{"user_id":"14931","year":"2018","status":"public","_id":"37966","type":"journal_article","keyword":["General Chemical Engineering","General Chemistry"],"publisher":"Walter de Gruyter GmbH","citation":{"mla":"Longwitz, Lars, and Thomas Werner. “Recent Advances in Catalytic Wittig-Type Reactions Based on P(III)/P(V) Redox Cycling.” <i>Pure and Applied Chemistry</i>, vol. 91, no. 1, Walter de Gruyter GmbH, 2018, pp. 95–102, doi:<a href=\"https://doi.org/10.1515/pac-2018-0920\">10.1515/pac-2018-0920</a>.","short":"L. Longwitz, T. Werner, Pure and Applied Chemistry 91 (2018) 95–102.","chicago":"Longwitz, Lars, and Thomas Werner. “Recent Advances in Catalytic Wittig-Type Reactions Based on P(III)/P(V) Redox Cycling.” <i>Pure and Applied Chemistry</i> 91, no. 1 (2018): 95–102. <a href=\"https://doi.org/10.1515/pac-2018-0920\">https://doi.org/10.1515/pac-2018-0920</a>.","bibtex":"@article{Longwitz_Werner_2018, title={Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling}, volume={91}, DOI={<a href=\"https://doi.org/10.1515/pac-2018-0920\">10.1515/pac-2018-0920</a>}, number={1}, journal={Pure and Applied Chemistry}, publisher={Walter de Gruyter GmbH}, author={Longwitz, Lars and Werner, Thomas}, year={2018}, pages={95–102} }","apa":"Longwitz, L., &#38; Werner, T. (2018). Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling. <i>Pure and Applied Chemistry</i>, <i>91</i>(1), 95–102. <a href=\"https://doi.org/10.1515/pac-2018-0920\">https://doi.org/10.1515/pac-2018-0920</a>","ieee":"L. Longwitz and T. Werner, “Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling,” <i>Pure and Applied Chemistry</i>, vol. 91, no. 1, pp. 95–102, 2018, doi: <a href=\"https://doi.org/10.1515/pac-2018-0920\">10.1515/pac-2018-0920</a>.","ama":"Longwitz L, Werner T. Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling. <i>Pure and Applied Chemistry</i>. 2018;91(1):95-102. doi:<a href=\"https://doi.org/10.1515/pac-2018-0920\">10.1515/pac-2018-0920</a>"},"language":[{"iso":"eng"}],"page":"95-102","publication":"Pure and Applied Chemistry","publication_identifier":{"issn":["1365-3075","0033-4545"]},"author":[{"first_name":"Lars","full_name":"Longwitz, Lars","last_name":"Longwitz"},{"full_name":"Werner, Thomas","last_name":"Werner","id":"89271","first_name":"Thomas"}],"publication_status":"published","doi":"10.1515/pac-2018-0920","date_created":"2023-01-22T20:45:38Z","department":[{"_id":"35"},{"_id":"2"},{"_id":"657"}],"volume":91,"date_updated":"2023-01-23T10:35:56Z","issue":"1","intvolume":"        91","abstract":[{"text":"<jats:title>Abstract</jats:title>\r\n               <jats:p>Numerous organic transformations are based on the use of stoichiometric amounts of phosphorus reagents. The formation of phosphane oxides from phosphanes is usually the thermodynamic driving force for these reactions. The stoichiometric amounts of phosphane oxide which are formed as by-products often significantly hamper the product purification. Organophosphorus catalysis based on P(III)/P(V) redox cycling aims to address these problems. Herein we present our recent advances in developing catalytic Wittig-type reactions. More specifically, we reported our results on catalytic Wittig reactions based on readily available Bu<jats:sub>3</jats:sub>P=O as pre-catalyst as well as the first microwave-assisted version of this reaction and the first enantioselective catalytic Wittig reaction utilizing chiral phosphane catalysts. Further developments led to the implementation of catalytic base-free Wittig reactions yielding highly functionalized alkylidene and arylidene succinates.</jats:p>","lang":"eng"}],"extern":"1","title":"Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling"}