TY - JOUR AB - AbstractWe conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (DiPPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions. AU - Peschtrich, Sebastian AU - Schoch, Roland AU - Kuckling, Dirk AU - Paradies, Jan ID - 52541 IS - 8 JF - European Journal of Organic Chemistry KW - Organic Chemistry KW - Physical and Theoretical Chemistry SN - 1434-193X TI - A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes VL - 27 ER - TY - JOUR AB - A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR‐spectroscopy, crystal structure analysis and by computational methods. The new Lewis acids were then applied in the Meinwald rearrangement of epoxides, predominantly furnishing aldehydes as the kinetic products. AU - Köring, Laura AU - Birenheide, Bernhard AU - Krämer, Felix AU - Wenzel, Jonas O. AU - Schoch, Roland AU - Brehm, Martin AU - Breher, Frank AU - Paradies, Jan ID - 52572 JF - European Journal of Inorganic Chemistry KW - Inorganic Chemistry SN - 1434-1948 TI - Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements ER - TY - JOUR AU - Bauch, Fabian AU - Dong, Chuan-Ding AU - Schumacher, Stefan ID - 52534 IS - 8 JF - The Journal of Physical Chemistry C KW - Surfaces KW - Coatings and Films KW - Physical and Theoretical Chemistry KW - General Energy KW - Electronic KW - Optical and Magnetic Materials SN - 1932-7447 TI - Dynamics of Electron–Hole Coulomb Attractive Energy and Dipole Moment of Hot Excitons in Donor–Acceptor Polymers VL - 128 ER - TY - GEN AU - Dechert, Christopher AU - Kenig, Eugeny ID - 52573 TI - Der Einfluss von Mikrostrukturen auf die Flüssigkeitsausbreitung in strukturierten Packungen ER - TY - THES AU - Frank, Maximilian ID - 52576 SN - 978-3-8440-9444-2 TI - Simulationsgestützte Bestimmung und Optimierung der Mischgüte in der Einschneckenextrusion VL - 2024,5 ER - TY - GEN AU - Hami Dindar, Iman AU - Lutters, Nicole AU - Kenig, Eugeny Y. ID - 52579 TI - Wässrige Glucosaminlösung als neues Lösungsmittel zur CO2-Abscheidung ER - TY - JOUR AB - In applications of piezoelectric actuators and sensors, the dependability and particularly the reliability throughout their lifetime are vital to manufacturers and end-users and are enabled through condition-monitoring approaches. Existing approaches often utilize impedance measurements over a range of frequencies or velocity measurements and require additional equipment or sensors, such as a laser Doppler vibrometer. Furthermore, the non-negligible effects of varying operating conditions are often unconsidered. To minimize the need for additional sensors while maintaining the dependability of piezoelectric bending actuators irrespective of varying operating conditions, an online diagnostics approach is proposed. To this end, time- and frequency-domain features are extracted from monitored current signals to reflect hairline crack development in bending actuators. For validation of applicability, the presented analysis method was evaluated on piezoelectric bending actuators subjected to accelerated lifetime tests at varying voltage amplitudes and under external damping conditions. In the presence of a crack and due to a diminished stiffness, the resonance frequency decreases and the root-mean-square amplitude of the current signal simultaneously abruptly drops during the lifetime tests. Furthermore, the piezoelectric crack surfaces clapping is reflected in higher harmonics of the current signal. Thus, time-domain features and harmonics of the current signals are sufficient to diagnose hairline cracks in the actuators. AU - Aimiyekagbon, Osarenren Kennedy AU - Bender, Amelie AU - Hemsel, Tobias AU - Sextro, Walter ID - 51518 IS - 3 JF - Electronics KW - piezoelectric transducer KW - self-sensing KW - fault detection KW - diagnostics KW - hairline crack KW - condition monitoring SN - 2079-9292 TI - Diagnostics of Piezoelectric Bending Actuators Subjected to Varying Operating Conditions VL - 13 ER - TY - CHAP AU - Fuchs, Christian ED - Litschka, Michael ED - Paganini, Claudia ED - Rademacher, Lars ID - 51364 SN - 9783748942801 T2 - Digitalisierte Massenkommunikation und Verantwortung TI - Grundlagen einer Ethik des Radikalen Digitalen Humanismus ER - TY - JOUR AU - Rezat, Sebastian ID - 52584 JF - ZDM – Mathematics Education TI - Research on curriculum resources in mathematics education: a survey of the field ER - TY - JOUR AU - Bodden, Eric AU - Pottebaum, Jens AU - Fockel, Markus AU - Gräßler, Iris ID - 52587 IS - 1 JF - IEEE Security & Privacy KW - Law KW - Electrical and Electronic Engineering KW - Computer Networks and Communications SN - 1540-7993 TI - Evaluating Security Through Isolation and Defense in Depth VL - 22 ER -