{"issue":"13","intvolume":"        23","date_updated":"2023-01-23T10:44:22Z","title":"Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction","abstract":[{"lang":"eng","text":"<p>PMHS proved to be a suitable terminal reductant for P(<sc>iii</sc>)/P(<sc>v</sc>) redox cycling with a methyl-substituted phosphetane as catalyst and BuOAc as solvent. The formation of water by silanol condensation was identified as main pathway of siloxane formation.</p>"}],"publication_status":"published","doi":"10.1039/d1gc00953b","date_created":"2023-01-22T20:25:13Z","publication_identifier":{"issn":["1463-9262","1463-9270"]},"author":[{"first_name":"Jan","full_name":"Tönjes, Jan","last_name":"Tönjes"},{"full_name":"Longwitz, Lars","last_name":"Longwitz","first_name":"Lars"},{"first_name":"Thomas","id":"89271","last_name":"Werner","full_name":"Werner, Thomas"}],"volume":23,"department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"language":[{"iso":"eng"}],"page":"4852-4857","publication":"Green Chemistry","status":"public","_id":"37945","user_id":"14931","year":"2021","keyword":["Pollution","Environmental Chemistry"],"type":"journal_article","publisher":"Royal Society of Chemistry (RSC)","citation":{"apa":"Tönjes, J., Longwitz, L., &#38; Werner, T. (2021). Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. <i>Green Chemistry</i>, <i>23</i>(13), 4852–4857. <a href=\"https://doi.org/10.1039/d1gc00953b\">https://doi.org/10.1039/d1gc00953b</a>","ieee":"J. Tönjes, L. Longwitz, and T. Werner, “Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction,” <i>Green Chemistry</i>, vol. 23, no. 13, pp. 4852–4857, 2021, doi: <a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>.","bibtex":"@article{Tönjes_Longwitz_Werner_2021, title={Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction}, volume={23}, DOI={<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>}, number={13}, journal={Green Chemistry}, publisher={Royal Society of Chemistry (RSC)}, author={Tönjes, Jan and Longwitz, Lars and Werner, Thomas}, year={2021}, pages={4852–4857} }","ama":"Tönjes J, Longwitz L, Werner T. Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction. <i>Green Chemistry</i>. 2021;23(13):4852-4857. doi:<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>","chicago":"Tönjes, Jan, Lars Longwitz, and Thomas Werner. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” <i>Green Chemistry</i> 23, no. 13 (2021): 4852–57. <a href=\"https://doi.org/10.1039/d1gc00953b\">https://doi.org/10.1039/d1gc00953b</a>.","mla":"Tönjes, Jan, et al. “Poly(Methylhydrosiloxane) as a Reductant in the Catalytic Base-Free Wittig Reaction.” <i>Green Chemistry</i>, vol. 23, no. 13, Royal Society of Chemistry (RSC), 2021, pp. 4852–57, doi:<a href=\"https://doi.org/10.1039/d1gc00953b\">10.1039/d1gc00953b</a>.","short":"J. Tönjes, L. Longwitz, T. Werner, Green Chemistry 23 (2021) 4852–4857."}}