TY - JOUR
AB - AbstractWe conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (DiPPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions.
AU - Peschtrich, Sebastian
AU - Schoch, Roland
AU - Kuckling, Dirk
AU - Paradies, Jan
ID - 52541
IS - 8
JF - European Journal of Organic Chemistry
KW - Organic Chemistry
KW - Physical and Theoretical Chemistry
SN - 1434-193X
TI - A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes
VL - 27
ER -
TY - JOUR
AB - A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR‐spectroscopy, crystal structure analysis and by computational methods. The new Lewis acids were then applied in the Meinwald rearrangement of epoxides, predominantly furnishing aldehydes as the kinetic products.
AU - Köring, Laura
AU - Birenheide, Bernhard
AU - Krämer, Felix
AU - Wenzel, Jonas O.
AU - Schoch, Roland
AU - Brehm, Martin
AU - Breher, Frank
AU - Paradies, Jan
ID - 52572
JF - European Journal of Inorganic Chemistry
KW - Inorganic Chemistry
SN - 1434-1948
TI - Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements
ER -
TY - JOUR
AU - Bauch, Fabian
AU - Dong, Chuan-Ding
AU - Schumacher, Stefan
ID - 52534
IS - 8
JF - The Journal of Physical Chemistry C
KW - Surfaces
KW - Coatings and Films
KW - Physical and Theoretical Chemistry
KW - General Energy
KW - Electronic
KW - Optical and Magnetic Materials
SN - 1932-7447
TI - Dynamics of Electron–Hole Coulomb Attractive Energy and Dipole Moment of Hot Excitons in Donor–Acceptor Polymers
VL - 128
ER -
TY - GEN
AU - Dechert, Christopher
AU - Kenig, Eugeny
ID - 52573
TI - Der Einfluss von Mikrostrukturen auf die Flüssigkeitsausbreitung in strukturierten Packungen
ER -
TY - THES
AU - Frank, Maximilian
ID - 52576
SN - 978-3-8440-9444-2
TI - Simulationsgestützte Bestimmung und Optimierung der Mischgüte in der Einschneckenextrusion
VL - 2024,5
ER -
TY - GEN
AU - Hami Dindar, Iman
AU - Lutters, Nicole
AU - Kenig, Eugeny Y.
ID - 52579
TI - Wässrige Glucosaminlösung als neues Lösungsmittel zur CO2-Abscheidung
ER -
TY - JOUR
AB - In applications of piezoelectric actuators and sensors, the dependability and particularly the reliability throughout their lifetime are vital to manufacturers and end-users and are enabled through condition-monitoring approaches. Existing approaches often utilize impedance measurements over a range of frequencies or velocity measurements and require additional equipment or sensors, such as a laser Doppler vibrometer. Furthermore, the non-negligible effects of varying operating conditions are often unconsidered. To minimize the need for additional sensors while maintaining the dependability of piezoelectric bending actuators irrespective of varying operating conditions, an online diagnostics approach is proposed. To this end, time- and frequency-domain features are extracted from monitored current signals to reflect hairline crack development in bending actuators. For validation of applicability, the presented analysis method was evaluated on piezoelectric bending actuators subjected to accelerated lifetime tests at varying voltage amplitudes and under external damping conditions. In the presence of a crack and due to a diminished stiffness, the resonance frequency decreases and the root-mean-square amplitude of the current signal simultaneously abruptly drops during the lifetime tests. Furthermore, the piezoelectric crack surfaces clapping is reflected in higher harmonics of the current signal. Thus, time-domain features and harmonics of the current signals are sufficient to diagnose hairline cracks in the actuators.
AU - Aimiyekagbon, Osarenren Kennedy
AU - Bender, Amelie
AU - Hemsel, Tobias
AU - Sextro, Walter
ID - 51518
IS - 3
JF - Electronics
KW - piezoelectric transducer
KW - self-sensing
KW - fault detection
KW - diagnostics
KW - hairline crack
KW - condition monitoring
SN - 2079-9292
TI - Diagnostics of Piezoelectric Bending Actuators Subjected to Varying Operating Conditions
VL - 13
ER -
TY - CHAP
AU - Fuchs, Christian
ED - Litschka, Michael
ED - Paganini, Claudia
ED - Rademacher, Lars
ID - 51364
SN - 9783748942801
T2 - Digitalisierte Massenkommunikation und Verantwortung
TI - Grundlagen einer Ethik des Radikalen Digitalen Humanismus
ER -
TY - JOUR
AU - Rezat, Sebastian
ID - 52584
JF - ZDM – Mathematics Education
TI - Research on curriculum resources in mathematics education: a survey of the field
ER -
TY - JOUR
AU - Bodden, Eric
AU - Pottebaum, Jens
AU - Fockel, Markus
AU - Gräßler, Iris
ID - 52587
IS - 1
JF - IEEE Security & Privacy
KW - Law
KW - Electrical and Electronic Engineering
KW - Computer Networks and Communications
SN - 1540-7993
TI - Evaluating Security Through Isolation and Defense in Depth
VL - 22
ER -