ziegler - first_name: Felix R. full_name: Fischer, Felix R. last_name: Fischer - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Bernd full_name: Plietker, Bernd last_name: Plietker - first_name: Michael R. full_name: Buchmeiser, Michael R. last_name: Buchmeiser - first_name: Bettina V. full_name: Lotsch, Bettina V. last_name: Lotsch citation: ama: 'Emmerling ST, Ziegler F, Fischer FR, et al. Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. Chemistry – A European Journal. 2021;28(8). doi:10.1002/chem.202104108' apa: 'Emmerling, S. T., Ziegler, F., Fischer, F. R., Schoch, R., Bauer, M., Plietker, B., Buchmeiser, M. R., & Lotsch, B. V. (2021). Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity. Chemistry – A European Journal, 28(8). https://doi.org/10.1002/chem.202104108' bibtex: '@article{Emmerling_Ziegler_Fischer_Schoch_Bauer_Plietker_Buchmeiser_Lotsch_2021, title={Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity}, volume={28}, DOI={10.1002/chem.202104108}, number={8}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Emmerling, Sebastian T. and Ziegler, Felix and Fischer, Felix R. and Schoch, Roland and Bauer, Matthias and Plietker, Bernd and Buchmeiser, Michael R. and Lotsch, Bettina V.}, year={2021} }' chicago: 'Emmerling, Sebastian T., Felix Ziegler, Felix R. Fischer, Roland Schoch, Matthias Bauer, Bernd Plietker, Michael R. Buchmeiser, and Bettina V. Lotsch. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” Chemistry – A European Journal 28, no. 8 (2021). https://doi.org/10.1002/chem.202104108.' ieee: 'S. T. Emmerling et al., “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity,” Chemistry – A European Journal, vol. 28, no. 8, 2021, doi: 10.1002/chem.202104108.' mla: 'Emmerling, Sebastian T., et al. “Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity.” Chemistry – A European Journal, vol. 28, no. 8, Wiley, 2021, doi:10.1002/chem.202104108.' short: S.T. Emmerling, F. Ziegler, F.R. Fischer, R. Schoch, M. Bauer, B. Plietker, M.R. Buchmeiser, B.V. Lotsch, Chemistry – A European Journal 28 (2021). date_created: 2023-01-30T16:48:22Z date_updated: 2023-01-31T08:05:07Z department: - _id: '35' - _id: '306' doi: 10.1002/chem.202104108 intvolume: ' 28' issue: '8' keyword: - General Chemistry - Catalysis - Organic Chemistry language: - iso: eng publication: Chemistry – A European Journal publication_identifier: issn: - 0947-6539 - 1521-3765 publication_status: published publisher: Wiley status: public title: 'Olefin Metathesis in Confinement: Towards Covalent Organic Framework Scaffolds for Increased Macrocyclization Selectivity' type: journal_article user_id: '48467' volume: 28 year: '2021' ... --- _id: '41003' abstract: - lang: eng text: Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the 3MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)2]2+ complex to 9.2 ps in [Fe(dpmi)2]2+12+. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap article_type: original author: - first_name: Thomas full_name: Reuter, Thomas last_name: Reuter - first_name: Ayla full_name: Kruse, Ayla last_name: Kruse - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Stefan full_name: Lochbrunner, Stefan last_name: Lochbrunner - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Katja full_name: Heinze, Katja last_name: Heinze citation: ama: Reuter T, Kruse A, Schoch R, Lochbrunner S, Bauer M, Heinze K. Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion. Chemical Communications. 2021;57(61):7541-7544. doi:10.1039/d1cc02173g apa: Reuter, T., Kruse, A., Schoch, R., Lochbrunner, S., Bauer, M., & Heinze, K. (2021). Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion. Chemical Communications, 57(61), 7541–7544. https://doi.org/10.1039/d1cc02173g bibtex: '@article{Reuter_Kruse_Schoch_Lochbrunner_Bauer_Heinze_2021, title={Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion}, volume={57}, DOI={10.1039/d1cc02173g}, number={61}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Reuter, Thomas and Kruse, Ayla and Schoch, Roland and Lochbrunner, Stefan and Bauer, Matthias and Heinze, Katja}, year={2021}, pages={7541–7544} }' chicago: 'Reuter, Thomas, Ayla Kruse, Roland Schoch, Stefan Lochbrunner, Matthias Bauer, and Katja Heinze. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>) Complexes by Chelate Ring Expansion.” Chemical Communications 57, no. 61 (2021): 7541–44. https://doi.org/10.1039/d1cc02173g.' ieee: 'T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, and K. Heinze, “Higher MLCT lifetime of carbene iron(<scp>ii</scp>) complexes by chelate ring expansion,” Chemical Communications, vol. 57, no. 61, pp. 7541–7544, 2021, doi: 10.1039/d1cc02173g.' mla: Reuter, Thomas, et al. “Higher MLCT Lifetime of Carbene Iron(<scp>ii</Scp>) Complexes by Chelate Ring Expansion.” Chemical Communications, vol. 57, no. 61, Royal Society of Chemistry (RSC), 2021, pp. 7541–44, doi:10.1039/d1cc02173g. short: T. Reuter, A. Kruse, R. Schoch, S. Lochbrunner, M. Bauer, K. Heinze, Chemical Communications 57 (2021) 7541–7544. date_created: 2023-01-30T16:49:33Z date_updated: 2023-01-31T08:06:16Z department: - _id: '35' - _id: '306' doi: 10.1039/d1cc02173g intvolume: ' 57' issue: '61' keyword: - Materials Chemistry - Metals and Alloys - Surfaces - Coatings and Films - General Chemistry - Ceramics and Composites - Electronic - Optical and Magnetic Materials - Catalysis language: - iso: eng page: 7541-7544 publication: Chemical Communications publication_identifier: issn: - 1359-7345 - 1364-548X publication_status: published publisher: Royal Society of Chemistry (RSC) status: public title: Higher MLCT lifetime of carbene iron(ii) complexes by chelate ring expansion type: journal_article user_id: '48467' volume: 57 year: '2021' ... --- _id: '40997' abstract: - lang: eng text: 'On transition metals such as iron rests lots of hope to replace precious metal catalysts in the field of photochemistry for a more sustainable future. Indeed, significant progress has been made in recent years in terms of lifetime extension and emerging applications in catalysis. For this reason, recent synthetic strategies of new photoactive iron compounds, which have proved to show particularly promising properties, are reviewed here. The lifetime of the excited state serves as a key parameter for comparison with the standard ruthenium complex, [Ru(bpy)3]2+, to discuss the potential and performance of the iron complexes. This approach is complemented by a more holistic examination of the sustainability of such a substitution strategy in order to answer the question: when or at which point can we assume that iron represents a more sustainable alternative for noble metals in photochemical applications?' article_type: review author: - first_name: Philipp full_name: Dierks, Philipp last_name: Dierks - first_name: Yannik full_name: Vukadinovic, Yannik last_name: Vukadinovic - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 citation: ama: 'Dierks P, Vukadinovic Y, Bauer M. Photoactive iron complexes: more sustainable, but still a challenge. Inorganic Chemistry Frontiers. 2021;9(2):206-220. doi:10.1039/d1qi01112j' apa: 'Dierks, P., Vukadinovic, Y., & Bauer, M. (2021). Photoactive iron complexes: more sustainable, but still a challenge. Inorganic Chemistry Frontiers, 9(2), 206–220. https://doi.org/10.1039/d1qi01112j' bibtex: '@article{Dierks_Vukadinovic_Bauer_2021, title={Photoactive iron complexes: more sustainable, but still a challenge}, volume={9}, DOI={10.1039/d1qi01112j}, number={2}, journal={Inorganic Chemistry Frontiers}, publisher={Royal Society of Chemistry (RSC)}, author={Dierks, Philipp and Vukadinovic, Yannik and Bauer, Matthias}, year={2021}, pages={206–220} }' chicago: 'Dierks, Philipp, Yannik Vukadinovic, and Matthias Bauer. “Photoactive Iron Complexes: More Sustainable, but Still a Challenge.” Inorganic Chemistry Frontiers 9, no. 2 (2021): 206–20. https://doi.org/10.1039/d1qi01112j.' ieee: 'P. Dierks, Y. Vukadinovic, and M. Bauer, “Photoactive iron complexes: more sustainable, but still a challenge,” Inorganic Chemistry Frontiers, vol. 9, no. 2, pp. 206–220, 2021, doi: 10.1039/d1qi01112j.' mla: 'Dierks, Philipp, et al. “Photoactive Iron Complexes: More Sustainable, but Still a Challenge.” Inorganic Chemistry Frontiers, vol. 9, no. 2, Royal Society of Chemistry (RSC), 2021, pp. 206–20, doi:10.1039/d1qi01112j.' short: P. Dierks, Y. Vukadinovic, M. Bauer, Inorganic Chemistry Frontiers 9 (2021) 206–220. date_created: 2023-01-30T16:47:45Z date_updated: 2023-01-31T08:04:56Z department: - _id: '35' - _id: '306' doi: 10.1039/d1qi01112j intvolume: ' 9' issue: '2' keyword: - Inorganic Chemistry language: - iso: eng page: 206-220 publication: Inorganic Chemistry Frontiers publication_identifier: issn: - 2052-1553 publication_status: published publisher: Royal Society of Chemistry (RSC) status: public title: 'Photoactive iron complexes: more sustainable, but still a challenge' type: journal_article user_id: '48467' volume: 9 year: '2021' ... --- _id: '41000' abstract: - lang: eng text: Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts. article_type: original author: - first_name: Pradip full_name: Ghosh, Pradip last_name: Ghosh - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Axel full_name: Jacobi von Wangelin, Axel last_name: Jacobi von Wangelin citation: ama: Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition. 2021;61(1). doi:10.1002/anie.202110821 apa: Ghosh, P., Schoch, R., Bauer, M., & Jacobi von Wangelin, A. (2021). Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition, 61(1). https://doi.org/10.1002/anie.202110821 bibtex: '@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={10.1002/anie.202110821}, number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021} }' chicago: Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition 61, no. 1 (2021). https://doi.org/10.1002/anie.202110821. ieee: 'P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis,” Angewandte Chemie International Edition, vol. 61, no. 1, 2021, doi: 10.1002/anie.202110821.' mla: Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition, vol. 61, no. 1, Wiley, 2021, doi:10.1002/anie.202110821. short: P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie International Edition 61 (2021). date_created: 2023-01-30T16:48:53Z date_updated: 2023-01-31T08:05:26Z department: - _id: '35' - _id: '306' doi: 10.1002/anie.202110821 intvolume: ' 61' issue: '1' keyword: - General Chemistry - Catalysis language: - iso: eng publication: Angewandte Chemie International Edition publication_identifier: issn: - 1433-7851 - 1521-3773 publication_status: published publisher: Wiley status: public title: Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis type: journal_article user_id: '48467' volume: 61 year: '2021' ... --- _id: '41013' abstract: - lang: eng text: Within this article, it is shown that an electrochemical defluorination and additional fluorination of Ruddlesden–Popper-type La2NiO3F2 is possible within all-solid-state fluoride-ion batteries. Structural changes within the reduced and oxidized phases have been examined by X-ray diffraction studies at different states of charging and discharging. The synthesis of the oxidized phase La2NiO3F2+x proved to be successful by structural analysis using both X-ray powder diffraction and automated electron diffraction tomography techniques. The structural reversibility on re-fluorinating and re-defluorinating is also demonstrated. Moreover, the influence of different sequences of consecutive reduction and oxidation steps on the formed phases has been investigated. The observed structural changes have been compared to changes in phases obtained via other topochemical modification approaches such as hydride-based reduction and oxidative fluorination using F2 gas, highlighting the potential of such electrochemical reactions as alternative synthesis routes. Furthermore, the electrochemical routes represent safe and controllable synthesis approaches for novel phases, which cannot be synthesized via other topochemical methods. Additionally, side reactions, occurring alongside the desired electrochemical reactions, have been addressed and the cycling performance has been studied. article_type: original author: - first_name: Kerstin full_name: Wissel, Kerstin last_name: Wissel - first_name: Roland full_name: Schoch, Roland id: '48467' last_name: Schoch orcid: 0000-0003-2061-7289 - first_name: Tobias full_name: Vogel, Tobias last_name: Vogel - first_name: Manuel full_name: Donzelli, Manuel last_name: Donzelli - first_name: Galina full_name: Matveeva, Galina last_name: Matveeva - first_name: Ute full_name: Kolb, Ute last_name: Kolb - first_name: Matthias full_name: Bauer, Matthias id: '47241' last_name: Bauer orcid: 0000-0002-9294-6076 - first_name: Peter R. full_name: Slater, Peter R. last_name: Slater - first_name: Oliver full_name: Clemens, Oliver last_name: Clemens citation: ama: Wissel K, Schoch R, Vogel T, et al. Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries. Chemistry of Materials. 2021;33(2):499-512. doi:10.1021/acs.chemmater.0c01762 apa: Wissel, K., Schoch, R., Vogel, T., Donzelli, M., Matveeva, G., Kolb, U., Bauer, M., Slater, P. R., & Clemens, O. (2021). Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries. Chemistry of Materials, 33(2), 499–512. https://doi.org/10.1021/acs.chemmater.0c01762 bibtex: '@article{Wissel_Schoch_Vogel_Donzelli_Matveeva_Kolb_Bauer_Slater_Clemens_2021, title={Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries}, volume={33}, DOI={10.1021/acs.chemmater.0c01762}, number={2}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Wissel, Kerstin and Schoch, Roland and Vogel, Tobias and Donzelli, Manuel and Matveeva, Galina and Kolb, Ute and Bauer, Matthias and Slater, Peter R. and Clemens, Oliver}, year={2021}, pages={499–512} }' chicago: 'Wissel, Kerstin, Roland Schoch, Tobias Vogel, Manuel Donzelli, Galina Matveeva, Ute Kolb, Matthias Bauer, Peter R. Slater, and Oliver Clemens. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries.” Chemistry of Materials 33, no. 2 (2021): 499–512. https://doi.org/10.1021/acs.chemmater.0c01762.' ieee: 'K. Wissel et al., “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries,” Chemistry of Materials, vol. 33, no. 2, pp. 499–512, 2021, doi: 10.1021/acs.chemmater.0c01762.' mla: Wissel, Kerstin, et al. “Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries.” Chemistry of Materials, vol. 33, no. 2, American Chemical Society (ACS), 2021, pp. 499–512, doi:10.1021/acs.chemmater.0c01762. short: K. Wissel, R. Schoch, T. Vogel, M. Donzelli, G. Matveeva, U. Kolb, M. Bauer, P.R. Slater, O. Clemens, Chemistry of Materials 33 (2021) 499–512. date_created: 2023-01-30T17:01:00Z date_updated: 2023-01-31T08:07:28Z department: - _id: '35' - _id: '306' doi: 10.1021/acs.chemmater.0c01762 intvolume: ' 33' issue: '2' keyword: - Materials Chemistry - General Chemical Engineering - General Chemistry language: - iso: eng page: 499-512 publication: Chemistry of Materials publication_identifier: issn: - 0897-4756 - 1520-5002 publication_status: published publisher: American Chemical Society (ACS) status: public title: Electrochemical Reduction and Oxidation of Ruddlesden–Popper-Type La2NiO3F2 within Fluoride-Ion Batteries type: journal_article user_id: '48467' volume: 33 year: '2021' ...