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Werner, Advanced Synthesis and Catalysis 358 (2016) 26–29."},"user_id":"89271","volume":358,"page":"26-29","_id":"37989","publisher":"Wiley","status":"public","keyword":["T2","CSSD"],"type":"journal_article","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"date_created":"2023-01-22T21:05:14Z","extern":"1","publication":"Advanced Synthesis and Catalysis","issue":"1","doi":"10.1002/adsc.201500762","language":[{"iso":"eng"}],"publication_status":"published","date_updated":"2025-11-10T09:22:07Z","intvolume":"       358","title":"Organocatalyzed Reduction of Tertiary Phosphine Oxides","year":"2016","author":[{"full_name":"Schirmer, Marie-Luis","first_name":"Marie-Luis","last_name":"Schirmer"},{"full_name":"Jopp, Stefan","first_name":"Stefan","last_name":"Jopp"},{"first_name":"Jens","last_name":"Holz","full_name":"Holz, Jens"},{"full_name":"Spannenberg, Anke","last_name":"Spannenberg","first_name":"Anke"},{"id":"89271","orcid":"0000-0001-9025-3244","first_name":"Thomas","last_name":"Werner","full_name":"Werner, Thomas"}],"publication_identifier":{"issn":["1615-4150"]}},{"citation":{"bibtex":"@article{Schirmer_Spannenberg_Werner_2016, title={Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione}, volume={72}, DOI={<a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>}, number={6}, journal={Acta Crystallographica Section C Structural Chemistry}, publisher={International Union of Crystallography (IUCr)}, author={Schirmer, Marie-Luis and Spannenberg, Anke and Werner, Thomas}, year={2016}, pages={504–508} }","ama":"Schirmer M-L, Spannenberg A, Werner T. Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione. <i>Acta Crystallographica Section C Structural Chemistry</i>. 2016;72(6):504-508. doi:<a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>","mla":"Schirmer, Marie-Luis, et al. “Highly Functionalized Alkenes Produced from Base-Free Organocatalytic Wittig Reactions: (<i>E</i>)-3-Benzylidenepyrrolidine-2,5-Dione, (<i>E</i>)-3-Benzylidene-1-Methylpyrrolidine-2,5-Dione and (<i>E</i>)-3-Benzylidene-1-<i>Tert</i>-Butylpyrrolidine-2,5-Dione.” <i>Acta Crystallographica Section C Structural Chemistry</i>, vol. 72, no. 6, International Union of Crystallography (IUCr), 2016, pp. 504–08, doi:<a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>.","chicago":"Schirmer, Marie-Luis, Anke Spannenberg, and Thomas Werner. “Highly Functionalized Alkenes Produced from Base-Free Organocatalytic Wittig Reactions: (<i>E</i>)-3-Benzylidenepyrrolidine-2,5-Dione, (<i>E</i>)-3-Benzylidene-1-Methylpyrrolidine-2,5-Dione and (<i>E</i>)-3-Benzylidene-1-<i>Tert</i>-Butylpyrrolidine-2,5-Dione.” <i>Acta Crystallographica Section C Structural Chemistry</i> 72, no. 6 (2016): 504–8. <a href=\"https://doi.org/10.1107/s2053229616008159\">https://doi.org/10.1107/s2053229616008159</a>.","short":"M.-L. Schirmer, A. Spannenberg, T. Werner, Acta Crystallographica Section C Structural Chemistry 72 (2016) 504–508.","ieee":"M.-L. Schirmer, A. Spannenberg, and T. Werner, “Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione,” <i>Acta Crystallographica Section C Structural Chemistry</i>, vol. 72, no. 6, pp. 504–508, 2016, doi: <a href=\"https://doi.org/10.1107/s2053229616008159\">10.1107/s2053229616008159</a>.","apa":"Schirmer, M.-L., Spannenberg, A., &#38; Werner, T. (2016). Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione. <i>Acta Crystallographica Section C Structural Chemistry</i>, <i>72</i>(6), 504–508. <a href=\"https://doi.org/10.1107/s2053229616008159\">https://doi.org/10.1107/s2053229616008159</a>"},"status":"public","volume":72,"user_id":"89271","_id":"37984","publisher":"International Union of Crystallography (IUCr)","page":"504-508","extern":"1","abstract":[{"text":"<jats:p>The Wittig reaction is a fundamental transformation for the preparation of alkenes from carbonyl compounds and phosphonium ylides. The ylides are prepared prior to the olefination step from the respective phosphonium salts by deprotonation utilizing strong bases. A first free-base catalytic Wittig reaction for the preparation of highly functionalized alkenes was based on tributylphosphane as the catalyst. Subsequently we developed a system employing a phospholene oxide as a pre-catalyst and trimethoxysilane as reducing agent which operates under milder conditions. The title compounds, (<jats:italic>E</jats:italic>)-3-benzylidenepyrrolidine-2,5-dione, C<jats:sub>11</jats:sub>H<jats:sub>9</jats:sub>NO<jats:sub>2</jats:sub>, (I), the methylpyrrolidine derivative, C<jats:sub>12</jats:sub>H<jats:sub>11</jats:sub>NO<jats:sub>2</jats:sub>, (II), and the<jats:italic>tert-</jats:italic>butylpyrrolidine derivative, C<jats:sub>15</jats:sub>H<jats:sub>17</jats:sub>NO<jats:sub>2</jats:sub>, (III), have been synthesized by base-free catalytic Wittig reactions. In the crystal of (I), molecules are linked into centrosymmetric dimers<jats:italic>via</jats:italic>pairs of N—H...O hydrogen bonds. Furthermore, in the crystal structure of (III), there are two molecules in the asymmetric unit, whereas in (I) and (II), only one molecule is present.</jats:p>","lang":"eng"}],"issue":"6","publication":"Acta Crystallographica Section C Structural Chemistry","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["T2"],"date_created":"2023-01-22T21:03:23Z","intvolume":"        72","publication_status":"published","date_updated":"2025-11-10T09:23:46Z","publication_identifier":{"issn":["2053-2296"]},"author":[{"first_name":"Marie-Luis","last_name":"Schirmer","full_name":"Schirmer, Marie-Luis"},{"full_name":"Spannenberg, Anke","first_name":"Anke","last_name":"Spannenberg"},{"id":"89271","first_name":"Thomas","last_name":"Werner","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas"}],"year":"2016","title":"Highly functionalized alkenes produced from base-free organocatalytic Wittig reactions: (<i>E</i>)-3-benzylidenepyrrolidine-2,5-dione, (<i>E</i>)-3-benzylidene-1-methylpyrrolidine-2,5-dione and (<i>E</i>)-3-benzylidene-1-<i>tert</i>-butylpyrrolidine-2,5-dione","doi":"10.1107/s2053229616008159","language":[{"iso":"eng"}]},{"publication_status":"published","date_updated":"2025-11-10T09:24:16Z","intvolume":"        14","year":"2016","title":"Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes","author":[{"full_name":"Diebler, J.","first_name":"J.","last_name":"Diebler"},{"first_name":"A.","last_name":"Spannenberg","full_name":"Spannenberg, A."},{"id":"89271","full_name":"Werner, Thomas","first_name":"Thomas","orcid":"0000-0001-9025-3244","last_name":"Werner"}],"publication_identifier":{"issn":["1477-0520","1477-0539"]},"doi":"10.1039/c6ob01081d","language":[{"iso":"eng"}],"extern":"1","abstract":[{"lang":"eng","text":"<p>The lithium <italic>tert</italic>-butoxide catalyzed addition of CS<sub>2</sub> to epoxides and thiiranes under mild conditions is reported. A mechanism has been proposed taking into account the regio- and stereochemical outcome of the reaction.</p>"}],"issue":"31","publication":"Organic and Biomolecular Chemistry","type":"journal_article","keyword":["CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"date_created":"2023-01-22T21:01:59Z","status":"public","user_id":"89271","volume":14,"page":"7480-7489","_id":"37981","publisher":"Royal Society of Chemistry (RSC)","citation":{"bibtex":"@article{Diebler_Spannenberg_Werner_2016, title={Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes}, volume={14}, DOI={<a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>}, number={31}, journal={Organic and Biomolecular Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Diebler, J. and Spannenberg, A. and Werner, Thomas}, year={2016}, pages={7480–7489} }","ama":"Diebler J, Spannenberg A, Werner T. Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes. <i>Organic and Biomolecular Chemistry</i>. 2016;14(31):7480-7489. doi:<a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>","mla":"Diebler, J., et al. “Atom Economical Synthesis of Di- and Trithiocarbonates by the Lithium Tert-Butoxide Catalyzed Addition of Carbon Disulfide to Epoxides and Thiiranes.” <i>Organic and Biomolecular Chemistry</i>, vol. 14, no. 31, Royal Society of Chemistry (RSC), 2016, pp. 7480–89, doi:<a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>.","chicago":"Diebler, J., A. Spannenberg, and Thomas Werner. “Atom Economical Synthesis of Di- and Trithiocarbonates by the Lithium Tert-Butoxide Catalyzed Addition of Carbon Disulfide to Epoxides and Thiiranes.” <i>Organic and Biomolecular Chemistry</i> 14, no. 31 (2016): 7480–89. <a href=\"https://doi.org/10.1039/c6ob01081d\">https://doi.org/10.1039/c6ob01081d</a>.","short":"J. Diebler, A. Spannenberg, T. Werner, Organic and Biomolecular Chemistry 14 (2016) 7480–7489.","ieee":"J. Diebler, A. Spannenberg, and T. Werner, “Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes,” <i>Organic and Biomolecular Chemistry</i>, vol. 14, no. 31, pp. 7480–7489, 2016, doi: <a href=\"https://doi.org/10.1039/c6ob01081d\">10.1039/c6ob01081d</a>.","apa":"Diebler, J., Spannenberg, A., &#38; Werner, T. (2016). Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes. <i>Organic and Biomolecular Chemistry</i>, <i>14</i>(31), 7480–7489. <a href=\"https://doi.org/10.1039/c6ob01081d\">https://doi.org/10.1039/c6ob01081d</a>"}},{"citation":{"apa":"Desens, W., Kohrt, C., Spannenberg, A., &#38; Werner, T. (2016). A novel zinc based binary catalytic system for CO<sub>2</sub>utilization under mild conditions. <i>Organic Chemistry Frontiers</i>, <i>3</i>(2), 156–164. <a href=\"https://doi.org/10.1039/c5qo00356c\">https://doi.org/10.1039/c5qo00356c</a>","ieee":"W. Desens, C. Kohrt, A. Spannenberg, and T. Werner, “A novel zinc based binary catalytic system for CO<sub>2</sub>utilization under mild conditions,” <i>Organic Chemistry Frontiers</i>, vol. 3, no. 2, pp. 156–164, 2016, doi: <a href=\"https://doi.org/10.1039/c5qo00356c\">10.1039/c5qo00356c</a>.","short":"W. Desens, C. Kohrt, A. Spannenberg, T. Werner, Organic Chemistry Frontiers 3 (2016) 156–164.","chicago":"Desens, Willi, Christina Kohrt, Anke Spannenberg, and Thomas Werner. “A Novel Zinc Based Binary Catalytic System for CO<sub>2</sub>Utilization under Mild Conditions.” <i>Organic Chemistry Frontiers</i> 3, no. 2 (2016): 156–64. <a href=\"https://doi.org/10.1039/c5qo00356c\">https://doi.org/10.1039/c5qo00356c</a>.","mla":"Desens, Willi, et al. “A Novel Zinc Based Binary Catalytic System for CO<sub>2</sub>Utilization under Mild Conditions.” <i>Organic Chemistry Frontiers</i>, vol. 3, no. 2, Royal Society of Chemistry (RSC), 2016, pp. 156–64, doi:<a href=\"https://doi.org/10.1039/c5qo00356c\">10.1039/c5qo00356c</a>.","ama":"Desens W, Kohrt C, Spannenberg A, Werner T. A novel zinc based binary catalytic system for CO<sub>2</sub>utilization under mild conditions. <i>Organic Chemistry Frontiers</i>. 2016;3(2):156-164. doi:<a href=\"https://doi.org/10.1039/c5qo00356c\">10.1039/c5qo00356c</a>","bibtex":"@article{Desens_Kohrt_Spannenberg_Werner_2016, title={A novel zinc based binary catalytic system for CO<sub>2</sub>utilization under mild conditions}, volume={3}, DOI={<a href=\"https://doi.org/10.1039/c5qo00356c\">10.1039/c5qo00356c</a>}, number={2}, journal={Organic Chemistry Frontiers}, publisher={Royal Society of Chemistry (RSC)}, author={Desens, Willi and Kohrt, Christina and Spannenberg, Anke and Werner, Thomas}, year={2016}, pages={156–164} }"},"page":"156-164","publisher":"Royal Society of Chemistry (RSC)","_id":"37987","user_id":"89271","volume":3,"status":"public","date_created":"2023-01-22T21:04:30Z","type":"journal_article","keyword":["T1","T3","CSSD"],"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"publication":"Organic Chemistry Frontiers","issue":"2","extern":"1","abstract":[{"text":"<p>A novel zinc based binary catalytic system for the synthesis of cyclic carbonates under mild and solvent-free conditions utilizing CO<sub>2</sub>as a C1 building block is reported.</p>","lang":"eng"}],"language":[{"iso":"eng"}],"doi":"10.1039/c5qo00356c","title":"A novel zinc based binary catalytic system for CO<sub>2</sub>utilization under mild conditions","year":"2016","author":[{"full_name":"Desens, Willi","first_name":"Willi","last_name":"Desens"},{"first_name":"Christina","last_name":"Kohrt","full_name":"Kohrt, Christina"},{"last_name":"Spannenberg","first_name":"Anke","full_name":"Spannenberg, Anke"},{"full_name":"Werner, Thomas","orcid":"0000-0001-9025-3244","last_name":"Werner","first_name":"Thomas","id":"89271"}],"publication_identifier":{"issn":["2052-4129"]},"publication_status":"published","date_updated":"2025-11-10T09:26:28Z","intvolume":"         3"},{"publication_identifier":{"issn":["0024-9297","1520-5835"]},"author":[{"full_name":"Diebler, Johannes","first_name":"Johannes","last_name":"Diebler"},{"first_name":"Hartmut","last_name":"Komber","full_name":"Komber, Hartmut"},{"first_name":"Liane","last_name":"Häußler","full_name":"Häußler, Liane"},{"last_name":"Lederer","first_name":"Albena","full_name":"Lederer, Albena"},{"last_name":"Werner","first_name":"Thomas","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271"}],"year":"2016","title":"Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers","intvolume":"        49","publication_status":"published","date_updated":"2025-11-10T09:25:16Z","language":[{"iso":"eng"}],"doi":"10.1021/acs.macromol.6b00728","issue":"13","publication":"Macromolecules","extern":"1","date_created":"2023-01-22T21:02:41Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"type":"journal_article","keyword":["CSSD"],"status":"public","publisher":"American Chemical Society (ACS)","_id":"37982","page":"4723-4731","volume":49,"user_id":"89271","citation":{"mla":"Diebler, Johannes, et al. “Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers.” <i>Macromolecules</i>, vol. 49, no. 13, American Chemical Society (ACS), 2016, pp. 4723–31, doi:<a href=\"https://doi.org/10.1021/acs.macromol.6b00728\">10.1021/acs.macromol.6b00728</a>.","bibtex":"@article{Diebler_Komber_Häußler_Lederer_Werner_2016, title={Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers}, volume={49}, DOI={<a href=\"https://doi.org/10.1021/acs.macromol.6b00728\">10.1021/acs.macromol.6b00728</a>}, number={13}, journal={Macromolecules}, publisher={American Chemical Society (ACS)}, author={Diebler, Johannes and Komber, Hartmut and Häußler, Liane and Lederer, Albena and Werner, Thomas}, year={2016}, pages={4723–4731} }","ama":"Diebler J, Komber H, Häußler L, Lederer A, Werner T. Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers. <i>Macromolecules</i>. 2016;49(13):4723-4731. doi:<a href=\"https://doi.org/10.1021/acs.macromol.6b00728\">10.1021/acs.macromol.6b00728</a>","ieee":"J. Diebler, H. Komber, L. Häußler, A. Lederer, and T. Werner, “Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers,” <i>Macromolecules</i>, vol. 49, no. 13, pp. 4723–4731, 2016, doi: <a href=\"https://doi.org/10.1021/acs.macromol.6b00728\">10.1021/acs.macromol.6b00728</a>.","apa":"Diebler, J., Komber, H., Häußler, L., Lederer, A., &#38; Werner, T. (2016). Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers. <i>Macromolecules</i>, <i>49</i>(13), 4723–4731. <a href=\"https://doi.org/10.1021/acs.macromol.6b00728\">https://doi.org/10.1021/acs.macromol.6b00728</a>","short":"J. Diebler, H. Komber, L. Häußler, A. Lederer, T. Werner, Macromolecules 49 (2016) 4723–4731.","chicago":"Diebler, Johannes, Hartmut Komber, Liane Häußler, Albena Lederer, and Thomas Werner. “Alkoxide-Initiated Regioselective Coupling of Carbon Disulfide and Terminal Epoxides for the Synthesis of Strongly Alternating Copolymers.” <i>Macromolecules</i> 49, no. 13 (2016): 4723–31. <a href=\"https://doi.org/10.1021/acs.macromol.6b00728\">https://doi.org/10.1021/acs.macromol.6b00728</a>."}}]