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In this study, the influence of the organogelator 12-hydroxyoctadecanoic acid (12-HOA) on the lamellar and hexagonal liquid crystalline phases of the binary system H2O–C12E7 (heptaethylene glycol monododecyl ether) is investigated. More precisely, we added 12-HOA at mass fractions from 0.015 to 0.05 and studied the resulting phase diagram of the system H2O–C12E7 by visual observation of birefringence and by 2H NMR spectroscopy. In addition, the dynamic shear moduli of the samples were measured in order to examine their gel character. The results show that 12-HOA is partly acting as co-surfactant, manifested by the destabilization of the hexagonal phase and the stabilization of the lamellar phase. The higher the total surfactant concentration, the more 12-HOA is incorporated in the surfactant layer. Accordingly, its gelation capacity is substantially reduced in the surfactant solution compared to the system 12-HOA–n-decane, and large amounts of gelator are required for gels to form, especially in the lamellar phase.</jats:p>","lang":"eng"}],"date_created":"2023-01-06T12:51:42Z","department":[{"_id":"2"},{"_id":"315"}],"keyword":["Polymers and Plastics","Organic Chemistry","Biomaterials","Bioengineering"],"type":"journal_article","author":[{"full_name":"Steck, Katja","first_name":"Katja","last_name":"Steck"},{"id":"466","last_name":"Schmidt","orcid":"0000-0003-3179-9997","first_name":"Claudia","full_name":"Schmidt, Claudia"},{"last_name":"Stubenrauch","first_name":"Cosima","full_name":"Stubenrauch, Cosima"}],"publication_identifier":{"issn":["2310-2861"]},"title":"The Twofold Role of 12-Hydroxyoctadecanoic Acid (12-HOA) in a Ternary Water—Surfactant—12-HOA System: Gelator and Co-Surfactant","year":"2018","article_type":"original","intvolume":"         4","publication_status":"published","date_updated":"2023-01-07T10:33:24Z","language":[{"iso":"eng"}],"article_number":"78","doi":"10.3390/gels4030078","citation":{"apa":"Steck, K., Schmidt, C., &#38; Stubenrauch, C. (2018). The Twofold Role of 12-Hydroxyoctadecanoic Acid (12-HOA) in a Ternary Water—Surfactant—12-HOA System: Gelator and Co-Surfactant. <i>Gels</i>, <i>4</i>(3), Article 78. <a href=\"https://doi.org/10.3390/gels4030078\">https://doi.org/10.3390/gels4030078</a>","ieee":"K. Steck, C. Schmidt, and C. Stubenrauch, “The Twofold Role of 12-Hydroxyoctadecanoic Acid (12-HOA) in a Ternary Water—Surfactant—12-HOA System: Gelator and Co-Surfactant,” <i>Gels</i>, vol. 4, no. 3, Art. no. 78, 2018, doi: <a href=\"https://doi.org/10.3390/gels4030078\">10.3390/gels4030078</a>.","short":"K. Steck, C. Schmidt, C. 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(2018). <i>Alltagspraktiken des Erzählens (Literaturwissenschaft und Linguistik)</i>."},"date_created":"2020-08-28T08:35:14Z","type":"book_editor","department":[{"_id":"5"},{"_id":"115"}],"title":"Alltagspraktiken des Erzählens (Literaturwissenschaft und Linguistik)","status":"public","year":"2018","date_updated":"2023-01-09T14:31:04Z","language":[{"iso":"ger"}],"_id":"18525","series_title":"(Literaturwissenschaft und Linguistik)","user_id":"16277","editor":[{"first_name":"Constanze","last_name":"Spieß","full_name":"Spieß, Constanze"},{"full_name":"Tophinke, Doris","last_name":"Tophinke","first_name":"Doris","id":"16277"}]}]
