---
_id: '25993'
abstract:
- lang: eng
  text: The growth of ZnS nanoparticles by precipitation from supersaturated aqueous
    solution is studied by stopped-flow UV absorption spectroscopy. The average size,
    size distribution, and concentration of the particles are monitored within the
    sub-second time regime with a resolution of 1.28 ms. Particle growth at these
    early stages is governed by pronounced ripening. The UV absorption data strongly
    suggest that growth occurs by preferential adsorption of HS- anions relative to
    Zn2+ or ZnOH+ cations. Correspondingly, the initial sulfide concentration has
    a much more pronounced influence on the growth kinetics than the initial zinc
    concentration. These findings are verified by ζ-potential measurements which confirm
    that the particle surfaces are negatively charged under near-neutral pH conditions.
article_type: original
author:
- first_name: Michael
  full_name: Tiemann, Michael
  id: '23547'
  last_name: Tiemann
  orcid: 0000-0003-1711-2722
- first_name: Frank
  full_name: Marlow, Frank
  last_name: Marlow
- first_name: Felix
  full_name: Brieler, Felix
  last_name: Brieler
- first_name: Mika
  full_name: Lindén, Mika
  last_name: Lindén
citation:
  ama: Tiemann M, Marlow F, Brieler F, Lindén M. Early Stages of ZnS Growth Studied
    by Stopped-Flow UV Absorption Spectroscopy:  Effects of Educt Concentrations on
    the Nanoparticle Formation. <i>The Journal of Physical Chemistry B</i>. Published
    online 2006:23142-23147. doi:<a href="https://doi.org/10.1021/jp0638383">10.1021/jp0638383</a>
  apa: Tiemann, M., Marlow, F., Brieler, F., &#38; Lindén, M. (2006). Early Stages
    of ZnS Growth Studied by Stopped-Flow UV Absorption Spectroscopy:  Effects of
    Educt Concentrations on the Nanoparticle Formation. <i>The Journal of Physical
    Chemistry B</i>, 23142–23147. <a href="https://doi.org/10.1021/jp0638383">https://doi.org/10.1021/jp0638383</a>
  bibtex: '@article{Tiemann_Marlow_Brieler_Lindén_2006, title={Early Stages of ZnS
    Growth Studied by Stopped-Flow UV Absorption Spectroscopy:  Effects of Educt Concentrations
    on the Nanoparticle Formation}, DOI={<a href="https://doi.org/10.1021/jp0638383">10.1021/jp0638383</a>},
    journal={The Journal of Physical Chemistry B}, author={Tiemann, Michael and Marlow,
    Frank and Brieler, Felix and Lindén, Mika}, year={2006}, pages={23142–23147} }'
  chicago: Tiemann, Michael, Frank Marlow, Felix Brieler, and Mika Lindén. “Early
    Stages of ZnS Growth Studied by Stopped-Flow UV Absorption Spectroscopy:  Effects
    of Educt Concentrations on the Nanoparticle Formation.” <i>The Journal of Physical
    Chemistry B</i>, 2006, 23142–47. <a href="https://doi.org/10.1021/jp0638383">https://doi.org/10.1021/jp0638383</a>.
  ieee: 'M. Tiemann, F. Marlow, F. Brieler, and M. Lindén, “Early Stages of ZnS Growth
    Studied by Stopped-Flow UV Absorption Spectroscopy:  Effects of Educt Concentrations
    on the Nanoparticle Formation,” <i>The Journal of Physical Chemistry B</i>, pp.
    23142–23147, 2006, doi: <a href="https://doi.org/10.1021/jp0638383">10.1021/jp0638383</a>.'
  mla: Tiemann, Michael, et al. “Early Stages of ZnS Growth Studied by Stopped-Flow
    UV Absorption Spectroscopy:  Effects of Educt Concentrations on the Nanoparticle
    Formation.” <i>The Journal of Physical Chemistry B</i>, 2006, pp. 23142–47, doi:<a
    href="https://doi.org/10.1021/jp0638383">10.1021/jp0638383</a>.
  short: M. Tiemann, F. Marlow, F. Brieler, M. Lindén, The Journal of Physical Chemistry
    B (2006) 23142–23147.
date_created: 2021-10-09T09:46:32Z
date_updated: 2023-03-09T08:56:40Z
department:
- _id: '35'
- _id: '2'
- _id: '307'
doi: 10.1021/jp0638383
extern: '1'
language:
- iso: eng
page: 23142-23147
publication: The Journal of Physical Chemistry B
publication_identifier:
  issn:
  - 1520-6106
  - 1520-5207
publication_status: published
quality_controlled: '1'
status: public
title: Early Stages of ZnS Growth Studied by Stopped-Flow UV Absorption Spectroscopy: 
  Effects of Educt Concentrations on the Nanoparticle Formation
type: journal_article
user_id: '23547'
year: '2006'
...