---
res:
  bibo_abstract:
  - We examined the effect of CaCl2 and LiCl on ice melting in mesoporous silica (MCM-41
    and SBA-15 silica). For that purpose, we determined the ice melting temperature
    in pores of various size (pore radii between 1.9 and 11.1 nm) in water and aqueous
    solutions up to high total solute molality (up to about 12 mol kg–1) using differential
    scanning calorimetry. We found that both electrolytes reduce the ice melting temperature
    within the pores. An exception is the melting of ice in the smallest pores, which
    does not seem to be affected by the presence of solutes, most likely owing to
    an exclusion of the ions from entering the pores. For all other pores, we observed
    that the ice melting temperature decreases as a function of pore size and electrolyte
    concentration. Using thermodynamic considerations as well as additional experimental
    data we developed a parametrization that can be used to predict the ice melting
    point as a function of pore size and total solute molality. For that purpose,
    we extended a formulation of the effective water activity of aqueous solutions
    under mechanical pressure toward its application in confinement and tested this
    new parametrization on literature data.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Evelyn
      foaf_name: Jantsch, Evelyn
      foaf_surname: Jantsch
  - foaf_Person:
      foaf_givenName: Christian
      foaf_name: Weinberger, Christian
      foaf_surname: Weinberger
      foaf_workInfoHomepage: http://www.librecat.org/personId=11848
  - foaf_Person:
      foaf_givenName: Michael
      foaf_name: Tiemann, Michael
      foaf_surname: Tiemann
      foaf_workInfoHomepage: http://www.librecat.org/personId=23547
    orcid: 0000-0003-1711-2722
  - foaf_Person:
      foaf_givenName: Thomas
      foaf_name: Koop, Thomas
      foaf_surname: Koop
  bibo_doi: 10.1021/acs.jpcc.9b06527
  dct_date: 2019^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1932-7447
  - http://id.crossref.org/issn/1932-7455
  dct_language: eng
  dct_title: Phase Transitions of Ice in Aqueous Salt Solutions within Nanometer-Sized
    Pores@
...